WO2012118199A1 - 蒸着装置、蒸着方法、有機elディスプレイ、及び照明装置 - Google Patents
蒸着装置、蒸着方法、有機elディスプレイ、及び照明装置 Download PDFInfo
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- WO2012118199A1 WO2012118199A1 PCT/JP2012/055445 JP2012055445W WO2012118199A1 WO 2012118199 A1 WO2012118199 A1 WO 2012118199A1 JP 2012055445 W JP2012055445 W JP 2012055445W WO 2012118199 A1 WO2012118199 A1 WO 2012118199A1
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/12—Organic material
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/24—Vacuum evaporation
- C23C14/243—Crucibles for source material
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/164—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using vacuum deposition
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/17—Passive-matrix OLED displays
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/30—Devices specially adapted for multicolour light emission
- H10K59/35—Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/10—Deposition of organic active material
- H10K71/16—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering
- H10K71/166—Deposition of organic active material using physical vapour deposition [PVD], e.g. vacuum deposition or sputtering using selective deposition, e.g. using a mask
Definitions
- the present invention relates to an evaporation technique for evaporating a film forming material and depositing it as a thin film on a substrate, and more particularly to an evaporation apparatus, an evaporation method, an organic EL display, and an illumination apparatus for forming a line-shaped thin film pattern.
- organic EL (electroluminescence) displays have high expectations as flat panel displays (FPDs) that will lead the next generation. Since organic EL displays are self-luminous and do not require a backlight, they are easy to reduce the thickness and weight, and are extremely excellent in terms of viewing angle, resolution, contrast, response speed, power consumption, and flexibility. Yes. However, for the reasons described later, enlargement and mass productivity are major issues.
- the light emission principle of organic EL is that a light emitting layer made of an organic substance is sandwiched between two electrodes (anode and cathode) and energized, that is, holes are injected from the anode side and simultaneously electrons are injected from the cathode side. The holes and electrons are recombined in the light emitting layer (exciting the light emitting layer), and light is generated when the excited state returns to the ground state again.
- vapor deposition is performed using a so-called shadow mask made of a metal having a hole at a position corresponding to a position where a film forming material is to be deposited on a substrate.
- a shadow mask is placed in front of the substrate, and a film forming material is deposited through the opening of the shadow mask.
- the color-arranged juxtaposition method as described above, since the patterns of the R, G, and B light emitting layers are the same, by shifting the position of the same shadow mask in parallel with the substrate, R, G, and B Each color light emitting layer can be applied separately by vapor deposition.
- the mask vapor deposition method as described above has many problems and has become a big foothold in the production of organic EL displays.
- Shadow masks there are many problems related to shadow masks.
- High definition shadow masks are very expensive.
- the organic material used for each color light emitting layer of R, G, and B is also very expensive.
- the proportion of the shadow mask opening in the total area of the mask is very small, and most of the evaporation material (generally 95% or more) adheres to the mask and adheres as a light emitting layer on the substrate, that is, an organic material.
- the utilization efficiency is less than 5%.
- the alignment positioning of the shadow mask. If the alignment is not performed correctly, for example, the R light emitting layer and the G light emitting layer overlap each other, which causes a decrease in yield. On the other hand, even if the alignment is accurate, there is an error in mask accuracy (opening pattern size error, alignment error, etc.) due to thermal expansion of the shadow mask that receives heat radiation from the high-temperature gas heated and evaporated during the film formation process. ) May occur. Furthermore, the back surface of the shadow mask may rub against the surface of the substrate and damage the thin film (light emitting layer) on the substrate. *
- the mask vapor deposition method performs vapor deposition over the entire surface of the substrate for each color of R, G, and B, in order to increase the throughput as much as possible in this way, for each color of R, G, and B An independent film forming chamber (processing chamber) is prepared, and the substrate is sequentially transferred to the film forming chamber for each color together with the shadow mask.
- processing chamber processing chamber
- an independent film forming chamber for each color of R, G, and B is naturally a great disadvantage in terms of space efficiency (footprint) and cost of the organic EL display manufacturing apparatus.
- an ordinary organic EL display sandwiches not only the light emitting layer but also an electron transport layer and a hole transport layer, and organic thin films such as an electron injection layer and a hole injection layer between the anode and the cathode.
- the mask vapor deposition method is used for coating the R, G, and B light emitting layers separately, separate film forming chambers are also required in the process of depositing these organic thin films due to throughput requirements as described above. Therefore, the above-described footprint and high cost problems in an actual manufacturing apparatus are becoming more serious.
- the mask vapor deposition method using the shadow mask has become a big footstep in promoting the enlargement of the screen and mass productivity of the organic EL display.
- the present invention solves the above-described problems of the prior art, and provides a vapor deposition apparatus and a vapor deposition method that can efficiently coat a plurality of line-shaped thin films on a substrate without using a shadow mask.
- the vapor deposition apparatus of the present invention includes a processing chamber that accommodates a substrate to be processed, a moving mechanism that moves the substrate in the first direction in the processing chamber, and a first raw material by evaporating the first film forming raw material.
- a first evaporation source for generating a gas; a first injection port; receiving the first source gas from the first evaporation source; and moving toward the substrate moving in the processing chamber.
- a first nozzle for injecting the first source gas from the injection port, a second evaporation source for generating a second source gas by evaporating the second film forming source, and the first direction.
- a second injection port that is offset from the first injection port in a second direction that intersects, receives the second source gas from the second evaporation source, and moves in the processing chamber;
- a second nozzle that injects the second source gas from the second injection port toward the substrate.
- the first source gas is deposited on the substrate to form a first line-shaped thin film extending in the first direction and at a distance from the first line-shaped thin film Then, the second source gas is deposited to form a second line-shaped thin film extending in the first direction.
- the shadow mask is formed by ejecting the first and second source gases to the first and second nozzles while scanning and moving the substrate once in the first direction in the processing chamber.
- the first and second on-line thin films can be formed on the substrate appropriately separated, that is, separately applied.
- a vapor deposition method includes a step of moving a substrate in a processing chamber in a first direction, a step of evaporating a first film forming raw material to generate a first raw material gas, Injecting the first source gas from a first injection port toward the substrate moving in a processing chamber; and depositing the first source gas on the substrate in the first direction.
- a step of injecting the second source gas from a second injection port that is offset from the first injection port in a second direction that intersects the direction, and the first line shape on the substrate Depositing the second source gas at a position spaced from the thin film; And forming a second linear thin film extending in serial first direction.
- the first and second source gases are ejected to the first and second nozzles while the substrate is scanned and moved once in the first direction in the processing chamber.
- the first and second line-shaped thin films can be appropriately separated, that is, separately formed on the substrate.
- the vapor deposition method includes a step of moving a substrate in a processing chamber in a first direction, a step of evaporating a first film forming raw material to generate a first raw material gas, A step of ejecting the first source gas from a first outlet toward the substrate moving in a processing chamber; and depositing the first source gas on the substrate to extend in the first direction. Forming a first line-shaped thin film; evaporating a second film forming raw material to generate a second raw material gas; and moving the first thin film toward the substrate moving in the processing chamber. A step of jetting the second source gas from the second jet port that is offset from the first jet port in a second direction that intersects with the first line-shaped thin film on the substrate.
- the second source gas is deposited at a spaced position. Forming a second line-shaped thin film extending in the first direction, evaporating a third film-forming raw material to generate a third raw material gas, and forming the third source gas on the substrate moving in the processing chamber And ejecting the third source gas from a third jet port offset from the first and second jet ports in a second direction intersecting the first direction, and on the substrate And depositing the third source gas at a position spaced from the first and second line-shaped thin films to form a third line-shaped thin film extending in the first direction.
- the first, second, and third source gases are moved to the first, second, and third nozzles while the substrate is scanned and moved once in the first direction in the processing chamber.
- the thin films on the first, second and third lines can be appropriately separated on the substrate without using a shadow mask, that is, separately formed.
- a vapor deposition method includes a step of moving a substrate in a processing chamber in a first direction, a step of evaporating a first film forming raw material to generate a first raw material gas, A step of ejecting the first source gas from a first outlet toward the substrate moving in a processing chamber; and depositing the first source gas on the substrate to extend in the first direction.
- a step of ejecting the second source gas from a second jet port that is offset from the first jet port in a second direction that intersects with the first line-shaped thin film on the substrate is deposited at the position where Forming a second line-shaped thin film extending in a first direction; evaporating a third film-forming raw material to generate a third raw material gas; and toward the substrate moving in the processing chamber Ejecting the third source gas from a third jet port offset from the first and second jet ports to the downstream side of the movement of the substrate in the first direction; And depositing the third source gas on the first and second line-shaped thin films to form a first planar thin film.
- the first, second, and third source gases are moved to the first, second, and third nozzles while the substrate is scanned and moved once in the first direction in the processing chamber.
- the first and second on-line thin films are appropriately separated on the substrate without using a shadow mask, that is, separately formed, and the first and second on-line thin films are formed.
- a first planar thin film can be formed that fills the gaps and covers them.
- a vapor deposition method includes a step of moving a substrate in a processing chamber in a first direction, a step of evaporating a first film forming raw material to generate a first raw material gas, A step of ejecting the first source gas from a first outlet toward the substrate moving in a processing chamber; and depositing the first source gas on the substrate to extend in the first direction.
- a step of ejecting the second source gas from a second jet port that is offset from the first jet port in a second direction that intersects with the first line-shaped thin film on the substrate is deposited at the position where Forming a second line-shaped thin film extending in a first direction; evaporating a third film-forming raw material to generate a third raw material gas; and toward the substrate moving in the processing chamber Ejecting the third source gas from a third jet port offset from the first and second jet ports to the upstream side of the movement of the substrate in the first direction; And forming a first planar thin film by depositing the third source gas prior to the formation of the first and second line-shaped thin films.
- the first, second, and third source gases are moved to the first, second, and third nozzles while the substrate is scanned and moved once in the first direction in the processing chamber.
- the first and second on-line thin films are appropriately separated on the substrate without using a shadow mask, that is, separately formed, and the first and second on-line thin films are formed.
- a first planar thin film can be formed as the underlying film.
- a plurality of line-shaped thin films can be efficiently coated on the substrate without using a shadow mask by the above-described configuration and operation.
- the vapor deposition apparatus of this embodiment is used in a process of laminating and forming a plurality of types of organic layers including a light emitting layer on a transparent substrate such as a glass substrate.
- the vapor deposition apparatus of this embodiment includes a hole injection layer (HIL), a hole transport layer (HTL), an R • G • B light emitting layer (REL / GEL / BEL), an electron transport layer (ETL).
- the transparent anode is made of, for example, ITO (indium tin oxide), and is formed in the previous step by another film forming apparatus such as a sputtering apparatus.
- the cathode is made of, for example, an aluminum alloy, and is formed in a later process by another film forming apparatus such as a sputtering apparatus.
- FIG. 1 the structure of the vapor deposition apparatus in one Embodiment of this invention is shown.
- FIG. 2 the structure of the principal part (raw material gas ejection part) of this vapor deposition apparatus is shown.
- this vapor deposition apparatus has, as a basic configuration, a processing chamber (chamber) 10 in which a glass substrate S to be processed is accommodated so as to be put in and out, and a substrate S held in the processing chamber 10 to be horizontal.
- a moving mechanism 12 that moves in one direction (X direction)
- an evaporation mechanism 14 that individually evaporates the raw materials or film forming materials of the plurality of types (seven types) of organic layers, and generates a raw material gas
- the evaporation mechanism 14 receives the above-described plural types (seven types) of source gases, and controls the source gas ejection unit 16 for ejecting the source gases toward the moving substrate S, and the status, mode, or operation of each unit in the apparatus and the whole.
- a controller 18 controls the source gas ejection unit 16 for ejecting the source gases toward the moving substrate S, and the status, mode, or operation of each unit in the apparatus and the whole.
- the processing chamber 10 is configured to be able to be depressurized, and is connected to an exhaust device (not shown) such as a vacuum pump through an exhaust port 20 formed on a side wall or a bottom surface thereof.
- an exhaust device such as a vacuum pump through an exhaust port 20 formed on a side wall or a bottom surface thereof.
- a substrate loading / unloading opening 24 that is opened and closed by a gate valve 22 is also formed on the side wall of the processing chamber 10.
- the moving mechanism 12 is coupled to the substrate holding table or stage 26 that holds the substrate S face down (with the processing surface of the substrate facing down), and the stage 26, and moves along the ceiling of the processing chamber 10 in the X direction. And a scanning unit 28 that slides at a constant speed.
- the stage 26 is embedded with an electrostatic chuck (not shown) that is electrically connected to a high-voltage DC power source (not shown) via a switch and detachably holds the substrate S by an electrostatic adsorption force. Yes.
- the stage 26 is also provided with a temperature adjustment mechanism for cooling the substrate S to a predetermined temperature.
- a cooling passage is formed inside the stage 26, and cooling water of a predetermined temperature is circulated and supplied from an external chiller device (not shown).
- the scanning unit 28 includes, for example, a linear motor (not shown) as a slide movement driving unit.
- the evaporation mechanism 14 has the number (seven) of evaporation sources 30 (1) to 30 (7) corresponding to the types (seven types) of thin films formed on the substrate S in this vapor deposition apparatus.
- the HIL evaporation source 30 (1) generates an HIL source gas by heating and evaporating an organic film-forming material that is a source of the hole injection layer (HIL) in a container such as a crucible.
- the HTL evaporation source 30 (2) generates an HTL source gas by heating and evaporating an organic film forming material that is a source of the hole transport layer (HTL) in the crucible.
- the REL evaporation source 30 (3) heats and evaporates an organic film forming material that is a raw material of the R light emitting layer (REL) in the crucible to generate a REL source gas.
- the GEL evaporation source 30 (4) heats and evaporates an organic film forming material which is a raw material of the G light emitting layer (GEL) in the crucible to generate a GEL raw material gas.
- the BEL evaporation source 30 (5) heats and evaporates an organic film forming material which is a raw material of the B light emitting layer (BEL) in a crucible to generate a BEL raw material gas.
- the ETL evaporation source 30 (6) generates an ETL source gas by heating and evaporating an organic film-forming material that is a source of the electron transport layer (ETL) in the crucible.
- the EIL evaporation source 30 (7) heats and evaporates an organic film forming material that is a raw material of the electron injection layer (EIL) in the crucible to generate an EIL raw material gas.
- Each of the evaporation sources 30 (1) to 30 (7) has a built-in or attached resistance heating element 32 (1) to 32 (7) made of a high melting point material, for example, as a heater for heating each film forming material. is doing.
- the heater power supply unit 34 supplies current to each of the resistance heating elements 32 (1) to 32 (7) individually, and heats the evaporation sources 30 (1) to 30 (7) (for example, 200 ° C. to 500 ° C.). ) Is controlled independently.
- the evaporation mechanism 14 includes a carrier gas supply mechanism 36 for mixing the source gas generated in each of the evaporation sources 30 (1) to 30 (7) with the carrier gas and transporting it to the source gas ejection unit 16.
- the carrier gas supply mechanism 36 includes a carrier gas supply source 38 for sending an inert gas (for example, argon gas, helium gas, krypton gas, or nitrogen gas) as a carrier gas, and the carrier gas supply source 38 as an evaporation source 30 (1 ) To 30 (7), which are individually connected to a plurality (seven) of gas pipes 40 (1) to 40 (7), and a plurality of gas pipes 40 (1) to 40 (7) ( 7) open / close valves 42 (1) to 42 (7) and mass flow controllers (MFC) 44 (1) to 44 (7).
- the mass flow controllers (MFC) 44 (1) to 44 (7) independently control the pressure or flow rate of the carrier gas flowing through the gas pipes 40 (1) to 40 (7) under the control of the controller 18. It is supposed to be.
- the raw material gas ejection section 16 is provided in the processing chamber 10 with a plurality (seven) of nozzles 46 (1) to 46 (7) respectively corresponding to the plurality (seven) of the evaporation sources 30 (1) to 30 (7). ).
- These nozzles 46 (1) to 46 (7) are all long nozzles, and are arranged in a line in the scanning direction (X direction) in the processing chamber 10, and each is arranged in the scanning direction (X It extends long in the horizontal direction (Y direction) intersecting at right angles to the direction), and the raw material gas is jetted upward from the jet ports formed on the respective upper surfaces.
- the HIL nozzle 46 (1) is connected to the HIL evaporation source 30 (1) via a gas pipe 48 (1) that penetrates the bottom wall of the processing chamber 10, and is scanned or deposited by the moving mechanism 12. It is arranged at the most upstream position closest to the scanning start position.
- the HTL nozzle 46 (2) is connected to the HTL evaporation source 30 (2) via a gas pipe 48 (2) penetrating the bottom wall of the processing chamber 10, and is in the second position in the order of vapor deposition scanning, that is, HIL. It is arranged at a position adjacent to the downstream side of the nozzle 46 (1).
- the REL nozzle 46 (3) is connected to the REL evaporation source 30 (3) through a gas pipe 48 (3) that penetrates the bottom wall of the processing chamber 10, and is in the third position in the order of vapor deposition scanning. That is, it is arranged at a position adjacent to the downstream side of the HTL nozzle 46 (2).
- the GEL nozzle 46 (4) is connected to the GEL evaporation source 30 (4) through a gas pipe 48 (4) penetrating the bottom wall of the processing chamber 10, and is in the fourth position in the order of vapor deposition scanning, that is, REL. It is arranged at a position adjacent to the downstream side of the nozzle 46 (3).
- the BEL nozzle 46 (5) is connected to the REL evaporation source 30 (5) through a gas pipe 48 (5) penetrating the bottom wall of the processing chamber 10, and is in the fifth position, that is, GEL in the order of vapor deposition scanning. It is arranged at a position adjacent to the downstream side of the nozzle 46 (5).
- the ETL nozzle 46 (6) is connected to the ETL evaporation source 30 (6) through a gas pipe 48 (6) that penetrates the bottom wall of the processing chamber 10, and is the sixth position in the order of vapor deposition scanning. That is, it is arranged at a position adjacent to the downstream side of the BEL nozzle 46 (5).
- the EIL nozzle 46 (7) is connected to the EIL evaporation source 30 (7) via a gas pipe 48 (7) penetrating the bottom wall of the processing chamber 10, and is located at the last position in the order of vapor deposition scanning, that is, ETL. It is arranged at a position adjacent to the downstream side of the nozzle 46 (6).
- the gas pipes 48 (1) to 48 (7) are provided with on-off valves 50 (1) to 50 (7), respectively. These on-off valves 50 (1) to 50 (7) are opened and closed (on / off) independently under the control of the controller 18. In order to prevent the deposition material from adhering in the gas pipes 48 (1) to 48 (7), it is desirable to heat from the surroundings with a heater (not shown). The same applies to the gas pipes 40 (1) to 40 (7) for the carrier gas.
- the nozzles 46 (1) to 46 (7) have jet outlets 52 (1) to 52 (7), respectively. More specifically, jets extending in a slit shape in the longitudinal direction of the nozzle (Y direction) are formed on the upper surfaces of the HIL nozzle 46 (1), the HTL nozzle 46 (2), the ETL nozzle 46 (6), and the EIL nozzle 46 (7). Outlets 52 (1), 52 (2), 52 (6), and 52 (7) are respectively formed. These nozzles 46 (1), 46 (2), 46 (6), 46 (7) have respective slit-shaped outlets 52 (1), 52 (2), 52 (6), 52 (7). Each of the height positions (FIG. 4) separates a relatively far distance DL (usually 10-20 mm) suitable for forming a planar thin film with respect to the substrate S passing directly above them during the vapor deposition process. Has been placed.
- DL relatively far distance
- the respective outlets 52 (3), 52 (4), 52 (5) have the same diameter K, and the nozzle longitudinal direction ( They are offset by P / 3 from each other in the Y direction (FIG. 6).
- the interval or pitch P in the nozzle longitudinal direction (Y direction) at each of the ejection ports 52 (3), 52 (4), 52 (5) substantially matches the pixel size in the organic EL display.
- the diameter K and the distance interval DS of each of the ejection ports 52 (3), 52 (4), 52 (5) are in accordance with the cosine method shown in FIG. 3A and FIG. The value is selected depending on the line width W of the layer (REL / GEL / BEL).
- the REL nozzle 46 (3), the GEL nozzle 46 (4), and the BEL nozzle 46 (5) for forming the line-shaped thin film (R / G / B light-emitting layer) are provided at the respective outlets 52 (3 ), 52 (4), 52 (5), the source gas is squeezed very finely and ejected toward the substrate processing surface at the closest distance DS, so that the ejected source gas is in all directions, particularly in the substrate scanning direction ( Does not diffuse in the X direction).
- the controller 18 controls the moving mechanism 12 so that the substrate S faces the stage 26. Install it down. At this time, the stage 26 is brought close to the loading / unloading port 24 to load the substrate S, and then the stage 26 is moved to a scanning start position far from the loading / unloading port 24. After the loading of the substrate S is completed, the gate valve 22 is closed, and the interior of the processing chamber 10 is reduced to a predetermined vacuum pressure by the exhaust device. Note that an anode (ITO) is formed on the surface to be processed of the substrate S carried into the processing chamber 10 in a previous process by another film forming apparatus (for example, a sputtering apparatus).
- ITO an anode
- the controller 18 controls the vapor deposition mechanism 14 to a standby state in accordance with the timing of loading the substrate S. For example, immediately before the substrate S is carried in, the heater power source 34 is turned on to prepare heating and evaporation of each film forming material in each of the evaporation sources 30 (1) to 30 (7). However, the on-off valves 50 (1) to 50 (7) are closed and the raw material gas ejection part 16 is stopped.
- the controller 18 causes the moving mechanism 12 to start the scanning movement of the stage 26 in order to execute the vapor deposition process on the substrate S. Then, when the front end of the substrate S reaches the front of the HIL nozzle 46 (1) in the scanning movement, the controller 18 starts the opening / closing valve 42 (1) of the carrier gas supply pipe 40 (1) and the source gas at a predetermined timing.
- the on-off valve 50 (1) of the supply pipe 48 (1) is switched from the previous closed (off) state to the open (on) state.
- the HIL nozzle 46 (1) starts to eject the HIL source gas (more precisely, a mixed gas of the HIL source gas and the carrier gas).
- the mass flow controller (MFC) 44 (1) sets the gas ejection pressure or flow rate of the HIL nozzle 46 (1) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (1). Control.
- the HIL nozzle 46 (1) ejects the HIL raw material gas from the slit-type ejection port 52 (1) in a strip shape directly above.
- the HIL source gas ejected in a band shape hits the surface of the substrate S to be processed passing right above the band, and is condensed and deposited at the position hitting the band shape.
- FIGS. 4 and 5 while the substrate S passes above the HIL nozzle 46 (1) at a constant speed in the scanning movement direction (X direction), from the front end to the rear end of the substrate S.
- a thin film of a hole injection layer (HIL) is formed in a planar shape with a constant thickness so as to cover the entire surface to be processed of the substrate.
- the controller 18 causes the opening / closing valve 42 (2) of the carrier gas supply pipe 40 (2) and the source gas at a predetermined timing.
- the on-off valve 50 (2) of the supply pipe 48 (2) is switched from the previous closed (off) state to the open (on) state.
- the HTL nozzle 46 (2) starts to eject the HTL source gas (more precisely, a mixed gas of the HTL source gas and the carrier gas).
- the on-off valves 42 (2) and 50 (2) are held in the open (on) state, and the HTL nozzle 46 (2) is turned on.
- the mass flow controller (MFC) 44 (2) sets the gas ejection pressure or flow rate of the HTL nozzle 46 (2) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (2). Control.
- the HTL nozzle 46 (2) ejects the HTL source gas from the slit-type nozzle 52 (2) in a strip shape directly above.
- the HTL source gas blown out in a belt-like shape hits the surface of the substrate S to be processed passing above, and is condensed and deposited at the position where the belt hits.
- FIGS. 4 and 5 while the substrate S passes above the HTL nozzle 46 (2) at a constant speed in the scanning movement direction (X direction), from the front end to the rear end of the substrate S.
- a thin film of the hole transport layer (HTL) is formed in a planar shape with a constant film thickness so as to follow the hole injection layer (HIL).
- the controller 18 reads the opening / closing valve 42 (3) of the carrier gas supply pipe 40 (3) and the source gas at a predetermined timing.
- the on-off valve 50 (3) of the supply pipe 48 (3) is switched from the previous closed (off) state to the open (on) state.
- the REL nozzle 46 (3) starts to eject the REL source gas (more precisely, a mixed gas of the REL source gas and the carrier gas).
- the on-off valves 42 (3) and 50 (3) are held in the open (on) state, and the REL nozzle 46 (3) is turned on.
- the REL source gas is continuously blown out.
- the mass flow controller (MFC) 44 (3) sets the gas ejection pressure or flow rate of the REL nozzle 46 (3) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (3). Control.
- the REL nozzle 46 (3) ejects the REL raw material gas from the porous jet port 52 (3) in a comb-teeth shape directly above.
- the REL source gas ejected in a comb-like shape discretely hits the surface to be processed of the substrate S that passes directly above, and is condensed and deposited at each discrete position.
- the substrate S passes from the front end to the rear end of the substrate S while passing over the REL nozzle 46 (3) at a constant speed in the scanning movement direction (X direction).
- HIL hole injection layer
- HTL hole transport layer
- REL R light emitting layer
- the controller 18 sets the opening / closing valve 42 (4) and the opening / closing valve 42 (4) of the carrier gas supply pipe 40 (4) at a predetermined timing.
- the on-off valve 50 (4) of the source gas supply pipe 48 (4) is switched from the previous closed (off) state to the open (on) state.
- the GEL nozzle 46 (4) starts to eject the REL source gas (more precisely, a mixed gas of the GEL source gas and the carrier gas).
- the mass flow controller (MFC) 44 (4) sets the gas ejection pressure or flow rate of the GEL nozzle 46 (4) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (4). Control.
- the GEL nozzle 46 (4) jets the GEL source gas from the porous jet port 52 (4) in a comb-teeth shape directly above.
- the GEL source gas ejected in a comb-like shape discretely hits the surface to be processed of the substrate S passing directly above, and is condensed and deposited at each of the discrete positions.
- FIGS. 4, 5, and 6 while the substrate S passes over the GEL nozzle 46 (4) at a constant speed in the scanning movement direction (X direction), the front end to the rear end of the substrate S are used.
- a certain gap g is opened next to the R emission layer (REL) so as to follow the hole injection layer (HIL), the hole transport layer (HTL), and the R emission layer (REL).
- a plurality of thin films of the G light emitting layer (GEL) are formed in a line with a constant film thickness and a constant interval P.
- the controller 18 sets the on-off valve 42 (5) and the opening / closing valve 42 (5) of the carrier gas supply pipe 40 (5) at a predetermined timing.
- the on-off valve 50 (5) of the source gas supply pipe 48 (5) is switched from the previous closed (off) state to the open (on) state.
- the BEL nozzle 46 (5) starts to eject the BEL source gas (more precisely, a mixed gas of the BEL source gas and the carrier gas).
- the mass flow controller (MFC) 44 (5) sets the gas ejection pressure or flow rate of the BEL nozzle 46 (5) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (5). Control.
- the BEL nozzle 46 (5) jets the BEL source gas from its porous jet 52 (5) in a comb-teeth shape directly above.
- the BEL source gas blown out in a comb shape discretely hits the surface to be processed of the substrate S passing directly above, and is condensed and deposited at each of the discrete positions.
- FIGS. 4, 5, and 6 while the substrate S passes above the BEL nozzle 46 (5) at a constant speed in the scanning movement direction (X direction), the front end to the rear end of the substrate S are used.
- the thin film of the B light emitting layer (BEL) has a constant film thickness and a constant interval P. Many lines are formed in line.
- the controller 18 starts the opening / closing valve 42 (6) of the carrier gas supply pipe 40 (6) and the source gas at a predetermined timing.
- the on-off valve 50 (6) of the supply pipe 48 (6) is switched from the previous closed (off) state to the open (on) state.
- the ETL nozzle 46 (6) starts to eject the ETL source gas (more precisely, a mixed gas of the ETL source gas and the carrier gas).
- the mass flow controller (MFC) 44 (6) sets the gas ejection pressure or flow rate of the ETL nozzle 46 (2) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (6). Control.
- the ETL nozzle 46 (6) ejects the ETL source gas from the slit-type ejection port 52 (6) in a strip shape directly above.
- the ETL source gas blown out in a belt-like shape hits the surface of the substrate S to be processed that passes right above, and is condensed and deposited at the position where the belt hits.
- FIG. 4 while the substrate S passes over the ETL nozzle 46 (6) at a constant speed in the scanning movement direction (X direction), holes are injected from the front end to the rear end of the substrate S.
- the hole transport layer (HTL) and the R • G • B light emitting layer (REL / GEL /) are followed to follow the layer (HIL), the hole transport layer (HTL) and the RGB light emitting layer (REL / GEL / BEL).
- BEL a thin film of an electron transport layer (ETL) is formed in a planar shape with a constant film thickness.
- the controller 18 starts the opening / closing valve 42 (7) of the carrier gas supply pipe 40 (7) and the raw material at a predetermined timing.
- the on-off valve 50 (7) of the gas supply pipe 48 (7) is switched from the previous closed (off) state to the open (on) state.
- the EIL nozzle 46 (7) starts to eject the EIL source gas (more precisely, a mixed gas of the EIL source gas and the carrier gas).
- the mass flow controller (MFC) 44 (7) sets the gas ejection pressure or flow rate of the EIL nozzle 46 (7) to a set value through control of the pressure or flow rate of the carrier gas flowing through the carrier gas supply pipe 40 (7). Control.
- the EIL nozzle 46 (7) ejects the REL source gas from the slit-type ejection port 52 (7) in a strip shape directly above.
- the EIL source gas ejected in a band shape hits the surface of the substrate S to be processed passing above, and is condensed and deposited at the position hitting the band shape.
- FIG. 4 while the substrate S passes above the EIL nozzle 46 (7) at a constant speed in the scanning movement direction (X direction), holes are injected from the front end to the rear end of the substrate S.
- an electron injection layer (EIL) thin film is formed in a planar shape with a constant film thickness.
- the controller 18 controls the moving mechanism 12 to stop the stage 28. Further, the vapor deposition mechanism 14 and the raw material gas ejection part 16 are controlled to open the on-off valve 42 (7) of the carrier gas supply pipe 40 (7) and the on-off valve 50 (7) of the raw material gas supply pipe 48 (7) ( Switch from ON to CLOSE. Next, the purging mechanism (not shown) is controlled to replace the atmosphere in the processing chamber 10 from the reduced pressure state to the atmospheric pressure state. Thereafter, the gate valve 22 is opened, and the external transfer device takes out the processed substrate S out of the processing chamber 10. Thereafter, the substrate S is moved to another film forming apparatus (for example, a sputtering apparatus) in order to form a cathode on the electron injection layer (EIL).
- another film forming apparatus for example, a sputtering apparatus
- a plurality of types of organic thin films are formed on the substrate S by simply scanning the substrate S in the horizontal direction (X direction) once in the processing chamber 10. That is, a hole injection layer (HIL), a hole transport layer (HIL), an R • G • B light emitting layer (REL / GEL / BEL), an electron transport layer (ETL), and an electron injection layer (EIL) are stacked.
- the R, G, B light emitting layer (REL / GEL / BEL) can be formed in parallel in a parallel line pattern.
- an organic EL color display having a device structure as shown in FIG.
- a passive matrix system as shown in FIG. 8 can be used as a drive system of the organic EL color display having the device structure as shown in FIG. 7, for example.
- the anode and the cathode are formed as line electrodes (row electrode / column electrode) orthogonal to each other, and when a voltage is applied to a pixel (R, G, B subpixel) at a position (intersection) where they intersect. , The sub-pixel emits light.
- TFT thin film transistors
- pixel electrodes for each of R, G, and B subpixels, scanning lines, and signal lines are formed on the anode (ITO) side.
- ITO anode
- the cathode serves as a common electrode and is formed as a single planar thin film.
- the REL nozzle 46 (3) and the GEL nozzle 46 (4) for forming the juxtaposed R / G / B light emitting layer (REL / GEL / BEL) in the source gas ejection section 16 are provided.
- the BEL nozzle 46 (5), the nozzles 52 (3), 52 (4), 52 (5) are common to the nozzles 46 (3), 46 (4), 46 (5).
- the structure provided in the integrated plate body or jet nozzle plate 60 to which it is attached can be taken suitably.
- FIG. 11 shows another embodiment of the REL nozzle 46 (3), the GEL nozzle 46 (4) and the BEL nozzle 46 (5) with respect to the ejection ports 52 (3), 52 (4), 52 (5).
- a plurality of nozzles 52 (3), 52 (4), 52 (5) of each nozzle 46 (3), 46 (4), 46 (5) are arranged in a row in the scanning movement direction (X direction) (illustrated).
- X direction scanning movement direction
- a configuration in which four are arranged can be suitably employed.
- each line-shaped thin film (REL / GEL / BEL) is several times thicker than the film thickness formed by one jet 52 (3), 52 (4), 52 (5). Can be obtained. From another viewpoint, the pressure or flow rate of the raw material gas ejected from one ejection port 52 (3), 52 (4), 52 (5) can be reduced to a fraction.
- the nozzles 52 (3), 52 (4), 52 (5) are provided at the nozzles 46 (3), 46 (4), 46 (5).
- positioned in zigzag form can be taken suitably. In such a configuration, the arrangement interval in the nozzle longitudinal direction (Y direction) at each of the jet outlets 52 (3), 52 (4), 52 (5) can be doubled.
- the HIL nozzle 46 (1), the HTL nozzle 46 (2), the ETL nozzle 46 (6) and the EIL nozzle 46 (7) for forming the planar thin film as shown in FIG. It is also possible to form 52 (3), 52 (4), 52 (6), 52 (7) in a single row or a plurality of rows of porous types.
- each of the jets 52 (3), 52 (4) is so formed that the HIL source gas, the HTL source gas, the ETL source gas, and the EIL source gas are jetted substantially in a strip shape to the substrate S passing above.
- 52 (6), 52 (7), the pitch, the pitch, and the separation distance DL are selected.
- the orientation of the long nozzles for ejecting each source gas with respect to the substrate movement direction (X direction), that is, the orientation of the nozzle longitudinal direction is usually orthogonal as in the above embodiment. Although it is (Y direction), you may incline diagonally within the horizontal surface from the same direction (Y direction) as needed.
- the posture of the substrate subjected to the vapor deposition process is not limited to the face-down method, and a face-up method or a method in which the surface to be processed of the substrate is directed in the horizontal direction is also possible.
- the direction in which the source gas is ejected from each nozzle can also take any direction depending on the direction or orientation of the substrate to be processed.
- a modified juxtaposition method combining a B light emission layer (BEL), an R fluorescent layer (RFL), and a G fluorescent layer (GFL) is known.
- an R fluorescent layer (RFL) and a G fluorescent layer (GFL) of an organic material are the same as the R light emitting layer (REL) and the G light emitting layer (GEL) on the hole transport layer (HTL), respectively. It is formed as a line-shaped thin film adjacent to each other.
- the B light emitting layer (BEL) is formed as a planar thin film that not only fills the B subpixel position but also covers the R fluorescent layer (RFL) and the G fluorescent layer (GFL).
- the ejection port 52 (5) of the BEL nozzle 46 (5) is slit-shaped (or substantially strip-shaped gas ejection).
- a relatively distant distance DL (usually 10 to 20 mm) suitable for forming a planar thin film with respect to the substrate S passing directly above the jet outlet 52 (5). Place it at a height that separates it.
- the film forming operation by the other nozzles 46 (1) to 46 (4), 46 (6), 46 (7) is substantially the same as the above embodiment, and the BEL nozzle 46 (5) is used. Only the film forming operation is significantly different from the above embodiment. That is, the BEL nozzle 46 (3) ejects the BEL source gas from the slit-shaped (or porous) ejection port 52 (5) in a band shape directly above. The BEL source gas blown out in a band shape hits the surface of the substrate S to be processed which passes right above, and is condensed and deposited at the position of the band. Thus, as shown in FIG.
- the R fluorescent layer (RFL) and G fluorescent layer (GFL) of the organic material may be replaced with an R phosphor layer (RPL) and a G phosphor layer (GPL) of the organic material, respectively.
- a partition plate 52 is also provided between the REL nozzle 46 (3) and the GEL nozzle 46 (4).
- the partition plate 52 By providing the partition plate 52 between the adjacent line-shaped thin film forming nozzles as described above, recoil of organic molecules (raw material gas molecules) can be more effectively prevented.
- the raw material gas ejection section 16 for example, FIG. 1 of the other embodiments described above, between the REL nozzle 46 (3) and the GEL nozzle 46 (4) and between the GEL nozzle 46 (4) and BEL for the same purpose.
- a partition plate 52 can be provided between each nozzle 46 (5).
- a plate-shaped heat shield 62 can be provided around the nozzle outlet.
- the heat shield 62 is made of a member having high thermal conductivity, and has a flow path 62a through which a cooling medium (for example, cooling water) cw flows, and absorbs and blocks heat radiated from the nozzle.
- the heat shield part 62 can be arranged laterally instead of in front of the nozzle jet outlet. is there. According to this configuration, the nozzle outlet can be as close as possible to the substrate (not shown).
- the vapor deposition apparatus of the present invention can also be advantageously applied to the production of a device structure in which a partition or bank for subpixel separation is provided between each color light emitting layer on a substrate.
- this subpixel separation method for example, as shown in FIG. 18A, not only the R, G, B light emitting layer (REL / GEL / BEL) but also the hole injection layer (HIL), the hole transport layer (HTL)
- HIL hole injection layer
- HTL hole transport layer
- ETL electron transport layer
- EIL electron injection layer
- the film quality or material of each layer so that the light emission characteristics of each color can be optimized independently while keeping the same thickness of the organic thin film in each of the first layer (HIL), the second layer (HTL),. Can also be selected individually.
- the film thickness of each thin film can be controlled to an independent film thickness for each color in accordance with the light emission characteristics of each color.
- the film thicknesses of the R light emitting layer (REL), the G light emitting layer (GEL), and the B light emitting layer (BEL) can be selected as 140 ⁇ 20 nm, 120 ⁇ 20 nm, and 100 ⁇ 20 nm, respectively.
- a shadow mask is not necessary as described above.
- a shadow mask may be used.
- the bank 64 is made of an organic material such as an acrylic resin, a novolak resin, a polyamide resin, or a polyimide resin.
- the bank 64 can be formed in a previous process by, for example, an ink jet method or a printing method. It can also be produced on the substrate S together.
- an evaporation source when the above-mentioned device structure is manufactured, an evaporation source, a nozzle, and a carrier gas for forming the bank 64 in the evaporation mechanism 14, the raw material gas ejection portion 16 and the carrier gas supply mechanism 36.
- Add supply units (dedicated gas pipes, on-off valves, MFC, etc.).
- the bank forming nozzles are preferably arranged at a position upstream of the HIL nozzle 46 (1), that is, at the most upstream position.
- nozzles 46 (1), 46 (7) for forming injection layers and transport layer formation Both nozzles 46 (2) and 46 (6) for use have a porous jet nozzle with a small diameter in order to form a line-shaped thin film, and each nozzle from the closest distance DS to the substrate S It is arranged at such a height position that the raw material gas is sprayed.
- the film thickness of each line-shaped thin film or line-shaped bank can be individually controlled or adjusted by the flow rate of each source gas, the diameter of the nozzle outlet, the number of multiples (in the case of FIG. 10), and the like.
- HIL nozzles 46 (1), HTL nozzles 46 (2), ETL nozzles 46 (6) and EIL nozzles 46 (7) for each color. is there.
- the line-shaped color light emitting layers were formed on the substrate S in the order of the R light emitting layer (REL), the G light emitting layer (GEL), and the B light emitting layer (BEL).
- REL light emitting layer
- GEL G light emitting layer
- BEL B light emitting layer
- the order is not limited to this order, and it is possible to form the line-shaped light emitting layers in any order. Therefore, the arrangement order of the REL nozzle 46 (3), the GEL nozzle 46 (4), and the BEL nozzle 46 (5) can be arbitrarily selected in the raw material gas ejection section 16.
- the transparent anode is used as a base layer, and the hole injection layer (HIL), the hole transport layer (HTL),.
- HIL hole injection layer
- HTL hole transport layer
- the organic EL display there is a device structure in which a part of the hole injection layer (HIL), the hole transport layer (HTL), the electron transport layer (ETL), and the electron injection layer (HIL) is omitted.
- HIL hole injection layer
- HTL hole transport layer
- ETL electron transport layer
- HIL electron injection layer
- the organic material is used for all the multilayer films constituting the organic EL display.
- the present invention is also applied to the manufacture of a device structure in which a part or all of the organic thin film is replaced with a thin film of an inorganic material. be able to.
- the present invention can also be applied to manufacture of an organic EL having a multiphoton light emitting structure.
- the present invention is applicable to any film forming process or application in which a plurality of types of line-shaped thin films are coated on a substrate using a vapor deposition method. Therefore, for example, the line width W of each line-shaped thin film, the diameter of the nozzle outlet of each nozzle, and the separation distance D can be set independently for each type of line-shaped thin film.
- the vapor deposition apparatus and vapor deposition method of the present embodiment can be used to manufacture a lighting device. That is, the vapor deposition apparatus and the vapor deposition method of this embodiment use this to form an R light-emitting layer, a G light-emitting layer, and a B light-emitting layer on a substrate in a line shape, and each light-emitting layer emits light, thereby producing a white color.
- a light emitting lighting device can be manufactured.
- the vapor deposition apparatus and vapor deposition method of the present embodiment can be used to form an R light emitting layer, a G light emitting layer, and a B light emitting layer on a substrate in a line shape, and adjust the light emission intensity of each light emitting layer. By making it possible, it is possible to manufacture a lighting device capable of adjusting the color of light emission.
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Abstract
Description
図1に、本発明の一実施形態における蒸着装置の構成を示す。図2に、この蒸着装置の要部(原料ガス噴き出し部)の構成を示す。
次に、図4~図6を参照して、この実施形態の蒸着装置における作用を説明する。ゲートバルブ22が開いて外部搬送装置(図示せず)により処理対象の基板Sが処理室10の中に搬入されると、コントローラ18は、移動機構12を制御してステージ26に基板Sをフェイスダウンで装着させる。この際、ステージ26を搬入/搬出口24の近くに寄せて基板Sのローディングを行い、次いでステージ26を搬入/搬出口24から遠い走査開始位置まで移動させる。基板Sのローディングが完了した後、ゲートバルブ22は閉じて、排気装置により処理室10の室内が所定の真空圧力まで減圧される。なお、処理室10内に搬入された基板Sの被処理面には、別の成膜装置(たとえばスパッタ装置)により前工程で陽極(ITO)が形成されている。
以上本発明の好適な実施形態を説明したが、本発明は上記実施形態に限定されず、その技術的思想の範囲内で他の実施形態または種種の変形が可能である。
12 移動機構
14 蒸着機構
16 原料ガス噴き出し部
18 コントローラ
20 排気口
26 ステージ
28 走査部
30(1)~30(7) 蒸発源
34 ヒータ電源部
38 キャリアガス供給源
44(1)~44(7) マス・フロー・コントローラ(MFC)
46(1)~46(7) ノズル
48(1)~48(7) ガス管
50(1)~50(7) 開閉弁
52(1)~52(7) 噴出口
60 噴出口プレート
62 遮熱部
64 バンク(隔壁)
Claims (56)
- 処理対象の基板を収容する処理室と、
前記処理室内で前記基板を第1の方向に移動させる移動機構と、
第1の成膜原料を蒸発させて第1の原料ガスを生成する第1の蒸発源と、
第1の噴出口を有し、前記第1の蒸発源より前記第1の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第1の噴出口より前記第1の原料ガスを噴き出す第1のノズルと、
第2の成膜原料を蒸発させて第2の原料ガスを生成する第2の蒸発源と、
前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている第2の噴出口を有し、前記第2の蒸発源より前記第2の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第2の噴出口より前記第2の原料ガスを噴き出す第2のノズルと、
を有し、
前記基板上において、前記第1の原料ガスが堆積して、前記第1の方向に延びる第1のライン状薄膜が形成されるとともに、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスが堆積して、前記第1の方向に延びる第2のライン状薄膜が形成される、
蒸着装置。 - 前記第1および第2のノズルは、いずれも前記第2の方向に延びる長尺型のノズルであって、前記第1の方向においてそれぞれの配置位置を互いにずらし、
前記第1および第2のノズルにおいて、前記第1および第2の噴出口が前記第2の方向に一定の間隔を置いてそれぞれ複数設けられる、
請求項1に記載の蒸着装置。 - 前記第1のノズルにおいて、前記第1の噴出口が前記第1の方向に一列に並んで複数設けられる、請求項1または請求項2に記載の蒸着装置。
- 前記第2のノズルにおいて、前記第2の噴出口が前記第1の方向に一列に並んで複数設けられる、請求項1~3のいずれか一項に記載の蒸着装置。
- 前記第1および第2のノズルの噴出口の近傍に、それらのノズルから放出される輻射熱を吸収して遮断する遮熱部をそれぞれ設ける、請求項1~4のいずれか一項に記載の蒸着装置。
- 前記第1のライン状薄膜のライン幅設定値をW1とすると、前記第1の噴出口の口径K1はK1=0.1~1.0W1に選ばれる、請求項1~5のいずれか一項に記載の蒸着装置。
- 前記第2のライン状薄膜のライン幅設定値をW2とすると、前記第2の噴出口の口径K2はK2=0.1~1.0W2に選ばれる、請求項1~6のいずれか一項に記載の蒸着装置。
- 前記第1および第2の噴出口は、前記第1および第2のノズルに共有される一体的な板体に形成されている、請求項1~7のいずれか一項に記載の蒸着装置。
- 前記第1および第2の蒸発源により生成される前記第1および第2の原料ガスをキャリアガスに混合して所望の圧力または流量で前記第1および第2のノズルへそれぞれ供給する第1および第2のキャリアガス供給部を有する、請求項1~8のいずれか一項に記載の蒸着装置。
- 前記第1および第2のライン状薄膜はいずれも発光層である、請求項1~9のいずれか一項に記載の蒸着装置。
- 前記第1および第2の成膜材料はいずれも有機物質である、請求項1~10のいずれか一項に記載の蒸着装置。
- 第3の成膜原料を蒸発させて第3の原料ガスを生成する第3の蒸発源と、
前記第2の方向において前記第1および第2の噴出口からオフセットしている第3の噴出口を有し、前記第3の蒸発源より前記第3の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第3の噴出口より前記第3の原料ガスを噴き出す第3のノズルと、
を有し、
前記基板上において、前記第1および第2のライン状薄膜から離間した位置に、前記第3の原料ガスが堆積して、前記第1の方向に延びる第3のライン状薄膜が形成される、
請求項1~11のいずれか一項に記載の蒸着装置。 - 前記第3のノズルは、前記第2の方向に延びる長尺型のノズルであって、前記第1の方向において前記第1および第2のノズルと異なる位置に配置され、
前記第3のノズルにおいて、前記第3の噴出口が前記第2の方向に一定の間隔を置いて複数設けられる、
請求項12に記載の蒸着装置。 - 前記第3のノズルにおいて、前記第3の噴出口が前記第1の方向に一列に並んで複数設けられる、請求項12または請求項13に記載の蒸着装置。
- 前記第3のライン状薄膜のライン幅設定値をW3とすると、前記第3の噴出口の口径K3はK3=0.1~1.0W3に選ばれる、請求項12~14のいずれか一項に記載の蒸着装置。
- 前記第1、第2および第3の噴出口は、前記第1、第2および第3のノズルに共有される一体的な板体に形成されている、請求項12~15のいずれか一項に記載の蒸着装置。
- 前記第3のライン状薄膜は発光層である、請求項12~16のいずれか一項に記載の蒸着装置。
- 第3の成膜原料を蒸発させて第3の原料ガスを生成する第3の蒸発源と、
前記第1の方向において前記第1および第2の噴出口から前記基板の移動の下流側にオフセットしている第3の噴出口を有し、前記第3の蒸発源より前記第3の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第3の噴出口より前記第3の原料ガスを噴き出す第3のノズルと、
を有し、
前記基板上において、前記第1および第2のライン状薄膜の上に前記第3の原料ガスが堆積して、面状の薄膜が形成される、
請求項1~11のいずれか一項に記載の蒸着装置。 - 前記第1および第2のライン状薄膜はいずれも蛍光層または燐光層であり、前記面状薄膜は発光層である、請求項18に記載の蒸着装置。
- 第3の成膜原料を蒸発させて第3の原料ガスを生成する第3の蒸発源と、
前記第1の方向において前記第1および第2の噴出口から前記基板の移動の上流側にオフセットしている第3の噴出口を有し、前記第3の蒸発源より前記第3の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第3の噴出口より前記第3の原料ガスを噴き出す第3のノズルと、
を有し、
前記基板上において、前記第1および第2のライン状薄膜が形成されるのに先立って、前記第3の原料ガスが堆積して、面状の薄膜が形成される、
請求項1~11のいずれか一項に記載の蒸着装置。 - 前記第3のノズルにおいて、前記第3の噴出口が前記第2の方向にスリット状に延びる、請求項18~20のいずれか一項に記載の蒸着装置。
- 前記第3のノズルにおいて、前記第3の噴出口が前記第2の方向に一定の間隔を置いて複数設けられる、請求項18~20のいずれか一項に記載の蒸着装置。
- 前記第3の噴出口は、前記第1および第2の噴出口よりも前記基板との距離間隔が大きい位置に配置される、請求項18~22のいずれか一項に記載の蒸着装置。
- 前記第3の蒸発源により生成される前記第3の原料ガスをキャリアガスに混合して所望の圧力または流量で前記第3のノズルへ送る第3のキャリアガス供給部を有する、請求項12~23のいずれか一項に記載の蒸着装置。
- 第3の成膜原料を蒸発させて第3の原料ガスを生成する第3の蒸発源と、
前記第1の方向において前記第1および第2の噴出口から前記基板の移動の上流側にオフセットしている第3の噴出口を有し、前記第3の蒸発源より前記第3の原料ガスを受け取り、前記処理室内で移動する前記基板に向けて前記第3の噴出口より前記第3の原料ガスを噴き出す第3のノズルと、
を有し、
前記基板上において、前記第1および第2のライン状薄膜がそれぞれ形成される領域の間を埋めるように前記第3の原料ガスが堆積して、前記第1の方向に延びる隔壁が形成される、
請求項1~11のいずれか一項に記載の蒸着装置。 - 前記第1、第2および第3の成膜材料はいずれも有機物質である、請求項11~25のいずれか一項に記載の蒸着装置。
- 処理室内で基板を第1の方向に移動させる工程と、
第1の成膜原料を蒸発させて、第1の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の原料ガスを第1の噴出口より噴き出す工程と、
前記基板上に前記第1の原料ガスを堆積させて、前記第1の方向に延びる第1のライン状薄膜を形成する工程と、
第2の成膜原料を蒸発させて、第2の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている第2の噴出口より前記第2の原料ガスを噴き出す工程と、
前記基板上において、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスを堆積させて、前記第1の方向に延びる第2のライン状薄膜を形成する工程と
を有する蒸着方法。 - 前記第1および第2の噴出口が、前記第2の方向にそれぞれ一定の間隔を置いて複数設けられ、
前記基板上に前記第1および第2のライン状薄膜が前記第2の方向で繰り返し交互に形成される、
請求項27に記載の蒸着方法。 - 処理室内で基板を第1の方向に移動させる工程と、
第1の成膜原料を蒸発させて、第1の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の原料ガスを第1の噴出口より噴き出す工程と、
前記基板上に前記第1の原料ガスを堆積させて、前記第1方向に延びる第1のライン状薄膜を形成する工程と、
第2の成膜原料を蒸発させて、第2の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている前記第2の噴出口より前記第2の原料ガスを噴き出す工程と、
前記基板上において、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスを堆積させて、前記第1の方向に延びる第2のライン状薄膜を形成する工程と、
第3の成膜原料を蒸発させて、第3の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1および第2の噴出口からオフセットしている第3の噴出口より前記第3の原料ガスを噴き出す工程と、
前記基板上において、前記第1および第2のライン状薄膜から離間した位置に、前記第3の原料ガスを堆積させて、前記第1の方向に延びる第3のライン状薄膜を形成する工程と
を有する蒸着方法。 - 前記第1、第2および第3の噴出口が前記第2の方向にそれぞれ一定の間隔を置いて複数設けられ、
前記基板上に前記第1、第2および第3のライン状薄膜が前記第2の方向で繰り返し交互に形成される、
請求項29に記載の蒸着方法。 - 前記第3の噴出口が、前記第1の方向に一列に並んで複数設けられ、
前記基板上において、前記第3のライン状薄膜が複数の重ね蒸着によって形成される、
請求項29または請求項30に記載の蒸着方法。 - 前記第3のライン状薄膜のライン幅設定値をW3とすると、前記第3の噴出口の口径K3はK3=0.1~1.0W3に選ばれる、請求項29~31のいずれか一項に記載の蒸着方法。
- 前記第3のライン状薄膜は発光層である、請求項29~32のいずれか一項に記載の蒸着方法。
- 処理室内で基板を第1の方向に移動させる工程と、
第1の成膜原料を蒸発させて、第1の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の原料ガスを第1の噴出口より噴き出す工程と、
前記基板上に前記第1の原料ガスを堆積させて、前記第1方向に延びる第1のライン状薄膜を形成する工程と、
第2の成膜原料を蒸発させて、第2の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている第2の噴出口より前記第2の原料ガスを噴き出す工程と、
前記基板上において、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスを堆積させて、前記第1の方向に延びる第2のライン状薄膜を形成する工程と、
第3の成膜原料を蒸発させて、第3の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向において前記第1および第2の噴出口から前記基板の移動の下流側にオフセットしている第3の噴出口より前記第3の原料ガスを噴き出す工程と、
前記基板上において、前記第1および第2のライン状薄膜の上に、前記第3の原料ガスを堆積させて、第1の面状薄膜を形成する工程と
を有する蒸着方法。 - 前記第1および第2のライン状薄膜はいずれも蛍光層または燐光層であり、前記第1の面状薄膜は発光層である、請求項34に記載の蒸着方法。
- 第4の成膜原料を蒸発させて、第4の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向において前記第3の噴出口から前記基板の移動の下流側にオフセットしている第4の噴出口より前記第4の原料ガスを噴き出す工程と、
前記基板上において、前記第1の面状薄膜の上に、前記第4の原料ガスを堆積させて、第2の面状薄膜を形成する工程と
を有する請求項34または請求項35に記載の蒸着方法。 - 処理室内で基板を第1の方向に移動させる工程と、
第1の成膜原料を蒸発させて、第1の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の原料ガスを第1の噴出口より噴き出す工程と、
前記基板上に前記第1の原料ガスを堆積させて、前記第1方向に延びる第1のライン状薄膜を形成する工程と、
第2の成膜原料を蒸発させて、第2の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている第2の噴出口より前記第2の原料ガスを噴き出す工程と、
前記基板上において、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスを堆積させて、前記第1の方向に延びる第2のライン状薄膜を形成する工程と、
第3の成膜原料を蒸発させて、第3の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向において前記第1および第2の噴出口から前記基板の移動の上流側にオフセットしている第3の噴出口より前記第3の原料ガスを噴き出す工程と、
前記基板上において、前記第1および第2のライン状薄膜が形成されるのに先立って、前記第3の原料ガスを堆積させて、第1の面状薄膜を形成する工程と
を有する蒸着方法。 - 第4の成膜原料を蒸発させて、第4の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向において前記第3の噴出口から前記基板の移動の上流側にオフセットしている第4の噴出口より前記第4の原料ガスを噴き出す工程と、
前記基板上において、前記第1の面状薄膜が形成されるのに先立って、前記第4の原料ガスを堆積させて、第2の面状薄膜を形成する工程と
を有する請求項37に記載の蒸着方法。 - 前記第4の噴出口は、前記第1および第2の噴出口よりも前記基板との距離間隔が大きい位置に配置される、請求項36または請求項38に記載の蒸着方法。
- 前記第4の原料ガスをキャリアガスと混合して所望の圧力または流量で前記第4の噴出口よりそれぞれ噴き出す、請求項36、38、39のいずれか一項に記載の蒸着方法。
- 前記第4の成膜材料は有機物質である、請求項36、37、39、40のいずれか一項に記載の蒸着方法。
- 前記第3の噴出口は、前記第1および第2の噴出口よりも前記基板との距離間隔が大きい位置に配置される、請求項34~41のいずれか一項に記載の蒸着方法。
- 処理室内で基板を第1の方向に移動させる工程と、
第1の成膜原料を蒸発させて、第1の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の原料ガスを第1の噴出口より噴き出す工程と、
前記基板上に前記第1の原料ガスを堆積させて、前記第1方向に延びる第1のライン状薄膜を形成する工程と、
第2の成膜原料を蒸発させて、第2の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1の噴出口からオフセットしている前記第2の噴出口より前記第2の原料ガスを噴き出す工程と、
前記基板上において、前記第1のライン状薄膜から離間した位置に、前記第2の原料ガスを堆積させて、前記第1の方向に延びる第2のライン状薄膜を形成する工程と、
第3の成膜原料を蒸発させて、第3の原料ガスを生成する工程と、
前記処理室内で移動する前記基板に向けて、前記第1の方向と交差する第2の方向において前記第1および第2の噴出口からオフセットしている第3の噴出口より前記第3の原料ガスを噴き出す工程と、
前記基板上において、前記第1および第2のライン状薄膜がそれぞれ形成される領域の間を埋めるように前記第3の原料ガスを堆積させて、前記第1の方向に延びる隔壁を形成する工程と
を有する蒸着方法。 - 前記第3の原料ガスをキャリアガスと混合して所望の圧力または流量で前記第3の噴出口よりそれぞれ噴き出す、請求項29~43のいずれか一項に記載の蒸着方法。
- 前記第3の成膜材料は有機物質である、請求項29~44のいずれか一項に記載の蒸着方法。
- 前記第1の噴出口が、前記第1の方向に一列に並んで複数設けられ、
前記基板上において、前記第1のライン状薄膜が複数の重ね蒸着によって形成される、
請求項27~45のいずれか一項に記載の蒸着方法。 - 前記第2の噴出口が、前記第1の方向に一列に並んで複数設けられ、
前記基板上において、前記第2のライン状薄膜が複数の重ね蒸着によって形成される、
請求項27~46のいずれか一項に記載の蒸着方法。 - 前記第1のライン状薄膜のライン幅設定値をW1とすると、前記第1の噴出口の口径K1はK1=0.1~1.0W1に選ばれる、請求項27~47のいずれか一項に記載の蒸着方法。
- 前記第2のライン状薄膜のライン幅設定値をW2とすると、前記第2の噴出口の口径K2はK2=0.1~1.0W2に選ばれる、請求項27~47のいずれか一項に記載の蒸着方法。
- 前記第1および第2の原料ガスをキャリアガスと混合して所望の圧力または流量で前記第1および第2の噴出口よりそれぞれ噴き出す、請求項27~49のいずれか一項に記載の蒸着方法。
- 前記第1および第2のライン状薄膜はいずれも発光層である、請求項27~33,36~50のいずれか一項に記載の蒸着方法。
- 前記第1および第2の成膜材料はいずれも有機物質である、請求項27~51のいずれか一項に記載の蒸着方法。
- 請求項1~26のいずれか1項に記載の蒸着装置を用いて製造された有機ELディスプレイ。
- 請求項1~26のいずれか1項に記載の蒸着装置を用いて製造された照明装置。
- 請求項27~52のいずれか1項に記載の蒸着方法を用いて製造された有機ELディスプレイ。
- 請求項27~52のいずれか1項に記載の蒸着方法を用いて製造された照明装置。
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| KR (1) | KR20140022804A (ja) |
| CN (1) | CN103430624A (ja) |
| TW (1) | TW201250024A (ja) |
| WO (1) | WO2012118199A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014034499A1 (ja) * | 2012-09-03 | 2014-03-06 | 東京エレクトロン株式会社 | 蒸着装置、蒸着方法、有機elディスプレイ、および有機el照明装置 |
| JP2020153019A (ja) * | 2020-06-25 | 2020-09-24 | キヤノントッキ株式会社 | 蒸着装置及び蒸発源 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102192500B1 (ko) * | 2013-10-24 | 2020-12-17 | 히다치 조센 가부시키가이샤 | 진공증착장치용 매니폴드 |
| CN103695848B (zh) * | 2013-12-30 | 2015-10-14 | 京东方科技集团股份有限公司 | 蒸镀设备及其蒸镀方法 |
| CN104617223B (zh) * | 2015-02-03 | 2017-12-08 | 京东方科技集团股份有限公司 | 有机发光二极管器件及其制作方法和蒸镀设备 |
| CN107326359B (zh) * | 2016-04-28 | 2019-12-17 | 清华大学 | 有机薄膜制备装置和制备方法 |
| JP6765237B2 (ja) * | 2016-07-05 | 2020-10-07 | キヤノントッキ株式会社 | 蒸着装置及び蒸発源 |
| KR102551354B1 (ko) * | 2018-04-20 | 2023-07-04 | 삼성전자 주식회사 | 반도체 발광 소자 및 그 제조 방법 |
| KR102823803B1 (ko) * | 2019-09-03 | 2025-06-24 | 삼성디스플레이 주식회사 | 증착 장치 |
| JP2022066943A (ja) * | 2020-10-19 | 2022-05-02 | 株式会社アルバック | 真空蒸着装置用の蒸着源 |
| CN117305799B (zh) * | 2023-10-10 | 2025-10-28 | 江苏派莱特光电科技有限公司 | 一种蒸发镀膜机镀膜抽真空系统 |
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| WO2010113659A1 (ja) * | 2009-03-31 | 2010-10-07 | 東京エレクトロン株式会社 | 成膜装置、成膜方法及び有機el素子 |
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| US7517551B2 (en) * | 2000-05-12 | 2009-04-14 | Semiconductor Energy Laboratory Co., Ltd. | Method of manufacturing a light-emitting device |
| JP4139186B2 (ja) * | 2002-10-21 | 2008-08-27 | 東北パイオニア株式会社 | 真空蒸着装置 |
| JP5203584B2 (ja) * | 2006-08-09 | 2013-06-05 | 東京エレクトロン株式会社 | 成膜装置、成膜システムおよび成膜方法 |
| WO2009028126A1 (ja) * | 2007-08-31 | 2009-03-05 | Sharp Kabushiki Kaisha | 有機el表示装置及びその製造方法 |
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- 2012-03-02 TW TW101107014A patent/TW201250024A/zh unknown
- 2012-03-02 KR KR1020137023216A patent/KR20140022804A/ko not_active Withdrawn
- 2012-03-02 WO PCT/JP2012/055445 patent/WO2012118199A1/ja not_active Ceased
- 2012-03-02 US US14/002,386 patent/US20140315342A1/en not_active Abandoned
- 2012-03-02 JP JP2013502428A patent/JPWO2012118199A1/ja active Pending
- 2012-03-02 CN CN201280011161XA patent/CN103430624A/zh active Pending
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| JP2002033190A (ja) * | 2000-05-12 | 2002-01-31 | Semiconductor Energy Lab Co Ltd | 発光装置の作製方法 |
| JP2007046100A (ja) * | 2005-08-09 | 2007-02-22 | Sony Corp | 蒸着装置、および表示装置の製造システム |
| JP2009256705A (ja) * | 2008-04-15 | 2009-11-05 | Hitachi Zosen Corp | 真空蒸着装置 |
| WO2010113659A1 (ja) * | 2009-03-31 | 2010-10-07 | 東京エレクトロン株式会社 | 成膜装置、成膜方法及び有機el素子 |
| WO2010114118A1 (ja) * | 2009-04-03 | 2010-10-07 | 東京エレクトロン株式会社 | 蒸着ヘッドおよび成膜装置 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014034499A1 (ja) * | 2012-09-03 | 2014-03-06 | 東京エレクトロン株式会社 | 蒸着装置、蒸着方法、有機elディスプレイ、および有機el照明装置 |
| JP2020153019A (ja) * | 2020-06-25 | 2020-09-24 | キヤノントッキ株式会社 | 蒸着装置及び蒸発源 |
| JP7247142B2 (ja) | 2020-06-25 | 2023-03-28 | キヤノントッキ株式会社 | 蒸着装置及び蒸発源 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2012118199A1 (ja) | 2014-07-07 |
| CN103430624A (zh) | 2013-12-04 |
| KR20140022804A (ko) | 2014-02-25 |
| TW201250024A (en) | 2012-12-16 |
| US20140315342A1 (en) | 2014-10-23 |
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