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RU2007126091A - METHOD FOR PRODUCING 9-CHLORO-10,11-DIALKYL-9-ALUMINABicyclo [6.3.0] UNDEKA-1 (8), 10-DIENOV - Google Patents

METHOD FOR PRODUCING 9-CHLORO-10,11-DIALKYL-9-ALUMINABicyclo [6.3.0] UNDEKA-1 (8), 10-DIENOV Download PDF

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Publication number
RU2007126091A
RU2007126091A RU2007126091/04A RU2007126091A RU2007126091A RU 2007126091 A RU2007126091 A RU 2007126091A RU 2007126091/04 A RU2007126091/04 A RU 2007126091/04A RU 2007126091 A RU2007126091 A RU 2007126091A RU 2007126091 A RU2007126091 A RU 2007126091A
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RU
Russia
Prior art keywords
dialkyl
chloro
dienov
aluminabicyclo
undeka
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RU2007126091/04A
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Russian (ru)
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RU2355698C2 (en
Inventor
Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
конов Владимир Анатольевич Дь (RU)
Владимир Анатольевич Дьяконов
Лили Фанисовна Галимова (RU)
Лилия Фанисовна Галимова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Галина Аркадьевна Джемилева (RU)
Галина Аркадьевна Джемилева
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Институт нефтехимии и катализа РАН (RU)
Институт нефтехимии и катализа РАН
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Priority to RU2007126091/04A priority Critical patent/RU2355698C2/en
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Claims (1)

Способ получения 9-хлор-10,11-диалкил-9-алюминабицикло-[6.3.0]ундека-1(8),10-диена общей формулы (1),The method of obtaining 9-chloro-10,11-dialkyl-9-aluminobicyclo- [6.3.0] undeca-1 (8), 10-diene of the general formula (1),
Figure 00000001
Figure 00000001
 характеризующийся тем, что эквимольную смесь циклооктина и диалкил-ацетилена (гекс-3-ин, окт-4-ин, дец-5-ин) подвергают взаимодействию с трихлоралюминием (AlCl3) в присутствии магния (порошок) и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклооктин:диалкилацетилен:AlCl3:Mg:Ср2ZrCl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that an equimolar mixture of cyclooctin and dialkyl-acetylene (hex-3-in, oct-4-in, dec-5-in) is reacted with trichloroaluminium (AlCl 3 ) in the presence of magnesium (powder) and a catalyst for zirconacene dichloride (Cp 2 ZrCl 2 ) in a molar ratio of cyclooctin: dialkylacetylene: AlCl 3 : Mg: Ср 2 ZrCl 2 = 10: 10: (10-14) :( 10-14) :( 0.4-0.6) in an argon atmosphere at normal pressure in tetrahydrofuran in within 8-12 hours
RU2007126091/04A 2007-07-09 2007-07-09 Method of obtaining 9-chloro-10,11-dialkyl-9-aluminabicyclo[6,3,0]undeca-1(8),10-dienes RU2355698C2 (en)

Priority Applications (1)

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RU2007126091/04A RU2355698C2 (en) 2007-07-09 2007-07-09 Method of obtaining 9-chloro-10,11-dialkyl-9-aluminabicyclo[6,3,0]undeca-1(8),10-dienes

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RU2007126091/04A RU2355698C2 (en) 2007-07-09 2007-07-09 Method of obtaining 9-chloro-10,11-dialkyl-9-aluminabicyclo[6,3,0]undeca-1(8),10-dienes

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RU2355698C2 RU2355698C2 (en) 2009-05-20

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RU2280037C2 (en) * 2004-10-05 2006-07-20 ГУ Институт нефтехимии и катализа АН РБ и УНЦ РАН METHOD FOR PREPARING 2,6-DIETHYL-5,7-DIPHENYL-1,2,3,3a,4,6,8,8a-OCTAHYDROALUMACYCLOPENTADIENO[3,4-f]-ISOALUMAINDOLE
RU2283315C1 (en) * 2005-03-30 2006-09-10 Институт нефтехимии и катализа РАН Method for preparing 1-chloro-2,3,4,5-tetraalkylaluminacyclopenta-2,4-dienes

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