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WO2006128583A1 - Preparations cosmetiques contenant un extrait de fruits d'anis aqueux et un ou plusieurs polymeres d'acide acrylamidomethylpropylsulfonique - Google Patents

Preparations cosmetiques contenant un extrait de fruits d'anis aqueux et un ou plusieurs polymeres d'acide acrylamidomethylpropylsulfonique Download PDF

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Publication number
WO2006128583A1
WO2006128583A1 PCT/EP2006/004642 EP2006004642W WO2006128583A1 WO 2006128583 A1 WO2006128583 A1 WO 2006128583A1 EP 2006004642 W EP2006004642 W EP 2006004642W WO 2006128583 A1 WO2006128583 A1 WO 2006128583A1
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WO
WIPO (PCT)
Prior art keywords
acid
sulfonic acid
cosmetic preparations
present
methyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2006/004642
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German (de)
English (en)
Inventor
Svenja Cerv
Stefan Gallinat
Christopher Mummert
Thomas Raschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beiersdorf AG
Original Assignee
Beiersdorf AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beiersdorf AG filed Critical Beiersdorf AG
Priority to EP06753666A priority Critical patent/EP1890774A1/fr
Publication of WO2006128583A1 publication Critical patent/WO2006128583A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9789—Magnoliopsida [dicotyledons]
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/002—Aftershave preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/004—Aftersun preparations

Definitions

  • Cosmetic preparations containing an aqueous aniseed extract and one or more acrylamidomethylpropylsulfonic acid polymers are included in Cosmetic preparations containing an aqueous aniseed extract and one or more acrylamidomethylpropylsulfonic acid polymers
  • the present invention relates to cosmetic preparations containing an aqueous aniseed fruit extract and Acrylamidomethylpropylsulfonklare polymer and their use in the field of cosmetic and pharmaceutical dermatology.
  • the horny layer is constantly worn in contact with the environment and must therefore be renewed continuously.
  • a skin model widely used today in the art understands the stratum corneum as a two-component system, similar to a brick wall (brick-mortar model).
  • the corneocytes homocells
  • the complex composite lipid membrane in the intercellular spaces corresponds to the mortar.
  • the epidermal lipids In addition to their barrier effect against external chemical and physical influences, the epidermal lipids also contribute to the cohesion of the horny layer and have an influence on the skin smoothness. In contrast to the sebaceous gland lipids, which do not form a closed film on the skin, the epidermal lipids are distributed over the entire horny layer.
  • the active ingredient combinations according to the invention or cosmetic or dermatological preparations containing them better than moisturizing agent will better protect against dehydration by emulsifiers and coemulsifiers better improve the barrier performance of the skin better protects the skin from exogenous noxious substances better against the symptoms of sensitive skin better protects the skin roughness reduces better against aging of the skin act as the active ingredients, drug combinations and preparations of the prior art.
  • an aqueous fruit extract from anise which is rich in inorganic minerals such as sodium and magnesium ions, especially potassium ions and with butylene glycol 0.36% and parabens 0.14% is conserved and obtainable by enzymatic hydrolysis in water of solubilized aniseed fruit, wherein the ratio of raw material to extract is about ⁇ A and is available under the trade name Bioxilift from SILAB, (Brive Cedex, France)
  • radical polymerization of 2-acrylamido-2-methylpropanesulfonic acid by radical copolymerization of 2-acrylamido-2-methylpropanesulfonic acid and. one or more macromonomers containing an end group capable of polymerization, a hydrophilic part based on polyalkylene oxides and a hydrophobic part containing hydrogen or a saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic or aromatic (C 1 -C 30 ) - Hydrocarbon radical comprises, and / or
  • one or more olefinically unsaturated comonomers containing oxygen, nitrogen, sulfur, phosphorus, chlorine and / or fluorine produced one or more olefinically unsaturated comonomers containing oxygen, nitrogen, sulfur, phosphorus, chlorine and / or fluorine produced.
  • the macromonomers A) are preferably those of the formula
  • R 1 -Y- (R 2 -O) X -R 3 wherein R 1 is a vinyl, allyl, acrylic or methacrylic radical; R 2 is (C 2 -C 4 ) alkylene; x is an integer between 1 and 500; Y is oxygen, sulfur, PH or NH and R 3 is hydrogen or a saturated or unsaturated, linear or branched, aliphatic, cycloaliphatic or aromatic (C 1 to C 30 ) hydrocarbon radical.
  • R1 is particularly preferably an acrylic or methacrylic radical.
  • R 2 is particularly important zugt for an ethylene or propylene radical. More preferably, x is a number between 3 and 50, more preferably a number between 7 and 30.
  • R3 is preferably aliphatic or cycloaliphatic hydrocarbons, which may be saturated or unsaturated.
  • R 3 particularly preferably represents a (C 6 to C 22 ) hydrocarbon radical, particularly preferably a (C 12 to C 18 ) hydrocarbon radical.
  • the monomer distribution of the macromonomers A) and / or comonomers B), and 2-acrylamido-2-methylpropanesulfonic acid in the polymers can be, for example, alternating, blocky (also multiblock) or random (also gradient).
  • the polymers generally have a number average molecular weight of from 1000 to 20,000,000 g / mol, preferably from 20,000 to 5,000,000, particularly preferably from 100,000 to 1,500,000 g / mol.
  • the polymers of the invention are crosslinked, d. H. they contain at least one crosslinker having at least two double bonds, which is polymerized into the polymer.
  • Suitable crosslinkers are in particular Methylenbisacryl- and - methacrylamide, esters of unsaturated mono- or polycarboxylic acids with polyols, eg. As diacrylates or triacrylates, such as. For example, butanediol and ethylene glycol diacrylate or methacrylate and Trimethy- lolpropantriacrylat, allyl compounds such.
  • allyl (meth) acrylate triallyl cyanurate, maleic acid diallyl esters, polyallyl esters, tetraallyloxyethane, triallylamine, tetraallylethylenediamine, allyl esters of phosphoric acid and / or vinylphosphonic acid derivatives.
  • the AMPS polymers may be commercially available as 100% active ingredient or as inverse thickener.
  • Aristoflex AVC ammonium acryloyldimethyltaurate / VP Copolymer, Clariant
  • Aristoflex HMB ammonium acryloyldimethyltaurate / beheneth-25 methacrylate copolymer, Clariant
  • Simulgel NS Hydroxyethyl acrylate / sodium acryloyl dimethyl taurate
  • Copolymer / squalane / polysorbate Polymers advantageous according to the invention are described, for example, in DE 100 29 462 A1.
  • Acrylamidomethylpropylsulfonklare polymer is the Ammoniu- macryloyldimethyltaurat / VP copolymer.
  • Cosmetic or dermatological preparations for the purposes of the present invention advantageously contain 0.05 to 5% by weight, in particular 0.1 to 3% by weight, based on the total weight of the preparations, of one or more acrylamidomethylpropylsulfonic acid polymers.
  • ammonium acryloyldimethyltaurate / vinylpyrrolidone copolymers have the empirical formula [C 7 H 16 N 2 SO 4 J n [C 6 H 9 NO]., Corresponding to a statistical structure as follows
  • the preparations are particularly advantageously characterized in that the one aqueous aniseed extract in concentrations of 0.01 to 10.00 wt .-%, preferably 0.05 to 5.00 wt .-%, particularly preferably 0.1 3.00% by weight, based in each case on the total weight of the composition.
  • Cosmetic preparations in which the aqueous aniseed extract is present in concentrations of 0.01-10.00% by weight, preferably 0.05-5.00% by weight, more preferably 0.1-3.00% by weight, each based on the total weight of the composition, is present, are also advantageous according to the invention.
  • antioxidants which are suitable or customary for cosmetic and / or dermatological applications can be used as favorable antioxidants.
  • the antioxidants are selected from the group consisting of amino acids (eg glycine, histidine, tyrosine, tryptophan) and their derivatives, peptides such as D, L-camosine, D-carnosine, L-carnosine and their derivatives (eg anserine), carotenoids (eg ⁇ -carotene, ⁇ -carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (eg dihydrolipoic acid), thiols (eg thioredoxin, glutathione, cysteine, cystine, cystamine) and their salts,, furthermore (metal ) Chelating agents (eg g-hydroxyfatty acids, phytic acid, lactoferrin), ⁇ -hydroxy acids (eg citric acid, lactic acid, malic acid), bile acid, bile extracts, bilirubin, biliverdin,
  • amino acids
  • the cosmetic preparations according to the invention may contain cosmetic aids as are commonly used in such preparations, e.g. Preservatives, bactericides, antioxidants, UV filters, perfumes, antifoaming agents, dyes, pigments which have a coloring effect, thickeners, surface-active substances, emulsifiers, emollients, moisturizing and / or moisturizing substances, fats, oils, waxes or other common ingredients of a cosmetic formulation such as alcohols, polyols, polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.
  • cosmetic aids as are commonly used in such preparations, e.g. Preservatives, bactericides, antioxidants, UV filters, perfumes, antifoaming agents, dyes, pigments which have a coloring effect, thickeners, surface-active substances, emulsifiers, emollients, moisturizing and / or moisturizing substances, fats, oils, waxes or other common ingredients of a
  • the preparations according to the present invention preferably contain at least one further UV-A, UV-B and / or broad-spectrum filter substance.
  • the formulations may, although not necessary, optionally also contain one or more organic and / or inorganic pigments as UV filter substances, which may be present in the water and / or the oil phase.
  • the preparations according to the invention may also advantageously be in the form of so-called oil-free cosmetic or dermatological emulsions which contain a water phase and at least one UV filter substance which is liquid at room temperature as further phase.
  • ICI homomenthyls
  • Preferred inorganic pigments are metal oxides and / or other sparingly water-soluble or insoluble metal compounds, in particular oxides of titanium (TiO 2 ), zinc (ZnO), Iron (eg Fe 2 O 3 ), zirconium (ZrO 2 ), silicon (SiO 2 ), manganese (eg MnO), aluminum (Al 2 O 3 ), cerium (eg Ce 2 O 3 ), mixed oxides of the corresponding metals and mixtures of such oxides and the sulfate of barium (BaSO 4 ).
  • the pigments can also be used advantageously in the form of commercially available oily or aqueous predispersions.
  • dispersants and / or solubilizers can be added to these predispersions.
  • the pigments can advantageously be treated superficially, it being intended, for example, to form or retain a hydrophilic, amphiphilic or hydrophobic character.
  • This surface treatment may consist in providing the pigments with a thin hydrophilic and / or hydrophobic inorganic and / or organic layer by processes known per se.
  • the various surface coatings may also contain water for the purposes of the present invention.
  • Inorganic surface coatings for the purposes of the present invention may consist of aluminum oxide (Al 2 O 3 ), aluminum hydroxide Al (OH) 3 , or aluminum oxide hydrate (also: alumina, CAS No .: 1333-84-2), sodium hexametaphosphate (NaPO 3 ). 6 , sodium metaphosphate (NaPO 3 ) n , silicon dioxide (SiO 2 ) (also: silica, CAS No .: 7631-86-9), or iron oxide (Fe 2 O 3 ). These inorganic surface coatings may be present alone, in combination and / or in combination with organic coating materials.
  • Organic surface coatings for the purposes of the present invention may consist of vegetable or animal aluminum stearate, vegetable or animal stearic acid, lauric acid, dimethylpolysiloxane (also: dimethicone), methylpolysiloxane (methicone), simethicone (a mixture of dimethylpolysiloxane with an average chain length of 200 to 350 Dimethylsiloxane units and silica gel) or alginic acid. These organic surface coatings may be present alone, in combination and / or in combination with inorganic coating materials.
  • Zinc oxide particles which are suitable according to the invention and predispersions of zinc oxide particles are obtainable from the following companies under the following commercial names:
  • Suitable titanium dioxide particles and predispersions of titanium dioxide particles are available from the following companies under the following trade names:
  • UV-A filter substances for the purposes of the present invention are dibenzoyl methane derivatives, in particular the 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS No. 70356-09-1), which is sold by Givaudan under the trade name Parsol ® is sold in 1789 and by Merck under the trade name Eusolex® 9020th
  • UV filter substances in the context of the present invention are sulfonated, water-soluble UV filters, such as. B .:
  • Sulfonic acid derivatives of 3-Benzylidencamphers such as. B. 4- (2-oxo-3-bomylidenemethyl) - benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
  • Advantageous UV filter substances for the purposes of the present invention are also so-called broadband filters, i. Filter substances that absorb both UV-A and UV-B radiation.
  • Advantageous broadband filters or UV-B filter substances are, for example, triazine derivatives, such as. B.
  • Diethylhexylbutylamidotriazone (INCI: diethylhexylbutamidotriazone), available under the trade designation UVASORB HEB from Sigma 3V;
  • An advantageous broadband filter for the purposes of the present invention is also the 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) phenol), which is available under the trade name Tinosorb® M from CIBA-Chemikalien GmbH.
  • Advantageous broadband filter for the purposes of the present invention is also the 2- (2H-benzotriazole) -ylM-methyl-e - ⁇ -methyl-S-fi .SSS-tetramethyl-i- ⁇ trimethylsilyOoxyJdisiloxanyOpropyl] - phenol (CAS no. : 155633-54-8) with the INCI name Drometrizole Trisiloxane, which is available under the trade name Mexoryl® XL from Chimex.
  • the other UV filter substances can be oil-soluble or water-soluble.
  • 3-benzylidene camphor derivatives preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
  • ⁇ cinnamic acid derivatives preferably 2-Ethylhexylmethoxycinnamate (CAS No .: 5466-77-3), which is available under the trade name Parsol MCX from Givaudan.
  • 4-aminobenzoic acid derivatives preferably (2-ethylhexyl) -4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
  • benzophenone preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-methylbenzophenone, 2,2-dihydroxy-4-methoxybenzophenone
  • Advantageous water-soluble filter substances are z. B.: Sulfonic acid derivatives of 3-Benzylidencamphers, such as. B. 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
  • a further light protection filter substance according to the invention to be used advantageously is ethylhexyl-2-cyano-3,3-diphenylacrylate, obtainable (octocrylene) from BASF under the name Uvinul ® N 539th
  • Particularly advantageous preparations in the context of the present invention which are distinguished by a high or very high UV-A and / or UV-B protection, preferably contain, in addition to the filter substance (s) according to the invention further UV-A and /or Broadband filter, in particular Dibenzoylmethanderivate [for example, the 4- (tert-butyl) -4'-methoxydibenzoylmethan], phenylene-1 I 4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and / or their salts, the 1,4-di (2-oxo-10-sulfo-3-bomylidenemethyl) benzene and / or its salts and / or the 2,4-bis - [[4- (2-ethyl-hexyloxy) 2-hydroxy] -phenyl ⁇ -6- (4-methoxyphenyl) -1,3,5-triazine, each individually or in any combination with one
  • UV filters which can be used in the context of the present invention is of course not intended to be limiting.
  • the preparations of the invention contain the substances which absorb UV radiation in the UV-A and / or UV-B range, in a total amount of z. B. 0.1 wt .-% to 30 wt .-%, preferably 0.5 to 20 wt .-%, in particular 1, 0 to 15.0 wt .-%, each based on the total weight of the preparations to cosmetic To provide preparations that protect the hair or the skin from the entire range of ultraviolet radiation.
  • the solvents used may be: water or aqueous solutions;
  • Oils such as triglycerides of capric or caprylic acid, fatty acid ethers such as dicaprylyl ether, carbonic acid esters such as dicaprylyl carbonate, and vegetable triglycerides such as sunflower oil; Octyldodecanol, cyclomethicone, dimethicone
  • Fats, waxes and other natural and synthetic fats preferably esters of fatty acids with lower C-number alcohols, e.g. with isopropanol, propylene glycol or glycerol, or esters of fatty alcohols with alkanoic acids of low C number or with fatty acids;
  • ethers preferably ethanol, isopropanol, propylene glycol, glycerol, ethylene glycol, ethylene glycol monoethyl or monobutyl ether, propylene glycol monomethyl, monoethyl or monobutyl ether, diethylene glycol monomethyl or monoethyl ether, ethylhexyl glycerol, Methylpropanediol and analog products.
  • O / W emulsifiers are glyceryl stearate citrate, polyglyceryl-3-methyl glucose distearate, cetearyl glucosides, PEG-40 stearate, PEG-100 stearate, stearic acid, ceteareth-20, steareth-20, steareth-21 and glyceryl stearate.
  • Cosmetic preparations in the sense of the present invention can also be present as gels which, in addition to an effective content of the active ingredient according to the invention and solvents used for this purpose, preferably water, additionally contain additional organic and / or inorganic thickeners. Furthermore, these thickeners are part of cosmetic emulsions.
  • Additional thickeners for such preparations are, for example, copolymers of C 10 . 30 alkyl acrylates and one or more monomers of acrylic acid, methacrylic acid or their esters.
  • the INCI name for such compounds is "acrylates / C 10-30 alkyl acrylate crosspolymer.”
  • Particularly advantageous are the Pemulen® types TR 1, TR 2 and TRZ from Goodrich (Noveon).
  • Carbopols are also advantageous additional gelling agents for such preparations.
  • Carbopols are polymers of acrylic acid, especially acrylate-alkyl acrylate copolymers.
  • advantageous carbopols are types 980, 981, 984 1342, 1382, 2984 and 5984.
  • gelling agents for such preparations are xanthan gum, polyvinylpyrrolidone, cellulose derivatives, in particular cellulose ethers such as, for example, hydroxypropylmethylcellulose, starch and starch derivatives, hyaluronic acid locust bean gum, silicon dioxide and aluminum silicates.
  • the thickening agent is present in the gel, dispersion or emulsion e.g. in an amount of between 0.01 and 5% by weight, preferably between 0.1 and 2% by weight.

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
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  • Microbiology (AREA)
  • Mycology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des préparations cosmétiques contenant (I) un extrait de fruit d'anis aqueux et (ii) un ou plusieurs polymères d'acide acrylamidométhylpropylsulfonique.
PCT/EP2006/004642 2005-06-03 2006-05-17 Preparations cosmetiques contenant un extrait de fruits d'anis aqueux et un ou plusieurs polymeres d'acide acrylamidomethylpropylsulfonique Ceased WO2006128583A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06753666A EP1890774A1 (fr) 2005-06-03 2006-05-17 Preparations cosmetiques contenant un extrait de fruits d'anis aqueux et un ou plusieurs polymeres d'acide acrylamidomethylpropylsulfonique

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005026003A DE102005026003A1 (de) 2005-06-03 2005-06-03 Kosmetische Zubereitungen mit einem Gehalt an einem wässrigen Anisfruchtextrakt und einem oder mehreren Acrylamidomethylpropylsulfonsäure-Polymeren
DE102005026003.9 2005-06-03

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Publication Number Publication Date
WO2006128583A1 true WO2006128583A1 (fr) 2006-12-07

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PCT/EP2006/004642 Ceased WO2006128583A1 (fr) 2005-06-03 2006-05-17 Preparations cosmetiques contenant un extrait de fruits d'anis aqueux et un ou plusieurs polymeres d'acide acrylamidomethylpropylsulfonique

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EP (1) EP1890774A1 (fr)
DE (1) DE102005026003A1 (fr)
WO (1) WO2006128583A1 (fr)

Cited By (1)

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