KR920701289A - 에폭시-말단화된 폴리옥사졸리돈, 이의 제조방법 및 이로부터의 전기 적층물 - Google Patents
에폭시-말단화된 폴리옥사졸리돈, 이의 제조방법 및 이로부터의 전기 적층물Info
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- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
- C08G59/22—Di-epoxy compounds
- C08G59/28—Di-epoxy compounds containing acyclic nitrogen atoms
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- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
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- B32B2260/046—Synthetic resin
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- B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
- B32B2309/02—Temperature
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Abstract
Description
Claims (27)
- (A)(1) 5내지 30중량의 폴리이소시아네이트 화합물을 (2) (a) 70내지 95중량%의 폴리에폭사이드 화합물 및 (b) 0.01 내지 2중량%의 촉매를 포함하는 혼합물에 3내지 90분의 시간내에 첨가하고(여기서, 중량%는 폴리에폭사이드 화합물과 폴리이소시아네이트 화합물의 합한 중량을 기준으로 한다), (B) 단계(A)에서 수득된 반응 혼합물을 5 내지 180분의 시간동안 110℃내지 200℃의 온도로 가열하여 50 내지 100%의 원래의 이소시아네이트 그룹이 옥사졸리돈 환으로 전환되고 0 내지 50%의 원래의 이소시아네이트 그룹이 이소시아누레이트환으로 전환된 에폭시-말단화된 폴리옥사졸리돈을 수득함을 특징으로 하는, 승온에서 에폭시 그룹과 이소시아네이트 그룹을 반응시키기 위한 촉매의 존재하에 폴리에폭사이드 화합물을 폴리이소시아네이트 화합물과 반응시킴을 포함하는 경화시 유리전이도온도가 135℃이상이고 N-메틸피롤리돈 흡수율이 0.5%미만인 에폭시-말단화된 폴리옥사졸리돈의 제조방법.
- 제1항에 있어서, 단계(A)에서 0.02 내지 0.1중량%의 촉매가 사용됨을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈의 제조방법.
- 제1항에 있어서, 단계(A)에서 0.02 내지 0.1중량%의 촉매가 사용됨을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈의 제조방법.
- 제1항 내지 제3항 중의 어느 한 항에 있어서, 단계(A)에서 폴리이소시아네이트 화합물이 폴리에폭사이드 화합물 및 촉매의 혼합물에 15 내지 60분의 시간내에 첨가됨을 특징으로 하는 방법.
- 제4항에 있어서, 단계(A)에서 폴리이소시아네이트 화합물이 폴리에폭사이드 화합물 및 촉매의 혼합물에 20 내지 45분의 시간내에 첨가됨을 특징으로 하는 방법.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, 단계(B)에서 반응 혼합물이 120℃ 내지 180℃의 온도로 가열됨을 특징으로 하는 방법.
- 제6항에 있어서, 단계(B)에서 반응 혼합물이 140℃ 내지 160℃의 온도로 가열됨을 특징으로 하는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 소정량의 촉매 및 소정량의 폴리이소시아네이트 화합물의 존재하에 이소시아네이트 그룹의 옥사졸리돈 환 및 이소시아누레이트 환으로의 전환이 단계(B)에서 사용된 반응온도에 의해 조절되는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 소정의 반응온도 및 소정량의 폴리이소시아네이트 화합물의 존재하에 이소시아네이트 그룹의 옥사졸리돈 환 및 이소시아누레이트 환으로의 전환이 단계(A)에서 사용된 촉매의 양에 의해 조절되는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 소정량의 촉매 및 소정의 반응온도하에 이소시아네이트 그룹의 옥사졸리돈 및 이소시아누레이트 환으로의 전환이 단계(A)에서 사용된 폴리리이소시아네이트 화합물의 양에 의해 조절되는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 소정의 반응온도더, 소정량의 촉매 및 소정량의 폴리에폭사이드 및 폴리이소시아네이트 화합물의 존재하에 이소시아네이트 그룹의 옥사졸리돈 환 및 이소시아누레이트 환으로의 전환이 폴리이소시아네이트 화합물의 첨가 속도에 의해 조절하는 방법.
- 제1항 내지 제11항 중의 어느 한 항에 있어서, 사용된 촉매기 이미다졸 화합물 또는 테트라페닐포스포늄 브로마이드임을 특징으로 하는 방법.
- 제12항에 있어서, 이미다졸 화합물이 2-페닐이미다-졸, 2-메틸이미다졸, 2-에틸-4-메틸이미-다졸, 4,4-메틸렌-비스(2-에틸-5-메틸이미-다졸)임을 특징으로 하는 방법.
- 폴리이소시아네이트 화합물로부터 유도된 5 내지 30중량%의 단위와 폴리에폭사이드 화합물로부터 유도된 70내지 95중량%의 단위(여기서, 중량%는 폴리에폭사이드 화합물과 폴리이소시아네이트 화합물의 합한 중량을 기준으로 한다)를 포함하고, 옥사졸리돈 환으로서 존재하는 50 내지 100%의 원래 이소시아네이트 그룹 및 이소시아네이트 환으로서 존재하는 0 내지 50%의 원래의 이소시아네이트 그룹을 가지며, 유리전이온도가 135℃이상이고 N-메틸피솔리돈 흡수율일 0.5%미만인 에폭시-말단화된 폴리옥사졸리돈.
- 제1항 내지 제13항 중의 어느 한 항의 방법에 의해 제조된, 이소시아네이트 함량이 5 내지 30중량%의 에폭시-말단화된 폴리옥사졸리돈.
- 제14항 또는 제15항에 있어서, 사용된 폴리에폭사이드가 하기 일반식을 가짐을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈.상기 식에서, R은 치환되거나 비치환된 방향족, 지방족, 지환족 또는 헤테로사이클릭 다가 그룹이고, n은 1이상 5미만의 평균치를 갖는다.
- 제16항에 있어서, 사용된 폴리에폭사이드가 2,2-비스(4-하이드록시페닐)프로판, 2,2-비스(3,5-디브로모하이드록시페닐)프로판 또는 이의 둘 이상의 혼합물임을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈.
- 제14항 내지 제17항 중의 어느 한 항에 있어서, 사용된 폴리이소시아네이트 화합물이 하기 일반식을 가짐을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈.상기 식에서, R'는 치환되거나 비치환된 지방족, 지환족, 방향족 또는 헤테로사이클릭 다가 그룹이과 m은 1이상 5미만, 바람직하게는 1.5 내지 4, 가장 바람직하게는 2 내지 3의 평균치를 갖는다.
- 제17항에 있어서, 폴리이소시아네이트가 4,4'-메틸렌비스(페닐이소시아네이트)또는 이의 이성체, 중합체성 MDI 또는 톨루엔 디이소시아네이트, 또는 이의 둘 이상의 혼합물임을 특징으로 하는 에폭시-말단화된 폴리옥사졸리돈.
- 에폭시 수지가 제14항 내지 제19항 중의 어느 한 항에서 청구된 에폭시-말단화된 폴리옥사졸리돈임을 특징으로 하는 에폭시 수지, 에폭시 수지용 경화제, 유기 용매 및 임의로 촉진제 및 기타 통상적인 보조제를 포함하는 에폭시 수지 와니스 조성물.
- 제20항에 있어서, 에폭시-말단화된 폴리옥사졸리돈이 25 내지 75중량%의 와니스 조성물을 포함함을 특징으로 하는 에폭시 수지 와니스 조성물.
- 제20항에 있어서, 에폭시-말단화된 폴리옥사졸리돈이 35 내지 65중량%의 와니스 조성물을 포함함을 특징으로 하는 에폭시 수지 와니스 조성물.
- 제20항에 있어서, 에폭시-말단화된 폴리옥사졸리돈이 40 내지 60중량%의 와니스 조성물을 포함함을 특징으로 하는 에폭시 수지 와니스 조성물.
- 사용된 에폭시 수지 와니스가 제20항 내지 제23항 중의 어느 한 항의 에폭시 수지 와니스 조성물임을 특징으로 하는 (a) 보강 웹을 에폭시 수지 와니스 조성물, 에폭시 수지용 경화제 및 유기 용매로 함침시키고, (b) 이와같이 제조된 프리프레그(prepreg)를 에폭시 수지가 경화제와 부분적으로 반응하기에 충분한 온도로 가열하고, (c) 상기 프리프레의 적어도 한층을 전기 전도성 재료와 함께 적충시키고 이와 같이 하여 제조된 적층물을 승온으로 가열시키는 단계를 포함하는 전기 적층물의 제조방법.
- 제24항에 있어서, 단계(B)에서 에폭시 수지와 경화제의 부분 반응을 100℃ 내지 230℃의 온도에서 수행하고 적층단계(C)를 130℃ 내지 230℃의 온도 및 34kPa 내지 6.9MPa의 압력에서 수행함을 특징으로 하는 방법.
- 제24항 또는 제25항의 방법에 의해 제조됨을 특징으로 하는 전기 적충물.
- 제26항의 전기 적충물로부터 제조됨을 특징으로 하는 인쇄 회로판.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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| GB898912952A GB8912952D0 (en) | 1989-06-06 | 1989-06-06 | Epoxy-terminated polyoxazolidones,process for the preparation thereof and electrical laminates made from the epoxy-terminated polyoxazolidones |
| GB89129522 | 1989-06-06 | ||
| PCT/US1990/002973 WO1990015089A1 (en) | 1989-06-06 | 1990-05-25 | Epoxy-terminated polyoxazolidones, process of preparation, and electrical laminates therefrom |
| SG9590553 | 1995-03-28 |
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| KR920701289A true KR920701289A (ko) | 1992-08-11 |
| KR0160755B1 KR0160755B1 (en) | 1999-01-15 |
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|---|---|---|---|
| KR1019910701786A Expired - Fee Related KR0160755B1 (en) | 1989-06-06 | 1991-12-06 | Epoxy terminated polyoxazolidones |
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| US (1) | US5112932A (ko) |
| EP (1) | EP0478606B1 (ko) |
| JP (1) | JP2859956B2 (ko) |
| KR (1) | KR0160755B1 (ko) |
| AT (1) | ATE115596T1 (ko) |
| AU (1) | AU628596B2 (ko) |
| BR (1) | BR9007428A (ko) |
| CA (1) | CA2018265A1 (ko) |
| DE (1) | DE69015188T2 (ko) |
| DK (1) | DK0478606T3 (ko) |
| ES (1) | ES2067030T3 (ko) |
| GB (1) | GB8912952D0 (ko) |
| NZ (1) | NZ233933A (ko) |
| WO (1) | WO1990015089A1 (ko) |
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| KR102606942B1 (ko) | 2017-09-12 | 2023-11-29 | 디디피 스페셜티 일렉트로닉 머티리얼즈 유에스, 엘엘씨 | 1액형 강화 에폭시 접착제 |
| WO2019063391A1 (de) * | 2017-09-29 | 2019-04-04 | Basf Se | Thermoplastische polyoxazolidone aus diisocyanten und diglycidylether von 2-phenyl-1,3-propandiol-derivaten |
| EP3737725B1 (en) | 2018-01-08 | 2023-03-01 | DDP Specialty Electronic Materials US, LLC | Epoxy resin adhesive compositions |
| ES3013876T3 (en) | 2018-05-18 | 2025-04-15 | Dow Global Technologies Llc | A polyisocyanate component, a polyurethane foaming system and an article made therefrom |
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| JP2021526168A (ja) | 2018-06-05 | 2021-09-30 | ダウ グローバル テクノロジーズ エルエルシー | エポキシ繊維複合体をポリオレフィンにリサイクルするための方法 |
| WO2019240897A1 (en) | 2018-06-15 | 2019-12-19 | Dow Global Technologies Llc | Toughened epoxy compositions |
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| JP7512249B2 (ja) * | 2018-07-18 | 2024-07-08 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリオキサゾリドンのバルク重合 |
| EP3830156B1 (en) * | 2018-07-30 | 2024-11-27 | Dow Global Technologies LLC | Curable resin composition |
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| US11225542B1 (en) * | 2018-11-09 | 2022-01-18 | ASK Chemicals LLC | Erosion resistant foundry shapes prepared with an epoxy-acrylate cold-box binder |
| US11732085B2 (en) | 2019-02-15 | 2023-08-22 | Dow Global Technologies Llc | Epoxy composition |
| KR102862608B1 (ko) | 2019-05-21 | 2025-09-24 | 디디피 스페셜티 일렉트로닉 머티리얼즈 유에스, 엘엘씨 | 에폭시 접착제 조성물 및 사용 방법 |
| EP3750933A1 (en) * | 2019-06-12 | 2020-12-16 | Covestro Deutschland AG | Method for the production of epoxy-group terminated polyoxazolidinones |
| EP3986949A1 (en) | 2019-06-18 | 2022-04-27 | DDP Specialty Electronic Materials US, LLC | One-component toughened epoxy adhesives with improved humidity resistance |
| JP7647101B2 (ja) * | 2019-11-18 | 2025-03-18 | 東レ株式会社 | 繊維強化複合材料の成形方法、およびそれに用いられるエポキシ樹脂組成物 |
| US20210253772A1 (en) * | 2020-02-18 | 2021-08-19 | Covestro Llc | Polyoxazolidinone compositions |
| WO2022122606A1 (en) | 2020-12-10 | 2022-06-16 | Covestro Deutschland Ag | Composition comprising epoxy-functional oxazolidinone |
| EP4011927A1 (en) | 2020-12-10 | 2022-06-15 | Covestro Deutschland AG | Composition comprising epoxy-functional oxazolidinone |
| JP2023149613A (ja) * | 2022-03-31 | 2023-10-13 | 日鉄ケミカル&マテリアル株式会社 | 硬化性樹脂組成物、及びそれを用いたトウプリプレグ |
| WO2024076408A1 (en) | 2022-10-06 | 2024-04-11 | Ddp Specialty Electronic Materials Us, Llc | Two-component adhesive composition |
| CN119968413A (zh) | 2022-10-06 | 2025-05-09 | Ddp 特种电子材料美国有限责任公司 | 双组分粘合剂组合物 |
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| US3305494A (en) * | 1963-04-12 | 1967-02-21 | Baker Chem Co J T | Oxazolidonyl sulfones and method of making same |
| US3334110A (en) * | 1965-08-16 | 1967-08-01 | Baker Chem Co J T | Method for preparing epoxyoxazolidinones |
| US3494888A (en) * | 1966-08-30 | 1970-02-10 | Wilbur R Mcelroy | Resin compositions from polyepoxides and isocyanate polymers |
| US3471442A (en) * | 1967-02-02 | 1969-10-07 | American Cyanamid Co | Process for the preparation of thermoplastic polymers prepared by reacting diepoxide monomers with aromatic diisocyanates |
| US3694406A (en) * | 1970-07-31 | 1972-09-26 | Us Air Force | Preparation of polyoxazolidones |
| US3767624A (en) * | 1971-12-27 | 1973-10-23 | Dow Chemical Co | Oxazolidinone modified epoxy novolac resin |
| JPS5231000B2 (ko) * | 1972-11-29 | 1977-08-11 | ||
| JPS5315757B2 (ko) * | 1973-08-31 | 1978-05-26 | ||
| JPS57131219A (en) * | 1981-02-06 | 1982-08-14 | Sumitomo Bakelite Co Ltd | Thermosetting resin composition |
| ZA839459B (en) * | 1982-12-30 | 1985-08-28 | Mobil Oil Corp | Polyoxazolidone powder coating compositions |
| DE3323122A1 (de) * | 1983-06-27 | 1985-05-23 | Siemens AG, 1000 Berlin und 8000 München | Verfahren zur herstellung von reaktionsharzformstoffen |
| FR2549277B1 (fr) * | 1983-07-13 | 1985-10-25 | Alsthom Atlantique | Procede d'isolation par impregnation d'un bobinage electrique, et vernis sans solvant stabilise utilisable dans ce procede |
| GB8412900D0 (en) * | 1984-05-21 | 1984-06-27 | Secr Defence | Thermosetting resin compositions |
| DE3720759A1 (de) * | 1987-06-24 | 1989-01-05 | Bayer Ag | Oxazolidongruppen enthaltende epoxidharze |
-
1989
- 1989-06-06 GB GB898912952A patent/GB8912952D0/en active Pending
-
1990
- 1990-05-25 DK DK90909068.0T patent/DK0478606T3/da active
- 1990-05-25 EP EP90909068A patent/EP0478606B1/en not_active Expired - Lifetime
- 1990-05-25 AT AT90909068T patent/ATE115596T1/de active
- 1990-05-25 JP JP2508802A patent/JP2859956B2/ja not_active Expired - Lifetime
- 1990-05-25 WO PCT/US1990/002973 patent/WO1990015089A1/en not_active Ceased
- 1990-05-25 BR BR909007428A patent/BR9007428A/pt not_active IP Right Cessation
- 1990-05-25 ES ES90909068T patent/ES2067030T3/es not_active Expired - Lifetime
- 1990-05-25 AU AU58291/90A patent/AU628596B2/en not_active Ceased
- 1990-05-25 DE DE69015188T patent/DE69015188T2/de not_active Expired - Lifetime
- 1990-06-01 US US07/531,963 patent/US5112932A/en not_active Expired - Lifetime
- 1990-06-05 NZ NZ233933A patent/NZ233933A/en unknown
- 1990-06-05 CA CA002018265A patent/CA2018265A1/en not_active Abandoned
-
1991
- 1991-12-06 KR KR1019910701786A patent/KR0160755B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| AU628596B2 (en) | 1992-09-17 |
| DE69015188T2 (de) | 1995-05-04 |
| EP0478606B1 (en) | 1994-12-14 |
| US5112932A (en) | 1992-05-12 |
| DK0478606T3 (da) | 1995-05-15 |
| NZ233933A (en) | 1993-05-26 |
| DE69015188D1 (de) | 1995-01-26 |
| ES2067030T3 (es) | 1995-03-16 |
| JPH04506678A (ja) | 1992-11-19 |
| KR0160755B1 (en) | 1999-01-15 |
| EP0478606A4 (en) | 1992-05-13 |
| JP2859956B2 (ja) | 1999-02-24 |
| AU5829190A (en) | 1991-01-07 |
| ATE115596T1 (de) | 1994-12-15 |
| WO1990015089A1 (en) | 1990-12-13 |
| GB8912952D0 (en) | 1989-07-26 |
| CA2018265A1 (en) | 1990-12-06 |
| EP0478606A1 (en) | 1992-04-08 |
| BR9007428A (pt) | 1992-07-21 |
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