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WO1994019091A1 - Procede et appareil d'absorption d'hydrogene sulfure - Google Patents

Procede et appareil d'absorption d'hydrogene sulfure Download PDF

Info

Publication number
WO1994019091A1
WO1994019091A1 PCT/SE1994/000030 SE9400030W WO9419091A1 WO 1994019091 A1 WO1994019091 A1 WO 1994019091A1 SE 9400030 W SE9400030 W SE 9400030W WO 9419091 A1 WO9419091 A1 WO 9419091A1
Authority
WO
WIPO (PCT)
Prior art keywords
solution
gas
stage
carbonate
sulphide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SE1994/000030
Other languages
English (en)
Inventor
Erik Simonson
Mats Wallin
Sune Bengtsson
Erik Dahlqvist
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ABB Technology FLB AB
Original Assignee
ABB Flaekt AB
Flaekt AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU61586/94A priority Critical patent/AU6158694A/en
Priority to JP6518871A priority patent/JPH08506993A/ja
Priority to PL94310320A priority patent/PL180733B1/pl
Priority to CA002156411A priority patent/CA2156411C/fr
Priority to RU95118712A priority patent/RU2103050C1/ru
Priority to BR9406271A priority patent/BR9406271A/pt
Priority to KR1019950703518A priority patent/KR100286384B1/ko
Priority to US08/505,338 priority patent/US6306357B1/en
Application filed by ABB Flaekt AB, Flaekt AB filed Critical ABB Flaekt AB
Publication of WO1994019091A1 publication Critical patent/WO1994019091A1/fr
Priority to SE9502814A priority patent/SE510644C2/sv
Priority to FI953882A priority patent/FI114084B/fi
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/06—Treatment of pulp gases; Recovery of the heat content of the gases; Treatment of gases arising from various sources in pulp and paper mills; Regeneration of gaseous SO2, e.g. arising from liquors containing sulfur compounds
    • D21C11/08—Deodorisation ; Elimination of malodorous compounds, e.g. sulfur compounds such as hydrogen sulfide or mercaptans, from gas streams
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10—Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Definitions

  • a hydroxide preferably a sodium hydroxide solution
  • a hydroxide solution may be supplied to the collecting vessels 19, 20 and 21 through conduits 26, 27 and 28, respectively, conducting alkali from a supply (not shown), which pre ⁇ ferably is common all the conduits.
  • the supply of sodium- hydroxide solution for adjusting the pH of the absorption solution is regulated on the basis of the measured pH values of the solutions in the collecting vessels 19, 20 and 21 (not shown).

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Paper (AREA)

Abstract

Procédé et appareil d'évaporation de liqueurs noires, servant à éliminer sélectivement, par absorption de liquide, l'hydrogène sulfuré compris dans le gaz produit (3) renfermant de l'hydrogène sulfuré ainsi que du gaz carbonique. Selon le procédé, on met le gaz en écoulement en contact, de préférence sur trois étages (6, 7, 8), avec des solutions alcalines contenant du carbonate et s'écoulant dans un sens contraire à celui du gaz, ces solutions étant de préférence des solutions de carbonate de sodium (25) dont on règle le pH pendant l'absorption de sorte qu'il soit compris entre 9 et 12, cela par adjonction d'un hydroxyde, de préférence une solution d'hydroxyde de sodium (26, 27, 28). De préférence, l'écoulement du gaz est turbulent et celui du liquide est laminaire lorsque le gaz et le liquide entrent en contact l'un avec l'autre. L'appareil comporte un récipient (1) muni d'un orifice (2) d'admission de gaz, d'un orifice (4) de décharge de gaz, et d'un corps de remplissage (9) placé sur plusieurs étages successifs (6, 7, 8). L'appareil possède un dispositif (25) d'alimentation du dernier étage en une solution contenant du carbonate et s'écoulant dans un sens contraire à celui du gaz, et de recyclage de la solution entre l'entrée et la sortie de cet étage; des conduits (29, 30) disposés entre les étages et destinés à renvoyer une partie de la solution en écoulement de l'un des étages à l'étage précédent; des dispositifs (26, 27, 28) d'alimentation en hydroxyde de la solution contenant du carbonate et se trouvant dans l'un au moins des étages (6, 7, 8); et un conduit d'évacuation (31) situé au niveau du premier étage dans le sens d'alimentation du gaz, et destiné à décharger un liquide renfermant du sulfure.
PCT/SE1994/000030 1993-02-18 1994-01-18 Procede et appareil d'absorption d'hydrogene sulfure Ceased WO1994019091A1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US08/505,338 US6306357B1 (en) 1994-01-18 1994-01-18 Process and apparatus for absorbing hydrogen sulphide
JP6518871A JPH08506993A (ja) 1993-02-18 1994-01-18 硫化水素の吸収方法および装置
PL94310320A PL180733B1 (pl) 1993-02-18 1994-01-18 Sposób i urzadzenie do absorpcji siarkowodoru PL PL
CA002156411A CA2156411C (fr) 1993-02-18 1994-01-18 Methode et appareil pour l'absorption de sulfure d'hydrogene
RU95118712A RU2103050C1 (ru) 1993-02-18 1994-01-18 Способ селективного удаления сульфида водорода из газа и устройство для его осуществления
AU61586/94A AU6158694A (en) 1993-02-18 1994-01-18 Process and apparatus for absorbing hydrogen sulphide
KR1019950703518A KR100286384B1 (ko) 1993-02-18 1994-01-18 황화수소를 흡수하기 위한 방법 및 장치
BR9406271A BR9406271A (pt) 1993-02-18 1994-01-18 Processo e aparelho para absorção de sulfeto de hidrogênio
SE9502814A SE510644C2 (sv) 1993-02-18 1995-08-11 Sätt och anordning för absorption av svavelväte vid svartlutsförgasning
FI953882A FI114084B (fi) 1993-02-18 1995-08-17 Menetelmä ja laitteisto rikkivedyn absorboimiseksi

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9300533-8 1993-02-18
SE9300533A SE9300533L (sv) 1993-02-18 1993-02-18 Sätt och anordning för absorption av svavelväte

Publications (1)

Publication Number Publication Date
WO1994019091A1 true WO1994019091A1 (fr) 1994-09-01

Family

ID=20388935

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SE1994/000030 Ceased WO1994019091A1 (fr) 1993-02-18 1994-01-18 Procede et appareil d'absorption d'hydrogene sulfure

Country Status (11)

Country Link
JP (1) JPH08506993A (fr)
KR (1) KR100286384B1 (fr)
CN (1) CN1050527C (fr)
AU (1) AU6158694A (fr)
BR (1) BR9406271A (fr)
CA (1) CA2156411C (fr)
FI (1) FI114084B (fr)
PL (1) PL180733B1 (fr)
RU (1) RU2103050C1 (fr)
SE (1) SE9300533L (fr)
WO (1) WO1994019091A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5798087A (en) * 1995-12-28 1998-08-25 Kansai Electric Power Co., Inc. Method of producing gypsum
CN1066634C (zh) * 1993-09-17 2001-06-06 Abb.弗拉克特有限公司 吸收硫化氢的方法和设备
EP2030670A1 (fr) * 2007-08-31 2009-03-04 Intega GmbH Procédé et appareil pour éliminer au moins un composé chalcogéné hydrogéné d'un flux de gaz d'émission
US7556715B2 (en) 2004-01-09 2009-07-07 Suncor Energy, Inc. Bituminous froth inline steam injection processing
US7662215B2 (en) 2004-07-12 2010-02-16 Exxonmobil Upstream Research Company Methods for removing sulfur-containing compounds
WO2010094437A3 (fr) * 2009-02-19 2011-09-15 Linde-Kca-Dresden Gmbh Procédé et dispositif d'épuration d'un flux gazeux contenant du dioxyde de carbone

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100347970B1 (ko) * 1999-08-11 2002-08-07 대경기계기술주식회사 악취 가스로부터 악취 물질을 제거하기 위한 시스템
KR100415917B1 (ko) * 2001-11-14 2004-01-24 주식회사 포스코 황화수소 포집탑내 익스펜드 메탈 패킹 세정방법
US7727374B2 (en) * 2004-09-23 2010-06-01 Skyonic Corporation Removing carbon dioxide from waste streams through co-generation of carbonate and/or bicarbonate minerals
KR100943537B1 (ko) 2008-05-27 2010-02-22 주식회사 애니텍 이산화탄소 저감기능을 겸비한 공기청정기
US8617494B2 (en) * 2012-03-30 2013-12-31 Alstom Technology Ltd Condenser and method for cleaning flue gases
CN105056709A (zh) * 2015-07-30 2015-11-18 江苏金曼科技有限责任公司 一种尾气处理方法
CN105854549A (zh) * 2016-05-06 2016-08-17 铜仁学院 一种处理含汞废气的方法
KR102325084B1 (ko) * 2019-10-04 2021-11-10 서정봉 어는점을 낮춘 산성 폐수 또는 산성 유해가스 중화용 조성물
CN111330413A (zh) * 2020-02-13 2020-06-26 东营联合石化有限责任公司 一种石油裂解气化物质脱硫装置
KR200499277Y1 (ko) 2024-09-27 2025-06-23 사회적협동조합 꿈나무 배전반에 내부에 탑재되는 황화수소 제거장치

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE319078B (fr) * 1968-06-07 1969-12-22 British Columbia Res Council
SE448173B (sv) * 1985-06-03 1987-01-26 Croon Inventor Ab Forfarande for utvinning av kemikalier fran cellulosaavlut genom pyrolys
EP0459962A1 (fr) * 1990-05-31 1991-12-04 Chemrec Aktiebolag Procédé de purification du produit gazeux obtenu lors de la combustion partielle de la liqueur noire
WO1993025751A1 (fr) * 1992-06-18 1993-12-23 Combustion Engineering, Inc. Appareil et processus de gazeification de liqueur noire par lit fluidise a circulation

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3554859A (en) * 1968-07-10 1971-01-12 British Columbia Res Council Process for recovery of sulphur from furnaced black liquor
SE462106B (sv) * 1986-11-28 1990-05-07 Alf Ove Andersson Saett att utvinna energi och kemikalier ur avlut fraan massaberedning

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE319078B (fr) * 1968-06-07 1969-12-22 British Columbia Res Council
SE448173B (sv) * 1985-06-03 1987-01-26 Croon Inventor Ab Forfarande for utvinning av kemikalier fran cellulosaavlut genom pyrolys
EP0459962A1 (fr) * 1990-05-31 1991-12-04 Chemrec Aktiebolag Procédé de purification du produit gazeux obtenu lors de la combustion partielle de la liqueur noire
WO1993025751A1 (fr) * 1992-06-18 1993-12-23 Combustion Engineering, Inc. Appareil et processus de gazeification de liqueur noire par lit fluidise a circulation

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1066634C (zh) * 1993-09-17 2001-06-06 Abb.弗拉克特有限公司 吸收硫化氢的方法和设备
US5798087A (en) * 1995-12-28 1998-08-25 Kansai Electric Power Co., Inc. Method of producing gypsum
US7556715B2 (en) 2004-01-09 2009-07-07 Suncor Energy, Inc. Bituminous froth inline steam injection processing
US7662215B2 (en) 2004-07-12 2010-02-16 Exxonmobil Upstream Research Company Methods for removing sulfur-containing compounds
EP2030670A1 (fr) * 2007-08-31 2009-03-04 Intega GmbH Procédé et appareil pour éliminer au moins un composé chalcogéné hydrogéné d'un flux de gaz d'émission
WO2009027534A1 (fr) * 2007-08-31 2009-03-05 Intega Gmbh Procédé et appareil pour éliminer d'un courant de gaz d'échappement au moins un composé hydrogène-chalcogène
WO2010094437A3 (fr) * 2009-02-19 2011-09-15 Linde-Kca-Dresden Gmbh Procédé et dispositif d'épuration d'un flux gazeux contenant du dioxyde de carbone
US20120031269A1 (en) * 2009-02-19 2012-02-09 Linde-Kca-Dresden Gmbh Method and device for purifying a gas stream containing carbon dioxide

Also Published As

Publication number Publication date
CA2156411A1 (fr) 1994-09-01
CN1118146A (zh) 1996-03-06
KR100286384B1 (ko) 2001-04-16
SE9300533D0 (sv) 1993-02-18
AU6158694A (en) 1994-09-14
CN1050527C (zh) 2000-03-22
PL310320A1 (en) 1995-12-11
SE9300533L (sv) 1994-08-19
RU2103050C1 (ru) 1998-01-27
CA2156411C (fr) 2004-05-11
JPH08506993A (ja) 1996-07-30
PL180733B1 (pl) 2001-03-30
BR9406271A (pt) 1996-01-02
KR960700799A (ko) 1996-02-24
FI114084B (fi) 2004-08-13
FI953882A7 (fi) 1995-08-17
FI953882A0 (fi) 1995-08-17

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