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RU2008106382A - METHOD FOR COLLECTING 3-ETHYL-3-ALUMINAPENTACYCLO- [12.5.1.02,13.04,12.015,19] IKOSA-4,16-DIENE and 3-Ethyl-3-ALUMINAPENTACYCLO- [12.5.1.02,13.04,12.015,19]] -ICOSA-4.17-DIENA - Google Patents

METHOD FOR COLLECTING 3-ETHYL-3-ALUMINAPENTACYCLO- [12.5.1.02,13.04,12.015,19] IKOSA-4,16-DIENE and 3-Ethyl-3-ALUMINAPENTACYCLO- [12.5.1.02,13.04,12.015,19]] -ICOSA-4.17-DIENA Download PDF

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Publication number
RU2008106382A
RU2008106382A RU2008106382/04A RU2008106382A RU2008106382A RU 2008106382 A RU2008106382 A RU 2008106382A RU 2008106382/04 A RU2008106382/04 A RU 2008106382/04A RU 2008106382 A RU2008106382 A RU 2008106382A RU 2008106382 A RU2008106382 A RU 2008106382A
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Russia
Prior art keywords
ethyl
diene
aluminapentacyclo
icosa
diena
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RU2008106382/04A
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Russian (ru)
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RU2375369C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Рустам Камилевич Тимерханов (RU)
Рустам Камилевич Тимерханов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов (RU)
Леонард Мухибович Халилов
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Priority to RU2008106382/04A priority Critical patent/RU2375369C2/en
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Abstract

Способ совместного получения региоизомерных 3-этил-3-алюминапентацикло[12.5.1.02,13.04,12.015,19]-икоза-4,16-диена и 3-этил-3-aлюминaпeнтaциклo[12.5.1.02,13.04,12.015,19]-икoзa-4,17-диeнa общей формулы (1) и (2), ! ! характеризующийся тем, что циклонона-1,2-диен и дициклопентадиен взаимодействуют с этилалюминийдихлоридом (EtAlCl2) и металлическим магнием в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:дициклопентадиен:EtAlCl2:Mg:Cp2ZrCl2=10: 10:(10-14):(10-14):(0.8-1.2) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч.The method of co-production of regioisomeric 3-ethyl-3-aluminapentacyclo [12.5.1.02,13.04,12.015,19] -icose-4,16-diene and 3-ethyl-3-aluminapentacyclo [12.5.1.02,13.04,12.015,19] - icosa-4,17-diene of the general formula (1) and (2),! ! characterized in that cyclonone-1,2-diene and dicyclopentadiene are reacted with ethyl aluminum dichloride (EtAlCl2) and magnesium metal in the presence of a catalyst of zirconacenedichloride (Cp2ZrCl2) in a molar ratio of cyclonone-1,2-diene: dicyclopentadiene: EtAlCl2: Mg2: = 2: Cl2 10: (10-14) :( 10-14) :( 0.8-1.2) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours.

Claims (1)

Способ совместного получения региоизомерных 3-этил-3-алюминапентацикло[12.5.1.02,13.04,12.015,19]-икоза-4,16-диена и 3-этил-3-aлюминaпeнтaциклo[12.5.1.02,13.04,12.015,19]-икoзa-4,17-диeнa общей формулы (1) и (2),Method coproduction of regioisomeric 3-ethyl-3-alyuminapentatsiklo [12.5.1.0 2,13 .0 4,12 .0 15,19] -ikoza-4,16-diene 3-ethyl-3-alyuminapentatsiklo [12.5.1.0 2 13 .0 4,12 .0 15,19] -ikoza-4,17-diena general formula (1) and (2),
Figure 00000001
Figure 00000001
 характеризующийся тем, что циклонона-1,2-диен и дициклопентадиен взаимодействуют с этилалюминийдихлоридом (EtAlCl2) и металлическим магнием в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:дициклопентадиен:EtAlCl2:Mg:Cp2ZrCl2=10: 10:(10-14):(10-14):(0.8-1.2) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that cyclonone-1,2-diene and dicyclopentadiene are reacted with ethyl aluminum dichloride (EtAlCl 2 ) and metallic metal in the presence of a catalyst of zirconocenti dichloride (Cp 2 ZrCl 2 ) in a molar ratio of cyclonone-1,2-diene: dicyclopentadiene: EtAlCl 2 : Mg : Cp 2 ZrCl 2 = 10: 10: (10-14) :( 10-14) :( 0.8-1.2) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours.
RU2008106382/04A 2008-02-18 2008-02-18 Method of combined production of 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,16-diene and 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,17-diene RU2375369C2 (en)

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RU2008106382/04A RU2375369C2 (en) 2008-02-18 2008-02-18 Method of combined production of 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,16-diene and 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,17-diene

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RU2008106382/04A RU2375369C2 (en) 2008-02-18 2008-02-18 Method of combined production of 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,16-diene and 3-ethyl-3-aluminapentacyclo-[12.5.1.02,13.04,12.015,19]-eicosa-4,17-diene

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DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2160269C1 (en) * 1999-03-15 2000-12-10 Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method of combined preparation of 1-ethyl -2,3-diackyl (phenyl)alumacyclopropenes, 1-ethyl-2,3-dialkyl (phenyl)alumacyclopent-2-enes and 1-ethyl-2,3,4,5-tetraalylalumacyclopentadienes
RU2295532C1 (en) * 2005-08-12 2007-03-20 Открытое акционерное общество "Нижнекамскнефтехим" Method for preparing aluminum alkyls
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane

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