MX2009003369A - Composiciones de poliester. - Google Patents
Composiciones de poliester.Info
- Publication number
- MX2009003369A MX2009003369A MX2009003369A MX2009003369A MX2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A MX 2009003369 A MX2009003369 A MX 2009003369A
- Authority
- MX
- Mexico
- Prior art keywords
- mole
- titanium
- phosphorus
- ethylene glycol
- residues
- Prior art date
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title abstract 10
- 229920000728 polyester Polymers 0.000 title abstract 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 title abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title 1
- NBBUYPNTAABDEY-UHFFFAOYSA-N cyclobutane-1,1-diol Chemical compound OC1(O)CCC1 NBBUYPNTAABDEY-UHFFFAOYSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 229910052698 phosphorus Inorganic materials 0.000 title 1
- 239000011574 phosphorus Substances 0.000 title 1
- 229910052719 titanium Inorganic materials 0.000 title 1
- 239000010936 titanium Substances 0.000 title 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical group CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical group OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-N terephthalic acid group Chemical group C(C1=CC=C(C(=O)O)C=C1)(=O)O KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Se describen como un aspecto de la invención composiciones de poliéster que comprenden por lo menos un poliéster que comprende: (a) un componente de ácido dicarboxílico que comprende: (i) aproximadamente 90 a aproximadamente 100% en mol de residuos de ácido tereftálico; (ii) aproximadamente 0 a aproximadamente 10% en mol de residuos de ácido dicarboxílico aromático y/o alifático que tiene hasta 20 átomos de carbono; y (b) un componente de glicol que comprende: (i) aproximadamente 1 a menor que 90% mol de residuos de 2,2,4,4,-tetrametil-1,3-ciclobutanodiol; y (ii) aproximadamente 0 a aproximadamente 89% en mol de residuos de ciclohexanodimetanol; (iii) mayor que 10% en mol de residuos de etilenglicol, y (iv) menor que aproximadamente 2% en mol de un glicol de modificación que tiene de 3 a 16 átomos de carbono; (c) átomos de titanio y átomos de fósforo, en donde el % en mol total del componente de ácido dicarboxílico es 100% en mol, y en donde el % en mol total del componente de glicol es 100% en mol; y en donde la viscosidad inherente del poliéster es de 0.50 a 1.2 dL/g como es determinado en 60/40 (peso/peso) fenol/tetracloroetano a una concentración de 0.25 g/50 ml a 25ºC. Los poliésteres se pueden manufacturar en artículos.
Applications Claiming Priority (24)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/588,458 US20070100122A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol and articles made therefrom |
| US11/588,524 US20100096589A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing low amounts of cyclobutanediol and articles made therefrom |
| US11/588,554 US20070100125A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
| US11/588,907 US20070106054A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom |
| PCT/US2006/042293 WO2007053550A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having high glass transition temperature and articles made therefrom |
| PCT/US2006/041917 WO2007053434A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| US11/588,906 US8193302B2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof |
| PCT/US2006/042292 WO2007053549A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| US11/588,527 US20100087574A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| PCT/US2006/042291 WO2007053548A2 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions comprising minimal amounts of cyclobutanediol |
| US11/588,883 US20070105993A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| PCT/US2006/042069 WO2007053460A1 (en) | 2005-10-28 | 2006-10-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| US11/635,433 US20070142511A1 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
| US11/635,434 US7737246B2 (en) | 2005-12-15 | 2006-12-07 | Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor |
| US11/706,791 US20070232779A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclohexanedimethanol, moderate cyclobutanediol, cyclohexanedimethanol, and high trans cyclohexanedicarboxylic acid |
| US11/706,476 US20070232778A1 (en) | 2006-03-28 | 2007-02-14 | Certain polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and high trans-cyclohexanedicarboxylic acid |
| PCT/US2007/007632 WO2007126855A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| PCT/US2007/007532 WO2007123631A1 (en) | 2006-03-28 | 2007-03-27 | Polyester compositions which comprise cyclobutanediol and at least one phosphorus compound |
| PCT/US2007/010551 WO2007139653A1 (en) | 2006-05-23 | 2007-05-02 | Lcd films or sheets comprising films comprising polyester compositions formed from 2,2,4,4,-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| PCT/US2007/010590 WO2007139655A1 (en) | 2006-05-23 | 2007-05-02 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| PCT/US2007/011150 WO2007139663A1 (en) | 2006-05-23 | 2007-05-09 | Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof |
| US91731607P | 2007-05-10 | 2007-05-10 | |
| US11/773,275 US8586701B2 (en) | 2005-10-28 | 2007-07-03 | Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
| PCT/US2007/015704 WO2008051321A1 (en) | 2006-10-27 | 2007-07-10 | Polyester compositions which comprise cyclobutanediol, ethylene glycol, titanium, and phosphorus with improved color and manufacturing processes therefor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009003369A true MX2009003369A (es) | 2009-04-14 |
Family
ID=47831243
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009003369A MX2009003369A (es) | 2006-10-27 | 2007-07-10 | Composiciones de poliester. |
| MX2009003375A MX2009003375A (es) | 2006-10-27 | 2007-07-10 | Composiones de poliester que comprenden tetrametilciclobutanodiol, ciclohexanodimetanol y etilenglicol, y procesos de manufctura para las mismas. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009003375A MX2009003375A (es) | 2006-10-27 | 2007-07-10 | Composiones de poliester que comprenden tetrametilciclobutanodiol, ciclohexanodimetanol y etilenglicol, y procesos de manufctura para las mismas. |
Country Status (8)
| Country | Link |
|---|---|
| EP (2) | EP2074174A1 (es) |
| JP (2) | JP2010507716A (es) |
| KR (2) | KR20090079211A (es) |
| BR (2) | BRPI0717761A2 (es) |
| CA (2) | CA2666571A1 (es) |
| MX (2) | MX2009003369A (es) |
| TW (2) | TW200819497A (es) |
| WO (4) | WO2008051320A1 (es) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8168721B2 (en) * | 2009-02-06 | 2012-05-01 | Eastman Chemical Company | Coating compositions containing tetramethyl cyclobutanediol |
| US8163850B2 (en) * | 2009-02-06 | 2012-04-24 | Eastman Chemical Company | Thermosetting polyester coating compositions containing tetramethyl cyclobutanediol |
| US9029460B2 (en) * | 2009-02-06 | 2015-05-12 | Stacey James Marsh | Coating compositions containing acrylic and aliphatic polyester blends |
| US7915374B2 (en) * | 2009-04-27 | 2011-03-29 | Eastman Chemical Company | Copolyesters having improved thermal stability and methods for making them |
| US9156941B2 (en) * | 2010-12-20 | 2015-10-13 | Eastman Chemical Company | Color in titanium catalyzed polyesters |
| US8309624B2 (en) * | 2011-01-17 | 2012-11-13 | Eastman Chemical Company | Haze reduction for blends of aromatic-aliphatic polyesters and antimicrobial additives |
| US8580872B2 (en) * | 2011-07-21 | 2013-11-12 | Eastman Chemical Company | Sulfopolyester polymer compositions with improved water dispersibility |
| TWI491664B (zh) | 2011-11-01 | 2015-07-11 | Midori Anzen Co Ltd | 樹脂組成物及成形體 |
| US8623483B1 (en) * | 2012-10-23 | 2014-01-07 | Eastman Chemical Company | Copolyesters containing neopentyl glycol and 2,2,4,4-tetraalkyl 1,3-cyclobutanediol |
| WO2015125644A1 (ja) * | 2014-02-24 | 2015-08-27 | 東レ株式会社 | ポリエステルフィルム |
| JPWO2015129500A1 (ja) * | 2014-02-27 | 2017-03-30 | 東レ株式会社 | 積層フィルム |
| JP6323872B2 (ja) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | 電子写真用トナー |
| JP6323871B2 (ja) * | 2014-07-31 | 2018-05-16 | 花王株式会社 | 電子写真用トナー |
| JP2015028177A (ja) * | 2014-09-22 | 2015-02-12 | イーストマン ケミカル カンパニー | ポリエステルを製造するための改善された方法 |
| WO2018035335A1 (en) | 2016-08-18 | 2018-02-22 | Eastman Chemical Company | Polyester compositions which comprise tetramethyl cyclobutanediol and ethylene glycol, with improved catalyst system |
| CN109563252B (zh) | 2016-08-18 | 2022-04-26 | 伊士曼化工公司 | 使用改进的催化剂体系的包含四甲基环丁二醇和乙二醇的聚酯组合物 |
| EP3500615B1 (en) | 2016-08-18 | 2025-08-06 | Eastman Chemical Company | Oriented films and shrink films comprising polyesters which comprise tetramethyl cyclobutanediol and ethylene glycol |
| KR102589382B1 (ko) * | 2018-08-08 | 2023-10-12 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조방법 |
| EP4007699A1 (en) * | 2019-08-02 | 2022-06-08 | Eastman Chemical Company | Multilayer sheet |
| US20220372216A1 (en) * | 2019-10-08 | 2022-11-24 | Eastman Chemical Company | Catalyst systems for crystallizable reactor grade resins |
| KR102498421B1 (ko) * | 2020-08-19 | 2023-02-10 | 효성티앤씨 주식회사 | 폴리에스터 성형체 및 그의 제조방법 |
| US11788317B2 (en) * | 2020-09-28 | 2023-10-17 | Kathryn Corcoran | Cell phone canopy |
| JP2023544827A (ja) * | 2020-10-08 | 2023-10-25 | イーストマン ケミカル カンパニー | 収縮性ポリエステルフィルム |
| JP7647302B2 (ja) * | 2021-04-28 | 2025-03-18 | 三菱ケミカル株式会社 | カード又はパスポート用樹脂組成物、カード又はパスポート用フィルム、カード、及びパスポート |
| JP7647301B2 (ja) * | 2021-04-28 | 2025-03-18 | 三菱ケミカル株式会社 | カード又はパスポート用樹脂組成物、カード又はパスポート用フィルム、カード、及びパスポート |
| JP7700515B2 (ja) * | 2021-05-28 | 2025-07-01 | 三菱ケミカル株式会社 | カード又はパスポート用樹脂組成物、カード又はパスポート用フィルム、カード、及びパスポート |
| WO2024164223A1 (en) * | 2023-02-09 | 2024-08-15 | Eastman Chemical (China) Co., Ltd. | Molded polyester articles with improved aesthetic chemical resistance |
| WO2025136741A1 (en) * | 2023-12-18 | 2025-06-26 | Eastman Chemical Company | Films for use in dental appliances |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4525504A (en) * | 1983-10-24 | 1985-06-25 | Eastman Kodak Company | Stabilized polyester compositions suitable for outdoor applications |
| US6495656B1 (en) * | 1990-11-30 | 2002-12-17 | Eastman Chemical Company | Copolyesters and fibrous materials formed therefrom |
| US5498668A (en) * | 1994-10-31 | 1996-03-12 | Eastman Chemical Company | Blends of certain polyesters with acrylics |
| US6043322A (en) * | 1996-12-28 | 2000-03-28 | Eastman Chemical Company | Clear polycarbonate and polyester blends |
| US6037424A (en) * | 1996-12-28 | 2000-03-14 | Eastman Chemical Company | Clear blends of polycarbonates and polyesters |
| US5989663A (en) * | 1996-12-30 | 1999-11-23 | Eastman Chemical Company | Blow-molding polyesters from terephthalic acid, 2, 2, 4, 4-tetramethyl-1,3-cyclobutanediol, and ethylene glycol |
| US6120889A (en) * | 1999-06-03 | 2000-09-19 | Eastman Chemical Company | Low melt viscosity amorphous copolyesters with enhanced glass transition temperatures |
| MXPA06000426A (es) * | 2003-07-11 | 2006-03-17 | Eastman Chem Co | Adicion de absorbedores uv al proceso de pet para rendimiento maximo. |
| US20050010017A1 (en) * | 2003-07-11 | 2005-01-13 | Blakely Dale Milton | Addition of UV inhibitors to pet process for maximum yield |
| US20060094858A1 (en) * | 2004-10-28 | 2006-05-04 | Turner Sam R | Novel copolyester compositions with improved impact strength at low temperatures |
| WO2007053549A1 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
| JP2009513799A (ja) * | 2005-10-28 | 2009-04-02 | イーストマン ケミカル カンパニー | 最小量のシクロブタンジオールを含むポリエステル組成物 |
-
2007
- 2007-07-10 KR KR1020097008483A patent/KR20090079211A/ko not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015701 patent/WO2008051320A1/en not_active Ceased
- 2007-07-10 WO PCT/US2007/015713 patent/WO2008054560A2/en not_active Ceased
- 2007-07-10 JP JP2009534565A patent/JP2010507716A/ja not_active Withdrawn
- 2007-07-10 CA CA002666571A patent/CA2666571A1/en not_active Abandoned
- 2007-07-10 MX MX2009003369A patent/MX2009003369A/es unknown
- 2007-07-10 EP EP07836026A patent/EP2074174A1/en not_active Withdrawn
- 2007-07-10 KR KR1020097008484A patent/KR20090079212A/ko not_active Withdrawn
- 2007-07-10 TW TW096125125A patent/TW200819497A/zh unknown
- 2007-07-10 CA CA002666585A patent/CA2666585A1/en not_active Abandoned
- 2007-07-10 BR BRPI0717761-5A patent/BRPI0717761A2/pt not_active Application Discontinuation
- 2007-07-10 WO PCT/US2007/015702 patent/WO2008054559A1/en not_active Ceased
- 2007-07-10 JP JP2009534566A patent/JP2010507717A/ja not_active Withdrawn
- 2007-07-10 TW TW096125089A patent/TW200819496A/zh unknown
- 2007-07-10 EP EP07836029A patent/EP2074158A1/en not_active Withdrawn
- 2007-07-10 WO PCT/US2007/015704 patent/WO2008051321A1/en not_active Ceased
- 2007-07-10 MX MX2009003375A patent/MX2009003375A/es unknown
- 2007-07-10 BR BRPI0717755-0A patent/BRPI0717755A2/pt not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| WO2008051320A1 (en) | 2008-05-02 |
| WO2008054560A2 (en) | 2008-05-08 |
| TW200819496A (en) | 2008-05-01 |
| MX2009003375A (es) | 2009-04-14 |
| JP2010507716A (ja) | 2010-03-11 |
| KR20090079211A (ko) | 2009-07-21 |
| WO2008051321A8 (en) | 2008-07-10 |
| WO2008051321A1 (en) | 2008-05-02 |
| EP2074174A1 (en) | 2009-07-01 |
| CA2666585A1 (en) | 2008-05-02 |
| CA2666571A1 (en) | 2008-05-02 |
| BRPI0717761A2 (pt) | 2013-03-12 |
| EP2074158A1 (en) | 2009-07-01 |
| WO2008054560A3 (en) | 2008-07-24 |
| KR20090079212A (ko) | 2009-07-21 |
| JP2010507717A (ja) | 2010-03-11 |
| WO2008054559A1 (en) | 2008-05-08 |
| BRPI0717755A2 (pt) | 2013-03-12 |
| TW200819497A (en) | 2008-05-01 |
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