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WO2010013749A1 - メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法 - Google Patents

メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法 Download PDF

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Publication number
WO2010013749A1
WO2010013749A1 PCT/JP2009/063499 JP2009063499W WO2010013749A1 WO 2010013749 A1 WO2010013749 A1 WO 2010013749A1 JP 2009063499 W JP2009063499 W JP 2009063499W WO 2010013749 A1 WO2010013749 A1 WO 2010013749A1
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WO
WIPO (PCT)
Prior art keywords
methacrylic acid
catalyst
producing
alkali metal
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2009/063499
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English (en)
French (fr)
Inventor
洋子 篠田
柾　朋博
近藤　正英
内藤　啓幸
雄一 田川
俊雄 長谷川
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Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP2009537338A priority Critical patent/JP5659490B2/ja
Priority to CN200980129513XA priority patent/CN102105223B/zh
Publication of WO2010013749A1 publication Critical patent/WO2010013749A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

　本発明は、メタクリル酸を高選択率で製造できるメタクリル酸製造用触媒、その製造方法、およびこの触媒を用いたメタクリル酸の製造方法を提供する。本発明では、水中に少なくともモリブデン原料およびＸ元素の原料を添加して、ヘテロポリ酸を含む水性スラリーまたは水溶液を調製し、その水性スラリーまたは水溶液にアルカリ金属化合物を添加して、ヘテロポリ酸の少なくとも一部がアルカリ金属塩になったヘテロポリ酸塩を析出させた後、リン原料を添加することで、リン元素、モリブデン元素、Ｘ元素（ケイ素、チタン、ゲルマニウム、ヒ素、アンチモンおよびセリウムからなる群より選ばれた少なくとも１種類の元素）およびアルカリ金属元素を含む触媒を製造し、メタクリル酸の製造に用いる。
PCT/JP2009/063499 2008-07-29 2009-07-29 メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法 Ceased WO2010013749A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009537338A JP5659490B2 (ja) 2008-07-29 2009-07-29 メタクリル酸製造用触媒の製造方法、およびメタクリル酸の製造方法
CN200980129513XA CN102105223B (zh) 2008-07-29 2009-07-29 甲基丙烯酸制造用催化剂及其制造方法、以及甲基丙烯酸的制造方法

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2008-194759 2008-07-29
JP2008194759 2008-07-29
JP2009119753 2009-05-18
JP2009-119753 2009-05-18

Publications (1)

Publication Number Publication Date
WO2010013749A1 true WO2010013749A1 (ja) 2010-02-04

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PCT/JP2009/063499 Ceased WO2010013749A1 (ja) 2008-07-29 2009-07-29 メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法

Country Status (4)

Country Link
JP (1) JP5659490B2 (ja)
KR (1) KR101593723B1 (ja)
CN (1) CN102105223B (ja)
WO (1) WO2010013749A1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011152519A (ja) * 2010-01-28 2011-08-11 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法
JP2011173114A (ja) * 2010-01-28 2011-09-08 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法
JP2012232245A (ja) * 2011-04-28 2012-11-29 Mitsubishi Rayon Co Ltd 不飽和カルボン酸合成用触媒の製造方法
JP2013006162A (ja) * 2011-06-27 2013-01-10 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
JP2013192988A (ja) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法
JP2013192989A (ja) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
WO2019208715A1 (ja) * 2018-04-26 2019-10-31 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、並びにメタクリル酸及びメタクリル酸エステルの製造方法
JP2019188268A (ja) * 2018-04-18 2019-10-31 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、およびメタクリル酸の製造方法
JP2020015043A (ja) * 2015-03-09 2020-01-30 日本化薬株式会社 メタクリル酸製造用触媒の製造方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110062656B (zh) * 2016-12-12 2022-05-13 三菱化学株式会社 α,β-不饱和羧酸制造用催化剂前体的制造方法
CN111545228B (zh) * 2020-05-29 2023-05-23 烟台大学 一种微波辅助老化的杂多酸盐/氧化铈复合催化剂及其制备方法
CN113893879B (zh) * 2021-11-04 2024-02-06 淄博市翔力致高新材料有限责任公司 一种杂多酸催化剂及其制备方法和用途
CN114797982A (zh) * 2022-05-26 2022-07-29 中国科学技术大学 一种用于异丁烷一步法制甲基丙烯酸的催化剂、其制备方法及应用

Citations (8)

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JPS5732734A (en) * 1980-08-05 1982-02-22 Standard Oil Co Metachlorine oxidation catalyst and its use
JPH081005A (ja) * 1994-06-22 1996-01-09 Sumitomo Chem Co Ltd メタクリル酸製造用触媒の製造法
JPH09183748A (ja) * 1995-10-31 1997-07-15 Sun Co Inc R & M アルカン類の不飽和カルボン酸への変換
JP2001104793A (ja) * 1999-08-17 2001-04-17 Rohm & Haas Co ヘテロポリ酸／ポリオキソメタレート触媒
JP2001114726A (ja) * 1999-10-12 2001-04-24 Nippon Shokubai Co Ltd メタクリル酸の製造方法
JP2004008834A (ja) * 2002-06-03 2004-01-15 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
JP2008272626A (ja) * 2007-04-26 2008-11-13 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒、その製造方法、およびメタクリル酸の製造方法
JP2009101251A (ja) * 2007-10-19 2009-05-14 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒、その製造方法、およびメタクリル酸の製造方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0733344B2 (ja) 1986-12-06 1995-04-12 旭化成工業株式会社 メタクリル酸および／またはメタクロレインの製法
JPH085820B2 (ja) 1988-04-05 1996-01-24 旭化成工業株式会社 メタクリル酸および／またはメタクロレインの製造法
JPH047037A (ja) 1990-04-23 1992-01-10 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の調製法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5732734A (en) * 1980-08-05 1982-02-22 Standard Oil Co Metachlorine oxidation catalyst and its use
JPH081005A (ja) * 1994-06-22 1996-01-09 Sumitomo Chem Co Ltd メタクリル酸製造用触媒の製造法
JPH09183748A (ja) * 1995-10-31 1997-07-15 Sun Co Inc R & M アルカン類の不飽和カルボン酸への変換
JP2001104793A (ja) * 1999-08-17 2001-04-17 Rohm & Haas Co ヘテロポリ酸／ポリオキソメタレート触媒
JP2001114726A (ja) * 1999-10-12 2001-04-24 Nippon Shokubai Co Ltd メタクリル酸の製造方法
JP2004008834A (ja) * 2002-06-03 2004-01-15 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
JP2008272626A (ja) * 2007-04-26 2008-11-13 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒、その製造方法、およびメタクリル酸の製造方法
JP2009101251A (ja) * 2007-10-19 2009-05-14 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒、その製造方法、およびメタクリル酸の製造方法

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011173114A (ja) * 2010-01-28 2011-09-08 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法
JP2011152519A (ja) * 2010-01-28 2011-08-11 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法、ならびにメタクリル酸の製造方法
JP2012232245A (ja) * 2011-04-28 2012-11-29 Mitsubishi Rayon Co Ltd 不飽和カルボン酸合成用触媒の製造方法
JP2013006162A (ja) * 2011-06-27 2013-01-10 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
JP2013192988A (ja) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒およびその製造方法
JP2013192989A (ja) * 2012-03-16 2013-09-30 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の製造方法
JP2020015043A (ja) * 2015-03-09 2020-01-30 日本化薬株式会社 メタクリル酸製造用触媒の製造方法
JP7006477B2 (ja) 2018-04-18 2022-02-10 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、およびメタクリル酸の製造方法
JP2019188268A (ja) * 2018-04-18 2019-10-31 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、およびメタクリル酸の製造方法
WO2019208715A1 (ja) * 2018-04-26 2019-10-31 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、並びにメタクリル酸及びメタクリル酸エステルの製造方法
KR20210002576A (ko) 2018-04-26 2021-01-08 미쯔비시 케미컬 주식회사 메타크릴산 제조용 촉매의 제조 방법, 및 메타크릴산 및 메타크릴산 에스터의 제조 방법
JPWO2019208715A1 (ja) * 2018-04-26 2021-05-20 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、並びにメタクリル酸及びメタクリル酸エステルの製造方法
CN112004597A (zh) * 2018-04-26 2020-11-27 三菱化学株式会社 甲基丙烯酸制造用催化剂的制造方法、以及甲基丙烯酸和甲基丙烯酸酯的制造方法
JP7031737B2 (ja) 2018-04-26 2022-03-08 三菱ケミカル株式会社 メタクリル酸製造用触媒の製造方法、並びにメタクリル酸及びメタクリル酸エステルの製造方法

Also Published As

Publication number Publication date
CN102105223A (zh) 2011-06-22
JP5659490B2 (ja) 2015-01-28
CN102105223B (zh) 2013-07-10
KR101593723B1 (ko) 2016-02-12
KR20110044266A (ko) 2011-04-28
JPWO2010013749A1 (ja) 2012-01-12

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