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RU2008105866A - METHOD FOR PRODUCING 10-ALKYL-12-Ethyl-12-ALUMINABicyclo [7.3.01.9] DODETS-1 (2) -ENES - Google Patents

METHOD FOR PRODUCING 10-ALKYL-12-Ethyl-12-ALUMINABicyclo [7.3.01.9] DODETS-1 (2) -ENES Download PDF

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RU2008105866A
RU2008105866A RU2008105866/04A RU2008105866A RU2008105866A RU 2008105866 A RU2008105866 A RU 2008105866A RU 2008105866/04 A RU2008105866/04 A RU 2008105866/04A RU 2008105866 A RU2008105866 A RU 2008105866A RU 2008105866 A RU2008105866 A RU 2008105866A
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ene
ethyl
enes
alkyl
cyclonone
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RU2008105866/04A
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RU2375368C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Владимир Анатольевич Дьяконов (RU)
Владимир Анатольевич Дьяконов
Рустам Камилевич Тимерханов (RU)
Рустам Камилевич Тимерханов
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Татьяна Викторовна Тюмкина (RU)
Татьяна Викторовна Тюмкина
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ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской академии наук (RU)
ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук
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Abstract

Способ получения 10-алкил-12-этил-12-алюминабицикло[7.3.01,9]додец-1(2)-енов (1) общей формулы (1), ! ! характеризующийся тем, что эквимольную смесь циклонона-1,2-диена и α-олефина (гекс-1-ен, окт-1-ен, дец-1-ен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:α-олефин:ЕtАlСl2:Mg:Ср2ZrСl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч.The method of obtaining 10-alkyl-12-ethyl-12-aluminobicyclo [7.3.01.9] dodec-1 (2) -enes (1) of the general formula (1),! ! characterized in that the equimolar mixture of cyclonone-1,2-diene and α-olefin (hex-1-ene, oct-1-ene, dec-1-ene) is reacted with ethyl aluminum dichloride (EtAlCl2) in the presence of magnesium (powder) and catalyst for zirconacene dichloride (Cp2ZrCl2) in a molar ratio of cyclonone-1,2-diene: α-olefin: EtAlCl2: Mg: Cp2ZrCl2 = 10: 10: (10-14) :( 10-14) :( 0.4-0.6) in argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours

Claims (1)

Способ получения 10-алкил-12-этил-12-алюминабицикло[7.3.01,9]додец-1(2)-енов (1) общей формулы (1),The method of obtaining 10-alkyl-12-ethyl-12-aluminobicyclo [7.3.0 1.9 ] dodec-1 (2) -enes (1) of the general formula (1),
Figure 00000001
Figure 00000001
 характеризующийся тем, что эквимольную смесь циклонона-1,2-диена и α-олефина (гекс-1-ен, окт-1-ен, дец-1-ен) подвергают взаимодействию с этилалюминийдихлоридом (EtAlCl2) в присутствии магния (порошок) и катализатора цирконацендихлорида (Cp2ZrCl2) в мольном соотношении циклонона-1,2-диен:α-олефин:ЕtАlСl2:Mg:Ср2ZrСl2=10:10:(10-14):(10-14):(0.4-0.6) в атмосфере аргона при температуре 20°С и нормальном давлении в тетрагидрофуране в течение 8-12 ч. characterized in that the equimolar mixture of cyclonone-1,2-diene and α-olefin (hex-1-ene, oct-1-ene, dec-1-ene) is reacted with ethyl aluminum dichloride (EtAlCl 2 ) in the presence of magnesium (powder) and a catalyst of zirconacene dichloride (Cp 2 ZrCl 2 ) in a molar ratio of cyclonone-1,2-diene: α-olefin: EtAlCl 2 : Mg: Cp 2 ZrCl 2 = 10: 10: (10-14) :( 10-14): (0.4-0.6) in an argon atmosphere at a temperature of 20 ° C and normal pressure in tetrahydrofuran for 8-12 hours
RU2008105866/04A 2008-02-15 2008-02-15 Method of producing 10-alkyl-12-ethyl-12-aluminabicyclo[7.3.01,9]dodec-1( 2 )-enes RU2375368C2 (en)

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DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2160269C1 (en) * 1999-03-15 2000-12-10 Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН Method of combined preparation of 1-ethyl -2,3-diackyl (phenyl)alumacyclopropenes, 1-ethyl-2,3-dialkyl (phenyl)alumacyclopent-2-enes and 1-ethyl-2,3,4,5-tetraalylalumacyclopentadienes
RU2295532C1 (en) * 2005-08-12 2007-03-20 Открытое акционерное общество "Нижнекамскнефтехим" Method for preparing aluminum alkyls
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane

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