TWI438283B - 處理來自燒結和造粒工廠之排氣的方法 - Google Patents
處理來自燒結和造粒工廠之排氣的方法 Download PDFInfo
- Publication number
- TWI438283B TWI438283B TW096106594A TW96106594A TWI438283B TW I438283 B TWI438283 B TW I438283B TW 096106594 A TW096106594 A TW 096106594A TW 96106594 A TW96106594 A TW 96106594A TW I438283 B TWI438283 B TW I438283B
- Authority
- TW
- Taiwan
- Prior art keywords
- reagent
- exhaust gas
- additive
- adsorbent
- exhaust
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 50
- 238000005245 sintering Methods 0.000 title claims description 19
- 239000008188 pellet Substances 0.000 title description 2
- 239000003153 chemical reaction reagent Substances 0.000 claims description 64
- 239000003463 adsorbent Substances 0.000 claims description 56
- 239000000654 additive Substances 0.000 claims description 54
- 230000000996 additive effect Effects 0.000 claims description 50
- 239000000463 material Substances 0.000 claims description 40
- 238000006243 chemical reaction Methods 0.000 claims description 20
- 229910001385 heavy metal Inorganic materials 0.000 claims description 13
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 12
- 238000005469 granulation Methods 0.000 claims description 11
- 230000003179 granulation Effects 0.000 claims description 11
- 239000012065 filter cake Substances 0.000 claims description 8
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical group [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 6
- 230000002441 reversible effect Effects 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 150000002894 organic compounds Chemical class 0.000 claims description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- 239000011362 coarse particle Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 239000007789 gas Substances 0.000 description 85
- 239000002245 particle Substances 0.000 description 21
- 239000000428 dust Substances 0.000 description 18
- 230000008569 process Effects 0.000 description 17
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 10
- 238000009826 distribution Methods 0.000 description 8
- 238000012546 transfer Methods 0.000 description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 7
- 230000002378 acidificating effect Effects 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- 238000001179 sorption measurement Methods 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 238000001914 filtration Methods 0.000 description 5
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 5
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 235000010269 sulphur dioxide Nutrition 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 230000005540 biological transmission Effects 0.000 description 4
- 239000000356 contaminant Substances 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- 239000012855 volatile organic compound Substances 0.000 description 4
- 238000009941 weaving Methods 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 3
- -1 PAC) Substances 0.000 description 3
- 229910000805 Pig iron Inorganic materials 0.000 description 3
- 235000011941 Tilia x europaea Nutrition 0.000 description 3
- 230000004913 activation Effects 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 3
- 239000004571 lime Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 229910052753 mercury Inorganic materials 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 description 1
- GJXOQWKOTPRJET-UHFFFAOYSA-N 2,3-diphenyl-1,4-dioxine Chemical class O1C=COC(C=2C=CC=CC=2)=C1C1=CC=CC=C1 GJXOQWKOTPRJET-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004291 sulphur dioxide Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
- B01D53/685—Halogens or halogen compounds by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/81—Solid phase processes
- B01D53/83—Solid phase processes with moving reactants
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0034006A AT502375B1 (de) | 2006-02-28 | 2006-02-28 | Verfahren zur behandlung von abgas aus sinter- und pelletanlagen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW200736402A TW200736402A (en) | 2007-10-01 |
| TWI438283B true TWI438283B (zh) | 2014-05-21 |
Family
ID=37776708
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW096106594A TWI438283B (zh) | 2006-02-28 | 2007-02-27 | 處理來自燒結和造粒工廠之排氣的方法 |
Country Status (6)
| Country | Link |
|---|---|
| CN (1) | CN101394915B (fr) |
| AT (1) | AT502375B1 (fr) |
| RU (1) | RU2508159C2 (fr) |
| TW (1) | TWI438283B (fr) |
| UA (1) | UA59847U (fr) |
| WO (1) | WO2007098867A1 (fr) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009048370A1 (de) * | 2009-07-24 | 2011-01-27 | Drysotec Gmbh | Verfahren zur Behandlung von Abgasen, insbesondere aus der Stahlherstellung |
| CN101862590A (zh) * | 2010-06-30 | 2010-10-20 | 马鞍山钢铁股份有限公司 | 一种烧结烟气的脱硫工艺 |
| CN103879970B (zh) * | 2014-03-14 | 2015-09-30 | 成都华西堂投资有限公司 | 一种从烟气中回收二氧化硫制取硫磺的生产工艺 |
| CN109499295A (zh) * | 2018-12-29 | 2019-03-22 | 米凯利科技（北京）有限公司 | 干法脱硫系统 |
| CN112619388A (zh) * | 2020-11-17 | 2021-04-09 | 天津浩创节能环保设备有限公司 | 一种烟气脱硫剂制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4100645A1 (de) * | 1991-01-11 | 1992-07-16 | Hansjoerg Regler | Verfahren zur abscheidung von schadstoffen, insbesondere von sauren schadstoffen, aus gasen und abgasen |
| FR2681795B1 (fr) * | 1991-09-30 | 1993-11-19 | Solvay | Procede pour epurer un gaz contenant de l'oxyde nitrique et du dioxyde de soufre. |
| JPH0647237A (ja) * | 1992-07-28 | 1994-02-22 | Topy Ind Ltd | 電気炉排ガスダストの処理方法 |
| DE19623981A1 (de) * | 1996-06-15 | 1998-01-08 | Rheinische Braunkohlenw Ag | Verfahren zum Entfernen schädlicher Inhaltsstoffe aus Abgasen von Sinteranlagen |
| FR2751560A1 (fr) * | 1996-07-26 | 1998-01-30 | Solvay | Procede pour epurer une fumee contenant du chlorure d'hydrogene, un oxyde d'azote ou du dioxyde de soufre |
| DE19651822C2 (de) * | 1996-12-13 | 1999-02-11 | Thyssen Stahl Ag | Verfahren zur Verringerung der PCDD- und/oder PCDF-Konzentration in Abgasen |
| CN1202388A (zh) * | 1997-06-16 | 1998-12-23 | 中国科学院生态环境研究中心 | 用铝矾土进行脱硫的方法 |
| US6299848B1 (en) * | 1998-09-25 | 2001-10-09 | Hamon Research-Cottrell | Process for removing sulfur dioxide out of a gas |
| DE19856260C1 (de) * | 1998-12-07 | 2000-03-16 | Steinmueller Gmbh L & C | Verfahren zur Verringerung der Konzentration von PCDD und PCDF im Abgasstrom einer Sinteranlage und Sinteranlage zur Durchführung des Verfahrens |
| DE20210008U1 (de) * | 2002-04-16 | 2002-10-24 | MSB Müllkraftwerk Schwandorf Betriebsgesellschaft mbH, 92421 Schwandorf | Reagentien für die Reinigung von Abgasen |
| AT8227U3 (de) * | 2005-12-13 | 2006-09-15 | Voest Alpine Ind Anlagen | Verfahren und vorrichtung zur behandlung von abgas aus sinteranlagen |
-
2006
- 2006-02-28 AT AT0034006A patent/AT502375B1/de not_active IP Right Cessation
-
2007
- 2007-02-19 UA UAA200811556U patent/UA59847U/ru unknown
- 2007-02-19 WO PCT/EP2007/001396 patent/WO2007098867A1/fr not_active Ceased
- 2007-02-19 RU RU2008138582/05A patent/RU2508159C2/ru active
- 2007-02-19 CN CN2007800070854A patent/CN101394915B/zh active Active
- 2007-02-27 TW TW096106594A patent/TWI438283B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2007098867A1 (fr) | 2007-09-07 |
| AT502375B1 (de) | 2007-03-15 |
| RU2008138582A (ru) | 2010-04-10 |
| RU2508159C2 (ru) | 2014-02-27 |
| CN101394915A (zh) | 2009-03-25 |
| CN101394915B (zh) | 2012-11-07 |
| UA59847U (ru) | 2011-06-10 |
| TW200736402A (en) | 2007-10-01 |
| AT502375A4 (de) | 2007-03-15 |
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