WO2014007265A1 - Pesticidal composition and pest control method - Google Patents
Pesticidal composition and pest control method Download PDFInfo
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- WO2014007265A1 WO2014007265A1 PCT/JP2013/068180 JP2013068180W WO2014007265A1 WO 2014007265 A1 WO2014007265 A1 WO 2014007265A1 JP 2013068180 W JP2013068180 W JP 2013068180W WO 2014007265 A1 WO2014007265 A1 WO 2014007265A1
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- Prior art keywords
- compound
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- phostiazate
- organophosphorus
- clothianidin
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
Definitions
- the present invention relates to a pesticidal composition containing an organophosphorus compound (A) and a compound (B) as active ingredients, which will be described later, and a pest control method using the pesticidal composition.
- Insecticide / nematicide composition comprising at least one organophosphorus nematicide selected from the group consisting of phostiazate, imisiafos and kazusafos and a specific organophosphorus pesticide as active ingredients
- Patent Document 1 an organic phosphorus compound represented by a specific chemical structural formula and at least one of an organic phosphorus compound, a carbamate compound, a pyrethroid compound, a urea compound, a sulfone compound, or an N-pyridylaniline compound are effective.
- Patent Document 2 discloses a harmful animal control agent contained as a component.
- Patent Document 3 discloses an agricultural and horticultural insecticide composition containing, as an active ingredient, a phostiazate and a neonicotinoid compound such as imidacloprid, nitenpyram, acetamiprid and the like, which has improved the simultaneous control of nematodes and above-ground pests. It is disclosed.
- An object of the present invention is to provide a highly active and long-lasting pesticidal composition having a broad spectrum of pesticidal insects, and a comprehensive labor-saving control method using the pesticidal composition. That is.
- the present inventors have made various studies and obtained the knowledge that a highly active pesticidal composition can be obtained by combining specific compounds, thereby completing the present invention.
- the present invention relates to at least one organophosphorus compound (A) (hereinafter abbreviated as Compound A) selected from the group consisting of phostiazates and imisiaphos (both generic names), clothianidin, dinotefuran, thiamethoxam, tefluthrin, silafluophene.
- a pesticidal composition containing as an active ingredient at least one compound (B) (hereinafter abbreviated as Compound B) selected from the group consisting of chlorofluazuron, flufenoxuron and teflubenzuron (generally named) (Excluding the combination of phostiazate and teflutrin).
- the present invention also relates to a method for controlling a pest by applying an effective amount of the insecticide of the composition.
- the pesticidal composition of the present invention has a synergistic action in controlling pests, and has a high control activity, a long lasting effect, and an immediate effect, compared to using each drug alone, Effective for pest control.
- Compound A of the present invention includes both optically active substances and racemates.
- clothianidin, dinotefuran and thiamethoxam are neonicotinoid compounds.
- Tefluthrin and silafluofen are pyrethroid compounds.
- Chlorfluazuron, flufenoxuron and teflubenzuron are benzoylurea compounds.
- the mixing ratio of Compound A and Compound B must be appropriately adjusted according to the formulation form, application method, weather conditions, the type of pests to be controlled, the occurrence status, etc., but cannot be determined unconditionally.
- the weight ratio is 1:
- the ratio is 0.01 to 1:20, preferably 1: 0.04 to 1:10.
- the mixing ratio is preferably from 1: 0.01 to 1:10, more preferably from 1: 0.02 to 1: 7.
- the pesticidal composition of the present invention can be applied at an active ingredient concentration of, for example, 10 to 10,000 ppm, desirably 100 to 5,000 ppm.
- the active ingredient concentration can be appropriately adjusted according to the mixing ratio of Compound A and Compound B, the preparation form, the application method, the weather conditions, the type of pests to be controlled and the state of occurrence.
- the application rate (effective amount of insecticidal insecticide) of Compound A and Compound B per unit area cannot be determined uniformly as described above.
- Compound A is 500 to 10,000 g / ha, preferably 750 to 5,000 g / ha.
- Compound B is 100 to 10,000 g / ha, desirably 200 to 5,000 g / ha.
- either application to a pest or application to a habitat of the pest may be selected.
- Application to soil can also be selected.
- various spraying forms such as a soil mixing process, a planting process, a planting process, and an irrigation process, can be selected.
- a spraying form such as a dipping process, a coating process, a dressing process, or the like for crop seeds or bulbs.
- an effective amount of the insecticidal insects of Compound A and Compound B can be applied according to the above-mentioned spraying form, and in this case, Compound A and Compound B may be applied simultaneously, or either one of them. The other may be applied after application.
- the pesticidal composition of the present invention includes nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, diptera pests, hymenoptera It is possible to control various insect pests such as eye pests, octopus pests, lice pests, and the like, Hemiptera pests, Paramecium, centipedes, millipedes, and the like.
- the pesticidal composition of the present invention is a pest that particularly harms agricultural and horticultural crops and trees in the soil, and a pest that harms agricultural and horticultural crops and tree seeds, such as the above nematodes, isopods, and pods. It is effective in controlling eye pests, lepidopterous insects, gastropods, straight-eyed insects, plant parasitic mites, hemiptera insects, and the like.
- this method can provide a control method that reduces the amount of application of the active ingredient and the number of times it is applied and has a long lasting effect. Specific examples of various pests are shown below.
- Nematode nematode (Pratylenchus coffeae), Nepalese nematode (Pratylenchus fallax), Chanegesu nematode (Pratylenchus loosi), Nematode nematode (Pratylenchus vulnus), etc .; Heterodera glycines), cyst nematodes such as potato cyst nematodes (Globodera rostochiensis); Aferenchoides, such as Ishku nematodes; Wasenchus; Pin nematodes; Longidols; Trichodols; Strawberry mesenchus; And the like.
- ⁇ Isopods include dandruff beetles, brackish beetles and the like.
- Coloptera Cone root worms such as Western corn root worm (Diabrotica virgifera virgifera), Southern corn root worm (Diabrotica undecimpunctata howardi); Bill (Sitophiluszeamais), weevil (Echinocnemus squameus), aphid weevil (Cylas formicarius), rice weevil (Lissorhoptrus oryzophilus), alfalfa weevil (Hypera pastica), chives okinawensis), Agriotes ogurae fusciollis, bark beetles such as Melanotus legatus; Tenebrio molitor, Kokunust Carabid beetles such as doki (Tribolium ⁇ ⁇ castaneum); leaf beetles (Aulacophora femoralis), beetle leaf beetle (Phyllotreta striolata), Colorado potato beetle (Leptin
- Lepidopterous insect pests include Chilo suppressalis, Cnaphalocrocis medinalis, European corn borer (Ostrinia nubilalis), Shibatatsuga (Parapediasia ⁇ teterrella), Cotton moth (Notarcha derogata) Spodoptera litura, Pseudaletia separata, Mamestra brassicae, Agrotis silsil, Trichopulcia, Heliotis, Helicoberpa, etc .; Tortoises such as Grapholita molesta and Cydia pomonella; Sinkigas such as Carposina niponensis; Anemone such as Rionetia; Limantria and Upproct Species of the genus Isu; Suga, such as Plutellaxylostella; Swab, such as Pectinophorapigossypiella; Hitriga, such as Hyphantria cunea, Tinea transluc
- ⁇ Gastropods include maimai and slugs.
- insects of the order Diptera examples include grasshopper, grasshopper, German cockroach (Blattella ⁇ germanica), black cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta ⁇ americana), black cockroach (Periplaneta brunnea), and British cockroach (Blatta orientalis).
- plant parasitic ticks examples include urticae, spider mites, citrus spider mites, and ticks.
- Thrips palmi Thrips ⁇ tabaci
- Thrips ⁇ ⁇ hawaiiensis Scirtothrips dorsalis
- Hella thrips An example of this species is Ponticulothrips diospyrosi.
- Culex pipiens lenpallens Culex hytritaeniorhynchus, etc .
- Aedes genus such as Aedes aegypti, Aedes albopictus
- Anopheles sinensis genus House flies such as Muscina stabulans; Black flies; Drosophila; Butterfly species; flyfish; abu species;
- arachnid pest examples include ants; wasps; hornets; hornets; bees such as Athalia rosae; and bees such as Arge pagana.
- insect pest examples include cat fleas (Ctenocephalides felis), dog fleas (Ctenocephalides canis), and human fleas (Pulex irritans).
- lice insects examples include white lice (Pediculus humanus corporis), white lice (Phthirus pubis), and human lice.
- insects of the order Lepidoptera examples include Yamato termites and termites.
- Hemiptera pests include larvae (Laodelphax striatellus), brown planthoppers (Nilaparvata lugens), white planthoppers (Sogatella furcifera), etc .; Nephotettix cincticeps; gossypii), peach aphid (Myzus persicae), citrus aphid (Aphis citricola), black-headed aphid (Lipaphis pserudobrassicae), nasipolio aphid (Nippolachnus piri), commuter aphid (Toxoptera Aphids such as Nezara ⁇ antennata, Cletus punctiger, Riptortus clavetus, Platia stali, etc .; Onshi Whiteflies such as whitefly (Trialeurodes vaporariorum), tobacco whitefly (Bemisia tabaci), silverleaf whitefly (Bemisia
- rotifer examples include Porcellio ⁇ scaber, Porcellionides pruinosus, Armadillidium vulgare, and the like.
- Centipedes include Tobism cadets (Scolopendra subspinipes japonica), Akas cadets (Scolopendra subspinipes multidens), Gezi (Thereuopoda hilgendorfi), and the like.
- millipede there are a Japanese millipede (Oxidus gracilis), an Obibabaya millipede (Parafontarialaminata laminata), and the like.
- the insecticidal composition of the present invention is used in combination with other agricultural chemicals such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc. In this case, a better effect may be exhibited.
- insecticides acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc.
- insecticides acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc.
- insecticidal composition of the present invention is used in combination with other agricultural chemicals such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc.
- a better effect may be exhibited.
- the range of applicable insect pests, the timing of chemical treatment, and insecticidal activity may be improved in
- the insecticidal composition of the present invention comprises compound A or compound B, which is an active ingredient, blended with various adjuvants in accordance with a conventional agricultural chemical formulation method, and powder, fine granules F, fine granules, granules, granules Wettable powders, wettable powders, tablets, pills, capsules (including forms packaged with water-soluble film), microcapsules, aqueous suspensions, oily suspensions, microemulsion formulations, suspoemulsion formulations,
- the preparations can be prepared and applied in various forms such as aqueous solvents, emulsions, solutions, pastes and aerosols.
- the soil admixing treatment, the planting hole treatment, and the grooving treatment in the form of powder, fine granule F, fine granule, granule tablet, or pill.
- the irrigation treatment is desirably performed in the form of a granulated wettable powder, wettable powder, microcapsule, aqueous suspension, oily suspension, aqueous solvent or liquid.
- Compound A and Compound B may be mixed together to prepare the preparation, or they may be prepared separately and mixed at the time of application.
- Adjuvants used in the formulation include kaolinite, sericite, diatomaceous earth, slaked lime, calcium carbonate, talc, white carbon, kaolin, bentonite, clay, sodium carbonate, sodium bicarbonate, sodium sulfate, zeolite, alumina, sulfur powder, starch, activated carbon Solid carriers such as soy flour, wheat flour, wood flour, fish flour, milk powder; water, toluene, xylene, trimethylbenzene, tetramethylbenzene, cyclohexane, solvent naphtha, acetone, methyl ethyl ketone, dioxane, tetrahydrofuran, kerosene, kerosene, chloroform, Chlorobenzene, acetic acid ethyl ester, glycerin ester of fatty acid, acetonitrile, dimethyl sulfoxide, N, N-dimethylformamide, dimethylacet
- each component of these adjuvants can be used by appropriately selecting one or two or more types without departing from the object of the present invention.
- auxiliary agents they can be appropriately selected from those known in the art.
- various commonly used adjuvants such as extenders, thickeners, anti-settling agents, antifreeze agents, dispersion stabilizers, safeners, antifungal agents, foaming agents, disintegrants, binders, etc. should also be used.
- the blending ratio of the active ingredient and various adjuvants in the insecticidal composition of the present invention can be about 0.001: 99.999 to 95: 5, preferably about 0.005: 99.995 to 90:10 in terms of weight%.
- Various methods can be adopted as the application method of the insecticidal composition of the present invention, and they can be appropriately used according to various conditions such as application place, formulation form, kind of pest to be controlled and growth situation. For example, the following methods are mentioned. 1. Compound A and Compound B are mixed together, and the preparation prepared is applied as it is. 2. Compound A and Compound B are mixed together, and the preparation prepared is diluted to a prescribed concentration with water, etc., and applied with various spreading agents (surfactant, vegetable oil, mineral oil, etc.) as necessary. To do. 3. Compound A and compound B are prepared separately and applied as they are. 4).
- the pesticide composition and the pest control method of the present invention have a synergistic effect on pest control.
- This synergistic action is based on a synergistic effect that cannot be predicted from various pest control properties possessed by each drug, and the usefulness of the present invention is more effective than the use of each drug alone.
- the pest control power in the soil is clearly enhanced, and an immediate effect may be imparted.
- the activity expected from the combination of the two active ingredients can be calculated based on the Colby equation (see Colby R S.R., “Weed”, Vol. 15, pages 20-22, 1967).
- the organophosphorus compound (A) is a phosphate thiazate, and the compound (B) is at least one benzoylurea compound selected from the group consisting of chlorfluazuron, flufenoxuron and teflubenzuron, (1) A pesticidal composition according to claim 1.
- the organophosphorus compound (A) is imisiaphos, and the compound (B) is at least one benzoylurea compound selected from the group consisting of chlorfluazuron, flufenoxuron, and teflubenzuron, (1)
- Pests are nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, diptera pests, hymenoptera pests, relics
- the pest is at least one selected from the group consisting of nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, and hemiptera pests
- the method of (20) The method according to (21), wherein the pest is at least one selected from the group consisting of nematodes, Coleoptera, Lepidoptera pests, and plant parasitic mites.
- the organophosphorus compound (A) is a phostiazate, and the compound (B) is at least one neonicotinoid compound selected from the group consisting of clothianidin, dinotefuran and thiamethoxam (13) to (23) The method described in 1.
- Test example 1 1 liter of sand loam mixed with steam-sterilized paddy soil and sand at a volume ratio of 1: 1 was placed in a 1 / 1,000,000 ha pot, and a predetermined amount of reagent was added and mixed. Immediately after the drug addition, 500 ml of soil contaminated with sweet potato root nematode (Meloidogyne incognita) was inoculated into each pot, and after mixing well, tomato (cultivar: yellow pair) seedlings were transplanted.
- sweet potato root nematode Malignant nematode
- Test example 3 Sand loam soil in which sand, non-sterile soil and sterilized soil were mixed at a volume ratio of 1: 1: 1 was placed in a 1 / 500,000 ha pot, and a predetermined amount of reagent was thoroughly mixed. There, transplanted 3 leaf stage seedlings of cabbage (variety: Okina), raised in the greenhouse for 11 days, cut the 4th leaf of cabbage, inoculated 10 second-instar larvae of Spodoptera litura, and survived 4 days later The number of individuals was investigated, and the control value was determined in the same manner as in Test Example 2. The test was conducted in triplicate. The test results are shown in Table 5 in terms of control value. Moreover, the theoretical value calculated
- Test example 4 Phosthiazate granules and clothianidin granules were mixed so that the amount of the active ingredient was a predetermined amount, and the mixture was sprinkled on the soil surface of the field and mixed well using a small rotary.
- the radish seeds were sown, and after 36 days of treatment, the degree of damage to the roots by larvae of the hornbill beetle was investigated according to the degree, and the degree of damage was determined by the following formula.
- the test results are shown in Table 6 in terms of control value.
- the theoretical values determined by Colby's formula are shown in parentheses in Table 6.
- the present invention it is possible to provide a pesticidal composition having a broad spectrum of pesticidal insects, a high activity, a reduced application amount of an active ingredient, and a long lasting effect.
- the pest control method using the pesticidal composition of the present invention is useful in the field of agriculture and horticulture, such as being able to control pests that inhabit the soil and pests that inhabit the above-ground part with a single chemical application. is there. It should be noted that the entire contents of the specification, claims, and abstract of Japanese Patent Application No. 2012-149204 filed on July 3, 2012 are incorporated herein as the disclosure of the specification of the present invention. Is.
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Description
本発明は、後記する、有機リン系化合物(A)と化合物(B)とを有効成分として含有する殺害虫性組成物、及び該殺害虫性組成物を用いた害虫の防除方法に関する。 The present invention relates to a pesticidal composition containing an organophosphorus compound (A) and a compound (B) as active ingredients, which will be described later, and a pest control method using the pesticidal composition.
ホスチアゼート、イミシアホス及びカズサホスからなる群から選ばれる少なくとも1種の有機リン系殺線虫剤と、特定の有機リン系殺虫剤とを有効成分として含有することを特徴とする殺虫・殺線虫剤組成物が特許文献1に開示されている。
また、特定の化学構造式で表される有機リン系化合物と、有機リン系化合物、カーバメート系化合物、ピレスロイド系化合物、ウレア系化合物、スルフォン系化合物又はN-ピリジルアニリン系化合物の少なくとも一種とを有効成分として含有する有害動物防除剤が特許文献2に開示されている。
さらに、ホスチアゼートと、イミダクロプリド、ニテンピラム、アセタミプリド等のネオニコチノイド系化合物とを有効成分として含有し、線虫と地上部害虫の同時防除性を高めた農園芸用殺虫剤組成物が特許文献3に開示されている。
Insecticide / nematicide composition comprising at least one organophosphorus nematicide selected from the group consisting of phostiazate, imisiafos and kazusafos and a specific organophosphorus pesticide as active ingredients A product is disclosed in Patent Document 1.
In addition, an organic phosphorus compound represented by a specific chemical structural formula and at least one of an organic phosphorus compound, a carbamate compound, a pyrethroid compound, a urea compound, a sulfone compound, or an N-pyridylaniline compound are effective. Patent Document 2 discloses a harmful animal control agent contained as a component.
Furthermore, Patent Document 3 discloses an agricultural and horticultural insecticide composition containing, as an active ingredient, a phostiazate and a neonicotinoid compound such as imidacloprid, nitenpyram, acetamiprid and the like, which has improved the simultaneous control of nematodes and above-ground pests. It is disclosed.
現在、数多くの殺害虫性組成物が開発され使用されているが、害虫を防除するには必ずしも十分でない場合があり、高活性な殺害虫性組成物の出現が望まれている。特に、土壌に施用したときに、土壌中に生息する害虫、並びに、地上部に生息する害虫を同時に防除できる高活性な殺害虫性組成物の出現が望まれている。
本発明の目的は、幅広い殺害虫スペクトルを持ち、高活性な、持続効果の長い殺害虫性組成物、及び該殺害虫性組成物を用いた、総合的に省力化された防除方法を提供することである。
At present, many pesticidal compositions have been developed and used. However, the pesticidal compositions may not always be sufficient for controlling the pests, and the emergence of highly active pesticidal compositions is desired. In particular, when applied to soil, there is a demand for the appearance of a highly active pesticidal composition that can simultaneously control pests that inhabit the soil and pests that inhabit the ground.
An object of the present invention is to provide a highly active and long-lasting pesticidal composition having a broad spectrum of pesticidal insects, and a comprehensive labor-saving control method using the pesticidal composition. That is.
本発明者らは種々検討を重ね、特定の化合物を組合せることにより高活性な殺害虫性組成物が得られるとの知見を得て、本発明を完成した。 The present inventors have made various studies and obtained the knowledge that a highly active pesticidal composition can be obtained by combining specific compounds, thereby completing the present invention.
即ち本発明は、ホスチアゼート及びイミシアホス(いずれも一般名)からなる群より選ばれる少なくとも1種の有機リン系化合物(A)(以下、化合物Aと略す)と、クロチアニジン、ジノテフラン、チアメトキサム、テフルトリン、シラフルオフェン、クロルフルアズロン、フルフェノクスロン及びテフルベンズロン(いずれも一般名)からなる群より選ばれる少なくとも1種の化合物(B)(以下、化合物Bと略す)とを有効成分として含有する殺害虫性組成物(但し、ホスチアゼートとテフルトリンとの組合せを除く)に関する。
また、本発明は、前記組成物の殺害虫有効量を施用して害虫を防除する方法に関する。
That is, the present invention relates to at least one organophosphorus compound (A) (hereinafter abbreviated as Compound A) selected from the group consisting of phostiazates and imisiaphos (both generic names), clothianidin, dinotefuran, thiamethoxam, tefluthrin, silafluophene. , A pesticidal composition containing as an active ingredient at least one compound (B) (hereinafter abbreviated as Compound B) selected from the group consisting of chlorofluazuron, flufenoxuron and teflubenzuron (generally named) (Excluding the combination of phostiazate and teflutrin).
The present invention also relates to a method for controlling a pest by applying an effective amount of the insecticide of the composition.
本発明の殺害虫性組成物は、害虫防除において共力的作用を有し、各薬剤を単独で使用するよりも、高い防除活性と、持続効果が長く、かつ即効的な効果を有し、害虫防除等に有効である。 The pesticidal composition of the present invention has a synergistic action in controlling pests, and has a high control activity, a long lasting effect, and an immediate effect, compared to using each drug alone, Effective for pest control.
ホスチアゼート(fosthiazate)及びイミシアホス(imicyafos)には、各々光学異性体が存在するが、本発明の化合物Aとしては、光学活性体、ラセミ体の双方が含まれる。 Optical isomers exist in fosthiazate and imiciafos, respectively. Compound A of the present invention includes both optically active substances and racemates.
本発明の化合物Bにおいて、クロチアニジン(clothianidin)、ジノテフラン(dinotefuran)及びチアメトキサム(thiamethoxam)はネオニコチノイド系化合物である。テフルトリン(tefluthrin)及びシラフルオフェン(silafluofen)はピレスロイド系化合物である。クロルフルアズロン(chlorfluazuron)、フルフェノクスロン(flufenoxuron)及びテフルベンズロン(teflubenzuron)はベンゾイルウレア系化合物である。 In the compound B of the present invention, clothianidin, dinotefuran and thiamethoxam are neonicotinoid compounds. Tefluthrin and silafluofen are pyrethroid compounds. Chlorfluazuron, flufenoxuron and teflubenzuron are benzoylurea compounds.
化合物Aと化合物Bの混合比率は、製剤形態、施用方法、気象条件、防除対象害虫の種類や発生状況などに応じ適宜調整する必要があり一概に定めることはできないが、例えば重量比で1:0.01~1:20であり、望ましくは1:0.04~1:10である。特に化合物Aがホスチアゼートであり、化合物Bがクロチアニジンの場合の混合比率は、重量比で1:0.01~1:10であるのが望ましく、1:0.02~1:7であるのがさらに望ましい。 The mixing ratio of Compound A and Compound B must be appropriately adjusted according to the formulation form, application method, weather conditions, the type of pests to be controlled, the occurrence status, etc., but cannot be determined unconditionally. For example, the weight ratio is 1: The ratio is 0.01 to 1:20, preferably 1: 0.04 to 1:10. In particular, when Compound A is phostiazate and Compound B is clothianidin, the mixing ratio is preferably from 1: 0.01 to 1:10, more preferably from 1: 0.02 to 1: 7.
本発明の殺害虫性組成物は、例えば10~10,000ppm、望ましくは100~5,000ppmの有効成分濃度で施用することができる。有効成分濃度は、化合物Aと化合物Bの混合比率、製剤形態、施用方法、気象条件、防除対象害虫の種類や発生状況などに応じ適宜調整することができる。
単位面積あたりの化合物Aと化合物Bの施用量(殺害虫有効量)は、前述と同様一概に定めることはできないが、例えば化合物Aは500~10,000g/ha、望ましくは750~5,000g/haであり、化合物Bは100~10,000g/ha、望ましくは200~5,000g/haである。
The pesticidal composition of the present invention can be applied at an active ingredient concentration of, for example, 10 to 10,000 ppm, desirably 100 to 5,000 ppm. The active ingredient concentration can be appropriately adjusted according to the mixing ratio of Compound A and Compound B, the preparation form, the application method, the weather conditions, the type of pests to be controlled and the state of occurrence.
The application rate (effective amount of insecticidal insecticide) of Compound A and Compound B per unit area cannot be determined uniformly as described above. For example, Compound A is 500 to 10,000 g / ha, preferably 750 to 5,000 g / ha. Compound B is 100 to 10,000 g / ha, desirably 200 to 5,000 g / ha.
本発明の殺害虫性組成物を施用する際は、害虫への施用又は害虫の生息場所への施用のいずれを選択してもよい。また、土壌への施用を選択することもできる。そして、土壌混和処理、植穴処理、植溝処理、潅注処理などのような種々の散布形態を選択することができる。
また、作物の種子や球根などに対する浸漬処理、塗布処理や、粉衣処理などのような散布形態を選択することもできる。また、本発明においては、化合物Aと化合物Bの殺害虫有効量を前述の散布形態に従って施用することができ、その際化合物Aと化合物Bは同時に施用してもよく、或はいずれか一方を施用した後に他方を施用してもよい。
When applying the insecticidal composition of the present invention, either application to a pest or application to a habitat of the pest may be selected. Application to soil can also be selected. And various spraying forms, such as a soil mixing process, a planting process, a planting process, and an irrigation process, can be selected.
Further, it is possible to select a spraying form such as a dipping process, a coating process, a dressing process, or the like for crop seeds or bulbs. In the present invention, an effective amount of the insecticidal insects of Compound A and Compound B can be applied according to the above-mentioned spraying form, and in this case, Compound A and Compound B may be applied simultaneously, or either one of them. The other may be applied after application.
本発明の殺害虫性組成物は、線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類、アザミウマ目害虫、双翅目害虫、膜翅目害虫、隠翅目害虫、シラミ目害虫、等翅目害虫、半翅目害虫、ワラジムシ類、ムカデ類、ヤスデ類などの各種害虫を防除することができる。
本発明の殺害虫性組成物は、特に農園芸作物および樹木などを土壌中で加害する害虫や、農園芸作物や樹木の種子を加害する害虫、例えば、前記線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類、半翅目害虫などの防除に有効である。
また、本発明の殺害虫性組成物を土壌に処理することにより、土壌中に生息する害虫、並びに、地上部に生息する害虫の同時防除が可能となる。また、この方法では、有効成分の施用量及び施用回数が低減され、且つ持続効果が長いため、総合的に省力化された防除方法が提供できる。
各種害虫の具体例を以下に示す。
The pesticidal composition of the present invention includes nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, diptera pests, hymenoptera It is possible to control various insect pests such as eye pests, octopus pests, lice pests, and the like, Hemiptera pests, Paramecium, centipedes, millipedes, and the like.
The pesticidal composition of the present invention is a pest that particularly harms agricultural and horticultural crops and trees in the soil, and a pest that harms agricultural and horticultural crops and tree seeds, such as the above nematodes, isopods, and pods. It is effective in controlling eye pests, lepidopterous insects, gastropods, straight-eyed insects, plant parasitic mites, hemiptera insects, and the like.
In addition, by treating the insecticidal composition of the present invention with soil, it is possible to simultaneously control pests that inhabit the soil and pests that inhabit the above-ground part. In addition, this method can provide a control method that reduces the amount of application of the active ingredient and the number of times it is applied and has a long lasting effect.
Specific examples of various pests are shown below.
線虫類としては、ミナミネグサレセンチュウ(Pratylenchus coffeae)、キタネグサレセンチュウ(Pratylenchus fallax)、チャネグサレセンチュウ(Pratylenchus loosi)、クルミネグサレセンチュウ(Pratylenchus vulnus)等のネグサレセンチュウ類;ダイズシストセンチュウ(Heterodera glycines)、ジャガイモシストセンチュウ(Globodera rostochiensis)等のシストセンチュウ類;キタネコブセンチュウ(Meloidogyne hapla)、サツマイモネコブセンチュウ(Meloidogyne incognita)等のネコブセンチュウ類;イネシンガレセンチュウ(Aphelenchoides besseyi)、イチゴセンチュウ(Aphelenchoides fragarieae)等のアフェレンコイデス類;イシュクセンチュウ類;ワセンチュウ類;ピンセンチュウ類;ロンギドルス類;トリコドルス類;イチゴメセンチュウ;マツノザイセンチュウなどが挙げられる。 As nematodes, Nematode nematode (Pratylenchus coffeae), Nepalese nematode (Pratylenchus fallax), Chanegesu nematode (Pratylenchus loosi), Nematode nematode (Pratylenchus vulnus), etc .; Heterodera glycines), cyst nematodes such as potato cyst nematodes (Globodera rostochiensis); Aferenchoides, such as Ishku nematodes; Wasenchus; Pin nematodes; Longidols; Trichodols; Strawberry mesenchus; And the like.
等脚類としては、ダンゴムシ、ワラジムシなどが挙げられる。 ¡Isopods include dandruff beetles, brackish beetles and the like.
鞘翅目害虫としては、ウエスタンコーンルートワーム(Diabrotica virgifera virgifera)、サザンコーンルートワーム(Diabrotica undecimpunctata howardi)等のコーンルートワーム類;ドウガネブイブイ(Anomala cuprea)、ヒメコガネ(Anomala rufocuprea)等のコガネムシ類;メイズウィービル(Sitophiluszeamais)、イネゾウムシ(Echinocnemus squameus)、アリモドキゾウムシ(Cylas formicarius)、イネミズゾウムシ(Lissorhoptrus oryzophilus)、アルファルファタコゾウムシ(Hypera pastica)、アズキゾウムシ(Callosobruchuys chienensis)等のゾウムシ類;オキナワカンシャクシコメツキ(Melanotus okinawensis)、トビイロムナボソコメツキ(Agriotes ogurae fusciollis)、クシコメツキ(Melanotus legatus)等のハリガネムシ類;チャイロコメノゴミムシダマシ(Tenebrio molitor)、コクヌストモドキ(Tribolium castaneum)等のゴミムシダマシ類;ウリハムシ(Aulacophora femoralis)、キスジノミハムシ(Phyllotreta striolata)、コロラドハムシ(Leptinotarsa decemlineata)等のハムシ類;ニジュウヤホシテントウ(Epilachna vigintioctopunctata)等のエピラクナ類;ナガシンクイムシ類;アオバアリガタハネカクシ(Paederus fuscipes)等が挙げられる。 Coleoptera: Cone root worms such as Western corn root worm (Diabrotica virgifera virgifera), Southern corn root worm (Diabrotica undecimpunctata howardi); Bill (Sitophiluszeamais), weevil (Echinocnemus squameus), aphid weevil (Cylas formicarius), rice weevil (Lissorhoptrus oryzophilus), alfalfa weevil (Hypera pastica), chives okinawensis), Agriotes ogurae fusciollis, bark beetles such as Melanotus legatus; Tenebrio molitor, Kokunust Carabid beetles such as doki (Tribolium ハ ム castaneum); leaf beetles (Aulacophora femoralis), beetle leaf beetle (Phyllotreta striolata), Colorado potato beetle (Leptinotarsa decemlineata), etc .; Examples include Paederus fuscipes.
鱗翅目害虫としては、ニカメイガ(Chilo suppressalis)、コブノメイガ(Cnaphalocrocis medinalis)、ヨーロピアンコーンボーラー(Ostrinia nubilalis)、シバツトガ(Parapediasia teterrella)、ワタノメイガ(Notarcha derogata)、ノシメマダラメイガ(Plodia interpunctella)等のメイガ類;ハスモンヨトウ(Spodoptera litura)、アワヨトウ(Pseudaletia separata)、ヨトウガ(Mamestra brassicae)、タマナヤガ(Agrotis ipsilon)、トリコプルシア属、ヘリオティス属、ヘリコベルパ属等のヤガ類;モンシロチョウ(Pierisrapae)等のシロチョウ類;アドキソフィエス属、ナシヒメシンクイ(Grapholita molesta)、コドリンガ(Cydia pomonella)等のハマキガ類;モモシンクイガ(Carposina niponensis)等のシンクイガ類;リオネティア属等のハモグリガ類;リマントリア属、ユープロクティス属等のドクガ類;コナガ(Plutellaxylostella)等のスガ類;ワタアカミムシ(Pectinophora gossypiella)等のキバガ類;アメリカシロヒトリ(Hyphantria cunea)等のヒトリガ類、イガ(Tinea translucens)、コイガ(Tineola bisselliella)等のヒロズコガ類等が挙げられる。 Lepidopterous insect pests include Chilo suppressalis, Cnaphalocrocis medinalis, European corn borer (Ostrinia nubilalis), Shibatatsuga (Parapediasia ワ teterrella), Cotton moth (Notarcha derogata) Spodoptera litura, Pseudaletia separata, Mamestra brassicae, Agrotis silsil, Trichopulcia, Heliotis, Helicoberpa, etc .; Tortoises such as Grapholita molesta and Cydia pomonella; Sinkigas such as Carposina niponensis; Anemone such as Rionetia; Limantria and Upproct Species of the genus Isu; Suga, such as Plutellaxylostella; Swab, such as Pectinophorapigossypiella; Hitriga, such as Hyphantria cunea, Tinea translucens, Tineola bisselli Hirosukoga and the like.
腹足類としてはマイマイ、ナメクジなどが挙げられる。 ¡Gastropods include maimai and slugs.
直翅目害虫としては、ケラ、バッタ、チャバネゴキブリ(Blattella germanica)、クロゴキブリ(Periplaneta fuliginosa)、ワモンゴキブリ(Periplaneta americana)、トビイロゴキブリ(Periplaneta brunnea)、トウヨウゴキブリ(Blatta orientalis)などが挙げられる。 Examples of the insects of the order Diptera include grasshopper, grasshopper, German cockroach (Blattella 、 germanica), black cockroach (Periplaneta fuliginosa), American cockroach (Periplaneta ト americana), black cockroach (Periplaneta brunnea), and British cockroach (Blatta orientalis).
植物寄生性ダニ類としては、ナミハダニ、ニセナミハダニ、ミカンハダニ、ネダニなどが挙げられる。 Examples of plant parasitic ticks include urticae, spider mites, citrus spider mites, and ticks.
アザミウマ目害虫としては、ミナミキイロアザミウマ(Thrips palmi)、ネギアザミウマ(Thrips tabaci)、ハナアザミウマ(Thrips hawaiiensis)、チャノキイロアザミウマ(Scirtothrips dorsalis)、ヒラズハナアザミウマ(Frankliniella intonsa)、ミカンキイロアザミウマ(Frankliniella occidentalis)、カキクダアザミウマ(Ponticulothrips diospyrosi)等が挙げられる。 The thrips of the order Thrips palmi, Thrips ハ tabaci, Thrips チ ャ hawaiiensis, Scirtothrips dorsalis, Hella thrips An example of this species is Ponticulothrips diospyrosi.
双翅目害虫としては、アカイエカ(Culex pipiens pallens)、コガタアカイエカ(Culex tritaeniorhynchus)等のイエカ類;Aedes aegypti、Aedes albopictus等のエーデス属;Anopheles sinensis等のアノフェレス属;ユスリカ類;イエバエ(Musca domestica)、オオイエバエ(Muscina stabulans)等のイエバエ類;クロバエ類;ニクバエ類;ヒメイエバエ類;タネバエ(Deliaplatura)、タマネギバエ(Delia antiqua)等のハナバエ類;マメハモグリバエ(Liriomyza trifolii)等のハモグリバエ類;ミバエ類;ショウジョウバエ類;チョウバエ類;ブユ類;アブ類;サシバエ類等が挙げられる。 As for Diptera, Culex pipiens lenpallens, Culex hytritaeniorhynchus, etc .; Aedes genus such as Aedes aegypti, Aedes albopictus; Anopheles sinensis genus; House flies such as Muscina stabulans; Black flies; Drosophila; Butterfly species; flyfish; abu species;
膜翅目害虫としては、アリ類;アシナガバチ類;スズメバチ類;アリガタバチ類;カブラハバチ(Athalia rosae)等のハバチ類;チュウレンジハバチ(Arge pagana)等のミフシハバチ類等が挙げられる。 Examples of the arachnid pest include ants; wasps; hornets; hornets; bees such as Athalia rosae; and bees such as Arge pagana.
隠翅目害虫としては、ネコノミ(Ctenocephalides felis)、イヌノミ(Ctenocephalides canis)、ヒトノミ(Pulex irritans)等が挙げられる。 Examples of the insect pest include cat fleas (Ctenocephalides felis), dog fleas (Ctenocephalides canis), and human fleas (Pulex irritans).
シラミ目害虫としては、コロモジラミ(Pediculus humanus corporis)、ケジラミ(Phthirus pubis)、ヒトジラミ等が挙げられる。 Examples of lice insects include white lice (Pediculus humanus corporis), white lice (Phthirus pubis), and human lice.
等翅目害虫としては、ヤマトシロアリ、イエシロアリなどが挙げられる。 Examples of the insects of the order Lepidoptera include Yamato termites and termites.
半翅目害虫としては、ヒメトビウンカ(Laodelphax striatellus)、トビイロウンカ(Nilaparvata lugens)、セジロウンカ(Sogatella furcifera)等のウンカ類;ツマグロヨコバイ(Nephotettix cincticeps)、タイワンツマグロヨコバイ(Nephotettix virescens)等のヨコバイ類;ワタアブラムシ(Aphis gossypii)、モモアカアブラムシ(Myzus persicae)、ミカンミドリアブラムシ(Aphis citricola)、ニセダイコンアブラムシ(Lipaphis pserudobrassicae)、ナシミドリオオアブラムシ(Nippolachnus piri)、コミカンアブラムシ(Toxoptera aurantii)、ミカンクロアブラムシ(Toxoptera ciidius)等のアブラムシ類;アオクサカメムシ(Nezara antennata)、ホソハリカメムシ(Cletus punctiger)、ホソヘリカメムシ(Riptortus clavetus)、チャバネアオカメムシ(Plautia stali)等のカメムシ類;オンシツコナジラミ(Trialeurodes vaporariorum)、タバココナジラミ(Bemisia tabaci)、シルバーリーフコナジラミ(Bemisia argentifolii)等のコナジラミ類;アカマルカイガラムシ(Aonidiella aurantii)、サンホーゼカイガラムシ(Comstockaspis perniciosa)、シトラススノースケール(Unaspis citri)、クワシロカイガラムシ(Pseudaulacaspis pentagona)、オリーブカタカイガラムシ(Saissetia oleae)、ミカンノカキカイガラムシ(Lepidosaphes beckii)、ルビーロウムシ(Ceroplastes rubens)、イセリヤカイガラムシ(Icerya purchasi)等のカイガラムシ類;グンバイムシ類;キジラミ類等が挙げられる。 Hemiptera pests include larvae (Laodelphax striatellus), brown planthoppers (Nilaparvata lugens), white planthoppers (Sogatella furcifera), etc .; Nephotettix cincticeps; gossypii), peach aphid (Myzus persicae), citrus aphid (Aphis citricola), black-headed aphid (Lipaphis pserudobrassicae), nasipolio aphid (Nippolachnus piri), commuter aphid (Toxoptera Aphids such as Nezara カ antennata, Cletus punctiger, Riptortus clavetus, Platia stali, etc .; Onshi Whiteflies such as whitefly (Trialeurodes vaporariorum), tobacco whitefly (Bemisia tabaci), silverleaf whitefly (Bemisia argentifolii); Scale insects such as scale insects (Pseudaulacaspis pentagona), olive scale insects (Saissetia oleae), citrus scale insects (Lepidosaphes beckii), ruby beetles (Ceroplastes rubens), Icerya purchasi, etc .; .
ワラジムシ類としては、ワラジムシ(Porcellio scaber)、ホソワラジムシ(Porcellionides pruinosus)、オカダンゴムシ(Armadillidium vulgare)等が挙げられる。 Examples of the rotifer include Porcellio ワ scaber, Porcellionides pruinosus, Armadillidium vulgare, and the like.
ムカデ類としては、トビズムカデ(Scolopendra subspinipes mutilans)、アオズムカデ(Scolopendra subspinipes japonica)、アカズムカデ(Scolopendra subspinipes multidens)、ゲジ(Thereuopoda hilgendorfi)等が挙げられる。 Centipedes include Tobism cadets (Scolopendra subspinipes japonica), Akas cadets (Scolopendra subspinipes multidens), Gezi (Thereuopoda hilgendorfi), and the like.
ヤスデ類としては、ヤケヤスデ(Oxidus gracilis)、オビババヤスデ(Parafontarialaminata laminata)等が挙げられる。 As the millipede, there are a Japanese millipede (Oxidus gracilis), an Obibabaya millipede (Parafontarialaminata laminata), and the like.
本発明の殺害虫性組成物は、他の農薬、例えば殺虫剤、殺ダニ剤、殺線虫剤、殺菌剤、抗ウイルス剤、誘引剤、除草剤、植物成長調整剤などと混用、併用することができ、この場合に一層優れた効果を示すことがある。例えば適用害虫の範囲、薬剤処理の時期、殺害虫活性等を、より好ましい方向へ改良できる場合がある。 The insecticidal composition of the present invention is used in combination with other agricultural chemicals such as insecticides, acaricides, nematicides, fungicides, antiviral agents, attractants, herbicides, plant growth regulators, etc. In this case, a better effect may be exhibited. For example, the range of applicable insect pests, the timing of chemical treatment, and insecticidal activity may be improved in a more preferable direction.
本発明の殺害虫性組成物は、有効成分である化合物A又は化合物Bを、通常の農薬の製剤方法に準じて各種補助剤と配合し、粉剤、微粒剤F、微粒剤、粒剤、顆粒水和剤、水和剤、錠剤、丸剤、カプセル剤(水溶性フィルムで包装する形態を含む)、マイクロカプセル剤、水性懸濁剤、油性懸濁剤、マイクロエマルジョン製剤、サスポエマルジョン製剤、水溶剤、乳剤、液剤、ペースト剤、エアゾール剤などの種々の形態に製剤調製し、施用することができる。すなわち、本発明の目的に適合するかぎり、通常の当該分野で用いられているあらゆる製剤形態にすることができる。
なお、前記した土壌への施用のうち、土壌混和処理、植穴処理及び植溝処理は、粉剤、微粒剤F、微粒剤、粒剤錠剤又は丸剤の製剤形態で行うのが望ましい。
また、潅注処理は、顆粒水和剤、水和剤、マイクロカプセル剤、水性懸濁剤、油性懸濁剤、水溶剤又は液剤の製剤形態で行うのが望ましい。
製剤調製に際しては、化合物Aと化合物Bとを一緒に混合し製剤調製しても、或はそれらを別々に製剤調製し施用時に混合してもよい。
The insecticidal composition of the present invention comprises compound A or compound B, which is an active ingredient, blended with various adjuvants in accordance with a conventional agricultural chemical formulation method, and powder, fine granules F, fine granules, granules, granules Wettable powders, wettable powders, tablets, pills, capsules (including forms packaged with water-soluble film), microcapsules, aqueous suspensions, oily suspensions, microemulsion formulations, suspoemulsion formulations, The preparations can be prepared and applied in various forms such as aqueous solvents, emulsions, solutions, pastes and aerosols. That is, as long as it meets the object of the present invention, it can be made into any pharmaceutical form usually used in the art.
In addition, among the application to the above-mentioned soil, it is desirable to perform the soil admixing treatment, the planting hole treatment, and the grooving treatment in the form of powder, fine granule F, fine granule, granule tablet, or pill.
In addition, the irrigation treatment is desirably performed in the form of a granulated wettable powder, wettable powder, microcapsule, aqueous suspension, oily suspension, aqueous solvent or liquid.
In preparation of the preparation, Compound A and Compound B may be mixed together to prepare the preparation, or they may be prepared separately and mixed at the time of application.
製剤に使用する補助剤としては、カオリナイト、セリサイト、珪藻土、消石灰、炭酸カルシウム、タルク、ホワイトカーボン、カオリン、ベントナイト、クレー、炭酸ナトリウム、重曹、芒硝、ゼオライト、アルミナ、硫黄粉末、澱粉、活性炭、大豆粉、小麦粉、木粉、魚粉、粉乳のような固形担体;水、トルエン、キシレン、トリメチルベンゼン、テトラメチルベンゼン、シクロヘキサン、ソルベントナフサ、アセトン、メチルエチルケトン、ジオキサン、テトラヒドロフラン、ケロシン、灯油、クロロホルム、クロロベンゼン、酢酸エチルエステル、脂肪酸のグリセリンエステル、アセトニトリル、ジメチルスルホキシド、N,N-ジメチルホルムアミド、ジメチルアセトアミド、N-メチル-2-ピロリドン、アルコール、エチレングリコールのような溶剤;脂肪酸塩、安息香酸塩、ポリカルボン酸塩、アルキル硫酸エステル塩、アルキル硫酸塩、アルキルアリール硫酸塩、アルキルジグリコールエーテル硫酸塩、アルコール硫酸エステル塩、アルキルスルホン酸塩、アルキルアリールスルホン酸塩、アリールスルホン酸塩、リグニンスルホン酸塩、アルキルジフェニルエーテルジスルホン酸塩、ポリスチレンスルホン酸塩、アルキルリン酸エステル塩、アルキルアリールリン酸塩、スチリルアリールリン酸塩、ポリオキシエチレンアルキルエーテル硫酸エステル塩、ポリオキシエチレンアルキルアリールエーテル硫酸塩、ポリオキシエチレンアルキルアリールエーテル硫酸エステル塩、ポリオキシエチレンアルキルエーテルリン酸塩、ポリオキシエチレンアルキルアリールリン酸エステル塩、ポリオキシエチレンアリールエーテルリン酸エステル塩、ナフタレンスルホン酸ホルマリン縮合物、アルキルナフタレンスルホン酸ホルマリン縮合物の塩のような陰イオン系の界面活性剤;ソルビタン脂肪酸エステル、グリセリン脂肪酸エステル、脂肪酸ポリグリセライド、脂肪酸アルコールポリグリコールエーテル、アセチレングリコール、アセチレンアルコール、オキシアルキレンブロックポリマー、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンアルキルアリールエーテル、ポリオキシエチレンスチリルアリールエーテル、ポリオキシエチレングリコールアルキルエーテル、ポリエチレングリコール、ポリオキシエチレン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、ポリオキシプロピレン脂肪酸エステルのような非イオン系の界面活性剤;オリーブ油、カポック油、ひまし油、シュロ油、椿油、ヤシ油、ごま油、トウモロコシ油、米ぬか油、落花生油、綿実油、大豆油、菜種油、亜麻仁油、きり油、液状パラフィンのような植物油や鉱物油などが挙げられる。これら補助剤の各成分は、本発明の目的から逸脱しないかぎり、1種又は2種以上を適宜選択して使用することができる。
また、前記した補助剤以外にも当該分野で知られたものの中から適宜選んで使用することもできる。例えば、増量剤、増粘剤、沈降防止剤、凍結防止剤、分散安定剤、薬害軽減剤、防黴剤、発泡剤、崩壊剤、結合剤などの通常使用される各種補助剤も使用することができる。
本発明の殺害虫性組成物における有効成分と各種補助剤との配合割合は、重量%比で0.001:99.999~95:5、望ましくは0.005:99.995~90:10程度とすることができる。
Adjuvants used in the formulation include kaolinite, sericite, diatomaceous earth, slaked lime, calcium carbonate, talc, white carbon, kaolin, bentonite, clay, sodium carbonate, sodium bicarbonate, sodium sulfate, zeolite, alumina, sulfur powder, starch, activated carbon Solid carriers such as soy flour, wheat flour, wood flour, fish flour, milk powder; water, toluene, xylene, trimethylbenzene, tetramethylbenzene, cyclohexane, solvent naphtha, acetone, methyl ethyl ketone, dioxane, tetrahydrofuran, kerosene, kerosene, chloroform, Chlorobenzene, acetic acid ethyl ester, glycerin ester of fatty acid, acetonitrile, dimethyl sulfoxide, N, N-dimethylformamide, dimethylacetamide, N-methyl-2-pyrrolidone, alcohol, ethylene glycol Solvents such as coal; fatty acid salts, benzoates, polycarboxylates, alkyl sulfates, alkyl sulfates, alkyl aryl sulfates, alkyl diglycol ether sulfates, alcohol sulfates, alkyl sulfonates, alkyls Aryl sulfonate, aryl sulfonate, lignin sulfonate, alkyl diphenyl ether disulfonate, polystyrene sulfonate, alkyl phosphate ester salt, alkyl aryl phosphate, styryl aryl phosphate, polyoxyethylene alkyl ether sulfate Ester salt, polyoxyethylene alkyl aryl ether sulfate, polyoxyethylene alkyl aryl ether sulfate ester, polyoxyethylene alkyl ether phosphate, polyoxyethylene alkyl aryl ester Anionic surfactants such as acid ester salts, polyoxyethylene aryl ether phosphate ester salts, naphthalene sulfonic acid formalin condensates, alkyl naphthalene sulfonic acid formalin condensates salts; sorbitan fatty acid esters, glycerin fatty acid esters, fatty acids Polyglyceride, fatty acid alcohol polyglycol ether, acetylene glycol, acetylene alcohol, oxyalkylene block polymer, polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene styryl aryl ether, polyoxyethylene glycol alkyl ether, polyethylene glycol, Polyoxyethylene fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene Nonionic surfactants such as Nglycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, polyoxypropylene fatty acid ester; olive oil, kapok oil, castor oil, palm oil, coconut oil, coconut oil, sesame oil, corn oil, rice bran oil , Peanut oil, cottonseed oil, soybean oil, rapeseed oil, linseed oil, cutting oil, vegetable oil and mineral oil such as liquid paraffin. Each component of these adjuvants can be used by appropriately selecting one or two or more types without departing from the object of the present invention.
In addition to the above-mentioned auxiliary agents, they can be appropriately selected from those known in the art. For example, various commonly used adjuvants such as extenders, thickeners, anti-settling agents, antifreeze agents, dispersion stabilizers, safeners, antifungal agents, foaming agents, disintegrants, binders, etc. should also be used. Can do.
The blending ratio of the active ingredient and various adjuvants in the insecticidal composition of the present invention can be about 0.001: 99.999 to 95: 5, preferably about 0.005: 99.995 to 90:10 in terms of weight%.
本発明の殺害虫性組成物の施用方法は、種々の方法を採用でき、施用場所、製剤形態、防除対象害虫の種類や生育状況などの各種条件に応じて適宜使い分けることができる。例えば以下のような方法が挙げられる。
1.化合物Aと化合物Bとを一緒に混合し、製剤調製したものをそのまま施用する。
2.化合物Aと化合物Bとを一緒に混合し、製剤調製したものを水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して施用する。
3.化合物Aと化合物Bとを別々に製剤調製し、各々をそのまま施用する。
4.化合物Aと化合物Bとを別々に製剤調製し、必要に応じて各々を水等で所定濃度に希釈し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して、各々施用する。
5.化合物Aと化合物Bとを別々に製剤調製したものを水等で所定濃度に希釈する時に混合し、必要に応じて各種展着剤(界面活性剤、植物油、鉱物油など)を添加して施用する。
Various methods can be adopted as the application method of the insecticidal composition of the present invention, and they can be appropriately used according to various conditions such as application place, formulation form, kind of pest to be controlled and growth situation. For example, the following methods are mentioned.
1. Compound A and Compound B are mixed together, and the preparation prepared is applied as it is.
2. Compound A and Compound B are mixed together, and the preparation prepared is diluted to a prescribed concentration with water, etc., and applied with various spreading agents (surfactant, vegetable oil, mineral oil, etc.) as necessary. To do.
3. Compound A and compound B are prepared separately and applied as they are.
4). Prepare compound A and compound B separately, dilute each with water to a prescribed concentration as necessary, and add various spreading agents (surfactant, vegetable oil, mineral oil, etc.) as necessary. Apply each.
5. Compound A and Compound B prepared separately are mixed when diluted to the prescribed concentration with water, etc., and added with various spreading agents (surfactant, vegetable oil, mineral oil, etc.) as necessary To do.
本発明の殺害虫性組成物及び害虫の防除方法は、害虫防除に関して共力的作用を有する。この共力的作用は、各薬剤の有する各種害虫防除特性からは予測し得ない相乗効果に基づくものであり、本発明の有用性は、各薬剤を単独で使用するよりも、害虫防除効果、特に土壌中の害虫防除力が明らかに増強され、即効的な効果が付与されることもある。2種の有効成分を組み合わせた場合の防除活性が、その2種の有効成分各々の防除活性から期待される防除活性よりも優れている場合、これを相乗効果という。2種の有効成分の組合せにより期待される活性は、コルビーの式(Colby S.R.、「Weed」15巻、20~22頁、1967年を参照)に基づいて計算することができる。 The pesticide composition and the pest control method of the present invention have a synergistic effect on pest control. This synergistic action is based on a synergistic effect that cannot be predicted from various pest control properties possessed by each drug, and the usefulness of the present invention is more effective than the use of each drug alone. In particular, the pest control power in the soil is clearly enhanced, and an immediate effect may be imparted. When the control activity when combining two active ingredients is superior to the control activity expected from the control activities of the two active ingredients, this is called a synergistic effect. The activity expected from the combination of the two active ingredients can be calculated based on the Colby equation (see Colby R S.R., “Weed”, Vol. 15, pages 20-22, 1967).
本発明の望ましい態様を以下に記載するが、本発明はこれらの記載に基づき限定して解釈されるものではない。
(1)ホスチアゼート及びイミシアホスからなる群より選ばれる少なくとも1種の有機リン系化合物(A)と、クロチアニジン、ジノテフラン、チアメトキサム、テフルトリン、シラフルオフェン、クロルフルアズロン、フルフェノクスロン及びテフルベンズロンからなる群より選ばれる少なくとも1種の化合物(B)とを有効成分として含有する殺害虫性組成物(但し、ホスチアゼートとテフルトリンとの組合せを除く)。
(2)有機リン系化合物(A)がホスチアゼートである、(1)に記載の殺害虫性組成物。
(3)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジン、ジノテフラン及びチアメトキサムからなる群より選ばれる少なくとも1種のネオニコチノイド系化合物である、(1)に記載の殺害虫性組成物。
(4)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジン又はチアメトキサムである、(1)に記載の殺害虫性組成物。
(5)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジンである、(1)に記載の殺害虫性組成物。
(6)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がチアメトキサムである、(1)に記載の殺害虫性組成物。
(7)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がシラフルオフェンである、(1)に記載の殺害虫性組成物。
(8)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロルフルアズロン、フルフェノクスロン及びテフルベンズロンからなる群より選ばれる少なくとも1種のベンゾイルウレア系化合物である、(1)に記載の殺害虫性組成物。
Preferred embodiments of the present invention are described below, but the present invention is not construed as being limited based on these descriptions.
(1) Selected from the group consisting of at least one organophosphorus compound (A) selected from the group consisting of phosphate thiazate and imisiaphos, clothianidin, dinotefuran, thiamethoxam, tefluthrin, silafluophene, chlorfluazuron, flufenoxuron and teflubenzuron A pesticidal composition containing at least one compound (B) as an active ingredient (except for the combination of phosthiazate and tefluthrin).
(2) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is phostiazate.
(3) The killing according to (1), wherein the organophosphorus compound (A) is a phostiazate and the compound (B) is at least one neonicotinoid compound selected from the group consisting of clothianidin, dinotefuran and thiamethoxam Insect composition.
(4) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is clothianidin or thiamethoxam.
(5) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is clothianidin.
(6) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is thiamethoxam.
(7) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is silafluophene.
(8) The organophosphorus compound (A) is a phosphate thiazate, and the compound (B) is at least one benzoylurea compound selected from the group consisting of chlorfluazuron, flufenoxuron and teflubenzuron, (1) A pesticidal composition according to claim 1.
(9)有機リン系化合物(A)がイミシアホスである、(1)に記載の殺害虫性組成物。
(10)有機リン系化合物(A)がイミシアホスであり、化合物(B)がクロチアニジン、ジノテフラン及びチアメトキサムからなる群より選ばれる少なくとも1種のネオニコチノイド系化合物である、(1)に記載の殺害虫性組成物。
(11)有機リン系化合物(A)がイミシアホスであり、化合物(B)がテフルトリン及びシラフルオフェンからなる群より選ばれる少なくとも1種のピレスロイド系化合物である、(1)に記載の殺害虫性組成物。
(12)有機リン系化合物(A)がイミシアホスであり、化合物(B)がクロルフルアズロン、フルフェノクスロン及びテフルベンズロンからなる群より選ばれる少なくとも1種のベンゾイルウレア系化合物である、(1)に記載の殺害虫性組成物。
(9) The pesticidal composition according to (1), wherein the organophosphorus compound (A) is imisiaphos.
(10) The killing according to (1), wherein the organophosphorus compound (A) is imisiaphos and the compound (B) is at least one neonicotinoid compound selected from the group consisting of clothianidin, dinotefuran and thiamethoxam Insect composition.
(11) The insecticidal composition according to (1), wherein the organophosphorus compound (A) is imisiaphos, and the compound (B) is at least one pyrethroid compound selected from the group consisting of tefluthrin and silafluophene. .
(12) The organophosphorus compound (A) is imisiaphos, and the compound (B) is at least one benzoylurea compound selected from the group consisting of chlorfluazuron, flufenoxuron, and teflubenzuron, (1) A pesticidal composition according to claim 1.
(13)ホスチアゼート及びイミシアホスからなる群より選ばれる少なくとも1種の有機リン系化合物(A)の殺害虫有効量と、クロチアニジン、ジノテフラン、チアメトキサム、テフルトリン、シラフルオフェン、クロルフルアズロン、フルフェノクスロン及びテフルベンズロンからなる群より選ばれる少なくとも1種の化合物(B)の殺害虫有効量とを施用して害虫を防除する方法(但し、ホスチアゼートとテフルトリンとの組合せを除く)。
(14)ホスチアゼート及びイミシアホスからなる群より選ばれる少なくとも1種の有機リン系化合物(A)の殺害虫有効量と、クロチアニジン、ジノテフラン、チアメトキサム、テフルトリン、シラフルオフェン、クロルフルアズロン、フルフェノクスロン及びテフルベンズロンからなる群より選ばれる少なくとも1種の化合物(B)の殺害虫有効量とを、害虫又は害虫の生息場所に施用して害虫を防除する、(13)に記載の方法(但し、ホスチアゼートとテフルトリンとの組合せを除く)。
(15)有機リン系化合物(A)の殺害虫有効量と、化合物(B)の殺害虫有効量とを、土壌に施用して害虫を防除する、(13)又は(14)に記載の方法。
(16)土壌混和処理、植穴処理、植溝処理又は潅注処理により土壌に施用して害虫を防除する、(15)に記載の方法。
(17)土壌混和処理により土壌に施用して害虫を防除する、(15)に記載の方法。
(18)有機リン系化合物(A)の殺害虫有効量と、化合物(B)の殺害虫有効量とを、土壌混和処理し、土壌に生息する害虫を防除し、作物を播種又は定植した後、更に作物に有機リン系化合物(A)及び化合物(B)を取り込ませて、作物の地上部に生息する害虫を防除する、(13)に記載の方法。
(19)作物の種子又は球根に対して、有機リン系化合物(A)の殺害虫有効量と、化合物(B)の殺害虫有効量とを浸漬処理、塗布処理又は粉衣処理することにより、土壌に施用して害虫を防除する、(13)~(15)に記載の方法。
(20)害虫が線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類、アザミウマ目害虫、双翅目害虫、膜翅目害虫、隠翅目害虫、シラミ目害虫、等翅目害虫、半翅目害虫、ワラジムシ類、ムカデ類及びヤスデ類からなる群から選択される少なくとも1種である、(13)~(19)に記載の方法。
(21)害虫が線虫類、等脚類、鞘翅目害虫、鱗翅目害虫、腹足類、直翅目害虫、植物寄生性ダニ類及び半翅目害虫からなる群から選択される少なくとも1種である、(20)の方法。
(22)害虫が線虫類、鞘翅目害虫、鱗翅目害虫及び植物寄生性ダニ類からなる群から選択される少なくとも1種である、(21)に記載の方法。
(23)土壌中に生息する害虫、並びに、地上部に生息する害虫を1回の薬剤施用で防除する、(13)~(22)に記載の方法。
(24)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジン、ジノテフラン及びチアメトキサムからなる群より選ばれる少なくとも1種のネオニコチノイド系化合物である、(13)~(23)に記載の方法。
(25)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジン又はチアメトキサムである、(13)~(23)に記載の方法。
(26)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がクロチアニジンである、(13)~(23)に記載の方法。
(27)有機リン系化合物(A)がホスチアゼートであり、化合物(B)がチアメトキサムである、(13)~(23)に記載の方法。
(13) A pesticidally effective amount of at least one organophosphorus compound (A) selected from the group consisting of phostiazate and imisiaphos, clothianidin, dinotefuran, thiamethoxam, tefluthrin, silafluophene, chlorfluazuron, flufenoxuron and teflubenzuron A method for controlling a pest by applying an effective amount of a pesticide of at least one compound (B) selected from the group consisting of (except for the combination of phostiazate and tefluthrin).
(14) A pesticidally effective amount of at least one organophosphorus compound (A) selected from the group consisting of phostiazate and imisiaphos, clothianidin, dinotefuran, thiamethoxam, tefluthrin, silafluophene, chlorfluazuron, flufenoxuron and teflubenzuron A method according to (13), wherein a pest or an insect pest habitat is applied to a pest or a pest habitat to control the pest by applying a pesticide effective amount of at least one compound (B) selected from the group consisting of: Excluding combination with).
(15) The method according to (13) or (14), wherein the insecticide effective amount of the organophosphorus compound (A) and the insecticide effective amount of the compound (B) are applied to soil to control the insect pests. .
(16) The method according to (15), wherein the method is applied to the soil by soil mixing treatment, planting hole treatment, grooving treatment or irrigation treatment to control pests.
(17) The method according to (15), wherein the method is applied to the soil by soil mixing treatment to control pests.
(18) After applying an effective amount of the organophosphorus compound (A) and the effective amount of the insecticide of the compound (B) to the soil, controlling the pests that inhabit the soil, and sowing or planting the crop Furthermore, the method according to (13), wherein the organic phosphorus compound (A) and the compound (B) are further incorporated into the crop to control pests that inhabit the above-ground part of the crop.
(19) By applying immersion treatment, coating treatment, or powdering treatment to the seeds or bulbs of the crop, the killing insect effective amount of the organophosphorus compound (A) and the killing insect effective amount of the compound (B), The method according to any one of (13) to (15), wherein the method is applied to soil to control pests.
(20) Pests are nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, thrips pests, diptera pests, hymenoptera pests, relics The method according to any one of (13) to (19), wherein the method is at least one selected from the group consisting of: eye pests, lice pests, isoptera pests, half-lepidopterous pests, rotifers, centipedes and millipedes.
(21) The pest is at least one selected from the group consisting of nematodes, isopods, Coleoptera pests, lepidopterous pests, gastropods, orthoptera pests, plant parasitic mites, and hemiptera pests The method of (20).
(22) The method according to (21), wherein the pest is at least one selected from the group consisting of nematodes, Coleoptera, Lepidoptera pests, and plant parasitic mites.
(23) The method according to any one of (13) to (22), wherein the pests that inhabit the soil and the pests that inhabit the above-ground part are controlled by one chemical application.
(24) The organophosphorus compound (A) is a phostiazate, and the compound (B) is at least one neonicotinoid compound selected from the group consisting of clothianidin, dinotefuran and thiamethoxam (13) to (23) The method described in 1.
(25) The method according to (13) to (23), wherein the organophosphorus compound (A) is phos thiazate and the compound (B) is clothianidin or thiamethoxam.
(26) The method according to (13) to (23), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is clothianidin.
(27) The method according to (13) to (23), wherein the organophosphorus compound (A) is phostiazate and the compound (B) is thiamethoxam.
次に本発明の実施例を記載するが、本発明はこれらの記載に限定して解釈されるものではない。
試験例1
蒸気滅菌水田土と砂とを容積比1:1で混合した砂壌土1リットルを、1/1,000,000haポットに入れ、所定量の供試薬剤を添加混合した。薬剤添加直後に、サツマイモネコブセンチュウ(Meloidogyne incognita)汚染土壌500ミリリットルを各々のポットに接種し、充分混和後トマト(品種:イエローペアー)苗を移植した。移植33~35日後に線虫のネコブ着生程度(0~100%着生)を肉眼で調査した。試験は2連制で行った。
試験結果として、薬剤無処理区のネコブ着生程度を100とした場合のネコブ着生指数を第1表~第3表に示す。また、前述のコルビーの式により求めた理論値を各表の( )内に示す。
Next, examples of the present invention will be described, but the present invention should not be construed as being limited to these descriptions.
Test example 1
1 liter of sand loam mixed with steam-sterilized paddy soil and sand at a volume ratio of 1: 1 was placed in a 1 / 1,000,000 ha pot, and a predetermined amount of reagent was added and mixed. Immediately after the drug addition, 500 ml of soil contaminated with sweet potato root nematode (Meloidogyne incognita) was inoculated into each pot, and after mixing well, tomato (cultivar: yellow pair) seedlings were transplanted. After 33 to 35 days from the transplantation, the degree of nematode formation of the nematode (0 to 100%) was examined with the naked eye. The test was conducted in a two-track system.
As a test result, Table 1 to Table 3 show the index values for the formation of the cat root when the degree of the root formation in the untreated section is 100. Moreover, the theoretical value calculated | required by the above-mentioned Colby type | formula is shown in () of each table | surface.
試験例2
蒸気滅菌水田土と砂とを容積比1:1で混合した砂壌土1リットルを、1/1,000,000haポットに入れ、所定量の供試薬剤を添加混合した。ナミハダニ(黄緑系)の成虫30頭を寄生させたナス(品種:千両2号)の苗を移植し、温室にて5日間育苗し、薬剤を各々のポットに接種した。薬剤処理14日後に、各ポットに寄生するナミハダニの頭数を調査した。試験は3連制で行った。試験の結果を第4表に防除価(%)で示した。また、コルビーの式により求めた理論値を第4表の( )内に示す。
なお、防除価(%)は下記の式により算出した。
防除価(%)=(1-(処理区の寄生虫数)/(無処理区の寄生虫数))×100
Test example 2
1 liter of sand loam mixed with steam-sterilized paddy soil and sand at a volume ratio of 1: 1 was placed in a 1 / 1,000,000 ha pot, and a predetermined amount of reagent was added and mixed. Seedlings of eggplant (variety: Senryo No. 2) infested with 30 adult spider mite (yellowish green) were transplanted, grown in a greenhouse for 5 days, and inoculated with each drug in each pot. Fourteen days after drug treatment, the number of nymph mite parasitic on each pot was examined. The test was conducted in triplicate. The test results are shown in Table 4 in terms of control value (%). The theoretical values determined by Colby's formula are shown in parentheses in Table 4.
The control value (%) was calculated by the following formula.
Control value (%) = (1− (number of parasites in treated area) / (number of parasites in untreated area)) × 100
試験例3
砂、非滅菌土及び滅菌土を容積比1:1:1で混合した砂壌土を、1/500,000haポットに入れ、所定量の供試薬剤を充分混和処理した。そこにキャベツ(品種:おきな)の3葉期苗を移植し、温室にて11日間育苗し、キャベツの第4葉目を切り、ハスモンヨトウの2齢幼虫各10頭を接種、4日後に生存個体数を調査し、試験例2と同様に防除価を求めた。試験は3連制で行った。試験の結果を第5表に防除価で示した。また、コルビーの式により求めた理論値を第5表中の( )内に示す。なお、ホスチアゼートとイミダクロプリドの組み合わせについては、比較例として試験を行った。
Test example 3
Sand loam soil in which sand, non-sterile soil and sterilized soil were mixed at a volume ratio of 1: 1: 1 was placed in a 1 / 500,000 ha pot, and a predetermined amount of reagent was thoroughly mixed. There, transplanted 3 leaf stage seedlings of cabbage (variety: Okina), raised in the greenhouse for 11 days, cut the 4th leaf of cabbage, inoculated 10 second-instar larvae of Spodoptera litura, and survived 4 days later The number of individuals was investigated, and the control value was determined in the same manner as in Test Example 2. The test was conducted in triplicate. The test results are shown in Table 5 in terms of control value. Moreover, the theoretical value calculated | required by Colby's formula is shown in () in Table 5. In addition, about the combination of a phostiazate and imidacloprid, the test was done as a comparative example.
試験例4
有効成分量が所定量となるように、ホスチアゼートの粒剤とクロチアニジンの粒剤を混合し、圃場の土壌表面に散粒し、小型ロータリーを用いて、十分混和した。ダイコン種子を播種し、処理36日後にキスジノミハムシ幼虫による根部の加害程度を程度別に調査し、次式により被害度を求めた。試験の結果を第6表に防除価で示した。また、コルビーの式により求めた理論値を第6表の( )内に示す。なお、ホスチアゼートの粒剤とイミダクロプリドの粒剤の組み合わせについては、比較例として試験を行った。
被害程度別(無:0、小:1、中:2、大:3、甚:4)
被害度={Σ(被害度指数×被害程度別調査個数)/(全調査個数×4)}×100
Test example 4
Phosthiazate granules and clothianidin granules were mixed so that the amount of the active ingredient was a predetermined amount, and the mixture was sprinkled on the soil surface of the field and mixed well using a small rotary. The radish seeds were sown, and after 36 days of treatment, the degree of damage to the roots by larvae of the hornbill beetle was investigated according to the degree, and the degree of damage was determined by the following formula. The test results are shown in Table 6 in terms of control value. The theoretical values determined by Colby's formula are shown in parentheses in Table 6. In addition, about the combination of the granule of a phostiazate and the granule of imidacloprid, it tested as a comparative example.
By damage level (None: 0, Small: 1, Medium: 2, Large: 3, Trap: 4)
Damage level = {Σ (Damage index × Number of surveys by degree of damage) / (Total number of surveys × 4)} × 100
本発明により、幅広い殺害虫スペクトルを持ち、高活性で、有効成分の施用量が低減され、且つ持続効果の長い殺害虫性組成物を提供することができる。
本発明の殺害虫性組成物を用いた防除方法は、土壌中に生息する害虫、地上部に生息する害虫を1回の薬剤施用で防除することが可能である等、農園芸分野において有用である。
なお、2012年7月3日に出願された日本特許出願2012-149204号の明細書、特許請求の範囲、及び要約書の全内容をここに引用し、本発明の明細書の開示として、取り入れるものである。
INDUSTRIAL APPLICABILITY According to the present invention, it is possible to provide a pesticidal composition having a broad spectrum of pesticidal insects, a high activity, a reduced application amount of an active ingredient, and a long lasting effect.
The pest control method using the pesticidal composition of the present invention is useful in the field of agriculture and horticulture, such as being able to control pests that inhabit the soil and pests that inhabit the above-ground part with a single chemical application. is there.
It should be noted that the entire contents of the specification, claims, and abstract of Japanese Patent Application No. 2012-149204 filed on July 3, 2012 are incorporated herein as the disclosure of the specification of the present invention. Is.
Claims (15)
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| CN201380000683.4A CN103429086B (en) | 2012-07-03 | 2013-07-02 | Composition for killing pests and method for controlling pests |
| EP13813755.9A EP2868198B1 (en) | 2012-07-03 | 2013-07-02 | Pesticidal composition comprising fosthiazate and clothianidin and pest control method |
| BR112014033117-0A BR112014033117B1 (en) | 2012-07-03 | 2013-07-02 | PESTICIDE COMPOSITION AND METHOD FOR PEST CONTROL |
| US14/402,171 US20150126475A1 (en) | 2012-07-03 | 2013-07-02 | Pesticidal composition and method for controlling pests |
| JP2014523754A JP6150796B2 (en) | 2012-07-03 | 2013-07-02 | Pesticide composition and pest control method |
| PH12014502591A PH12014502591B1 (en) | 2012-07-03 | 2014-11-20 | Pesticidal composition and method for controlling pests |
| ZA2015/00013A ZA201500013B (en) | 2012-07-03 | 2015-01-05 | Pesticidal composition and method for controlling pests |
| MA37824A MA37824B1 (en) | 2012-07-03 | 2015-02-02 | Pesticide composition and method of pest control |
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Also Published As
| Publication number | Publication date |
|---|---|
| KR20150035793A (en) | 2015-04-07 |
| BR112014033117A2 (en) | 2017-06-27 |
| JP6150796B2 (en) | 2017-06-21 |
| EP2868198A4 (en) | 2016-01-20 |
| US20150126475A1 (en) | 2015-05-07 |
| BR112014033117B1 (en) | 2020-03-17 |
| EP2868198A1 (en) | 2015-05-06 |
| MA37824A1 (en) | 2016-04-29 |
| CN103429086A (en) | 2013-12-04 |
| ZA201500013B (en) | 2016-10-26 |
| CN103429086B (en) | 2016-09-28 |
| PH12014502591B1 (en) | 2021-06-23 |
| KR102015382B1 (en) | 2019-08-28 |
| PL2868198T3 (en) | 2017-08-31 |
| JPWO2014007265A1 (en) | 2016-06-02 |
| MA37824B1 (en) | 2016-11-30 |
| HUE031964T2 (en) | 2017-09-28 |
| EP2868198B1 (en) | 2017-02-22 |
| PH12014502591A1 (en) | 2015-01-12 |
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