[go: up one dir, main page]

WO2001060159A1 - Compositions fongicides tolerantes et inoculantes - Google Patents

Compositions fongicides tolerantes et inoculantes Download PDF

Info

Publication number
WO2001060159A1
WO2001060159A1 PCT/EP2001/001745 EP0101745W WO0160159A1 WO 2001060159 A1 WO2001060159 A1 WO 2001060159A1 EP 0101745 W EP0101745 W EP 0101745W WO 0160159 A1 WO0160159 A1 WO 0160159A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
composition according
weight
amount
tolerant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2001/001745
Other languages
English (en)
Inventor
Douthitt Pruitt Merritt
Christian Schlatter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syngenta Participations AG
Original Assignee
Syngenta Participations AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Participations AG filed Critical Syngenta Participations AG
Priority to BRPI0108497-6B1A priority Critical patent/BR0108497B1/pt
Priority to CA2400428A priority patent/CA2400428C/fr
Priority to AU35482/01A priority patent/AU3548201A/en
Publication of WO2001060159A1 publication Critical patent/WO2001060159A1/fr
Anticipated expiration legal-status Critical
Priority to US11/835,726 priority patent/US20080004179A1/en
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06—Coating or dressing seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Definitions

  • the present invention relates to inoculant tolerant, aqueous fungicidal compositions, the preparation of such compositions and a method of using such compositions to combat phytopathogenic fungi.
  • the fungicidal compositions of the invention have particular application in the protection of plant propagation materials, such as seeds, against fungal disease.
  • Fungicides typically are applied directly to plant propagation materials (such as seeds) prior to sowing and/or are used in foliar or furrow applications.
  • Rhizobia bacteria for example, form nodules on the plant roots and are sustained by the plant and in turn provide nitrogen for the plant as mentioned above.
  • compositions and bacteria may exhibit direct toxicity to the various strains of nitrogen-fixing bacteria when such compositions and bacteria are mixed together for seed treatment or when such compositions and bacteria are added to the seed sequentially.
  • a storage stable, aqueous fungicidal composition which is substantially free of organic solvents, comprising at least one fungicidally active compound and at least one anionic surfactant is tolerant to nitrogen-fixing bacteria such as Rhizobium spp. when applied concurrently or sequentially to plant propagation materials such as seeds; the inventive compositions are storage stable, ready-to-apply (RTA), ecologically and toxicologically favorable and have good fungicidal efficacy.
  • RTA ready-to-apply
  • the present invention provides an inoculant tolerant, aqueous fungicidal composition, which is substantially free of organic solvents, comprising: a fungicidally effective amount of at least one fungicidally active compound; a stabilizing effective and nitrogen-fixing bacteria tolerant amount of a preservative; and at least one anionic surfactant.
  • the preservative is present in the composition in an amount of from about 0.0001 to about 0.05% by weight of the composition.
  • the aqueous fungicidal composition is an aqueous solution.
  • the invention further provides for a method for preparing the fungicidal composition which is achieved by intimately mixing the components with water, optionally using a concentrated premix of the preservative and one or more formulation components, until a homogeneous phase is achieved.
  • the invention also provides for plant propagation materials treated with the fungicidal composition and for a method for reducing fungal infestation and for promoting the growth of plant propagation materials such as seeds.
  • the method comprises contacting the seeds with the aqueous fungicidal composition described above either before, during or after addition of a plant growth-promoting amount of a nitrogen-fixing bacterium to the seed. 4. DETAILED DESCRIPTION OF THE INVENTION
  • fungicidally active compound as utilized herein is intended to cover compounds active against phytopathogenic fungi that may belong to a very wide range of compound classes.
  • compound classes to which the suitable fungicidally active compound may belong include: triazole derivatives, strobilurins, carbamates, benzimidazoles (thiabendazole), N-trihalomethylthio compounds (captan), substituted benzenes, carboxamides, phenylamides and phenylpyrroles, and mixtures thereof.
  • Suitable triazole derivatives include propiconazole, difenconazole and tebuconazole.
  • Suitable strobilurins include trifloxystrobin, azoxystrobin and kresoxim-methyl.
  • Suitable carbamates include thiram.
  • Suitable substituted benzenes include PCNB and chlorothalonil.
  • Suitable carboxamides include carboxin.
  • a preferred phenylamide usable in the compositions and methods falling within the scope of the present invention include metalaxyl; metalaxyl consisting of more than 70% by weight of the R-enantiomer; metalaxyl consisting of more than 85% by weight of the R-enantiomer; metalaxyl consisting of more than 92% by weight of the R-enantiomer; metalaxyl consisting of more than 97% by weight of the R-enantiomer; and mefenoxam (i.e., R-metalaxyl or metalaxyl-M).
  • a specific phenylpyrrole usable in the compositions and methods falling within the scope of the present invention is fludioxonil.
  • the fungicidally active compounds are employed in a fungicidally effective amount in the composition.
  • Mixtures of one or more of the foregoing fungicidally active compounds also are usable as an active component in the practice of the present invention.
  • Preservatives useful in the practice of the invention include ascorbic acid, ascorbyl palmitate, benzoic acid, hexamethylenetetramine, propyl p-hydroxybenzoate, sodium propionate, sorbic acid (and potassium salt), sulfurous acid, 1 ,2-benzisothiazolin-3-one, 5-Chloro-2-methyl-4-isothiazolin-3-one (in combination with 2-methyl-4-isothiazolin-3- one), formaldehyde, magnesium nitrate (in combination with 2-meth-yl-4-isothiazolin-3- one and 5-chloro-2-methyl-4-isothiazolin-3-one), methyl p-hydroxybenzoate, 2-methyl-4- isothiazolin-3-one (in combination with 5-chloro-2-methyl-4-isothiazolin-3-one), paraformaldehyde, sodium o-phenylphenate, ascorbyl palmitate, benzoic acid, methyl- p-hydroxy
  • Preservatives containing 1 ,2-benzisothiazolin-3-one are preferred.
  • the preservative is present in the fungicidal composition in a stabilizing effective and nitrogen-fixing bacteria tolerant amount.
  • the preservative is present from 0.0001 to about 0.05 % by weight of the composition. More particularly, the preservative is present in an amount of from 0.005 to about 0.02 % by weight, preferably 0.005 to 0.01 % by weight.
  • the inoculent tolerant fungicidal compositions in accordance with the invention may take the form of aqueous solutions, dispersions, suspensions, emulsions or suspoemulsions.
  • the composition is preferably a ready for use solution.
  • the aqueous composition of the invention is substantially free of organic solvents; i.e. the amount of organic solvent is less that 0.5%.
  • Some commercially available materials may contain a small amount of organic solvent, which, when more than about 0.1 % can be removed for example in a separator.
  • the aqueous composition may contain polyhydrate alcohols such as glycerin.
  • the aqueous composition of the invention is substantially free of nonaqueous solvents (0 to 0.5% by weight, preferably 0 to less than about 0.1 % by weight).
  • nonaqueous solvents there may be mentioned N-methyl-2- pyrrolidone and 1 -octyl-2-pyrrolidone.
  • the ready-to-apply (RTA) aqueous compositions according to the invention are stable for at least 12 months at 25°C.
  • the present invention provides an aqueous fungicidal composition, which is substantially free of organic solvents, comprising a) a fungicidally effective amount of at least one fungicidally active compound, b) a stabilizing effective and nitrogen-fixing bacteria tolerant amount of a preservative; and comprising as auxiliaries: d ) at least one anionic surfactant; and c2) at least one nonionic surfactant.
  • composition optionally contains (d) at least one thickener.
  • At least one ambient liquid fungicide for example, a phenylamide such as R- metalaxyl
  • at least one ambient solid fungicide for example, a phenylpyrrole such as fludioxonil
  • mixtures in which the mixing ratio of the active substances l:ll is from 7:1 to 1 :10, e.g. from 7:1 to 1 :1 are advantageous.
  • Other advantageous mixing ratios are 6:1 , 7:2, 2:3.
  • the fungicidally active compound(s) is present in the composition in an amount of from about 0.5 % to about 10 % by weight.
  • suitable auxiliaries include surfactants, thickeners and other agronomically acceptable auxiliaries and adjuvants employed in the pesticide formulation art.
  • Suitable anionic surfactants are in general oligomers and polymers, as well as polycondensates, which contain a sufficient number of anionic groups to ensure their water-solubility.
  • suitable anionic groups are sulfo groups or carboxyl groups; but polymers containing carboxyl groups can only be used in the higher pH range, preferably at a pH higher than 5.
  • the number of anionic groups per polymer molecule is usually at least 60% of the number of monomer units contributing to the structure of the molecule.
  • Oligomers and polymers that contain sulfo groups can be prepared either by polymerising monomers that contain sulfo groups or by sulfonating the appropriate oligomers or polymers.
  • Polymers that contain carboxyl groups can be obtained by saponifying polyacrylates or polymethacrylates, in which case the degree of saponification must be at least 60%.
  • Particularly suitable anionic surfactants are sulfonated polymers and condensates of aromatic sulfonic acids with formaldehyde. Typical examples of such anionic surfactants are:
  • Salts of polystyrenesulfonic acid in particular the alkali metal, alkaline earth metal and ammonium salts, and the salts of organic amines which can be obtained by polymerising styrenesulfonic acid or salts thereof or by sulfonation of polystyrene and subsequent neutralisation with a suitable base, in which latter case the degree of sulfonation must be at least 60%.
  • Salts of polyvinylsulfonic acid in particular the alkali metal, alkaline earth metal and ammonium salts, and the salts with organic amines which can be obtained by polymerising vinylsulfonic acid or salts therof .
  • the molecular weight of these compounds is in the range from about 500 to 6000.
  • These products are sulfo group containing polymers with an average molecular weight of 6000 to 8000, in which the monomer units naphthalene and phenol are linked to each other partly through methylene groups and partly through sulfo groups.
  • Salts of ligninsulfonic acid in particular the sodium, potassium, magnesium, calcium or ammonium salt.
  • Prefered anionic surfactants include -[2,4,6-tris[1 - (phenyl)ethyl]phenyl]-o hydroxypolyoxy(ethylene), mixture of monohydrogen and dihydrogen phosphate esters, such as those having a poly(oxyethylene) content of from about 4 to about 150 moles.
  • Suitable anionic surfactants can be prepared by methods known per se and also are commercially available.
  • the anionic surfactant(s) is present in the composition in an amount of from about 0.3 % to about 5 % by weight.
  • a nonionic surfactant and a thickener may be added additionally to the aqueous fungicidal composition.
  • Suitable nonionic surfactants when present, are in general nonionic water-soluble polymers having an average molecular weight of below 20,000.
  • Particularly suitable nonionic surfactants of this kind are the products which can be obtained by reaction of ethylene oxide, or by the combined reaction of ethylene oxide and propylene oxide, with fatty alcohols, alkylphenols, fatty acids, fatty acid esters of polyhydroxy compounds, fatty acid amides and fatty amines, where the number of ethylene oxide and propylene oxide units may vary within wide limits.
  • the number of ethylene oxide units or ethylene oxide and propylene oxide units is from 1 to 200, preferably from 5 to 100 and, most preferably, from 8 to 40.
  • Preferred nonionic sufactants include ⁇ -butyl-co-hydroxypropyl-(oxypropylene) block polymers with poly(oxyethylene) such as those with a molecular weight of from 2400 to 3500, and -[2,4,6-tris[1 -(phenyl)ethyl]phenyl]- ⁇ -hydroxypolyoxy(eth ' ylene) such as those having a poly(oxyethylene) content of from about 4 to about 150 moles.
  • Suitable nonionic surfactants can be prepared by methods known per se and also are commercially available.
  • thickeners water-soluble polymers which exhibit pseudoplastic properties in an aqueous medium
  • gum arabic gum karaya
  • gum tragacanth gum tragacanth
  • guar gum locust bean gum
  • xanthan gum carrageenan
  • alginate salt casein, dextran, pectin, agar
  • 2- hydroxyethyl starch 2-aminoethyl starch
  • 2-hydroxyethyl cellulose methyl cellulose, carboxymethyl cellulose salt
  • cellulose sulfate salt polyacrylamide, alkali metal salts of the maleic anhydride copolymers, alkali metal salts of poly(meth)acrylate, and the like.
  • Attapulgite-type clay carrageenan, croscarmellose sodium , furcelleran , glycerol, hydroxypropyl methylcellulose, polystyrene, hydroxypropyl cellulose, hydroxypropyl guar gum, and sodium carboxymethylcellulose.
  • Xanthan gum is preferred.
  • aqueous composition according to the invention can be employed together with the adjuvants customary in formulation technology, further carriers, surfactants (cationic, anionic, nonionic, amphoteric), emulsifiers (lethicin, sorbitan, and the like), antifreeze agents (glycerin), dyes, antifoam agents or application-promoting adjuvants customarily employed in the art of formulation.
  • surfactants cationic, anionic, nonionic, amphoteric
  • emulsifiers lethicin, sorbitan, and the like
  • antifreeze agents glycerin
  • dyes antifoam agents or application-promoting adjuvants customarily employed in the art of formulation.
  • inoculants brighteners and polymers.
  • inventive compositions contain and/or may be applied together or sequentially with further active compounds.
  • further compounds can be fertilizers or micronutrient donors or other preparations that influence plant growth. They can also be selective herbicides, insecticides, fungicides, bactericides, insect growth regulators, plant growth regulators, nematicides, molluscicides or mixtures of several of these preparations.
  • sodium molybdate is mentioned as an additional fungicidally active ingredient.
  • the aqueous fungicidal compositions of the invention can be prepared by a process which comprises the steps: (a) forming a premix with a preservative and (i) at least one fungicidally active compound and/or (ii) at least one formulation auxiliary, wherein the preservative in the premix is at a concentration that is toxic to nitrogen-fixing bacteria; (b) diluting the premix of step (a) with water while concurrently or sequentially adding the remaining ingredients; and (c) stirring the mixture to form a homogeneous composition, wherein the preservative is present in the final composition in a stabilizing effective and nitrogen-fixing bacteria tolerant amount.
  • step (b) is carried out sequentially to allow a homogenous precursor composition to be achieved before the additional component(s) are added.
  • solid fungicidally active compounds may be milled prior to being added.
  • the final composition can be screened to remove any insoluble particles.
  • Suitable concentrations of the components in relation to the total weight of the aqueous fungicidal composition comprise:
  • fungicidally active compound or mixture of compounds 1) of the fungicidally active compound or mixture of compounds: 0.5 to 10 %, preferably 0.1 to 5 %, more preferred 0.5 to 2% fungicidally active compounds in relation to the total composition;
  • 3) of the preservative 0.0001 to about 0.05 %, preferably 0.005 to about 0.02 % by weight, more preferred 0.005 to 0.01 % by weight.
  • the aqueous fungicidal compositions of the invention are formulated for protecting cultivated plants and their propagation materials.
  • the inventive compositions are advantageously formulated for seed treatment applications against diseases in the soil, which mostly occur in the early stages of plant development.
  • the compositions can be formulated to target pathogens including Pythium, Tilletia, Gerlachia, Septoria, Ustilago, Fusarium, Rhizoctonia (so-called "damping off complex”); Oomycetes such as Phytophthora, Plasmopara, Pseudoperonospora, Bremia etc. as well as against the Botrytis species, Pyrenophora, Monilinia and further representatives of the Ascomycetes, Deuteromycetes and Basidiomycetes classes.
  • Suitable target crops are especially potatoes, cereals, (wheat, barley, rye, oats, rice), maize, sugar beet, cotton, millet varieties such as sorghum, sun flowers, beans, peas, oil plants such as rape, soybeans, cabbages, tomatoes, eggplants (aubergines), pepper and other vegetables and spices as well as ornamental shrubs and flowers.
  • compositions are particularly suited for dressing applications on plant propagation material.
  • the latter term embraces seeds of all kinds (fruit, tubers, grains), cuttings, cut shoots and the like.
  • the preferred field of application is the treatment of all kinds of seeds (as specified in the target crops above), and in particular the seed treatment of soybeans and other legumes and crops that are susceptible to Rhizobium symbiosis that results from the deliberate coating of a legume seed with the appropriate Rhizobium spp. prior to planting.
  • the techniques of seed treatment application are well known to those skilled in the art, and they may be used readily in the context of the present invention.
  • the aqueous fungicidal composition of the invention is applied to the seed as slurry or a soak.
  • the coating processes are well known in the art, and employ, for seeds, the techniques of film coating or encapsulation, or for the other multiplication products, the techniques of immersion. Needless to say, the method of application of the inventive compositions to the seed may be varied and the invention is intended to include any technique that is to be used.
  • a preferred method of applying the aqueous fungicidal composition according to the invention consists in spraying or wetting the plant propagation material with the aqueous liquid preparation, or mixing the plant material with such liquid preparation.
  • compositions of this invention may be formulated or mixed in the seed treater tank or combined on the seed by overcoating with other seed treating agents.
  • the agents to be mixed with the compounds of this invention may be for the control of pests, nutrition, the control of plant diseases, or for the modification of plant growth, especially with nitrogen-fixing bacteria.
  • the inventive aqueous fungicidal composition has particular application to concurrent (such as by slurry) and sequential seed treatments with a plant growth promoting amount of a nitrogen-fixing bacteria including Rhizobia spp..
  • Suitable Rhizobia formulations can be prepared by methods known per se and also are commercially available.
  • suitable Rhizobia formulations there may be mentioned Cell-Tech 2000 TM available from Lipha Tech (Milwaukee WI).
  • Soprophor BSU (Rhodia) ⁇ -[2,4,6-tris[1 -(phenyl)ethyl]phenyl]- ⁇ - hydroxypolyoxy(ethylene)
  • Soprophor 3D-33 (Rhodia) ⁇ -[2,4,6-tris[1-(phenyl)ethyl]phenyl]- ⁇ - hydroxypolyoxy(ethylene), mixture of monohydrogen and dihydrogen phosphate esters
  • Rhodopol 23 Rhodia
  • Xanthan Gum Proxel GXL Rheneca
  • Example 1 % WT of the total composition. The components are intimately mixed until a homogeneous phase is achieved.
  • Soybean nodulation is evaluated at 37 days after planting. The data was analyzed at a

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Environmental Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Soil Sciences (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Virology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

L'invention concerne une composition fongicide aqueuse, tolérante et inoculante, sensiblement dépourvue de solvants organiques, qui comprend une quantité fongicide efficace d'au moins un agent actif fongicide, une quantité tolérante et stabilisante d'une bactérie de fixation de l'azote d'un agent de conservation, et au moins un tensioactif anionique. La composition est tolérante à une bactérie de fixation de l'azote, tel que le Rhizobium spp, lorsqu'elle est appliquée simultanément ou séquentiellement à des matières de propagation de la plante, telles que des semences. Les compositions de l'invention sont stables au stockage, prêtes à l'emploi, écologiquement et toxicologiquement favorables et des fongicides efficaces.
PCT/EP2001/001745 2000-02-18 2001-02-16 Compositions fongicides tolerantes et inoculantes Ceased WO2001060159A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0108497-6B1A BR0108497B1 (pt) 2000-02-18 2001-02-16 método para reduzir infestação fúngica de plantas, partes de plantas e sementes, e para promover crescimento de planta
CA2400428A CA2400428C (fr) 2000-02-18 2001-02-16 Compositions fongicides tolerantes et inoculantes
AU35482/01A AU3548201A (en) 2000-02-18 2001-02-16 Inoculant tolerant fungicidal compositions
US11/835,726 US20080004179A1 (en) 2001-02-16 2007-08-08 Inoculant tolerant fungicidal compositions

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US50676500A 2000-02-18 2000-02-18
US09/506,765 2000-02-18

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/835,726 Continuation US20080004179A1 (en) 2001-02-16 2007-08-08 Inoculant tolerant fungicidal compositions

Publications (1)

Publication Number Publication Date
WO2001060159A1 true WO2001060159A1 (fr) 2001-08-23

Family

ID=24015919

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/001745 Ceased WO2001060159A1 (fr) 2000-02-18 2001-02-16 Compositions fongicides tolerantes et inoculantes

Country Status (8)

Country Link
CN (2) CN1253083C (fr)
AR (1) AR027435A1 (fr)
AU (1) AU3548201A (fr)
BR (1) BR0108497B1 (fr)
CA (1) CA2400428C (fr)
GT (1) GT200100026A (fr)
TW (1) TWI230036B (fr)
WO (1) WO2001060159A1 (fr)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6884754B1 (en) 2001-09-28 2005-04-26 Syngenta Crop Protection, Inc. Aqueous compositions for seed treatment
US20050187107A1 (en) * 2003-12-23 2005-08-25 Nitragin, Inc. Methods and compositions providing agronomically beneficial effects in legumes and non-legumes
WO2005089546A1 (fr) * 2004-03-16 2005-09-29 Syngenta Participations Ag Compositions pesticides de traitement de semences
WO2005089545A1 (fr) * 2004-03-16 2005-09-29 Syngenta Participations Ag Compositions pesticides pour le traitement des graines
WO2006117192A3 (fr) * 2005-05-03 2007-04-26 Syngenta Participations Ag Compositions pesticides
WO2010124973A3 (fr) * 2009-04-27 2011-01-06 Basf Se Composition comprenant un pesticide, un conservateur et un 1,2-alcanediol non ramifié
WO2012025534A1 (fr) 2010-08-24 2012-03-01 Euroferm Gmbh Produit phytosanitaire contenant des virus entomopathogènes, notamment des baculovirus et du sulfate de cellulose
WO2012025533A1 (fr) 2010-08-24 2012-03-01 Euroferm Gmbh Procédé de protection des cultures à l'aide de virus entomopathogènes et de sulfate de cellulose
WO2014079771A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
WO2014079730A1 (fr) * 2012-11-23 2014-05-30 Basf Se Mélanges pesticides

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5149171B2 (ja) * 2005-06-30 2013-02-20 シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト 機能強化製剤
CN101856024A (zh) * 2010-05-27 2010-10-13 江苏天禾宝农化有限责任公司 一种防治棉花苗期病害的种衣剂及其制备方法

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4161397A (en) * 1977-08-08 1979-07-17 Kalo Laboratories, Inc. Liquid combination seed treatment compositions
US4306027A (en) * 1976-09-10 1981-12-15 Cornell Research Foundation, Inc. Pesticidally resistant rhizobium and agronomic use thereof
US4755468A (en) * 1981-12-29 1988-07-05 Rhone-Poulenc S.A. Inocula of low water activity with improved resistance to temperature and rehydration, and preparation thereof
EP0609099A1 (fr) * 1993-01-28 1994-08-03 Sankyo Company Limited Compositions antimicrobiennes et antifongique contenant composés de silicium, et leur utilisation par l'agriculture et l'horticulture
WO1995000019A2 (fr) * 1993-06-18 1995-01-05 Zeneca Limited Formulation aqueuse stable de benzisothiazolin-3-one et gomme de xanthane________________________________________________________
EP0790000A1 (fr) * 1996-02-15 1997-08-20 Novartis AG Microbicides
US5684025A (en) * 1995-07-21 1997-11-04 Huls America Inc. Liquid formulations of 1,2-benzisothiazolin-3-one
US5846905A (en) * 1993-12-22 1998-12-08 Clariant Gmbh Oil-in-water emulsions
WO1999040784A1 (fr) * 1998-02-10 1999-08-19 Novartis Ag Compositions pesticides

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4306027A (en) * 1976-09-10 1981-12-15 Cornell Research Foundation, Inc. Pesticidally resistant rhizobium and agronomic use thereof
US4161397A (en) * 1977-08-08 1979-07-17 Kalo Laboratories, Inc. Liquid combination seed treatment compositions
US4755468A (en) * 1981-12-29 1988-07-05 Rhone-Poulenc S.A. Inocula of low water activity with improved resistance to temperature and rehydration, and preparation thereof
EP0609099A1 (fr) * 1993-01-28 1994-08-03 Sankyo Company Limited Compositions antimicrobiennes et antifongique contenant composés de silicium, et leur utilisation par l'agriculture et l'horticulture
WO1995000019A2 (fr) * 1993-06-18 1995-01-05 Zeneca Limited Formulation aqueuse stable de benzisothiazolin-3-one et gomme de xanthane________________________________________________________
US5846905A (en) * 1993-12-22 1998-12-08 Clariant Gmbh Oil-in-water emulsions
US5684025A (en) * 1995-07-21 1997-11-04 Huls America Inc. Liquid formulations of 1,2-benzisothiazolin-3-one
EP0790000A1 (fr) * 1996-02-15 1997-08-20 Novartis AG Microbicides
WO1999040784A1 (fr) * 1998-02-10 1999-08-19 Novartis Ag Compositions pesticides

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7199081B2 (en) 2001-09-28 2007-04-03 Syngenta Crop Protection, Inc. Aqueous compositions for seed treatment
US6884754B1 (en) 2001-09-28 2005-04-26 Syngenta Crop Protection, Inc. Aqueous compositions for seed treatment
US20050187107A1 (en) * 2003-12-23 2005-08-25 Nitragin, Inc. Methods and compositions providing agronomically beneficial effects in legumes and non-legumes
AP2269A (en) * 2004-03-16 2011-08-04 Syngenta Participations Ag Seed treatment pesticidal compositions.
US8476192B2 (en) 2004-03-16 2013-07-02 Syngenta Crop Protection Llc Seed treatment pesticidal compositions
WO2005089546A1 (fr) * 2004-03-16 2005-09-29 Syngenta Participations Ag Compositions pesticides de traitement de semences
WO2005089545A1 (fr) * 2004-03-16 2005-09-29 Syngenta Participations Ag Compositions pesticides pour le traitement des graines
WO2006117192A3 (fr) * 2005-05-03 2007-04-26 Syngenta Participations Ag Compositions pesticides
EA014933B1 (ru) * 2005-05-03 2011-04-29 Зингента Партисипейшнс Аг Пестицидные композиции
US8691727B2 (en) 2005-05-03 2014-04-08 Syngenta Crop Protection, Llc Pesticidal compositions
EA018690B1 (ru) * 2005-05-03 2013-09-30 Зингента Партисипейшнс Аг Нематоцидные композиции
WO2010124973A3 (fr) * 2009-04-27 2011-01-06 Basf Se Composition comprenant un pesticide, un conservateur et un 1,2-alcanediol non ramifié
WO2012025533A1 (fr) 2010-08-24 2012-03-01 Euroferm Gmbh Procédé de protection des cultures à l'aide de virus entomopathogènes et de sulfate de cellulose
CN103179854A (zh) * 2010-08-24 2013-06-26 欧罗弗姆有限公司 用昆虫病原病毒和硫酸纤维素保护植物的方法
DE102010037140A1 (de) * 2010-08-24 2012-03-01 EuroFerm Gesellschaft für Fermentation und Messtechnik mbH Verfahren zum Schutz von Pflanzen
DE102010037141A1 (de) * 2010-08-24 2012-03-01 EuroFerm Gesellschaft für Fermentation und Messtechnik mbH Pflanzenschutzmittel enthaltend insektenpathogene Viren, insbesondere Baculoviren und Zellulosesulfat
WO2012025534A1 (fr) 2010-08-24 2012-03-01 Euroferm Gmbh Produit phytosanitaire contenant des virus entomopathogènes, notamment des baculovirus et du sulfate de cellulose
WO2014079771A1 (fr) * 2012-11-22 2014-05-30 Basf Se Mélanges pesticides
WO2014079730A1 (fr) * 2012-11-23 2014-05-30 Basf Se Mélanges pesticides

Also Published As

Publication number Publication date
BR0108497A (pt) 2003-03-18
GT200100026A (es) 2002-02-21
TWI230036B (en) 2005-04-01
CA2400428A1 (fr) 2001-08-23
CN1820600A (zh) 2006-08-23
AU3548201A (en) 2001-08-27
AR027435A1 (es) 2003-03-26
CN1253083C (zh) 2006-04-26
CA2400428C (fr) 2013-09-03
CN1418059A (zh) 2003-05-14
BR0108497B1 (pt) 2013-07-16

Similar Documents

Publication Publication Date Title
US7071188B2 (en) Composition and method for improving plant growth
US20080004179A1 (en) Inoculant tolerant fungicidal compositions
CA2400428C (fr) Compositions fongicides tolerantes et inoculantes
CN1946294B (zh) 用于种子处理的农药组合物和方法
EP2793574A1 (fr) Formulations de strobilurine
CN101536654A (zh) 减轻线虫损害的方法
CN101534645A (zh) 增强植物内在生产力的方法
KR100437065B1 (ko) 살진균제
JP4287515B2 (ja) 植物病害の予防用組成物およびその使用方法
WO2015007250A1 (fr) Mélange fongicide
CN101541177A (zh) 增强植物耐受性的方法
JPH0717811A (ja) 殺微生物剤
WO2024069656A1 (fr) Composition insecticide comprenant du n-(cyanométhyl)-4-(trifluorométhyl)-3-pyridinecarboxamide
TW201709822A (zh) 除草組成物及用於控制植物生長之方法
JP2007529453A (ja) 種子処理殺虫組成物
CN1311742C (zh) 含吡啶基甲基苯甲酰胺衍生物和百菌清的杀真菌组合物
EA014774B1 (ru) Применение киралаксила для защиты от фитопатогенов и соответствующие способы и композиции
CN103348989A (zh) 一种杀真菌混合物
WO2003011029A1 (fr) Composition permettant de lutter contre une bacterie pathogene de plante et procede de lutte contre ladite bacterie pathogene de plante
WO2022129552A1 (fr) Procédés de régulation ou de prévention de l'infestation de plantes par un micro-organisme phytopathogène du genre aspergillus
CN113149775A (zh) 一种含芳基吡咯腈与甲氧基丙烯酸酯的控释药肥粒剂
CN106889077B (zh) 含有吩乙霉素和丙硫菌唑的杀菌组合物及其应用
AU755982B2 (en) Fungicidal compositions based on metalaxyl
WO2024246953A1 (fr) Composition fongicide ternaire comprenant du prothioconazole et de la strobilurine et un autre fongicide
RU2171576C2 (ru) Фунгицидный двухкомпонентный препарат и способ борьбы и предупреждения поражения грибами

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
WWE Wipo information: entry into national phase

Ref document number: 10204116

Country of ref document: US

Ref document number: 2400428

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 018067638

Country of ref document: CN

REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP