RU2103050C1 - Способ селективного удаления сульфида водорода из газа и устройство для его осуществления - Google Patents
Способ селективного удаления сульфида водорода из газа и устройство для его осуществления Download PDFInfo
- Publication number
- RU2103050C1 RU2103050C1 RU95118712A RU95118712A RU2103050C1 RU 2103050 C1 RU2103050 C1 RU 2103050C1 RU 95118712 A RU95118712 A RU 95118712A RU 95118712 A RU95118712 A RU 95118712A RU 2103050 C1 RU2103050 C1 RU 2103050C1
- Authority
- RU
- Russia
- Prior art keywords
- gas
- solution
- hydrogen sulfide
- carbonate
- absorption
- Prior art date
Links
- 229910000037 hydrogen sulfide Inorganic materials 0.000 title claims abstract description 92
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims abstract description 88
- 239000007789 gas Substances 0.000 title claims abstract description 76
- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000010521 absorption reaction Methods 0.000 claims abstract description 73
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 72
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 66
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 39
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 37
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 36
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 31
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 16
- 238000001704 evaporation Methods 0.000 claims abstract description 15
- 230000008020 evaporation Effects 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 14
- 238000004064 recycling Methods 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 103
- 239000012670 alkaline solution Substances 0.000 claims description 14
- -1 hydrogen sulfide ions Chemical class 0.000 claims description 14
- 238000012856 packing Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 10
- 239000000126 substance Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 20
- 235000017550 sodium carbonate Nutrition 0.000 description 14
- 238000000926 separation method Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000010411 cooking Methods 0.000 description 6
- 229910021653 sulphate ion Inorganic materials 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000002745 absorbent Effects 0.000 description 4
- 239000002250 absorbent Substances 0.000 description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000005587 carbonate group Chemical group 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 229910052979 sodium sulfide Inorganic materials 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C11/00—Regeneration of pulp liquors or effluent waste waters
- D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
- D21C11/08—Deodorisation ; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
- Paper (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE9300533A SE9300533L (sv) | 1993-02-18 | 1993-02-18 | Sätt och anordning för absorption av svavelväte |
| SE9300533-8 | 1993-02-18 | ||
| PCT/SE1994/000030 WO1994019091A1 (fr) | 1993-02-18 | 1994-01-18 | Procede et appareil d'absorption d'hydrogene sulfure |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU95118712A RU95118712A (ru) | 1997-10-10 |
| RU2103050C1 true RU2103050C1 (ru) | 1998-01-27 |
Family
ID=20388935
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU95118712A RU2103050C1 (ru) | 1993-02-18 | 1994-01-18 | Способ селективного удаления сульфида водорода из газа и устройство для его осуществления |
Country Status (11)
| Country | Link |
|---|---|
| JP (1) | JPH08506993A (fr) |
| KR (1) | KR100286384B1 (fr) |
| CN (1) | CN1050527C (fr) |
| AU (1) | AU6158694A (fr) |
| BR (1) | BR9406271A (fr) |
| CA (1) | CA2156411C (fr) |
| FI (1) | FI114084B (fr) |
| PL (1) | PL180733B1 (fr) |
| RU (1) | RU2103050C1 (fr) |
| SE (1) | SE9300533L (fr) |
| WO (1) | WO1994019091A1 (fr) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE501782C2 (sv) * | 1993-09-17 | 1995-05-15 | Flaekt Ab | Sätt och anordning för att selektivt avlägsna svavelväte från en gas |
| JPH09183618A (ja) * | 1995-12-28 | 1997-07-15 | Kansai Electric Power Co Inc:The | 石膏の製造方法 |
| KR100347970B1 (ko) * | 1999-08-11 | 2002-08-07 | 대경기계기술주식회사 | 악취 가스로부터 악취 물질을 제거하기 위한 시스템 |
| KR100415917B1 (ko) * | 2001-11-14 | 2004-01-24 | 주식회사 포스코 | 황화수소 포집탑내 익스펜드 메탈 패킹 세정방법 |
| CA2455011C (fr) | 2004-01-09 | 2011-04-05 | Suncor Energy Inc. | Traitement de mousse bitumineuse par injection de vapeur en ligne |
| EA010565B1 (ru) | 2004-07-12 | 2008-10-30 | Эксонмобил Апстрим Рисерч Компани | Способ удаления содержащих серу соединений из углеводородсодержащих газов (варианты) |
| US7727374B2 (en) * | 2004-09-23 | 2010-06-01 | Skyonic Corporation | Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals |
| EP2030670A1 (fr) * | 2007-08-31 | 2009-03-04 | Intega GmbH | Procédé et appareil pour éliminer au moins un composé chalcogéné hydrogéné d'un flux de gaz d'émission |
| KR100943537B1 (ko) | 2008-05-27 | 2010-02-22 | 주식회사 애니텍 | 이산화탄소 저감기능을 겸비한 공기청정기 |
| DE102009009476A1 (de) * | 2009-02-19 | 2010-08-26 | Linde-Kca-Dresden Gmbh | Verfahren und Vorrichtung zur Reinigung eines kohlendioxidhaltigen Gasstroms |
| US8617494B2 (en) * | 2012-03-30 | 2013-12-31 | Alstom Technology Ltd | Condenser and method for cleaning flue gases |
| CN105056709A (zh) * | 2015-07-30 | 2015-11-18 | 江苏金曼科技有限责任公司 | 一种尾气处理方法 |
| CN105854549A (zh) * | 2016-05-06 | 2016-08-17 | 铜仁学院 | 一种处理含汞废气的方法 |
| KR102325084B1 (ko) * | 2019-10-04 | 2021-11-10 | 서정봉 | 어는점을 낮춘 산성 폐수 또는 산성 유해가스 중화용 조성물 |
| CN111330413A (zh) * | 2020-02-13 | 2020-06-26 | 东营联合石化有限责任公司 | 一种石油裂解气化物质脱硫装置 |
| KR200499277Y1 (ko) | 2024-09-27 | 2025-06-23 | 사회적협동조합 꿈나무 | 배전반에 내부에 탑재되는 황화수소 제거장치 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3554859A (en) * | 1968-07-10 | 1971-01-12 | British Columbia Res Council | Process for recovery of sulphur from furnaced black liquor |
| US4808264A (en) * | 1985-06-03 | 1989-02-28 | Kignell Jean Erik | Process for chemicals and energy recovery from waste liquors |
| US4872950A (en) * | 1986-11-28 | 1989-10-10 | Andersson Alf Ove | Process for recovering energy and chemicals from spent liquor in pulp preparation |
| EP0459962A1 (fr) * | 1990-05-31 | 1991-12-04 | Chemrec Aktiebolag | Procédé de purification du produit gazeux obtenu lors de la combustion partielle de la liqueur noire |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE319078B (fr) * | 1968-06-07 | 1969-12-22 | British Columbia Res Council | |
| US5284550A (en) * | 1992-06-18 | 1994-02-08 | Combustion Engineering, Inc. | Black liquier gasification process operating at low pressures using a circulating fluidized bed |
-
1993
- 1993-02-18 SE SE9300533A patent/SE9300533L/ not_active Application Discontinuation
-
1994
- 1994-01-18 PL PL94310320A patent/PL180733B1/pl not_active IP Right Cessation
- 1994-01-18 JP JP6518871A patent/JPH08506993A/ja active Pending
- 1994-01-18 KR KR1019950703518A patent/KR100286384B1/ko not_active Expired - Fee Related
- 1994-01-18 CA CA002156411A patent/CA2156411C/fr not_active Expired - Fee Related
- 1994-01-18 RU RU95118712A patent/RU2103050C1/ru not_active IP Right Cessation
- 1994-01-18 AU AU61586/94A patent/AU6158694A/en not_active Abandoned
- 1994-01-18 BR BR9406271A patent/BR9406271A/pt not_active IP Right Cessation
- 1994-01-18 CN CN94191218A patent/CN1050527C/zh not_active Expired - Fee Related
- 1994-01-18 WO PCT/SE1994/000030 patent/WO1994019091A1/fr not_active Ceased
-
1995
- 1995-08-17 FI FI953882A patent/FI114084B/fi not_active IP Right Cessation
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3554859A (en) * | 1968-07-10 | 1971-01-12 | British Columbia Res Council | Process for recovery of sulphur from furnaced black liquor |
| US4808264A (en) * | 1985-06-03 | 1989-02-28 | Kignell Jean Erik | Process for chemicals and energy recovery from waste liquors |
| US4872950A (en) * | 1986-11-28 | 1989-10-10 | Andersson Alf Ove | Process for recovering energy and chemicals from spent liquor in pulp preparation |
| EP0459962A1 (fr) * | 1990-05-31 | 1991-12-04 | Chemrec Aktiebolag | Procédé de purification du produit gazeux obtenu lors de la combustion partielle de la liqueur noire |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100286384B1 (ko) | 2001-04-16 |
| SE9300533D0 (sv) | 1993-02-18 |
| PL180733B1 (pl) | 2001-03-30 |
| KR960700799A (ko) | 1996-02-24 |
| WO1994019091A1 (fr) | 1994-09-01 |
| FI953882A0 (fi) | 1995-08-17 |
| PL310320A1 (en) | 1995-12-11 |
| CA2156411A1 (fr) | 1994-09-01 |
| SE9300533L (sv) | 1994-08-19 |
| CN1118146A (zh) | 1996-03-06 |
| FI953882A7 (fi) | 1995-08-17 |
| AU6158694A (en) | 1994-09-14 |
| FI114084B (fi) | 2004-08-13 |
| BR9406271A (pt) | 1996-01-02 |
| JPH08506993A (ja) | 1996-07-30 |
| CN1050527C (zh) | 2000-03-22 |
| CA2156411C (fr) | 2004-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20050119 |