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WO2014079771A1 - Mélanges pesticides - Google Patents

Mélanges pesticides Download PDF

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Publication number
WO2014079771A1
WO2014079771A1 PCT/EP2013/073900 EP2013073900W WO2014079771A1 WO 2014079771 A1 WO2014079771 A1 WO 2014079771A1 EP 2013073900 W EP2013073900 W EP 2013073900W WO 2014079771 A1 WO2014079771 A1 WO 2014079771A1
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WIPO (PCT)
Prior art keywords
methyl
compound
mixtures
chloro
phenyl
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English (en)
Inventor
Lutz Brahm
Burghard Liebmann
Ronald Wilhelm
Markus Gewehr
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BASF SE
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BASF SE
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
    • A01N63/20—Bacteria; Substances produced thereby or obtained therefrom
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

Definitions

  • the present invention relates to synergistic mixtures comprising as active components, 1 ) one fungicidal compound IA selected from the group consisting of
  • Inhibitors of complex III at Qo site coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fenoxy-strobin/flufenoxystrobin, fluoxastrobin, kresoxim- methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, trifloxystrobin, 2-[2-(2,5-dimethyl-phenoxymethyl)-phenyl]-3-methoxy- acrylic acid methyl ester and 2-(2-(3-(2,6-di-chlorophenyl)-1 -methyl-allylideneaminooxy- methyl)-phenyl)-2-methoxyimino-N-methyl-acetamide, pyribencarb, triclopyricarb/chloro- dincarb, famoxadone, fen
  • inhibitors of complex II e. g. carboxamides: benodanil, bixafen, boscalid, fen-furam, fluopyram, flutolanil, fluxapyroxad, furametpyr, isopyrazam, mepronil, oxycarboxin, pen- flufen, penthiopyrad, sedaxane, tecloftalam, thifluzamide, N-(4'-trifluoromethylthiobiphenyl- 2-yl)-3-difluoromethyl-1 -methyl-1 H-pyrazole-4-carboxamide, N-(2-(1 ,3,3-trimethyl-butyl)- phenyl)-1 ,3-dimethyl-5-fluoro-1 H-pyrazole-4-carboxamide, N-[9-(dichloromethylene)- 1 ,2,3,4-tetrahydro-1 ,4-methanonaphthalen-5-yl]-3-(
  • 4-carboxamide (benzovindiflupyr), 3-(difluoromethyl)-1 -methyl-N-(1 ,1 ,3-trimethylindan- 4-yl)pyrazole-4-carboxamide, 3-(trifluoromethyl)-1 -methyl-N-(1 ,1 ,3-trimethylindan-4-yl)- pyrazole-4-carboxamide, 1 ,3-dimethyl-N-(1 ,1 ,3-trimethylindan-4-yl)pyrazole-4-carbox- amide, 3-(trifluoromethyl)-1 ,5-dimethyl-N-(1 ,1 ,3-trimethylindan-4-yl)pyrazole-4-carbox- amide, 3-(difluoromethyl)-1 ,5-dimethyl-N-(1 ,1 ,3-trimethylindan-4-yl)pyrazole-4-carbox- amide, 1 ,3,5-trimethyl-N-(1 ,1 ,
  • respiration inhibitors diflumetorim, (5,8-difluoro-quinazolin-4-yl)- ⁇ 2-[2-fluoro- 4-(4-trifluoromethylpyridin-2-yloxy)-phenyl]-ethyl ⁇ -amine; nitrophenyl derivates: binapacryl, dinobuton, dinocap, fluazinam; ferimzone; organometal compounds: fentin salts, such as fentin-acetate, fentin chloride or fentin hydroxide; ametoctradin; and silthiofam;
  • DMI fungicides triazoles: azaconazole, bitertanol, bro- muconazole, cyproconazole, difenoconazole,diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, imibenconazole, ip- conazole, metconazole, myclobutanil, oxpoconazole, paclobutrazole, penconazole, pro- piconazole, prothioconazole, simeconazole, tebuconazole, tetraconazole, triadimefon, tri- adimenol, triticonazole, uniconazole, 1 -[rel-(2S;3R)-3-(2-chlorophenyl)-2
  • Delta14-reductase inhibitors aldimorph, dodemorph, dodemorph-acetate, fenpropimorph, tridemorph, fenpropidin, piperalin, spiroxamine;
  • phenylamides or acyl amino acid fungicides benalaxyl, benalaxyl-M, kiralaxyl, ofurace, oxadixyl;
  • tubulin inhibitors carbendazim, fuberidazole, thiabendazole; triazolopyrimidines: 5-chloro- 7-(4-methylpiperidin-1 -yl)-6-(2,4,6-trifluorophenyl)-[1 ,2,4]triazolo[1 ,5-a]pyrimidine;
  • cell division inhibitors diethofencarb, ethaboxam, pencycuron, fluopicolide, zox- amide, metrafenone, pyriofenone;
  • - methionine synthesis inhibitors cyprodinil, mepanipyrim, pyrimethanil;
  • blasticidin-S blasticidin-S, kasugamycin, kasugamycin hydrochloride- hydrate, mildiomycin, streptomycin, oxytetracyclin, polyoxine, validamycin A;
  • MAP / histidine kinase inhibitors fluoroimid, iprodione, procymidone, vinclozolin, fen- piclonil;
  • - Phospholipid biosynthesis inhibitors edifenphos, iprobenfos, pyrazophos, isoprothiolane;
  • lipid peroxidation dicloran, tecnazene, tolclofos-methyl, biphenyl, chloroneb, etridiazole;
  • - thio- and dithiocarbamates ferbam, maneb, metam, metiram, propineb, zineb, ziram; - organochlorine compounds: anilazine, chlorothalonil, folpet, dichlofluanid, dichlorophen, hexachlorobenzene, pentachlorphenole and its salts, phthalide, tolylfluanid, N-(4-chloro- 2-nitro-phenyl)-N-ethyl-4-methyl-benzenesulfonamide;
  • guanidine dodine, dodine free base, guazatine, guazatine- acetate, iminoctadine, iminoctadine-triacetate, iminoctadine-tris(albesilate), dithianon,
  • glucan synthesis validamycin, polyoxin B; melanin synthesis inhibitors: pyro- quilon, tricyclazole, carpropamid, dicyclomet, fenoxanil;
  • Ampelomyces quisqualis e.g. AQ 10® from Intrachem Bio GmbH & Co. KG, Germany
  • Aspergillus flavus e.g. AFLAGUARD® from Syngenta, CH
  • Aureobasidium pullulans e.g. BOTECTOR® from bio-ferm GmbH, Germany
  • Bacillus pumilus e.g. NRRL B-30087 in SONA-TA® and BALLAD® Plus from AgraQuest Inc., USA
  • Candida oleophila I-82 e.g.
  • ASPIRE® from Ecogen Inc., USA
  • Candida saitoana e.g. BIOCURE® (in mixture with ly- sozyme) and BIO-COAT® from Micro Flo Company, USA (BASF SE) and Arysta
  • Chi- tosan e.g. ARMOUR-ZEN from BotriZen Ltd., NZ
  • Clonostachys rosea f. catenulata also named Gliocladium catenulatum (e.g. isolate J1446: PRESTOP® from Verdera, Finland), Coniothyrium minitans (e.g. CONTANS® from Prophyta, Germany), Cryphonectria parasitica (e.g.
  • Endothia parasitica from CNICM, France Cryptococcus albidus (e.g. YIELD PLUS® from Anchor Bio-Technologies, South Africa), Fusarium oxysporum (e.g. BIO- FOX® from S.I.A.P.A., Italy, FUSACLEAN® from Natural Plant Protection, France), Metschnikowia fructicola (e.g. SHEMER® from Agrogreen, Israel), Microdochium dimerum (e.g. ANTIBOT® from Agrauxine, France), Phlebiopsis gigantea (e.g. ROTSOP® from Verdera, Finland), Pseudozyma flocculosa (e.g. SPORODEX® from Plant Products Co.
  • Cryptococcus albidus e.g. YIELD PLUS® from Anchor Bio-Technologies, South Africa
  • Fusarium oxysporum e.g. BIO- FOX® from S.I.A.P.A., Italy, F
  • Pythium oligandrum DV74 e.g. POLYVERSUM® from Remeslo SSRO, Bi- opreparaty, Czech Rep.
  • Reynoutria sachlinensis e.g. REGALIA® from Marrone Biolnno- vations, USA
  • Talaromyces flavus V1 17b e.g. PROTUS® from Prophyta, Germany
  • Trichoderma asperellum SKT-1 e.g. ECO-HOPE® from Kumiai Chemical Industry Co., Ltd., Japan
  • T. atroviride LC52 e.g. SENTINEL® from Agrimm Technologies Ltd, NZ
  • harzianum T-22 e.g. PLANTSHIELD® der Firma BioWorks Inc., USA
  • T. harzianum TH 35 e.g. ROOT PRO® from Mycontrol Ltd., Israel
  • T. harzianum T-39 e.g. TRICHODEX® and TRICHODERMA 2000® from Mycontrol Ltd., Israel and Makhteshim Ltd., Israel
  • T. harzianum and T. viride e.g. TRICHOPEL from Agrimm Technologies Ltd, NZ
  • T. harzianum ICC012 and T. viride ICC080 e.g. REMEDIER® WP from Isagro Ricerca, Italy
  • T. harzianum e.g. BINAB® from BINAB Bio-Innovation AB, Sweden
  • T. stromaticum e.g. TRICOVAB® from C.E.P.L.A.C., Brazil
  • T. virens GL-21 e.g. SOIL- GARD® from Certis LLC, USA
  • T. viride e.g. TRIECO® from Ecosense Labs. (India) Pvt. Ltd., Indien, BIO-CURE® F from T. Stanes & Co. Ltd., Indien
  • T. viride TV1 e.g. T. viride TV1 from Agribiotec srl, Italy
  • Ulocladium oudemansii HRU3 e.g. BOTRY-ZEN® from Bot- ry-Zen Ltd, NZ
  • BOTRY-ZEN® from Bot- ry-Zen Ltd, NZ
  • insecticidal compound IB selected from the group consisting of
  • M-1 A acetylcholine esterase inhibitors from the class of carbamates: aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbofuran, carbosulfan, ethio- fencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metol- carb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, and triazamate;
  • M-2.B fiproles phenylpyrazoles: ethiprole, fipronil, flufiprole, pyrafluprole, or pyriprole; M-2. Others: 4-[5-[3-chloro-5-(trifluoromethyl)phenyl]-5-(trifluoromethyl)-4H-isoxazol-3-yl]- N-[2-oxo-2-(2,2,2-trifluoroethylamino)ethyl]naphthalene-1 -carboxamide (known from WO 2007/079162), 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4H-isoxazol-3-yl]-2-methyl- N-[2-oxo-2-(2,2,2-trifluoroethylamino)ethyl]benzamide (known from WO 05/085216);
  • M-3 sodium channel modulators from the class of pyrethroids acrinathrin, allethrin, d-cis- trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bio- resmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gam- ma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenval
  • hydroprene hydroprene, kinoprene, methoprene, fenoxycarb or pyriproxyfen;
  • M-8 non-specific multi-site inhibitors methyl bromide and other alkyl halides, chloropicrin, sulfuryl fluoride, borax or tartar emetic;
  • M-9 selective homopteran feeding blockers pymetrozine, flonicamid, pyrifluquinazon, 2-(5- fluoro-3-pyridyl)-5-(6-pyrimidin-2-yl-2-pyridyl)thiazole hydrofluoride;
  • M-10 mite growth inhibitors clofentezine, hexythiazox, diflovidazin or etoxazole;
  • M-1 1 inhibitors of mitochondrial ATP synthase diafenthiuron, azocyclotin, cyhexatin, fenbutatin oxide, propargite, or tetradifon;
  • M-12 uncouplers of oxidative phosphorylation chlorfenapyr, DNOC, or sulfluramid;
  • M-13 nicotinic acetylcholine receptor channel blockers bensultap, cartap hydrochloride, thiocyclam, thiosultap sodium;
  • M-14 inhibitors of the chitin biosynthesis type 0 bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, tefluben- •on, triflumuron;
  • M-15 inhibitors of the chitin biosynthesis type 1 buprofezin;
  • M-16 moulting disruptors cyromazine
  • M-17 Ecdyson receptor agonists methoxyfenozide, tebufenozide, halofenozide, fufenozide or chromafenozide;
  • Mitochondrial complex III electron transport inhibitors hydramethylnon, acequinocyl, flometoquin, fluacrypyrim or pyriminostrobin;
  • M-20 Mitochondrial complex I electron transport inhibitors fenazaquin, fenpyroximate, py- rimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, or rotenone;
  • M-21 Voltage-dependent sodium channel blockers indoxacarb, metaflumizone or
  • M-23 Mitochondrial complex II electron transport inhibitors cyenopyrafen, cyflumetofen or pyflubumide;
  • M-24 Ryanodine receptor-modulators from the class of diamides flubendiamide, chlorantraniliprole (rynaxypyr), cyantraniliprole (cyazypyr), (R)-3-chloro-N1 - ⁇ 2-methyl-
  • M-26 Bacillus firmus (e.g. Bacillus strain CNCM 1-1582; WO 09/126473 and
  • one compound IC having plant growth regulator activity selected from the group consisting of:
  • Antiauxins clofibric acid, 2,3,5-tri-iodobenzoic acid;
  • - Ethylene modulators aviglycine, 1 -methylcyclopropene (1 -MCP), prohexadione, prohexa- dione calcium, trinexapac, trinexapac-ethyl;
  • abscisic acid abscisic acid, ancymidol, butralin, carbaryl, chlorphonium, chlorprop- ham, dikegulac, flumetralin, fluoridamid, fosamine, glyphosine, isopyrimol, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquat pentaborate, piproctanyl, prohy- drojasmon, propham, 2,3,5-tri-iodobenzoic acid;
  • chlormequat chlormequat chloride, daminozide, flurprimidol, mefluid- ide, paclobutrazol, tetcyclacis, uniconazole, metconazole;
  • Unclassified plant growth regulators / classification unknown amidochlor, benzofluor, buminafos, carvone, choline chloride, ciobutide, clofencet, cloxyfonac, cyanamide, cyclanilide, cycloheximide, cyprosulfamide, epocholeone, ethychlozate, ethylene, fenrida- zon, fluprimidol, fluthiacet, heptopargil, holosulf, inabenfide, karetazan, lead arsenate, methasulfocarb, pydanon, sintofen, triapenthenol; and
  • B. japonicum SEMIA 566 B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. japonicum E-109, B. japonicum 532C, B. japonicum
  • B. japonicum TA-1 1 B. japonicum G49, B. japonicum 3407, B. japonicum CPAC 15, B. japonicum USDA 3, B. japonicum USDA 31 , B. japonicum USDA 1 10, B. japonicum
  • Bradyrhizobium strains B. liaoningense, B. sp. (Arachis) CB1015, B. sp. (Arachis) SEMIA 6462, B. sp. (Arachis) SEMIA 6144, B. sp. (Arachis) SEMIA 6464, B. sp. (Arachis) USDA 3446, B. sp. (Lupinus) WU425, B. sp. (Lupinus) WSM471 , B. sp. (Lupinus) LL13, B. sp. (Lupinus) WSM4024, B. sp. (Vigna), B. sp. SEMIA 6144, B. sp. PNL01 ;
  • Sources for compound II are e.g. VAULT HP, "liquid inoculant for Peanut with Biostacked Technology, Becker Underwood (Bradyrhizobium sp. (Vigna)), VAULT HP “peat based inoculant for Peanut”, Becker Underwood (Bradyrhizobium sp. (Arachis)), HiStick peat based inoculant for Lupins, Becker Underwood (Bradyrhizobien sp. (lupinus).
  • VAULT HP liquid inoculant for Peanut with Biostacked Technology
  • Becker Underwood Bradyrhizobium sp. (Vigna)
  • VAULT HP peat based inoculant for Peanut
  • Becker Underwood Bradyrhizobium sp. (Arachis)
  • HiStick peat based inoculant for Lupins Becker Underwood (Bradyrhizobien sp. (lupinus).
  • the present invention also relates to mixtures, wherein compound II is selected from Bradyrhi- zobium elkanii and Bradyrhizobium liaoningense (B. elkanii and B. liaoningense), more preferably from B. elkanii. These mixtures are particularly suitable in soybean.
  • B. elkanii and liaoningense were cultivated using media and fermentation techniques known in the art, e.g. in yeast extract-mannitol broth (YEM) at 27°C for about 5 days.
  • YEM yeast extract-mannitol broth
  • B. elkanii strains are U-1301 and U-1302 (e.g. product Ni- troagin® Optimize from Novozymes Bio As S.A., Brazil or NITRASEC for soybean from LAGE y Cia, Brazil). These strains are especially suitable for soybean grown in Australia or South America, in particular in Brazil.
  • the present invention also relates to mixtures comprising compound II and comprising com- pound III, wherein compound II is selected from Bradyrhizobium elkanii and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • the present invention also relates to mixtures, wherein compound II is selected from Bradyrhizobium japonicum (B. japonicum). These mixtures are particularly suitable in soybean.
  • B. japon- icum strains were cultivated using media and fermentation techniques known in the art, e.g. in yeast extract-mannitol broth (YEM) at 27°C for about 5 days.
  • B. japonicum is not one of the strains TA-1 1 or 532c.
  • USDA 1 10 IITA 2121 , SEMIA 5032, RCR 3427, ARS 1-1 10, Nitragin 61A89; isolated from Glycine max in Florida in 1959, Serogroup 1 10; AppI Environ Microbiol 60, 940-94, 1994
  • USDA31 Nitragin 61A164; isolated from Glycine max in Wisoconsin in 1941 , USA, Serogroup 31
  • B. japonicum strain TA-1 1 (TA1 1 NOD + ) (NRRL B-18466) is i.a. described in US 5,021 ,076; AppI Environ Microbiol (1990) 56, 2399-2403 and commercially available as liq- uid inoculant for soybean (VAULT® NP, Becker Underwood, USA). Further B.
  • japonicum strains as example for compound III are described in US2012/0252672A. Further suitable and especially in Canada commercially available strain 532c (The Nitragin Company, Milwaukee, Wisconsin, USA, field isolate from Wisconsin; Nitragin strain collection No. 61A152; Can J Plant Sci 70 (1990), 661 -666).
  • strains have been re-classified as a novel species Bradyrhizobium elkanii, e.g. strain USDA 76 (Can. J. Microbiol., 1992, 38, 501 - 505).
  • B. japonicum strain is E-109 (variant of strain USDA 138, see e.g. Eur. J. Soil Biol. 45 (2009) 28-35; Biol Fertil Soils (201 1 ) 47:81-89, deposited at Agriculture Collection Laboratory of the Instituto de Microbiologia y Zoologia Agncola (IMYZA), Instituto Nacional de Tecnologi ' a Agropecuaria (INTA), Castelar, Argentina).
  • This strain is especially suitable for soybean grown in South America, in particular in Argentina.
  • Mixtures consisting of B. japonicum strain 532c and B. subtilis MBI 600 have been disclosed earlier in World J Microbiol Biotechnol (2012) 28, 2541 -2550.
  • the present invention also relates to mixtures consisting of as active ingredients compound II and comprising compound III, wherein compound III is selected from Bradyrhizobium japonicum (B. japonicum), provided that compound III is not B. japonicum TA-1 1 or 532c.
  • compound III is selected from Bradyrhizobium japonicum (B. japonicum), provided that compound III is not B. japonicum TA-1 1 or 532c.
  • the present invention also relates to mixtures comprising compound II and comprising compound III, wherein compound II is selected from Bradyrhizobium japonicum (B. japonicum) and compound III, wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • the present invention also relates to mixtures, wherein compound II is selected from Bradyrhizobium sp. (Arachis) (B. sp.
  • Arachis which shall describe the cowpea miscellany cross- inoculation group which includes inter alia indigenous cowpea bradyrhizobia on cowpea (Vigna unguiculata), siratro (Macroptilium atropurpureum), lima bean (Phaseolus lunatus), and peanut (Arachis hypogaea).
  • This mixture comprising compound II and B. sp. Arachis is especially suit- able for use in peanut, Cowpea, Mung bean, Moth bean, Dune bean, Rice bean, Snake bean and Creeping vigna, in particular peanut.
  • the present invention also relates to mixtures comprising compound II and comprising compound III, wherein compound II is selected from Bradyrhizobium sp. (Arachis) and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • the present invention also relates to mixtures, wherein compound II is selected from Bradyrhizobium sp. (Lupine) (also called B. lupini, B. lupines). This mixture is especially suitable for use in dry beans and lupins.
  • Bradyrhizobium sp. (Lupine) (also called B. lupini, B. lupines). This mixture is especially suitable for use in dry beans and lupins.
  • B. lupini strain is LL13 (isolated from Lupinus iuteus nodules from French soils; deposited at INRA, Dijon and Angers, France;
  • B. lupini strains WU425 isolated in Esperance, Western Australia from a non-Australian legume Ornthopus compressus
  • WSM4024 isolated from lupins in Australia by CRS during a 2005 survey
  • WSM471 isolated from Ornithopus pinnatus in Oyster Harbour, Western Australia
  • the present invention also relates to mixtures comprising compound II and comprising compound III, wherein compound II is selected from Bradyrhizobium sp. (Lupine) (B. lupini) and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • compound II is selected from Bradyrhizobium sp. (Lupine) (B. lupini) and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • strains WSM1271 (collected in Sardinia, Italy, from plant host Biserrula pelecinus), WSM 1497 (collected in Mykonos, Greece, from plant host Biserrula pelecinus), M. loti strains CC829 (commerical inoculant for Lotus pedunculatus and L. ulginosus in Australia, isolated from L.
  • WSM Western Australian Soil Microbiology
  • CC CSIRO collection
  • Australian Capirtal Territo- ry see e.g. Soil Biol Biochem (2004) 36(8), 1309-1317; Plant and Soil (201 1 ) 348(1 -2), 231 - 243).
  • M. loti strains are e.g. M. loti CC829 for Lotus peduncula- tus.
  • the present invention also relates to mixtures comprising compound II and comprising compound III, wherein compound II is selected from Mesorhizobium ciceri and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • the present invention also relates to mixtures, wherein compound II is selected from Mesorhizobium huakuii (see e.g. Appl. Environ. Microbiol. 201 1 , 77(15), 5513-5516). These mixtures are particularly suitable in Astralagus, e.g. Astalagus sinicus (Chinese milkwetch), Thermopsis, e.g. Thermopsis sinoides (Goldenbanner) and alike.
  • Astralagus e.g. Astalagus sinicus (Chinese milkwetch)
  • Thermopsis e.g. Thermopsis sinoides (Goldenbanner) and alike.
  • M. huakuii strain is HN3015 which was isolated from Astralagus sinicus in a rice-growing field of Southern China (see e.g. World J. Microbiol. Biotechn. (2007) 23(6), 845-851 , ISSN 0959-3993).
  • the present invention also relates to mixtures comprising compound II and comprising compound III, wherein compound II is selected from Mesorhizobium huakuii and wherein compound III is selected from jasmonates or salts or derivatives thereof.
  • the present invention also relates to synergistic mixtures comprising compound I, com- pound II and compound III as set forth in Table 1 below:
  • the present invention relates to synergistic mixtures comprising one microbial strain as compound II as defined herein and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (Vigna) and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (Arachis) and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (Lupinus) and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA 1 10, and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum USDA31 , and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA76, and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA121 , and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA3 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain E-109 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain G49 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain 532c and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain TA-1 1 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strains TA-1 1 and 532c and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strains SEMIA 5079 and SEMIA 5080 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising B. elkanii strains SEMIA 587 and SEMIA 5019 and one compound IA.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium ssp. and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (Vigna) and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (Arachis) and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising Bradyrhizobium sp. (lupinus) and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA 1 10), and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum USDA31 , and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA76, and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA121 , and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain USDA3 and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain E-109 and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain G49 and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain 532c and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strain TA-1 1 and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strains TA-1 1 and 532c and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. japonicum strains SEMIA 5079 and SEMIA 5080 and one compound IB.
  • the present invention furthermore relates to synergistic mixtures comprising B. elkanii strains SEMIA 587 and SEMIA 5019 and one compound IB.
  • the present invention furthermore relates o synergistic mixtures comprising Bradyrhizobium ssp. and one compound IC.
  • the present invention furthermore relates o synergistic mixtures comprising Bradyrhizobium sp.
  • the present invention furthermore relates o synergistic mixtures comprising Bradyrhizobium sp.
  • the present invention furthermore relates o synergistic mixtures comprising Bradyrhizobium sp.
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum and one compound IC.
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strain
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strains TA-1 1 and 532c and one compound IC
  • the present invention furthermore relates o synergistic mixtures comprising B. japonicum strains SEMIA 5079 and SEMIA 5080 and one compound IC.
  • the present invention furthermore relates o synergistic mixtures comprising B. elkanii strains
  • pests embrace animal pests, and harmful fungi.
  • compositions that improve plants a process which is commonly and hereinafter referred to as "plant health”.
  • insecticidal also denotes not only action against (or attack by) insects, but also against (by) arachnids and nematodes.
  • the present invention relates to the inventive mixtures having synergistically enhanced action of controlling harmful fungi.
  • the invention relates to a method for controlling pest, using the inventive mixtures having synergistically enhanced action for controlling pests and to the use of compound I and compound II for preparing such mixtures, and also to compositions comprising such mixtures, wherein such methods relate seed treatment or soil application.
  • the present invention relates to inventive mixtures having synergistically enhanced action of increasing the health of plants.
  • the invention relates to a method for improving the health of plants, using the inventive mixtures having synergistically enhanced action for improving the health of plants and to the use of compound I and compound II for preparing such mixtures, and also to compositions comprising such mixtures, wherein such methods relate seed treatment or or soil application.
  • the present invention relates to a method for protection of plant propagation material from pests and/or improving the health of plants, wherein the plant propagation material is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation mate- rial from pests, wherein the plant propagation material is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from animal pests (insects, acarids or nematodes), wherein the plant propagation material are treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from harmful fungi, wherein the plant propagation material is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for improving the health of plants grown from said plant propagation material, wherein the plant propagation material is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from pests and/or improving the health of plants grown from said plant propagation material, wherein the soil, wherein plant propagation material is sown, is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from pests, wherein the soil, wherein plant propagation material is sown, is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from harmful fungi, wherein the soil, wherein plant propagation material is sown, is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for protection of plant propagation material from animal pests (insects, acarids or nematodes), wherein the soil, wherein plant propagation material is sown, is treated with an effective amount of an inventive mixture.
  • the present invention relates to a method for improving the health of plants grown from plant propagation material, wherein the soil, wherein plant propagation material is sown, is treated with an effective amount of an inventive mixture.
  • the compounds of the inventive mixtures can be applied simultaneously, that is jointly or separately, or in succession.
  • plant propagation material is to be understood to denote all the generative parts of the plant such as seeds and vegetative plant material such as cuttings and tubers (e. g. potatoes), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, sprouts and other parts of plants, including seedlings and young plants, which are to be transplanted after germination or after emergence from soil. These young plants may also be protected before transplantation by a total or partial treatment by immersion or pouring.
  • the term propagation material denotes seeds.
  • pesticidally effective amount means the amount of the inventive mixtures or of compositions comprising the mixtures needed to achieve an observable effect on growth, including the effects of necrosis, death, retardation, prevention, and removal, destruction, or otherwise diminishing the occurrence and activity of the target organism.
  • the pesticidally effective amount can vary for the various mixtures / compositions used in the invention.
  • a pesticidally effective amount of the mixtures / compositions will also vary according to the prevailing conditions such as desired pesticidal effect and duration, weather, target species, locus, mode of application, and the like.
  • plant health effective amount denotes an amount of the inventive mixtures, which is sufficient for achieving plant health effects as defined herein below. More exemplary information about amounts, ways of application and suitable ratios to be used is given below. Again, the skilled artisan is well aware of the fact that such an amount can vary in a broad range and is dependent on various factors, e.g. the treated cultivated plant or material and the climatic condi- tions.
  • Healthier plants are desirable since they result among others in better yields and/or a better quality of the plants or crops, specifically better quality of the harvested plant parts. Healthier plants also better resist to biotic and/or abiotic stress. A high resistance against biotic stresses in turn allows the person skilled in the art to reduce the quantity of pesticides applied and consequently to slow down the development of resistances against the respective pesticides.
  • health of a plant or “plant health” is defined as a condition of the plant and/or its products which is determined by several aspects alone or in combination with each other such as increased yield, plant vigor, quality of harvested plant parts and tolerance to abiotic and/or biotic stress.
  • Each plant health indicator listed below which is selected from the groups consisting of yield, plant vigor, quality and tolerance of the plant to abiotic and/or biotic stress, is to be understood as a preferred embodiment of the present invention either each on its own or preferably in combination with each other.
  • "increased yield" of a plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the inventive mixture.
  • Gram and “fruit” are to be understood as any plant product which is further utilized after harvesting, e.g. fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants), flowers (e.g. in the case of gardening plants, ornamentals) etc., that is anything of economic value that is produced by the plant.
  • the yield is increased by at least 4%.
  • the yield increase may even be higher, for example 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 %
  • the yield - if measured in the absence of pest pressure - is increased by at least 2 %
  • the yield increase may even be higher, for example until 4%-5% or even more.
  • the plant vigor becomes mani- fest in several aspects such as the general visual appearance.
  • improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant; and/or improved plant growth; and/or improved plant development; and/or improved visual appearance; and/or improved plant stand (less plant verse/lodging); and/or improved emergence; and/or enhanced root growth and/or more developed root system; and/or enhanced nodulation, in particular rhizobial nodulation;-and/or increased plant height; and/or increased tiller number; and/or increased number of side shoots; and/or increased number of flowers per plant; and/or increased shoot growth;-and/or less non-productive tillersand/or less input needed (such as ferti- lizers or water); and/or less seeds neededf and/or stronger and/or more productive tillersand/or improved quality of seeds (for being seeded in the following seasons for seed production); and/or field establishment.
  • Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
  • quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention.
  • Enhanced quality can be char- acterized, among others, by following improved properties of the plant or its product: increased nutrient content; and/or increased protein content; and/or increased oil content; and/or increased starch content; and/or increased content of fatty acids; and/or increased metabolite content; and/or increased carotenoid content; and/or increased sugar content; and/or increased amount of essential amino acids; and/or improved nutrient composition; and/or improved protein composition; and/or improved composition of fatty acids; and/or improved metabolite composition; and/or improved carotenoid composition; and/or improved sugar composition; and/or improved amino acids composition ; and/or improved or optimal fruit color; and/or improved leaf color; and/or higher storage capacity; and/or better processability of the harvested products.
  • Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors.
  • Biotic and abiotic stress can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes.
  • "enhanced tolerance or resistance to biotic and/or abiotic stress factors” means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with an inventive mixture and (2.) that the negative effects are not diminished by a direct action of the inventive mixture on the stress factors, e.g.
  • Negative factors caused by biotic stress such as pathogens and pests are widely known and are caused by living organisms, such as competing plants (for example weeds), microorganisms (such as phythopathogenic fungi and/or bacteria) and/or viruses.
  • Negative factors caused by abiotic stress are also well-known and can often be observed as reduced plant vigor (see above), for example:
  • Abiotic stress can be caused for example by: extremes in temperature such as heat or cold (heat stress / cold stress); and/or strong variations in temperature; and/or temperatures unusual for the specific season; and/or drought (drought stress); and/or extreme wetness; and/or high salinity (salt stress); and/or radiation (for example by increased UV radiation due to the decreasing ozone layer); and/or increased ozone levels (ozone stress); and/or organic pollution (for example by phythotoxic amounts of pesticides); and/or inorganic pollution (for example by heavy metal contaminants).
  • extremes in temperature such as heat or cold (heat stress / cold stress); and/or strong variations in temperature; and/or temperatures unusual for the specific season; and/or drought (drought stress); and/or extreme wetness; and/or high salinity (salt stress); and/or radiation (for example by increased UV radiation due to the decreasing ozone layer); and/or increased ozone levels (ozone stress); and/or organic pollution (for example by
  • the above identified indicators for the health condition of a plant may be interdependent and may result from each other.
  • an increased resistance to biotic and/or abiotic stress may lead to a better plant vigor, e.g. to better and bigger crops, and thus to an increased yield.
  • a more developed root system may result in an increased re- sistance to biotic and/or abiotic stress.
  • these interdependencies and interactions are neither all known nor fully understood and therefore the different indicators are described separately.
  • inventive mixtures effectuate an increased yield of a plant or its product.
  • inventive mixtures effectuate an increased vigor of a plant or its product.
  • inventive mixtures effectuate in an increased quality of a plant or its product.
  • inventive mixtures effectuate an increased tolerance and/or resistance of a plant or its product against biotic stress. In yet another embodiment the inventive mixtures effectuate an increased tolerance and/or resistance of a plant or its product against abiotic stress.
  • the inventive mixtures effectuate an increase in the yield.
  • the inventive mixtures effect an increase in the yield.
  • the inventive mixtures effect an improvement of the plant vigor.
  • the plant health effects of the inventive mixtures effect increased resistance of plant against biotic stress. In another preferred embodiment of the invention, the plant health effects of the inventive mixtures effect increased resistance of plant against abiotic stress.
  • the inventive mixtures effect an increase in the yield.
  • the inventive mixtures effect an increase in the vigor.
  • the mass ratio of any two ingredients in each combination is selected as to give the desired, for example, synergistic action. In general, the mass ratio would vary depending on the specific compound I.
  • the ratio by weight between any two ingredients in any combination of the present invention (compound I: compound II) [in the ternary mixtures ratios between any of the compounds I, II and III], independently of one another, is from 1000:1 to 1 :1000, preferably from 500:1 to 1 :500, more preferably the ratios from 100:1 to 1 :100 (for example ratios from 99:1 , 98:2, 97:3, 96:4, 95:5, 94:6, 93:7, 92:8, 91 :9, 90:10, 89:1 1 , 88:12, 87:13, 86:14, 85:15, 84:16, 83:17, 82:18, 81 :19, 80:20, 79:21 , 78:22, 77:23, 76:24, 75:
  • preferred mass ratios are those between any two com- ponents of present invention are from 75:1 to 1 :75, more preferably, 50:1 to 1 :50, especially 25:1 to 1 :25, advantageously 10:1 to 1 :10, such as 5:1 to 1 :5.
  • ratios are suitable for inventive mixtures applied by seed treatment or soil treatment.
  • all of these ratios refer to a preparation with at least 10 6 CFU/g ("colony forming units per gram").
  • compound II may be supplied in any physiological state such as active or dormant.
  • Dormant compound II may be supplied for example frozen, dried, or lyophilized or partly desiccated (proceduers to produce these partly desiccated organisms are given in
  • Organisms in an active state can be delivered in a growth medium without any additional additives or materials or in combination with suitable nutrient mixtures.
  • the compound II is preferably delivered and formulated in a dormant stage.
  • the microorganisms as used according to the invention can be cultivated continuously or discontinuously in the batch process or in the fed batch or repeated fed batch process.
  • a review of known methods of cultivation will be found in the textbook by Chmiel (Bioreaktoren und periphere bamboo (Vieweg Verlag, Braunschweig/Wiesbaden, 1994)).
  • the culture medium that is to be used must satisfy the requirements of the particular strains in an appropriate manner.
  • culture media for various microorganisms are given in the handbook "Manual of Methods for General Bacteriology” of the American Society for Bacte- riology (Washington D. C, USA, 1981 ).
  • These culture media that can be used according to the invention generally comprise one or more sources of carbon, sources of nitrogen, inorganic salts, vitamins and/or trace elements.
  • Preferred sources of carbon are sugars, such as mono-, di- or polysaccharides.
  • Very good sources of carbon are for example glucose, fructose, man- nose, galactose, ribose, sorbose, ribulose, lactose, maltose, sucrose, raffinose, starch or cellulose.
  • Sugars can also be added to the media via complex compounds, such as molasses, or other by-products from sugar refining. It may also be advantageous to add mixtures of various sources of carbon.
  • Other possible sources of carbon are oils and fats such as soybean oil, sunflower oil, peanut oil and coconut oil, fatty acids such as palmitic acid, stearic acid or linoleic acid, alcohols such as glycerol, methanol or ethanol and organic acids such as acetic acid or lactic acid.
  • Sources of nitrogen are usually organic or inorganic nitrogen compounds or materials containing these compounds.
  • sources of nitrogen include ammonia gas or ammonium salts, such as ammonium sulfate, ammonium chloride, ammonium phosphate, ammonium carbonate or ammonium nitrate, nitrates, urea, amino acids or complex sources of ni- trogen, such as corn-steep liquor, soybean flour, soybean protein, yeast extract, meat extract and others.
  • the sources of nitrogen can be used separately or as a mixture.
  • Inorganic salt compounds that may be present in the media comprise the chloride, phosphate or sulfate salts of calcium, magnesium, sodium, cobalt, molybdenum, potassium, manganese, zinc, copper and iron.
  • Inorganic sulfur-containing compounds for example sulfates, sulfites, dithionites, tetrathi- onates, thiosulfates, sulfides, but also organic sulfur compounds, such as mercaptans and thiols, can be used as sources of sulfur.
  • Phosphoric acid, potassium dihydrogenphosphate or dipotassium hydrogenphosphate or the corresponding sodium-containing salts can be used as sources of phosphorus.
  • Chelating agents can be added to the medium, in order to keep the metal ions in solution.
  • Especially suitable chelating agents comprise dihydroxyphenols, such as catechol or protocatechuate, or organic acids, such as citric acid.
  • the culture media used may also contain other growth factors, such as vitamins or growth promoters, which include for example biotin, riboflavin, thiamine, folic acid, nicotinic acid, pantothenate and pyridoxine. Growth factors and salts often come from complex components of the media, such as yeast extract, molasses, corn-steep liquor and the like. In addition, suitable precursors can be added to the culture medium. The precise composition of the compounds in the medium is strongly dependent on the particular experiment and must be decided individually for each specific case. Information on media optimization can be found in the textbook "Applied Microbiol. Physiology, A Practical Approach" (Publ. P.M. Rhodes, P.F. Stanbury, IRL Press (1997) p.
  • Growing media can also be obtained from commercial suppliers, such as Standard 1 (Merck) or BHI (Brain heart infusion, DIFCO) etc. All components of the medium are sterilized, either by heating (20 min at 2.0 bar and 121 °C) or by sterile filtration. The components can be sterilized either together, or if necessary separately. All the components of the medium can be present at the start of growing, or optionally can be added continuously or by batch feed.
  • the temperature of the culture of the respective microorganism is normally between 15°C and 45°C, preferably 25°C to 40°C and can be kept constant or can be varied during the experiment.
  • the pH value of the medium should be in the range from 5 to 8.5, preferably around 7.0.
  • the pH value for growing can be controlled during growing by adding basic compounds such as sodium hydroxide, potassium hydroxide, ammonia or ammonia water or acid compounds such as phos- phoric acid or sulfuric acid.
  • Antifoaming agents e.g. fatty acid polyglycol esters, can be used for controlling foaming.
  • suitable substances with selective action e.g. antibiotics
  • Oxygen or oxygen-containing gas mixtures e.g. the ambient air, are fed into the culture in order to maintain aerobic conditions.
  • the temperature of the culture is normally from 20°C to 45°C. Culture is continued until a maximum of the desired product has formed. This is normally achieved within 10 hours to 160 hours.
  • the cells can be disrupted optionally by high-frequency ultrasound, by high pressure, e.g. in a French pressure cell, by osmolysis, by the action of detergents, lytic enzymes or organic solvents, by means of homogenizers or by a combination of several of the methods listed.
  • the methodology of the present invention can further include a step of recovering individual compositions such as cell-free extracts, supernatants, metabolites or alike.
  • the term "recovering" includes extracting, harvesting, isolating or purifying of an extract, supernatant or metabolite e.g. from whole culture broth.
  • Recovering can be performed according to any conventional isolation or purification methodology known in the art including, but not limited to, treatment with a conventional resin (e.g., anion or cation exchange resin, non-ionic adsorption resin, etc.), treatment with a conventional adsorbent (e.g., activated charcoal, silicic acid, silica gel, cellulose, alumina, etc.), alteration of pH, solvent extraction (e.g., with a conventional solvent such as an alcohol, ethyl acetate, hexane and the like), distillation, dialysis, filtration, concentration, crystallization, recrystallization, pH adjustment, lyophilization and the like.
  • a conventional resin e.g., anion or cation exchange resin, non-ionic adsorption resin, etc.
  • a conventional adsorbent e.g., activated charcoal, silicic acid, silica gel, cellulose, alumina, etc.
  • solvent extraction e.g.
  • the agent can be recovered from culture media by first removing the microorganisms. The remaining broth is then passed through or over a cation exchange resin to remove unwanted cations and then through or over an anion exchange resin to remove unwanted inorganic anions and organic acids.
  • Preferred inventive mixtures are those comprising compound II and fungicidal compound IA selected from the group consisting of
  • Inhibitors of complex III at Qo site coumethoxystrobin, coumoxystrobin, dimoxystrobin, enestroburin, fenaminstrobin, fenoxy-strobin/flufenoxystrobin, fluoxastrobin, kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, pyrametostrobin, pyraoxystrobin, trifloxystrobin, 2-[2-(2,5-dimethyl-phenoxymethyl)-phenyl]-3-methoxy-acrylic acid methyl ester and 2-(2-(3-(2,6-di-chlorophenyl)-1 -methyl-allylideneaminooxymethyl)-phenyl)-2-methoxyimino- N-methyl-acetamide, pyribencarb, triclopyricarb/chlorodincarb, famoxadone, fenamidone;
  • inhibitors of complex III at Qi site cyazofamid, amisulbrom, [(3S,6S,7R,8R)-8-benzyl- 3-[(3-acetoxy-4 methoxy-pyridine-2-carbonyl)amino]-6-methyl-4,9-dioxo-1 ,5-dioxonan-7-yl] 2-methylpropanoate, [(3S,6S,7R,8R)-8-benzyl-3-[[3-(acetoxymethoxy)-4-methoxy-pyridine- 2-carbonyl]amino]-6-methyl-4,9-dioxo-1 ,5-dioxonan-7-yl] 2-methylpropanoate, [(3S,6S,7R,8R)- 8-benzyl-3-[(3-isobutoxycarbonyloxy-4-methoxy-pyridine-2-carbonyl)amino]-6-methyl-4,9-dioxo- 1
  • inhibitors of complex II e. g. carboxamides: flutolanil, bixafen, boscalid, fluopyram, fluxa- pyroxad, isopyrazam, penflufen, penthiopyrad, sedaxane, N-(4'-trifluoromethylthiobiphenyl-2-yl)-
  • respiration inhibitors e.g. complex I, uncouplers: (5,8-difluoroquinazolin-4-yl)- ⁇ 2-[2-fluoro-4-(4-trifluoromethylpyridin-2-yloxy)-phenyl]-ethyl ⁇ -amine, fluazinam; ametoctradin; and silthiofam;
  • C14 demethylase inhibitors (DMI fungicides): triazoles: bitertanol, cyproconazole, difeno- conazole,diniconazole, diniconazole-M, epoxiconazole, fluquinconazole, flusilazole, flutriafol, hexaconazole, ipconazole, metconazole, myclobutanil, propiconazole, prothio-conazole, sime- conazole, tebuconazole, tetraconazole, triadimenol, triticonazole, 1 -[rel-(2S;3R)-3-(2-chloro- phenyl)-2-(2,4-difluorophenyl)-oxiranylmethyl]-5-thiocyanato-1 H-[1 ,2,4]triazole,
  • imidazoles imazalil, pefurazoate, prochloraz, triflumizol;
  • methionine synthesis inhibitors anilino-pyrimidines: cyprodinil, pyrimethanil;
  • phospholipid biosynthesis and cell wall deposition dimethomorph, flumorph, mandipro- pamid, pyrimorph, N-(1 -(1 -(4-cyano-phenyl)ethanesulfonyl)-but-2-yl) carbamic acid-(4-fluoro- phenyl) ester;
  • inorganic active substances Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur;
  • guanidines and others dodine, guazatine, guazatine-acetate, iminoctadine, iminoctadine- triacetate, iminoctadine-tris(albesilate), dithianon, 2,6-dimethyl-1 H,5H-[1 ,4]dithi- ino[2,3-c:5,6-c']dipyrrole-1 ,3,5,7(2H,6H)-tetraone;
  • inhibitors of glucan synthesis validamycin
  • melanin synthesis inhibitors pyroquilon, tricy- clazole
  • Ampelomyces quisqualis e.g. AQ 10® from Intrachem Bio GmbH & Co. KG, Germany
  • Aspergillus flavus e.g. AFLAGUARD® from Syngenta, CH
  • Aureobasidium pullulans e.g. BO- T ECTOR® from bio-ferm GmbH, Germany
  • Bacillus pumilus e.g. NRRL B-30087 in SONATA® and BALLAD® Plus from AgraQuest Inc., USA
  • Candida oleophila I-82 e.g. ASPIRE® from Ecogen Inc., USA
  • Candida saitoana e.g.
  • BIOCURE® in mixture with lysozyme
  • BIO-COAT® from Micro Flo Company, USA (BASF SE) and Arysta
  • Chitosan e.g. ARMOUR- ZEN from BotriZen Ltd., NZ
  • Clonostachys rosea f. catenulata also named Gliocladium catenu- latum (e.g. isolate J1446: PRESTOP® from Verdera, Finland), Coniothyrium minitans (e.g. CONTANS® from Prophyta, Germany), Cryphonectria parasitica (e.g. Endothia parasitica from CNICM, France), Cryptococcus albidus (e.g.
  • Fusarium oxysporum e.g. BIOFOX® from S.I.A.P.A., Italy, FUSACLEAN® from Natural Plant Protection, France
  • Metschnikowia fructicola e.g. SHEMER® from Agrogreen, Israel
  • Microdochium dimerum e.g. ANTIBOT® from Agrauxine, France
  • Phlebiopsis gigantea e.g. ROTSOP® from Verdera, Finland
  • Pseudozyma flocculosa e.g. SPORODEX® from Plant Products Co. Ltd., Canada
  • Pythium oligandrum DV74 e.g.
  • harzianum TH 35 e.g. ROOT PRO® from Mycontrol Ltd., Israel
  • T. harzianum T-39 e.g. TRICHODEX® and TRICHODERMA 2000® from Mycontrol Ltd., Israel and Makhteshim Ltd., Israel
  • T. harzianum and T. viride e.g. TRICHOPEL from Agrimm Technologies Ltd, NZ
  • T. harzianum ICC012 and T. viride ICC080 e.g. REMEDIER® WP from Isagro Ricerca, Italy
  • T. polysporum and T. harzianum e.g. BINAB® from BINAB Bio-Innovation AB, Sweden
  • T. virens GL-21 e.g. SOILGARD® from Certis LLC, USA
  • T. viride e.g. TRIECO® from Ecosense Labs. (India) Pvt. Ltd., Indien, BIO-CURE® F from T. Stanes & Co. Ltd., Indien
  • T. viride TV1 e.g. T. viride TV1 from Agribiotec srl, Italy
  • Ulocladium oudemansii HRU3 e.g. BOTRY-ZEN® from Botry-Zen Ltd, NZ.
  • Preferred inventive mixtures especially useful for seed treatment are those comprising compound II and fungicidal compound IA selected from Pyraclostrobin, Azoxystrobin, Trifloxystrobin, Picoxystrobin, Boscalid, Fluoxapyroxad, Fluopyram, Penflufen, Benzovindiflupyr, Sedaxane, Penthiopyrad, Difenoconazole, Fluquinconazole, Triticonazole, Tebuconazole, Tetraconazole, Hexaconazole, Thiophanate-methyl, Pyrimethanil, Cyrodinil, Metalaxyl, Dimethomorph and Mandipropamid; more preferably selected from Pyraclostrobin, Azoxystrobin, Trifloxystrobin, Picoxystrobin, Boscalid, Fluoxapyroxad, Fluopyram, Penflufen, Benzovindiflupyr, Sedaxane, Penthiopyrad, Difen
  • Preferred inventive mixtures especially useful for soil treatment are those comprising compound II and fungicidal compound IA selected from Pyraclostrobin, Azoxystrobin, Trifloxystrobin, Picoxystrobin, Fluoxapyroxad, Fluopyram, Benzovindiflupyr, Metalaxyl, Fludioxonil, Oryzastro- bin, Boscalid, Penthiopyrad, Iprodione, Dimethomorph and Mandipropamid, more preferably selected from Pyraclostrobin, Azoxystrobin, Trifloxystrobin, Picoxystrobin, Fluoxapyroxad, Fluopyram, Benzovindiflupyr, Metalaxyl and Fludioxonil.
  • Equally preferred inventive mixtures are those comprising compound II and one inseciticdal compound IB selected from the group consisting of
  • aldicarb for example aldicarb, benfuracarb, carbofuran, carbosulfan, isoprocarb, methiocarb, methomyl, oxamyl, pirimicarb, thiodicarb, triazamate;
  • ethiprole for example ethiprole, fipronil, flufiprole, pyrafluprole, or pyriprole;
  • acrinathrin for example acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, deltamethrin, esfenvalerate, etofenprox, fenvalerate, flucythrinate, permethrin, silafluofen, tefluthrin;
  • acetamiprid for example acetamiprid, chlothianidin, cycloxaprid, dinotefuran, flupyradifurone, nitenpyram, sulfoxaflor, thiacloprid, 1 -[(6-chloro-3-pyridyl)methyl]-7-methyl-8-nitro-5-propoxy-3,5,6,7-tetra- hydro-2H-imidazo[1 ,2-a]pyridine (known from WO 2007/101369);
  • spinosad spinetoram
  • M-6 chloride channel activators from the class of mectins for example spinosad, spinetoram; M-6 chloride channel activators from the class of mectins,
  • abamectin for example abamectin, emamectin benzoate, ivermectin, lepimectin or milbemectin;
  • chlorfenapyr for example chlorfenapyr
  • diflubenzuron for example diflubenzuron, flufenoxuron, lufenuron, novaluron, teflubenzuron;
  • M-15 inhibitors of the chitin biosynthesis type 1 for example buprofezin;
  • M-17 Ecdyson receptor agonists for example methoxyfenozide
  • spirodiclofen for example spirodiclofen, spirotetramat
  • M-24 Ryanodine receptor-modulators from the class of diamides for example flubendiamide, chlorantraniliprole, cyanthraniliprole, (R)-3-chloro-N1 - ⁇ 2-methyl-4-[1 ,2,2,2-tetrafluoro-1 -(trifluoro- methyl)ethyl]phenyl ⁇ -N2-(1 -methyl-2-methylsulfonylethyl)phthalamide or (S)-3-chloro-N1 - ⁇ 2-me- thyl-4-[1 ,2,2,2-tetrafluoro-1 -(trifluoromethyl)ethyl]phenyl ⁇ -N2-(1 -methyl-2-methylsulfonylethyl)- phthalamide (both known from WO 2007/101540), 3-bromo-N- ⁇ 2-bromo-4-chloro-6-[(1 -cyclo- propylethyl)carbamoyl]phenyl ⁇
  • M-25 Others for example afidopyropen, flumetoquin, 2-(5-ethylsulfinyl-2-fluoro-4-methyl- phenyl)-5-methyl-1 ,2,4-triazol-3-amine (known from WO 06/043635), 1 -(5-ethylsulfinyl-2,4-di- methyl-phenyl)-3-methyl-1 ,2,4-triazole (known from WO 06/043635), metaldehyde.
  • flumetoquin 2-(5-ethylsulfinyl-2-fluoro-4-methyl- phenyl)-5-methyl-1 ,2,4-triazol-3-amine
  • 1 -(5-ethylsulfinyl-2,4-di- methyl-phenyl)-3-methyl-1 ,2,4-triazole known from WO 06/043635
  • metaldehyde metaldehyde
  • M-26 Bacillus firmus (e.g. Bacillus firmus CNCM 1-1582).
  • More preferred inventive mixtures are those comprising compound II and fungicidal compound IA as displayed in Table 1A:
  • Endothia parasitica A M-144. T. polysporum and T. A coccus albidus harzianum
  • mixtures N-1 to N-149 comprising Bradyrhizobium sp. (Vigna) as compound II instead of "A” and compound I A corresponding to M-1 to M-149 as de- fined in Table 1A.
  • mixtures M-1 to M-149 comprising Bradyrhizobium sp. (Arachis) as compound II instead of "A" and compound I A corresponding to M-1 to M-149 as defined in Table 1 A.
  • mixtures 0-1 to 0-149 comprising Bradyrhizobien sp. (Lu- pinus) as compound II instead of "A” and compound I A corresponding to M-1 to M-149 as de- fined in Table 1A.
  • Table 1A-04
  • mixtures P-1 to P-149 comprising B. japonicum G49 as compound II instead of "A” and compound I A corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures Q-1 to Q-149 comprising B. japonicum strain USDA 1 10) as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures T-1 to T-149 comprising B. japonicum USDA31 as compound II instead of "A” and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures U-1 to U-149 comprising B. japonicum strain USDA76 as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures V-1 to V-149 comprising B. japonicum strain USDA121 as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures W-1 to W-149 comprising B. japonicum strain USDA3 as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures X-1 to X-149 comprising B. japonicum strain E- 109 as compound II instead of "A” and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures Y-1 to Y-149 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures Z-1 to Z-149 comprising B. japonicum strain 532c as compound II instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures AA-1 to AA-149 comprising B. japonicum strain TA-1 1 as compound I I instead of "A” and compound I A corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures BB-1 to BB-149 comprising a mixture of B. japon- icum strains 532c and TA-1 1 as compound I I instead of "A" and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • mixtures CC-1 to CC-149 comprising a mixture of B. japonicum strains SEMIA 5079 and SEMIA 5080 as compound I I instead of "A” and compound IA corresponding to M-1 to M-149 as defined in Table 1A.
  • Equally more preferred mixtures are mixtures DD-1 to DD-149, comprising a mixture of B.
  • Equally more preferred mixtures are those comprising compound I I and compound I B displayed in Table 1 B:
  • mixtures ZN-1 to ZN-89 comprising Bradyrhizobium sp. (Vigna) as compound II instead of "A" and compound IB corresponding to M'-1 to I -89 as defined in Table 1 B.
  • mixtures ZM-1 to ZM-89 comprising Bradyrhizobium sp. (Arachis) as compound II instead of "A" and compound IB corresponding to M'-1 to M'-89 as defined in Table 1 B.
  • mixtures ZO-1 to ZO-89 comprising Bradyrhizobien sp. (Lupinus) as compound II instead of "A" and compound IB corresponding to M'-1 to M'-89 as defined in Table 1 B.
  • Table 1 B-04
  • mixtures ZP-1 to ZP-89 comprising B. japonicum G49 as compound II instead of "A" and compound IB corresponding to M'-1 to I -89 as defined in Table 1 B.
  • mixtures ZQ-1 to ZQ-89 comprising B. japonicum strain USDA 1 10) as compound II instead of "A" and compound IB corresponding to M'-1 to IW-89 as defined in Table 1 B.
  • mixtures ZT-1 to ZT-89 comprising B. japonicum USDA31 as compound II instead of "A" and compound IB corresponding to M'-1 to IW-89 as defined in Table 1 B.
  • mixtures ZU-1 to ZU-89 comprising B. japonicum strain USDA76 as compound II instead of "A" and compound IB corresponding to IW-1 to IW-109 as defined in Table 1 B.
  • mixtures ZV-1 to ZV-89 comprising B. japonicum strain USDA121 as compound II instead of "A" and compound IB corresponding to IW-1 to IW-89 as defined in Table 1 B.
  • mixtures ZW-1 to ZW-89 comprising B. japonicum strain USDA3 as compound II instead of "A" and compound IB corresponding to IW-1 to IW-89 as de- fined in Table 1 B.
  • mixtures ZX-1 to ZX-89 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IB corresponding to IW-1 to IW-89 as defined in Table 1 B.
  • mixtures ZY-1 to ZY-89 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IB corresponding to IW-1 to IW-89 as defined in Table 1 B.
  • mixtures ZZ-1 to ZZ-89 comprising B. japonicum strain 532c as compound II instead of "A" and compound IB corresponding to M'-1 to I -89 as defined in Table 1 B.
  • mixtures ZAA-1 to ZAA-89 comprising B. japonicum strain TA-1 1 as compound II instead of "A” and compound IB corresponding to M'-1 to M'-89 as defined in Table 1 B.
  • mixtures ZBB-1 to ZBB-89 comprising a mixture of B. japonicum strains 532c and TA-1 1 as compound II instead of "A" and compound IB corresponding to I -1 to IW-89 as defined in Table 1 B.
  • mixtures ZCC-1 to ZCC-89 comprising a mixture of B. japonicum strains SEMIA 5079 and SEMIA 5080 as compound II instead of "A" and compound IB corresponding to M'-1 to M'-89 as defined in Table 1 B.
  • mixtures ZDD-1 to ZDD-89 comprising a mixture of B. elkanii strains SEMIA 587 and SEMIA 5019 as compound II instead of "A" and compound IB corresponding to M'-1 to M'-89 as defined in Table 1 B.
  • More preferred inventive mixtures especially useful for seed and soil treatment are those com- prising compound II and insecticidal compound IB selected from momfluorothrin; 1 -[(6-chloro- 3-pyridyl)methyl]-2-nitro-1 -[(E)-pentylideneamino]guanidine; 1 -[(E)-[2-(4-cyanophenyl)-
  • Equally preferred inventive mixtures are those comprising compound II and compound IC having plant growth regulating activity displayed in Table 1 C:
  • More preferred inventive mixtures especially useful for seed and soil treatment are those comprising compound II and compound IC having plant growth regulating activity selected from 6-benzylaminopurine, chlormequat, chlormequat chloride, choline chloride, cyclanilide, dikegu- lac, diflufenzopyr, dimethipin, ethephon, flumetralin, fluthiacet, forchlorfenuron, gibberellic acid, inabenfide, maleic hydrazide, mepiquat, mepiquat chloride, 1 -MCP, paclobutrazol, prohexadione, prohexadione calcium, prohydrojasmon, thidiazuron, triapenthenol, tributyl phosphorotrithi- oate, trinexapac-ethyl and uniconazole.
  • compound II and compound IC having plant growth regulating activity selected from 6-benzylaminopurine, chlormequat, chlorme
  • inventive mixtures especially useful for seed and soil treatment are those comprising compound II and compound IC having plant growth regulating activity selected from chlormequat, chlormequat chloride, choline chloride, cyclanilide, dimethipin, ethephon, forchlorfenuron, gibberellic acid, maleic hydrazide, mepiquat, mepiquat chloride, 1 -MCP, prohexadione, prohexadione calcium, pthidiazuron and trinexapac-ethyl.
  • mixtures CN-1 to CN-39 comprising Bradyrhizobium sp. (Vigna) as compound II instead of "A” and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CM-1 to CM-39 comprising Bradyrhizobium sp. (Arachis) as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • Equally more preferred mixtures are mixtures CO-1 to CO-39, comprising Bradyrhizobien sp. (Lupinus) as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CP-1 to CP-39 comprising B. japonicum G49 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CQ-1 to CQ-39 comprising B. japonicum strain USDA 1 10) as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CT-1 to CT-39 comprising B. japonicum USDA31 as compound II instead of "A” and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CU-1 to CU-39 comprising B. japonicum strain USDA76 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-109 as defined in Table 1 C.
  • mixtures CV-1 to CV-39 comprising B. japonicum strain USDA121 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CW-1 to CW-39 comprising B. japonicum strain USDA3 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CX-1 to CX-39 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CY-1 to CY-39 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CZ-1 to CZ-39 comprising B. japonicum strain 532c as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CAA-1 to CAA-39 comprising B. japonicum strain TA-1 1 as compound II instead of "A” and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CBB-1 to CBB-39 comprising a mixture of B. ja- ponicum strains 532c and TA-1 1 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • mixtures CDD-1 to CDD-39 comprising a mixture of B. elkanii strains SEMIA 587 and SEMIA 5019 as compound II instead of "A" and compound IC corresponding to M"-1 to M"-39 as defined in Table 1 C.
  • Most preferred mixtures are those comprising compound II and compound IA displayed in Table 2A:
  • Bacillus pumilus A Bacillus pumilus A
  • Bacillus subtilis A Bacillus subtilis A
  • mixtures YN-1 to YN-124 comprising Bradyrhizobium sp. (Vigna) as compound II instead of "A” and compound IA corresponding to C-1 to C-124 as de- fined in Table 2A.
  • mixtures YM-1 to YM-124 comprising Bradyrhizobium sp. (Arachis) as compound II instead of "A” and compound I A corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YO-1 to YO-124 comprising Bradyrhizobien sp. (Lupinus) as compound II instead of "A” and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YP-1 to YP-124 comprising B. japonicum G49 as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YQ-1 to YQ-124 comprising B. japonicum strain USDA 1 10) as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YT-1 to YT-124 comprising B. japonicum
  • mixtures YU-1 to YU-124 comprising B. japonicum strain USDA76 as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YV-1 to YV-124 comprising B. japonicum strain USDA121 as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YW-1 to YW-124 comprising B. japonicum strain USDA3 as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YX-1 to YX-124 comprising B. japonicum strain E-109 as compound II instead of "A" and compound I A corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YY-1 to YY-124 comprising B. japonicum strain E-109 as compound II instead of "A" and compound I A corresponding to C-1 to C-124 as de- fined in Table 2A.
  • mixtures YZ-1 to YZ-124 comprising B. japonicum strain 532c as compound I I instead of "A" and compound I A corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YAA-1 to YAA-124 comprising B. japonicum strain TA-1 1 as compound I I instead of "A” and compound I A corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YBB-1 to YBB-124 comprising a mixture of B. japonicum strains 532c and TA-1 1 as compound II instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YCC-1 to YCC-124 comprising a mixture of B. japonicum strains SEMIA 5079 and SEMIA 5080 as compound I I instead of "A” and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures YDD-1 to YDD-124 comprising a mixture of B. elkanii strains SEMIA 587 and SEMIA 5019 as compound I I instead of "A" and compound IA corresponding to C-1 to C-124 as defined in Table 2A.
  • mixtures FN-1 to FN-59 comprising Bradyrhizobium sp. (Vigna) as compound I I instead of "A” and compound IB corresponding to C-1 to C-59 as de- fined in Table 2B.
  • mixtures FM-1 to FM-59 comprising Bradyrhizobium sp. (Arachis) as compound II instead of "A" and compound I B corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FO-1 to FO-59 comprising Bradyrhizobien sp. (Lupinus) as compound I I instead of "A” and compound I B corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FP-1 to FP-59 comprising B. japonicum G49 as compound I I instead of "A” and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • Table 2B-05
  • mixtures FQ-1 to FQ-59 comprising B. japonicum strain USDA 1 10) as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FT-1 to FT-59 comprising B. japonicum USDA31 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FU-1 to FU-59 comprising B. japonicum strain USDA76 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as de- fined in Table 2B.
  • mixtures FV-1 to FV-59 comprising B. japonicum strain USDA121 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FW-1 to FW-59 comprising B. japonicum strain USDA3 as compound II instead of "A” and compound IB corresponding to C-1 to C-59 as de- fined in Table 2B.
  • mixtures FX-1 to FX-59 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FY-1 to FY-59 comprising B. japonicum strain E- 109 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FZ-1 to FZ-59 comprising B. japonicum strain 532c as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FAA-1 to FAA-59 comprising B. japonicum strain TA-1 1 as compound II instead of "A” and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FBB-1 to FBB-59 comprising a mixture of B. ja- ponicum strains 532c and TA-1 1 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FCC-1 to FCC-59 comprising a mixture of B. ja- ponicum strains SEMIA 5079 and SEMIA 5080 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • mixtures FDD-1 to FDD-59 comprising a mixture of B. elkanii strains SEMIA 587 and SEMIA 5019 as compound II instead of "A" and compound IB corresponding to C-1 to C-59 as defined in Table 2B.
  • the present invention furthermore relates to mixtures comprising compound I, compound II and compound III, wherein compound III is selected jasmonic acid, salts or derivatives thereof.
  • Salts of jasmonic acid or derivatives include without limitation the jasmonate salts potassium jasmonate, sodium jasmonate, lithium jasmonate, ammonium jasmonate, dimethylammonium jasmonate, isopropylammonium jasmonate, diolammonium jasmonate, diethtriethanolammoni- urn jasmonate, jasmonic acid methyl ester, jasmonic acid amide, jasmonic acid methylamide, jasmonic acid-L-amino acid (amide-linked) conjugates (e.g., conjugates with L- isoleucine, L- valine, L-leucine, or L-phenylalanine), 12-oxo-phytodienoic acid, coronatine, coronafacoyl- L- serine, coronafacoyl-L-threonine, methyl esters of 1 - oxo-indanoyl-isoleucine, methyl esters
  • jasmonic acid Preferred amongst the group of salts of jasmonic acid or derivatives are jasmonic acid, methyl jasmonate, sodium jasmonate, potassium jasmonate, lithium jasmonate and ammonium jasmonate. More preferred is jasmonic acid methyl ester.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-01 .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-02.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-03.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-04.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-05.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-06.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-07.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-08.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-09.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-10.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-1 1 .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-12.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-13.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-14.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-15.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1A-16.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 ⁇ -0 ⁇ .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-02.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-03.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-04.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-05.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-06.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-07.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-08.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-09.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-10.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-1 1 .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-12.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-13.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-14.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-15.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 B-16.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-01.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-02.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-03.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-04.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-05.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-06.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-07.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-08.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-09.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-10.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-1 1 .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-12.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-13.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-14.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-15.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 1 C-16.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-01 .
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-02.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-03.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-04.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-05.
  • the present invention furthermore relates to ternary mixtures, wherein compound III is methyl jasmonate, and the combination of compounds I and II in each case corresponds to a row of Table 2A-06.

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Biotechnology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Virology (AREA)
  • Agronomy & Crop Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne des mélanges pesticides comprenant un composé biologique et au moins un fongicide, un insecticide ou un composé régulateur de croissance des plantes, ainsi que des utilisations respectives de ceux-ci en agriculture, tels que définis dans la description.
PCT/EP2013/073900 2012-11-22 2013-11-15 Mélanges pesticides Ceased WO2014079771A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP12193743 2012-11-22
EP12193743.7 2012-11-22
EP13182481.5 2013-08-30
EP13182481 2013-08-30

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WO2014079771A1 true WO2014079771A1 (fr) 2014-05-30

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Cited By (12)

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US10076119B2 (en) 2012-11-22 2018-09-18 Basf Corporation Pesticidal mixtures
US10212934B2 (en) 2014-06-25 2019-02-26 BASF Agro B.V. Pesticidal compositions
US10251400B2 (en) 2014-05-23 2019-04-09 Basf Se Mixtures comprising a Bacillus strain and a pesticide
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10537110B2 (en) 2012-11-22 2020-01-21 Basf Corporation Pesticidal mixtures
US10743535B2 (en) 2017-08-18 2020-08-18 H&K Solutions Llc Insecticide for flight-capable pests
US10759767B2 (en) 2012-12-20 2020-09-01 BASF Agro B.V. Compositions comprising a triazole compound
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10537110B2 (en) 2012-11-22 2020-01-21 Basf Corporation Pesticidal mixtures
US11284623B2 (en) 2012-11-22 2022-03-29 Basf Corporation Pesticidal mixtures
US10076119B2 (en) 2012-11-22 2018-09-18 Basf Corporation Pesticidal mixtures
US10759767B2 (en) 2012-12-20 2020-09-01 BASF Agro B.V. Compositions comprising a triazole compound
US10981883B2 (en) 2013-01-09 2021-04-20 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10519122B2 (en) 2013-01-09 2019-12-31 BASF Agro B.V. Process for the preparation of substituted oxiranes and triazoles
US10512267B2 (en) 2013-07-08 2019-12-24 BASF Agro, B.V. Compositions comprising a triazole compound and a biopesticide
US10251400B2 (en) 2014-05-23 2019-04-09 Basf Se Mixtures comprising a Bacillus strain and a pesticide
US11083202B2 (en) 2014-05-23 2021-08-10 Basf Se Mixtures comprising a bacillus strain and a pesticide
US10212934B2 (en) 2014-06-25 2019-02-26 BASF Agro B.V. Pesticidal compositions
US10779536B2 (en) 2014-11-07 2020-09-22 Basf Se Pesticidal mixtures
US12302901B2 (en) 2014-11-07 2025-05-20 Basf Se Pesticidal mixtures
US10905122B2 (en) 2016-03-16 2021-02-02 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on cereals
US11241012B2 (en) 2016-03-16 2022-02-08 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on soybean
US11425909B2 (en) 2016-03-16 2022-08-30 Basf Se Use of tetrazolinones for combating resistant phytopathogenic fungi on fruits
US10743535B2 (en) 2017-08-18 2020-08-18 H&K Solutions Llc Insecticide for flight-capable pests

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