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WO2011065682A3 - Method for producing cmb catalyst recycled with lithium ion battery and ternary cathode materials - Google Patents

Method for producing cmb catalyst recycled with lithium ion battery and ternary cathode materials Download PDF

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Publication number
WO2011065682A3
WO2011065682A3 PCT/KR2010/007750 KR2010007750W WO2011065682A3 WO 2011065682 A3 WO2011065682 A3 WO 2011065682A3 KR 2010007750 W KR2010007750 W KR 2010007750W WO 2011065682 A3 WO2011065682 A3 WO 2011065682A3
Authority
WO
WIPO (PCT)
Prior art keywords
manganese
cobalt
ternary cathode
cmb
recovery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2010/007750
Other languages
French (fr)
Korean (ko)
Other versions
WO2011065682A2 (en
Inventor
신선명
강진구
주성호
장한권
손정수
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Korea Institute of Geoscience and Mineral Resources KIGAM
Original Assignee
Korea Institute of Geoscience and Mineral Resources KIGAM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Korea Institute of Geoscience and Mineral Resources KIGAM filed Critical Korea Institute of Geoscience and Mineral Resources KIGAM
Priority to CN2010800535942A priority Critical patent/CN102665912A/en
Priority to JP2012541932A priority patent/JP5572222B2/en
Publication of WO2011065682A2 publication Critical patent/WO2011065682A2/en
Publication of WO2011065682A3 publication Critical patent/WO2011065682A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68—Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/54—Reclaiming serviceable parts of waste accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/84—Recycling of batteries or fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Secondary Cells (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to recovery of cobalt and manganese from waste battery materials, and a method for making liquid catalysts from recovered Co-Mn-Br (CMB). More specifically, lithium-ion powder and ternary cathode materials are produced by leaching scrap battery materials with sulfate reduction, and sequential application of the following three process steps: neutralization titration, solid-liquid separation and solvent extraction, leads to recovery of cobalt and manganese as a liquid extract comprised of a Co-Mn-Br catalyst. According to the present invention, a CMB liquid phase catalyst that is useful for application in various manufacturing processes is provided by recovery of cobalt and manganese from waste ternary cathode and lithium-ion battery materials, enhancing the removal of other impurities, and recovering high purity cobalt and manganese.
PCT/KR2010/007750 2009-11-30 2010-11-04 Method for producing cmb catalyst recycled with lithium ion battery and ternary cathode materials Ceased WO2011065682A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2010800535942A CN102665912A (en) 2009-11-30 2010-11-04 Method for producing CMB catalyst recycled with lithium ion battery and ternary cathode materials
JP2012541932A JP5572222B2 (en) 2009-11-30 2010-11-04 Method for producing CMB liquid phase catalyst from lithium ion battery and ternary positive electrode active material

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR20090116570A KR101089519B1 (en) 2009-11-30 2009-11-30 Method for producing CMW catalyst from lithium ion battery and ternary cathode active material
KR10-2009-0116570 2009-11-30

Publications (2)

Publication Number Publication Date
WO2011065682A2 WO2011065682A2 (en) 2011-06-03
WO2011065682A3 true WO2011065682A3 (en) 2011-10-06

Family

ID=44067045

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2010/007750 Ceased WO2011065682A2 (en) 2009-11-30 2010-11-04 Method for producing cmb catalyst recycled with lithium ion battery and ternary cathode materials

Country Status (4)

Country Link
JP (1) JP5572222B2 (en)
KR (1) KR101089519B1 (en)
CN (1) CN102665912A (en)
WO (1) WO2011065682A2 (en)

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KR101189798B1 (en) * 2011-08-17 2012-10-10 한국지질자원연구원 Method for producing cobalt-manganese-acetic acid(cma) catalyst from spent cobalt-manganese-bromine (cmb) catalyst
JP5406260B2 (en) * 2011-09-29 2014-02-05 Ｊｘ日鉱日石金属株式会社 Method for separating aluminum and manganese
JP5847741B2 (en) * 2013-02-18 2016-01-27 Jx日鉱日石金属株式会社 Waste cathode material and method for recovering metal from waste battery
JP5847742B2 (en) * 2013-02-18 2016-01-27 Jx日鉱日石金属株式会社 Waste cathode material and method for recovering metal from waste battery
JP5706457B2 (en) * 2013-02-27 2015-04-22 Jx日鉱日石金属株式会社 Method for separating and recovering metal from mixed metal solution
JP6290633B2 (en) * 2014-01-22 2018-03-07 Ｊｘ金属株式会社 Lithium ion battery waste treatment method and metal recovery method using the same
EP3202929B1 (en) * 2014-09-30 2021-12-22 JX Nippon Mining & Metals Corporation Leaching method for lithium ion battery scrap and method for recovering metal from lithium ion battery scrap
EP4209604A1 (en) * 2014-09-30 2023-07-12 JX Nippon Mining & Metals Corporation Method for leaching lithium ion battery scrap and method for recovering metals from lithium ion battery scrap
KR101528507B1 (en) * 2015-01-13 2015-06-12 한국지질자원연구원 Co-recovery method of cobalt and manganese from litium cells
CN113215409A (en) * 2016-03-16 2021-08-06 捷客斯金属株式会社 Treatment method of lithium ion battery waste
CN109072335B (en) * 2016-03-16 2021-07-20 捷客斯金属株式会社 How to dispose of lithium-ion battery waste
CA3096116C (en) 2017-05-30 2024-04-16 Li-Cycle Corp. A process, apparatus, and system for recovering materials from batteries
CN108011144B (en) * 2017-10-31 2019-09-13 合肥国轩高科动力能源有限公司 Recovery treatment process of ternary cathode material of lithium ion battery
KR102750561B1 (en) * 2017-12-19 2025-01-06 바스프 에스이 Battery recycling by treatment of leachate using metallic nickel
KR102206952B1 (en) * 2019-04-22 2021-01-25 코스모에코켐(주) Manufacturing Method of Mixed Metal Compounds for Preparing Precursors from Waste Cathode Active Material Powders
KR102154599B1 (en) * 2019-04-30 2020-09-10 코스모에코켐(주) Method for Separation and Recovery of Valuable Metals from Cathode Active Material
JP7365846B2 (en) * 2019-10-16 2023-10-20 Ｊｘ金属株式会社 Method for producing high purity cobalt sulfate solution and method for producing cobalt sulfate
US11811035B2 (en) * 2020-05-27 2023-11-07 Ut-Battelle, Llc Recovery of critical elements from end-of-life lithium ion batteries with supported membrane solvent extraction
KR20230172482A (en) * 2021-04-14 2023-12-22 메트소 핀란드 오이 Extraction of metals from lithium-ion battery materials
US20240213562A1 (en) * 2021-04-14 2024-06-27 Metso Finland Oy Extraction of metals from lithium-ion battery material
CN113802002B (en) * 2021-08-17 2022-11-15 广东邦普循环科技有限公司 Method for recovering valuable metals in lithium battery by wet process
CN113846219B (en) * 2021-09-06 2022-11-15 广东邦普循环科技有限公司 Method for extracting lithium from waste lithium batteries
CN116103499B (en) * 2023-02-16 2024-07-16 西安金藏膜环保科技有限公司 Method for leaching valuable metals from waste lithium batteries by photoelectrocatalysis of double photoelectrodes

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US5858061A (en) * 1994-12-20 1999-01-12 Varta Batterie Atkiengesellschaft Process for the recovery of metals from used nickel/metal hydride storage batteries
US6001763A (en) * 1996-07-29 1999-12-14 Feitler; David Method for re-manufacturing a cobalt/manganese/bromine catalyst from residue containing used catalyst
JP2003203680A (en) * 2002-01-08 2003-07-18 Sumitomo Metal Mining Co Ltd Method for recovering valuable metals from used nickel metal hydride secondary batteries
KR20090087801A (en) * 2008-02-13 2009-08-18 닛코 킨조쿠 가부시키가이샤 Process for recovering valuable metals from CO, Ni, Mn-containing lithium battery waste

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JP4388091B2 (en) * 2007-03-22 2009-12-24 日鉱金属株式会社 Noble metal recovery method from Co, Ni, Mn containing battery
CN101586192B (en) * 2009-06-23 2011-03-16 四川师范大学 Leaching method for anode and cathode mixed materials of waste LiCoxNiyMnzO2 battery

Patent Citations (4)

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US5858061A (en) * 1994-12-20 1999-01-12 Varta Batterie Atkiengesellschaft Process for the recovery of metals from used nickel/metal hydride storage batteries
US6001763A (en) * 1996-07-29 1999-12-14 Feitler; David Method for re-manufacturing a cobalt/manganese/bromine catalyst from residue containing used catalyst
JP2003203680A (en) * 2002-01-08 2003-07-18 Sumitomo Metal Mining Co Ltd Method for recovering valuable metals from used nickel metal hydride secondary batteries
KR20090087801A (en) * 2008-02-13 2009-08-18 닛코 킨조쿠 가부시키가이샤 Process for recovering valuable metals from CO, Ni, Mn-containing lithium battery waste

Also Published As

Publication number Publication date
JP5572222B2 (en) 2014-08-13
WO2011065682A2 (en) 2011-06-03
KR20110060089A (en) 2011-06-08
KR101089519B1 (en) 2011-12-05
CN102665912A (en) 2012-09-12
JP2013512345A (en) 2013-04-11

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