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WO1997028245A1 - Preparations d'agents nettoyants solides - Google Patents

Preparations d'agents nettoyants solides Download PDF

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Publication number
WO1997028245A1
WO1997028245A1 PCT/EP1997/000340 EP9700340W WO9728245A1 WO 1997028245 A1 WO1997028245 A1 WO 1997028245A1 EP 9700340 W EP9700340 W EP 9700340W WO 9728245 A1 WO9728245 A1 WO 9728245A1
Authority
WO
WIPO (PCT)
Prior art keywords
solid
sodium
weight
detergent preparation
preparation according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP1997/000340
Other languages
German (de)
English (en)
Inventor
Hans-Friedrich Kruse
Hans-Josef Beaujean
Dirk Gerst
Peter Jeschke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7784343&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1997028245(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to EP97902225A priority Critical patent/EP0885289B2/fr
Priority to AT97902225T priority patent/ATE201713T1/de
Priority to DE59703675T priority patent/DE59703675D1/de
Publication of WO1997028245A1 publication Critical patent/WO1997028245A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
    • C11D17/065—High-density particulate detergent compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to solid detergent preparations for automatic dishwashing and a process for their production.
  • typical cleaning agents can contain sodium citrate, citric acid, soda, sodium silicate, sodium hydrogen carbonate, sodium perborate, sodium percarbonate, bleach activators, surfactants and enzymes.
  • the dosage form of the powder mixture that is often offered in conventional cleaning agents has the disadvantage that it is often very dusty during manufacture and use.
  • powders tend to separate the individual components, which can have a negative effect on reproducible cleaning performance.
  • sticking and caking of the individual base bodies can often not be ruled out, which has a negative effect on the free-flowing properties of the cleaning agents and thus their metering capacity and their storage stability. So far, this can only be prevented by complex, often multi-stage, drying processes.
  • DE 39 26 253 discloses processes for the production of extrudates, in which a homogeneous, solid premix is extruded under pressure and the strand is cut to the predetermined pellet size after exiting the hole shape by means of a cutting device.
  • the homogeneous and solid premix contains a plasticizer and / or lubricant, which causes the premix to become plastically softened and extrudable under pressure or under the entry of specific work.
  • Preferred plasticizers and / or lubricants are surfactants and / or polymers, which are preferably used in liquid, pasty or gel-like preparation form.
  • the premix can also contain powders and / or granules, the granules being obtained, inter alia, by granulation processes or also by conventional spray drying processes. After exiting the hole shape, the system is no longer subjected to shear forces and the viscosity of the system increases in such a way that the extruded strand can be cut to predeterminable extrudate dimensions.
  • the disadvantages of the powder form are avoided here, but by the
  • Another object of the invention is to provide new, solid detergents for automatic dishwashing in the form of compacts which, with a high bulk density, can be offered as free-flowing products which do not tend to cake.
  • Another object of the invention is to propose a suitable manufacturing process for such products, which works with little or no water and manages with a minimum of drying processes.
  • "low water” means a quantity of water which, depending on the water absorption capacity of the feed materials, makes an additional drying step unnecessary.
  • the invention thus relates to a solid detergent preparation for machine dishwashing in the form of compacts in giant-shaped grain form, which are compressed to bulk densities of at least 700 g / l, containing solid ingredients which are at least partly of the class of builders, alkali carriers, oxygen bleaches and / or Bleach activators belong and continue to be at least partly liquid or plastically deformable substances (liquid phase) at temperatures above 30 ° C, which can belong to the class of surfactants, characterized in that the liquid phase contains at least one component below approx. 30 ° C in solid form a melting point of less than 60 ° C includes.
  • liquid phase liquid or plastically deformable substances
  • Another object of the invention is a process for the production of solid detergent preparations, characterized in that solid and liquid components are prepared into a homogeneous, compressible mass by mixing, this mass in the form of holes with hole widths of the predetermined compact dimension at temperatures above 30 ° C. ve ⁇ reßt, the emerging compacted material strands by means of a cutting device to the predetermined compact size, if desired, the resulting plastic particles are changed in shape and the additional component melting between 30 and 60 ° C solidifies by cooling. This can be done in an extruder, for example.
  • the component used in the products according to the invention with a melting point of between 30 and 60 ° C. is present as a liquid confectioning agent in the course of the processing process and her Solidification after the end of processing contributes to the solidification of the resulting compacts. It is crucial that this component, even if it is mixed with other liquid components, solidifies, ie at least partially crystallizes out. It is assumed that the still liquid portions of the cooled liquid phase are absorbed in the pore volume of the solids, whereas the hardened portions contribute to solidification.
  • the cleaning agents according to the invention contain the liquid phase in proportions of 5 to 20% by weight, particularly preferably in 10 to 15% by weight.
  • the liquid phase described can preferably contain one or more components which are selected from the group of paraffins, nonionic surfactants, fatty acid and / or fatty alcohol derivatives.
  • the liquid phase contains this component or the sum of these components preferably in amounts of 1 to 15% by weight, based on the entire preparation, in particularly preferred embodiments in 2 to 5% by weight.
  • the melting point of the component or of the components should preferably between 35 C and C are 45 ° C.
  • Further parts of the liquid phase can be selected in the sense of the application, for example from the group of surfactants.
  • Surfactants Alkyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-propyl-propyl-propyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-aminoethyl-N-(2-aminoethyl)-2-amino
  • nonionic surfactants selected from the group of ethoxylated fatty alcohols, alkyl polyglycosides and / or fatty acid glucamides is particularly preferred.
  • alkoxylated alcohols the reaction products of alkylene oxide, preferably ethylene oxide, with alcohols, preferred in the sense of the present invention, the longer-chain alcohols.
  • n moles of ethylene oxide and one mole of alcohol form a complex mixture of addition products of different degrees of ethoxylation, depending on the reaction conditions.
  • a further embodiment consists in the use of mixtures of the alkylene oxides, preferably the mixture of ethylene oxide and propylene oxide.
  • final etherification with short-chain alkyl groups such as preferably the butyl group, can also give the class of "closed" alcohol ethoxylates, which can also be used in the context of the invention. Highly ethoxylated fatty alcohols or their mixtures with end-capped fatty alcohol ethoxylates are very particularly preferred for the purposes of the present invention.
  • Alkyl polyglycosides are surfactants which can be obtained by the reaction of sugars and alcohols using the relevant methods of preparative organic chemistry, with a mixture of monoalkylated, oligomeric or polymeric sugars depending on the type of preparation.
  • Preferred alkyl polyglycosides can be alkyl polyglucosides, the alcohol being particularly preferably a long-chain fatty alcohol or a mixture of long-chain fatty alcohols and the degree of oligomerization of the sugars being between 1 and 10.
  • Fatty acid polyhydroxylamides are acylated reaction products of the reductive amination of a sugar (glucose) with ammonia, whereby long-chain fatty acids, long-chain fatty acid esters or long-chain fatty acid chlorides are generally used as acylating agents. Secondary amides are formed when reducing with methylamine or ethylamine instead of with ammonia, such as. B. in S ⁇ FW-Journal, 119, (1993), 794-808. Carbon chain lengths of C 6 to C 12 in the fatty acid residue are preferably used. In addition, further components can be used in the cleaning agent and the method described below, as will be illustrated below by way of example.
  • water-soluble and water-insoluble builders can be used especially for binding calcium and magnesium.
  • Water-soluble builders are preferred because they generally have less tendency to form insoluble residues on dishes and hard surfaces.
  • Customary builders which can be present in the scope of the invention between 10 and 90% by weight, based on the entire preparation, are the low molecular weight polycarboxylic acids and their salts, the homopolymeric and copolymeric polycarboxylic acids and their salts, the carbonates, phosphates and silicates.
  • Water-insoluble builders include the zeolites, which can also be used, as well as mixtures of the abovementioned builder substances. Trisodium citrate and / or pentasodium tripolyphosphate and silicate builders from the class of the disilicates are preferably used for the cleaning agents according to the invention.
  • Alkali carriers can be present as further constituents.
  • Alkali metal hydroxides, alkali metal carbonates, alkali metal hydrogen carbonates, alkali metal sesquicarbonates, alkali silicates, alkali metal silicates, and mixtures of the abovementioned substances are considered to be alkali carriers be used.
  • oxygen bleaches are Typical oxygen bleaching agents.
  • Typical oxygen bleaching agents are the alkali metal perborates and their hydrates and the alkali metal percarbonates, sodium perborate, as the mono- or tetrahydrate, or sodium percarbonate and whose hydrates are used in amounts of 2 to 12% by weight, based on the entire preparation.
  • Typical components of detergent preparations for machine dishwashing which can also be added subsequently in the form of a powder, granules or as a liquid, for technical reasons, are bleach activators, enzymes, perfume oils, corrosion protection agents and packaging aids.
  • bleach activators are compounds which contain one or more N- or O-acyl groups, such as substances from the class of anhydrides, esters, imides and acylated imidazoles or oximes. Examples are tetraacetylethylenediamine TAED, tetraacetyimethylenediamine TAMD and tetraacetylhexylenediamine TAHD, but also pentaacetylglucose PAG, 1,5-diacetyl-2,2-dioxo-hexahydro-1, 3,5-triazine DADHT and isatoic anhydride ISA. Bleach activator proportions of between 1 and 5% by weight, based on the preparation as a whole, have proven useful for the present invention.
  • enzymes between 0 and 5% by weight of enzymes, based on the entire preparation, can be added to the cleaning agent in order to increase the performance of the cleaning agents or to guarantee the same quality of cleaning performance under milder conditions.
  • the most commonly used enzymes include lipases, amylases, cellulases and proteases.
  • Preferred proteases are e.g. B. BLAP ⁇ 140 from Biozym, Optimase®-M-440 and Opticlean®-M-250 from Solvay Enzymes; Maxacal®CX and Maxapem® or Esperase® from Gist Brocades or Savinase® from Novo.
  • cellulases and lipases are Celluzym® 0.7 T and Lipolase® 30 T from Novo Nordisk.
  • Termamyl® 60 T and Termamyl® 90 T from Novo are particularly used as amylases, but other enzymes can also be used.
  • Dishwashing agents according to the invention can contain corrosion inhibitors to protect the washware or the machine, silver protection agents in particular being particularly important in the area of machine dishwashing, as described, for example, in B. are described in DE 43 25 922, DE 41 28 672 or DE 43 38 724.
  • detergent formulations often contain agents containing active chlorine, which can significantly reduce the corrosion of the silver surface.
  • agents containing active chlorine which can significantly reduce the corrosion of the silver surface.
  • oxygen and nitrogen-containing organic redox-active compounds such as di- and trihydric phenols, e.g. As hydroquinone, pyrocatechol, hydroxyhydroquinone, gallic acid, phloroglucin, pyrogallol or derivatives of these classes of compounds.
  • Salt-like and complex-like inorganic compounds such as salts of the metals Mn, Ti, Zr, Hf, V, Co and Ce, are also frequently used.
  • Zinc compounds can also be used to prevent corrosion on the wash ware.
  • detergents and cleaning agents are often taken from the group of perfume oils. They can also be contained in the detergent compositions according to the invention.
  • additives can be used for assembly, such as for example to powder off the residual moisture in some preparations, fine-grain reference fittings, which the person skilled in the art usually from the group of precipitated silicas, alkali metal carbonates (especially sodium carbonate), alkali metal bicarbonates (especially
  • Sodium bicarbonate which can select zeolites and similar suitable agents.
  • a preferred cleaning agent preparation according to the present invention thus contains, for example, 20 to 70% by weight sodium citrate, 2 to 10% by weight surfactants, 2 to 15% by weight soda, 10 to 50% by weight sodium bicarbonate, 2 up to 12% by weight sodium perborate, 0 to 30% by weight polycarboxylic acid in each case based on the entire preparation.
  • the extrusion system used in the method described below can be charged with material in various ways.
  • So z. B. all components to be extruded are fed in a premix, or mixed in the extruder itself, in which case the liquid components are preferably added through a separate nozzle.
  • the other active ingredients such as bleach activators, corrosion inhibitors for silver, enzymes and the like, can be admixed in granular form or as liquid or solid additives.
  • the mixture is plasticized by pressure build-up in front of the perforated disks, energy input by the screws and additional heating by the jacket heating of the extruder.
  • the detergent mass to be extruded is pressed at pressures above 50 bar.
  • the particularly preferred embodiment of the method works at pressures above 100 bar.
  • the temperature at which the mass plasticizes so that pressing through the perforated plate and cutting into cylindrical shaped bodies is possible without sticking is dependent on the formulation constituents and is preferably between 45 and 60 ° C., particularly preferably above of 50 ° C. In the extruder, care is taken to ensure that the throughput is as uniform as possible through all openings in the perforated disc, so that the strands can be cut uniformly by the rotating knives.
  • a preferred embodiment for spherical compacts is that the diameter of the strand of material corresponds approximately to the height of the particles.
  • the emerging plasticized strands it may be desirable to cool them at least superficially by shock cooling, in particular by means of cold air, before and / or during the cutting.
  • the still plastic bodies are then preferably reprocessed in a rounding machine customary on the market, the spherical parts then being able to be made up by powdering.
  • Finely divided reference fittings in particular precipitated silicas, sodium carbonate, sodium hydrogen carbonate, zeolites and the like are used.
  • drying steps can generally be dispensed with according to the invention. If, however, depending on the water absorption capacity of the feedstocks, residual liquid is still present, a drying step can also be carried out.
  • the amount of water is preferably below 5% by weight, particularly preferably below 3% by weight and very particularly preferably below 2% by weight. Such a small amount of water, which no longer requires an additional drying step, can be very useful in controlling the plasticity of the mixture. Therefore, in selected examples, if the plasticization is not controlled and changed by other known measures, a water content above 1% by weight is preferred.
  • the detergent preparations described below were processed in a twin-screw laboratory extruder from Leistritz.
  • alkylpolyglycoside (C. 8 10) (70%) 3.8
  • the continuously metered mixture of components was plasticized in the extruder by the energy input of the screws, optionally by additional jacket heating and by pressure build-up in front of the perforated disk.
  • the temperature at which the mass plasticizes so that pressing through the 1.6 mm holes in the perforated plate and cutting into cylindrical shaped bodies is possible without causing sticking was 54-58 ° C. in the present case.
  • the cylindrical shaped body with a The length / diameter ratio of 1: 1 was processed into spherical particles in a rounder available on the market. A free-flowing, non-caking product was obtained at normal temperature, which was mixed with components 9-11 to a finished product with a bulk density of 860 g / l.
  • Example 1 If the process is carried out with the components in this composition in such a way that the solids 1-4 and the liquid components 5-8 are each metered as a mixture into the extruder, then a finished product with the properties of Example 1 is also obtained after processing
  • the crude extrudate is produced by using a mixture of components 1-7 under the same conditions as in Example 1 and a processing temperature of 50-53 ° C. after rounding with powdering with Component 10 and residual mixing with components 8 and 9 gave a readily flowable finished product with a bulk density of 920 g / l.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une préparation d'agents nettoyants solides pour lavage de vaisselle en machine, se présentant sous forme de comprimés dans une structure granuleuse coulante d'une masse volumique apparente d'au moins 700 g/l. Ces préparations peuvent être produites avec peu d'eau ou sans eau, avec un minimum de processus de séchage. A cet effet, on utilise des constituants solides appartenant au moins en partie à la catégorie des adjuvants, des supports alcalins, des agents de blanchiment oxygénés et/ou des activateurs de blanchiment, conjointement avec des substances au moins en partie liquides ou à déformation plastique (phase liquide) à des températures supérieures à 30 °C. La phase liquide contient au moins un constituant additionnel présent sous forme solide à des températures inférieures à approximativement 30 °C et ayant un point de fusion inférieur à 60 °C. L'invention concerne en outre un procédé de production de préparations d'agents nettoyants selon lequel les constituants sous forme de mélange homogène compressible de manière à leur conférer une forme, sont extrudés à une température supérieure à 30 °C, puis découpés aux dimensions prédéterminées des comprimés et éventuellement modifiés dans leur forme. Les constituants additionnels de la phase liquide sont durcis par refroidissement.
PCT/EP1997/000340 1996-02-02 1997-01-25 Preparations d'agents nettoyants solides Ceased WO1997028245A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP97902225A EP0885289B2 (fr) 1996-02-02 1997-01-25 Preparations d'agents nettoyants solides et procede pour leur obtention
AT97902225T ATE201713T1 (de) 1996-02-02 1997-01-25 Feste reinigungsmittelzubereitungen
DE59703675T DE59703675D1 (de) 1996-02-02 1997-01-25 Feste reinigungsmittelzubereitungen

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19603760A DE19603760A1 (de) 1996-02-02 1996-02-02 Feste Reinigungsmittelzubereitungen
DE19603760.3 1996-02-02

Publications (1)

Publication Number Publication Date
WO1997028245A1 true WO1997028245A1 (fr) 1997-08-07

Family

ID=7784343

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1997/000340 Ceased WO1997028245A1 (fr) 1996-02-02 1997-01-25 Preparations d'agents nettoyants solides

Country Status (6)

Country Link
EP (1) EP0885289B2 (fr)
AT (1) ATE201713T1 (fr)
DE (2) DE19603760A1 (fr)
ES (1) ES2158487T5 (fr)
PT (1) PT885289E (fr)
WO (1) WO1997028245A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9228157B2 (en) 2009-04-24 2016-01-05 Conopco, Inc. Manufacture of high active detergent particles

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10002009A1 (de) * 2000-01-19 2001-07-26 Cognis Deutschland Gmbh Tensidgranulate
DE10015289A1 (de) * 2000-03-28 2001-10-18 Henkel Kgaa Teilchenförmige maschinelle Geschirrspülmittel mit Klarspüleffekt
US7226899B2 (en) 2003-12-23 2007-06-05 Kimberly - Clark Worldwide, Inc. Fibrous matrix of synthetic detergents
DE102009029637A1 (de) * 2009-09-21 2011-03-24 Henkel Ag & Co. Kgaa Maschinelles Geschirrspülmittel

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2714093A (en) * 1952-07-02 1955-07-26 Blumenthal Armin Method of preparing detergent compositions
US4087369A (en) * 1976-11-08 1978-05-02 The Procter & Gamble Company Peroxybleach activated detergent composition
EP0364881A2 (fr) * 1988-10-21 1990-04-25 Henkel Kommanditgesellschaft auf Aktien Préparation de granulés contenant des agents tensio-actifs
EP0534525A2 (fr) * 1991-09-27 1993-03-31 Unilever N.V. Poudres détergentes et leur procédé de préparation
DE4232170A1 (de) * 1992-09-25 1994-03-31 Henkel Kgaa Schwachalkalische Geschirreinigungsmittel
DE4233696A1 (de) * 1992-10-07 1994-04-14 Henkel Kgaa Maschinenpflegestift
EP0643130A1 (fr) * 1993-09-13 1995-03-15 The Procter & Gamble Company Composition détergentes granulaires contenant un tensio-actif non-ionique et procédé de sa préparation
WO1996023048A1 (fr) * 1995-01-26 1996-08-01 The Procter & Gamble Company Procede de fabrication des compositions detergentes granulaires contenant des tensioactifs non-ioniques

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4100097A (en) † 1977-02-02 1978-07-11 The Hewitt Soap Company, Inc. Low pH detergent bar
DE59006160D1 (de) † 1989-08-09 1994-07-21 Henkel Kgaa Herstellung verdichteter granulate für waschmittel.
GB9021761D0 (en) † 1990-10-06 1990-11-21 Procter & Gamble Detergent compositions
US5300249A (en) † 1991-09-23 1994-04-05 The Procter & Gamble Company Mild personal cleansing bar composition with balanced surfactants, fatty acids, and paraffin wax

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2714093A (en) * 1952-07-02 1955-07-26 Blumenthal Armin Method of preparing detergent compositions
US4087369A (en) * 1976-11-08 1978-05-02 The Procter & Gamble Company Peroxybleach activated detergent composition
EP0364881A2 (fr) * 1988-10-21 1990-04-25 Henkel Kommanditgesellschaft auf Aktien Préparation de granulés contenant des agents tensio-actifs
EP0534525A2 (fr) * 1991-09-27 1993-03-31 Unilever N.V. Poudres détergentes et leur procédé de préparation
DE4232170A1 (de) * 1992-09-25 1994-03-31 Henkel Kgaa Schwachalkalische Geschirreinigungsmittel
DE4233696A1 (de) * 1992-10-07 1994-04-14 Henkel Kgaa Maschinenpflegestift
EP0643130A1 (fr) * 1993-09-13 1995-03-15 The Procter & Gamble Company Composition détergentes granulaires contenant un tensio-actif non-ionique et procédé de sa préparation
WO1996023048A1 (fr) * 1995-01-26 1996-08-01 The Procter & Gamble Company Procede de fabrication des compositions detergentes granulaires contenant des tensioactifs non-ioniques

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9228157B2 (en) 2009-04-24 2016-01-05 Conopco, Inc. Manufacture of high active detergent particles

Also Published As

Publication number Publication date
ATE201713T1 (de) 2001-06-15
EP0885289A1 (fr) 1998-12-23
PT885289E (pt) 2001-11-30
EP0885289B1 (fr) 2001-05-30
DE19603760A1 (de) 1997-08-07
EP0885289B2 (fr) 2005-06-08
ES2158487T5 (es) 2005-12-01
ES2158487T3 (es) 2001-09-01
DE59703675D1 (de) 2001-07-05

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