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WO2007045055A3 - Method for electroextaction of zinc - Google Patents

Method for electroextaction of zinc Download PDF

Info

Publication number
WO2007045055A3
WO2007045055A3 PCT/BG2006/000019 BG2006000019W WO2007045055A3 WO 2007045055 A3 WO2007045055 A3 WO 2007045055A3 BG 2006000019 W BG2006000019 W BG 2006000019W WO 2007045055 A3 WO2007045055 A3 WO 2007045055A3
Authority
WO
WIPO (PCT)
Prior art keywords
zinc
solution
electroextraction
calcine
zinc sulphate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/BG2006/000019
Other languages
French (fr)
Other versions
WO2007045055A2 (en
Inventor
Pencho Lesidrenski
Ivan Gruev
Nikola Nikolov
Atanas Apostolov
Slaveya Stoyanova
Nikola Petrov
Angel Grozev
Tsvetan Alexandrov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LEAD AND ZINC COMPLEX PEC
Original Assignee
LEAD AND ZINC COMPLEX PEC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LEAD AND ZINC COMPLEX PEC filed Critical LEAD AND ZINC COMPLEX PEC
Publication of WO2007045055A2 publication Critical patent/WO2007045055A2/en
Publication of WO2007045055A3 publication Critical patent/WO2007045055A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/20—Obtaining zinc otherwise than by distilling
    • C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrolytic Production Of Metals (AREA)

Abstract

A method for electroextraction of zinc from zinc sulphate solution obtained by leaching of zinc calcine in which a sulphite reagent is added continuously to a purified from impurities zinc sulphate solution to provide a concentration of SO3-2 in the solution of 300 to 1500 mg/1 and said zinc sulphate solution is subjected to electroextraction where the zinc is plated on the cathode and a part of the spent electrolyte is fed for dissolving new portions of calcine. Sulphurous acid or water solution of its salt is used as sulphite reagent. Preferably a solution of sodium bisulphite NaHSO3 is used.
PCT/BG2006/000019 2005-10-20 2006-10-19 Method for electroextaction of zinc Ceased WO2007045055A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
BG109329A BG109329A (en) 2005-10-20 2005-10-20 Method for electroextraction of zinc
BG109329 2005-10-20

Publications (2)

Publication Number Publication Date
WO2007045055A2 WO2007045055A2 (en) 2007-04-26
WO2007045055A3 true WO2007045055A3 (en) 2007-11-15

Family

ID=37872467

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/BG2006/000019 Ceased WO2007045055A2 (en) 2005-10-20 2006-10-19 Method for electroextaction of zinc

Country Status (2)

Country Link
BG (1) BG109329A (en)
WO (1) WO2007045055A2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101824549A (en) * 2010-04-15 2010-09-08 赤峰中色库博红烨锌业有限公司 Method for improving purity of zinc ingot by filtering waste electrolyte
CN103774185B (en) * 2014-01-24 2016-05-04 中国环境科学研究院 The device that a kind of dry method is removed the crystallization of electrolytic zinc anode plate zinc sulfate and collected
CN113249592B (en) * 2021-05-13 2022-09-20 西南科技大学 Method for selective leaching of zinc from zinc ferrite-containing waste residue by mechanically activated directional reduction
CN117926346A (en) * 2024-03-22 2024-04-26 清华大学 Process for producing electrodeposited zinc by leaching zinc-containing paint slag in ammonium chloride solution

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4053552A (en) * 1976-03-15 1977-10-11 General Mills Chemicals Co. Solvent extraction of zinc from sulfite-bisulfite solution
US4439288A (en) * 1983-07-11 1984-03-27 Exxon Research & Engineering Company Process for reducing Zn consumption in zinc electrolyte purification
US4488942A (en) * 1983-08-05 1984-12-18 Omi International Corporation Zinc and zinc alloy electroplating bath and process
EP0215643A1 (en) * 1985-09-12 1987-03-25 Cominco Ltd. Method for monitoring the quality of zinc sulfate electrolyte containing antimony (V)

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4053552A (en) * 1976-03-15 1977-10-11 General Mills Chemicals Co. Solvent extraction of zinc from sulfite-bisulfite solution
US4439288A (en) * 1983-07-11 1984-03-27 Exxon Research & Engineering Company Process for reducing Zn consumption in zinc electrolyte purification
US4488942A (en) * 1983-08-05 1984-12-18 Omi International Corporation Zinc and zinc alloy electroplating bath and process
EP0215643A1 (en) * 1985-09-12 1987-03-25 Cominco Ltd. Method for monitoring the quality of zinc sulfate electrolyte containing antimony (V)

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
SOLE K C ET AL: "Solvent extraction in southern Africa: An update of some recent hydrometallurgical developments", HYDROMETALLURGY, ELSEVIER SCIENTIFIC PUBLISHING CY. AMSTERDAM, NL, vol. 78, no. 1-2, July 2005 (2005-07-01), pages 52 - 78, XP004963376, ISSN: 0304-386X *
T. MORI ET AL.: "Effect of cathodic reduction on catalytic activity of amorphous alloy electrodes for electrooxidation of sulfite", JOURNAL OF APPLIED ELECTROCHEMISTRY, vol. 25, 1995, pages 953 - 961, XP008083224 *

Also Published As

Publication number Publication date
WO2007045055A2 (en) 2007-04-26
BG109329A (en) 2007-04-30

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