USRE2308E - Improvement in plating, tempering - Google Patents
Improvement in plating, tempering Download PDFInfo
- Publication number
- USRE2308E USRE2308E US RE2308 E USRE2308 E US RE2308E
- Authority
- US
- United States
- Prior art keywords
- steel
- plating
- bath
- tempering
- iron
- Prior art date
Links
- 238000007747 plating Methods 0.000 title description 18
- 238000005496 tempering Methods 0.000 title description 8
- 229910000831 Steel Inorganic materials 0.000 description 40
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 40
- 239000010959 steel Substances 0.000 description 40
- 229910052742 iron Inorganic materials 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 16
- 239000002184 metal Substances 0.000 description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 14
- 229910052709 silver Inorganic materials 0.000 description 14
- 239000004332 silver Substances 0.000 description 14
- 239000011780 sodium chloride Substances 0.000 description 10
- NNFCIKHAZHQZJG-UHFFFAOYSA-N Potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000000110 cooling liquid Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000012047 saturated solution Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Definitions
- Such invention is an improved method of obtaining the first film or deposit upon the surface of the iron or steel of the metal desired, as silver, copper, gold, 850., and an improved method of heating iron and steel, and of preserving them from oxidation.
- the surface of the steel is first polished, but care is not required to remove the grease or to avoid touching the polished surface with the fingers.
- a crucible or other suitable vessel is then made ready, adapted to the size of the steel and containing melted cyanide of potassium of the temperature of say 500 or 600 Fahrenheit.
- the steel is then to be plunged into this and allowed to remain uutilit hasacquired the temperature of the bath. It is then, while hot, removed to a bath containing a nearly saturated solution of cyanide of potassium in water, to which is added a salt of silver --as the chloride of silver-sufficient to make a strength of about 10 Baum.
- the steel may be removed from this latter bath as soon as it is cool, and will be found to be perfectly coated with a film of silver without spots or discolorations. The further deposit of silver is to be effected in theordinary manner.
- the steel when taken from the bath of melted cyanide, will have enough of that substance adhering to it to preserve it from the action of the oxygen of the atmosphere while being removed to the cooling bath. While it isinthat bath theadhering portion of the melted cyanide will be dissolved 011' by the solution, and, as the steel is hot, the first particles of silver deposited penetrate the pores of the steel, forming at the surface an actual alloy, and hence the plating will not peel ofi'.
- haloid salts of the metals are preferable for the cooling-bath, as those contain no acids; but the oxy-salts may be employed if 'the acid be neutralized.
Description
UNITED STATES THE AMEEIcAN METAL COMPANY, or WEST MERIDEN, CONNECTICUT,
ASSIGNEES, BY MESNE ASSIGNMENTS, or ELLIOT SAVAGE.
IMPROVEMENT IN PLATING, TEMPERING, AND HARDENING IRON AND STEEL.
Specification forming part of Letters Patent No. 51,754, dated December 26, 1865; Reissue No. 2,308, dated J nly 10, 1866.
To all whom it may concern:
Be it known that I, ELLIOT SAVAGE, of West Meriden, New Haven county, Connecticut, have invented certain new and useful improvements in plating upon iron and steel and in treating iron and steel for hardening and tempering them, and for other purposes; and I do hereby declare that the following is a full, clear, and exact description of the same.
Such invention is an improved method of obtaining the first film or deposit upon the surface of the iron or steel of the metal desired, as silver, copper, gold, 850., and an improved method of heating iron and steel, and of preserving them from oxidation.
Hitherto,in plating upon iron or steel ithas been found necessaryto polish the surface of the iron or steel, then to wash it well with alkaliesin order to remove all traces of grease or oil, and finally finish with a brush, carefully avoiding even the touch of the fingers upon the polished surface. This is then properly introduced into a galvanic bath havinga powerful battery. In a short time it can be taken out, there being then a film of metal deposited upon it. If, however, the cleaning was not perfect there will be spots or discolorations upon the deposit, and these are apt to appear on the finished article afterit has received the thicker plating in the subsequent weak battery. Sometimes, too, the plating can be readily peeled off.
The following is a description of the manner of carrying out my improvement as applied to the plating of steel with silver: The surface of the steel is first polished, but care is not required to remove the grease or to avoid touching the polished surface with the fingers. A crucible or other suitable vessel is then made ready, adapted to the size of the steel and containing melted cyanide of potassium of the temperature of say 500 or 600 Fahrenheit. The steel is then to be plunged into this and allowed to remain uutilit hasacquired the temperature of the bath. It is then, while hot, removed to a bath containing a nearly saturated solution of cyanide of potassium in water, to which is added a salt of silver --as the chloride of silver-sufficient to make a strength of about 10 Baum. The steel may be removed from this latter bath as soon as it is cool, and will be found to be perfectly coated with a film of silver without spots or discolorations. The further deposit of silver is to be effected in theordinary manner.
I n the aforesaid process the steel, when taken from the bath of melted cyanide, will have enough of that substance adhering to it to preserve it from the action of the oxygen of the atmosphere while being removed to the cooling bath. While it isinthat bath theadhering portion of the melted cyanide will be dissolved 011' by the solution, and, as the steel is hot, the first particles of silver deposited penetrate the pores of the steel, forming at the surface an actual alloy, and hence the plating will not peel ofi'.
If it is desired to harden the steel as well as -to plate it, this will be effected by raising the temperature of the melted cyanide before the steel is plunged into it to the desired point. A temperature of, say, 800 Fahrenheit, will give a great degree of hardness when the steel is afterward plunged into the cooling-bath above described.
It will be obvious that other metals may also be plated upon steel or iron, it being only necessary to substitute for the salt of silver in the cooling-bath a salt of the metal to be deposited.
The haloid salts of the metals are preferable for the cooling-bath, as those contain no acids; but the oxy-salts may be employed if 'the acid be neutralized.
What I claim as my invention in plating upon iron and steel, and in treating iron and steel for hardening and tempering them, and for other purposes is 1. Heating the metal by immersing it in a bath of melted cyanide of potassium, substantially as described.
2. Cooling the metal by immersing it in a cooling-liquid, substantially as described, after it has been heat-ed in a bath of melted cyanide of potassium, substantially as described.
. ELLIOT SAVAGE. Witnesses:
JOSEPH J. WOOLLEY, W. B. BooTH.
Family
ID=
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