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WO2011065682A3 - Procédé de production de catalyseur cmb recyclé à partir d'une batterie au lithium-ion et de matières de cathode ternaires - Google Patents

Procédé de production de catalyseur cmb recyclé à partir d'une batterie au lithium-ion et de matières de cathode ternaires Download PDF

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Publication number
WO2011065682A3
WO2011065682A3 PCT/KR2010/007750 KR2010007750W WO2011065682A3 WO 2011065682 A3 WO2011065682 A3 WO 2011065682A3 KR 2010007750 W KR2010007750 W KR 2010007750W WO 2011065682 A3 WO2011065682 A3 WO 2011065682A3
Authority
WO
WIPO (PCT)
Prior art keywords
manganese
cobalt
ternary cathode
cmb
recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2010/007750
Other languages
English (en)
Korean (ko)
Other versions
WO2011065682A2 (fr
Inventor
신선명
강진구
주성호
장한권
손정수
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Institute of Geoscience and Mineral Resources KIGAM
Original Assignee
Korea Institute of Geoscience and Mineral Resources KIGAM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Institute of Geoscience and Mineral Resources KIGAM filed Critical Korea Institute of Geoscience and Mineral Resources KIGAM
Priority to CN2010800535942A priority Critical patent/CN102665912A/zh
Priority to JP2012541932A priority patent/JP5572222B2/ja
Publication of WO2011065682A2 publication Critical patent/WO2011065682A2/fr
Publication of WO2011065682A3 publication Critical patent/WO2011065682A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Secondary Cells (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

La présente invention porte sur la récupération de cobalt et de manganèse à partir de matières de batteries mises au rebut et sur un procédé de fabrication de catalyseurs liquides à partir de Co-Mn-Br (CMB) récupéré. De façon plus spécifique, de la poudre de lithium-ion et des matières de cathode ternaires sont produites par lixiviation de matières de batteries mises au rebut avec réduction des sulfates et application séquentielle des trois étapes de traitement suivantes : un titrage de neutralisation, une séparation solide-liquide et une extraction au solvant, ce qui conduit à la récupération de cobalt et de manganèse sous forme d'un extrait liquide constitué d'un catalyseur Co-Mn-Br. Selon la présente invention, un catalyseur CMB en phase liquide qui est utile pour une application dans divers procédés de fabrication est fourni par récupération de cobalt et de manganèse à partir de matières de cathode ternaires et de batteries au lithium-ion mises au rebut, amélioration de l'élimination d'autres impuretés et récupération de cobalt et de manganèse de haute pureté.
PCT/KR2010/007750 2009-11-30 2010-11-04 Procédé de production de catalyseur cmb recyclé à partir d'une batterie au lithium-ion et de matières de cathode ternaires Ceased WO2011065682A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2010800535942A CN102665912A (zh) 2009-11-30 2010-11-04 从锂离子电池和三元正极材料制备cmb催化剂的方法
JP2012541932A JP5572222B2 (ja) 2009-11-30 2010-11-04 リチウムイオン電池及び三元系正極活物質からのcmb液相触媒の製造方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20090116570A KR101089519B1 (ko) 2009-11-30 2009-11-30 리튬이온전지 및 3원계 양극활물질로부터 cmb 촉매 제조방법
KR10-2009-0116570 2009-11-30

Publications (2)

Publication Number Publication Date
WO2011065682A2 WO2011065682A2 (fr) 2011-06-03
WO2011065682A3 true WO2011065682A3 (fr) 2011-10-06

Family

ID=44067045

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/007750 Ceased WO2011065682A2 (fr) 2009-11-30 2010-11-04 Procédé de production de catalyseur cmb recyclé à partir d'une batterie au lithium-ion et de matières de cathode ternaires

Country Status (4)

Country Link
JP (1) JP5572222B2 (fr)
KR (1) KR101089519B1 (fr)
CN (1) CN102665912A (fr)
WO (1) WO2011065682A2 (fr)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101189798B1 (ko) * 2011-08-17 2012-10-10 한국지질자원연구원 폐cmb촉매로부터 cma 액상촉매의 제조방법
JP5406260B2 (ja) * 2011-09-29 2014-02-05 Jx日鉱日石金属株式会社 アルミニウム及びマンガンの分離方法
JP5847741B2 (ja) * 2013-02-18 2016-01-27 Jx日鉱日石金属株式会社 廃正極材及び廃電池からの金属回収方法
JP5847742B2 (ja) * 2013-02-18 2016-01-27 Jx日鉱日石金属株式会社 廃正極材及び廃電池からの金属回収方法
JP5706457B2 (ja) * 2013-02-27 2015-04-22 Jx日鉱日石金属株式会社 金属混合溶液からの金属の分離回収方法
JP6290633B2 (ja) * 2014-01-22 2018-03-07 Jx金属株式会社 リチウムイオン電池廃棄物の処理方法及び、それを用いる金属回収方法
EP3202929B1 (fr) * 2014-09-30 2021-12-22 JX Nippon Mining & Metals Corporation Procédé de lixiviation pour déchet de batterie lithium-ion et procédé de récupération de métal à partir d'un déchet de batterie lithium-ion
EP4209604A1 (fr) * 2014-09-30 2023-07-12 JX Nippon Mining & Metals Corporation Procédé de lixiviation de déchets de batterie au lithium-ion et procédé de récupération de métaux à partir de déchets de batterie au lithium-ion
KR101528507B1 (ko) * 2015-01-13 2015-06-12 한국지질자원연구원 리튬계 전지로부터 코발트 및 망간의 동시 회수 방법
CN113215409A (zh) * 2016-03-16 2021-08-06 捷客斯金属株式会社 锂离子电池废料的处理方法
CN109072335B (zh) * 2016-03-16 2021-07-20 捷客斯金属株式会社 锂离子电池废料的处理方法
CA3096116C (fr) 2017-05-30 2024-04-16 Li-Cycle Corp. Procede, appareil et systeme de recuperation de materiaux a partir de batteries
CN108011144B (zh) * 2017-10-31 2019-09-13 合肥国轩高科动力能源有限公司 一种锂离子电池三元正极材料的回收处理工艺
KR102750561B1 (ko) * 2017-12-19 2025-01-06 바스프 에스이 금속 니켈을 사용한 침출물의 처리에 의한 배터리 재활용
KR102206952B1 (ko) * 2019-04-22 2021-01-25 코스모에코켐(주) 폐양극활물질분말로부터 전구체 제조를 위한 혼합금속화합물의 제조방법
KR102154599B1 (ko) * 2019-04-30 2020-09-10 코스모에코켐(주) 양극활물질의 유가금속 분리회수방법
JP7365846B2 (ja) * 2019-10-16 2023-10-20 Jx金属株式会社 高純度硫酸コバルト溶液の製造方法及び、硫酸コバルトの製造方法
US11811035B2 (en) * 2020-05-27 2023-11-07 Ut-Battelle, Llc Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction
KR20230172482A (ko) * 2021-04-14 2023-12-22 메트소 핀란드 오이 리튬 이온 배터리 재료로부터 금속의 추출
US20240213562A1 (en) * 2021-04-14 2024-06-27 Metso Finland Oy Extraction of metals from lithium-ion battery material
CN113802002B (zh) * 2021-08-17 2022-11-15 广东邦普循环科技有限公司 湿法回收锂电池中有价金属的方法
CN113846219B (zh) * 2021-09-06 2022-11-15 广东邦普循环科技有限公司 一种从废旧锂电池中提取锂的方法
CN116103499B (zh) * 2023-02-16 2024-07-16 西安金藏膜环保科技有限公司 一种双光电极光电催化废旧锂电池有价金属浸出的方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5858061A (en) * 1994-12-20 1999-01-12 Varta Batterie Atkiengesellschaft Process for the recovery of metals from used nickel/metal hydride storage batteries
US6001763A (en) * 1996-07-29 1999-12-14 Feitler; David Method for re-manufacturing a cobalt/manganese/bromine catalyst from residue containing used catalyst
JP2003203680A (ja) * 2002-01-08 2003-07-18 Sumitomo Metal Mining Co Ltd 使用済みニッケル水素二次電池からの有価金属回収方法
KR20090087801A (ko) * 2008-02-13 2009-08-18 닛코 킨조쿠 가부시키가이샤 Co, Ni, Mn 함유 리튬 전지 찌꺼기로부터의 유가 금속 회수 방법

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0448038A (ja) * 1990-06-15 1992-02-18 Daihachi Chem Ind Co Ltd インジウムの分離方法およびインジウムとガリウムとの分離方法
JPH10287864A (ja) * 1997-04-14 1998-10-27 Nippon Chem Ind Co Ltd リチウムイオン二次電池用正極活物質からの有価金属の回収方法
TWI231063B (en) * 2003-11-14 2005-04-11 Ind Tech Res Inst Process of recovering valuable metals from waste secondary batteries
JP4388091B2 (ja) * 2007-03-22 2009-12-24 日鉱金属株式会社 Co,Ni,Mn含有電池滓からの貴金属回収方法
CN101586192B (zh) * 2009-06-23 2011-03-16 四川师范大学 镍钴锰酸锂废电池正负极混合材料的浸出方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5858061A (en) * 1994-12-20 1999-01-12 Varta Batterie Atkiengesellschaft Process for the recovery of metals from used nickel/metal hydride storage batteries
US6001763A (en) * 1996-07-29 1999-12-14 Feitler; David Method for re-manufacturing a cobalt/manganese/bromine catalyst from residue containing used catalyst
JP2003203680A (ja) * 2002-01-08 2003-07-18 Sumitomo Metal Mining Co Ltd 使用済みニッケル水素二次電池からの有価金属回収方法
KR20090087801A (ko) * 2008-02-13 2009-08-18 닛코 킨조쿠 가부시키가이샤 Co, Ni, Mn 함유 리튬 전지 찌꺼기로부터의 유가 금속 회수 방법

Also Published As

Publication number Publication date
JP5572222B2 (ja) 2014-08-13
WO2011065682A2 (fr) 2011-06-03
KR20110060089A (ko) 2011-06-08
KR101089519B1 (ko) 2011-12-05
CN102665912A (zh) 2012-09-12
JP2013512345A (ja) 2013-04-11

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