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GB2186594A - Steel alloys - Google Patents

Steel alloys Download PDF

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Publication number
GB2186594A
GB2186594A GB08700647A GB8700647A GB2186594A GB 2186594 A GB2186594 A GB 2186594A GB 08700647 A GB08700647 A GB 08700647A GB 8700647 A GB8700647 A GB 8700647A GB 2186594 A GB2186594 A GB 2186594A
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GB
United Kingdom
Prior art keywords
alloy
boron
sulphur
carbon
chromium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB08700647A
Other versions
GB2186594B (en
GB8700647D0 (en
Inventor
Peter Richard Roberts
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hunting Oilfield Services Ltd
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Hunting Oilfield Services Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hunting Oilfield Services Ltd filed Critical Hunting Oilfield Services Ltd
Publication of GB8700647D0 publication Critical patent/GB8700647D0/en
Publication of GB2186594A publication Critical patent/GB2186594A/en
Application granted granted Critical
Publication of GB2186594B publication Critical patent/GB2186594B/en
Expired legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/42Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/54Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

A low carbon steel alloy particularly but not exclusively for making forged tubular elements such as oilfield pipe connectors comprises (by weight): carbon 0.05 - 0.25% silicon 0.01 - 0.35% manganese 1.15 - 0.65% phosphorus up to - 0.015% sulphur up to - 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.10 niobium 0.015 - 0.10% boron 0.0005 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.05% aluminium 0.04 - 0.15% nitrogen 0.001 - 0.15% the balance being iron and unavoidable impurities.

Description

SPECIFICATION Steel alloys This invention is concerned with low carbon steel alloys which are suitable for use, inter alia, for forgings and roll forged tubular elements used in the manufacture of tubular metal components, such as oilfield connectors.
Particularly demanding requirements are placed on materials for such uses; suitable steels should have a combination of very high yield strength, high notch ductility at sub-zero temperatures, particularly in heavy wall thicknesses, be weldable and machinable, but yet be economical to manufacture.
Forged alloy steels having relatively high carbon, nickel, chromium and molybdenum contents (up to 0.45%, 1.8%, 1.1% and 0.35% respectively) are conventionally employed for such uses.
Such steels have high yield strength, but are expensive to manufacture and have relatively poor notch ductility, particularly at sub-zero temperatures, and poor weldability.
We have now developed a range of steel alloys which largely overcome the limitations of such conventional alloys. The alloys of the present invention make use of other alloying elements, particularly manganese, vanadium, niobium, zirconium, boron and copper, to replace the greater proportion of the nickel and chromium in the conventional steels, have reduced carbon, phosphorus and sulphur contents, and may be calcium treated. The resulting alloys have high yield strength, greatly improved sub-zero notch ductility and weldability, and excellent machining properties.
According to the present invention, there is provided a low carbon steel alloy, which comprises (by weight): carbon 0.05 - 0.25% silicon 0.01 - 0.35% manganese 1.15 - 1.65% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.10% niobium 0.015 - 0.10% boron 0.0005 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.04 - 0.15% nitrogen 0.001 - 0.15% the balance being iron and unavoidable impurities.
The alloy may, depending on the sulphur content, be calcium treated during production.
It has been found that the preferred composition of the alloy for use in manufacturing forged tubular elements, such as pipes and pipe connectors, is dependent on the wall thickness of the forging.
In the manufacture of forgings having a wall thickness of up to 60 mm, it is preferred that the alloy comprises (by weight): carbon 0.10 - 0.20% silicon 0.15 - 0.35% manganese 1.15 - 1.45% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.50% molybdenum 0.30 - 0.55% nickel 0.15 - 0.50% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.002 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.05% aluminium 0.085 - 0.12% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
To further improve the weldability of the alloy for forgings which are required to be welded and have a wall thickness up to 60 mm, the boron and aluminium contents are advantageously adjusted to provide an alloy comprising (by weight): carbon 0.10 - 0.20% silicon 0.15 - 0.35% manganese 1.15 - 1.45% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.50% molybdenum 0.30 - 0.55% nickel 0.15 - 0.50% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.0005 - 0.002% titanium 0.001 - 0.05% zirconium 0.001 - 0.05% aluminium 0.04 - 0.06% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
For forgings having a wall thickness of greater than 60 mm, it is preferred that the alloy comprises (by weight): carbon 0.15 - 0.25% silicon 0.15 - 0.35% manganese 1.25 - 1.55% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.002 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.085 - 0.12% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
To further improve the weldability of the alloy for forgings which are required to be welded and have a wall thickness greater than 60 mm, the boron and aluminium contents are advantageously adjusted to provide an alloy comprising (by weight): carbon 0.15 - 0.25% silicon 0.15 - 0.35% manganese 1.25 - 1.55% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.0005 - 0.002% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.04 - 0.06% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
The alloys of the present invention are fully killed, fine grained, may, depending on the sulphur content, be calcium treated, and have a low sulphur content. They can be produced by any of the more modern steel making processes and may be forged from ingot or from continuously cast stock. Depending on the range and specific mechanical properties required, the alloys may, after forging, be normalised or quenched with oil or water and then tempered, preferably at a temperature above 600 C.
When forged, quenched, and tempered, the mechanical properties of the alloys both before and after welding are typically as follows: yield strength (0.2% PS) - not less than 700 N/mm2 ultimate tensile strength - not less than 860 n/mm2 % elongation - not less than 15 % reduction in area - not less than 40 impact strength (Kv, and KV1) at-55C - not less than 27 joules.
The alloys have good weldability and excellent machinability.
By way of specific example, typical values for a steel having mechanical properties which fall within the ranges given above are as follows: yield strength (0.2% PS) - 871 N/mm2 ultimate tensile strength - 914 N/mm2 % elongation 22 22 % reduction in area - 64 Charpy Vee notch impact value at- 55"C
K - 71 78 )joules 66 Kvi - 71 64 )joules 70

Claims (7)

1. A low carbon steel alloy comprising (by weight): carbon 0.05 - 0.25% silicon 0.01 - 0.35% manganese 1.15 - 1.65% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.10% niobium 0.015 - 0.10% boron 0.0005 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.04 - 0.15% nitrogen 0.001 - 0.15% the balance being iron and unavoidable impurities.
2. An alloy as claimed in claim 1, wherein the alloy is calcium treated.
3. A forged tubular element made from an alloy as claimed in either claim 1 or claim 2.
4. A tubular element having a wall thickness of up to 60 mm made from an alloy which comprises (by weight): carbon 0.10 - 0.20% silicon 0.15 - 0.35% manganese 1.15 - 1.45% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.50% molybdenum 0.30 - 0.55% nickel 0.15 - 0.50% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.002 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.05% aluminium 0.085 - 0.12% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
5. A tubular element having a wall thickness of up to 60 mm made from an alloy which comprises (by weight): carbon 0.10 - 0.20% silicon 0.15 - 0.35% manganese 1.15 - 1.45% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.50% molybdenum 0.30 - 0.55% nickel 0.15 - 0.50% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.0005 - 0.002% titanium 0.001 - 0.05% zirconium 0.001 - 0.05% aluminium 0.04 - 0.06% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
6. A tubular element having a wall thickness greater than 60 mm made from an alloy which comprises (by weight): carbon 0.15 - 0.25% silicon 0.15 - 0.35% manganese 1.25 - 1.55% phosphorus up to 0.015% sulphur up to 0.015% chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.035 niobium 0.015 - 0.035% boron 0.002 - 0.005% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.085 - 0.12% nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
7. A tubular element having a wall thickness greater than 60 mm made from an alloy which comprises (by weight): carbon 0.15 - 0.25% silicon 0.15 - 0.35% manganese 1.25 - 1.55% phosphorus up to 0.015% sulphur up to 0.0150 chromium 0.15 - 0.75% molybdenum 0.30 - 0.65% nickel 0.15 - 0.75% copper 0.10 - 0.50% vanadium 0.015 - 0.035% niobium 0.015 - 0.035% boron 0.0005 - 0.002% titanium 0.001 - 0.05% zirconium 0.001 - 0.10% aluminium 0.04 - 0.06to nitrogen 0.001 - 0.010% the balance being iron and unavoidable impurities.
GB8700647A 1986-02-13 1987-01-13 Steel alloys Expired GB2186594B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB868603500A GB8603500D0 (en) 1986-02-13 1986-02-13 Steel alloys

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GB8700647D0 GB8700647D0 (en) 1987-02-18
GB2186594A true GB2186594A (en) 1987-08-19
GB2186594B GB2186594B (en) 1989-11-08

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GB8700647A Expired GB2186594B (en) 1986-02-13 1987-01-13 Steel alloys

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Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0460591A1 (en) * 1990-06-05 1991-12-11 The Ferrous Wheel Group, Inc. High performance high strength low alloy steel
WO1993016208A1 (en) * 1992-02-14 1993-08-19 Nauchno-Proizvodstvennoe Predpriyatie 'salma' Cold-resistant cast steel
EP0709481A1 (en) * 1994-10-31 1996-05-01 CREUSOT LOIRE INDUSTRIE (Société Anonyme) Low alloy steel for the manufacture of moulds for plastic materials or for rubber articles
EP0775756A1 (en) * 1995-11-27 1997-05-28 ASCOMETAL (Société anonyme) Steel for the production of forgings with bainitic structure, and production process of forged parts
FR2748037A1 (en) * 1996-04-29 1997-10-31 Creusot Loire WELD REPAIRABLE STEEL FOR THE MANUFACTURING OF MOLDS FOR PLASTIC MATERIALS
FR2756298A1 (en) * 1996-11-26 1998-05-29 Ascometal Sa STEEL AND PROCESS FOR THE MANUFACTURE OF A MECHANICAL PART HAVING A BATH STRUCTURE
EP0851038A1 (en) * 1996-12-31 1998-07-01 Ascometal Steel and process for forming a steel article by cold plastic working
EP1081245A1 (en) * 1999-08-31 2001-03-07 Sumitomo Metal Industries, Ltd. Heat resistant Cr-Mo alloy steel
RU2217520C2 (en) * 2002-02-08 2003-11-27 Открытое акционерное общество специального машиностроения и металлургии "Мотовилихинские заводы" Steel
FR2847592A1 (en) * 2002-11-27 2004-05-28 Ispat Unimetal Steel for the fabrication of high performance precision mechanical components by either hot or cold deformation processes, has a bainitic structure
RU2243288C1 (en) * 2003-12-03 2004-12-27 Открытое акционерное общество "Северсталь" Steel
RU2249625C1 (en) * 2003-12-26 2005-04-10 Общество с ограниченной ответственностью "Интелмет НТ" Round-profiled rolled iron from low-alloyed steel for cold die forging of high-strength fastening members
GB2412178B (en) * 2002-09-20 2007-05-02 Enventure Global Technology Pipe formability evaluation for expandable tubulars
FR2931166A1 (en) * 2008-05-15 2009-11-20 Arcelormittal Gandrange Sa HOT FORGED STEEL WITH HIGH MECHANICAL CHARACTERISTICS OF THE PARTS PRODUCED
RU2414521C1 (en) * 2009-10-06 2011-03-20 Общество с ограниченной ответственностью "Самарский инженерно-технический центр" Corrosion resistant steel for flow and casing strings
CN102071367A (en) * 2010-11-24 2011-05-25 南京迪威尔重型锻造股份有限公司 Steel forging manufacturing process for deep-sea Christmas tree equipment connectors
CN102181793A (en) * 2011-04-02 2011-09-14 南京迪威尔重型锻造股份有限公司 Process for manufacturing steel forge piece of vertical conveying pipe of deep sea oil extraction equipment
CN102312173A (en) * 2010-06-29 2012-01-11 鞍钢股份有限公司 Steel for large heat input welded structure with tensile strength of 700MPa and its manufacturing method
DE10143073B4 (en) 2000-09-01 2022-06-09 Nippon Steel & Sumitomo Metal Corporation Low carbon steel and method of making structural steel tube with high cold temperature toughness

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104357752B (en) * 2014-10-21 2016-11-23 盐城奥克阀门有限公司 A kind of alloy material for valve casting and process technique thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1034859A (en) * 1963-03-02 1966-07-06 Ishikawajima Harima Heavy Ind Alloy
GB1083466A (en) * 1963-12-05 1967-09-13 Ishikawajima Harima Heavy Ind Method of manufacturing steel with improved mechanical properties
GB1473934A (en) * 1973-07-31 1977-05-18 Nippon Steel Corp Steel making

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2155035B (en) * 1984-02-29 1988-07-27 Skf Steel Eng Ab Steel ring

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1034859A (en) * 1963-03-02 1966-07-06 Ishikawajima Harima Heavy Ind Alloy
GB1083466A (en) * 1963-12-05 1967-09-13 Ishikawajima Harima Heavy Ind Method of manufacturing steel with improved mechanical properties
GB1473934A (en) * 1973-07-31 1977-05-18 Nippon Steel Corp Steel making

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0460591A1 (en) * 1990-06-05 1991-12-11 The Ferrous Wheel Group, Inc. High performance high strength low alloy steel
WO1993016208A1 (en) * 1992-02-14 1993-08-19 Nauchno-Proizvodstvennoe Predpriyatie 'salma' Cold-resistant cast steel
EP0709481A1 (en) * 1994-10-31 1996-05-01 CREUSOT LOIRE INDUSTRIE (Société Anonyme) Low alloy steel for the manufacture of moulds for plastic materials or for rubber articles
FR2726287A1 (en) * 1994-10-31 1996-05-03 Creusot Loire LOW-ALLOY STEEL FOR THE MANUFACTURE OF MOLDS FOR PLASTICS OR RUBBER
US5645794A (en) * 1994-10-31 1997-07-08 Creusot Loire Inudstrie Low alloy steel for the manufacture of molds for plastics and for rubber
US5762725A (en) * 1995-11-27 1998-06-09 Ascometal Steel for the manufacture of forging having a bainitic structure and process for manufacturing a forging
EP0775756A1 (en) * 1995-11-27 1997-05-28 ASCOMETAL (Société anonyme) Steel for the production of forgings with bainitic structure, and production process of forged parts
FR2741632A1 (en) * 1995-11-27 1997-05-30 Ascometal Sa STEEL FOR MANUFACTURING A FORGED PIECE HAVING A BAINITIQUE STRUCTURE AND METHOD FOR MANUFACTURING A PIECE
EP0805221A1 (en) * 1996-04-29 1997-11-05 CREUSOT LOIRE INDUSTRIE (Société Anonyme) Steel, repairable by welding, for the manufacture of moulds for the plastics industry
US5855846A (en) * 1996-04-29 1999-01-05 Creusot Loire Industrie Steel repairable by welding for the manufacture of molds for plastics
FR2748037A1 (en) * 1996-04-29 1997-10-31 Creusot Loire WELD REPAIRABLE STEEL FOR THE MANUFACTURING OF MOLDS FOR PLASTIC MATERIALS
CN1073642C (en) * 1996-04-29 2001-10-24 克罗索·洛利工业责任有限公司 Steel repairable by welding for manufacture of moulds for plastics
FR2756298A1 (en) * 1996-11-26 1998-05-29 Ascometal Sa STEEL AND PROCESS FOR THE MANUFACTURE OF A MECHANICAL PART HAVING A BATH STRUCTURE
EP0845544A1 (en) * 1996-11-26 1998-06-03 Ascometal Steel product made from bainitic steel and process for making the steel product
RU2201468C2 (en) * 1996-12-31 2003-03-27 Аскометаль Steel for manufacture of part by cold plastic deformation and method of manufacture of such part
EP0851038A1 (en) * 1996-12-31 1998-07-01 Ascometal Steel and process for forming a steel article by cold plastic working
FR2757877A1 (en) * 1996-12-31 1998-07-03 Ascometal Sa STEEL AND PROCESS FOR THE MANUFACTURE OF A STEEL PART SHAPED BY COLD PLASTIC DEFORMATION
US5919415A (en) * 1996-12-31 1999-07-06 Ascometal Steel and process for the manufacture of a steel component formed by cold plastic deformation
EP1081245A1 (en) * 1999-08-31 2001-03-07 Sumitomo Metal Industries, Ltd. Heat resistant Cr-Mo alloy steel
US6358336B1 (en) 1999-08-31 2002-03-19 Sumitomo Metal Industries, Ltd. Heat resistance Cr-Mo alloy steel
DE10143073B4 (en) 2000-09-01 2022-06-09 Nippon Steel & Sumitomo Metal Corporation Low carbon steel and method of making structural steel tube with high cold temperature toughness
RU2217520C2 (en) * 2002-02-08 2003-11-27 Открытое акционерное общество специального машиностроения и металлургии "Мотовилихинские заводы" Steel
GB2412178B (en) * 2002-09-20 2007-05-02 Enventure Global Technology Pipe formability evaluation for expandable tubulars
FR2847592A1 (en) * 2002-11-27 2004-05-28 Ispat Unimetal Steel for the fabrication of high performance precision mechanical components by either hot or cold deformation processes, has a bainitic structure
WO2004050935A1 (en) * 2002-11-27 2004-06-17 Mittal Steel Gandrange Ready-use low-carbon steel mechanical component for plastic deformation and method for making same
RU2243288C1 (en) * 2003-12-03 2004-12-27 Открытое акционерное общество "Северсталь" Steel
RU2249625C1 (en) * 2003-12-26 2005-04-10 Общество с ограниченной ответственностью "Интелмет НТ" Round-profiled rolled iron from low-alloyed steel for cold die forging of high-strength fastening members
WO2009138586A3 (en) * 2008-05-15 2010-01-07 Arcelormittal Gandrange Micro-alloyed steel for hot forging parts having high mechanical characteristics
FR2931166A1 (en) * 2008-05-15 2009-11-20 Arcelormittal Gandrange Sa HOT FORGED STEEL WITH HIGH MECHANICAL CHARACTERISTICS OF THE PARTS PRODUCED
RU2414521C1 (en) * 2009-10-06 2011-03-20 Общество с ограниченной ответственностью "Самарский инженерно-технический центр" Corrosion resistant steel for flow and casing strings
CN102312173A (en) * 2010-06-29 2012-01-11 鞍钢股份有限公司 Steel for large heat input welded structure with tensile strength of 700MPa and its manufacturing method
CN102071367A (en) * 2010-11-24 2011-05-25 南京迪威尔重型锻造股份有限公司 Steel forging manufacturing process for deep-sea Christmas tree equipment connectors
CN102071367B (en) * 2010-11-24 2012-04-04 南京迪威尔重型锻造股份有限公司 Steel forging manufacturing process for deep-sea Christmas tree equipment connectors
CN102181793A (en) * 2011-04-02 2011-09-14 南京迪威尔重型锻造股份有限公司 Process for manufacturing steel forge piece of vertical conveying pipe of deep sea oil extraction equipment
CN102181793B (en) * 2011-04-02 2012-05-30 南京迪威尔重型锻造股份有限公司 Process for manufacturing steel forge piece of vertical conveying pipe of deep sea oil extraction equipment

Also Published As

Publication number Publication date
GB2186594B (en) 1989-11-08
GB8700647D0 (en) 1987-02-18
GB8603500D0 (en) 1986-03-19

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Legal Events

Date Code Title Description
732 Registration of transactions, instruments or events in the register (sect. 32/1977)
PCNP Patent ceased through non-payment of renewal fee

Effective date: 19970113