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US20070079951A1 - Heat storage unit - Google Patents

Heat storage unit Download PDF

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Publication number
US20070079951A1
US20070079951A1 US10/580,048 US58004804A US2007079951A1 US 20070079951 A1 US20070079951 A1 US 20070079951A1 US 58004804 A US58004804 A US 58004804A US 2007079951 A1 US2007079951 A1 US 2007079951A1
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US
United States
Prior art keywords
heat storage
heat
supply pipe
storage body
exchange medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/580,048
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English (en)
Inventor
Kazuo Takahashi
Hiromiki Yagi
Yasuo Higashi
Toshiya Miyake
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Assigned to KABUSHIKI KAISHA KOBE SEIKO SHO reassignment KABUSHIKI KAISHA KOBE SEIKO SHO ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HIGASHI, YASUO, MIYAKE, TOSHIYA, TAKAHASHI, KAZUO, YAGI, HIROMIKI
Publication of US20070079951A1 publication Critical patent/US20070079951A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02—Materials undergoing a change of physical state when used
    • C09K5/06—Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063—Materials absorbing or liberating heat during crystallisation; Heat storage materials
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/025—Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being in direct contact with a heat-exchange medium or with another heat storage material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14—Thermal energy storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Definitions

  • the present invention relates to a heat storage unit capable of storing generated heat and transporting the heat to a remote place.
  • Heat generated from a factory such as an ironworks and garbage-disposal facility, for example, is used in various kinds of facility near the factory. Further, by temporarily storing the heat generated from the factory in a heat storage body or the like and by transporting the heat storage body, the heat can be used in the remote place from the factory.
  • a device for storing heat there exists a device that performs heat exchange by allowing a medium such as oil, to which heat is supplied, to directly contact metal hydrate and stores heat in the metal hydrate.
  • the heat storage body such as sodium acetate and oil having a smaller specific gravity than that of the heat storage body are housed in the storage container of Patent Document 1. Since the specific gravity of oil is smaller and the oil and the heat storage body do not mix, they are housed vertically in a separated manner. Then, pipes are disposed in the oil and the heat storage body, and they are severally connected to a heat exchanger. The oil is taken into the heat exchanger from one pipe to supply heat, and the oil to which heat was supplied is discharged from the other pipe into the heat storage body. Since the discharged oil has a small specific gravity, it goes up to the oil in the upper area. Heat is exchanged by the direct contact between the heat storage body and the oil while the oil goes up. By repeating the above-described action, heat is stored in the heat storage body. Then, the pipes of Patent Document 1 are in a double pipe structure in order to prevent impurities from being mixed into the pipes or the heat exchanger.
  • Patent Document 1 International Publication No. WO 03/019099 ( FIG. 1 )
  • the heat storage body such as sodium acetate that stores heat utilizes latent heat of fusion, where the state of the heat storage body changes from solid to liquid as heat is added, and heat is thus stored. Therefore, in Patent Document 1, the heat storage body is solid at the starting point of heat supply, so that discharge holes are clogged up by solid heat storage body even when the oil to which heat was supplied is ready to be discharged from the pipe arranged inside the heat storage body, the oil cannot be discharged until heat is applied to the heat storage body to change its state to liquid, and heat cannot be supplied to the heat storage body. As a result, enormous time is spent in storing heat.
  • the present invention includes: a storage container that houses a heat storage body, which stores heat by a state change from solid to liquid, and a heat exchange medium, which exchanges heat by directly contacting the heat storage body, has a smaller specific gravity than that of the heat storage body, and is separated from the heat storage body; a supply pipe that passes through at least the heat storage body housed in the storage container and supplies the heat exchange medium into the storage container; and a discharge pipe that discharges the heat exchange medium housed in the storage container to the outside of the storage container, in which the supply pipe crosses a boundary surface between the heat exchange medium and the heat storage body, has a plurality of discharge holes that discharge the supplied heat exchange medium, and at least one of the discharge holes is positioned inside the heat exchange medium.
  • the heat exchange medium can be discharged from the supply pipe regardless of the state of the heat storage body because the discharge holes are provided in the heat exchange medium side.
  • the heat storage body is solid under normal state and changes to liquid as heat is stored. For this reason, the discharge holes are clogged up by the solid heat storage body at the starting point of heat supply even if the discharge holes are provided for the supply pipe arranged in the heat storage body.
  • the supplied heat exchange medium can be discharged by providing the discharge holes on the heat exchange medium side, and heat can be conducted to the heat storage body.
  • the heat exchange medium can be discharged from the discharge holes provided on the heat storage body side as well.
  • the supply pipe of the present invention cross vertically with respect to the boundary surface.
  • the heat exchange medium can be discharged along the supply pipe by allowing the supply pipe to cross vertically the boundary surface, and heat can be stored in the heat storage body near the supply pipe first.
  • heat exchange from the heat exchange medium to the heat storage body can be performed efficiently.
  • the supply pipe be disposed coaxially around the circumference of an area having the discharge holes and have a circulation pipe to allow the heat exchange medium discharged from the discharge holes to go up in the vertical direction.
  • the present invention includes: a storage container that houses a heat storage body, which stores heat by a state change from solid to liquid, and a heat exchange medium, which exchanges heat by directly contacting the heat storage body, has a smaller specific gravity than that of the heat storage body, and is separated from the heat storage body; a supply pipe that passes through at least the heat storage body housed in the storage container and supplies the heat exchange medium into the storage container; and a discharge pipe that discharges the heat exchange medium housed in the storage container to the outside of the storage container, in which the supply pipe includes a first supply pipe having discharge holes that discharge the supplied heat exchange medium into the heat storage body and a second supply pipe that crosses the boundary surface between the heat exchange medium and the heat storage body, which are housed in the storage container, and has an outlet inside the heat exchange medium.
  • heat storage time can be shortened by using first and second flow pipes.
  • the heat storage body can store heat by changing its state from solid to liquid. Therefore, since the heat storage body is solid at the starting point of heat storage, the discharge holes provided for the first supply pipe are clogged up and they cannot discharge the supplied heat exchange medium.
  • the second supply pipe since the second supply pipe has an outlet in the heat exchange medium, it can constantly discharge the supplied heat exchange medium. For this reason, heat can be conducted by indirect contact of the heat exchange medium flowing in the second supply pipe to change the heat storage body from solid to liquid. Then, by changing the heat storage body to liquid, the heat exchange medium can be discharged from the discharge holes of the first supply pipe. By switching the two supply pipes to store heat in the heat storage body in this manner, heat storage time can be shortened.
  • the second supply pipe surround at least a part of the first supply pipe including the discharge holes and have a communicating portion that guides the discharge holes to the heat exchange medium.
  • a switching valve for switching supply and cutoff of the heat exchange medium depending on the state of the heat storage body be provided severally for the first and second supply pipes.
  • timing for switching the supply pipes can be changed depending on the state of the heat storage body, and heat can be stored more efficiently.
  • the pipes can be switched such that the heat exchange medium is supplied to both of the first supply pipe and the second supply pipe at the starting point of heat storage and then the medium is supplied only to the first supply pipe, and thus heat can be stored efficiently.
  • the present invention may be provided with the discharge holes for an area extending in the horizontal direction such that the holes are open in the vertically downward direction.
  • the specific gravity of the heat exchange medium is smaller than that of the heat storage body, so that a danger that the heat storage body enters inside the supply pipe from the discharge holes is eliminated when the discharge holes are open downward.
  • the supply pipe or the first supply pipe have an expanded portion that is in a shape that widens toward the end and provided with the discharge holes on the bottom surface.
  • the specific gravity of the heat exchange medium is smaller than that of the heat storage body, so that a danger that the heat storage body enters inside the supply pipe from the discharge holes is eliminated because the discharge holes are open downward.
  • more heat exchange medium can be discharged by forming the pipe in the shape that widens toward the end, and the heat storage time can be shortened.
  • the present invention includes: a storage container that houses a heat storage body, which stores heat by a state change from solid to liquid, and a heat exchange medium, which exchanges heat by directly contacting the heat storage body, has a smaller specific gravity than that of the heat storage body, and is separated from the heat storage body; a supply pipe that passes through at least the heat storage body housed in the storage container and supplies the heat exchange medium into the storage container; and a discharge pipe that discharges the heat exchange medium -housed in the storage container to the outside of the storage container, in which the supply pipe includes a first supply pipe having an outlet that discharges the supplied heat exchange medium into the housed heat storage body and a second supply pipe that has at least a part of the first supply pipe inside thereof and has discharge holes that discharge the supplied heat exchange medium into the heat storage body.
  • the heat exchange medium can constantly flow in the first supply pipe regardless of the state of heat storage body, so that heat can be conducted to the heat exchange medium in the second supply pipe and high temperature can be maintained.
  • high temperature can be discharged from the discharge holes, so that heat can be sufficiently stored.
  • the present invention in the case where the supply pipes are provided parallelly in the heat storage body, be provided with a thermal conduction member for conducting heat of the supply pipes to the heat storage body between the supply pipes.
  • a thermal conduction member for conducting heat of the supply pipes to the heat storage body between the supply pipes.
  • the supply pipe of the present invention be provided on the bottom surface of the storage container.
  • the heat exchange medium to be discharged goes up because its specific gravity is lighter than the heat storage body, and a contact time between the discharged heat exchange medium and the heat storage body can be made longer by providing the supply pipe on the bottom surface.
  • the second supply pipe be provided on the bottom surface of the storage container so as to cover the bottom surface. With this, a contact surface between the second supply pipe and the heat storage body is wide and heat can be stored from the bottom portion of the heat storage body, so that the heat storage time can be shortened.
  • connection port of the supply pipe of the present invention be positioned above the connection port of the discharge pipe.
  • the connection port of the supply pipe by allowing the connection port of the supply pipe to be positioned higher than the connection port of the discharge pipe, the heat exchange medium from the discharge pipe can be inversely flown first when the heat storage body or the heat exchange medium flows inversely, and it is possible to avoid a danger that the heat storage body to which heat is stored flows inversely.
  • the present invention have wave-absorbing plates that are parallelly arranged with each other along the boundary surface between the heat storage body and the heat exchange medium, arranged vertically with respect to the boundary surface, and prevent agitation on the boundary surface. With this constitution, it is possible to prevent agitation on the boundary surface caused by vibration associated with transportation in the heat storage state.
  • the discharge pipe of the present invention include a separation mechanism that separates the heat storage body and the heat exchange medium.
  • the heat storage body can be removed if it is mixed in the heat exchange medium to be discharged outside the storage container.
  • the separation mechanism have a separator for allowing the heat exchange medium and the heat storage body, which were taken in, to flow horizontally in one direction and a discharge hole that discharges the heat storage body, which is being precipitated, from the separator, and the separator have a shape for guiding the precipitated heat storage body toward the discharge hole.
  • the heat storage body of the present invention be erythritol. With this, it is possible to store heat efficiently in a short time.
  • a heat storage unit 1 according to the first embodiment of the present invention is preferably used in a portable heat storage unit.
  • a portable heat storage unit For example, as shown in FIG. 1 , it is applied for a heat transportation system that transports heat when a factory 60 generating heat and facility 70 using the heat are remote from each other.
  • the heat storage unit 1 is detachable to connection ports 51 , 52 of heat exchangers 5 a, 5 b that store heat or discharge heat to/from the heat storage unit 1 , and is transported between the factory 60 and the facility 70 by a vehicle 50 such as a truck.
  • the factory 60 is a garbage-incinerating facility, a power generating plant, an ironworks or the like, and heat generated in the factory is stored in the heat storage unit 1 via the heat exchanger 5 a.
  • the facility 70 is facility such as a heated swimming pool and a hospital, and the heat stored in the heat storage unit 1 is applied for temperature-control system or the like in the facility via the heat exchanger 5 b.
  • heat exchange in the factory 60 side will be explained.
  • the heat storage unit 1 includes a heat storage container 1 a (storage container) that houses oil 2 (heat exchange medium) and sodium acetate trihydrate salt 3 (heat storage body) (hereinafter, referred to as sodium acetate 3 ), a supply pipe 4 , and a discharge pipe 6 . Since the oil 2 and the sodium acetate 3 are not mixed with each other and the oil 2 has a smaller specific gravity than that of the sodium acetate 3 , the oil 2 and the sodium acetate 3 are housed in the heat storage container 1 a severally in an upper layer and a lower layer in a separate manner.
  • oil 2 and the sodium acetate 3 are not mixed with each other and the oil 2 has a smaller specific gravity than that of the sodium acetate 3 , the oil 2 and the sodium acetate 3 are housed in the heat storage container 1 a severally in an upper layer and a lower layer in a separate manner.
  • the oil 2 and the sodium acetate 3 are not mixed, that is, the oil 2 and the sodium acetate 3 are separate from each other, a member or the like for separating the oil 2 from the sodium acetate 3 is not laid between them and the oil 2 is in directly contact with the sodium acetate 3 .
  • the oil 2 performs heat exchange with the sodium acetate 3 by direct contact with the sodium acetate 3 .
  • the oil 2 when it is taken into the heat exchanger 5 a from the discharge pipe 6 (described later) and heat is supplied in the heat exchanger 5 a (in the description below, the oil 2 to which heat was supplied in the heat exchanger 5 a will be called oil 2 a ), it is discharged into the sodium acetate 3 via the supply pipe 4 . Since the discharged oil 2 a has a smaller specific gravity than that of the sodium acetate 3 , it goes up to the oil 2 of the upper layer and is taken in by the oil 2 . During the upward movement, the heat supplied to the oil 2 a is conducted to the sodium acetate 3 due to the direct contact with the sodium acetate 3 .
  • the sodium acetate 3 stores the heat conducted from the above-described oil 2 a.
  • the melting point of the sodium acetate 3 is about 58° C. and it is solid under the normal state (room temperature). Then, its state changes from solid to liquid when the heat is conducted from the oil 2 a due to the direct contact, and heat is stored during a liquid state.
  • the supply pipe 4 is provided in the upper layer portion of the heat storage container 1 a , where the housed oil 2 is positioned, in a penetrated manner, and a connection port 41 is detachably connected to the connection port 51 of the heat exchanger 5 a.
  • the supply pipe 4 that is provided for the heat storage container 1 a in a penetrated manner vertically crosses the boundary surface between the oil 2 and the sodium acetate 3 and enters the sodium acetate 3 , and furthermore, it is bent in an L-shape and horizontally extended.
  • the supply pipe 4 has an internal space and the oil 2 a to which heat was supplied by the heat exchanger 5 a flows in the internal space.
  • the supply pipe 4 has a plurality of discharge holes 4 a, 4 b, which discharge the oil 2 a flowing inside the pipe, along its axis direction.
  • a plurality of discharge holes 4 a are provided above a boundary surface while using the boundary surface between the oil 2 and the sodium acetate 3 as a boundary, that is, on the supply pipe 4 of the oil 2 side.
  • one or more discharge holes 4 b are provided below the boundary surface, that is, on the supply pipe 4 of the sodium acetate 3 side.
  • the discharge holes 4 b provided in an area where the supply pipe 4 is bent in an L-shape and horizontally extended are provided so as to be open vertically downward.
  • the sodium acetate 3 since the sodium acetate 3 has a larger specific gravity than that of the oil 2 a, the sodium acetate 3 does not enter the supply pipe 4 while pushing aside the oil 2 a to be discharged from the discharge holes 4 b, and this prevents the sodium acetate 3 from being solidified and clogged inside the supply pipe 4 .
  • the discharge pipe 6 is provided in the upper layer portion of the heat storage container 1 a , where the housed oil 2 is positioned, in a penetrated manner. Then, a connection port 61 of the discharge pipe 6 is detachably connected to the connection port 52 of the heat exchanger 5 a to take the oil 2 inside the heat storage container 1 a into the heat exchanger 5 a. At this point, the connection port 61 of the discharge pipe 6 is disposed on the heat storage container 1 a so as to be below the connection port 41 of the supply pipe 4 , that is, such that the discharge pipe 6 is below the supply pipe 4 .
  • the supply pipe 4 and the discharge pipe 6 are removed from the heat exchanger 5 a in a wrong procedure, there is a possibility that the oil 2 or the sodium acetate 3 flows inversely due to a pressure difference between the outside and the inside of the heat storage container 1 a .
  • the discharge pipe 6 is arranged below the supply pipe 4 to allow the oil 2 to which heat is not applied to flow inversely first from the discharge pipe 6 . Consequently, a pressure difference from the outside is eliminated and a danger that the sodium acetate 3 to which heat is stored flows inversely from the supply pipe 4 is prevented.
  • the heat exchanger 5 a stores heat generated from the factory 60 in the heat storage container 1 a .
  • the supply pipe 4 and the discharge pipe 6 are connected detachably to the heat exchanger 5 a. Then, the supply pipe 4 and the discharge pipe 6 are communicated with each other in the heat exchanger 5 a.
  • a pipe (not shown) that takes in the heat generated from the factory 60 as steam and a pipe (also not shown) that discharges steam from which heat has been removed are connected to the heat exchanger 5 a, and the pipes are communicated with each other in the heat exchanger 5 a via a pipe arranged so as to surround the communicated portion between the supply pipe 4 and the discharge pipe 6 .
  • a pump (not shown) is disposed for the connection port 51 of the heat exchanger 5 a, and it takes the oil 2 into the heat exchanger 5 a and sends the oil 2 that was taken in to the heat storage container 1 a.
  • the heat exchanger 5 a takes in the oil 2 inside heat storage container 1 a by the pump via the discharge pipe 6 while it takes in steam generated from the factory 60 via the pipe.
  • the steam that was taken in conducts heat to the oil 2 , which was taken in, by indirect contact of the pipes in the communicated portion between the supply pipe 4 and the discharge pipe 6 .
  • the oil 2 a to which heat was supplied is supplied into the heat storage container 1 a via the supply pipe 4 .
  • the steam from which heat was removed is discharged via the pipe.
  • the steam generated from the factory 60 is taken into the heat exchanger 5 a.
  • the oil 2 inside the heat storage container 1 a is taken into the heat exchanger 5 a via the discharge pipe 6 .
  • heat of the steam is conducted to the oil 2 that was taken in.
  • the oil 2 a to which heat was supplied is returned to the heat storage container 1 a via the supply pipe 4 .
  • the oil 2 a flows in the supply pipe 4 and is discharged from the discharge holes 4 a, 4 b. Since the sodium acetate 3 at the starting point of heat storage is solid and the discharge holes 4 b are provided in the sodium acetate 3 side, the discharge holes 4 b is in the state of being clogged by the solid sodium acetate 3 . For this reason, the oil 2 a is not discharged from the discharge holes 4 b.
  • the oil 2 a can be discharged without clogging the discharge holes 4 a. Then, the oil 2 a discharged from the discharge holes 4 a conducts heat to the sodium acetate 3 near the boundary surface between the oil 2 and the sodium acetate 3 . With this, the state of the sodium acetate 3 gradually changes from solid to liquid from the upper portion thereof, and the oil 2 a is discharged from the discharge holes 4 b as well. Due to the direct contact with the discharged oil 2 a, heat is stored in the sodium acetate 3 . Furthermore, the oil 2 a flowing in the supply pipe 4 conducts heat to the sodium acetate 3 via the supply pipe 4 due to the indirect contact. This makes it possible to change the sodium acetate 3 from solid to liquid even faster and the heat storage time can be shortened.
  • the sodium acetate 3 becomes a liquid state and the oil 2 a is discharged into the sodium acetate 3 , it goes up to the oil 2 in the upper layer and is taken into the layer because the specific gravity of the oil 2 a is smaller than that of the sodium acetate 3 .
  • the oil 2 a conducts heat to the sodium acetate 3 as it goes up. By repeating the above-described action, heat can be stored in the sodium acetate 3 .
  • the sodium acetate 3 is liquid in the state where heat was supplied, and stored heat can be taken out from the liquid.
  • the supply pipe 4 and the discharge pipe 6 of the heat storage unit 1 are connected detachably to the heat exchanger 5 b that takes out the heat stored in the heat storage unit 1 , and furthermore, a pipe for taking in gas or liquid and a pipe for supplying to heated gas or liquid and for supplying to the temperature-control system of the facility 70 are connected to the heat exchanger 5 b.
  • the heat exchanger 5 b discharges the oil 2 into the sodium acetate 3 in which heat is stored via the supply pipe 4 . Heat is conducted from the sodium acetate 3 to the discharged oil 2 due to the direct contact as it goes up. With this, heat is supplied to the oil 2 in the upper layer and the oil is taken into the heat exchanger 5 b from the discharge pipe 6 . On the other hand, gas or liquid such as water is taken into the heat exchanger 5 b. Then, heat is conducted from the oil 2 to which heat was applied to gas or liquid. The gas or liquid to which heat was conducted passes through the pipe and is supplied to the temperature-control system in the facility 70 . By repeating the above-described action, heat stored in the sodium acetate 3 can be taken out.
  • the heat generated from the factory 60 due to garbage incineration or the like is stored in the heat storage unit 1 . Since the heat storage unit 1 is connected to the heat exchanger 5 a detachably, it is removed after heat storage is completed, and transported to the facility 70 requiring the stored heat by the vehicle 50 such as a truck. The transported heat storage unit 1 is connected to the heat exchanger 5 b, the heat stored in the heat storage unit 1 is taken out, and used in the temperature-control system or the like of the facility 70 .
  • the discharge holes 4 a are provided in the oil 2 side of the supply pipe 4 in this embodiment, even if the sodium acetate 3 is solid at the starting point of heat storage, the solid sodium acetate 3 can be changed to liquid in a shorter time by discharging the oil 2 a from the discharge holes 4 a. With this, the heat storage time to the sodium acetate 3 can be shortened.
  • the sodium acetate 3 near the supply pipe 4 can be changed from solid to a liquid state by the oil 2 a discharged from the discharge holes 4 a, and thus the oil 2 a can be discharged faster from the discharge holes 4 b. Consequently, the heat storage time can be even shorter.
  • a circulation pipe 4 c may be provided as shown in FIG. 3 .
  • the circulation pipe 4 c is provided so as to surround the circumference of the supply pipe 4 that vertically crosses boundary surface between the oil 2 and the sodium acetate 3 , and serves as a guide for allowing the oil 2 a, which is discharged from the discharge holes 4 b, to go up in the vertical direction after the state of the sodium acetate 3 is changed to liquid.
  • a plurality of plates 11 may be provided so as to vertically cross the boundary surface between the oil 2 and the sodium acetate 3 as shown in FIG. 4 .
  • the plates 11 By providing the plates 11 , the oil 2 and the sodium acetate 3 vibrate during the transportation of the heat storage unit 1 to generate waves, and agitation on the boundary surface can be prevented. By preventing agitation, heat stored in the sodium acetate 3 can be held.
  • a separation device 12 may be provided halfway the discharge pipe 6 .
  • the separating device 12 is a device that separates the oil 2 and the sodium acetate 3 when the sodium acetate 3 is mixed in the oil 2 that was taken in.
  • the separation device 12 has a structure where it takes out the oil 2 , which was taken in, from the upper portion of the separation device 12 while it spirally rotates the oil 2 that was taken in.
  • the sodium acetate 3 since the sodium acetate 3 has a larger specific gravity than that of the oil 2 , the sodium acetate 3 is discharged from an outlet at the bottom portion of the separation device 12 along the sidewall surface of the separation device 12 when it hits the sidewall surface due to centrifugal force, and only the oil 2 is taken into the heat exchanger 5 a. With this, the sodium acetate 3 can be removed from the oil 2 to be taken into the heat exchanger 5 a, and a danger of a failure or the like that is caused when the sodium acetate 3 enters the heat exchanger 5 a is eliminated.
  • the above-described modified examples can be applied for embodiments described below.
  • the supply pipe 4 vertically crosses the boundary surface between the oil 2 and the sodium acetate 3 in this embodiment described above, but it may cross the boundary surface diagonally instead of vertically. Further, the supply pipe 4 is bent in the L-shape and extended in the horizontal direction, but it may not be extended in the horizontal direction.
  • the pipe may be any shape as long as it can discharge the oil 2 in the sodium acetate 3 .
  • the side surface may be a shape that widens toward the end as shown in FIG. 6 , or a supply portion 13 (expanded portion) having the shape that widens toward the end may be provided halfway the supply pipe 4 . In this case, it may be a conical shape or may be hemispherical shape. Further, in this case, by providing discharge holes 13 a at the bottom surface portion, a danger that the sodium acetate 3 enters inside the pipe is eliminated.
  • the discharge holes 4 b which are provided in the horizontally extended portion of the supply pipe 4 in the sodium acetate 3 , are provided on the lower portion of the supply pipe 4 , but they may be provided on the upper portion thereof.
  • sodium acetate is used as a substance for storing heat and oil is used as a substance for conducting heat, but the substances are not limited to them.
  • the heat storage body may be erythritol. Since erythritol can be heated by oil having the temperature of 120° C. or higher, it exerts an effect that heat can be stored efficiently in a short time.
  • the heat storage unit according to this embodiment is different from the first embodiment on the point that it is provided with two supply pipes. In the following, only the different point will be described. Note that the same reference numerals are applied to the same members as those of the first embodiment, and their explanation will be omitted.
  • the heat storage unit 1 is provided with a first supply pipe 7 (first supply pipe) and a second supply pipe 8 (second supply pipe).
  • the first supply pipe 7 and the second supply pipe 8 are provided in the upper layer portion of the heat storage container 1 a , where the housed oil 2 is positioned, in a penetrated manner, and is detachably connected to the heat exchanger 5 a.
  • the connection port of one supply pipe 11 is detachably connected to the connection port 51 of the heat exchanger 5 a, and the supply pipe 11 branches into the first supply pipe 7 and the second supply pipe 8 .
  • the first supply pipe 7 and the second supply pipe 8 which are provided for the heat storage container 1 a in a penetrated manner, vertically cross the boundary surface between the oil 2 and the sodium acetate 3 and go into the sodium acetate 3 , and furthermore, is bent in the L-shape and extended horizontally. Moreover, the second supply pipe 8 vertically crosses the boundary surface between the oil 2 and the sodium acetate 3 from the end portion of the horizontally extended portion.
  • the first supply pipe 7 and the second supply pipe 8 have an internal space, and the oil 2 a to which heat was supplied by the heat exchanger 5 a flows in the internal space.
  • the first supply pipe 7 has a plurality of discharge holes 7 a that discharge the supplied oil 2 a into the sodium acetate 3 along the axis direction thereof. Further, the second supply pipe 8 has outlets 8 a that discharge the supplied oil 2 a into the oil 2 . The outlets 8 a are provided on the terminal portion of the second supply pipe 8 , the oil 2 a supplied from the heat exchanger 5 a flows in the second supply pipe 8 , and is discharged into the oil 2 from the outlets 7 a.
  • the discharge holes 4 b provided on the portion of the first supply pipe 7 which is extended in the horizontal direction, are provided in the vertically downward direction. Note that the first supply pipe 7 may have discharge holes on the oil 2 side similar to the first embodiment.
  • the supply pipe 11 is detachably connected to the heat exchanger 5 a, and is separated into the first supply pipe 7 and the second supply pipe 8 .
  • valves 9 a, 9 b switching valves
  • valves 9 a, 9 b switching valves
  • the valves 9 a, 9 b open/close depending on the state of the sodium acetate 3 . Specifically, when the sodium acetate 3 is solid, the valve 9 b is closed to prevent the oil 2 a from being supplied to the second supply pipe 8 in order to supply the oil 2 a only to the first supply pipe 7 . Further, when the sodium acetate 3 is liquid, the valve 9 a is closed and the valve 9 b is opened to allow the oil 2 a to be supplied only to the second supply pipe 8 .
  • the valves 9 a, 9 b may be manually opened/closed by an operator, or a controller may be connected to automatically open/close the valves. Note that description of the other members will be omitted because they are the same as the first embodiment.
  • the valve 9 b When the sodium acetate 3 becomes approximately liquid, the valve 9 b is closed and the valve 9 a is opened to cutoff the second supply pipe 8 , and the oil 2 a is supplied to the first supply pipe 7 .
  • the oil 2 a supplied to the first supply pipe 7 flows through the first supply pipe 7 and is discharged into the sodium acetate 3 from the discharge holes 7 a.
  • the oil 2 a When the oil 2 a is discharged, it goes up to the oil 2 in the upper layer and taken into the oil. Heat is conducted to the sodium acetate 3 during the upward movement due to the direct contact with the sodium acetate 3 . With this, heat can be stored in the sodium acetate 3 .
  • the oil 2 a is supplied to the second supply pipe 8 when the sodium acetate 3 is solid to conduct heat to the sodium acetate 3 by indirect contact, the oil 2 a is supplied to the first supply pipe 7 and discharged when the sodium acetate 3 becomes liquid to conduct heat to the sodium acetate 3 by direct contact, and thus heat can be efficiently stored in the sodium acetate 3 .
  • the first supply pipe 7 could burst because the supplied oil 2 a is not discharged from the discharge holes 7 a at the starting point of heat storage. For this reason, burst of the first supply pipe 7 can be prevented by switching the first supply pipe 7 and the second supply pipe 8 , and the heat storage unit 1 can be used safely.
  • the oil 2 is supplied either one of the first supply pipe 7 and the second supply pipe 8 depending on the state of the sodium acetate 3 , but the invention is not limited to this.
  • the oil 2 a may be supplied to only the second supply pipe 8 at the starting point of heat storage, and after that, the oil 2 a may be supplied to both of the first supply pipe 7 and the second supply pipe 8 .
  • the first supply pipe 7 a does not have discharge holes in the above-described embodiment, the pipe may have the discharge holes.
  • supply pipes may not have the valves 9 a, 9 b.
  • the heat storage unit according to this embodiment is the same as the second embodiment on the point that it is provided with two supply pipes but is different on the point that one supply pipe surrounds the other supply pipe. In the following, only the different point will be described. Note that the same reference numerals are applied to the same members as those of the first and the second embodiments, and their explanation will be omitted.
  • the heat storage unit 1 has two pipes that are the first supply pipe 7 and a second supply pipe 10 .
  • the first supply pipe 7 and the second supply pipe 10 are provided in the upper layer portion of the heat storage container 1 a in a penetrated manner, where the housed oil 2 is positioned, and is detachably connected to the heat exchanger 5 a.
  • the connection port of one supply pipe 11 is detachably connected to the connection port 51 of the heat exchanger 5 a, and the supply pipe 11 branches into the first supply pipe 7 and the second supply pipe 10 .
  • the first supply pipe 7 is arranged in the heat storage container 1 a so as to surround the second supply pipe 10 .
  • the first supply pipe 7 and the second supply pipe 10 vertically cross the boundary surface between the oil 2 and the sodium acetate 3 and go into the sodium acetate 3 , and furthermore, are bent in the L-shape and extended horizontally.
  • the first supply pipe 7 and the second supply pipe 10 have an internal space, and the oil 2 a to which heat was supplied by the heat exchanger 5 a flows in the internal space.
  • the first supply pipe 7 is arranged in the internal space of the second supply pipe 10 .
  • a plurality of supply tubes 10 a which vertically cross the boundary surface between the oil 2 and the sodium acetate 3 , are disposed.
  • the supply tubes 10 a have outlets 10 b on the oil 2 side, and the oil 2 a flowing through the second supply pipe 10 passes through the supply tubes 10 a to be discharged from the outlets 10 b into the oil 2 , as shown in FIG. 9 .
  • communication portions 10 c for discharging the oil 2 a flowing through the first supply pipe 7 into the sodium acetate 3 are provided for the second supply pipe 10 at positions that superpose the discharge holes 7 a of the first supply pipe 7 to be surrounded. Note that description of the other members will be omitted because they are the same as the first embodiment.
  • the oil 2 a to which heat was supplied flows through the second supply pipe 10 and the supply tubes 10 a
  • the oil 2 a conducts heat to the sodium acetate 3 by indirect contact via the second supply pipe 10 and the supply tubes 10 a.
  • the sodium acetate 3 gradually changes from solid to liquid.
  • the valve 9 b is closed and the valve 9 a is opened. This allows the oil 2 a to be supplied to the first supply pipe 7 .
  • the discharge holes 7 a and the communication portions 10 c are not clogged and the oil 2 a can be discharged from the discharge holes 7 a and the communication portions 10 c.
  • heat is conducted from the oil 2 a flowing through the surrounding second supply pipe 10 . This further increases the temperature and time to store heat in the sodium acetate 3 can be further shortened.
  • the second supply pipe 10 surrounds approximately the entire first supply pipe 7 in the sodium acetate 3 , but it may surround only a part of the first supply pipe 7 . Further, similar to the second embodiment, the oil 2 a may be supplied to both of the first supply pipe 7 and the second supply pipe 10 after the sodium acetate 3 changes to liquid. In addition, the pipes may not have the valves 9 a, 9 b.
  • the heat storage unit according to this embodiment is the same as the third embodiment on the point that it is provided with two supply pipes and one supply pipe surrounds the other supply pipe but structure of each supply pipe is different. In the following, only the different point will be described. Note that the same reference numerals are applied to the same members as those of the first to the third embodiments, and their explanation will be omitted.
  • the heat storage unit 1 has two pipes that are a first supply pipe 15 and a second supply pipe 16 .
  • the first supply pipe 15 and the second supply pipe 16 are provided in the upper layer portion of the heat storage container 1 a in a penetrated manner, where the housed oil 2 is positioned, and is detachably connected to the heat exchanger 5 a.
  • the connection port of one supply pipe 11 is detachably connected to the connection port 51 of the heat exchanger 5 a, and the supply pipe 11 branches into the first supply pipe 15 and the second supply pipe 16 .
  • the first supply pipe 15 and the second supply pipe 16 vertically cross the boundary surface between the oil 2 and the sodium acetate 3 and go into the sodium acetate 3 , and furthermore, are bent in the L-shape and extended horizontally.
  • the first supply pipe 15 is further bent in the L-shape, vertically crosses the boundary surface again, and an outlet 15 a for discharging the oil 2 a is provided on the tip of the area bent in the L-shape.
  • the first supply pipe 15 and the second supply pipe 16 have an internal space, and the oil 2 a to which heat was supplied by the heat exchanger 5 a flows in the internal space.
  • a second supply tube 16 surrounds the first supply pipe 15 .
  • the portion where the supply pipes 15 , 16 are horizontally extended is arranged on the bottom surface of the heat storage container 1 a .
  • contact time of the oil 2 a discharged from discharge holes 16 a and the sodium acetate 3 can be made longer, and heat of the oil 2 a can be sufficiently conducted to the sodium acetate 3 .
  • the oil 2 a has a smaller specific gravity than that of the sodium acetate 3 and goes up once it is discharged from the discharge holes 16 a, so that it becomes difficult to conduct heat to the sodium acetate 3 near the bottom surface of the heat storage container 1 a and a long time is necessary in storing heat.
  • the first supply pipes 15 , 16 on the bottom surface heat can be sufficiently stored in the sodium acetate 3 near the bottom surface, and the heat storage time can be shortened.
  • the discharge holes 16 a for discharging the oil 2 a into the sodium acetate 3 are provided on the second supply pipe 16 in the opposite direction to the bottom surface side of the heat storage container 1 a .
  • the oil 2 a supplied to the supply pipe 11 passes through the first supply pipe 15 and is discharged from the outlet 15 a into the oil 2
  • the sodium acetate 3 Since the sodium acetate 3 is solid at the starting point of heat storage, it becomes difficult for the oil 2 a to be discharged from the discharge holes 16 a and the outlets are clogged, and thus the oil 2 a cannot flow well through the second supply pipe 16 . Then, there is a danger that the temperature of oil 2 a is reduced while they are clogged.
  • the outlet 15 a of the first supply pipe 15 is provided in the oil 2 , the oil 2 a can constantly flow through the first supply pipe 15 regardless of the state of the sodium acetate 3 at the starting point of heat storage, and the high-temperature oil 2 a constantly flows in the first supply pipe 15 .
  • heat is conducted to the oil 2 a in the second supply pipe 16 by contacting the first supply pipe 15 in which the high-temperature oil 2 a constantly flows, and high-temperature can be maintained without reducing temperature.
  • the high-temperature oil 2 a can be discharged from the discharge holes 16 a to the sodium acetate 3 .
  • high-temperature can be also maintained in the second supply pipe 16 , and heat can be conducted to the sodium acetate 3 near the second supply pipe 16 as well.
  • the supply pipes 15 , 16 are arranged on the bottom surface of the heat storage container 1 a , but they may not be arranged on the bottom surface.
  • the disposing positions of the discharge holes 16 a are not limited as described above.
  • the supply pipes 15 , 16 are not arranged on the bottom surface, it is preferable that the supply pipes 15 , 16 be arranged near the bottom surface.
  • the supply pipes 15 , 16 may be provided parallelly in the lateral direction with the same gap as shown in FIG. 12 .
  • a corrugated conduction plate 17 thermal conduction member
  • the conduction plate 17 has a corrugated shape where circular arcs are oppositely joined alternately, the second supply pipes 16 are fitted into the circular arc portions, they are closely adhered by welding or the like, and arranged on the bottom surface. With this, the contact area between the second supply pipe 16 and the conduction plate 17 becomes larger and heat quantity to be conducted to the conduction plate 17 becomes larger, and heat can be sufficiently conducted to the sodium acetate 3 between the supply pipes 15 , 16 . Consequently, the heat storage time can be made even shorter. It is preferable that the conduction plate 17 be constituted by metal having high thermal conductivity such as copper, aluminum and iron. Note that the conduction plate 17 may be a planar shape instead of the corrugated shape. In addition, the supply pipes 15 , 16 may be parallelly provided in a longitudinal direction and adjacent supply pipes 15 , 16 may not be arranged in the same gap.
  • the second supply pipe 16 may cover approximately the entire bottom surface of the heat storage container 1 a and the first supply pipe 15 may be extended in the second supply pipe 16 covering the bottom surface.
  • the first supply pipe 15 is designed to pass through the entire second supply pipe 16 , the oil 2 a in the second supply pipe 16 can be maintained at high-temperature. In this case, it is preferable that the first supply pipe 15 pass near the discharge holes 16 a. This makes it possible to maintain the oil 2 a to be discharged from the discharge holes 16 a at as high-temperature as possible, and the heat storage time can be shortened.
  • a separation device 14 (separation mechanism) as shown in FIG. 15 may be provided between the outlet 15 a of the first supply pipe 15 and the discharge pipe 6 .
  • the separation device 14 is a device for separating the oil 2 and the sodium acetate 3 when the sodium acetate 3 is mixed into the oil 2 that was taken in.
  • the separation device 14 has a main body 14 a (separator) that takes in the oil 2 containing the sodium acetate 3 .
  • the oil 2 is filled in the main body 14 a, the oil 2 horizontally taken into the body flows horizontally in one direction, and then is discharged.
  • the bottom surface of the main body 14 a has a level surface and a tilt surface, where a hole 14 b for discharging the sodium acetate 3 is provided in the level surface. Although described later, since the bottom surface has the tilt surface, the sodium acetate 3 to be precipitated is guided toward the hole 14 b.
  • the sodium acetate 3 having a larger specific gravity than that of the oil 2 precipitates while horizontally flowing in the main body 14 a.
  • the precipitated sodium acetate 3 is discharged from the hole 14 b.
  • the sodium acetate 3 precipitated on the tilt surface also moves toward the hole 14 b in a sliding manner to be discharged from the hole 14 b.
  • the separation device 14 may be provided halfway the discharge pipe 6 .
  • FIG. 1 An entire schematic view of the heat transportation system of the present invention
  • FIG. 2 A sectional view of the heat storage unit according to the first embodiment of the present invention
  • FIG. 3 A modified example of the heat storage unit according to the first embodiment
  • FIG. 4 Another modified example of the heat storage unit according to the first embodiment
  • FIG. 5 Another modified example of the heat storage unit according to the first embodiment
  • FIG. 6 Another modified example of the heat storage unit according to the first embodiment
  • FIG. 7 A sectional view of the heat storage unit according to the second embodiment of the present invention
  • FIG. 8 A sectional view of the heat storage unit according to the third embodiment of the present invention
  • FIG. 9 A sectional view on IX-IX line of FIG. 8
  • FIG. 10 A sectional view on X-X line of FIG. 8
  • FIG. 11 A sectional view of the heat storage unit according to the fourth embodiment of the present invention
  • FIG. 12 A modified example of the heat storage unit according to the fourth embodiment and a sectional view on XII-XII line of FIG. 11
  • FIG. 13 Another modified example of the heat storage unit according to the fourth embodiment and a sectional view on XIII-XIII line of FIG. 11
  • FIG. 14 Another modified example of the heat storage unit according to the fourth embodiment and a sectional view on XIV-XIV line of FIG. 11
  • FIG. 15 Another modified example of the heat storage unit according to the fourth embodiment and an enlarged sectional view of a separation device

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Other Air-Conditioning Systems (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
  • Air-Conditioning For Vehicles (AREA)
  • Loading And Unloading Of Fuel Tanks Or Ships (AREA)
US10/580,048 2003-12-02 2004-12-01 Heat storage unit Abandoned US20070079951A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2003-40257 2003-12-02
JP2003402457 2003-12-02
JP2004116574A JP4469208B2 (ja) 2003-12-02 2004-04-12 熱貯蔵ユニット
JP2004-116574 2004-04-12
PCT/JP2004/017834 WO2005054767A1 (ja) 2003-12-02 2004-12-01 熱貯蔵ユニット

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US10/580,048 Abandoned US20070079951A1 (en) 2003-12-02 2004-12-01 Heat storage unit

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US (1) US20070079951A1 (ja)
EP (1) EP1693636B1 (ja)
JP (1) JP4469208B2 (ja)
CA (1) CA2546687C (ja)
WO (1) WO2005054767A1 (ja)

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US20070029065A1 (en) * 2005-08-05 2007-02-08 Kabushiki Kaisha Kobe Seiko Sho Heat-storage unit and operation method of heat-storage unit
US20110042036A1 (en) * 2007-11-13 2011-02-24 Panasonic Corporation Chemical heat-storage apparatus
EP2489973A4 (en) * 2009-10-13 2014-06-18 Kobe Steel Ltd HEAT STORAGE DEVICE

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JP2007132569A (ja) * 2005-11-09 2007-05-31 Kurimoto Ltd 潜熱蓄熱装置
JP4617505B2 (ja) * 2005-11-09 2011-01-26 三機工業株式会社 潜熱蓄熱装置
JP4890029B2 (ja) * 2006-01-06 2012-03-07 三機工業株式会社 潜熱蓄熱装置およびその運転方法
JP4494375B2 (ja) * 2006-08-11 2010-06-30 株式会社神鋼環境ソリューション 熱輸送システム
JP2008128593A (ja) * 2006-11-22 2008-06-05 Kobe Steel Ltd 蓄熱装置
JP2008157578A (ja) * 2006-12-26 2008-07-10 Kobe Steel Ltd 蓄熱システム及び蓄熱装置
JP4680941B2 (ja) * 2007-01-11 2011-05-11 株式会社神鋼環境ソリューション 熱貯蔵器
JP2008180434A (ja) * 2007-01-24 2008-08-07 Kobelco Eco-Solutions Co Ltd 熱貯蔵器
JP2008180428A (ja) * 2007-01-24 2008-08-07 Kobelco Eco-Solutions Co Ltd 熱貯蔵器
JP2008190747A (ja) * 2007-02-02 2008-08-21 Kobe Steel Ltd 蓄熱装置
JP2008249192A (ja) * 2007-03-29 2008-10-16 Kobe Steel Ltd 蓄熱装置
JP2008298390A (ja) * 2007-06-01 2008-12-11 Kobelco Eco-Solutions Co Ltd 熱有効利用システム
JP4851394B2 (ja) * 2007-06-12 2012-01-11 三機工業株式会社 蓄熱装置
DE102007049385A1 (de) * 2007-10-15 2009-04-16 Rev Renewable Energy Ventures, Inc. Latentwärmespeicher
JP5160202B2 (ja) * 2007-11-22 2013-03-13 株式会社神鋼環境ソリューション 熱媒油の劣化防止方法、および熱輸送システム
KR100950299B1 (ko) 2008-03-27 2010-03-31 주식회사 케너텍 급속 축열 및 방열이 가능한 축열콘테이너
KR100950302B1 (ko) 2008-03-27 2010-03-31 주식회사 케너텍 센서형 축열콘테이너
JP5257982B2 (ja) * 2008-07-15 2013-08-07 三機工業株式会社 蓄熱装置および蓄熱ユニット
JP5252282B2 (ja) * 2008-09-22 2013-07-31 三機工業株式会社 蓄熱装置
EP2476736A1 (de) * 2011-01-12 2012-07-18 Gebr. Bruns GmbH Latentwärmespeicher mit Korrosionsschutzpolster
CN102538063A (zh) * 2012-03-15 2012-07-04 上海海事大学 耦合式相变移动供热装置及其供热方法
DK178864B1 (en) * 2016-02-23 2017-04-10 Suntherm Aps Faseændringsmateriale-baseret varmesystem
CN110707257B (zh) * 2019-10-25 2022-05-27 中铁轨道交通装备有限公司 一种具有加热功能的电池箱系统

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US7654306B2 (en) * 2005-08-05 2010-02-02 Kabushiki Kaisha Kobe Seiko Sho Heat-storage unit and operation method of heat-storage unit
US20110042036A1 (en) * 2007-11-13 2011-02-24 Panasonic Corporation Chemical heat-storage apparatus
EP2489973A4 (en) * 2009-10-13 2014-06-18 Kobe Steel Ltd HEAT STORAGE DEVICE

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JP2005188916A (ja) 2005-07-14
CA2546687A1 (en) 2005-06-16
CA2546687C (en) 2010-02-16
JP4469208B2 (ja) 2010-05-26
EP1693636B1 (en) 2015-02-11
EP1693636A4 (en) 2012-12-19
EP1693636A1 (en) 2006-08-23
WO2005054767A1 (ja) 2005-06-16

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