WO2019245083A1 - Composition for skin care enhancement and cosmetics containing same - Google Patents
Composition for skin care enhancement and cosmetics containing same Download PDFInfo
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- WO2019245083A1 WO2019245083A1 PCT/KR2018/006985 KR2018006985W WO2019245083A1 WO 2019245083 A1 WO2019245083 A1 WO 2019245083A1 KR 2018006985 W KR2018006985 W KR 2018006985W WO 2019245083 A1 WO2019245083 A1 WO 2019245083A1
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- Prior art keywords
- collagen
- composition
- film
- alginate
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Definitions
- the present invention relates to a composition for enhancing skin care and a cosmetic containing the same, and more particularly, to a composition for enhancing skin care containing collagen and alginate and a cosmetic prepared in the form of a film.
- the biggest enemy of the skin is the high temperature, high humidity and ultraviolet.
- the protection of the skin itself is weakened. This causes a lot of skin secretions such as sweat and sebum in the skin. Excessive sweating and sebum secretion widen the pores and reduce the elasticity of the skin. Skin irritation caused by UV light causes blemishes, blemishes, and freckles due to skin pigmentation, and accelerates aging of the skin. Therefore, proper skin care is required for this.
- skin care that satisfies the absorption and hydration of skin secretions is required. Therefore, it is absorbent as a material to be applied to the skin, which can absorb and remove skin secretions, and it is effective to use a pack that can supply moisture to the skin due to its high moisture content.
- the connective tissue of the dermis which is closely related to skin aging, is mainly composed of collagen and elastin, and collagen is the main protein of connective tissue, which accounts for 70-80% of the dry weight of dermis, which gives elasticity and strength to the skin. It also plays a big role in maintaining moisturizing.
- the collagen decreases in function and content due to photoaging and natural aging, the skin is adversely affected, including wrinkle formation, skin roughness, elasticity reduction, and drying.
- collagen is a kind of fibrous protein, which is the main component of connective tissue that forms the skeleton such as muscle, skin, cartilage, cornea, and bone of the human body.
- hydroxyproline, glycine, and serine which are amino acids, Affects moisturizing;
- cosmetic compositions used to enhance skin beauty have been developed using a natural vegetable or animal ingredients, but in the case of natural cosmetics in order to prevent the deterioration of natural ingredients, such as encapsulation or antiseptic treatment There was a burden to go through.
- French Patent Publication No. 2001-0007671 discloses a cosmetic for skin comprising a reinforcing member and a composition comprising a hydrophilic gelling system comprising at least one gellan gum and at least one other hydrocolloid, Other hydrocolloids include at least one hydrocolloid selected from cellulose and its derivatives; Seaweed extract; Seed extract; Plant exudate; Microbial emissions; Fruit extracts; Gelling agents of animal origin; Amphiphilic polymers; Water-soluble synthetic gelling polymers; A patch for skin comprising a terephthalic acid / isophthalic acid / sodium isophthalic acid sulfonate / glycol copolymer and silicone derivative is proposed.
- Korean Patent Registration No. 10-1803451 relates to a method for manufacturing a hydrogel mask pack, characterized in that the hydrogel is formed to have a rigid and stable film thickness of 0.1 mm to 5 mm even when manufactured at room temperature without a heating process.
- the crosslinked polymer is a three-dimensional hydrogel mask pack by a non-heat treatment method comprising a composition comprising a water-soluble collagen crosspolymer, algin, carob bean gum, potassium alginate, chitosan and hydroxyethyl cellulose It is proposed with respect to the technology for manufacturing.
- Korean Patent Registration No. 10-0853301 is a hydrogel composition configured to contain a natural polymer material, 0.5 to 10% by weight based on the total weight of the composition, functional cosmetic ingredients 6 to impart skin cosmetic function 40% by weight, preservative 0.001 to 0.3% by weight and the balance water, wherein the natural polymer material is a two-component mixture of Iota Carrageenan and Locust Bean Gum (LBG) or the two components Kappa Carrageenan, Gelatin, Agar, Alginate, Chitosan, Chitosan Derivatives, Starch, Pullulan, Galactomannan, Glucomannan, Guar gum ), Pluronic, Algin, Gellanum, Xanthan gum, and Pectin, one or two or more substances selected from the group consisting of It proposes a hydrogel composition of the features.
- LBG Locust Bean Gum
- Patent Document 1 French Patent Publication No. 2001-0007671
- Patent Document 2 Korean Patent Registration No. 10-1803451
- Patent Document 3 Korean Patent Registration No. 10-0853301
- the present invention is to compose a composition of a new composition different from the prior art, and when using it as a cosmetic, it is possible to use cosmetics for a long time stably and conveniently even without using a preservative Shall be.
- an object of the present invention is to provide a new concept for improving skin care composition that can be prepared and used as a cosmetic without preservatives.
- Another object of the present invention is to provide a composition for skin promotion wherein water is removed, including collagen and alginate.
- Another object of the present invention is to provide a collagen dry body such as a collagen film for cosmetics prepared using collagen and alginate.
- Another object of the present invention is to provide a film-type cosmetics containing collagen and alginate and substantially free of moisture can be used for a long time.
- the present invention provides a composition for enhancing skin care containing collagen and alginate and water is removed.
- the present invention provides a collagen dry body comprising a collagen and alginate, and made of a composition for promoting skin care, from which moisture is removed.
- the present invention provides a film-like cosmetics made of a composition for enhancing skin care containing collagen and alginate and water is removed.
- the present invention provides a method for producing a film cosmetics by mixing collagen and alginate, and drying them to produce a film or sheet form.
- composition for enhancing skin care according to the present invention has the following effects.
- the skin rejection reaction is low, but exhibits improved physical properties than the existing collagen powder, and thus can be used for manufacturing various and excellent cosmetics.
- collagen and alginate are mixed to form a composition, and when dried and manufactured in cosmetics, etc., it does not contain moisture, and thus long-term distribution is possible even without adding a preservative.
- the cosmetics produced using the composition for promoting skin care of the present invention is composed of a film of a physical property of the specific surface area of collagen, which is insoluble in water, when it is prepared in a dried film form, so that water is easily added to water. Melted and can be used easily in the same form as general cosmetics.
- the film-type cosmetics using the composition for enhancing skin care of the present invention is easily dissolved by water, and when applied to the skin, the skin penetration is excellent and the absorption is fast, and the effect of using cosmetics is remarkably improved.
- the present invention is easy to carry and store when using as a dry film-type cosmetics using the composition for improving skin care, and can easily be used as a disposable cosmetics by simply dissolving water if necessary to meet the needs of various consumers It can be used as a new concept cosmetic.
- the film cosmetics of the present invention can be manufactured in addition to collagen and alginate in addition to the cosmetic active ingredients, additives, etc. can be produced as a general cosmetic or functional cosmetics having a specific effect, it can be produced into a variety of cosmetic products .
- a thin film of a collagen film is formed when applied to the skin it can be produced as an anti-aging cosmetics to prevent the loss of moisture of the skin to prevent wrinkles and prevent aging.
- composition for enhancing skin care according to the present invention contains a large amount of collagen and is composed of a porous film by drying, when applied to the skin in a dissolved state using water, the skin absorption is very good, which is very excellent for skin moisturizing and skin improvement. It is effective.
- collagen when used in combination with other cosmetically active ingredients, it helps to easily absorb the skin of the cosmetically active ingredient, thereby improving the skin absorption effect.
- 1 is a photograph of the actual product of the collagen film prepared using the composition for enhancing skin care according to the present invention.
- the film type generally means a thin material, and includes all of various shapes having a thin shape such as a film, a sheet, and a matrix.
- the present invention relates to a composition for enhancing skin care, which is essentially a collagen.
- the present invention consists of a composition in which collagen essentially constitutes a basic ingredient but contains alginate in collagen.
- composition for enhancing skin care of the present invention is a composition which is substantially free of moisture as it has been removed therefrom. It may therefore consist of a composition in a dried state.
- the moisture content of the composition for promoting skin care from which moisture is removed is within 15% by weight, more preferably 5-12% by weight.
- compositions of the present invention are preferably water removed, and have different properties from existing hydrogel compositions or gelled compositions.
- natural collagen may be preferably used.
- the collagen and alginate preferably contains 30 to 120 parts by weight of alginate based on 100 parts by weight of collagen.
- the alginate is contained in an amount of 50-90 parts by weight, most preferably 55-80 parts by weight, based on 100 parts by weight of collagen.
- composition of the present invention can be used as a composition for promoting skin care when mixed with a liquid solubilizer such as water as such. Therefore, the preferred composition of the present invention does not additionally contain a component or water-insoluble component which continuously impart moldability.
- the composition of the present invention may further contain a cosmetic active ingredient and a conventional cosmetic additive without including a component imparting moldability, a water-insoluble component.
- the composition for enhancing skin care according to the present invention is intended to be usefully used for producing a cosmetic material or a film-type cosmetics through film drying. Furthermore, the present invention is characterized in that it is made of a structure that is easily dissolved in water when used as a film cosmetic. Therefore, in order to satisfy the conditions of such a film-type cosmetics, it is preferable that the composition is easily dissolved in water.
- the alginate when used in excess of collagen in the composition of the present invention, when the film is manufactured using the composition for promoting skin care, the dried film is easily broken, and thus the commercial property is significantly lowered.
- the alginate if used in a small amount, the specific surface area of the film-like material after drying is significantly small, so that even if water is used, it is not easily dissolved in water, and thus may be inconvenient to use when used as a material such as cosmetics.
- the alginate when used in excess of the collagen, it may be a serious problem that cannot be effectively utilized in film-type cosmetics, etc., so it is preferable to use a smaller amount than the collagen.
- the present invention comprises a collagen film made of a composition for promoting skin care as described above, such collagen film is made of a dry state of the composition.
- the collagen film using the composition of the present invention when the collagen film using the composition of the present invention is dissolved in water and applied to the skin, a thin film of the collagen is formed, thereby preventing the loss of moisture of the skin, thereby making it an anti-aging cosmetic for preventing wrinkles and aging.
- composition for promoting skin care in addition to the composition for promoting skin care, it may provide a cosmetic film containing a cosmetic active ingredient in a dried state.
- composition of the present invention can be prepared as a general cosmetic or a variety of functional cosmetics having a particular effect.
- film-type cosmetics contain a large amount of collagen and apply to the skin in a dissolved state using water, so the skin absorption is very good, so it is very good for moisturizing and improving the skin, and it helps to absorb the skin easily by other cosmetic active ingredients. The effect is further improved.
- the film-type material containing collagen from which moisture is removed by drying since the film-type material containing collagen from which moisture is removed by drying, the specific surface area of collagen may be greatly increased. It has a formed structure.
- the porosity may be made of a structure having a 10-80%, more preferably 20-50%.
- the film-like structure having such voids is to provide a surprising effect that the collagen is easily dissolved when water is added to the film-like material to facilitate the use.
- the other collagen dry matter of the present invention may also have the same porosity as that of the film.
- natural collagen such as animal collagen derived from terrestrial animals or fish or vegetable collagen such as green tea collagen may be used, and specifically, for example, Any one or more natural collagen selected from donpicollagen, uppicollagen, green tea collagen, young collagen and apicollagen may be used.
- salts of monovalent cations and salts of divalent cations may be used as the alginate used in the composition for promoting skin care.
- salts of monovalent cations such as alginate
- salts of divalent cations such as calcium alginate, iron alginate, zinc alginate and copper alginate
- sodium alginate can be used.
- the composition for enhancing skin care can be prepared with various types of collagen desiccant, and can be prepared with a dry body such as spherical, pellet, sheet, matrix, film, most preferably collagen film or film It can be produced as a cosmetic type.
- the present invention is to prepare a skin care composition for removing moisture by a method such as lyophilization, etc., in order to remove moisture, in particular, in the form of collagen film, which is easy to use as a cosmetic among various forms It can be prepared in the collagen dry body of.
- the film-like cosmetics may be prepared through a process comprising the steps of preparing a mixture by mixing collagen and alginate in purified water and putting the mixture into a mold.
- the mold used herein may be a mold of a film or other similar form or a desired cosmetic form for deformation.
- Such film cosmetics may consist essentially of collagen film.
- Such collagen film may not include other cosmetic ingredients or may additionally include cosmetic ingredients.
- the mixture containing the collagen and alginate may additionally contain a cosmetic active ingredient and additives.
- the cosmetic active ingredient may be one or more natural extracts or natural fermentation products, such as vegetable or animal, and as an additive, conventional emulsifiers, surfactants, fragrances, etc. commonly used in cosmetic compositions One or more may be used.
- the resulting foam is mixed with each other, such as collagen and alginate or other additional ingredients, and the mixture is completely dissolved and dispersed at about 40-80 ° C, more preferably 50-70 ° C.
- the mixture is completely dissolved and dispersed at about 40-80 ° C, more preferably 50-70 ° C.
- the method of drying the composition is preferably carried out by a lyophilization method, such lyophilization, for example, to cool the composition and the cooled composition solution -30 ⁇ 20 °C It can be carried out for about 12 to 24 hours in the temperature range of.
- a lyophilization method such as lyophilization, for example, to cool the composition and the cooled composition solution -30 ⁇ 20 °C It can be carried out for about 12 to 24 hours in the temperature range of.
- lyophilization is also possible using commercially available freeze dryers.
- it is lyophilized it is possible to remove the moisture inside the composition for enhancing skin care to produce a collagen film or film-like cosmetics in the form of a porous membrane.
- the cooling method may be important when the lyophilization method is used to dry the composition for promoting skin care as described above to maintain the film form.
- cooling can be divided into a stepwise cooling method and a continuous cooling method.
- Stepwise cooling means a method of rapidly lowering the temperature after lowering the temperature to a constant level irrespective of the composition solution.
- Continuous cooling means a method of lowering the cooling temperature little by little depending on the temperature of the composition-solution. If the temperature of the composition solution is rapidly lowered during cooling, the appearance of the film may be cracked or the shape of the dried body may not be constant due to thermal shock.
- the cooling of the mixture solution in which each component is mixed, so as to close to the so-called equilibrium state can minimize the thermal shock to ensure a stable formulation.
- the cooler in the case of rapid cooling, the cooler is directly cooled in a state where the target temperature is set to a target temperature.
- continuous cooling in the present invention is set equal to the temperature of the cooler specimen and lowers the temperature while lowering the temperature of the cooler. will be.
- the opposite concept of rapid cooling can be expressed as slow cooling.
- Slow cooling in the present invention means such a continuous cooling method.
- the freeze-dried dried product has an advantage that it can be easily dissolved even in a small amount of water due to its wider surface area.
- the solubility of the collagen in water can be improved to improve the skin penetration effect of collagen.
- the dried film-type cosmetics may be processed in various forms to broaden the specific surface area for the purpose of improving moisture absorption.
- a collagen film or a film cosmetic it is preferably a circular shape having a diameter of about 20-50 mm, and can be processed into a film shape having a thickness of about 0.5-3 mm.
- water may be added or mixed with cosmetics containing moisture to apply the skin more effectively.
- the collagen and alginate mixture is well soluble in water.
- the alginate used in combination with the collagen in the present invention when dried in the mixed state with the collagen is separated from the moisture contained in the network-shaped pore structure formed by the molecular chain of the alginate to form the overall composition as a dried solid
- a collagen film having a film-like structure is formed.
- Such collagen film may be used as a film cosmetic as it is.
- the cosmetic active ingredient is mixed with the composition for promoting skin care before drying, it may be prepared as a film-type cosmetics dried by the same mechanism as described above.
- the dried product prepared after drying as described above for example, a collagen film or a film cosmetic product is formed in a thin film form, and voids are formed in the film by drying, so that when water is added, it is easily dissolved by water and is commonly used. It can be used in a manner that is easily applied to the skin, such as cosmetics.
- the composition for enhancing skin care can be prepared, for example, in a film-type cosmetics by a lyophilization method, and when water is added thereto, is easily dissolved and in a liquid or cream form as in a conventional cosmetic form. It may be changed to be applied to the skin.
- the composition of the present invention configured as described above or the collagen film or film cosmetics prepared by drying the same, ingesting or reducing the amount of collagen to improve skin beauty, such as preventing skin aging
- collagen cosmetics it is produced in the form of a film and dissolved in separate water and applied to the skin, so that collagen can be directly added to the damaged part of the dermis to replenish moisture and collagen.
- Other dry forms may be used similarly to films.
- hydrogel mask packs containing collagen have been known, but such mask packs are oxidized when stored for a long time and are difficult to distribute for a long time due to the disadvantages of color deterioration and deterioration of physical properties.
- preservatives such as methyl paraben, propylene paraben, phenoxy ethanol and hexanediol and metal salts such as calcium salt, magnesium salt, barium salt and aluminum salt may cause skin irritation.
- the film-type cosmetics using the composition according to the present invention is excellent in storage properties without adding a preservative by removing moisture through drying as described above is possible long-term distribution.
- a modified alcohol-based or benzoic acid-based preservative should be added.
- the modified alcohol-based is substantially reduced due to a very low moisture content.
- the weight can be reduced, thereby reducing the logistics cost.
- the composition for skin promotion using natural collagen and alginate can be produced in a film form using, for example, a freeze-drying method, and the natural collagen is applied to the skin It can be added directly to the dermis or damaged parts of the dermis to replenish the skin with moisture and collagen.
- the film in the form of a film it is preferable to prepare and apply the film in the form of a film to supplement collagen as described above. Since the collagen powder is not easily dissolved like the collagen film, the surface area in contact with water as the collagen film is maximized to maximize the water, skin, essence, etc. It is desirable to manufacture in the form of a film so that the consumer can be used in conjunction with the cosmetic of the desired form.
- the collagen content is contained in 0.5 ⁇ 10% by weight in the composition for enhancing skin care before drying to prepare a film-type cosmetics in consideration of the composition of the film-like cosmetics and the effects of penetration of the skin It is desirable to. If the collagen is more than 10% by weight, the formulation may be in a high density state and not easily dissolved in water. If the content is less than 0.5% by weight, the skin penetration effect due to collagen may be insignificant.
- alginates used with collagen are included as gelling agents.
- Such alginates are linear polymers in which ⁇ -D-mannuric acid is a linear polymer connected by ⁇ -1,4 bond and aL-guluronic acid is linearly connected by a-1,4 bond.
- These are complex polysaccharides having a molecular weight of about 220,000 that form their structural units.
- Alginate is viscous when dissolved in water and has excellent effects as a stabilizer and a thickener.
- the alginate aqueous solution used in the present invention is dried to remove moisture, the result is a sponge-like form, and since its form is very stable, when 0.2 to 6% by weight of alginate is used with respect to the total composition before drying when producing a film form, As an excellent role.
- the preferred collagen and alginate are contained in 1-12% by weight, more preferably 5-8% by weight in the total composition before drying.
- propylene glycol alginate which can be added additionally can be used as an emulsifier.
- This increases the adhesion and viscosity and enhances the emulsion stability.
- the content of the propylene glycol alginate is preferably 0.01 to 1% by weight before drying. If it is less than 0.01% by weight, it is difficult to expect the effect of improving the emulsification performance, and if it is more than 1% by weight, there is a problem that the viscosity rises more than necessary.
- niacinamide which may be additionally added in the present invention, may be added as a whitening ingredient. It is a vitamin B complex that corresponds to heat and light stable ingredients. Niacinamide acts into the skin, helping to soften or inhibit melanin pigmentation and to even out skin tone. In addition, as well as the whitening effect to increase the moisture retention capacity to soften the skin and create a sense of volume on the skin.
- the content before drying of the niacinamide is preferably 2 to 5% by weight. If less than 2% by weight it is difficult to expect the whitening effect, if more than 5% by weight may cause excessive irritation to the skin.
- colostrum or colostrum fermentation product may be added.
- colostrum or colostrum fermentation product may be added to improve the moisturizing power.
- Colostrum is the milk that the mother cow produces for three days after the calf is born. Colostrum will contain more than 82 natural bioactive ingredients. Examples include hyaluronic acid, immunoglobulins, TFG-BETA, lactoferrin, IGF, EGF, FGF, alpha hydroxy acids, vitamin B, and the like.
- hyaluronic acid is present in a large amount in colostrum to prevent the loss of moisture in the dermal layer of the skin shows an excellent moisturizing effect.
- Immunoglobulins protect the skin by killing or inhibiting the growth of microorganisms. Vitamin B can help calm irritated skin.
- the content of the cosmetically active ingredient is preferably contained in an amount of 1 to 10% by weight based on the total composition before drying. If the content is less than 1% by weight, the effect of the addition of a cosmetic active ingredient is insignificant, and if the content is more than 10% by weight, the viscosity of the liquid is very high during the manufacturing process, which makes it difficult to produce a thin sheet form. Can be.
- a surfactant may also be added together, which is used to dissolve substances that are not easily dissolved in water, for example, contained in the cosmetic active ingredient. Additional ingredients such as the solids to be added and the fragrances which may be further contained are added to dissolve the purified water.
- the surfactant dioctyl sodium sulfosuccinate, polyglyceryl-10 laurate and the like can be used.
- the content before drying is preferably 0.01 to 0.1% by weight. If less than 0.01% by weight, solubilization of additional ingredients, including fragrance, may not be made sufficiently. If it exceeds 0.1% by weight, a large amount of bubbles may be generated and produced in a film cosmetic product. It may adversely affect.
- an additional agent may be added.
- the fragrance is preferably added in an amount of 0.1 to 1% by weight before drying.
- composition for enhancing skin care according to the present invention may include a cosmetic active ingredient, and may further include a functional additive capable of supplying nutrients necessary for skin.
- the functional additive may include a variety of ingredients that can supply the nutrients necessary for the skin when used as a mask pack.
- the functional additive may be horse oil or snail mucus.
- composition for enhancing skin care according to the present invention may further include a moisturizer to further improve the moisturizing effect on the skin.
- the moisturizing agent may include various ingredients for moisturizing and moisturizing the skin at a constant level.
- the moisturizing agent may include hyaluronic acid or glycerin.
- An example of a preferred configuration according to the present invention for example, 0.5 to 10% by weight of collagen, 0.2 to 6% by weight of alginate, 0.01 to 1% by weight of propylene glycol alginate, 2 to 5% by weight of niacinamide, makeup It can be composed of 1.0 to 10% by weight of active ingredient, 0.01 to 0.1% by weight of surfactant, and the remaining amount of purified water. If the fragrance is added to it, it may be added in an amount of 0.1 to 1% by weight based on the composition before drying.
- the present invention can be used as a composition for promoting skin care consisting of only collagen and alginate, but an effective cosmetic ingredient may be mixed therein, but in the present invention, the amount of such cosmetic ingredient need not be limited. none. However, in order to be used as a preferred cosmetic, it is preferable to use it in a certain content range.
- the total amount added to the additives is 150 parts by weight based on 100 parts by weight of the collagen and alginate mixture It is preferred to mix at -300 parts by weight, more preferably 180-250 parts by weight.
- collagen and alginate when collagen and alginate are mixed to form a composition and dried to produce cosmetics, it does not contain water, and thus long-term distribution is possible even without adding a preservative.
- dried film form of the physical properties of the collagen's specific surface area is expanded, so that it is easily dissolved in water when water is added and can be used easily in the same form as general cosmetics, disposable in consideration of convenience It can be used as a new concept cosmetic that can be conveniently used as a cosmetic.
- the film-type cosmetics of the present invention is easily dissolved by water, when applied to the skin is excellent skin penetration and quick absorption so that the effect of using the cosmetics is remarkably improved, and further comprising a functional cosmetic containing a cosmetic active ingredient
- the thin film collagen film is formed when applied to the skin is useful as an anti-aging cosmetics to prevent the loss of moisture of the skin to prevent wrinkles and prevent aging.
- the collagen used in the present invention is dissolved and used in a dry state in a dispersed state, for example, in the form of a film, the skin absorption ability is very good, and thus the skin moisturizing and skin improvement are very excellent.
- the collagen dry or film cosmetics as described above may be commercialized by packaging the dry or film cosmetics and water in a separate state in one wrapping paper. Therefore, the moisture is removed from the dried or film cosmetics, there is no need to use a separate preservative.
- the collagen film which is the film-like material, may be manufactured as an external medicine, a detergent, a soap, a shampoo, etc., when the external medicine, a cleaning component, etc. are added to the composition before drying.
- Collagen and alginate were mixed in the composition shown in Table 1 below to prepare a composition for promoting skin care, but lyophilized to prepare a film-like cosmetic form.
- the collagen used used natural collagen derived from fish (kinetic) shell, and sodium alginate as alginate.
- a functional cosmetic ingredient to be used additionally a mixed component of colostrum, dioctyl sodium sulfosuccinate, and propylene glycol alginate was used.
- each component was mixed, completely dissolved and dispersed at about 60 ° C., and then cooled at room temperature until the resulting foam was completely removed, thereby preparing a composition solution.
- Each prepared solution of the composition is frozen in a continuous cooling method from room temperature to about -30 °C for about 4 hours, and dried by heating up from about -30 °C to room temperature for about 15 hours in the form of a film of 25mm diameter ⁇ 1mm thickness Cosmetic samples were prepared.
- the prepared sample was prepared in the form shown in the photograph in FIG. Figure 1 is a photograph of the actual product exemplified to show the form of the film-type cosmetics prepared by lyophilizing the composition for enhancing skin care prepared in the embodiment.
- Example 5 For the film-type cosmetics prepared in Example 5 was carried out a microorganism identification test for confirming long-term distribution effects such as deterioration or contamination during long-term distribution.
- Example 5 For five samples according to Example 5, the presence of bacteria after 2 months, 4 months, 6 months, and 8 months after preparation was confirmed. Table 2 below shows the microbial identification test results. The test method is notified by the Korea Food and Drug Administration. Dry film method was used according to the general test method, 8. Microbial test method.
- Microorganism types Psalm 1 Psalm 2 Psalm 3 Psalm 4 Psalm 5 Hours in months 0 2 4 6 8 General bacteria Not detected Not detected Not detected Not detected Not detected Not detected Not detected Fungus / fungus Not detected Not detected Not detected Not detected Not detected Not detected Staphylococcus aureus Not detected Not detected Not detected Not detected Not detected Not detected Escherichia coli / Coliform group Not detected Not detected Not detected Not detected Not detected Not detected Not detected Not detected
- the colostrum collagen composite composition film according to the present invention does not propagate microorganisms even after a long period of time even without the addition of cosmetic preservatives, there was no change when using the formulation.
- the moisture content ratio of the film cosmetic according to the storage organ was measured.
- the same specimen as in Example 5 was used, and the moisture content ratio did not decrease even after the storage period.
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Abstract
Description
본 발명은 피부미용 증진용 조성물과 이를 함유하는 화장료에 관한 것으로서, 보다 상세하게는 콜라겐과 알지네이트를 함유하는 피부미용 증진용 조성물과 이를 이용하여 필름형으로 제조한 화장품에 관한 것이다.The present invention relates to a composition for enhancing skin care and a cosmetic containing the same, and more particularly, to a composition for enhancing skin care containing collagen and alginate and a cosmetic prepared in the form of a film.
피부의 최대의 적은 높은 기온과 높은 습도, 그리고 자외선이라고 할 수 있다. 피부가 고온 다습한 날씨에 노출되면 피부 자체의 보호력이 약해진다. 이로 인해 피부에서 땀과 피지 등의 피부 분비물이 많아진다. 과도한 땀과 피지의 분비는 모공을 넓히고 피부의 탄력을 감소시킨다. 자외선에 의한 피부 자극은 피부 색소 침착에 의해 기미, 잡티, 주근깨 등이 생기게 하며, 피부의 노화를 가속화시킨다. 따라서 이에 대한 적절한 피부 관리가 필요하다.The biggest enemy of the skin is the high temperature, high humidity and ultraviolet. When the skin is exposed to hot and humid weather, the protection of the skin itself is weakened. This causes a lot of skin secretions such as sweat and sebum in the skin. Excessive sweating and sebum secretion widen the pores and reduce the elasticity of the skin. Skin irritation caused by UV light causes blemishes, blemishes, and freckles due to skin pigmentation, and accelerates aging of the skin. Therefore, proper skin care is required for this.
이러한 피부 관리와 관련하여, 우선 땀과 피지 등의 피부 분비물이 생기면, 즉시 닦아주고 가능한 한 자주 씻어서 청결감과 청량감을 유지해야 한다. 그러나 이 때 세안을 자주 하게 되면 피부의 수분 손실로 피부는 건조하고 거칠어지기 쉬우므로 수분 공급이 필요하다. Regarding this skin care, if you have any skin secretions such as sweat and sebum, you should wipe it off immediately and wash it as often as possible to keep it clean and refreshed. However, if you wash your face frequently, the skin is dry and rough due to the loss of moisture.
그러므로 피부 분비물의 흡수와 수분 공급을 동시에 만족시키는 피부 관리가 요구된다. 따라서 피부에 적용하는 재료로서 흡수성이 있어 피부 분비물을 흡수, 제거할 수 있고, 수분 함량이 많아 피부에 수분 공급을 할 수 있는 팩의 사용이 효과적이다.Therefore, skin care that satisfies the absorption and hydration of skin secretions is required. Therefore, it is absorbent as a material to be applied to the skin, which can absorb and remove skin secretions, and it is effective to use a pack that can supply moisture to the skin due to its high moisture content.
일반적으로, 피부노화와 밀접하게 관련이 있는 진피의 결합조직은 주로 콜라겐과 엘라스틴 등으로 이루어지며, 콜라겐은 결합 조직의 주된 단백질로 진피 건조 중량의 70-80%를 차지하여 피부에 탄성과 힘을 주며 보습 유지에 큰 역할을 한다. In general, the connective tissue of the dermis, which is closely related to skin aging, is mainly composed of collagen and elastin, and collagen is the main protein of connective tissue, which accounts for 70-80% of the dry weight of dermis, which gives elasticity and strength to the skin. It also plays a big role in maintaining moisturizing.
따라서 광노화 및 자연 노화에 의해 콜라겐의 기능 저하 및 함유량이 낮아지면 주름 생성, 피부 거칠기, 탄력 저하, 건조 등 피부에 악영향을 미친다.Therefore, if the collagen decreases in function and content due to photoaging and natural aging, the skin is adversely affected, including wrinkle formation, skin roughness, elasticity reduction, and drying.
이와 같이, 콜라겐은 섬유성 단백질의 일종으로 인체의 근육, 피부, 연골, 각막, 뼈 등 골격을 형성하는 결합조직의 주요성분이며 단백질의 일종으로 아미노산 성분인 hydroxyproline, glycine, serine은 피부의 탄력과 보습에 영향을 미친다.Like this, collagen is a kind of fibrous protein, which is the main component of connective tissue that forms the skeleton such as muscle, skin, cartilage, cornea, and bone of the human body. As a kind of protein, hydroxyproline, glycine, and serine, which are amino acids, Affects moisturizing;
이러한 이유로 피부노화를 막기 위해 기존에는 콜라겐을 식용으로 섭취하거나 미량의 콜라겐이 첨가된 화장품을 이용하는 추세였다. 그러나 식용 콜라겐은 효능의 객관적 검증이 미흡하며, 콜라겐을 식용으로 사용하여 인체의 콜라겐 함량을 높일 수 있는 지에 대하여 연구가 부족한 실정이다.For this reason, in order to prevent skin aging, conventionally, it was a trend to use cosmetics ingested with collagen or a small amount of collagen added. However, edible collagen has insufficient objective verification of efficacy, and there is a lack of research on whether collagen content can be used to increase the human collagen content.
한편, 기존에 피부미용을 증진시키기 위해 사용되는 화장료 조성물은 식물성 또는 동물성 천연 성분을 사용하는 경우가 많이 개발되고 있으나, 천연 화장품의 경우 천연 성분의 변질을 방지하기 위하여 캡슐화나 방부처리 등의 과정을 거쳐야 하는 부담이 있었다.On the other hand, cosmetic compositions used to enhance skin beauty have been developed using a natural vegetable or animal ingredients, but in the case of natural cosmetics in order to prevent the deterioration of natural ingredients, such as encapsulation or antiseptic treatment There was a burden to go through.
이를 극복하기 위하여, 일부에서는 방부효과가 있는 천연 성분을 배합하여 실질적으로 화학성분이나 방부제가 함유되지 않은 천연 화장품의 제조를 시도하고 있지만 기술적으로 이를 만족시키기 어려운 문제가 있다.In order to overcome this problem, some attempts to prepare natural cosmetics that are substantially free of chemical ingredients or preservatives by combining natural ingredients with antiseptic effect, but there is a technical problem that is difficult to satisfy.
종래 화장품의 예로서 프랑스특허공개 제2001-0007671호에서는 하나 이상의 젤란검 및 하나 이상의 다른 하이드로 콜로이드를 포함하는, 친수성 겔화 시스템을 포함하는 보강 부재 및 조성물을 포함하는 피부용 화장품에 관하여 개시하면서, 적어도 하나의 다른 하이드로 콜로이드는 셀룰로오스 및 그 유도체로부터 선택되는 적어도 하나의 하이드로 콜로이드를 포함하고; 해초 추출물; 종자 추출물; 식물 삼출물; 미생물 배출물; 과일 추출물; 동물 기원의 겔화제; 양친매성 고분자; 수용성 합성 겔화 고분자; 테레프탈산 / 이소프탈산 / 나트륨 이소프탈산 술포네이트 / 글리콜 공중합체 및 실리콘 유도체를 포함하는 피부용 패치에 대하여 제안하고 있다.As an example of a conventional cosmetic, French Patent Publication No. 2001-0007671 discloses a cosmetic for skin comprising a reinforcing member and a composition comprising a hydrophilic gelling system comprising at least one gellan gum and at least one other hydrocolloid, Other hydrocolloids include at least one hydrocolloid selected from cellulose and its derivatives; Seaweed extract; Seed extract; Plant exudate; Microbial emissions; Fruit extracts; Gelling agents of animal origin; Amphiphilic polymers; Water-soluble synthetic gelling polymers; A patch for skin comprising a terephthalic acid / isophthalic acid / sodium isophthalic acid sulfonate / glycol copolymer and silicone derivative is proposed.
또한, 한국특허등록 제10-1803451호에서는 하이드로겔 마스크팩을 제조하는 방법에 관한 것으로, 가온 공정이 없이 실온에서 제조하여도 단단하고 안정한 막의 두께가 0.1mm~5mm로 하이드로겔을 형성하는 것을 특징으로 하며, 1) 가교결합 폴리머를 수용성 겔화 하는 단계; 2) 경화속도 안정화제를 가교결합 폴리머 속에 분산하는 단계; 3) 효능성분 및 첨가제를 투입하는 단계; 4) 경화제를 혼합하는 단계; 5) 주형 틀에 부어 경화시키는 단계; 6) 잔여부 절단 단계;를 포함하고, 상기 가교결합 폴리머는 수용성 콜라겐 크로스폴리머, 알진, 캐럽콩검, 포타슘알지네이트, 키토산 및 하이드록시에틸셀룰로오스를 포함하는 조성물을 비열처리 공법에 의하여 입체형 하이드로 겔 마스크팩을 제조하는 기술에 관하여 제안하고 있다.In addition, Korean Patent Registration No. 10-1803451 relates to a method for manufacturing a hydrogel mask pack, characterized in that the hydrogel is formed to have a rigid and stable film thickness of 0.1 mm to 5 mm even when manufactured at room temperature without a heating process. 1) water-soluble gelling the crosslinked polymer; 2) dispersing the cure rate stabilizer in the crosslinked polymer; 3) adding an active ingredient and an additive; 4) mixing the curing agent; 5) pouring into a mold mold to cure; 6) residue cutting step; wherein the crosslinked polymer is a three-dimensional hydrogel mask pack by a non-heat treatment method comprising a composition comprising a water-soluble collagen crosspolymer, algin, carob bean gum, potassium alginate, chitosan and hydroxyethyl cellulose It is proposed with respect to the technology for manufacturing.
또한, 한국특허등록 제10-0853301호에서는 천연 고분자 물질을 함유하도록 구성되는 하이드로겔 조성물로서, 상기 조성물 총 중량에 대하여 천연 고분자 물질 0.5 내지 10중량%, 피부 미용 기능을 부여하는 기능성 화장 성분 6 내지 40중량%, 방부제 0.001 내지 0.3중량% 및 잔량으로서 물을 포함하되, 상기 천연 고분자 물질은 아이오타 카라기난(Iota Carrageenan)과 로커스트콩 검(LBG; Locust Bean Gum)과의 2성분 혼합물이거나 상기 2성분 혼합물에 카파 카라기난(Kappa Carrageenan), 젤라틴, 한천(Agar), 알기네이트, 키토산, 키토산 유도체, 전분, 풀루란(Pullulan), 갈락토만난(Galactomannan), 곤약만난(Glucomannan), 구아검(Guar gum), 플루로닉(Pluronic), 알긴(Algin), 젤란검(Gellangum), 잔탄검(xanthan gum) 및 팩틴(Pectin)으로 이루어진 군에서 선택된 1종 또는 2종 이상의 물질을 사용하는 이수 방지 기능의 하이드로겔 조성물을 제안하고 있다.In addition, Korean Patent Registration No. 10-0853301 is a hydrogel composition configured to contain a natural polymer material, 0.5 to 10% by weight based on the total weight of the composition, functional cosmetic ingredients 6 to impart skin cosmetic function 40% by weight, preservative 0.001 to 0.3% by weight and the balance water, wherein the natural polymer material is a two-component mixture of Iota Carrageenan and Locust Bean Gum (LBG) or the two components Kappa Carrageenan, Gelatin, Agar, Alginate, Chitosan, Chitosan Derivatives, Starch, Pullulan, Galactomannan, Glucomannan, Guar gum ), Pluronic, Algin, Gellanum, Xanthan gum, and Pectin, one or two or more substances selected from the group consisting of It proposes a hydrogel composition of the features.
그러나 이러한 종래 기술들은 그 사용성분이 매우 복잡할 뿐만 아니라 대부분 마스크팩의 제조에 의존하고 있으며, 특히 방부효과가 있는 별도의 성분을 혼합하여 사용하여야 하는 번거로운 문제는 여전히 해결하지 못하고 있다.However, these conventional techniques are not only very complicated components, but also largely depend on the manufacture of the mask pack, in particular, the cumbersome problem of using a separate ingredient having an antiseptic effect is still not solved.
이와 같이, 종래의 화장료 조성물이나 화장품 제조 기술에서는 방부제 등을 사용하여 제품의 유통기한을 확보하거나 이에 대한 특별한 대안이 없이 통상적인 마스크팩이나 일반 화장품 또는 천연 화장품을 제조하고 있어서, 변질 가능성이 높거나 장기간 사용이 불가능한 문제점을 그대로 안고 있으며, 방부제를 사용하면 피부트러블 등의 원인이 되고 있어서, 소비자의 다양한 요구를 만족시키기 위해서는 이에 관한 개선이 매우 시급하다.As described above, in the conventional cosmetic composition or cosmetic manufacturing technology, using a preservative or the like to secure a shelf life of the product or to manufacture a conventional mask pack, general cosmetics or natural cosmetics without a special alternative to it, The problem is that it is impossible to use for a long time as it is, and the use of preservatives is a cause of skin problems, etc., in order to satisfy various needs of consumers, it is very urgent to improve it.
{선행기술문헌}{Prior art technical literature}
{특허문헌}{Patent Literature}
(특허문헌 1) 프랑스 특허공개 제2001-0007671호(Patent Document 1) French Patent Publication No. 2001-0007671
(특허문헌 2) 한국특허등록 제10-1803451호(Patent Document 2) Korean Patent Registration No. 10-1803451
(특허문헌 3) 한국특허등록 제10-0853301호(Patent Document 3) Korean Patent Registration No. 10-0853301
상기와 같은 종래기술의 문제점을 해결하기 위하여, 본 발명은 종래와 다른 새로운 조성의 조성물을 구성하고 이를 화장료로 이용하는 경우 방부제 등을 사용하지 않더라도 장기간 안정되고 편리하게 화장품을 사용할 수 있도록 하는 것을 해결과제로 한다.In order to solve the problems of the prior art as described above, the present invention is to compose a composition of a new composition different from the prior art, and when using it as a cosmetic, it is possible to use cosmetics for a long time stably and conveniently even without using a preservative Shall be.
따라서 본 발명의 목적은 방부제 없이 화장품으로 제조하여 사용할 수 있는 새로운 개념의 피부미용 증진용 조성물을 제공하는데 있다.Therefore, an object of the present invention is to provide a new concept for improving skin care composition that can be prepared and used as a cosmetic without preservatives.
또한, 본 발명의 다른 목적은 콜라겐과 알지네이트를 포함하는 수분이 제거된 피부증진용 조성물을 제공하는데 있다.In addition, another object of the present invention is to provide a composition for skin promotion wherein water is removed, including collagen and alginate.
또한, 본 발명의 또 다른 목적은 콜라겐과 알지네이트를 이용하여 제조된 화장품용 콜라겐 필름과 같은 콜라겐 건조체를 제공하는데 있다.In addition, another object of the present invention is to provide a collagen dry body such as a collagen film for cosmetics prepared using collagen and alginate.
또한, 본 발명의 또 다른 목적은 콜라겐과 알지네이트를 포함하고 수분을 실질적으로 함유하지 않아 장기간 사용할 수 있는 필름형 화장품을 제공하는데 있다.In addition, another object of the present invention is to provide a film-type cosmetics containing collagen and alginate and substantially free of moisture can be used for a long time.
위와 같은 본 발명의 과제해결을 위하여, 본 발명은 콜라겐과 알지네이트를 함유하고 수분이 제거된 피부미용 증진용 조성물을 제공한다.In order to solve the above problems of the present invention, the present invention provides a composition for enhancing skin care containing collagen and alginate and water is removed.
또한, 본 발명은 콜라겐과 알지네이트를 함유하고 수분이 제거된 피부미용 증진용 조성물로 이루어진 콜라겐 건조체를 제공한다.In addition, the present invention provides a collagen dry body comprising a collagen and alginate, and made of a composition for promoting skin care, from which moisture is removed.
또한, 본 발명은 콜라겐과 알지네이트를 함유하고 수분이 제거된 피부미용 증진용 조성물로 이루어진 필름형 화장품을 제공한다.In addition, the present invention provides a film-like cosmetics made of a composition for enhancing skin care containing collagen and alginate and water is removed.
또한, 본 발명은 콜라겐과 알지네이트를 혼합하고, 이를 건조하여 필름 또는 시트형상으로 제조하는 필름형 화장품의 제조방법을 제공한다.In addition, the present invention provides a method for producing a film cosmetics by mixing collagen and alginate, and drying them to produce a film or sheet form.
본 발명에 의한 피부미용 증진용 조성물은 다음과 같은 효과가 있다.The composition for enhancing skin care according to the present invention has the following effects.
첫째, 천연재료로부터 추출한 콜라겐을 사용하는 경우 피부 거부반응은 낮은 반면에 기존의 콜라겐 파우더보다 향상된 물성을 나타내므로 다양하고 효과가 우수한 화장품 제조에 이용될 수 있다.First, in the case of using collagen extracted from natural materials, the skin rejection reaction is low, but exhibits improved physical properties than the existing collagen powder, and thus can be used for manufacturing various and excellent cosmetics.
둘째, 콜라겐과 알지네이트를 혼합하여 조성물로 구성함으로서 이를 건조하여 화장품 등으로 제조하는 경우 수분을 포함하고 있지 않아, 방부제를 첨가하지 않은 상태에서도 장기간 유통이 가능하다.Second, collagen and alginate are mixed to form a composition, and when dried and manufactured in cosmetics, etc., it does not contain moisture, and thus long-term distribution is possible even without adding a preservative.
셋째, 본 발명의 피부미용 증진용 조성물을 이용하여 제조되는 화장품은 건조된 필름형태로 제조하는 경우 물에 잘 녹지 않는 콜라겐의 비표면적이 넓혀진 물성의 필름형태로 구성되므로 물을 가하게 되면 물에 쉽게 녹아 일반 화장품과 동일한 형태로 손쉽게 사용할 수 있다. Third, the cosmetics produced using the composition for promoting skin care of the present invention is composed of a film of a physical property of the specific surface area of collagen, which is insoluble in water, when it is prepared in a dried film form, so that water is easily added to water. Melted and can be used easily in the same form as general cosmetics.
넷째, 본 발명의 피부미용 증진용 조성물을 사용한 필름형 화장품은 물에 의해 쉽게 용해되어 피부에 도포하는 경우 피부 침투력이 우수하고 흡수가 빨라서 화장품 사용 효과가 현저하게 개선되는 효과가 있다.Fourth, the film-type cosmetics using the composition for enhancing skin care of the present invention is easily dissolved by water, and when applied to the skin, the skin penetration is excellent and the absorption is fast, and the effect of using cosmetics is remarkably improved.
다섯째, 본 발명은 피부미용 증진용 조성물을 이용하여 건조한 필름형 화장품으로 사용하는 경우 휴대와 보관이 간편하고 물만 있으면 쉽게 용해하여 사용함으로서 일회용 화장품으로 편리하게 사용할 수 있는 등 다양한 소비자의 요구에 부응하는 신개념 화장품으로 활용이 가능하다.Fifth, the present invention is easy to carry and store when using as a dry film-type cosmetics using the composition for improving skin care, and can easily be used as a disposable cosmetics by simply dissolving water if necessary to meet the needs of various consumers It can be used as a new concept cosmetic.
여섯째, 본 발명의 필름형 화장품에는 콜라겐과 알지네이트 이외에도 추가로 화장 유효성분, 첨가제 등을 혼합하여 일반 화장품이나 특정 효능을 가지는 기능성 화장품으로 제조할 수 있으므로 다양한 종류의 화장품으로 제품화할 수 있는 효과가 있다. 특히, 피부에 적용시 얇은 막의 콜라겐 필름이 형성됨으로 피부의 수분 손실을 막아 주름개선 효과와 노화를 방지하기 위한 안티에이징 화장품으로 제조될 수 있다.Sixth, the film cosmetics of the present invention can be manufactured in addition to collagen and alginate in addition to the cosmetic active ingredients, additives, etc. can be produced as a general cosmetic or functional cosmetics having a specific effect, it can be produced into a variety of cosmetic products . In particular, a thin film of a collagen film is formed when applied to the skin it can be produced as an anti-aging cosmetics to prevent the loss of moisture of the skin to prevent wrinkles and prevent aging.
일곱째, 본 발명에 따른 피부미용 증진용 조성물은 콜라겐을 다량 함유하고 건조에 의해 다공성 필름으로 구성하는 경우 물을 사용하여 용해한 상태로 피부에 적용하면 피부 흡수력이 매우 좋아서 피부 보습 및 피부개선에 매우 우수한 효과를 발휘한다. 또한, 콜라겐을 다른 화장 유효성분과 혼합하여 사용할 때 화장 유효성분의 피부 흡수를 용이하게 도와주어 피부 흡수 효과가 더욱 개선되는 효과가 있다.Seventh, when the composition for enhancing skin care according to the present invention contains a large amount of collagen and is composed of a porous film by drying, when applied to the skin in a dissolved state using water, the skin absorption is very good, which is very excellent for skin moisturizing and skin improvement. It is effective. In addition, when collagen is used in combination with other cosmetically active ingredients, it helps to easily absorb the skin of the cosmetically active ingredient, thereby improving the skin absorption effect.
여덟째, 본 발명에 따른 피부미용 증진용 조성물을 이용하여 제조된 콜라겐 필름에 외용 약제를 첨가하여 제조하는 경우 상기와 같은 방법으로 다양한 효과를 가지는 성분을 혼합하여 필름형으로 제조함으로서, 외용 약제나 세정제, 비누, 샴푸 등으로도 활용할 수 있는 효과가 있다.Eighth, in the case of manufacturing by adding an external medicine to the collagen film prepared by using the composition for promoting skin care according to the present invention by mixing the components having various effects in the same manner as described above to produce a film, an external medicine or cleaning agent , Soap, shampoo, etc. can be used as an effect.
도 1은 본 발명에 따른 피부미용 증진용 조성물을 이용하여 제조한 콜라겐 필름의 실제품 사진이다.1 is a photograph of the actual product of the collagen film prepared using the composition for enhancing skin care according to the present invention.
이하, 본 발명을 하나의 구현예로서 더욱 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail as one embodiment.
본 발명에서 사용되는 전문용어는 단지 특정 구현예로서의 실시예를 언급하기 위한 것이며, 본 발명을 한정하는 것을 의도하지 않는다.The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
본 발명에서 사용되는 단수 형태들은 문구들이 이와 명백히 반대의 의미를 나타내지 않는 한 복수 형태들도 포함한다.As used herein, the singular forms "a", "an" and "the" include plural forms unless the context clearly dictates the opposite.
본 발명에서 사용되는 "포함하는"의 의미는 특정 특성, 영역, 정수, 단계, 동작, 요소 및/또는 성분을 구체화하며, 다른 특정 특성, 영역, 정수, 단계, 동작, 요소, 성분 및/또는 군의 존재나 부가를 제외시키는 것은 아니다.As used herein, the meaning of "comprising" embodies a particular characteristic, region, integer, step, operation, element and / or component, and other specific characteristics, region, integer, step, operation, element, component and / or component. It does not exclude the presence or addition of groups.
본 발명에서 사용되는 기술용어 및 과학용어를 포함하는 모든 용어들은 본 발명에서 별도로 정의하지 않는 한 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 일반적으로 이해하는 의미와 동일한 의미를 가진다. 보통 사용되는 사전에 정의된 용어들은 관련 기술문헌과 현재 개시된 내용에 부합하는 의미를 가지는 것으로 추가 해석되고, 정의되지 않는 한 이상적이거나 매우 공식적인 의미로 해석되지 않는다.All terms including technical terms and scientific terms used in the present invention have the same meaning as commonly understood by one of ordinary skill in the art unless otherwise defined in the present invention. Commonly defined terms used are additionally interpreted to have a meaning consistent with the related technical literature and the presently disclosed contents, and are not interpreted in an ideal or very formal sense unless defined.
본 발명에서 필름형이라 함은 통상적으로 얇은 형태의 소재로서, 예컨대 필름, 시트, 매트릭스 등의 얇게 이루어진 형태를 가진 다양한 형상을 모두 포함하는 것을 의미한다.In the present invention, the film type generally means a thin material, and includes all of various shapes having a thin shape such as a film, a sheet, and a matrix.
본 발명은 본질적으로는 콜라겐을 기본성분으로 하는 피부미용 증진용 조성물에 관한 것이다.The present invention relates to a composition for enhancing skin care, which is essentially a collagen.
본 발명은 콜라겐이 본질적으로 기본성분을 구성하되 콜라겐에 알지네이트를 함유하는 조성물로 이루어진 것이다.The present invention consists of a composition in which collagen essentially constitutes a basic ingredient but contains alginate in collagen.
본 발명의 피부미용 증진용 조성물은 수분이 제거된 것으로서, 실질적으로 수분이 함유되지 않은 조성물이다. 그러므로 건조된 상태의 조성물로 구성될 수 있다.The composition for enhancing skin care of the present invention is a composition which is substantially free of moisture as it has been removed therefrom. It may therefore consist of a composition in a dried state.
본 발명의 바람직한 구현예에 따르면, 이러한 수분이 제거된 피부미용 증진용 조성물에는 수분 함량이 15중량% 이내, 더욱 바람직하게는 5-12중량% 인 것이 바람직하다.According to a preferred embodiment of the present invention, it is preferable that the moisture content of the composition for promoting skin care from which moisture is removed is within 15% by weight, more preferably 5-12% by weight.
본 발명에 다른 조성물은 바람직하게도 수분이 제거된 것으로서, 기존의 하이드로겔 조성이나 겔화된 조성물과는 다른 성질을 가진다.Other compositions of the present invention are preferably water removed, and have different properties from existing hydrogel compositions or gelled compositions.
본 발명에서 사용되는 콜라겐은 천연 콜라겐이 바람직하게 사용될 수 있다.As the collagen used in the present invention, natural collagen may be preferably used.
본 발명의 바람직한 구현예에 따르면, 콜라겐과 알지네이트는 콜라겐 100중량부에 대해 알지네이트가 30-120중량부로 함유되는 것이 바람직하다. According to a preferred embodiment of the present invention, the collagen and alginate preferably contains 30 to 120 parts by weight of alginate based on 100 parts by weight of collagen.
본 발명의 목적을 고려할 때, 바람직하게는 콜라겐에 비해 알지네이트가 소량 사용되는 경우이다. 더욱 바람직하게는 콜라겐 100중량부에 대해 알지네이트가 50-90중량부, 가장 좋기로는 55-80중량부로 함유하는 경우이다.In consideration of the object of the present invention, it is preferable when a small amount of alginate is used as compared to collagen. More preferably, the alginate is contained in an amount of 50-90 parts by weight, most preferably 55-80 parts by weight, based on 100 parts by weight of collagen.
본 발명의 조성물은 그 자체로서 물과 같은 액상의 용해제와 혼합하면 피부미용 증진용 조성물로 사용될 수 있다. 따라서 본 발명의 바람직한 조성물은 지속적으로 성형성을 부여하는 성분 또는 수불용성 성분을 추가적으로 포함하지 아니한다.The composition of the present invention can be used as a composition for promoting skin care when mixed with a liquid solubilizer such as water as such. Therefore, the preferred composition of the present invention does not additionally contain a component or water-insoluble component which continuously impart moldability.
본 발명의 바람직한 구현예에 따르면, 본 발명의 조성물은 성형성을 부여하는 성분, 수불용성 성분을 포함하지 아니하고 화장 유효성분과 통상의 화장품용 첨가제를 추가적으로 함유할 수 있다.According to a preferred embodiment of the present invention, the composition of the present invention may further contain a cosmetic active ingredient and a conventional cosmetic additive without including a component imparting moldability, a water-insoluble component.
본 발명의 바람직한 구현예에 따르면, 본 발명에 따른 피부미용 증진용 조성물은 궁극적으로는 건조를 통해 필름형의 화장용 소재 또는 필름형 화장품으로 제조하는 데 유용하게 활용하기 위한 것이다. 더욱이 본 발명은 필름형 화장품으로 사용하는 경우 물에 쉽게 용해되는 구조로 이루어지는 것을 특징으로 한다. 그러므로 이러한 필름형 화장품의 조건을 만족하기 위해서는 물에 쉽게 용해되는 구성으로 이루어지는 것이 바람직하다.According to a preferred embodiment of the present invention, the composition for enhancing skin care according to the present invention is intended to be usefully used for producing a cosmetic material or a film-type cosmetics through film drying. Furthermore, the present invention is characterized in that it is made of a structure that is easily dissolved in water when used as a film cosmetic. Therefore, in order to satisfy the conditions of such a film-type cosmetics, it is preferable that the composition is easily dissolved in water.
그러므로 본 발명의 조성물에서 콜라겐보다 알지네이트가 지나치게 과량 사용되는 경우에는 상기 피부미용 증진용 조성물을 이용하여 필름형으로 제조하는 경우 건조된 필름이 쉽게 깨지므로 상품성이 현저하게 저하된다. 또한, 상기 알지네이트가 너무 소량 사용되면 건조 후 필름형 소재의 비표면적이 현저하게 작아서 물을 사용하더라도 물에 쉽게 용해되지 않아서 화장품 등의 소재로 사용하는 경우 사용에 불편한 문제가 발생할 수 있다.Therefore, when the alginate is used in excess of collagen in the composition of the present invention, when the film is manufactured using the composition for promoting skin care, the dried film is easily broken, and thus the commercial property is significantly lowered. In addition, if the alginate is used in a small amount, the specific surface area of the film-like material after drying is significantly small, so that even if water is used, it is not easily dissolved in water, and thus may be inconvenient to use when used as a material such as cosmetics.
특히, 본 발명에 따르면 상기 알지네이트는 콜라겐에 비해 과량 사용하는 경우 실질적으로 필름형 화장품 등으로 활용할 수 없는 심각한 문제가 발생할 수 있어서 콜라겐 보다 소량 사용하는 것이 바람직하다.In particular, according to the present invention, when the alginate is used in excess of the collagen, it may be a serious problem that cannot be effectively utilized in film-type cosmetics, etc., so it is preferable to use a smaller amount than the collagen.
본 발명의 바람직한 구현예에 따르면, 상기와 같은 피부미용 증진용 조성물로 이루어진 콜라겐 필름을 포함하는데, 이러한 콜라겐 필름은 상기 조성물이 건조된 상태로 이루어진 것이다.According to a preferred embodiment of the present invention, it comprises a collagen film made of a composition for promoting skin care as described above, such collagen film is made of a dry state of the composition.
예컨대, 본 발명의 조성물을 이용한 콜라겐 필름을 물에 용해하여 피부에 적용시 얇은 막의 콜라겐 필름이 형성됨으로 피부의 수분 손실을 막아 주름개선 효과와 노화를 방지하기 위한 안티에이징 화장품으로 제조될 수 있다.For example, when the collagen film using the composition of the present invention is dissolved in water and applied to the skin, a thin film of the collagen is formed, thereby preventing the loss of moisture of the skin, thereby making it an anti-aging cosmetic for preventing wrinkles and aging.
또한, 본 발명의 바람직한 구현예에 따르면, 상기와 같은 피부미용 증진용 조성물에 추가적으로 화장 유효성분을 포함하고 건조된 상태로 이루어진 필름형 화장품을 제공할 수 있다.In addition, according to a preferred embodiment of the present invention, in addition to the composition for promoting skin care, it may provide a cosmetic film containing a cosmetic active ingredient in a dried state.
예컨대, 본 발명의 조성물에 추가로 화장 유효성분, 첨가제 등을 혼합하여 일반 화장품이나 특정 효능을 가지는 다양한 기능성 화장품으로 제조할 수 있다. For example, by adding a cosmetic active ingredient, additives and the like to the composition of the present invention can be prepared as a general cosmetic or a variety of functional cosmetics having a particular effect.
이러한 필름형 화장품은 콜라겐을 다량 함유하여 물을 사용하여 용해한 상태로 피부에 적용하면 피부 흡수력이 매우 좋아서 피부 보습 및 피부개선에 매우 우수하며, 다른 화장 유효성분의 피부 흡수를 용이하게 도와주어 피부 흡수 효과가 더욱 개선되는 것이다.These film-type cosmetics contain a large amount of collagen and apply to the skin in a dissolved state using water, so the skin absorption is very good, so it is very good for moisturizing and improving the skin, and it helps to absorb the skin easily by other cosmetic active ingredients. The effect is further improved.
본 발명에 따르면, 상기 콜라겐 필름 또는 필름형 화장품의 경우 건조에 의해 수분이 제거된 콜라겐이 함유된 필름형 소재이므로 콜라겐의 비표면적이 크게 증가된 형태로 이루어질 수 있는바, 필름에 미세 공극이 다수 형성된 구조를 가진다. 바람직하게는 공극률(porosity)이 10-80%, 더욱 바람직하게는 20-50%를 가지는 구조로 이루어질 수 있다. 이러한 공극을 가지는 필름형 구조는 그 필름형 소재에 물을 가하는 경우 콜라겐이 쉽게 용해되도록 하여 사용이 편리하도록 하게 되는 놀라운 효과를 제공하는 것이다. 본 발명의 다른 콜라겐 건조체의 경우도 상기 필름과 동일한 정도의 공극률을 가질 수 있다.According to the present invention, in the case of the collagen film or film cosmetics, since the film-type material containing collagen from which moisture is removed by drying, the specific surface area of collagen may be greatly increased. It has a formed structure. Preferably the porosity (porosity) may be made of a structure having a 10-80%, more preferably 20-50%. The film-like structure having such voids is to provide a surprising effect that the collagen is easily dissolved when water is added to the film-like material to facilitate the use. The other collagen dry matter of the present invention may also have the same porosity as that of the film.
본 발명의 바람직한 구현예에 따르면, 상기 피부미용 증진용 조성물에 사용되는 콜라겐으로서는 육상동물 또는 어류 등에서 유래되는 동물성 콜라겐이나 녹차콜라겐과 같은 식물성 콜라겐 등의 천연 콜라겐이 사용될 수 있으며, 구체적으로는 예컨대, 돈피콜라겐, 우피콜라겐, 녹차콜라겐, 어린콜라겐 및 어피콜라겐 중에 선택된 어느 하나 이상의 천연 콜라겐이 사용될 수 있다.According to a preferred embodiment of the present invention, as the collagen used in the composition for enhancing skin care, natural collagen such as animal collagen derived from terrestrial animals or fish or vegetable collagen such as green tea collagen may be used, and specifically, for example, Any one or more natural collagen selected from donpicollagen, uppicollagen, green tea collagen, young collagen and apicollagen may be used.
또한, 본 발명의 바람직한 구현예에 따르면, 상기 피부미용 증진용 조성물에 사용되는 알지네이트로서는 1가 양이온의 염과 2가 양이온의 염이 사용될 수 있는 바, 예를 들면, 소듐 알지네이트, 포타슘 알지네이트, 암모늄 알지네이트 등의 1가 양이온의 염이나 알긴산 칼슘, 알긴산 철, 알긴산 아연, 알긴산 구리 등의 2가 양이온의 염 중에서 선택된 하나 이상을 사용할 수 있다. 더욱 바람직하게는 소듐 알지네이트, 포타슘 알지네이트, 암모늄 알지네이트 중에서 선택된 하나 이상이 사용될 수 있다. 가장 바람직하게는 소듐 알지네이트를 사용할 수 있다.In addition, according to a preferred embodiment of the present invention, as the alginate used in the composition for promoting skin care, salts of monovalent cations and salts of divalent cations may be used. For example, sodium alginate, potassium alginate, ammonium One or more selected from salts of monovalent cations such as alginate, and salts of divalent cations such as calcium alginate, iron alginate, zinc alginate and copper alginate can be used. More preferably one or more selected from sodium alginate, potassium alginate, ammonium alginate can be used. Most preferably sodium alginate can be used.
본 발명에 따르면, 상기 피부미용 증진용 조성물은 다양한 형태의 콜라겐 건조제로 제조될 수 있으며, 구형, 펠릿형, 시트형, 매트릭스, 필름 등의 건조체로 제조될 수 있으며, 가장 바람직하게는 콜라겐 필름 또는 필름형 화장품으로 제조할 수 있다.According to the present invention, the composition for enhancing skin care can be prepared with various types of collagen desiccant, and can be prepared with a dry body such as spherical, pellet, sheet, matrix, film, most preferably collagen film or film It can be produced as a cosmetic type.
본 발명은 바람직하게는 수분을 제거하기 위해 예컨대 동결 건조 등과 같은 방법으로 수분이 제거된 피부미용 증진용 조성물로 제조하는 것이 바람직한데, 특히 여러 가지 형태 중에서 화장품으로 사용하기 용이한 형태로서 콜라겐 필름 형태의 콜라겐 건조체로 제조될 수 있다.Preferably, the present invention is to prepare a skin care composition for removing moisture by a method such as lyophilization, etc., in order to remove moisture, in particular, in the form of collagen film, which is easy to use as a cosmetic among various forms It can be prepared in the collagen dry body of.
본 발명의 바람직한 구현예에 따르면, 콜라겐과 알지네이트를 정제수에 혼합하여 혼합물을 제조하는 단계 및 상기 혼합물을 성형틀에 넣고 건조하는 단계를 포함하는 공정을 거쳐서 필름형 화장품을 제조할 수 있다.According to a preferred embodiment of the present invention, the film-like cosmetics may be prepared through a process comprising the steps of preparing a mixture by mixing collagen and alginate in purified water and putting the mixture into a mold.
여기서 사용되는 성형틀은 변형을 위해서는 필름형이나 이와 유사한 다른 형태의 성형틀 또는 원하는 화장품 형태의 성형틀이 이용될 수 있다The mold used herein may be a mold of a film or other similar form or a desired cosmetic form for deformation.
이러한 필름형 화장품은 본질적으로는 콜라겐 필름으로 구성할 수 있다. 이러한 콜라겐 필름에는 다른 화장 성분이 포함되지 않거나 추가로 화장성분이 포함될 수 있다.Such film cosmetics may consist essentially of collagen film. Such collagen film may not include other cosmetic ingredients or may additionally include cosmetic ingredients.
본 발명의 바람직한 구현예에 따르면, 상기 콜라겐과 알지네이트를 함유하는 혼합물에는 추가적으로 화장 유효성분과 첨가제가 함유될 수 있다.According to a preferred embodiment of the present invention, the mixture containing the collagen and alginate may additionally contain a cosmetic active ingredient and additives.
본 발명의 일 구현예에 따르면, 상기 화장 유효성분으로서는 식물성 또는 동물성이 천연 추출물이나 천연 발효산물 등이 하나 이상 사용될 수 있으며, 첨가제로서는 화장품 조성물에 흔히 사용되는 통상의 유화제, 계면활성제, 향료 등이 하나 이상 사용될 수 있다.According to one embodiment of the present invention, the cosmetic active ingredient may be one or more natural extracts or natural fermentation products, such as vegetable or animal, and as an additive, conventional emulsifiers, surfactants, fragrances, etc. commonly used in cosmetic compositions One or more may be used.
본 발명에 따르면 상기와 콜라겐과 알지네이트 또는 여기에 다른 추가 성분 등의 각 성분을 혼합하고, 그 혼합물을 약 40-80℃, 더욱 바람직하게는 50-70℃에서 완전히 용해하여 분산시킨 후 생성된 거품이 완전히 제거 될 때까지 상온에서 냉각 시켜 피부미용 증진용 조성물을 제조할 수 있다.According to the present invention, the resulting foam is mixed with each other, such as collagen and alginate or other additional ingredients, and the mixture is completely dissolved and dispersed at about 40-80 ° C, more preferably 50-70 ° C. By cooling at room temperature until it is completely removed can be prepared a composition for promoting skin care.
본 발명의 일 구현예에 따르면, 상기 조성물을 건조하는 방법으로는 좋기로는 동결건조 방법으로 시행하는 것이 바람직한 바, 이러한 동결건조는 예컨대, 조성물을 냉각시키고 냉각된 조성물 용액을 -30 ~ 20 ℃의 온도 범위에서 약 12 ~ 24시간 동안 수행할 수 있다. 이러한 동결건조는 현재 시판되어 있는 동결 건조기를 사용하는 것도 가능하다. 이렇게 동결건조된 경우 피부미용 증진용 조성물 내부의 수분을 제거하게 되어 다공성 막의 형태로 콜라겐 필름 또는 필름형 화장품을 제조하는 것이 가능하다.According to one embodiment of the present invention, the method of drying the composition is preferably carried out by a lyophilization method, such lyophilization, for example, to cool the composition and the cooled composition solution -30 ~ 20 ℃ It can be carried out for about 12 to 24 hours in the temperature range of. Such lyophilization is also possible using commercially available freeze dryers. When it is lyophilized it is possible to remove the moisture inside the composition for enhancing skin care to produce a collagen film or film-like cosmetics in the form of a porous membrane.
본 발명에 따르면, 상기와 같은 피부미용 증진용 조성물을 건조하여 필름형태를 유지하기 위해서 동결건조 방법을 사용하는 경우는 냉각방법이 중요할 수 있다. 예를 들어, 조성물을 동결건조하는 경우 냉각은 단계적으로 냉각하는 방식과 연속적으로 냉각하는 방식으로 나눌 수 있다. 단계적으로 냉각하는 방식은 조성물 용액과 상관 없이 온도를 일정한 수준으로 낮춘 후에 급격하여 온도를 낮추는 방식을 의미한다. 연속적으로 냉각하는 방식은 조성물-용액의 온도에 따라 조금씩 냉각 온도를 낮추는 방식을 의미한다. 조성물 용액의 냉각시 급격하게 온도를 내릴 경우 열충격에 의해 필름의 외형이 갈라지거나 건조체 형상이 일정하게 되지 않는 문제점이 발생할 수 있다. 본 발명에서 각 성분이 혼합된 혼합물 용액의 냉각시 이른 바 준 평형상태에 가깝도록 냉각하게 되면 열충격을 최소화시켜 안정적인 제형을 확보할 수 있다. 일반적으로 급속냉각의 경우 냉각기의 온도를 목표온도로 세팅한 상태에서 바로 냉각시키는 것으로서 이와는 상이하게 본 발명에서의 연속냉각은 냉각기의 시편의 온도와 동일하게 설정하고 냉각기의 온도를 낮춰가면서 온도를 낮추는 것이다. 급속냉각의 상반된 개념으로 이를 완속 냉각으로도 표현할 수 있다. 본 발명에서 완속 냉각은 이러한 연속냉각 방식을 의미하는 것이다.According to the present invention, the cooling method may be important when the lyophilization method is used to dry the composition for promoting skin care as described above to maintain the film form. For example, when lyophilizing the composition, cooling can be divided into a stepwise cooling method and a continuous cooling method. Stepwise cooling means a method of rapidly lowering the temperature after lowering the temperature to a constant level irrespective of the composition solution. Continuous cooling means a method of lowering the cooling temperature little by little depending on the temperature of the composition-solution. If the temperature of the composition solution is rapidly lowered during cooling, the appearance of the film may be cracked or the shape of the dried body may not be constant due to thermal shock. In the present invention, the cooling of the mixture solution in which each component is mixed, so as to close to the so-called equilibrium state can minimize the thermal shock to ensure a stable formulation. In general, in the case of rapid cooling, the cooler is directly cooled in a state where the target temperature is set to a target temperature. Unlike this, continuous cooling in the present invention is set equal to the temperature of the cooler specimen and lowers the temperature while lowering the temperature of the cooler. will be. The opposite concept of rapid cooling can be expressed as slow cooling. Slow cooling in the present invention means such a continuous cooling method.
본 발명에 따르면, 연속냉각 방식을 취하는 경우 얼음결정을 작고 균일한 크기로 냉각시켜 얼음을 승화시켜 건조시키게 된다. 이 경우 동결 건조된 건조체 제품은 표면적이 더욱 넓어져 적은 양의 물에도 쉽게 녹을 수 있는 장점이 있다. 또한, 사용감을 편하게 할 뿐만 아니라 콜라겐의 수분에 대한 용해도가 높아져 콜라겐의 피부 침투 효과를 향상시킬 수 있다.According to the present invention, in the case of continuous cooling, ice crystals are cooled to a small and uniform size to sublimate the ice and dry it. In this case, the freeze-dried dried product has an advantage that it can be easily dissolved even in a small amount of water due to its wider surface area. In addition, not only ease of use, but also the solubility of the collagen in water can be improved to improve the skin penetration effect of collagen.
본 발명의 바람직한 구현예에 따르면, 건조된 필름형 화장품에 대해 수분 흡수력을 향상시키는 등의 목적으로 비표면적으로 넓히기 위해 다양한 형태로 가공될 수 있다. 예를 들면, 콜라겐 필름이나 필름형 화장품의 경우 바람직하게는 지름 약20-50mm의 원형 형태이고, 두께 약 0.5-3mm의 필름 형태로 가공할 수 있다. 이렇게 제조하는 경우 예컨대, 사용자가 아이패치로 활용하고자 할 때, 물을 투입하거나, 수분을 포함하는 화장품에 혼합하여 피부에 도포하는 경우 보다 효과적으로 도포하여 사용할 수 있다. According to a preferred embodiment of the present invention, the dried film-type cosmetics may be processed in various forms to broaden the specific surface area for the purpose of improving moisture absorption. For example, in the case of a collagen film or a film cosmetic, it is preferably a circular shape having a diameter of about 20-50 mm, and can be processed into a film shape having a thickness of about 0.5-3 mm. In this case, for example, when the user intends to use the eye patch, water may be added or mixed with cosmetics containing moisture to apply the skin more effectively.
본 발명에 따르면, 콜라겐과 알지네이트 혼합물을 물에 잘 녹는다. 특히, 본 발명에서 콜라겐과 혼합하여 사용되는 알지네이트는 콜라겐과 혼합된 상태에서 건조시키는 경우 알지네이트의 분자쇄로 인해 형성되는 그물망 형태의 공극 구조 중에 함유된 수분이 분리되어 전체적인 조성물이 건조된 고형물로 형성되어 필름형 구조의 콜라겐 필름을 형성하게 된다. 이러한 콜라겐 필름은 그대로 필름형 화장품으로 사용될 수도 있다. 또한, 이러한 건조 전의 피부미용 증진용 조성물에 화장 유효성분이 혼합된 경우에는 상기와 동일한 메카니즘에 의해 건조된 필름형 화장품으로 제조될 수 있다.According to the invention, the collagen and alginate mixture is well soluble in water. In particular, the alginate used in combination with the collagen in the present invention, when dried in the mixed state with the collagen is separated from the moisture contained in the network-shaped pore structure formed by the molecular chain of the alginate to form the overall composition as a dried solid Thus, a collagen film having a film-like structure is formed. Such collagen film may be used as a film cosmetic as it is. In addition, when the cosmetic active ingredient is mixed with the composition for promoting skin care before drying, it may be prepared as a film-type cosmetics dried by the same mechanism as described above.
본 발명에 따르면 상기와 같이 건조 후에 제조된 건조체, 예컨대 콜라겐 필름 또는 필름형 화장품은 얇은 필름형태로 형성되어 있고 건조에 의해 필름 내에 공극이 형성되어 있으므로 물을 가하는 경우 수분에 의해 쉽게 용해되어 통상의 화장품과 같이 피부에 용이하게 도포하는 방식으로 사용될 수 있다.According to the present invention, the dried product prepared after drying as described above, for example, a collagen film or a film cosmetic product is formed in a thin film form, and voids are formed in the film by drying, so that when water is added, it is easily dissolved by water and is commonly used. It can be used in a manner that is easily applied to the skin, such as cosmetics.
본 발명의 바람직한 구현예에 따르면, 상기 피부미용 증진용 조성물은 예컨대 동결건조방식에 의해 필름형 화장품으로 제조될 수 있으며, 여기에 물을 가하게 되면 쉽게 용해되어 통상적인 화장품 형태와 같이 액상이나 크림상으로 변하여 피부에 도포되는 것일 수 있다.According to a preferred embodiment of the present invention, the composition for enhancing skin care can be prepared, for example, in a film-type cosmetics by a lyophilization method, and when water is added thereto, is easily dissolved and in a liquid or cream form as in a conventional cosmetic form. It may be changed to be applied to the skin.
본 발명의 바람직한 구현예에 따르면, 상기와 같이 구성된 본 발명의 조성물이나 이를 건조하여 제조한 콜라겐 필름 또는 필름형 화장품을 사용하게 되면, 피부노화 방지 등의 피부미용 증진을 위해 콜라겐을 섭취하거나 미량의 콜라겐 화장품을 이용하는 것이 아니라, 필름형태로 제작하여 별도의 물을 이용하여 용해시켜 피부에 도포함으로써, 콜라겐이 진피의 손상부분에 직접적으로 투입되어 수분과 콜라겐을 보충을 할 수 있다. 다른 건조체 형태도 필름과 유사하게 사용될 수 있다.According to a preferred embodiment of the present invention, when using the composition of the present invention configured as described above or the collagen film or film cosmetics prepared by drying the same, ingesting or reducing the amount of collagen to improve skin beauty, such as preventing skin aging Instead of using collagen cosmetics, it is produced in the form of a film and dissolved in separate water and applied to the skin, so that collagen can be directly added to the damaged part of the dermis to replenish moisture and collagen. Other dry forms may be used similarly to films.
종래에 콜라겐을 함유한 하이드로겔 마스크 팩이 알려진바 있으나, 이러한 마스크 팩은 장시간 보관 시 산화되어 색상의 변질, 물성 저하 등의 단점으로 장기간 유통이 어려운 상황이다. 또한 메틸 파라벤, 프로필렌 파라벤, 페녹시 에탄올, 헥산디올 등 방부제 및 칼슘염, 마그네슘염, 바륨염, 알루미늄염 등의 금속염의 첨가로 인해 피부 자극을 유발할 수 있다.Conventionally, hydrogel mask packs containing collagen have been known, but such mask packs are oxidized when stored for a long time and are difficult to distribute for a long time due to the disadvantages of color deterioration and deterioration of physical properties. In addition, preservatives such as methyl paraben, propylene paraben, phenoxy ethanol and hexanediol and metal salts such as calcium salt, magnesium salt, barium salt and aluminum salt may cause skin irritation.
그러나 본 발명에 따른 조성물을 이용한 필름형 화장품은 상기와 같이 건조를 통하여 수분을 제거함으로써 방부제를 첨가하지 않아도 보관성이 우수하여 장기간 유통이 가능하다. 보통 액상 화장품의 경우 변성 알코올계 또는 벤조산 계열의 방부제를 첨가하여야 하지만, 본 발명에서와 같이 건조된 필름형 화장품으로 제조되는 경우에는 실질적으로는 수분이 없는 상태로 매우 낮아진 수분 함량으로 인해 변성 알코올계 또는 벤조산 계열 등의 방부제를 첨가하지 않고 제품 자체의 방부능력으로도 유통 및 보관 기간 동안 변질되는 것을 방지할 수 있다는 장점이 있다. 또한 수분이 제거됨에 따라 무게를 줄일 수 있어 물류비를 절감하는 효과도 얻을 수 있다.However, the film-type cosmetics using the composition according to the present invention is excellent in storage properties without adding a preservative by removing moisture through drying as described above is possible long-term distribution. In the case of liquid cosmetics, a modified alcohol-based or benzoic acid-based preservative should be added. However, in the case of manufacturing a dried film-type cosmetic as in the present invention, the modified alcohol-based is substantially reduced due to a very low moisture content. Alternatively, there is an advantage of preventing deterioration during distribution and storage even with the preservative ability of the product itself without adding a preservative such as benzoic acid series. In addition, as the moisture is removed, the weight can be reduced, thereby reducing the logistics cost.
본 발명의 바람직한 일 구현예에 따르면, 상기 조성물을 구성함에 있어서 천연콜라겐과 알지네이트를 사용한 피부증진용 조성물이 예컨대 동결건조 방식을 활용하여 필름형으로 제작될 수 있고, 이를 피부에 도포함으로써 천연콜라겐이 진피 또는 진피의 손상부분에 직접적으로 투입되어 피부에 수분과 콜라겐의 보충이 가능하다. According to a preferred embodiment of the present invention, in the composition of the composition, the composition for skin promotion using natural collagen and alginate can be produced in a film form using, for example, a freeze-drying method, and the natural collagen is applied to the skin It can be added directly to the dermis or damaged parts of the dermis to replenish the skin with moisture and collagen.
본 발명에 따르면 콜라겐 보충을 위해서는 상기와 같이 필름형태로 제조하여 도포하는 것이 바람직한 바, 콜라겐 파우더는 콜라겐 필름처럼 쉽게 용해되지 않기 때문에 콜라겐 필름처럼 물과 접촉하는 표면적을 최대한 늘려 물, 스킨, 에센스 등 소비자가 원하는 형태의 화장품과 융합하여 사용할 수 있도록 필름형태로 제조하는 것이 바람직하다.According to the present invention, it is preferable to prepare and apply the film in the form of a film to supplement collagen as described above. Since the collagen powder is not easily dissolved like the collagen film, the surface area in contact with water as the collagen film is maximized to maximize the water, skin, essence, etc. It is desirable to manufacture in the form of a film so that the consumer can be used in conjunction with the cosmetic of the desired form.
본 발명의 바람직한 구현예에 따르면, 필름형 화장품의 구성과 피부의 침투에 의한 효과를 고려할 때 필름형 화장품을 제조하기 위한 건조 전의 피부미용 증진용 조성물 중에 콜라겐의 함량은 0.5~10 중량%로 함유하는 것이 바람직하다. 만일, 콜라겐이 10 중량% 초과의 경우 제형이 고밀도 상태가 되어 물에 쉽게 녹지 않을 수 있으며, 0.5 중량% 미만의 경우 콜라겐에 의한 피부 침투효과가 미미할 수 있다.According to a preferred embodiment of the present invention, the collagen content is contained in 0.5 ~ 10% by weight in the composition for enhancing skin care before drying to prepare a film-type cosmetics in consideration of the composition of the film-like cosmetics and the effects of penetration of the skin It is desirable to. If the collagen is more than 10% by weight, the formulation may be in a high density state and not easily dissolved in water. If the content is less than 0.5% by weight, the skin penetration effect due to collagen may be insignificant.
본 발명에 따르면, 콜라겐과 함께 사용되는 알지네이트는 겔형성제로서 포함된다. 이러한 알지네이트는 β-D-만누르산이 β-1,4결합에 의해 연결된 직선상의 중합체와 a-L-굴루론산이 a-1,4 결합에 의해 연결된 직선상의 중합체의 양자가 서로 교대로 연결된 직선상 중합체들이 구성단위가 되고 있는 분자량 약 22만의 복합 다당류이다. 알지네이트는 물에 녹으면 점성이 있으며, 안정제 및 증점제로서 그 효과가 우수하다. 본 발명에서 사용되는 알지네이트 수용액을 건조시켜서 수분이 제거되면 스펀지와 같은 형태를 띄고 그 형태가 매우 안정적이기 때문에 필름 형태로 제작할 때 건조 전의 전체 조성에 대해 알지네이트를 0.2 ~ 6중량%를 사용하면 제형 안정제로써 우수한 역할을 한다.According to the invention, alginates used with collagen are included as gelling agents. Such alginates are linear polymers in which β-D-mannuric acid is a linear polymer connected by β-1,4 bond and aL-guluronic acid is linearly connected by a-1,4 bond. These are complex polysaccharides having a molecular weight of about 220,000 that form their structural units. Alginate is viscous when dissolved in water and has excellent effects as a stabilizer and a thickener. When the alginate aqueous solution used in the present invention is dried to remove moisture, the result is a sponge-like form, and since its form is very stable, when 0.2 to 6% by weight of alginate is used with respect to the total composition before drying when producing a film form, As an excellent role.
또한, 본 발명에 따르면, 바람직하는 콜라겐과 알지네이트가 건조 전의 전체 조성물 중에 1-12중량%, 더욱 바람직하게는 5-8중량%로 함유하는 것이 바람직하다. Further, according to the present invention, it is preferable that the preferred collagen and alginate are contained in 1-12% by weight, more preferably 5-8% by weight in the total composition before drying.
본 발명에 따른 바람직하는 구현예에 따르면, 추가적으로 첨가할 수 있는 프로필렌글리콜 알지네이트(propylene glycol alginate)는 유화제로 사용될 수 있다. 이는 점착성과 점도를 증가시키고 유화안정성을 증진시킨다. 상기 프로필렌글리콜 알지네이트의 함량은 건조 전 중량으로 0.01 ~ 1 중량%가 바람직하다. 0.01중량% 미만인 경우 유화성능의 향상 효과를 기대하기 어렵고, 1 중량% 초과인 경우 필요 이상으로 점도가 상승하는 문제가 있다.According to a preferred embodiment according to the invention, propylene glycol alginate which can be added additionally can be used as an emulsifier. This increases the adhesion and viscosity and enhances the emulsion stability. The content of the propylene glycol alginate is preferably 0.01 to 1% by weight before drying. If it is less than 0.01% by weight, it is difficult to expect the effect of improving the emulsification performance, and if it is more than 1% by weight, there is a problem that the viscosity rises more than necessary.
또한, 본 발명에서 추가적으로 첨가할 수 있는 나이아신아마이드는 미백성분으로 첨가될 수 있다. 이는 비타민 B 복합체로서 열과 빛에 안정적인 성분에 해당한다. 나이아신아마이드는 피부 속으로 작용함으로써 멜라닌 색소 침착을 연하게 혹은 억제하여 피부톤을 전체적으로 균일화 시키는데 도움이 된다. 또한, 미백 효과뿐만 아니라 수분 보유력을 높여 피부를 부드럽게 하고 피부에 볼륨감을 형성시키기도 한다. 상기 나이아신아마이드의 건조 전 함량은 2 ~ 5 중량%가 바람직하다. 2 중량% 미만의 경우 미백효능을 기대하기 어렵고, 5 중량% 초과의 경우 피부에 과도하게 자극이 발생할 수 있다.In addition, niacinamide, which may be additionally added in the present invention, may be added as a whitening ingredient. It is a vitamin B complex that corresponds to heat and light stable ingredients. Niacinamide acts into the skin, helping to soften or inhibit melanin pigmentation and to even out skin tone. In addition, as well as the whitening effect to increase the moisture retention capacity to soften the skin and create a sense of volume on the skin. The content before drying of the niacinamide is preferably 2 to 5% by weight. If less than 2% by weight it is difficult to expect the whitening effect, if more than 5% by weight may cause excessive irritation to the skin.
본 발명의 바람직한 구현예에 따르면, 화장 유효성분을 추가로 함유할 수 있는데, 예컨대 초유 또는 초유 발효산물을 첨가할 수 있다. 이러한 초유 또는 초유 발효산물은 보습력을 향상시키기 위해 첨가될 수 있다. 초유는 어미 젖소가 송아지를 출산 후 3일 동안 나오는 우유를 말한다. 초유는 82가지 이상의 천연 생체 활성성분을 포함하게 된다. 예를 들어 히아루로닉산, 면역글로불린, TFG-BETA, 락토페린, IGF, EGF, FGF, 알파하이드록시산, 비타민B 등이 있다. 특히 히아루로닉산은 초유에 다량으로 존재하여 피부의 진피층을 이루고 있는 수분의 손실을 방지하여 뛰어난 보습효과를 나타낸다. 면역글로불린은 미생물을 죽이거나 미생물의 성장을 억제하여 피부를 보호한다. 비타민 B의 경우 자극 받은 피부를 진정시키는 데 도움이 된다. According to a preferred embodiment of the present invention, it may further contain a cosmetic active ingredient, for example, colostrum or colostrum fermentation product may be added. Such colostrum or colostrum fermentation product may be added to improve the moisturizing power. Colostrum is the milk that the mother cow produces for three days after the calf is born. Colostrum will contain more than 82 natural bioactive ingredients. Examples include hyaluronic acid, immunoglobulins, TFG-BETA, lactoferrin, IGF, EGF, FGF, alpha hydroxy acids, vitamin B, and the like. In particular, hyaluronic acid is present in a large amount in colostrum to prevent the loss of moisture in the dermal layer of the skin shows an excellent moisturizing effect. Immunoglobulins protect the skin by killing or inhibiting the growth of microorganisms. Vitamin B can help calm irritated skin.
본 발명에 따르면 추가적으로 화장 유효성분을 첨가하여 사용하는 경우 그 화장 유효성분의 함량은 전체 건조 전 조성물에 대해 1 ~ 10 중량%로 함유하는 것이 바람직하다. 만일, 그 함량이 1 중량% 미만의 경우 화장 유효성분의 첨가에 따른 효과가 미미하며, 10 중량%를 초과의 경우 제조공정 중에 액상의 점도가 매우 상승하여 얇은 시트 형태로 제작하기 어려운 문제가 발생할 수 있다.According to the present invention, when the cosmetically active ingredient is added and used, the content of the cosmetically active ingredient is preferably contained in an amount of 1 to 10% by weight based on the total composition before drying. If the content is less than 1% by weight, the effect of the addition of a cosmetic active ingredient is insignificant, and if the content is more than 10% by weight, the viscosity of the liquid is very high during the manufacturing process, which makes it difficult to produce a thin sheet form. Can be.
본 발명의 바람직한 구현예에 따르면, 화장 유효성분을 사용하는 경우 계면활성제도 함께 추가될 수 있는데, 상기 계면활성제는 물에 잘 용해되지 않는 물질들을 용해시키는 데 사용되는 것으로서, 예컨대 화장 유효성분 중에 함유되는 고형분과 추가적으로 함유될 수 있는 향료 등과 같은 추가 성분들을 정제수에 용해시키기 위해 첨가된다. 계면할성제의 예로서, 디옥틸 소듐 설포석시네이트, 폴리글리세릴-10 라우레이트 등이 사용될 수 있다. 본 발명에 따르면 추가로 계면활성제를 사용하는 경우 그 건조 전 함량은 0.01 ~ 0.1 중량%가 바람직하다. 만일 0.01중량% 미만의 경우 향료 등을 포함한 추가성분에 대한 가용화가 충분히 이루어지지 않을 수 있으며, 0.1중량%를 초과할 경우 다량의 기포가 발생하여 필름형 화장품으로 제조되는 경우 제품의 외관과 물성에 악영향을 줄 수 있다. According to a preferred embodiment of the present invention, in the case of using a cosmetic active ingredient, a surfactant may also be added together, which is used to dissolve substances that are not easily dissolved in water, for example, contained in the cosmetic active ingredient. Additional ingredients such as the solids to be added and the fragrances which may be further contained are added to dissolve the purified water. As examples of the surfactant, dioctyl sodium sulfosuccinate, polyglyceryl-10 laurate and the like can be used. According to the present invention, when a surfactant is further used, the content before drying is preferably 0.01 to 0.1% by weight. If less than 0.01% by weight, solubilization of additional ingredients, including fragrance, may not be made sufficiently. If it exceeds 0.1% by weight, a large amount of bubbles may be generated and produced in a film cosmetic product. It may adversely affect.
상기 성분 이외에 항료가 추가적으로 첨가될 수 있다. 향료는 건조 전 함량으로 0.1 ~ 1 중량%가 첨가되는 것이 바람직하다. In addition to the above ingredients, an additional agent may be added. The fragrance is preferably added in an amount of 0.1 to 1% by weight before drying.
또한, 본 발명에 따른 피부미용 증진용 조성물은 화장 유효성분을 포함할 수 있으며, 추가적으로 피부에 필요한 영양분을 공급할 수 있는 기능성 첨가제를 더 포함할 수 있다. 상기 기능성 첨가제는 마스크팩 등으로 사용하는 경우 피부에 필요한 영양분을 공급할 수 있는 다양한 성분이 포함될 수 있다. 상기 기능성 첨가제는 마유 또는 달팽이 점액일 수 있다.In addition, the composition for enhancing skin care according to the present invention may include a cosmetic active ingredient, and may further include a functional additive capable of supplying nutrients necessary for skin. The functional additive may include a variety of ingredients that can supply the nutrients necessary for the skin when used as a mask pack. The functional additive may be horse oil or snail mucus.
또한, 본 발명에 따른 피부미용 증진용 조성물에는 피부에 보습효과를 더욱 향상시킬 수 있도록 보습제를 더 포함할 수 있다. 상기 보습제는 피부에 일정한 수준의 수분공급 및 보습을 위해 다양한 성분이 포함될 수 있다. 상기 보습제는 히아루론산 또는 글리세린을 포함함 수 있다.In addition, the composition for enhancing skin care according to the present invention may further include a moisturizer to further improve the moisturizing effect on the skin. The moisturizing agent may include various ingredients for moisturizing and moisturizing the skin at a constant level. The moisturizing agent may include hyaluronic acid or glycerin.
본 발명에 따른 바람직한 구성의 일예를 설명하면, 예컨대 건조 전의 혼합물 구성으로 콜라겐 0.5 ~ 10 중량%, 알지네이트 0.2 ~ 6 중량%, 프로필렌글리콜 알지네이트 0.01 ~ 1 중량%, 나이아신아마이드 2 ~ 5 중량%, 화장 유효성분 1.0 ~ 10 중량%, 계면활성제 0.01~ 0.1 중량%, 정제수 잔량으로 구성될 수 있다. 만일, 여기에 향료를 첨가하는 경우 건조 전 조성물에 대해 0.1 ~ 1 중량%의 양으로 항료를 첨가할 수 있다.An example of a preferred configuration according to the present invention, for example, 0.5 to 10% by weight of collagen, 0.2 to 6% by weight of alginate, 0.01 to 1% by weight of propylene glycol alginate, 2 to 5% by weight of niacinamide, makeup It can be composed of 1.0 to 10% by weight of active ingredient, 0.01 to 0.1% by weight of surfactant, and the remaining amount of purified water. If the fragrance is added to it, it may be added in an amount of 0.1 to 1% by weight based on the composition before drying.
본 발명의 바람직한 구현예에 따르면, 콜라겐과 알지네이트만으로 이루어진 피부미용 증진용 조성물로도 사용할 수 있지만, 여기에 유효 화장성분이 혼합될 수 있는데, 본 발명에서는 이러한 화장성분은 그 사용량이 제한될 필요는 없다. 그러나 바람직한 화장품으로 사용할 수 있기 위해서는 일정 함량범위로 사용하는 것이 바람직하다.According to a preferred embodiment of the present invention, it can be used as a composition for promoting skin care consisting of only collagen and alginate, but an effective cosmetic ingredient may be mixed therein, but in the present invention, the amount of such cosmetic ingredient need not be limited. none. However, in order to be used as a preferred cosmetic, it is preferable to use it in a certain content range.
본 발명에 따른 바람직한 구현예에 따르면, 상기 본 발명의 조성물에 추가적으로 첨가되는 화장 유효성분과 첨가제, 그리고 기타 다양한 기능 또는 컨셉 원료 등의 부가 원료에 대한 총 첨가량은 콜라겐과 알지네이트 혼합물 100중량부에 대해 150-300중량부, 더욱 바람직하게는 180-250중량부로 혼합하는 것이 바람직하다.According to a preferred embodiment according to the present invention, the total amount added to the additives, such as cosmetically active ingredients and additives, and other various functional or concept raw materials additionally added to the composition of the present invention is 150 parts by weight based on 100 parts by weight of the collagen and alginate mixture It is preferred to mix at -300 parts by weight, more preferably 180-250 parts by weight.
상기한 바와 같이 본 발명의 바람직한 구현예에 따르면, 콜라겐과 알지네이트를 혼합하여 조성물로 구성함으로서 이를 건조하여 화장품 등으로 제조하는 경우 수분을 포함하고 있지 않아, 방부제를 첨가하지 않은 상태에서도 장기간 유통이 가능하고, 건조체 형태, 예컨대 건조된 필름형으로 제조하여 콜라겐의 비표면적이 넓혀진 물성의 필름형태로 구성되므로 물을 가하게 되면 물에 쉽게 녹아 일반 화장품과 동일한 형태로 손쉽게 사용할 수 있으므로, 편의성을 고려할 때 일회용 화장품으로 편리하게 사용할 수 있는 신개념 화장품으로 활용이 가능하다.As described above, according to the preferred embodiment of the present invention, when collagen and alginate are mixed to form a composition and dried to produce cosmetics, it does not contain water, and thus long-term distribution is possible even without adding a preservative. And, in the form of a dry body, for example, dried film form of the physical properties of the collagen's specific surface area is expanded, so that it is easily dissolved in water when water is added and can be used easily in the same form as general cosmetics, disposable in consideration of convenience It can be used as a new concept cosmetic that can be conveniently used as a cosmetic.
또한, 본 발명의 필름형 화장품은 물에 의해 쉽게 용해되어 피부에 도포하는 경우 피부 침투력이 우수하고 흡수가 빨라서 화장품 사용 효과가 현저하게 개선되고, 추가로 화장 유효성분을 포함하는 기능성 화장품으로 제조할 수 있으며, 특히 피부에 적용시 얇은 막의 콜라겐 필름이 형성됨으로 피부의 수분 손실을 막아 주름개선 효과와 노화를 방지하기 위한 안티에이징 화장품으로 유용하다.In addition, the film-type cosmetics of the present invention is easily dissolved by water, when applied to the skin is excellent skin penetration and quick absorption so that the effect of using the cosmetics is remarkably improved, and further comprising a functional cosmetic containing a cosmetic active ingredient In particular, the thin film collagen film is formed when applied to the skin is useful as an anti-aging cosmetics to prevent the loss of moisture of the skin to prevent wrinkles and prevent aging.
특히, 본 발명에서 사용되는 콜라겐이 분산된 상태의 건조체, 예컨대 필름 형태에서 용해되어 사용되기 때문에 피부 흡수력이 매우 좋아서 피부 보습 및 피부개선에 매우 우수한 효과를 나타낸다.In particular, since the collagen used in the present invention is dissolved and used in a dry state in a dispersed state, for example, in the form of a film, the skin absorption ability is very good, and thus the skin moisturizing and skin improvement are very excellent.
본 발명의 바람직한 구현예로서, 상기와 같은 콜라겐 건조체나 필름형 화장품은 상기 건조체나 필름형 화장품과 물을 하나의 포장지에 분리된 상태로 포장하여 상품화할 수 있다. 따라서 건조체나 필름형 화장품에서는 수분이 제거되어 있어서 별도의 방부제를 사용할 필요가 없다.As a preferred embodiment of the present invention, the collagen dry or film cosmetics as described above may be commercialized by packaging the dry or film cosmetics and water in a separate state in one wrapping paper. Therefore, the moisture is removed from the dried or film cosmetics, there is no need to use a separate preservative.
본 발명의 바람직한 구현예에 따르면, 상기 필름형 소재인 콜라겐 필름은 건조 전의 조성물에 외용 약제, 세정성분 등을 첨가하여 제조하는 경우 외용 약제나 세정제, 비누, 샴푸 등으로도 제품화할 수 있다.According to a preferred embodiment of the present invention, the collagen film, which is the film-like material, may be manufactured as an external medicine, a detergent, a soap, a shampoo, etc., when the external medicine, a cleaning component, etc. are added to the composition before drying.
이하, 본 발명을 실시예에 의거 상세하게 설명하겠는 바, 본 발명이 실시예에 의해 한정되는 것은 아니다.EMBODIMENT OF THE INVENTION Hereinafter, although this invention is demonstrated in detail based on an Example, this invention is not limited by an Example.
실시예 1-8, 비교예 1-5Example 1-8, Comparative Example 1-5
콜라겐과 알지네이트를 하기 표 1과 같은 조성으로 혼합하여 피부미용 증진용 조성뭉을 제조하되 이를 동결건조하여 필름형 화장품 형태로 제조하였다.Collagen and alginate were mixed in the composition shown in Table 1 below to prepare a composition for promoting skin care, but lyophilized to prepare a film-like cosmetic form.
사용된 콜라겐은 어류(동태) 껍질로부터 유래된 천연 콜라겐을 사용하였고, 알지네이트로서는 소듐 알지네이트를 사용하였다.The collagen used used natural collagen derived from fish (kinetic) shell, and sodium alginate as alginate.
또한, 추가적으로 사용되는 기능성 화장 성분으로서는 초유와 디옥틸 소듐 설포석시네이트, 프로필렌글리콜 알지네이트의 혼합성분을 사용하였다.In addition, as a functional cosmetic ingredient to be used additionally, a mixed component of colostrum, dioctyl sodium sulfosuccinate, and propylene glycol alginate was used.
상기와 같이 각 성분을 혼합하고 약 60℃에서 완전히 용해하여 분산시킨 후 생성된 거품이 완전히 제거 될 때까지 상온에서 냉각 시켜 조성물 용액을 제조하였다. As described above, each component was mixed, completely dissolved and dispersed at about 60 ° C., and then cooled at room temperature until the resulting foam was completely removed, thereby preparing a composition solution.
제조된 각각의 조성물 용액을 상온에서부터 약 -30℃까지 연속냉각 방식으로 약 4시간 동안 동결하고 약 15 시간 동안 약 -30℃에서부터 상온까지 승온시켜 건조시켜 지름 25mm ×두께 1mm 의 필름형태로 필름형 화장품 샘플을 제조하였다. Each prepared solution of the composition is frozen in a continuous cooling method from room temperature to about -30 ℃ for about 4 hours, and dried by heating up from about -30 ℃ to room temperature for about 15 hours in the form of a film of 25mm diameter × 1mm thickness Cosmetic samples were prepared.
제조된 시료는 도 1에 사진으로 제시한 형태로 제조되었다. 도 1은 실시예에서 제조된 피부미용 증진용 조성물을 동결건조 하여 제조된 필름형 화장품의 형태를 보여주기 위해 예시하여 나타낸 실제품 사진이다.The prepared sample was prepared in the form shown in the photograph in FIG. Figure 1 is a photograph of the actual product exemplified to show the form of the film-type cosmetics prepared by lyophilizing the composition for enhancing skin care prepared in the embodiment.
실험예 1Experimental Example 1
상기 실시예에서 제조된 필름형 화장품에 대하여 반복 제조시에 나타나는 물성과 필름특성을 확인하고 각각에 대하여 물을 가하여 용해력을 확인하였다. 각 시료는 같은 방법으로 5개씩 제조하여 평균 상태를 표시한 것이다.For the film-type cosmetics prepared in the above example, the physical properties and film properties appearing during repeated manufacturing were confirmed, and water was added to each of them to determine the dissolving power. Each sample was manufactured five by the same method, and the average state was shown.
그 결과는 다음 표 1에 나타내었는바, 콜라겐 성분에 비해 알지네이트가 지나치게 과량 사용되거나 두 성분 모두 전체 조성에 대해 과량 사용되는 경우 등(비교예에 해당)은 물성과 필름 물성 및 물 용해력 등에서 좋지 않은 결과를 나타내는 것으로 확인되었다.The results are shown in the following Table 1, when the alginate is excessively used compared to the collagen component, or both components are used in excess of the total composition (corresponding to the comparative example) is not good in physical properties, film properties and water solubility It was confirmed that the results are shown.
실험예 2Experimental Example 2
상기 실시예 5에서 제조된 필름형 화장품에 대하여 장기간 유통시 변질이나 오염여부 등 장기간 유통효과 확인을 위한 미생물 확인 테스트를 수행하였다. For the film-type cosmetics prepared in Example 5 was carried out a microorganism identification test for confirming long-term distribution effects such as deterioration or contamination during long-term distribution.
상기 실시예 5에 따른 5개의 시료에 대해 제조 직후, 2개월, 4개월, 6개월, 8개월 후의 세균 존재 여부를 확인하였다. 하기 표 2는 미생물 확인 테스트 결과를 나타낸다. 실험방법은 식품의약안전청 고시 제7. 일반시험법, 8. 미생물 시험법에 따라 건조 필름법을 사용하였다.For five samples according to Example 5, the presence of bacteria after 2 months, 4 months, 6 months, and 8 months after preparation was confirmed. Table 2 below shows the microbial identification test results. The test method is notified by the Korea Food and Drug Administration. Dry film method was used according to the general test method, 8. Microbial test method.
상기 표 2에 나타난 바와 같이, 본 발명에 따른 초유 콜라겐 복합 조성물 필름은 화장품용 방부제를 따로 첨가하지 않았음에도 장기간 지나도 미생물이 번식하지 않으며, 제형 사용시 변화가 없었다.As shown in Table 2, the colostrum collagen composite composition film according to the present invention does not propagate microorganisms even after a long period of time even without the addition of cosmetic preservatives, there was no change when using the formulation.
실험예 3Experimental Example 3
상기 실시예의 필름형 화장품에 대하여 보관 기관에 따른 필름형 화장품의 수분 함량비를 측정하였다. 시편은 상기 실시예 5와 동일한 시편을 사용하였으며, 보관기간의 경과하여도 수분 함량비는 감소하지 않음을 알 수 있었다.For the film cosmetic of the above example, the moisture content ratio of the film cosmetic according to the storage organ was measured. As the specimen, the same specimen as in Example 5 was used, and the moisture content ratio did not decrease even after the storage period.
위와 같이 본 발명의 실시예를 설명하였지만, 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자는 본 발명이 그 기술적 사상이나 필수적인 특징을 변경하지 않고서 다른 구체적인 형태로 실시될 수 있다는 것을 이해할 수 있을 것이다.Although the embodiments of the present invention have been described above, those skilled in the art will understand that the present invention can be implemented in other specific forms without changing the technical spirit or essential features. .
본 발명의 범위는 상기 상세한 설명보다는 후술하는 청구범위에 의하여 나타내어지며, 청구범위의 의미 및 범위 그리고 그 균등 개념으로부터 도출되는 모든 변경 또는 변경된 형태가 본 발명의 범위에 포함되는 것으로 해석되어야 한다.The scope of the invention is indicated by the following claims rather than the above description, and it should be construed that all changes or modifications derived from the meaning and scope of the claims and their equivalents are included in the scope of the invention.
Claims (16)
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| KR100730321B1 (en) * | 2005-09-30 | 2007-06-19 | 한국콜마 주식회사 | Two-part cosmetic composition for lifting in the form of a patch, preparation method and use thereof |
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