RU2008134477A - Композиция для стирки с тиазолиевым красителем - Google Patents
Композиция для стирки с тиазолиевым красителем Download PDFInfo
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- RU2008134477A RU2008134477A RU2008134477/04A RU2008134477A RU2008134477A RU 2008134477 A RU2008134477 A RU 2008134477A RU 2008134477/04 A RU2008134477/04 A RU 2008134477/04A RU 2008134477 A RU2008134477 A RU 2008134477A RU 2008134477 A RU2008134477 A RU 2008134477A
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- Prior art keywords
- moiety
- alkyl moiety
- formula
- saturated
- substituted
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- 239000000203 mixture Substances 0.000 title claims abstract 6
- 229920006395 saturated elastomer Polymers 0.000 claims abstract 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract 9
- 150000007942 carboxylates Chemical class 0.000 claims abstract 9
- 239000000975 dye Substances 0.000 claims abstract 9
- 239000001257 hydrogen Substances 0.000 claims abstract 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 7
- 125000000623 heterocyclic group Chemical group 0.000 claims abstract 7
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical group CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 5
- 229910002651 NO3 Inorganic materials 0.000 claims abstract 4
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical group [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims abstract 4
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 4
- 125000002837 carbocyclic group Chemical group 0.000 claims abstract 4
- 239000012634 fragment Substances 0.000 claims abstract 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical group [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract 4
- 239000010452 phosphate Chemical group 0.000 claims abstract 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract 3
- 239000007844 bleaching agent Substances 0.000 claims abstract 3
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical compound O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000004430 oxygen atom Chemical group O* 0.000 claims abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 3
- 229920000570 polyether Polymers 0.000 claims abstract 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical group CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract 2
- 239000000987 azo dye Substances 0.000 claims abstract 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract 2
- 150000002431 hydrogen Chemical group 0.000 claims abstract 2
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims abstract 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract 2
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims abstract 2
- 238000005406 washing Methods 0.000 claims abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims 4
- 230000002087 whitening effect Effects 0.000 claims 4
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical group C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- BBBUAWSVILPJLL-UHFFFAOYSA-N 2-(2-ethylhexoxymethyl)oxirane Chemical compound CCCCC(CC)COCC1CO1 BBBUAWSVILPJLL-UHFFFAOYSA-N 0.000 claims 1
- AQKDMKKMCVJJTC-UHFFFAOYSA-N 2-(2-methylpropoxymethyl)oxirane Chemical compound CC(C)COCC1CO1 AQKDMKKMCVJJTC-UHFFFAOYSA-N 0.000 claims 1
- YZUMRMCHAJVDRT-UHFFFAOYSA-N 2-(hexadecoxymethyl)oxirane Chemical compound CCCCCCCCCCCCCCCCOCC1CO1 YZUMRMCHAJVDRT-UHFFFAOYSA-N 0.000 claims 1
- LKMJVFRMDSNFRT-UHFFFAOYSA-N 2-(methoxymethyl)oxirane Chemical compound COCC1CO1 LKMJVFRMDSNFRT-UHFFFAOYSA-N 0.000 claims 1
- NWLUZGJDEZBBRH-UHFFFAOYSA-N 2-(propan-2-yloxymethyl)oxirane Chemical compound CC(C)OCC1CO1 NWLUZGJDEZBBRH-UHFFFAOYSA-N 0.000 claims 1
- SFJRUJUEMVAZLM-UHFFFAOYSA-N 2-[(2-methylpropan-2-yl)oxymethyl]oxirane Chemical compound CC(C)(C)OCC1CO1 SFJRUJUEMVAZLM-UHFFFAOYSA-N 0.000 claims 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 abstract 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/10—Azo dyes containing onium groups containing cyclammonium groups attached to an azo group by a carbon atom of the ring system
- C09B44/20—Thiazoles or hydrogenated thiazoles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
1. Отбеливающий агент для композиций для стирки, включающий тиазолиевый краситель, выбираемый из азокрасителей общей формулы (V): ! ! Формула V ! в которой ! а.) R1 выбирают из разветвленного или неразветвленного (С1-С22)-алкильного фрагмента, ароматического алкильного фрагмента, полиалкиленоксидного фрагмента или фрагмента, имеющего формулу (VI), представленную ниже: ! ! Формула VI ! в которой ! (i) R2 выбирают из водорода, метильного, этильного, пропильного, ацетатного или гидроксильного фрагмента; m и p являются независимо целыми числами от 0 до (n-1), при условии, что n является целым числом от 1 до 6 и m+p=(n-1); ! (ii) Y выбирают из гидроксильного, сульфонатного, сульфатного, карбоксилатного или ацетатного фрагмента; ! b.) R3 и R4: ! i.) независимо выбирают из водорода; насыщенного или ненасыщенного (С1-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента, включающего в дополнение к кислороду гидроксила еще атом кислорода; фрагмента простого полиэфира; амино-(С1-С22)-алкильного фрагмента; замещенного или незамещенного фенильного фрагмента; замещенного или незамещенного бензильного фрагмента; (С1-С22)-алкильного фрагмента, содержащего концевой сульфонат, сульфат, ацетат или карбоксилат; или ! ii.) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический или карбоциклический фрагмент; или ! iii.) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический или карбоциклический фрагмент, замещенный сульфатом, сульфонатом, фосфатом, нитратом и карбоксилатом; ! с.) Х является фрагментом, имеющим формулу VII, представленную ниже: ! ! Формула VII ! в которой ! i.) R5 и R6: ! (а) независимо выбирают и
Claims (6)
1. Отбеливающий агент для композиций для стирки, включающий тиазолиевый краситель, выбираемый из азокрасителей общей формулы (V):
Формула V
в которой
а.) R1 выбирают из разветвленного или неразветвленного (С1-С22)-алкильного фрагмента, ароматического алкильного фрагмента, полиалкиленоксидного фрагмента или фрагмента, имеющего формулу (VI), представленную ниже:
Формула VI
в которой
(i) R2 выбирают из водорода, метильного, этильного, пропильного, ацетатного или гидроксильного фрагмента; m и p являются независимо целыми числами от 0 до (n-1), при условии, что n является целым числом от 1 до 6 и m+p=(n-1);
(ii) Y выбирают из гидроксильного, сульфонатного, сульфатного, карбоксилатного или ацетатного фрагмента;
b.) R3 и R4:
i.) независимо выбирают из водорода; насыщенного или ненасыщенного (С1-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента, включающего в дополнение к кислороду гидроксила еще атом кислорода; фрагмента простого полиэфира; амино-(С1-С22)-алкильного фрагмента; замещенного или незамещенного фенильного фрагмента; замещенного или незамещенного бензильного фрагмента; (С1-С22)-алкильного фрагмента, содержащего концевой сульфонат, сульфат, ацетат или карбоксилат; или
ii.) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический или карбоциклический фрагмент; или
iii.) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический или карбоциклический фрагмент, замещенный сульфатом, сульфонатом, фосфатом, нитратом и карбоксилатом;
с.) Х является фрагментом, имеющим формулу VII, представленную ниже:
Формула VII
в которой
i.) R5 и R6:
(а) независимо выбирают из водорода; насыщенного или ненасыщенного (С1-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента; гидрокси-(С2-С22)-алкильного фрагмента, включающего в дополнение к кислороду гидроксила еще атом кислорода; кэппированного или некэппированного фрагмента простого полиэфира; амино-(С1-С22)-алкильного фрагмента; замещенного или незамещенного фенильного фрагмента; замещенного или незамещенного бензильного фрагмента; (С1-С22)-алкильного фрагмента, включающего концевой (С1-С4) алкиловый эфир, сульфонатный, сульфатный, ацетатный или карбоксилатный фрагмент; тиазольного фрагмента или
(b) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический фрагмент;
(с) взятые вместе, образуют насыщенный или ненасыщенный гетероциклический фрагмент, замещенный одним или более алкоксилатным, сульфатным, сульфонатным, фосфатным, нитратным и/или карбоксилатным фрагментами;
(d) взятые вместе с R7, R8 или R7 и R8, образуют один или более насыщенных или ненасыщенных гетероциклических фрагментов, необязательно замещенных одним или более алкоксилатным, сульфатным, сульфонатным, фосфатным, нитратным и/или карбоксилатным фрагментами;
(е) взятые вместе, образуют тиазольный фрагмент;
ii.) R7 и R8 могут быть независимо выбраны из водорода или насыщенного или ненасыщенного алкильного фрагмента;
d.) Q- является анионом, который уравновешивает общий заряд соединения формулы I, и показатель q равен 0 или 1.
2. Отбеливающий агент по п.1, в котором для тиазолиевого красителя:
а.) R1 является метильным фрагментом;
b.) R3 и R4 являются водородом; и
с.) Х имеет формулу VIII, представленную ниже:
Формула VIII
в которой
(i) R5 и R6 являются такими, как определено в п.1;
(ii) R7 является водородом или метильным фрагментом; и
(iii) R8 является водородом.
3. Отбеливающий агент по п.1, в котором R5 и R6 каждый включает независимо от 1 до 20 алкиленоксидных звеньев и, независимо, фрагмент, выбираемый из группы, состоящей из: стиролоксида, глицидилметилового эфира, изобутилглицидилового эфира, изопропилглицидилового эфира, трет-бутилглицидилового эфира, 2-этилгексилглицидилового эфира или глицидилгексадецилового эфира.
4. Отбеливающий агент по п.1, в котором тиазолиевый краситель выбирают из тиазолиевых красителей таблицы 1 №№ от 1 до 80 и их смесей.
5. Отбеливающий агент по п.4, в котором тиазолиевый краситель выбирают из тиазолиевых красителей таблицы 1 №№ 1, 4, 5, 7, 8, 12, 13, 15, 16, 17, 21, 24, 25, 26, 30, 31, 33, 36, 38, 40, 45, 48 и их смесей.
6. Отбеливающий агент по п.5, в котором тиазолиевый краситель выбирают из тиазолиевых красителей таблицы 1 №№ 12, 13, 15, 16, 24, 25, 26, 30, 31, 33, 36, 38, 40, 45, 48 и их смесей.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US76142806P | 2006-01-23 | 2006-01-23 | |
| US60/761,428 | 2006-01-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2008134477A true RU2008134477A (ru) | 2010-02-27 |
| RU2463339C2 RU2463339C2 (ru) | 2012-10-10 |
Family
ID=38134084
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008134477/04A RU2463339C2 (ru) | 2006-01-23 | 2007-01-19 | Композиция для стирки с тиазолиевым красителем |
| RU2008126376/04A RU2398012C2 (ru) | 2006-01-23 | 2007-01-19 | Композиции для ухода за бельем при стирке, содержащие тиазолиевый краситель |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2008126376/04A RU2398012C2 (ru) | 2006-01-23 | 2007-01-19 | Композиции для ухода за бельем при стирке, содержащие тиазолиевый краситель |
Country Status (10)
| Country | Link |
|---|---|
| US (6) | US7674757B2 (ru) |
| EP (2) | EP1976968B1 (ru) |
| JP (2) | JP5345399B2 (ru) |
| CN (2) | CN101370925B (ru) |
| BR (2) | BRPI0707211A2 (ru) |
| CA (2) | CA2633794A1 (ru) |
| MX (1) | MX338062B (ru) |
| RU (2) | RU2463339C2 (ru) |
| WO (2) | WO2007084729A2 (ru) |
| ZA (2) | ZA200805719B (ru) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2695059C2 (ru) * | 2014-07-17 | 2019-07-19 | Басф Се | Жидкие композиции моющих средств и их изготовление |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0314210D0 (en) * | 2003-06-18 | 2003-07-23 | Unilever Plc | Laundry treatment compositions |
| RU2463339C2 (ru) * | 2006-01-23 | 2012-10-10 | Милликен Энд Компани | Композиция для стирки с тиазолиевым красителем |
| US20080177089A1 (en) | 2007-01-19 | 2008-07-24 | Eugene Steven Sadlowski | Novel whitening agents for cellulosic substrates |
| US7642282B2 (en) | 2007-01-19 | 2010-01-05 | Milliken & Company | Whitening agents for cellulosic substrates |
| DE102007037430A1 (de) * | 2007-08-08 | 2009-02-12 | Henkel Ag & Co. Kgaa | Farbschützendes Wasch- oder Reinigungsmittel mit optischem Aufheller |
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-
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- 2007-01-19 WO PCT/US2007/001553 patent/WO2007084729A2/en not_active Ceased
- 2007-01-19 CN CN200780002960.XA patent/CN101370925B/zh active Active
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- 2007-01-19 CA CA002633794A patent/CA2633794A1/en not_active Abandoned
- 2007-01-19 EP EP07717982.8A patent/EP1976968B1/en not_active Not-in-force
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2695059C2 (ru) * | 2014-07-17 | 2019-07-19 | Басф Се | Жидкие композиции моющих средств и их изготовление |
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