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WO1993002321A1 - Procede d'incineration de materiaux, notamment de graphite irradie - Google Patents

Procede d'incineration de materiaux, notamment de graphite irradie Download PDF

Info

Publication number
WO1993002321A1
WO1993002321A1 PCT/FR1992/000659 FR9200659W WO9302321A1 WO 1993002321 A1 WO1993002321 A1 WO 1993002321A1 FR 9200659 W FR9200659 W FR 9200659W WO 9302321 A1 WO9302321 A1 WO 9302321A1
Authority
WO
WIPO (PCT)
Prior art keywords
suspension
graphite
combustion
particles
solid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FR1992/000659
Other languages
English (en)
French (fr)
Inventor
Gérard Antonini
Olivier Lepez
Jean-Pierre Perotin
Philippe Sajet
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GRADIENT
Association Gradient
Original Assignee
GRADIENT
Association Gradient
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GRADIENT, Association Gradient filed Critical GRADIENT
Priority to JP5502617A priority Critical patent/JPH0697088B2/ja
Priority to EP92915960A priority patent/EP0593665B1/de
Priority to DE69208467T priority patent/DE69208467T2/de
Publication of WO1993002321A1 publication Critical patent/WO1993002321A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F9/00Treating radioactively contaminated material; Decontamination arrangements therefor
    • G21F9/04Treating liquids
    • G21F9/06Processing
    • G21F9/14Processing by incineration; by calcination, e.g. desiccation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/18Radioactive materials

Definitions

  • the present invention relates to a method for incinerating graphite, in particular irradiated graphite and more generally a combustible material, such as waste, with a limited production of fumes, in order to avoid significant and costly treatment thereof.
  • the invention proposes a process for incinerating a material, with a prior preparation of the latter.
  • the process comprises, before combustion, the continuous production of the following steps: division of the material into particles,
  • the oxidizing gas can be oxygen or enriched air and the pressure of the foam obtained will be of the order of 2 to 10 bars, depending on whether the opening of a regulating valve located before the combustion furnace, i.e. the pressure in the furnace and the pressure drop between the pump outlet and the combustion furnace.
  • the maximum of the solid fraction (from 35 to 45% by weight of the suspension) will depend on the apparent density of the pulverized solid and on its lower calorific value. For example, since graphite has a high calorific value and an apparent density, the solid fraction will be of the order of 35%. For lower criteria, the fraction may be higher without damaging the pumpable nature of the product or leading to too hot combustion.
  • the powdered graphite obtained at the outlet of the mills 2 is added with water in a mixer 3.
  • a pump 4 With the aid of a pump 4, the continuous circulation of the product coming from the mixer 3 is ensured in the direction for example of a concentration 5 (acting by measuring the viscosity for example) to result in a mixer 6 for adjusting this concentration by adding water.
  • the product leaving this mixer 6 will have a content at most equal to 35% of solid particles.
  • This is a relatively charged aqueous suspension which is very easily pumpable.
  • This suspension is by means of a pump 7 introduced into a mixer 8 intended to produce a three-phase liquid-solid-gas mixture. To do this, is introduced into the mixer, in addition to the suspension to be transformed into foam, surfactant additives 9 and a swelling gas 10. In the present case the gas will be oxygen.
  • the pressurization of the foam has a double advantage: firstly it becomes self-propelling by partial expansion in the supply lines 12 of a combustion hearth 13, and secondly the relaxation of this foam in the hearth promotes his injection.
  • the hearth 13 is a cyclone hearth known in itself which has the advantages mentioned above with regard to the residence time of the particles and the relative gas-solid speed, in order to achieve complete combustion of the product.
  • Oxygen 14 is introduced into the hearth 13 as combustion gas. It should be noted that the combustion may include a post-combustion stage.
  • the ashes are collected in an ashtray 15 while the fumes 16 are led into a water cooler 17 which makes it possible to condense the water vapor produced by combustion.
  • This cooler will include a devesiculator retaining the droplets of water.
  • the fumes thus freed from the aqueous effluents pass through a heater 18 which places them at a temperature above the dew point to avoid any condensation which could be detrimental to the operation of the very high efficiency filters 19 through which the fumes pass.
  • These filters make it possible to trap the solid residues 20 while the gaseous phase of the fumes is transmitted to the atmosphere by an extraction fan and a chimney 22.

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Gasification And Melting Of Waste (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)
  • Structure Of Printed Boards (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Air Supply (AREA)
PCT/FR1992/000659 1991-07-15 1992-07-09 Procede d'incineration de materiaux, notamment de graphite irradie Ceased WO1993002321A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP5502617A JPH0697088B2 (ja) 1991-07-15 1992-07-09 特に廃グラファイトの焼却方法
EP92915960A EP0593665B1 (de) 1991-07-15 1992-07-09 Verfahren zur einäscherung von materialen, insbesondere von bestrahltem graphit
DE69208467T DE69208467T2 (de) 1991-07-15 1992-07-09 Verfahren zur einäscherung von materialen, insbesondere von bestrahltem graphit

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR91/08899 1991-07-15
FR9108899A FR2679320B1 (fr) 1991-07-15 1991-07-15 Procede d'incineration de materiaux, notamment de graphite irradie.

Publications (1)

Publication Number Publication Date
WO1993002321A1 true WO1993002321A1 (fr) 1993-02-04

Family

ID=9415106

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR1992/000659 Ceased WO1993002321A1 (fr) 1991-07-15 1992-07-09 Procede d'incineration de materiaux, notamment de graphite irradie

Country Status (8)

Country Link
EP (1) EP0593665B1 (de)
JP (1) JPH0697088B2 (de)
AT (1) ATE134432T1 (de)
CA (1) CA2113109C (de)
DE (1) DE69208467T2 (de)
ES (1) ES2085632T3 (de)
FR (1) FR2679320B1 (de)
WO (1) WO1993002321A1 (de)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2014736A1 (de) * 1968-07-26 1970-04-17 Prenco Mfg Co
US3848548A (en) * 1973-11-27 1974-11-19 Hercules Inc Incineration process for disposal of waste propellant and explosives
FR2318385A1 (fr) * 1975-07-16 1977-02-11 Creusot Loire Procede et installation de recuperation de dechets liquides combustibles

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2014736A1 (de) * 1968-07-26 1970-04-17 Prenco Mfg Co
US3848548A (en) * 1973-11-27 1974-11-19 Hercules Inc Incineration process for disposal of waste propellant and explosives
FR2318385A1 (fr) * 1975-07-16 1977-02-11 Creusot Loire Procede et installation de recuperation de dechets liquides combustibles

Also Published As

Publication number Publication date
CA2113109A1 (fr) 1993-02-04
JPH0697088B2 (ja) 1994-11-30
FR2679320A1 (fr) 1993-01-22
JPH06503874A (ja) 1994-04-28
CA2113109C (fr) 1997-01-21
DE69208467D1 (de) 1996-03-28
DE69208467T2 (de) 1996-09-05
EP0593665B1 (de) 1996-02-21
EP0593665A1 (de) 1994-04-27
FR2679320B1 (fr) 1993-10-15
ES2085632T3 (es) 1996-06-01
ATE134432T1 (de) 1996-03-15

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