SU65095A1 - Method of refining lead from copper - Google Patents
Method of refining lead from copperInfo
- Publication number
- SU65095A1 SU65095A1 SU1391A SU322194A SU65095A1 SU 65095 A1 SU65095 A1 SU 65095A1 SU 1391 A SU1391 A SU 1391A SU 322194 A SU322194 A SU 322194A SU 65095 A1 SU65095 A1 SU 65095A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- copper
- lead
- refining
- refining lead
- sodium
- Prior art date
Links
- 239000010949 copper Substances 0.000 title description 14
- 229910052802 copper Inorganic materials 0.000 title description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title description 11
- 238000007670 refining Methods 0.000 title description 5
- 238000000034 method Methods 0.000 title description 4
- 239000002184 metal Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 4
- 239000010931 gold Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052709 silver Inorganic materials 0.000 description 4
- 229910052725 zinc Inorganic materials 0.000 description 4
- 239000011701 zinc Substances 0.000 description 4
- 229910052787 antimony Inorganic materials 0.000 description 3
- 229910052785 arsenic Inorganic materials 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 241000699670 Mus sp. Species 0.000 description 1
- 241001494479 Pecora Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- OXWYKLKNHOSCBS-UHFFFAOYSA-N [Na][Cu][Pb] Chemical compound [Na][Cu][Pb] OXWYKLKNHOSCBS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical class [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Description
При существующем ликвационном методе освобождени Овинца от меди в медные шлик.керы в среднем переходит около 40% золота , наход щегос в полученном из ватер-жакетов веркблее. Выход овинца в шликкеры 1составл ет в среднем 10-25% и вследствие этого приходитс на рафинировочных заводах создавать специальные отделени дл переработки шлвккеров . Переплавка шликкеров в шликкериых печах вл етс достаточно с южной, технически и экономически мало эффективной опе(рацией, так как вызьввает большой угар и потери всех ценных -металлов.With the existing segregation method of freeing Ovintz from copper, on average, about 40% of gold is transferred to copper shells, which is found in the helium obtained from water jacket. The output of the sheep to the slurries 1 is on average 10-25%, and as a result, it is necessary at the refining plants to create special compartments for the processing of the slurries. Melting slips in slip furnaces is sufficient with a southern, technically and economically inefficient operation (as it causes great waste and loss of all valuable metals.
Предлагаемый способ рафинировани свинца от Меди с примене .шем сульфидов заключаетс в TOIM, что рафинкр01ваНие ведут при помощи жидкого натрие.во-овиидовомедиого mTeuiHa.The proposed method of refining lead from copper with the use of sulphides consists in TOIM, that refining is carried out with the help of liquid sodium-ovidiomedate mTeuiHa.
Предлагаемый опособ освобождс;1и от меди выполн етс в один Праем. При этом, благодар тому, что все металлы, наход щиес в .еркблее, распредел ютс уже. не между ДВУМЯ м-еталлическилш фазами , а Л1ежду Металлом и натриевым штейном, удаетс практически полностью сохранить драгоценные металлы в веркблее, откуда ониThe proposed procedure is free; 1i is made of copper in one Pray. However, due to the fact that all the metals in the nodule are already distributed. not between the TWO and metal phases, but between Metal and sodium matte, it is possible to almost completely save precious metals in the back, where they are from
легко, дешево и без заметных потерь быстро могут быть швлечены. Лабораторные в полупроиэводственные опыты показали, что освобождение от меди по предлагаемоAiy сно,собу дает веркблей с весьма малым Содержанием меди- (сотые и даже тыс чные доли процента).can be easily, cheaply and without noticeable losses. Laboratory experiments in semiproducts showed that exemption from copper, according to the proposal, is clear, and it gives a recruit with a very small content of copper (hundredths and even thousandths of a percent).
Обычными ПрИ1МеСЯМИ; к С1ВИНЦу вConventional MEASURES; to the s1vintz in
веркб ее -вл ютс : Си, Sb, As, Sn, Bi, Ag, Au, Cd, Zn, Fe, Ni, Co.its werkb — ex: Cu, Sb, As, Sn, Bi, Ag, Au, Cd, Zn, Fe, Ni, Co.
Кзк было вы влено опытами, оптимальный температурный интервал , В которол протекает освобождение от лгеди натриево-свинцавомедным щтейнол лежит в пределах 500-700° С. Равновесные упругости паров серы при, диссоциации сульфидов перечисленных выше метал700-C составл ют (noKzk was detected by experiments, the optimum temperature range, in which the release of the sodium-lead-copper scale shteynol proceeds within 500-700 ° C.
лов при Еллинвку):Fishing at the Yellingovka):
1,, , ,515
AsoSs BioSsAsoSs BioSs
4,04.0
4,24.2
AgoSAgoS
5,65.6
SnSSns
8,08.0
FeSFes
9,6 9.6
Cu.S 10,0 Cu.S 10.0
FeS 12,2 FeS 12.2
CdS 13.0CdS 13.0
PbSPbS
8,08.0
СравиеНИе -равновесных упруго:стеи диссоциации сульфи дов металлов , вл ющихс Дримес дш к овиНЦу, с упругостью диссоциации сульфидов свинца и меди,-вход щих -в cocTaiB ЖИДКОГО штейиа (NasS, PbS, CugS), показывает, что As, Bi, Sb, Ag и Аи остаютс -в веркблее, а Cd, Си, Zn, частично Sn и по.виостью Металлы группы железл переход т в штен) при -ос.вобождении от меди. Такое распрелелеиие вл етс благопри тным , разложение натрнсвы.м штейном туголлавных химических соединений меди с сурьлюй и .мышь 1КОЛ1, твердых растворов в меди, химических соединений золота и серебра, с цинком и т. д. позвол ет As и Sb полнее извлечь щелочным или опнавым раф«ниро за1нием са-инца, а золото и серебро овделить последующим паркеоированием . Кадмий, свинец и цинк могут быть легко уловлены пылеуловительными установками при переработке щтейна в конверторах медеплавильных заводов: в качестве холодных добавок. Таким образом вед освобождение от меди жидкилг патриеео - свинцово - лшдным щтейном можно не только получить за одну операцию полностью освобожденный от меди веркблей, но н наиболее целесообразно распредел ть существующие в исходном веркблее примеси дл пос.тедующсIO их рационального извлече. существующими способами.Comparison of equilibrium elasticity: the dissociation of metal sulfide dyes, which are Drimes dv to ovici, with the elasticity of dissociation of lead and copper sulphides, entering the cocTaiB of liquid Steyo (NasS, PbS, CugS), shows that As, Bi, s, , Ag, and Au remain вер in sharper, and Cd, Cu, Zn, partly Sn, and by their violence. The metals of the iron group are rolled into pieces) at -os. Release from copper. Such a dispersion is advantageous, the decomposition of sodium and matte chemical compounds of copper with antimony and mice. 1KOL1, solid solutions in copper, chemical compounds of gold and silver, zinc, etc., allows the As and Sb to be more completely removed by alkaline or Openly, it is Niro Zeniem Saenza, and gold and silver should be divided into subsequent parking. Cadmium, lead, and zinc can be easily captured by dust collection plants during the processing of stein in the converters of smelters: as cold additives. Thus, ved copper-free liquid preeeeo-lead-ice shteyn can not only be obtained in one operation completely by a stainless steel butt, but it is most expedient to distribute the impurities present in the original helium for rational extraction. existing ways.
П р е д мет изобретен и PRED MET INITIATED AND
Способ р.афИнированИЯ CBi-гнца от меди с применениелг суль.ф доа, о т л И: чающийс тем, что рафйнирова-Ние ведут при помощи жидкого натриево-овинцово-медпого штейна.The method of affixing CBi-gnts from copper with the use of sul. Foda, about tl i: due to the fact that refining is carried out with the help of a liquid sodium-ovintsov-medpy matte.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1391A SU65095A1 (en) | 1943-05-18 | 1943-05-18 | Method of refining lead from copper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU1391A SU65095A1 (en) | 1943-05-18 | 1943-05-18 | Method of refining lead from copper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU65095A1 true SU65095A1 (en) | 1944-11-30 |
Family
ID=51293241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1391A SU65095A1 (en) | 1943-05-18 | 1943-05-18 | Method of refining lead from copper |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU65095A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2177045C1 (en) * | 2001-02-14 | 2001-12-20 | Федеральное Государственное Унитарное Предприятие "Государственный Научно-Исследовательский Институт Цветных Металлов "Гинцветмет" | Method for fine decopperization of lead |
-
1943
- 1943-05-18 SU SU1391A patent/SU65095A1/en active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2177045C1 (en) * | 2001-02-14 | 2001-12-20 | Федеральное Государственное Унитарное Предприятие "Государственный Научно-Исследовательский Институт Цветных Металлов "Гинцветмет" | Method for fine decopperization of lead |
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