WO1992013624A1 - Procede et installation pour la separation de melanges liquide-solide - Google Patents
Procede et installation pour la separation de melanges liquide-solide Download PDFInfo
- Publication number
- WO1992013624A1 WO1992013624A1 PCT/AT1992/000010 AT9200010W WO9213624A1 WO 1992013624 A1 WO1992013624 A1 WO 1992013624A1 AT 9200010 W AT9200010 W AT 9200010W WO 9213624 A1 WO9213624 A1 WO 9213624A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- pressing
- filter
- trough
- pressure
- press
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D25/00—Filters formed by clamping together several filtering elements or parts of such elements
- B01D25/12—Filter presses, i.e. of the plate or plate and frame type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D25/00—Filters formed by clamping together several filtering elements or parts of such elements
- B01D25/30—Feeding devices ; Discharge devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D25/00—Filters formed by clamping together several filtering elements or parts of such elements
- B01D25/32—Removal of the filter cakes
- B01D25/38—Removal of the filter cakes by moving parts, e.g. scrapers, contacting stationary filter elements sprayers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D25/00—Filters formed by clamping together several filtering elements or parts of such elements
- B01D25/32—Removal of the filter cakes
- B01D25/38—Removal of the filter cakes by moving parts, e.g. scrapers, contacting stationary filter elements sprayers
- B01D25/386—Nozzles
Definitions
- the chemical conditioning ie the addition of lime-iron chloride enables press cake thickness ⁇ up to 40 mm, as long as the pressing is carried out with a filter arranged on both sides of the press cake and gives, for example in the case of municipal sludges, dry matter contents of up to a maximum of 40 to 45%; this conditioning is mainly used in chamber filter presses.
- a disadvantage is the increase in the presscake volume caused by the addition of lime by about 30%, as a result of which the actual dry matter content is considerably reduced with regard to the solids to be filtered out.
- the above-mentioned restrictions do not apply to fiber-containing sludges from, for example, paper mill sewage treatment plants or other easily dewatered industrial sludges.
- Paper mill sludges in particular are polymer-conditioned in membrane cylinder presses to over 60% To drain dry matter without any problems.
- the squeezing out of these fiber-containing sludges is, however, not to be compared with the squeezing out of the sludges, the squeezing of which is to be improved according to the invention, since special precautions have to be taken in terms of construction and process technology, since initially the liquid is rather light and extremely difficult to press on is squeezable.
- the aim of the present invention is to create a method or a separation device with which sludge which is difficult to dewater, such as municipal sludge and / or sludge from sewage treatment plants, can be separated to a large extent, so that dry matter contents of at least 40% , in particular of at least 50% and more can be achieved, even if these sludges have been aerobically stabilized.
- Such aerobically stabilized sludges are extremely difficult to etch to dry matter contents of more than 30% with the conventional methods.
- the aim of the invention is therefore to design a method of the type mentioned in the introduction such that both liquid-solid mixtures which are easy to squeeze out and mixtures or slurries, slurries, etc.
- a method of the type mentioned at the outset is characterized by the features stated in the characterizing part of patent claim 1.
- a Tre ⁇ n driving invention is characterized by the features stated in the characterizing part of claim 13. The invention is based on the idea of parallel and at a predetermined maximum distance in a pressing space delimited by a generally closed trough, which is divided into a plurality of non-dense or at least below and optionally also laterally and above open pressing volumes.
- the inlet container is separated from the press rooms by a slide.
- the surface of the lamellar filler has dimensions which are in the essential to that of Press chamber or the trough or their clear width correspond when the slide is closed, so that when pressing out, ie moving the plate filter in the direction of reducing the partial volumes in the direction of the longitudinal axis of the press chamber, the lamella filters with their edges on all sides on the boundary surfaces almost brush the trough or housing or baling chamber or get as close as possible to it; a seal between the peripheral surfaces or edges of the lamella filter and the housing interior is not provided; the contact between the lamella filters and the trough wall or the slide is seal-free.
- the pressing process itself is brought about by the fact that the pressing space is reduced in the longitudinal direction, that is to say in a direction perpendicular to the surface of the filter plates, as a result of which the filled mixture between the filter plates is pressed out.
- the internal friction angle of the press cake increases relatively rapidly due to the small filling thickness or the small distance between the filter plates, and a loss of liquid, so that only in the initial phase of the squeezing process with a low pressing pressure squeezing out of the mixture, ie the liquid together with solids occurs at the edges of the lamella filter.
- the trough can be folded away sideways or moved laterally or in the longitudinal direction, so that the space under the lamella filters is completely released. Subsequently, the lamella filters are then moved back into their original position, which movement or position by means of a limiting device attached to the individual lamella filters, e.g. Chain links or the like is limited or specified.
- a limiting device attached to the individual lamella filters e.g. Chain links or the like is limited or specified.
- a scraping device, a detaching device in the form of compressed air lances or the like which can be moved into the press rooms can be used. be provided.
- the pressing pressure exerted in the course of the volume reduction in a first squeezing step is kept essentially at a constant value and is increased to an E ⁇ d value in a subsequent squeezing step which further reduces the volume. It is advantageous to proceed according to the features of claims 9 and 10, respectively. In this way, a relatively large reduction in volume is achieved in the course of the first squeezing step, so that a correspondingly long-stroke drive unit for the pressing device has to be provided, which, however, does not have to exert particularly large forces.
- This desired linear volume restriction in the second pressing step or the desired final pressure can alternatively also be achieved in a single pressing step in which the pressure profile can preferably be made to increase steadily.
- the drive unit or the pressing device is constructed in two or more stages, since the pressing pressure rises significantly in the second pressing step or towards the end of the pressing and thus considerably greater pressing forces are required, albeit over a smaller distance. Further advantageous embodiments of the invention can be found in the following description, the drawings and the claims.
- FIG. 1 shows purely schematically a separating device according to the invention
- FIG. 2 schematically shows a view of an embodiment of a separating device according to the invention
- FIGS. 3 and 4 different working positions
- FIG. 5 schematically shows the emptying
- FIG. 6 and 6a show detailed views of filter plates
- FIG.7 the mutual connection fertilization of filter plates and the stripping of filter cakes
- FIG. 9 schematically shows a separating device for filter cakes adhering to the filter plates and a connecting device.
- Fig.l shows schematically an embodiment of a separating device according to the invention.
- This Trennei ⁇ cardi comprises an elongated housing formed by sheet metal walls or a trough 8, with front, back and side walls 51, which are indicated by dashed lines in the drawing; the trough 8 is closed at the bottom with a tiltable trough 11; the upper cover surface of the housing can be formed by a slide 18. Furthermore, an end plate 4 and a pressure plate 2 are arranged on or in the trough 8 or integrated therein; outside or in the housing also run, at most integrally with the front and rear walls, longitudinal members or guide members 1, which are connected to the end plate 4 at one end of the trough 8 and the other end to an abutment 5 for applying the pressing pressure, on which a press unit 6 is supported.
- the pressing unit 6, which is arranged between the abutment 5 and the pressure plate 2, acts on the pressure plate 2 for an adjustment movement in the direction of the end plate 4.
- the pressing space 30 lying between the end plate 4 and the pressure plate 2 is made up of a large number of pressing spaces located between filter plates 3 22 subdivided, which partial volumes 22 represent the pressing space 30 and are reduced in the course of the pressing process.
- a feed container 7 and / or a number of feed channels 7 opens into the press chamber 30, which, if applicable, with respect to the press chamber 30 by means of the slide 18 or other shut-off devices can be lockable.
- the closure is usually done after filling the press chamber 30, but can also be omitted.
- the tub 11 is tightly connected to the trough walls via possibly inflatable seals 41.
- a filter 25 runs essentially horizontally in the trough 11, which lies directly on the undersides of the filter plate 3 or is arranged at a distance from the latter; furthermore, the tub 11 carries an outlet 26 'for filtrate 16 and an outlet 24 for liquid-solid mixtures which emerge from the press rooms 22 when pressed and from a rinsing device 27 which is carried by the tub and / or the housing (FIG .3), can be rinsed off.
- the housing or the trough 8 or the filter 25 in the trough 11 or the slide 18 lie closely against the edges of the filter plates 3, but without the use of seals, which results in the advantage that the housing or the trough 8 does not have to be designed to be pressure-resistant and only has to withstand the filling pressure or the pressure of the first pressing step. If not only the filtrate but also the mixture escapes due to an increase in the pressing pressure, this can escape onto or through the filter plate 25 into the trough 11, so that a large pressure build-up in the pressing chamber 30, which would burden the housing walls 8, is avoided.
- FIG. 3 shows the separating device according to the invention in the course of its first working step, in the course of which, when the tub 11 is closed or slightly tilted, solid / liquid mixture escaping by means of the flushing device 27 can be flushed out into a line 51, which
- Line 51 is at most recirculated into the import container 7, to squeeze this mixture out again. It can be seen that the
- the recesses 24 serve to receive the sprayed mixture which emerges in the first squeezing step and to convey it into the recirculation line 51 to the filling container 7.
- the space 26 below the filter 25 is guided to an outlet 26 'from which the filtrate 16 is discharged or one Sewage treatment plant for further supply is supplied.
- Chains or ropes 48 extending through the opening direction can be used, on each of which the filter plates 3, e.g. by clamping screws 49 or the like. are set.
- the ends of the cables 48 are connected to the end plate 4 or the pressure plate 2 (FIG. 9).
- edges of the filter plate, or the filter plate itself are always spaced apart from one another during the pressing operation and are open at least over a circumferential surface, preferably over their entire circumferential surface.
- An alternative to separating the filter cake 19 from the filter surfaces 31 can be to insert a blowing lance 21 between two filter plates 3 moved back into their starting position into the upper region of the respective pressing chamber 22, the nozzles 32 of which are adjacent to the Surfaces 31 of the filter plates 3 are arranged and which release the filter cake 19 with the jet pressure and allow it to exit downwards.
- a piston 9 can be arranged, which forces the press chamber 30 to be loaded and thus presses the mixture to a certain extent when the filter plate 3 is stationary in the starting position.
- the piston 9 carries a check valve 23 which prevents the mixture filled in the pressing chamber 30 from passing upwards.
- the filter material 13 applied to the filter plates 3 can consist of plastic and / or metal mesh; the filter plates 3 can consist of plastic, cast metal or profiled steel sheets.
- the embodiment according to FIG. 8 a is advantageously produced from plastic plate, which are provided with the longitudinal channels 33 by means of corresponding processing methods.
- the filter plates 3 can have any type of profiled or perforated surface; it is only necessary that the filtrate penetrating through the filter material 13 can flow between the filter material 13 and the filter plate 3 or in the filter plate 3. Discharge channels 33 which run obliquely or horizontally are also possible.
- Opening devices according to the invention can have a length of several meters; their cross-sectional dimensions are e.g. 100 x 100 cm. It is advantageously provided that the pressure in the course of the first pressing step is set to a value of 0.5 to 6 bar, preferably 1 to 5 bar, in particular 2 to 4 bar, and that the final value of the pressing pressure in the second pressing step is set to at least 10 bar , in particular to 20 to 50 bar or higher.
- the course of the pressure in the course of the first pressing step is kept essentially constant and also results from the fact that along the relatively long pressing path there is due to the large liquid portion of the mixture used and the large areas available for the filtrate outlet and the thinness of the pressing rooms the pressure does not increase, but rather shows a tendency to remain the same despite narrowing the partial volumes.
- the pressure does not increase, but rather shows a tendency to remain the same despite narrowing the partial volumes.
- by forming only thin press cakes clogging of the cakes is avoided or the efficiency of the separation process is ensured due to the large number of cakes to be pressed.
- the pressure rise in this second squeezing step takes place either linearly, stepwise or more steeply than linearly, until the predetermined final value is reached, which can be maintained over a predetermined period of time.
- the tub 11 is also rinsed just before the start of the second squeezing step, that is to say the leaked mixture is removed through the recirculation line 51 in order to be able to dispose of the pure filtrate 16. A very clean separation of the mixture is achieved in this way.
- the number of filter plates 3 provided in a separating device can be 160 to 200 pieces with a length of, for example, 8 m, depending on the selected maximum distance in the starting position of the filter plates 3.
- a major advantage of the press is that only small pressures have to be applied in the course of the first pressing process, but this over long ways; Such drive devices are relatively easy to create; High-pressure devices are complex, which only have to be used in the second pressing step over short distances.
- the separation can also take place in only one pressing step.
- the number of guides provided for or on the filter plates 3 can be selected as desired;
- the guides are advantageously arranged on the lateral vertical surfaces or edges of the filter plates 3.
- the trough 8 is formed by a concrete wall, in particular a metal concrete wall, which can be too open at the bottom or can be provided with filters 67 which can be tilted or swiveled or pushed sideways.
- the concrete casing or the concrete trough 8 forms the abutment for the pressing devices 6 arranged on both sides in the trough, which act on a number of filter plates 3 via corresponding pressure plates 2.
- a central plate 64 which is anchored stably in the trough 8 and against which the filter plates 3 can be pressed, as a result of which the pressure distribution in the press volume is equalized.
- the press volume is delimited by side walls 66, which at most have filter wall sections or can be formed by filter walls, so that a filtrate filter came out easily and easily to the side.
- the side walls 66 can be placed laterally with hydraulic cylinders on the filter plates 3 and removed for the execution of the second pressing step or for the application of the filter cake.
- the filter plates 3 can also be covered or closed at the top by means of a slide 68. It is also possible to arrange a lowerable filter 25 in a lowerable trough in the lower region of the trough 8 formed by a concrete trough, with hydraulic devices possibly being provided for the lowering; the lower cover of the separating device could also be moved to the side.
- 63 scraping blades 62 are each arranged via spring bars 11b shows, laterally in the area of the movable arrangement 61, a guide 74 that can be inserted into the press volumes is pivotally mounted about a pivot point 75, which can be inserted with its tapered end 76 into the press volumes or into its upper end, as in FIG Fig. 11b is shown successively: As soon as the guide 74 has achieved a firm fit, the Guide 74, the blades 62 of the scraper blades are lowered and scrape the filter cake 19 from the filter surfaces of the filter plates 3.
- FIG. 12 shows a section through a trough 8, which has an inlet channel 7 in its upper region, which extends over a number of pressing volumes in the longitudinal direction of the trough 8 and can be shut off by means of a slide 18.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Filtration Of Liquid (AREA)
Abstract
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS931544A CZ154493A3 (en) | 1991-02-01 | 1992-01-29 | Method of separating mixture of liquids and solid substances, and apparatus for making the same |
| JP4503849A JPH06506141A (ja) | 1991-02-01 | 1992-01-29 | 液体分と固体分との混合体を分離するための方法並びに装置 |
| SK827-93A SK82793A3 (en) | 1991-02-01 | 1992-01-29 | Method and device for separating liquid/solid mixtures |
| CA002101732A CA2101732A1 (fr) | 1991-02-01 | 1992-01-29 | Methode et dispositif de separation de melanges liquide-solide |
| AU12007/92A AU656169B2 (en) | 1991-02-01 | 1992-01-29 | Method and device for separating liquid/solid mixtures |
| BR9205579A BR9205579A (pt) | 1991-02-01 | 1992-01-29 | Processo e equipamento para a separação de misturas de líquido e material sólido |
| NO93932735A NO932735L (no) | 1991-02-01 | 1993-07-29 | Fremgangsmaate og innretning for separering av vaeske-faststoff-blandinger |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ATA225/91 | 1991-02-01 | ||
| AT0022591A AT396923B (de) | 1991-02-01 | 1991-02-01 | Verfahren und trenneinrichtung zum auftrennen bzw. entwässern von flüssigkeit-feststoff-gemischen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1992013624A1 true WO1992013624A1 (fr) | 1992-08-20 |
Family
ID=3484865
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/AT1992/000010 Ceased WO1992013624A1 (fr) | 1991-02-01 | 1992-01-29 | Procede et installation pour la separation de melanges liquide-solide |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0569459A1 (fr) |
| JP (1) | JPH06506141A (fr) |
| AT (1) | AT396923B (fr) |
| AU (1) | AU656169B2 (fr) |
| BR (1) | BR9205579A (fr) |
| CA (1) | CA2101732A1 (fr) |
| CZ (1) | CZ154493A3 (fr) |
| HU (1) | HUT67819A (fr) |
| SK (1) | SK82793A3 (fr) |
| WO (1) | WO1992013624A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4425755C1 (de) * | 1994-07-21 | 1995-09-14 | Netzsch Erich Holding | Vorrichtung zum Ableiten von Filtrat unterhalb einer Filterpresse |
| EP0860188A1 (fr) * | 1997-02-22 | 1998-08-26 | Erich Netzsch GmbH & Co. Holding KG | Filtre-presse |
| CN112757680A (zh) * | 2019-11-01 | 2021-05-07 | 王树岩 | 一种餐厨垃圾接料挤压一体机 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1314040A (fr) * | 1960-12-12 | 1963-01-04 | Almasfuezitoi Timfoldgyar | Filtre-presse et procédé pour séparer des matières solides d'avec des liquides, en particulier pour la filtration de liqueurs troubles et de liqueurs analogues |
| DE1190315B (de) * | 1962-11-24 | 1965-04-01 | Heidenau Maschf Veb | Hydraulische Topfpresse zum Entoelen von Kakaomasse |
| FR2095091A5 (fr) * | 1970-10-13 | 1972-02-04 | Ind Filter Pump | |
| US4519903A (en) * | 1983-01-24 | 1985-05-28 | Johnson Willard L | Filter machine |
| GB2176417A (en) * | 1985-06-05 | 1986-12-31 | Seitz Enzinger Noll Masch | Filter press |
| EP0276355A1 (fr) * | 1987-01-29 | 1988-08-03 | Lenser Kunststoff-Presswerk GmbH & Co. KG | Filtre-presse avec un nombre de plaques de filtration à membrane |
| WO1989004204A1 (fr) * | 1987-11-13 | 1989-05-18 | Larox Oy | Procede pour le nettoyage de la toile d'un filtre-presse, et filtre-presse permettant la mise en oeuvre du procede |
| EP0318732A2 (fr) * | 1987-11-28 | 1989-06-07 | Klöckner-Humboldt-Deutz Aktiengesellschaft | Dispositif pour exprimer les liquides d'un produit en vrac et/ou à faculté d'écoulement |
| EP0337218A2 (fr) * | 1988-04-14 | 1989-10-18 | Hoppe + Partner | Procédé et dispositif de déshydratation de la boue |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2813236A1 (de) * | 1978-03-28 | 1979-10-11 | Rittershaus & Blecher Gmbh | Filterpresse mit einer abspritzeinrichtung |
| US4222873A (en) * | 1978-08-23 | 1980-09-16 | Exxon Research & Engineering Co. | Plate and frame filter press having modified flow pattern method |
| AT376642B (de) * | 1979-07-31 | 1984-12-10 | Oestreicher Friedrich Ing | Einrichtung zum entwaessern und transport von schlaemmen od. dgl. massen |
| GB2159724A (en) * | 1984-06-08 | 1985-12-11 | Johnson Progress Ltd | Filter press |
| AU584461B2 (en) * | 1985-09-06 | 1989-05-25 | Kurita Machinery Manufacturing Co., Limited | Filter press |
| SE453726B (sv) * | 1986-07-10 | 1988-02-29 | Sala International Ab | Forfarande och anordning vid pressfilter |
| DE3636799A1 (de) * | 1986-10-29 | 1988-05-05 | Rittershaus & Blecher Gmbh | Verfahren zur regelung des filterplatten-anlagedruckes bei filterpressen und vorrichtung zur durchfuehrung des verfahrens |
-
1991
- 1991-02-01 AT AT0022591A patent/AT396923B/de not_active IP Right Cessation
-
1992
- 1992-01-29 AU AU12007/92A patent/AU656169B2/en not_active Ceased
- 1992-01-29 SK SK827-93A patent/SK82793A3/sk unknown
- 1992-01-29 HU HU9302184A patent/HUT67819A/hu unknown
- 1992-01-29 CA CA002101732A patent/CA2101732A1/fr not_active Abandoned
- 1992-01-29 JP JP4503849A patent/JPH06506141A/ja active Pending
- 1992-01-29 BR BR9205579A patent/BR9205579A/pt unknown
- 1992-01-29 WO PCT/AT1992/000010 patent/WO1992013624A1/fr not_active Ceased
- 1992-01-29 EP EP92904360A patent/EP0569459A1/fr not_active Ceased
- 1992-01-29 CZ CS931544A patent/CZ154493A3/cs unknown
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1314040A (fr) * | 1960-12-12 | 1963-01-04 | Almasfuezitoi Timfoldgyar | Filtre-presse et procédé pour séparer des matières solides d'avec des liquides, en particulier pour la filtration de liqueurs troubles et de liqueurs analogues |
| DE1190315B (de) * | 1962-11-24 | 1965-04-01 | Heidenau Maschf Veb | Hydraulische Topfpresse zum Entoelen von Kakaomasse |
| FR2095091A5 (fr) * | 1970-10-13 | 1972-02-04 | Ind Filter Pump | |
| US4519903A (en) * | 1983-01-24 | 1985-05-28 | Johnson Willard L | Filter machine |
| GB2176417A (en) * | 1985-06-05 | 1986-12-31 | Seitz Enzinger Noll Masch | Filter press |
| EP0276355A1 (fr) * | 1987-01-29 | 1988-08-03 | Lenser Kunststoff-Presswerk GmbH & Co. KG | Filtre-presse avec un nombre de plaques de filtration à membrane |
| WO1989004204A1 (fr) * | 1987-11-13 | 1989-05-18 | Larox Oy | Procede pour le nettoyage de la toile d'un filtre-presse, et filtre-presse permettant la mise en oeuvre du procede |
| EP0318732A2 (fr) * | 1987-11-28 | 1989-06-07 | Klöckner-Humboldt-Deutz Aktiengesellschaft | Dispositif pour exprimer les liquides d'un produit en vrac et/ou à faculté d'écoulement |
| EP0337218A2 (fr) * | 1988-04-14 | 1989-10-18 | Hoppe + Partner | Procédé et dispositif de déshydratation de la boue |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4425755C1 (de) * | 1994-07-21 | 1995-09-14 | Netzsch Erich Holding | Vorrichtung zum Ableiten von Filtrat unterhalb einer Filterpresse |
| EP0860188A1 (fr) * | 1997-02-22 | 1998-08-26 | Erich Netzsch GmbH & Co. Holding KG | Filtre-presse |
| CN112757680A (zh) * | 2019-11-01 | 2021-05-07 | 王树岩 | 一种餐厨垃圾接料挤压一体机 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0569459A1 (fr) | 1993-11-18 |
| ATA22591A (de) | 1993-05-15 |
| CA2101732A1 (fr) | 1992-08-02 |
| AU656169B2 (en) | 1995-01-27 |
| SK82793A3 (en) | 1994-01-12 |
| AU1200792A (en) | 1992-09-07 |
| AT396923B (de) | 1993-12-27 |
| JPH06506141A (ja) | 1994-07-14 |
| HUT67819A (en) | 1995-05-29 |
| HU9302184D0 (en) | 1993-10-28 |
| BR9205579A (pt) | 1994-10-11 |
| CZ154493A3 (en) | 1994-03-16 |
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