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RU2008105865A - METHOD FOR PRODUCING 3-ETHYL-3-ALUMINETETRACYCLO [12.2.1.02,13.04,12] HEPTADETS-4-ENA - Google Patents

METHOD FOR PRODUCING 3-ETHYL-3-ALUMINETETRACYCLO [12.2.1.02,13.04,12] HEPTADETS-4-ENA Download PDF

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RU2008105865A
RU2008105865A RU2008105865/04A RU2008105865A RU2008105865A RU 2008105865 A RU2008105865 A RU 2008105865A RU 2008105865/04 A RU2008105865/04 A RU 2008105865/04A RU 2008105865 A RU2008105865 A RU 2008105865A RU 2008105865 A RU2008105865 A RU 2008105865A
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ethyl
norbornene
ene
diene
heptadets
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RU2008105865/04A
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Russian (ru)
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RU2375367C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Рустам Камилевич Тимерханов (RU)
Рустам Камилевич Тимерханов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Леонард Мухибович Халилов (RU)
Леонард Мухибович Халилов
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Abstract

Способ получения 3-этил-3-алюминатетрацикло[12.2.1.02,13.04,12]-гептадец-4-ена общей формулы (1), ! ! характеризующийся тем, что эквимольную смесь циклонона-1,2-диена и бицикло[2.2.1]гепт-2-ена (норборнен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:норборнен:ЕtАlСl2:Mg:Ср2ZrСl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч.The method of obtaining 3-ethyl-3-aluminate tetracyclo [12.2.1.02,13.04,12] -heptadec-4-ene of the general formula (1),! ! characterized in that the equimolar mixture of cyclonon-1,2-diene and bicyclo [2.2.1] hept-2-ene (norbornene) is reacted with ethyl aluminum dichloride (EtAlCl2) in the presence of magnesium (powder) and a catalyst of zirconacenedichloride (Cp2ZrCl2) in a molar ratio cyclonone-1,2-diene: norbornene: EtAlCl2: Mg: Cr2ZrCl2 = 10: 10: (10-14) :( 10-14) :( 0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran within 8-12 hours

Claims (1)

Способ получения 3-этил-3-алюминатетрацикло[12.2.1.02,13.04,12]-гептадец-4-ена общей формулы (1),A process for preparing 3-ethyl-3-alyuminatetratsiklo [12.2.1.0 2,13 .0 4,12] -geptadets-4-ene of the general formula (1),
Figure 00000001
Figure 00000001
 характеризующийся тем, что эквимольную смесь циклонона-1,2-диена и бицикло[2.2.1]гепт-2-ена (норборнен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:норборнен:ЕtАlСl2:Mg:Ср2ZrСl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that an equimolar mixture of cyclonon-1,2-diene and bicyclo [2.2.1] hept-2-ene (norbornene) is reacted with ethyl aluminum dichloride (EtAlCl 2 ) in the presence of magnesium (powder) and a catalyst of zirconacene dichloride (Cp 2 ZrCl 2 ) in a molar ratio cyclononyl-1,2-diene: norbornene: EtAlSl 2: Mg: Cp 2 ZrSl 2 = 10: 10 (10-14) :( 10-14) :( 0.4-0.6) in an argon atmosphere at a temperature 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours
RU2008105865/04A 2008-02-15 2008-02-15 Method of producing 3-ethyl-3-aluminatetracyclo[12.2.1.02,13.04,12]heptadec-4-ene RU2375367C2 (en)

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RU2008105865/04A RU2375367C2 (en) 2008-02-15 2008-02-15 Method of producing 3-ethyl-3-aluminatetracyclo[12.2.1.02,13.04,12]heptadec-4-ene

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RU2008105865/04A RU2375367C2 (en) 2008-02-15 2008-02-15 Method of producing 3-ethyl-3-aluminatetracyclo[12.2.1.02,13.04,12]heptadec-4-ene

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DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2160269C1 (en) * 1999-03-15 2000-12-10 Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method of combined preparation of 1-ethyl -2,3-diackyl (phenyl)alumacyclopropenes, 1-ethyl-2,3-dialkyl (phenyl)alumacyclopent-2-enes and 1-ethyl-2,3,4,5-tetraalylalumacyclopentadienes
RU2295532C1 (en) * 2005-08-12 2007-03-20 Открытое акционерное общество "Нижнекамскнефтехим" Method for preparing aluminum alkyls
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane

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