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EP1336001B1 - Textile flachengebilde mit hoher sichtbarkeit - Google Patents

Textile flachengebilde mit hoher sichtbarkeit Download PDF

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Publication number
EP1336001B1
EP1336001B1 EP01982566A EP01982566A EP1336001B1 EP 1336001 B1 EP1336001 B1 EP 1336001B1 EP 01982566 A EP01982566 A EP 01982566A EP 01982566 A EP01982566 A EP 01982566A EP 1336001 B1 EP1336001 B1 EP 1336001B1
Authority
EP
European Patent Office
Prior art keywords
yarns
fibres
family
fibers
warp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01982566A
Other languages
English (en)
French (fr)
Other versions
EP1336001A1 (de
Inventor
Laurent Thiriot
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kermel SNC
Original Assignee
Kermel SNC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Kermel SNC filed Critical Kermel SNC
Publication of EP1336001A1 publication Critical patent/EP1336001A1/de
Application granted granted Critical
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Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00—Materials specially adapted for outerwear
    • A41D31/04—Materials specially adapted for outerwear characterised by special function or use
    • A41D31/08—Heat resistant; Fire retardant
    • D—TEXTILES; PAPER
    • D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/34—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns
    • D02G3/346—Yarns or threads having slubs, knops, spirals, loops, tufts, or other irregular or decorative effects, i.e. effect yarns with coloured effects, i.e. by differential dyeing process
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3065—Including strand which is of specific structural definition
    • Y10T442/313—Strand material formed of individual filaments having different chemical compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/3187—Triaxially woven fabric
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/3195—Three-dimensional weave [e.g., x-y-z planes, multi-planar warps and/or wefts, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/322—Warp differs from weft
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30—Woven fabric [i.e., woven strand or strip material]
    • Y10T442/3179—Woven fabric is characterized by a particular or differential weave other than fabric in which the strand denier or warp/weft pick count is specified
    • Y10T442/322—Warp differs from weft
    • Y10T442/3228—Materials differ

Definitions

  • the present invention relates to the field of high visibility textile surfaces. More particularly, it relates to a woven textile article that can be used to make high visibility clothing and provides good protection against heat and flame.
  • Yarns of yellow color and orange threads are thus known which, when woven, make it possible to obtain a sufficient level of visibility. Visibility criteria are for example defined in the EN 471 standard.
  • yellow fabrics are known which meet the criteria of high visibility and fire protection. These fabrics are obtained by weaving yarn intrinsically resistant to heat containing yellow pigments. These fabrics also have a relatively poor color retention.
  • the object of the present invention is to propose a solution to this problem, and to propose new textile surfaces of high visibility and offering protection against the risks associated with fire, especially new yellow textile surfaces.
  • the textile surface has at least one high visibility face, yellow or orange.
  • High visibility is characterized by the chromaticity coordinates and the luminance factor in accordance with EN 471.
  • the methods for measuring the chromaticity coordinates and the luminance factor are specified in CIE 15: 2: 1968.
  • the surface is obtained from yarns or fibers of several types, the yarns or fibers A, B, C. If a yarn or a fiber has both the characteristics of yarns or fibers of two types A and B, it falls within each of these natures.
  • the surface is for example obtained by weaving or knitting, with a construction such that the son or fibers C appear on the face of high visibility.
  • the son or fibers A are arranged in the textile surface in two distinct directions, for example in two weaving directions.
  • Yarn means a continuous multifilament object, a continuous yarn of fibers, obtained from a single type of fibers, or a mixture of fibers, for example fibers A and B in intimate mixture, or fibers A or B with other fibers.
  • the son or fibers A are thermostable. These are yarns or fibers whose shrinkage and loss of mechanical properties are limited after short exposure to a flame (of the order of 3 to 4 seconds).
  • aramid-based yarns or fibers such as polyamide-imide, polyparaphenylene terephthalamide, polymetaphenylene isophthalamide, polyimides, polybenzimidazole (PBI), and polyparaphenylene-2,6-benzobisoxazole (PBO).
  • Yarns A may consist of a blend of fibers, intimate blend or heart / skin blend (core fiber yarns).
  • the yarns may also consist of polymetaphenylene isophthalamide fibers, or mixtures of these fibers with, in particular, polyparaphenylene terephthalamide fibers.
  • fiber yarns comprising modacrylic fibers are Protex M or S fibers marketed by Kaneka, Lufnen fibers VF1 and VE1, Super valzer fibers.
  • the son or fibers B preferably have an oxygen limit index greater than 30%.
  • They may for example be son or fibers based on polyethylene terephthalate comprising a pigment introduced before the spinning and conferring the required color son or fibers.
  • the pigment is advantageously orange. It may for example be orange threads marketed by the company Trevira under the reference Texturgarn Typ 501 V.
  • the surface is obtained by weaving at least three families of son.
  • Wire families define at least part of the structure and construction of the surface. Each family may comprise threads or fibers of different types.
  • a first family is called the family of superior sons. This family constitutes a chain or a frame appearing on the face of high visibility. It comprises yarns or fibers C. It may optionally also comprise yarns or fibers A and / or B.
  • a second family is called the family of lower sons. This family is made up of threads parallel to the family of lower threads. The lower threads do not appear on the high visibility side.
  • a third family is called the family of transverse threads. This family consists of wires perpendicular to the lower threads. It is woven with at least the family of lower threads. It can be woven also with other families of threads, for example with the family of higher threads or with another family of fibers, different from the family of upper sons and the family of lower threads.
  • At least one family chosen from the family of lower son and the family of transverse son comprises son or fiber B, and the family of lower son and the family of transverse son each comprise
  • one of the families comprises both yarns or fibers A and yarns or fibers B. It may be a yarn spun from A fibers and fibers. B. This family may for example be made of fiber yarn A and B in intimate mixture.
  • the family of transverse yarns consists of yarns spun from A and B fibers in intimate mixture, and the family of lower yarns is made of yarns obtained from heat-stable fibers, alone or as a mixture, for example an intimate mixture with other fibers.
  • the latter son may, for example, be intimate mixtures of aramid fibers and flame retarded fibers based on viscose.
  • the surface may for example be obtained by double-warp or double-weave weaving.
  • double-warp weave the family of upper threads constitutes the upper warp
  • the family of lower threads constitutes the lower warp
  • the family of transverse threads constitutes the warp.
  • double weft structure the family of upper threads constitutes the upper weft
  • the family of lower threads constitutes the lower thread
  • the family of cross threads constitutes the thread.
  • the lower thread family is not apparent on the high visibility face.
  • the family of upper sons is not apparent.
  • the two faces are respectively weavings transverse son with respectively upper and lower son.
  • the weave armor can be armor derived from linen, satin, twill.
  • a preferred armor is twill weave of 4 double warp or double warp.
  • the proportion by weight in the textile surface of yarns or fibers A is preferably greater than 35%.
  • the proportion by weight of yarns or fibers C for example based on polyethylene terephthalate, is preferably less than 50% and even more preferably less than 30%.
  • the weight ratio of yarns or fibers B to yarns or fibers C for example based on polyethylene terephthalate, is preferably between 25/75 and 75/25.
  • all the son of the family of transverse yarns are yarns obtained by assembling a yarn A and a yarn B, or by intimate mixing of fibers A and fibers B.
  • all the son of the family of the lower son are son A.
  • the son of the family of upper son preferably covers at least 70% of the upper face of the surface.
  • Figure 1 shows schematically the structure of the fabric.
  • the fabric is subjected to the tests defined in EN 471 and EN 531.
  • the fabric complies with these standards, with classification A, B1, C1, E1 for EN 531.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Woven Fabrics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (10)

  1. Spinnstoff, der mindestens auf einer Seite eine hohe Sichtbarkeit aufweist, wobei die chromatischen Koordinaten und der Leuchtfaktor dieser Seite unter den folgenden auszuwählen sind:
    * die chromatischen Koordinaten innerhalb der durch folgende Koordinatenpaare (X; Y) definierten Ellipse: (0.610; 0.390), (0.544; 0.376), (0.579; 0.341), (0.655; 0.344), mit einem Leuchtfaktor β oberhalb 0.40
    * die chromatischen Koordinaten innerhalb der durch folgende Koordinatenpaare (X; Y) definierten Ellipse: (0.387; 0.610), (0.356; 0.494), (0.398; 0.452), (0.460; 0.540), mit einem Leuchtfaktor β oberhalb 0.76
    dadurch gekennzeichnet, daß er aus mindestens drei Arten Fäden oder Fasern besteht:
    * Faden oder Faser A: thermostabile Fäden oder Fasern
    * Faden oder Faser B: Erstickungsfäden oder -fasern, die ein Gas entwickeln, wenn sie einer Flamme ausgesetzt werden
    * Faden oder Faser C: Fäden oder Fasern mit optischen Eigenschaften, durch die ein ausschließlich aus diesen Fäden oder Fasern hergestelltes Gewebe eine der folgenden chromatischen Koordinaten und Leuchtfaktoren hat:
    - die chromatischen Koordinaten innerhalb der durch folgende Koordinatenpaare (X; Y) definierten Ellipse: (0.610; 0.390), (0.544; 0.376), (0.579; 0.341), (0.655; 0.344), mit einem Leuchtfaktor β oberhalb 0.40
    - die chromatischen Koordinaten innerhalb der durch folgende Koordinatenpaare (X; Y) definierten Ellipse: (0.387; 0.610), (0.356; 0.494), (0.398; 0.452), (0.460; 0.540), mit einem Leuchtfaktor β oberhalb 0.76.
  2. Spinnstoff nach Anspruch 1, dadurch gekennzeichnet, daß er durch Verweben von mindestens drei Familien von Fäden hergestellt wird
    * die Familie der oberen Fäden, die Kettfäden oder Schußfäden darstellen, welche auf der Seite des Spinnstoffes mit hoher Sichtbarkeit sichtbar sind,
    * die Familie der unteren Fäden, parallel zur Familie der oberen Fäden liegend, aber nicht auf der Seite des Spinnstoffes mit hoher Sichtbarkeit sichtbar,
    * die Familie der Querfäden, senkrecht zur Familie der unteren Fäden liegend und mindestens mit der Familie der unteren Fäden verwebt,
    - wenigstens eine der Familien entweder der unteren Fäden oder der Querfäden enthält Fäden oder Fasern B
    - sowohl die Familie der unteren Fäden als auch die Familie der Querfäden enthält Fäden oder Fasern A
    - die Familie der oberen Fäden enthält Fäden oder Fasern C und eventuell Fäden oder Fasern A oder B.
  3. Spinnstoff nach Anspruch 2, dadurch gekennzeichnet, daß er durch Weben mit doppeltem Kettfaden oder doppeltem Schußfaden hergestellt wird, wobei die Familie der oberen Fäden bei einem Artikel mit doppeltem Kettfaden einen oberen Kettfaden oder bei einem Artikel mit doppeltem Schußfaden einen oberen Schußfaden darstellt, während die Familie der unteren Fäden bei einem Artikel mit doppeltem Kettfaden einen unteren Kettfaden oder bei einem Artikel mit doppeltem Schußfaden einen unteren Schußfaden darstellt, und die Familie der Querfäden bei einem Artikel mit doppeltem Kettfaden den Schußfaden oder bei einem Artikel mit doppeltem Schußfaden den Kettfaden darstellt.
  4. Spinnstoff nach einem der Ansprüche 2 oder 3, dadurch gekennzeichnet, daß mindestens eine Familie entweder der unteren Fäden oder der Querfäden Fäden enthält, die aus den Fasern A und den Fasern B gesponnen sind.
  5. Spinnstoff nach einem der Ansprüche 2 bis 3, dadurch gekennzeichnet, daß die Familie der Querfäden aus Fäden besteht, die aus Fasern A und Fasern B in intimer Mischung gesponnen sind, und dadurch, daß die Familie der unteren Fäden aus Fäden besteht, die aus Fasern A, einzeln oder in Mischung mit anderen Fasern, gesponnen sind.
  6. Spinnstoff nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, daß die Fäden oder Fasern B auf Basis von Modacrylfasern oder voroxidiertem Polyacrylnitril sind.
  7. Spinnstoff nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, daß die Fäden oder Fasern A auf Basis eines der folgenden synthetischen Materialien sind: Polyamidimid, Polyparaphenylen-Terephthalamid, Polymetaphenylen-Isophthalamid, Polybenzimidazol, Polyparaphenylen-2,6-Benzobisoxazol.
  8. Spinnstoff nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, daß die Fäden oder Fasern C auf Basis von Polyethylen-Terephthalat sind, und dadurch, daß sie ein vor dem Spinnen zugefügtes Pigment enthalten, welches ihnen die gewünschte Farbe verleiht.
  9. Spinnstoff nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, daß die Fäden oder Fasern C mindestens 70 % der Seite mit hoher Sichtbarkeit bedecken.
  10. Spinnstoff nach einem der vorangegangenen Ansprüche, dadurch gekennzeichnet, daß die Fäden oder Fasern C weniger als 35 % des Gewichts des Spinnstoffes ausmachen.
EP01982566A 2000-11-03 2001-10-26 Textile flachengebilde mit hoher sichtbarkeit Expired - Lifetime EP1336001B1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0014124A FR2816176B1 (fr) 2000-11-03 2000-11-03 Surface textile de haute visibilite
FR0014124 2000-11-03
PCT/FR2001/003333 WO2002036870A1 (fr) 2000-11-03 2001-10-26 Surface textile de haute visibilite

Publications (2)

Publication Number Publication Date
EP1336001A1 EP1336001A1 (de) 2003-08-20
EP1336001B1 true EP1336001B1 (de) 2007-01-24

Family

ID=8856041

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01982566A Expired - Lifetime EP1336001B1 (de) 2000-11-03 2001-10-26 Textile flachengebilde mit hoher sichtbarkeit

Country Status (21)

Country Link
US (1) US7312166B2 (de)
EP (1) EP1336001B1 (de)
JP (1) JP3994054B2 (de)
KR (1) KR100563797B1 (de)
CN (1) CN1281801C (de)
AT (1) ATE352649T1 (de)
AU (2) AU2002214115B2 (de)
BR (1) BR0115391B1 (de)
CA (1) CA2427598A1 (de)
CZ (1) CZ300205B6 (de)
DE (1) DE60126315T2 (de)
DK (1) DK1336001T3 (de)
ES (1) ES2280409T3 (de)
FR (1) FR2816176B1 (de)
HU (1) HU227954B1 (de)
NO (1) NO20031947L (de)
NZ (1) NZ525663A (de)
PL (1) PL205696B1 (de)
PT (1) PT1336001E (de)
RU (1) RU2244770C1 (de)
WO (1) WO2002036870A1 (de)

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FR2826669B1 (fr) * 2001-06-28 2003-08-15 Kermel Fil composite
US20070094763A1 (en) * 2002-08-30 2007-05-03 Safety-Short Workwair Inc. Safety outerwear with fire resistant mesh
ITVI20030037A1 (it) * 2003-02-25 2004-08-26 Q2 Roma Srl Tessuto ad elevate proprieta' ignifughe.
FR2854547B1 (fr) * 2003-05-06 2005-08-05 Kermel Surface textile utilisable pour la realisation de vetements de protection, notamment pour sapeurs-pompiers et complexes multicouches comprenant cette surface
US7681417B2 (en) 2005-06-17 2010-03-23 Hayashi Yarn Twisting Co., Ltd. Heat-resistant fabric and garment and heat-resistant glove using the same
US20080003905A1 (en) * 2006-06-30 2008-01-03 Canbelin Industrial Co., Ltd. Mat
DE102007050175A1 (de) * 2007-10-19 2009-04-23 W. L. Gore & Associates Gmbh Materialstruktur mit flammfestem Material, insbesondere für Warnkleidung
US20090107575A1 (en) * 2007-10-29 2009-04-30 Yucheng Ma Mixed Fabric Woven by Untwisted Yarns and Twisted Yarns
GB201004692D0 (en) * 2010-03-19 2010-05-05 Toray Textiles Europ Ltd Fabric for personal protection garments
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DE102011102428A1 (de) 2011-05-24 2012-11-29 Glanzstoff Bohemia S.R.O. Lumineszierende cellulosische Regeneratfaser und Verfahren zu deren Herstellung
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JP6162447B2 (ja) * 2013-03-25 2017-07-12 ユニチカトレーディング株式会社 高視認性重ね織物
JP6173053B2 (ja) * 2013-06-07 2017-08-02 株式会社クラレ 高視認性を有する難燃布帛
JP6158602B2 (ja) * 2013-06-11 2017-07-05 帝人株式会社 伸縮性難燃布帛および繊維製品
FR3008434A1 (fr) 2013-07-11 2015-01-16 Europrotect France Sa Procede de coloration d'un support textile non feu en un coloris haute visibilite
US10451780B2 (en) 2013-12-12 2019-10-22 3M Innovative Properties Company Retroreflective article
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JP6468746B2 (ja) * 2014-07-24 2019-02-13 ユニチカトレーディング株式会社 高視認性織物
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EP3276059B1 (de) * 2015-03-24 2021-05-05 Toray Industries, Inc. Stoff und kleidungsstück
EP3310950B1 (de) * 2015-06-17 2019-01-09 Kucukcalik Tekstil Sanayi Ve Ticaret Anonim Sirketi Garn, gewebe und herstellungsverfahren davon für screening-anwendungen
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BR0115391A (pt) 2003-08-19
CZ300205B6 (cs) 2009-03-18
RU2244770C1 (ru) 2005-01-20
NO20031947D0 (no) 2003-04-29
DK1336001T3 (da) 2007-05-21
US20040035489A1 (en) 2004-02-26
FR2816176B1 (fr) 2002-12-20
AU1411502A (en) 2002-05-15
EP1336001A1 (de) 2003-08-20
KR20030063371A (ko) 2003-07-28
PL365580A1 (en) 2005-01-10
CA2427598A1 (fr) 2002-05-10
HU227954B1 (hu) 2012-07-30
FR2816176A1 (fr) 2002-05-10
DE60126315D1 (de) 2007-03-15
PL205696B1 (pl) 2010-05-31
AU2002214115B2 (en) 2005-01-06
CZ20031200A3 (cs) 2003-09-17
DE60126315T2 (de) 2007-11-15
KR100563797B1 (ko) 2006-03-28
JP2004513252A (ja) 2004-04-30
CN1281801C (zh) 2006-10-25
CN1478159A (zh) 2004-02-25
BR0115391B1 (pt) 2009-12-01
US7312166B2 (en) 2007-12-25
ATE352649T1 (de) 2007-02-15
RU2003116242A (ru) 2005-01-10
HUP0400838A2 (en) 2008-02-28
ES2280409T3 (es) 2007-09-16
NO20031947L (no) 2003-06-19
WO2002036870A1 (fr) 2002-05-10
NZ525663A (en) 2004-06-25
JP3994054B2 (ja) 2007-10-17
PT1336001E (pt) 2007-05-31

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