RU2161635C2 - Polymer composition with antistatic finishing, method of preparing thereof and composition for antistatic finishing - Google Patents

Abstract

FIELD: chemistry of polymers. SUBSTANCE: described is polymer composition with antistatic finishing comprising thermoplastic, structurally cross-linked elastomeric or thermoreactive polymer, antistatic agent containing inorganic salts, and filler. Composition comprises per 100 wt parts of said polymer (a) 0.01-70 wt % of polar filler, adsorbing inorganic or organic material in the form of fibers which are granular or fibrous natural organic materials contacting with each other onto which absorptionally bonded is (b) polar antistatic agent consisting of mixture comprising, ((b¹)) 0.01-20 wt parts per 10 wt parts of polyoxyalkylene polymer of formula I:

wherein R₁, is H, C₁-C₂₄ alkyl, C₂-C₂₄ alkylene, C₁-C₂₄ alkyl C(O)C₂-C₂₄ alkylene C(O),

or

; R₂ is C₁-C₂₄ alkyl, C₂-C₂₄ alkenyl, CH₂COOH or N(C₁-C₈-alkil)₃Ha] or if r=O, R₂ is

or

; R₃ is H or CH₃. Hal is Cl, Br or J, n is integer of equal or grater than 2, p is integer of 1 to 6, and q and r independently are 0 or 1; and in which (b²) 0.01-0.5 wt parts of inorganic salt per 100 wt parts of said polymer, consisting of

is solvated or forms complex in polyoxyalkylene of formula I, ratio of component ((b¹) to inorganic salt ((b²) being from 200:1 to 1:1. Described are method of preparing composition and composition for antistatic finishing. EFFECT: increased antistatic effect that imparts to polymer electric conduction and stable antistatic properties. 12 cl, 6 ex, 1 tbl

Description

 The invention relates to a polymer composition with an antistatic finish, a process for its preparation and a composition for antistatic finish. The inventive composition may find application for insulation of wires or cables. It can also be used for the manufacture of decorative films, foams, agricultural films, hoses, gaskets and more.

 It is known that polymers are subject to strong electrification and, as a result of limited electrical conductivity, discharge very slowly. However, in addition to the aesthetic aspect, various safety aspects require quick discharge.

 Complications encountered in practice can include: contamination of the polymer surface, electric shock to personnel in contact with polymers, damage to products during bonding of polymer sheets, destruction of electronic parts, clumping of polymer powders and sparking as a result of strong electrification followed by fire, which very often leads to severe explosions.

 It is known that static charge can be limited by the introduction of supplements that increase surface conductivity. However, these substances have the disadvantage that, as a result of limited moisture absorption in air, they are practically ineffective. Therefore, it is better to use additives that increase bulk conductivity. However, known substances that increase bulk conductivity, such as carbon black or metal powder, impair the mechanical properties of polymers and cannot be used for transparent polymers. This is often joined by the requirement that the supplement be environmentally friendly. Other types of antistatic additives and static electricity mechanism can be found, for example, in "Plastics Additives", Handbook, Herausgeber R. Gachter und H. Muller, Hanser Verlag, 3. Auflage, 1990, s. 749-775.

 In order to achieve a permanent antistatic finish according to DE 4324062, a material with a large surface, such as, for example, fiber, is coated with a colorless substance with a semiconductor conductivity, for example zinc oxide. A material with such a coating is then mixed with polymer granules and processed into a product. Such a coating, of course, is used to obtain a coating with semiconductor properties. It is necessary to impregnate the fibrous substrate with an aqueous salt solution, followed by drying and thermal conditioning of the separated salts. Such chemical and thermal treatment of the fiber can damage it, so that limited conductivity can be achieved instead of the expected conductivity of the semiconductor. Another disadvantage is that the fiber breaks under the action of a mechanical load, and a brittle semiconductor coating can break, resulting in impaired conductivity.

 Another method is described in DE 4316607. It is proposed to add metallized chemical fiber, which is commercially available, in lubricating, adhesive or coating compositions to increase electrical conductivity. However, metallized fibers are relatively expensive, their production is expensive, and they greatly reduce the transparency of the polymers into which they are introduced. Mechanical damage to the conductive layer and the fiber itself (tearing) cannot be completely repaired.

Known composition with antistatic finish and method for antistatic finish of polymers described in patent WO 94/29401 A, C 09 K 3/16, 1994 (or in the application EP-A-0654515). The composition includes a polymer, an inorganic particulate filler, and an antistatic agent. The component used as an antistatic agent is a solution of an organic or inorganic salt, for example, LiNO ₃ salt in an organic solvent (for example glycol). The specified composition has insufficiently high antistatic properties.

 Therefore, there is a need for additives that have an effective antistatic effect at low air humidity and are environmentally friendly to increase bulk conductivity, which could be achieved by a simple method and would be stable over time, and which could be introduced into various without limitation commercially available polymers .

 The basis of the invention is the development of a polymer composition with an antistatic finish, a method for its preparation and a composition for antistatic finish, having a highly effective antistatic effect, giving the polymer electrical conductivity, stable antistatic properties.

The problem is solved in that the polymer composition with an antistatic finish, including a thermoplastic, structurally cross-linked elastomeric or thermosetting polymer, an antistatic agent containing an inorganic salt, and a filler according to the invention contains 100 parts by weight the specified polymer:
(a) 0.01-70 wt. including filler - a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in joint contact with each other, on which adsorption is connected
(b) a polar antistatic agent consisting of a mixture containing
(b ') 0.01 to 20 wt. parts per 100 parts of a polyoxyalkylene polymer of the formula (I):
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ (I)
where R ₁ means H, C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, C ₁ -C ₂₄ alkyl-C (O) -, C ₂ -C ₂₄ alkenyl-C (O) -, CH ₂ = CH-C (O) - or CH ₂ = (CH ₃ ) C (O) -,
R ₂ is C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, CH ₂ COOH or
N (C ₁ -C ₈ -alkyl) ₃ Hal or,
if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -,
R ₃ means H or CH ₃ ,
Hal means Cl, Br or J,
n is the number ≥ (greater than or equal to) 2,
p is a number from 1 to 6 and
q and r, independently of one another, mean 0 or 1; and in which
(b ² ) 0.01 to 5 parts by weight of inorganic salt per 100 parts of said polymer selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , solvated or complexed in the polyoxyalkylene of formula (I);
moreover, the ratio of component (b ¹ ) and inorganic salt (b ² ) is from 200: 1 to 1: 1.

 The specified thermoplastic, structurally cross-linked elastomeric or thermosetting polymer is preferably selected from the group of compounds consisting of polyolefins, polystyrenes, polymers of α, β-unsaturated acids, halogen-containing polymers, homo- and copolymers of cyclic ethers, polymers of unsaturated alcohols and amines, polyacetals, polyphenols , polyurethanes, polyamides, polyesters, polyureas, polycarbonates, polysulfones, products of the crosslinking of aldehydes with phenols, on the one hand, urea or melamine, with nother hand, alkyd resins, crosslinkable acrylic resins, crosslinked epoxy resins, natural rubber cellulose.

 According to the invention, thermoplastic, structurally cross-linked or thermosetting polymers are more preferably selected from the group of compounds consisting of polyolefins, polystyrenes, polymers of α, β-unsaturated acids, halogen-containing polymers, homo- and copolymers of cyclic ethers.

 The inventive composition may contain as natural fibers chopped wood or vegetable waste, cotton, bast, jute, kapok, remy, linen, hemp, wool or silk. Organic fibers preferably have a length of 0.01-200 mm.

The inventive composition preferably contains a polyoxyalkylene of formula (I), where R ₁ means H, C ₁ -C ₄ -alkyl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) - or polyoxyalkylene of formula (I), where R ₂ is C ₆ -C ₂₀ alkyl, C ₆ -C ₂₀ alkenyl or N (C ₁ -C ₈ alkyl) ₃ Cl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) —C (O) -, where n is a number from 2 to 20, and p is a number from 2 to 6.

 The inventive composition as compounds of formula (I) may contain a compound selected from the group consisting of polypropylene glycol laurate, polypropylene glycol oleyl ether, polypropylene glycol methyl diethyl ammonium chloride, polyethylene glycol monomethyl ether, polyethylene glycol dimethyl ether, polyethylene glycol polyethylene glycol polyethylene glycol polyethylene glycol polyethylene glycol polyethylene glycol polyethylene glycol stearate, simple lauryl ether polyethylene glycol polypropi carboxylic acid, polyethylene glycol lauryl ether, polyethylene glycol diacrylate, β-monoacrylate and β-triacrylate and polyethylene glycol dimethacrylate, β-monomethacrylate and β-trimethacrylate.

The invention is also a method for producing a polymer with an antistatic finish by mixing a thermoplastic, structurally crosslinked elastomeric or thermosetting polymer with an antistatic agent containing an inorganic salt and a filler using a mixing device selected from the group consisting of calendars, rollers, mixers, extruders, with the introduction of or without the introduction of target additives, in which according to the invention 100 wt. parts of the polymer are mixed with
(a) 0.01-70 parts by weight of a filler — a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in joint contact with each other, on which adsorption is connected
(b) a polar antistatic agent consisting of a mixture containing
(b ¹ ) 0.01 to 20 wt. parts per 100 parts of a polyoxyalkylene polymer of the formula (I):
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ (I) where
R ₁ is H, C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, C ₁ -C ₂₄ alkyl-C (O) -, C ₂ -C ₂₄ alkenyl-C (O) -, CH ₂ = CH-C (O) - or CH ₂ = (CH ₃ ) C (O) -,
R ₂ is C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, CH ₂ COOH or
N (C ₁ -C ₈ -alkyl) ₃ Hal or,
if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -,
R ₃ means H or CH ₃ ,
Hal means Cl, Br or J,
n is the number ≥ (greater than or equal to) 2,
p is a number from 1 to 6 and
q and r, independently of one another, mean 0 or 1; and in which
(b ² ) 0.01 to 5 parts by weight of inorganic salt per 100 parts of said polymer selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , solvated or complexed in the polyoxyalkylene of formula (I);
moreover, the ratio of component (b ¹ ) and inorganic salt (b ² ) is from 200: 1 to 1: 1 in the form as it is, or in the form of components administered separately.

A composition for antistatic finishing, comprising an antistatic and a filler, which according to the invention contains
(a) 0.01-70 parts by weight of a filler — a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in joint contact with each other, on which adsorption is connected
(b) a polar antistatic agent consisting of a mixture containing
(b ¹ ) 0.01 to 20 parts by weight of a polyoxyalkylene of formula (I):
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ (I) where
R ₁ is H, C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, C ₁ -C ₂₄ alkyl-C (O) -, C ₂ -C ₂₄ alkenyl-C (O) -, CH ₂ = CH-C (O) - or CH ₂ = (CH ₃ ) C (O) -,
R ₂ is C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, CH ₂ COOH or
N (C ₁ -C ₈ -alkyl) ₃ Hal or,
if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -,
R ₃ means H or CH ₃ ,
Hal means Cl, Br or J,
n is the number ≥ (greater than or equal to) 2,
p is a number from 1 to 6 and
q and r, independently of one another, mean 0 or 1; and in which
(b ² ) 0.01 to 5 parts by weight of an inorganic salt selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , solvated or complexed in the polyoxyalkylene of formula (I);
moreover, the ratio of component (b ¹ ) and inorganic salt (b ² ) is from 200: 1 to 1: 1.

 The inventive compositions have a highly effective antistatic effect and have stable antistatic properties.

 It was found that polar organic compounds containing at least 5 C atoms and at least 3 heteroatoms in combination with an inorganic salt adsorbed as adsorbents on the surface or in the pores of inorganic or organic substances can be introduced into thermoplastic, structurally - crosslinked or cured (capable of crosslinking) polymers and give them excellent and stable antistatic properties. In the case of polar inorganic or organic porous materials, organic compounds with inorganic salts can be introduced into them and adsorbed, which leads to a particularly stable effect of antistatic finish.

 A particular advantage is that even relatively low molecular weight combinations of polar or surface-active compounds and inorganic salts, prone to sweating on the surface of polymeric materials, are bound primarily by adsorption on a polar inorganic or organic material.

 Salt-containing polar organic compounds may additionally have functional groups forming ionic or covalent bonds with the functional groups of the carrier material. By functional groups, first of all, we mean groups capable of polymerization, whereby a particularly stable coating can be achieved by polymerization or crosslinking.

 It is essential to achieve good electrical conductivity that particles or fibers of polar inorganic or organic materials come into contact or cross in as many places as possible during their incorporation into polymers. Due to this, an electrically conductive structure is created (a network of fibers or granules), which ensures the drainage of an electric charge, that is, the polymer is given electrical conductivity.

 The stability of polymers, such as thermal stability, light resistance and resistance to hydrolysis, remain in most cases unchanged. In the case of a low content of the additive, the optical properties also change only slightly and the optically transparent materials remain mostly transparent. The parameters of thermoplastic, structurally cross-linked or thermoset polymers are given below.

 1. Polymers of mono- and diolefins, for example polypropylene, polyisobutylene, polybutene-1, poly-4-methylpentene-1, polyisoprene or polybutadiene, as well as polymerizates of cycloolefins, such as cyclopentene or norbornene, in addition, polyethylene (possibly crosslinked), for example, high density polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), branched low density polyethylene.

Polyolefins, i.e. polymers of monoolefins, such as, for example, those mentioned above, especially polyethylene and polypropylene, can be obtained by various methods, in particular, by the following methods:
a) radical (usually at high pressure and temperature);
b) by means of a catalyst, the catalyst usually containing one or more metals of group IVa, Vb or VIII. These metals usually have one or more ligands, such as oxides, halides, alkoxides, esters, ethers, amines, alkyls, alkenyls and / or aryls, which can also be π- or σ-coordinated. These metal complexes can be free or fixed on a carrier, such as, for example, activated magnesium chloride, trivalent titanium chloride, aluminum oxide or silicon oxide. These catalysts may be soluble or insoluble in the polymerization medium. The catalysts can be active in the polymerization process per se, or other activators can be used, such as, for example, metal alkyls, metal hydrides, metal halides, metal oxides or metal alkoxanes, the metal being an element of group Ia, IIa and / or IIIa. Activators can be modified, for example, with other ester, ether, amino or silyl ether groups. These catalysts are commonly referred to as Phillips, Standart Oil Indiana, Ziegler (Natta), TNZ (DuPont), Mettallocen or Single Site Katalysatoren (SSC).

 2. Mixtures of the polymers referred to in paragraph 1), for example a mixture of polypropylene with polyisobutylene, polypropylene with polyethylene (for example, PP / HDPE; PP / LDPE) and mixtures of various types of polyethylene (for example, LDPE / HDPE).

 3. Copolymers of mono- and diolefins with each other or with other vinyl monomers, such as, for example, ethylene-propylene copolymers, linear low density polyethylene (LLDPE) and mixtures thereof with low density polyethylene (LDPE), propylene-butene-1 copolymers, copolymers of propylene with isobutylene, copolymers of ethylene with butene-1, copolymers of ethylene with hexene, copolymers of ethylene with methylpentene, copolymers of ethylene with heptene, copolymers of ethylene with octene, copolymers of ethylene with butadiene, copolymers of isobutylene with isoprene, copolymers of ethylene with isoprene acrylate, copolymers of ethylene with alkyl methacrylate, copolymers of ethylene with vinyl acetate and their copolymers with carbon monoxide or copolymers of ethylene with acrylic acid and their salts (ionomers), as well as ethylene terpolymers with propylene and diene, such as hexadine, dicyclopentadiene or ethylideneborneborne mixtures of such copolymers with each other and with the copolymers referred to in paragraph 1), for example copolymers of polypropylene / ethylene-propylene, LDPE / ethylene-vinyl acetate copolymers, LDPE / ethylene-acrylic acid copolymers, LLDPE / ethylene-vinyl acetate copolymers, LLDPE / ethylene-acrylic acid copolymers and static copolymers of polyalkylene / carbon monoxide and mixtures thereof with other polymers, such as, for example, polyamides.

4. Hydrocarbon resins (for example, C ₅ -C ₉ ), including their hydrogenated modifications (for example, tackifying resins) and mixtures of polyalkylene and starch.

 5. Polystyrene, poly- (n-methylstyrene), poly- (α-methylstyrene).

 6. Copolymers of styrene or α-methyl styrene with dienes or acrylic monomers, for example, such as styrene-butadiene, styrene-acrylonitrile, styrene-alkyl methacrylate, styrene-butadiene-alkyl acrylate and methacrylate, styrene-maleic acid anhydride, styrene-methyl acrylate, maleic acrylate, methyl styrene-anhydride mixtures with high impact strength from copolymers of styrene and other polymers, such as, for example, polyacrylate, diene polymers or ethylene-propylene-diene thermopolymers, as well as block copolymers of styrene, such as, for example, styrene-butadiene-styrene, styrene-isoprene-st roll, styrene / butylene-styrene or styrene-ethylene / propylene-styrene.

 7. Grafted copolymers of styrene or α-methyl styrene, such as styrene on polybutadiene, styrene on copolymers of polybutadiene-styrene or polybutadiene-acrylonitrile, styrene and acrylonitrile (eg methyl acrylonitrile) on polybutadiene; styrene, acrylonitrile and maleic anhydride and maleimide on polybutadiene, styrene and maleimide on polybutadiene, styrene and alkyl acrylate, for example, alkyl methacrylate on polybutadiene, styrene and acrylonitrile, ethylene propylene, styrene acrylate-butadiene, as well as mixtures thereof with the copolymers referred to in paragraph 6), such as, for example, the so-called polymers ABS, MBS, ASA or NPP.

 8. Halogen-containing polymers, such as, for example, polychloroprene, chlorinated rubber, chlorinated or chlorosulphonated polyethylene, copolymers of ethylene and chlorinated ethylene, especially homo- and copolymers of epichlorohydrin, polymers of halogen-containing vinyl monomers, such as, for example, polyvinyl chloride, polyvinylidene-vinylidene-vinylidene-vinylidene-vinyl chloride, as well as their copolymers, such as copolymers of vinyl chloride with vinylidene chloride, vinyl chloride with vinyl acetate or vinylidene chloride with vinyl acetate.

9. Polymers of α, β-unsaturated acids and their derivatives, such as polyacrylates and polymethacrylates, modified with respect to the impact strength of butyl acrylate polymethyl methacrylate, polyacrylamide and polyacrylonitrile
10. Copolymers of the monomers referred to in clause 9) with each other or with other unsaturated monomers, such as, for example, acrylonitrile-butadiene copolymers, acrylonitrile-alkyl acrylate copolymers, acrylonitrile-alkylene-acrylonitrile-vinylidetrileryl-vinyltrimethyl-acrylonitrile-vinylidene trimer-vinyltrimethyl-acrylonitrile-vinylidene trimer .

 11. Polymers of unsaturated alcohols and amines or their acyl derivatives or acetals, such as, for example, polyvinyl alcohol, polyvinyl acetate, β-stearate, β-benzoate, maleate, polyvinyl butyral, polyallyl phthalate, polyallyl melamine, as well as their copolymers with olefins.

 12. Homo- and copolymers of cyclic ethers, such as polyalkylene glycols, polyethylene oxide, polypropylene oxide or their copolymers with biglycidyl ethers.

 13. Polyacetals, such as, for example, polyoxymethylene, as well as those polyoxymethylene, which contain comonomers, such as, for example, ethylene oxide, polyacetals modified with thermoplastic polyurethanes, acrylates or MBS.

 14. Polyphenylene oxides and sulfides and mixtures thereof with styrene polymers or polyamides.

 15. Polyurethanes obtained from simple and complex polyesters and polybutadienes with terminal hydroxyl groups, on the one hand, and aliphatic or aromatic polyisocyanates, on the other hand, as well as their precondensates.

 16. Polyamides and copolyamides derived from diamines and dicarboxylic acids and / or aminocarboxylic acids or corresponding lactams, such as polyamide 4, polyamide 6, polyamide 6/6, 6/10, 6/9, 6/12, 4/6, 12/12, polyamide 11, polyamide 12, aromatic polyamides based on m-xylene, diamine and adipic acid, polyamides derived from hexamethylene diamine and iso- and / or terephthalic acid and, if necessary, an elastomer as a modifier, for example poly- 2,4,4-trimethylhexamethylene terephthalamide or poly-m-phenyleneisophthalamide. The block copolymers of these polyamides with polyolefins, olefin copolymers, ionomers or chemically bonded or grafted elastomers, or with polyethers, such as, for example, polyethylene glycol, polypropylene glycol or polytetramethylene glycol. Then with EPDM or ABS modified polyamide or copolyamide, as well as polyamides condensed during processing ("RIM-polyamide systems").

 17. Polyureas, polyimides, polyamidimides and polybenzimidazoles.

 18. Polyesters derived from dicarboxylic acids and dihydric alcohols and / or hydroxycarboxylic acids or corresponding lactones, such as, for example, polyethylene terephthalate, polybutylene terephthalate, polybutylene terephthalate, poly-1,4-dimethylol cyclohexane terephthalate, polyhydroxybenzoate, and polyether copolymer obtained from polyethers with hydroxyl groups, in addition, polyesters modified with polycarbonates and MBS.

 19. Polycarbonates and polyester (complex) carbonates.

 20. Polysulfones, polyester (simple) sulfones and polyester (simple) ketones.

 21. Branched polymers obtained, on the one hand, from aldehydes and, on the other hand, phenols or melamine, such as phenol-formaldehyde, urea-formaldehyde and melamine-formaldehyde resins.

 22. Dried and non-dried alkyd resins.

 23. Unsaturated polyester resins obtained from copolymers of saturated and unsaturated dicarboxylic acids with branched alcohols, as well as vinyl compounds as a crosslinking agent, as well as their halogen-containing refractory modifications.

 24. Crosslinkable acrylic resins derived from substituted acrylic esters, such as, for example, epoxy acrylates, urethane acrylates and polyether acrylates.

 25. Alkyd resins, polyester resins and acrylic resins crosslinked with melamine resins, urea resins, polyisocyanates or epoxies.

 26. Crosslinked epoxies derived from polyepoxides, for example from biglycidyl ethers or from cycloaliphatic diepoxides.

 27. Natural polymers such as cellulose, natural rubber, gelatins, and chemically modified polymer-homologous derivatives thereof, such as cellulose acetate, propionate and butyrate cellulose, as well as cellulose ethers such as methyl cellulose or colophonium resins and derivatives.

 28. Mixtures (polysmes) of these polymers, such as, for example, PP / EPDM, polyamide / EPDM or ABS, PVC / EVA, PVC / ABS, PVC / MBS, PC / ABS, PBTP / ABS, PC / ASA, PC / PBT, PVC / CPE, PVC / POM acrylate / thermoplastic PUR, PC / thermoplastic PUR, POM / acrylate, POM / thermoplastic PUR, PC / thermoplastic PUP, POM / acrylate, POM / MBS, PPO / HIPS, PPO / PA6 and copolymers , PA / HDPE, PA / PP, PA / PPO.

 Examples of preferred thermoplastic, structurally crosslinked or thermoset polymers are polymers selected from the group consisting of polyolefins, polystyrenes, polymers of α, β-unsaturated acids, halogen-containing polymers, homo- and copolymers of cyclic ethers, polymers of unsaturated alcohols and amines, polyenoacetals, polyenoacetals, , polyurethanes, polyamides, polyesters, polyureas, polycarbonates, polysulfones, crosslinked products from aldehydes, on the one hand, and phenols, urea or melamines, on the other hand, alkyd with ols curable acrylic resins, crosslinked epoxy resins, cellulose, and natural rubber.

 Particularly preferred are polyolefins, polystyrene, polymers of α, β-unsaturated acids, halogen-containing polymers, especially PVC, homo- and copolymers of cyclic ethers, especially with bisphenol-A-diglycidyl ether.

 Even more preferred are polyolefins, such as polyethylene and its various modifications, such as polypropylene or a halogen-containing polymer, such as, for example, polyvinyl chloride (PVC), especially polymerized in bulk or in suspension.

 The polar adsorbed inorganic or organic material may be in the form of fibers or discrete particles. Adsorption may occur on the surface and / or in the pores of the fiber or particles.

"Porous" according to this invention means that the inorganic or organic material has internal voids with an internal surface of at least 1 m ² / h, arranged so as to accumulate substances and ions in them.

 The value of the inner surface can be determined, for example, by the BET method.

If the inorganic or organic material is porous, then the value of its inner surface is preferably 5-500 m ² / h. As porous, adsorption inorganic materials, for example, natural minerals such as calcite, talc, kaolin, diatomaceous earth, montmorillonite or attapulgite can be used. Laminated silicates such as sepiolite or bentonite, highly dispersed silicic acid, synthetic silicic acids with high adsorption ability, silica gel, molecular sieves - zeolite, pumice, brick chips or porous glass can also be used.

 Porous adsorption inorganic materials in aqueous solutions can give an acidic, neutral or basic reaction.

 Molecular zeolite sieves mean crystalline, hydrated aluminosilicates, synthetic or natural with a sclerostructure, containing ion-exchange cations of alkali and alkaline earth metals (as defined by D. W. Breck, Zeolite Molecular Sieves, J. Wiley, New York, 1974).

 Examples of suitable molecular sieve zeolites are: zeolite A, zeolite ZSM-5, mordenite, zeolite L, zeolite X, zeolite Y in their Na-, K- or Ca-form. Also suitable are layered silicates of the class of philosilicates with a tetraid environment of the Si atom by oxygen atoms. Two such tetraid Si layers are bonded via an octahedrally coordinated metal layer, such as Al or Mg, through an oxygen atom. The result is a set of layers of tetrahedrons, octahedra and tetrahedrons, which are separated from the next repeating structural unit by means of a two-dimensional space.

 In this intermediate space there may be counterions to compensate for the charge. Possible counterions are metal ions, oligo-, polyoxymethallions or organic cations.

 Filosilicates having a fibrous structure are particularly suitable. In particular, the hormone group (Hormit-gruppe) has the ability to form chain, fibrous structures with channel-like voids. They are especially well suited.

 Especially advantageous is the use of attapulgite or sepiolite as fibrous layered silicates.

 Mixtures of different fibrous layered silicates with each other or mixtures of molecular sieve zeolites are equally well suited.

 A review of the feed group and their origin is given in Ullman Encyclopedia of lnd. Chem., 5-te Ausgabe 1986, VCH Verlag Weinheim, vol. A7, s. 118.

 Natural and synthetic porous adsorption inorganic materials are commercially available. As porous adsorption organic materials, for example, urea-formaldehyde polycondensate (Pergopak), as well as natural sorption porous substances, can be used.

 As the adsorption organic fibers, a large number of granular or fiber-like natural organic materials can be used, such as shredded wood or vegetable waste or prepared natural fibers.

 Preferred natural fibers are, for example, cellulosic, such as cotton, bast, kapok, jute, ramie, linen or hemp. Woolen or silk fibers may also be used.

 Cellulose of natural origin may also be in the form of its derivatives, for example in the form of viscose, cellulose ethers and esters. Ethers and esters can have varying degrees of substitution, usually from 1 to 3. Organic fibrous material can be used as a continuous spinning fiber or as short staple fibers.

 It is also possible to use fibers in the form of flat nets, woven patterns, rovings or felt.

 Synthetic polymer fibers can also be used since they have a sufficiently high polarity on the surface and adsorb antistatic.

 Examples of suitable fibers are polyamide, polyester or polyacrylonitrile fibers. The surface of non-polar fibers, such as, for example, polyolefin fibers, can be modified by chemical and / or physical treatment so that such fibers can also be used according to the invention. Typical examples of this modification are additional plasma or corona treatment, for example, polypropylene fibers.

 In the case of using polar polymer fibers, such as, for example, polyamide fibers, the polar organic compounds that are adsorbed on them should preferably contain a functional group capable of polymerization or crosslinking.

 As a result of such polymerization or crosslinking, particularly stable antistatic properties are achieved.

 To achieve the desired effect, the fibers or particles must be in contact with each other in the polymer matrix to provide bulk conductivity or ionic or electronic conductivity.

 Inorganic or organic particles may be in the form of needles, laminae, cylinders, stitched laminae (Whiskern), regular or irregular marbles, or similar irregular shapes.

 In the General case, they have an average particle size of from 1 to 5000 microns, mainly from 10 to 1000 microns and in particular from 50 to 500 microns.

 Particularly preferred are particles that are not spherical and have a larger size in one direction. For example, needles, cylinders and plates.

 Advantageously, polar inorganic or polar organic fibers are used, since with a lower degree of filling they provide better electrical conductivity than spherical particles.

 Inorganic or organic fibers generally have a length of from 0.01 to 200 mm, preferably from 0.1 to 20 mm.

 An antistatic agent consists in part of a polar organic compound with at least 5 C atoms and at least 3 heteroatoms. Examples of heteroatoms are oxygen, nitrogen, sulfur or phosphorus of varying degrees of oxidation. The antistatic agents used according to the invention are in most cases known and are described, for example, in Kunststoffe 67 (1977) 3, s. 154-159.

 Examples of polar organic compounds containing at least 5 C atoms and at least 3 heteroatoms that can be solvated or complexed with a salt of inorganic protonic acids are polyamines, polymers derived from pyridine, macrocyclic azo compounds, polysulfides or polyphosphines, simple polyester, crown ether, polyols.

 Preferred are polar organic compounds with 3-20 heteroatoms and 5-10 C atoms.

 Preferred heteroatoms are oxygen and nitrogen. The molecular weight of the polar organic compounds is preferably 200-5000, in particular 300-3000 Daltons.

Polar organic compounds are predominantly liquid at temperatures up to 60 ^o C or soluble in organic solvents.

 Examples of polymerizable functional groups are olefinically unsaturated hydrocarbons obtained, for example, from α, β-unsaturated carboxylic acids or their derivatives, glycidyl groups, such as, for example, glycidyl ether or isocyanate groups.

Examples of inorganic salts that can be added according to the invention are salts of zinc, alkali or alkaline earth metals and ammonium with inorganic mineral acids, oxoacids or alkylsulfonic acids containing lower alkyl. Mostly inorganic salts are selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ .

Used according to the invention as component (b ¹ ) polyoxyalkylene of the formula (I):
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ (I) where
R ₁ is H, C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, C ₁ -C ₂₄ alkyl-C (O) -, C ₂ -C ₂₄ alkenyl-C (O) -, CH ₂ = CH-C (O) - or CH ₂ = (CH ₃ ) C (O) -,
R ₂ is C ₁ -C ₂₄ alkyl, C ₂ -C ₂₄ alkenyl, CH ₂ COOH or
N (C ₁ -C ₈ -alkyl) ₃ Hal or,
if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -,
R ₃ means H or CH ₃ ,
Hal means Cl, Br or J,
n is the number ≥ (greater than or equal to) 2,
p is a number from 1 to 6 and
q and r, independently from each other, mean 0 or 1, are well known and are either commercially available or can be obtained by a conventional chemical reaction.

If the substituents in the compounds of formula (I) are C ₁ -C ₂₄ alkyl, then they are methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, hexadecyl, octadecyl , necosyl, docosyl and tetracosyl, as well as the corresponding branched positional isomers.

If the substituents in the compounds of formula (I) mean C ₁ -C ₂₄ alkenyl, then it is obtained from the above-mentioned alkyl residues, and one or more double bonds may be present. If there is only one double bond, then it is located mainly in the middle of the hydrocarbon chain. If there are several double bonds in a hydrocarbon chain, then this radical is obtained predominantly from an unsaturated fatty acid. Oleyl is preferred as an alkenyl radical.

Preferred is the polyoxyalkylene of formula (I), wherein R ₁ is H, C ₁ -C ₄ alkyl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -, or a polyoxyalkylene of formula (I), wherein R ₂ is C ₆ -C ₂₀ alkyl, C ₆ -C ₂₀ alkenyl or N (C ₁ -C ₈ alkyl) ₃ Cl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -, where n means a number from 2 to 20, and p means a number from 2 to 6.

 Preferred specific compounds of formula (I) are polipropilenglikollaurat, polypropyleneglycol ether, polypropyleneglycol-metildietilammoniyhlorid, polyethylene glycol monomethyl ether, polietilenglikoldimetilovy ether polietilenglikollaurilovy ether polietilenglikololeat simple polietilenglikololeinovy ether polietilenglikolsorbitanmonolaurat, polyethylene glycol stearate, polietilenglikolpolipropilenglikollaurilovy ether polietilenglikollaurilovy ether carboxylic sour you, polyethylene glycol, and -mono -triakrilat or polietilenglikoldimetakrilat, mono- and -trimetakrilat.

 If an olefinically unsaturated compound is introduced, it can be polymerized or crosslinked on fiber. As a result, a coating forms on the fiber with which the inorganic salt is complexed or solvated.

 A particularly good finishing effect is achieved by using polyethylene glycol diacrylate, which is polymerized or crosslinked on a polar inorganic or organic material. In this way, a particularly stable effect of antistatic finish is achieved, which eliminates the sweating of the salt or organic component. Crosslinking can occur on the surface of the fiber or particles, as well as in internal structures (pores).

 Other suitable components that can be used are, for example, trimethylol propane triacrylate, trimethylol propane trimetric acrylate or other trifunctional compounds. These compounds are commercially available.

Crosslinking or polymerization reactions are known and can be carried out either thermally or photochemically. The catalysts are, for example, peroxy compounds, such as, for example, H ₂ O ₂ , or photoinitiators, such as benzyldimethyl ketal. These catalysts are known and are also commercially available. Polar inorganic or organic material is introduced in an amount of mainly from 0.01 to 70 parts by weight, in particular from 0.1 to 30 parts by weight. hours per 100 parts by weight polymer.

 Polar organic compounds are introduced in an amount of from 0.01 to 20 parts by weight per 100 parts by weight. polymer.

 Used inorganic salt is administered in an amount of from 0.01 to 5 parts by weight per 100 parts by weight polymers. The ratio of organic compound to inorganic salt is mainly 200: 1-1: 1.

 Usually, the inorganic salt is first mixed with the polar organic compound and then the polar inorganic or organic material is impregnated with this mixture.

 A thermoplastic, structurally crosslinked, or thermosetting polymer may contain other additives. First of all, these additives belong to the group of thermal and / or light stabilizers. In this case, thermal stabilization refers to both processing and use (stability over time). Such other additives are known to those skilled in the art and are for the most part commercially available.

If halogen-containing polymers, such as those described above, are subjected to antistatic treatment, it is advisable that they contain at least one inorganic compound of zinc, barium, cadmium, aluminum, calcium, magnesium or rare earth elements, such as, for example, oxide, hydroxide , chloride or zinc sulfide, or an additive compound of zinc oxide / hydroxide of increased basicity, or an organic compound of zinc, barium, cadmium, aluminum, calcium, magnesium or rare earth elements, selected from a number of compounds C ₂ -C ₂₂ carboxylates, aliphatic unsaturated C ₃ -C ₂₂ carboxylates, aliphatic C ₂ -C ₂₂ carboxylates substituted by at least one OH group, or the hydrocarbon chain of which is interrupted by an O (oxo-acid) atom, cyclic and bicyclic carboxylates with 5-22 C atoms, unsubstituted, substituted by at least one OH group and / or C ₁ -C ₁₆ alkyl substituted phenyl carboxylates, unsubstituted, substituted by at least one OH group, and / or C ₁ -C ₁₆ alkylnaphthylcarboxylates, phenyl-C ₁ -C ₁₆ -alkylcarboxylates, naphthyl-C ₁ -C ₁₆ -alkylcarb oxylates or, if necessary, C ₁ -C ₁₂ alkyl phenolates.

 The named compounds may be present in the form of a mixture of various compounds. Preferred in this case are the so-called synergistic mixtures of metal soaps, for example Ca and Zn or Ba and Zn. Organic compounds of zinc, barium, cadmium, aluminum, calcium, magnesium or rare earth elements can be coated onto hydrocalcite, zeolite or dawsonite (see also DE-A-4031818).

As antioxidants, for example, can be named:
1. Alkinated monophenols.

 For example, 2,6-di-tert. butyl-4-methylphenol, 2-butyl-4,6-dimethylphenol, 2,6-di-tert. butyl-4-ethylphenol, 2,6-tert-butyl-4-H-butylphenol, 2,6-di-tert. -butyl-4- isobutylphenol, 2,6-dicyclopentyl-4-methylphenol, 2- (α-methylcyclohexyl) -4,6-dimethylphenol, 2,6-di-octadecyl-4-methylphenol, 2,4,6-three -cyclohexylphenol, 2,6-di-tert-butyl-4-methoxymethylphenol, 2,6-di-nonyl-4-methylphenol, 2,4-dimethyl-6- (1'-methyl-undec-1'-yl) - phenol, 2,4-dimethyl-6- (1'-methyl-heptadec-1'-yl) -phenol, 2,4-dimethyl-6- (1'-methyl-tridec-1'-yl) -phenol , octylphenol, nonylphenol and mixtures thereof.

 2. For example, 1,4-di-octylthiomethyl-6-tert. butylphenol, 2,4-di-octylthiomethyl-6-methylphenol, 2,4-di-octyl-thiomethyl-6-ethylphenol, 2,6-di-dodecyl-thiomethyl-4-nonylphenol.

 3. Hydroquinones and alkylated hydroquinones.

 For example, 2,6-di-tert. butyl-4-methoxyphenol, 2,5-di-tert. butyl-hydroquinone, 2,5-di-tert. amyl hydroquinone, 2,6-diphenyl-4-octadecyloxyphenol, 2,6-di-tert. butyl hydroquinone, 2,5-di-tert. butyl-4-hydroxyanisole, 3,5-di-tert. butyl-4-hydroxyanisole, 3,5-di-tert-butyl-4-hydroxy-phenyl stearate, bis (3,5-di-tert-butyl-4-hydroxyphenyl) adilate.

 4. Hydroxylated thiodiphenyl ether.

 For example, 2,2'-thio-bis (6-tert. Butyl-4-methylphenol), 2,2'-thio-bis (4-octylphenol), 4,4'-thio-bis (6-tert. Butyl -3-methylphenol), 4,4'-thio-bis (6-tert. Butyl-2-methylphenol), 4,4'-thio-bis (3,6-di-sec-amylphenol), 4,4 ' bis (2,6-dimethyl-4-hydroxyphenol) disulfide.

 5. Alkylidene-bisphenols.

 For example, 2,2'-methylene-bis- (6-tert-butyl-4-methylphenol), 2,2'-methylene-bis (6-tert. Butyl-4-ethylphenol), 2,2'-methylene- bis- [4-methyl-6 - (α-methyl-cyclohexyl) phenol], 2,2'-methylene-bis- (4-methyl-6-cyclohexylphenol), 2,2'-methylene bis- (6 nonyl-4-methylphenol), 2,2'-methylene-bis- (4,6-di-tert-butylphenol), 2,2'-ethylidene-bis- (6-tert. butyl-4-isobutylphenol), 2,2'-methylene-bis- [6 - (α-methylbenzyl) -4-nonylphenol], 2,2'-methylene-bis- [6 - (α, α-dimethylbenzyl) -4-nonylphenol], 4, 4'-methylene-bis- (2,6-di-tert-butylphenol), 4,4'-methylene-bis- (6- tert. Butyl-2-methylphenol), 1,1-bis- (5- tert .butyl-4-hydroxy-2-methylphenyl) -butane, 2,6-bis- (3- tr etc. butyl-5-methyl-2-hydroxybenzyl) -4-methylphenol, 1,1,3-tris (5-tert. butyl-4-hydroxy-2-methylphenyl) butane, 1,1-bis (5- heated butyl-4-hydroxy-2-methylphenyl) 3-H-dodecylmercaptobutane, ethylene glycol bis- [3,3-bis- (3'-tert-butyl-4'-hydroxyphenyl) butyrate], bis- (3 - tert.butyl-4-hydroxy-5-methyl-phenyl) dicyclopentadine, bis- [2- (3'- tert.butyl-2'-hydroxy-5'-methylbenzyl) -6-tert. butyl 4-methylphenyl] terephthalate, 1,1'-bis- (3,5-dimethyl-2-hydroxyphenyl) butane, 2,2-bis- (3,5-di-tert.butyl-4 -hydroxyphenyl) propane, 2,2-bis- (4-hydroxyphenyl) propane, 2,2-bis- (5-tert. butyl-4-hydroxy-2-methylphenyl) -4-H-dodecylmercaptobutane, 1, 1,5,5-tetra- (5-tert-butyl-4-hydroxy-2-methylphenyl) pentane.

 6. O-, N- and S-benzyl compounds.

 For example, 3, 5, 3 ', 5'-tetra-tert.butyl-4', 4'-dihydroxybenzyl ether, octadecyl-4-hydroxy-3,5-dimethylbenzyl mercaptoacetate, tris- (3,5-di tert. butyl-4-hydroxybenzyl) amine, bis (4-tert.butyl-3-hydroxy-2,6-dimethylbenzyl) -dithiotherephthalate, bis (3,5-di-tert.butyl-4-hydroxybenzyl) sulfide, isooctyl-3,5-di-tert.butyl-4-hydroxybenzyl mercaptoacetate.

 7. Hydroxybenzylated malonates.

 For example, dioctadecyl-2,2-bis (3,5-di-tert. Butyl-2-hydroxybenzyl) malonate, dioctadecyl-2- (3-tert.butyl-4-hydroxy-5-methylbenzyl) malonate, di- dodecyl mercapto-ethyl-2,2-bis (3,5-di-tert. butyl-4-hydroxybenzyl) malonate, di- [4- (1,1,3,3-tetramethylbutyl) phenyl] -2,2 bis (3,5-di-tert.butyl-4-hydroxybenzyl) malonate.

 8. Hydroxybenzyl aromatics.

 For example, 1,3,5-tris (3,5-di-gret.butyl-4-hydroxybenzyl) -2,4,6-trimethylbenzene, 1,4-bis- (3,5-di-tert. Butyl- 4-hydroxybenzyl) -2,3,5,6-tetramethylbenzene, 2,4,6-tris (3,5-di-tert-butyl-4-hydroxybenzyl) phenol.

 9. Triazine compounds.

 For example, 2,4-bis (octyl mercapto) -6- (3,5-di-tert.butyl-4-hydroxyanilino) -1,3,5-triazine, 2-octyl mercapto-4,6-bis (3,5 -di-tert. butyl-4-hydroxyanilino) -1,3,5-triazine, 2-octylmercapto-4,6-bis (3,5-di-tert.butyl-4-hydroxyphenoxy) -1,3,5 triazine, 2,4,6-tris (3,5-di-tert. butyl-4-hydroxyphenoxy) -1,2,3-triazine, 1,3,5-tris (3,5-di-tert. butyl-4-hydroxybenzyl) isocyanurate, 1,3,5-tris (4-tert.butyl-3-hydroxy-2,6-dimethylbenzyl) isocyanurate, 2,4,6-tris (3,5-di- tert. butyl-4-hydroxyphenylethyl) -1,3,4-triazine, 1,3,5-tris (3,5-di-tert. butyl-4-hydroxyphenylpropionyl) hexahydro-1,3,5-triazine, 1,3,5-tris (3,5-dicyclohex il-4-hydroxybenzyl) isocyanurate.

 10. Phosphonates, phosphites and phosphonites.

For example, dimethyl-2,5-di-tert.butyl-4-hydroxybenzylphosphonate, diethyl-3,5-di-tert. butyl 4-hydroxybenzylphosphonate, dioctadecyl-3,5-di-tert.butyl-4-hydroxybenzylphosphonate, dioctadecyl-5-tert.butyl-4-hydroxy-3 - methylbenzylphosphonate, Ca-salt of 3,5-di-tert.butyl -4- gidroksibenziletilfosfonata, triphenyl phosphite, difenilalkilfosfit, fenildialkilfosfit, tris (nonylphenyl) phosphate, trilauryl phosphite, trioctadecyl phosphite, distearyl pentaerythritol diphosphite, tris (2,4-di-tert. butylphenyl) phosphite, diizodetsilpentaeritritdifosfit, bis (2,4-di- tert .butylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert.butyl-4-methyl-phenyl) pentaerythritol diphosphite, bis (isodecylox i) - pentaerythritol diphosphite, bis (2,4-di-tert. butyl-6-methylphenyl) pentaerythritol diphosphite, bis- (2,4,6-tri-tert-butylphenyl) - pentaerythritol diphosphite, tristearylsorbitol triphosphite, tetrakis (2,4-di tert. butylphenyl) -4,4'-biphenylene diphosphonite, 6-isooctyloxy-2,4,8,10-tetra-tert. butyl-12H-dibenz [d, g] -1,3,2-dioxaphosphocin, 6-fluoro-2,4,8,10-tetra-tert. butyl-12-methyl-dibenz [d, g] -1,3,2-dioxaphosphocin, bis- (2,4-di-tert. butyl-6-methylphenyl) methylphosphite, bis- (2,4-di- tert-butyl-6-methylphenyl) ethylphosphite, (C ₉ H ₁₉ - C ₆ H ₄ ) _1,5 -P- (O-C _12-13 H _25-27 ) _1.5 .

 11. Acylaminophenols.

 For example, 4-hydroxylauric acid anilide, N- (3,5-di-tert. Butyl-4-hydroxyphenyl) carbamic acid octyl ester, anilide-4-hydroxylauryl acid.

 12. Esters of β- (3,5-di-tert.butyl-4-hydroxyphenyl) propionic acid with mono- or polybasic alcohols.

 For example, with methanol, ethanol, octanol, octadecanol, 1,6-hexadiol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thioethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, tris (hydroxy) N'-bis (hydroxyethyl) oxalic acid, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo [2.2.2] octane.

 13. Esters of β- (5-tert.butyl-4-hydroxy-3-methylphenyl) propionic acid with mono- or polyhydric alcohols.

 For example, with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thioethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, ethisamis (di , N'-bis (hydroxyethyl) oxalic acid, 3-thiaundecanol, 3-thiapentadecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo [2,2,2] octane.

 14. Esters of β-(3,5-dicyclohexyl-4-hydroxyphenyl) propionic acid with mono- or polyhydric alcohols.

 For example, with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, ethisis (tri , N'-bis (hydroxyethyl) oxalic acid, 3-thiaundecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo- [2,2,2] octane.

 15. Esters of 3,5-di-tert-butyl-4-hydroxy-phenylacetic acid with mono- or polyhydric alcohols.

 For example, with methanol, ethanol, octanol, octadecanol, 1,6-hexanediol, 1,9-nonanediol, ethylene glycol, 1,2-propanediol, neopentyl glycol, thiodiethylene glycol, diethylene glycol, triethylene glycol, pentaerythritol, ethisis (tri , N'-bis (hydroxyethyl) oxalic acid, 3-thiaundecanol, trimethylhexanediol, trimethylolpropane, 4-hydroxymethyl-1-phospha-2,6,7-trioxabicyclo- [2,2,2] octane.

 16. Amides of β- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid.

 For example, N, N'-bis (3,5-di-tert-butyl-4-hydroxyphenylpropionyl) -hexamethylenediamine, N, N'-bis (3,5-di-tert.butyl-4-hydroxyphenylpropionyl) - trimethylenediamine, N, N'-bis (3,5-di-tert-butyl-4-hydroxyphenylpropionyl) hydrazine.

 17. Esters of thiodiuscous and thiodipropionic acid.

 Preferred are antioxidants of groups 5, 10 and 14, in particular 2,2-bis- (4-hydroxyphenyl) propane, ether 3,5-di-tert. butyl-4-hydroxyphenylpropionic acid with octadecanol or pentaerythritol and tris (2,4-di-tert-butylphenyl) phosphite. If necessary, mixtures of antioxidants of various structures can also be used.

 Antioxidants can be used, for example, in an amount of from 0.01 to 10, suitably 0.1-10 and in particular from 0.1 to 5 parts by weight. per 100 parts by weight polymer.

As the UV adsorbent and light stabilizer can be named:
1. 2- (2'-hydroxyphenyl) benzyltriazoles.

For example, such as 2- (2'-hydroxy-5'-methylphenyl) benzotriazole, 2- (3 ', 5'-di-tert-butyl-2'-hydroxyphenyl) benztriazole, 2- (5'-tert. butyl-2'-hydroxyphenyl) benztriazole, 2- (2'-hydroxy-5 '- (1,1,3,3-tetramethylbutyl) phenyl) benztriazole, 2- (3', 5'-di-heated. butyl- 2'-hydroxyphenyl) -5-chloro-benzotriazole, 2- (3'-tert. Butyl-2'-hydroxy-5'-methylphenyl) -5-chloro-benzotriazole, 2- (3'-sec-butyl-5 '- tert.butyl-2'-hydroxyphenyl) benzotriazole, 2- (2'-hydroxy-4'-octoxyphenyl) benztriazole, 2- (3'-5'-di-tert.amyl-2'-hydroxy- phenyl) benzotriazole, 2- (3 ', 5'-bis - (α, α-dimethylbenzyl) -2'-hydroxyphenyl) benzotriazole, a mixture of 2- (3'-tert. Utyl-2'-hydroxy-5 '- (2-octyl-hydroxycarbonyl) phenyl-5-chloro-benzotriazole, 2- (3'-tert-butyl-5' - [2- (2-ethylhexyloxy) -carbonylethyl] - 2'-hydroxyphenyl) -5-chlorobenzotriazole, 2- (3'-tert.butyl-2-hydroxy-5 '- (2-methoxycarbonylethyl) phenyl-5-chlorobenzotriazole, 2- (3'-tert. butyl-2'-hydroxy-5- (2-methoxycarbonylethyl) phenyl) benztriazole, 2- (3'-tert. butyl-2'-hydroxy-5 '- (2-octyloxycarbonylethyl) phenyl) benzotriazole, 2 - (3'-tert. butyl-5 '- [2- (2-ethylhexyloxy) carbonylethyl] -2'-hydroxyphenyl] benzotriazole, 2- (3'-dodecyl-2'-hydroxy-5'-methylphenyl) benztriazole and 2- (3'- tert-butyl-2'-hydroxy-5 '- (2-isooctyl-hydroxycarbonylethyl) phenylbenzotriazole, 2,2'-methylene-bis [4- (1,1,3,3-tetramethylbutyl) -6-benztriazole-2- il-phenol], the product of the interaction of 2- [3'-tert.butyl-5 '- (2-methoxycarbonylethyl) -2'-hydroxyphenyl] benzotriazole with polyethylene glycol 300; [R-CH ₂ CH ₂ -COO (CH ₂ ) ₃ ], where R is 3'-tert. Butyl-4'-hydroxy-5'-2H-benzotriazol-2-yl-phenyl.

 2.2 2-hydroxybenzophenones.

 For example, such as 4-hydroxy, 4-methoxy, 4-octoxy, 4-decyloxy, 4-dodecyloxy, 4-benzyloxy, 4.2 ', 4'-trihydroxy, 2'-hydroxy 4,4'-dimethyloxy derivatives.

 3. Esters, possibly substituted benzoic acids.

 For example, such as 4-tert-butyl phenyl salicylate, phenyl salicylate, octyl phenyl salicylate, bis (4-tert butyl benzoyl) resorcinol, benzoyl resorcinol, 3,5-di-tert. butyl 4-hydroxybenzoic acid 2,4-di-tert. butylphenyl ether, 3,5-di-tert. butyl-4-hydroxybenzoic acid hexadecyl ether, 3,5-di-tert-butyl-4-hydroxybenzoic acid octadecyl ether, 3,5-di-tert-butyl-4-hydroxybenzoic acid 2-methyl-4,6-di tert-butylphenyl ether.

 4. Acrylates.

 Such as, for example, a-cyan-β, β-diphenylacrylic acid, ethyl or isooctyl ether, α-carbomethoxy cinnamic acid methyl ether, α-cyano-β-methyl-n-methoxy-cinnamic acid methyl or butyl ether, α- carbomethoxy-n-methoxy-cinnamic acid methyl ester, N - (β-carbomethoxy-β-cyano-vinyl) -2-methylindoline.

 5. Nickel compounds.

 For example, such as nickel complexes with 2,2'-thio-bis [4- (1,1,3,3-tetramethyl-butyl) phenols, such as 1: 1 or 1: 2 complex compounds, possibly with additional ligands, such as n-butylamine, triethanolamine or N-cyclohexyl diethanolamine, nickel dibutyl dithiocarbamate, nickel salts with 4-hydroxy-3,5-di-tert-butylbenzylalkylphosphonates, such as methyl or ethyl phosphonates, nickel complex complexes with ketones 2-hydroxy-4-methyl-phenyl-undecyl-ketoxime, nickel complexes with 1-phenyl-4-lauroyl-5-hydroxypyr azoles, possibly with additional ligands.

 6. Steric hindered amines.

 For example, bis (2,2,6,6-tetramethyl-piperidyl) sebacate, bis (2,2,6,6-tetramethylpiperidyl) succinate, bis (1,2,2,6,6-pentamethyl-piperidyl) sebacinate, n-butyl-3,5-di-tert. butyl-4-hydroxybenzylmalonic acid bis (1,2,2,6,6-pentamethylpiperidyl) ether, condensation product of 1-hydroxyethyl-2,2,6,6-tetramethyl-4-hydroxypiperidine with succinic acid, condensation product N, N '-bis (2,2,6,6-tetra-methyl-4-piperidyl) - hexamethylenediamine with 4-tert. octylamino-2,6-dichloro-1,3,5,5-triazine, tris (2,2 , 6,6-tetramethyl-4-piperidyl) nitrilotriacetate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl) -1,2,3,4-butanetetraoate, 1,1 '- (1,2 -ethanediyl) bis (3,3,5,5-tetramethyl-piperazinone), 4-benzoyl-2,2,6,6-tetramethylpiperidine, 4-stearyloxy-2,2,6,6-tetra-tetramethylpiperidine, bis (1,2,2,6, 6-pentamethyl-piperidyl) -2-n-butyl-2- (2-hydroxy-3,5-di-tert. Butylbenzyl) malonate, 3-n-octyl-7,7,9,9-tetramethyl-1, 3,8-triazaspiro [4,5] decane-2,4-dione, bis- (1-octyloxy-2,2,6,6-tetramethylpiperidyl) sebacet, bis- (1-octyloxy-2,2,6 , 6-tetramethylpiperidyl) succinate, a condensation product of N, N'-bis (2,2,6,6-tetramethyl-4-piperidyl) hexamethylenediamine and 4-morpholino-2,6-dichloro-1,3,5- triazine, a condensation product of 2-chloro-4,6-di (4-n-butylamino-2,2,6,6-tetramethylpiperidyl) -1,3,5-triazine and 1,2-bis (3-aminopropylamino) ethane , condensation product of 2-chloro-4,6-di (4-n-butylamino-1,2,2,6,6-pentamethylpiperidyl) -1,3,5 - triazine and 1,2-bis (3-aminopropylamino) ethane, 8-acetyl-3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazospiro- [4,5] -decane- 2,4-dione, 3-dodecyl-1 - (2,2,6,6-tetramethyl-4-piperidyl) pyrrolidin-2,5-dione, 3-dodecyl-1- (1,2,2,6, 6-pentamethyl-4-piperidyl) pyrrolidin-2,5 dione, as well as Chimassorb 966.

 7. Diamines of oxalic acid.

 For example, such as 4,4'-dioctyloxyoxanilide, 2,2'-dioctyloxy-5,5'-di-tert-butyl-oxanilide, 2,2'-didodecyloxy-5,5'-di-tert-butyl-oxanilide, 2-ethoxy-2'-ethyloxanilide, N, N'-bis (3-dimethylaminopropyl) oxamide, 2-ethoxy-5-tert. butyl-2'-ethyloxanilide and a mixture thereof with 2-ethoxy-2'-ethyl-5,4'-di-tert. butyl oxanilide, a mixture with O- or p-methoxy- or O- or p-ethoxy-disubstituted oxanilides.

 8. 2- (2-hydroxyphenyl) -1,3,5-triazines.

 Such as, for example, 2,4,6-tris (2-hydroxy-4-octyl-hydroxyphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-octyl-hydroxyphenyl) -4,6- bis (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2,4-dihydroxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2, 4-bis (2-hydroxy-4-propyloxy-phenyl) -6- (2,4-dimethylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-octyloxyphenyl) -4,6-bis (4-methylphenyl) -1,3,5-triazine, 2- (2-hydroxy-4-dodecyloxyphenyl) -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2- [ 2- hydroxy-4- (2-hydroxy-3-butyloxypropoxy) phenyl] -4,6-bis (2,4-dimethylphenyl) -1,3,5-triazine, 2- [2-hydroxy-4- (2 -hydroxy-3-octyloxypropyloxy) phenyl] -4,6-bis (2,4-dimethylpheny l) -1.3.5-triazine.

 As peroxy compound decomposers, there can be, for example, the following: β-thio-dipropionic acid esters, for example, lauryl, stearyl, myristyl or tridecyl ether, mercaptobenzimidazole, zinc salt of 2-mercaptobenzimidazo-dimethyl-dimethyl-dimethylacetamide, ) propionate or ethylene glycol bismercaptoacetate.

 The inventive method for producing thermoplastic, structurally crosslinked or thermosetting polymers with an antistatic finish is carried out by a known method, for which a polymer with an antistatic agent and a filler is used using a device selected from the group consisting of calendars, rollers, mixers, extruders for mixing, with or without introduction named additives can also enter the so-called masterbatch.

 The obtained thermoplastic polymer with an antistatic finish can be given the desired shape by known methods, for example, grinding, calendering, extrusion, extrusion, sintering, extrusion / sintering or spinning, extrusion-blowing or plastisol processing. The antistatic polymer can also be recycled into porous materials.

The inventive composition for antistatic finishes is used to improve the antistatic properties of thermoplastic, structurally cross-linked or thermosetting polymers,
The polymer composition of the invention is particularly suitable for insulating wires or cables. It can also be used for the manufacture of decorative films, foams, agricultural films, hoses, seals and stationery films. The polymer compositions of the invention can also be used as molding materials for the manufacture of hollow articles (bottles), packaging films (elongated films), blown films, Crash pad films (automobile), pipes, foams, difficult profiles (window) frames), profiles of light walls (Lichtwandprofilen), building profiles, seats, fittings, stationery films and apparatus cases (computer, household appliances).

 The invention is illustrated by the following examples.

 Example 1

Cellulose plates (solid bleached wood) are cut into strips (approximately 6 x 1 cm ² ) and placed in 7.28 g of a solution of polyethylene glycol laurate (lrgastat 51, Ciba) containing 10% lithium methyl sulfonate. The strips are placed in a porcelain cup, which is located in a vessel from which air can be removed. A pressure degassing of 0.5 mbar is carried out for 30 minutes. In conclusion, they allow the excess liquid to drip dropwise from the soaked strips. The impregnated cellulose mass is then 11.39 g. The strips so impregnated are cut into pieces of about 1 x 1 cm ² and pulverized in an ultracentrifugal mill (Retsch, Tour ZM 1000) with 0.5 mm round sieve mesh.

 Example 2

To 50 g of Moplen FLF 20 polypropylene, 4 g of impregnated cellulose according to Example 1 was added and mixed thoroughly. The mixture is processed on a 2-stage milling machine (calender) at 180 ^° C. for 5 minutes into a milled sheet (0.5 mm gap). In conclusion, plates are made by means of a metal template (15x15x0.05 cm ² ) under pressure in a heated hydraulic press (treatment for 5 minutes at 190 ^° C). The plates made in this way have a flow resistance of Rd 4 · 10 ¹¹ Ohms (measured at a voltage of 500 V, round electrode 20 cm ² , gap 0.5 cm (DJN 53482) at 22 ^o C). After storage at 22 ^° C and about 70% humidity for one week, Rd drops to 6 · 10 ¹¹ Ohms (round electrode) and the surface resistance is 4.2 · 10 ⁸ Ohms (Federzungen electrode according to DJN 53482).

 Example 3

The frame fibers (length 6 mm. Type 290, Fisher CH-Dottikon) are ground in an ultracentrifugal mill (Retsch, type ZM 100) with 0.12 mm round sieve mesh. 3 g of these fibers are introduced into a beaker, immersed in a 400 Sartomer SR 344 polyethylene glycol diacrylate solution and 4% NaClO ₄ · H ₂ O, mixed and degassed in a vacuum vessel to about 0.5 mbar for 30 minutes.

 Then the solution and the residue are filtered off, i.e. the impregnated fiber is freed from excess solution between the filter paper in a hydraulic press (the residue has a mass of 4.9 g).

 Example 4

2 g of the fibers impregnated according to Example 3 are finely chopped, 60 g of Moplen FLF 20 polypropylene are added and mixed. The mixture is processed into a rolled film on a rolling machine (calender) with 2 rollers at 180 ^o C for 7 min in a rolled sheet (a gap of 0.5 mm). In conclusion, plates are made by means of a metal template (15x15x0.05 cm ² ) under pressure in a heated hydraulic press (treatment for 5 minutes at 190 ^° C). The plates made in this way have a flow resistance of Rd 9.9 × 10 ¹⁰ Ω and a surface resistance of Ro 1.3 × 10 ¹¹ Ω (measured at a voltage of 500 V and a round electrode of 20 cm ² , a gap of 0.5 cm (DJN 53482) at 22 ^o C). After storage for 2 months at 30-40% relative humidity and room temperature, the values are Rd 2.5 · 10 ⁹ Ohms and Ro 6.0 · 10 ¹⁰ Ohms.

 Example 5

446 g of cellulose plates (solid wood, bleached) are cut into strips (approximately 2.5 x 14.8 cm ² ) and injected in three portions into a solution consisting of polyethylene glycol diacrylate 400 Sartomer SR 344 and 4% NaClO ₄ · H ₂ O The strips are placed in a vessel that is in a vacuum vessel. Degassed with a pressure of 0.3 mbar for about 30 minutes. In conclusion, the soaked strips are allowed to drain. The impregnated cellulose mass is about 681 g. The strips so impregnated are cut into pieces of about 1 × 1 cm ² and pulverized in an ultracentrifugal mill (Retsch, type ZM 100), first with sieve mesh sizes of 2 mm and then 1 mm.

 Example 6

To 45 g of Profax 6501 polypropylene, cellulose impregnated as described in Example 5 is added (the amount and test results are shown in the table) and mixed thoroughly. The resulting mixture is processed into a rolled sheet on a rolling machine with two rollers (calender) at 180 ^o C for 9 min (a gap of 0.4 mm). In conclusion, plates are made using a metal template (15x15x0.05 cm ² ) under pressure in a heated hydraulic press (processing for 5 minutes at 200 ^° C). The plates thus obtained are dried for one week over blue gel. In conclusion, the surface DIN resistance is measured by means of an electrode with a recorder according to DIN 53482, with a voltage of 500 V at 22 ^o C and in an atmosphere with low humidity (humidity of about less than 15%).

 The measurement results are shown in the table.

Claims (11)

1. The composition of the polymer with an antistatic finish, including a thermoplastic, structurally crosslinked elastomeric or thermosetting polymer, an antistatic agent containing inorganic salt, and a filler, characterized in that it contains 100 wt.h. the specified polymer (a) 0.01 to 70 parts by weight filler is a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in contact with each other, on which (b) a polar antistatic is adsorbed, consisting of a mixture containing (b ¹ ) 0 01 - 20 parts by weight per 100 parts by weight a polyoxyalkylene polymer of formula I
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ ,
where R ₁ means H, C ₁ - C ₂₄ -alkyl, C ₂ - C ₂₄ -alkenyl, C ₁ - C ₂₄ -alkyl-C (O) -, C ₂ - C ₂₄ -alkenyl-C (O) -, CH ₂ = CH — C (O) - or CH ₂ = (CH) —C (O) -;
R ₂ is C ₁ - C ₂₄ alkyl, C ₂ - C ₂₄ alkenyl, CH ₂ COOH or N (C ₁ - C ₈ alkyl) ₃ Hal, or, if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -;
R ₃ means H or CH ₃ ;
Hal is Cl, Br or J;
n is a number ≥ 2;
p is the number 1 to 6;
q and r, independently of one another, mean 0 or 1,
in which (b ² ) 0.01 to 5 parts by weight inorganic salt per 100 parts by weight the specified polymer selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , solvated or complexed in a polyoxyalkylene of formula I, wherein the ratio of component (b ¹ ) to inorganic salt (b ² ) is 200: 1 - 1: 1.  2. The composition according to claim 1, characterized in that said thermoplastic, structurally cross-linked elastomeric or thermosetting polymer is selected from the group of compounds consisting of polyolefins, polystyrenes, polymers of α, β-unsaturated acids, halogen-containing polymers, homo- and copolymers of cyclic ethers polymers of unsaturated alcohols and amines, polyacetals, polyphenylene oxides, polyurethanes, polyamides, polyesters, polyureas, polycarbonates, polysulfones, products of the crosslinking of aldehydes with phenols on the one hand, urine or melamine on the other hand, alkyd resins capable of crosslinking acrylic resins, crosslinked epoxies, cellulose and natural rubber.  3. The composition according to claim 2, characterized in that the thermoplastic, structurally crosslinked or thermosetting polymers are selected from the group of compounds consisting of silt polyolefins, polystyrenes, polymers of α, β-unsaturated acids, halogen-containing polymers, homo- and copolymers of cyclic ethers.  4. The composition according to p. 1, characterized in that it contains, as natural fibers, chopped wood or vegetable waste, cotton, bast, jute, kapok, remy, linen, hemp, wool or silk.  5. The composition according to claim 1, characterized in that the organic fibers have a length of 0.01 to 200 mm 6. The composition according to p. 1, characterized in that R ₁ means H, C ₁ - C ₄ -alkyl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) - . 7. The composition according to claim 1, characterized in that R ₂ means C ₆ - C ₂₀ -alkyl, C ₆ - C ₂₀ -alkenyl or N (C ₁ - C ₈ -alkyl) ₃ Cl, CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -.  8. The composition according to claim 1, characterized in that n means the number 2 to 20, and p means the number 2 to 6.  9. The composition according to p. 1, characterized in that it contains, as compounds of the formula I, a compound selected from the group consisting of polypropylene glycol laurate, polypropylene glycol oleic ether, polypropylene glycolmethyldiethylammonium chloride, polyethylene glycol monomethyl ether, polyethylene glycol simplet dimethyl ether, polyethylene glycol polyethylene glycol ether, polyethylene glycol sorbitan monolaurate, polyethylene glycol stearate, polyethylene glycol polypropylene lauryl ether glycol polietilenglikollaurilovy simple carboxylic acid ester, polyethylene glycol, and -monoakrilat -triakrilat and polietilenglikoldimetakrilat - monomethacrylate and -trimetakrilat. 10. A method of producing a polymer with an antistatic finish by mixing a thermoplastic, structurally crosslinked elastomeric or thermosetting polymer with an antistatic agent containing an inorganic salt and a filler, using a device selected from the group consisting of calendars, rollers, mixers, extruders with or without introduction to mix the introduction of targeted additives, characterized in that 100 wt.h. the polymer is mixed with (a) 0.01 to 70 parts by weight filler is a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in contact with each other, on which (b) a polar antistatic is adsorbed, consisting of a mixture containing (b ¹ ) 0 01 - 20 parts by weight per 100 parts by weight a polyoxyalkylene polymer of formula I
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ ,
where R ₁ means H, C ₁ - C ₂₄ -alkyl, C ₂ - C ₂₄ -alkenyl, C ₁ - C ₂₄ -alkyl-C (O) -, C ₂ - C ₂₄ -alkenyl-C (O) -, CH ₂ = CH — C (O) - or CH ₂ = (CH) —C (O) -;
R ₂ is C ₁ - C ₂₄ alkyl, C ₂ - C ₂₄ alkenyl, CH ₂ COOH or N (C ₁ - C ₈ alkyl) ₃ Hal, or, if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -;
R ₃ means H or CH ₃ ;
Hal is Cl, Br or J;
n is a number ≥ 2;
p is the number 1 to 6;
q and r, independently of one another, mean 0 or 1,
and in which (b ² ) 0.01 to 5 parts by weight inorganic salt per 100 parts by weight the specified polymer selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ , KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , solvated or complexed in a polyoxyalkylene of formula I, wherein the ratio of component (b ¹ ) to inorganic salt (b ² ) is 200: 1 - 1: 1, as it is, or as components administered separately. 11. Composition for antistatic finish, comprising an antistatic agent containing inorganic salt, and a filler, characterized in that it contains (a) 0.01 to 70 parts by weight of filler is a polar, adsorbing inorganic or organic material in the form of fibers, which are granular or fibrous natural organic materials in contact with each other, on which (b) a polar antistatic is adsorbed, consisting of a mixture containing (b ¹ ) 0 01 - 20 parts by weight polyoxyalkylene of formula I
R ₁ -O- [CH (R ₃ ) -CH ₂ -O-] _n - [CH ₂ - [CH (OH)] _p -CH ₂ -O-] _q - [C (O)] _r -R ₂ ,
where R ₁ means H, C ₁ - C ₂₄ -alkyl, C ₂ - C ₂₄ -alkenyl, C ₁ - C ₂₄ -alkyl-C (O) -, C ₂ - C ₂₄ -alkenyl-C (O) -, CH ₂ = CH — C (O) - or CH ₂ = (CH ₃ ) —C (O) -;
R ₂ is C ₁ - C ₂₄ alkyl, C ₂ - C ₂₄ alkenyl, CH ₂ COOH or N (C ₁ - C ₈ alkyl) ₃ Hal, or, if r = 0, R ₂ also means CH ₂ = CH-C (O) - or CH ₂ = C (CH ₃ ) -C (O) -;
R ₃ means H or CH ₃ ;
Hal is Cl, Br or J;
n is a number ≥ 2;
p is the number 1 to 6;
q and r, independently of one another, mean 0 or 1,
in which (b ² ) 0.01 to 5 parts by weight an inorganic salt selected from the group consisting of LiClO ₄ , LiCF ₃ SO ₃ , NaClO ₄ , LiBF ₄ , NaBF ₄ , KBF ₄ , NaCF ₃ SO ₃ , KClO ₄ ,
KPF ₆ , KCF ₃ SO ₃ , KC ₄ F ₉ SO ₃ , Ca (ClO ₄ ) ₂ , Ca (PF ₆ ) ₂ , Mg (ClO ₄ ) ₂ , Mg (CF ₃ SO ₃ ) ₂ , Zn (ClO ₄ ) ₂ , Zn (PF ₆ ) ₂ and Ca (CF ₃ SO ₃ ) ₂ , is solvated or complexed in the polyoxyalkylene of formula I, wherein the ratio of component (b ¹ ) to inorganic salt (b ² ) is 200: 1 - 1: 1.

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