RU2038367C1 - Detergent for washing textile materials - Google Patents

Abstract

FIELD: domestic chemistry. SUBSTANCE: the detergent comprises (wt): 1- 20 a mixture of anoinic and nonionic surfactants; 5-10 complexing composition (diphonate); 0.1-10 zeolite and/or 10-20 sodium tripolyphosphate; 3-8 liquid soda glass; 15- 20 sodium peroxoborate; 0.05-0.2 disodium salt of ethylene diamine tetracetic acid; 0.09-0.15 optical bleaching agent; 0.5-1.5 sodium carboxymethyl cellulose; 0.001-1 complex CO₂-extract or hydrophytoconcentrate made of daisy and carrot seeds, or complex CO₂ extract or hydrophytoconcentrate made of daisy, carrot seeds and rice waste; 0.001-1 CO₂-extract or hydrophytoconcentrate made of millet meal or CO₂-extract or hydrophytoconcentrate made of hemp; 0.001-0.5 CO₂-extract or hydrophytoconcentrate made of fir; 0.05-0.2 aroma; up to 100 sodium sulfate and water. EFFECT: improved properties of the detergent. 4 tbl

Description

 The invention relates to household chemicals and for the production of detergents.

 Known formulations of detergent compositions containing anionic surfactants, bleaches, water-alcohol-glycerin plant extracts, perfume and other special additives.

Known detergent that provides increased foaming, foam resistance, reducing the degreasing effect of the agent on the skin, as well as giving the agent regenerative properties, which contains, sulfoethoxylates 6.0-9.0; fatty acid diethanolamides C ₁₀ -C ₁₃ 1.0-3.0; triethanolamine salt of lauryl sulfate 2.0-4.0; citric acid 0.05-0.5; sodium chloride 0.1-1.5; synthetic pine oil 1.0-2.0; preservative 0.2-0.4; water-alcohol-glyceric extract of yarrow 0.1-0.3; mummy extract 0.2-0.4; dye 0.007-0.018; perfume 0.1-2.5; water the rest. [1]
Proposed a detergent with washing obtbelivayuschim action and whitening natural and synthetic fabrics mixed at 40-60 ^{° C,} characterized in that it comprises (h.): 8-20 anionic surfactants, such as Na alkylaryl sulfonate, alkyl sulfate Na, α alpha-olefinsulfonates Na or a mixture thereof; 20-38 polyphosphates, for example, sodium tripolyphosphate, Na hydrogen phosphate or a mixture thereof in a ratio of 3: 1 to 4: 1; 16-28 hydrosulphuric Na, 0.1-8 Na ₂ Co ₃ or 0.1-4 Na-salt of ethylenediaminetetraacetic acid 3-10 NaCl, 0.1-0.5 whitening preparation; 1-3 CMC; 9-21 Na ₂ SO ₄ 0.2-0.7 perfumes (2).

Closest to the claimed detergent "Lily of the valley" having the following composition, wt. Surface-active substances (in terms of 100% of the basic substance), including: 16.0 a) Alkylbenzenesulfonates: sulfonol, 40% solution obtained from N-paraffins 12.0 or Sulfonol, 45% solution b) Oxyethylated fatty alcohols: 2.0-3.0 Sintanol ALM-10 or Sintanol ACSE-12 or Sintanol DS-10 or Sintamid-5 c) Soap powder 1.0-2.0 or soap shavings or soap of fatty acids, including 0.9
Fatty Acids
tetic fractions
C ₁₇ -C ₂₀ or
Fatty acids
nicholas
(distilled)
or their mixture and
Technical caustic soda
cue (in terms of
100% of the main substance) for saponification of fatty acids 0.1 Diphonate 8.0 Zeolite Na-A 0.1-10.0 Sodium liquid glass (in terms of SiO ₂ ) 5.0 Sodium tripolyphosphate technical 10.0-20.0 Peroxoborate (perborate) sodium 20.0 Disodium salt of ethylenediaminetetraacetic acid (Trilon B) (in terms of 100% of the main substance), technical 0.1
or ethylenediaminetetraacetic acid (in terms of 100% of the main substance) Optical bleaches: 0.15 Belofor KD-2 conc. or Belofor KD-2 N or Rilyuks D or Rilyuks RR or Vobital ZBT Perfumery fragrance for soap and SMS 0.1 Sodium carboxymethyl cellulose technical and purified (in terms of 100% of the main substance) of grade 70/300, 75 / 400 1,2 Technical sodium sulfate (w / s) or crystallization sodium sulfate and water Up to 100 [3]
Synthetic detergent "Lily of the valley" is produced by the Moscow factory of synthetic detergents. This is a low-phosphate low-foaming SMS. Contains peroxide salts, has a high washing ability in soft and hard water. Non-toxic and environmentally friendly.

 However, all nonionic surfactants in relation to the skin have a strong detergent effect. They negatively affect the condition of the skin, fat components are especially easily removed, which is accompanied by a sensation of excessive dryness of the skin. In addition, they irritate and inhibit the skin glands, causing inflammatory processes.

 In connection with the creation of a new tool, it is advisable to consider the function of the so-called "overweight" additives. Their presence in the detergent formulation in a solubilized form can significantly reduce the extraction of lipid components and have a gelling effect on the skin. The intensive exchange of fatty contaminants and solubilizate between the surface of the skin and surfactant micelles makes it possible to purposefully replace some of the natural lipids with synthetic ones to ensure greater elasticity and smoothness of the skin. Detergents should not cause excessive dryness, a feeling of tightness after washing.

 The present invention solves the problem of obtaining a detergent that reduces allergic reactions and supports turgor and a healthy tone of soft tissues and epidermis of the skin of the hands.

The goal is achieved by the fact that in the proposed detergent containing a mixture of anionic and nonionic surfactants, diphonate, liquid sodium glass, zeolite and / or sodium tripolyphosphate, sodium peroxoborate, disodium salt of ethylenediaminetetraacetic acid, optical brightener, sodium carboxymethyl sulfonate water additionally introduced integrated or CO ₂ extract of chamomile gidrofitokontsentrat and carrot seeds or integrated CO ₂ extract or gidrofitokontsentrat chamomile, carrot seed, and isovyh waste CO ₂ extract or gidrofitokontsentrat millet mucheli or CO ₂ extract or gidrofitokontsentrat hemp, CO ₂ extract gidrofitokontsentrat or fir in the following ratio, wt. A mixture of anionic and nonionic surfactants 10-20 Diphonate 5-10 Zeolite and / or 0.1-10 Sodium tripolyphosphate 10-20 Sodium liquid glass 3-8 Sodium peroxoborate 15-20 Disodium salt of ethylenediaminetetra-acetic acid 0.05-0.2 Optical bleach 0.05-0.15 Sodium carboxymethyl cellulose 0.5-1.5 Complex CO ₂ - extract or hydrophytoconcentrate from chamomile and carrot seeds or complex CO ₂ - ekst- pAKT or gidrofito- romash- ki concentrate, carrot seeds and rice waste 0.001-1.0 CO ₂ extract or hydro rofitokontsentrat millet mucheli Whether the CO ₂ extract or hydro rofitokontsentrat hemp 0.001-1.0 CO ₂ extract or hydro rofitokontsentrat fir 0.001-0.5 Perfume 0.05-0.2 Sodium sulfate and water Up to 100
To mitigate the undesirable effects of surfactants, various biostimulants of metabolic processes, over-the-counter additives, nutrients, soothing and healing ingredients are added to detergent formulations. Plant hormones, unlike synthetic and animals, as natural regulators of metabolic processes, have an antioxidant and anti-degreasing effect, do not irritate the skin, do not cause allergies, increase blood circulation, and maintain normal skin tone. All this indicates the advisability of using plant extracts in detergents as containing the optimal set of plant biologically active substances and vitamins in a natural solvent, fat-like substances of plants.

Comparative analysis with the prototype allows us to conclude that the claimed composition of the detergent differs from the known one by the introduction of new components - individual and complex CO ₂ extracts (or their hydrophytoconcentrates) that reduce skin dryness due to lipoid enrichment of the skin with natural vegetable fats with a natural smell of chamomile and fir.

When using a product made according to the proposed recipe, in soapy water and foam, complex CO ₂ extracts N 21 or N 27, CO ₂ extract of millet flour or CO ₂ extract of hemp and CO ₂ extract of fir are in a molecularly dispersed state and therefore, they have an increased ability to affect the skin and penetrate the pores of the skin, increasing the vitamins of the skin of the hands, which largely prevents dry skin and irritation.

The properties of complex CO ₂ extracts are due to the creation of a mixture of the individual ingredients of the raw materials at the stage of preparation and extraction in certain proportions with liquid carbon dioxide with a moisture content of not more than 12% under pressure. They are either oily liquids or ointment-like substances that dissolve in vegetable oils, various solvents, surfactants, etc.

 Hydrophytoconcentrates for SMS are obtained from waste from various food industries or from meal after CO extraction by grinding raw materials, isolating the hydrophilic fraction and drying with an adsorbent, which is used as a mixture of structure-forming and surfactants (a mixture of CMC or Na-CMC, or gelatin or gelatinized starch or the like with sodium lauryl sulfate or oleate or stearate and the like).

Complex CO ₂ extract from carrot seeds and chamomile pharmacy (N 21), is a complex mixture combining the properties of chamomile and carrot seeds, contains azulenogens, carotene, tocopherols, phytosterols, essential oil, fatty oil, polyunsaturated fatty acids (vitamin F factor )

 Complex biostimulant is a vitamin complex of plasticizing, regenerating and nourishing effects. Biologically active substances included in the complex biostimulant No. 21 provide anti-inflammatory, anti-allergic, epithelizing, bactericidal effect of the extract, corresponds to TU 10.048549-043-91.

Integrated CO ₂ extract N 27 from chamomile seeds, rice waste and carrot seeds is a complex mixture combining the properties of carrot seeds, rice waste and chamomile. Conforms to TU 10.048549-009-90.

 Contains a mixture of biologically active substances and aromatic compounds tocopherols, waxes and wax-like substances, carotenoids, azulenogens, essential and fatty oils. In essential oil, the most valuable component is azulene. In fatty unsaturated fatty acids, the factor of vitamin F. In total, all valuable components provide anti-inflammatory, plasticizing, wound healing effects.

 Chamomile contains an essential oil consisting of the main biologically active substance of chamazulene, its precursor prochamazulene and other monoterpenes and sesquiterpenes. Of the sesquiterpenes, the lactones of the matrix and matricarin are of paramount importance. in the process of processing raw materials, chamazulene is also formed from them. Sesquiterpene hydrocarbons (farnesene and cadinene), sesquiterpene alcohols (bisabolol), caprylic acid are found in essential oil. The flowers of the plant contain flavonoids, coumarin, sitosterol, choline, carotene, ascorbic acid, isovalerianic and other organic acids and polysaccharides.

 Chamomile extractives is a complex multicomponent mixture of active substances of a lipoid, terpenoid nature. The lipoid fraction of this extract contains, waxes 5-7, free and bound acids 5.4-10; phytosterols (vitamin D) 1-1.2, tocopherols 0.09-0.11, carotenoids 0.011-0.03. The presence of other biologically active substances of the components of essential oil and essential fatty acids linoleic and linolenic enhances the overall effect of chamomile extract. Extractive substances of chamomile are a biologically active complex of anti-inflammatory, anti-allergic and disinfectant effects. Carrot seeds contain essential (2.47-5.66%) and fatty oils, flavonoids and other chemical compounds. Terpenes such as citral, caratol, daucol, azaron, cineole, α-pinene and l-limonene are isolated from essential oil.

 17 substances were found in the composition of the essential oil, but the main part of it is geraniol alcohol and its ether geranyl acetate, the content of which ranges from 30 to 70%. In addition to the essential oil, carrot fruits include flavonoids and fatty oil up to 11-13%. Fatty oil contains palmitic and linoleic glycerides oleic acid.

 Extractives of carrot seeds is a vitamin complex of plasticizing, regenerating and nourishing action, which contains free acids and acidic components of esters up to 49, tocopherols up to 0.02, sterols 0.42, carotenoids 0.002, phospholipids. Its value is also determined by the biologically active polyunsaturated fatty acids linoleic and linolenic (vitamin F factor).

 Extractive substances of rice waste (rice flour) are a complex of substances of hydratant, plasticizing and overriding action, containing free and fatty acids 11.7; unsaponifiable fraction 27.3, saponifiable fraction 39.0; waxes 0.6; tocopherols 0.007.

A complete or partial replacement of complex CO ₂ -extracts N 21 or N 27 is possible with powder hydrophytoconcentrates of the same blends of plant materials. The introduction of hydrophytoconcentrates prepared using sodium carboxymethyl cellulose as an adsorbent of water-soluble components of plants simplifies the introduction of biologically active substances in the detergent formulation.

The CO ₂ -extract of millet flour has a highly active biological effect, because it contains almost all biologically active substances.

 Unsaturated fatty acids comprise 89.48% of which 64.08% linoleic acid. Unsaponifiable substances comprise: 9.5-10.5% pigments (carotenoids) 3.1-3.6% ergosterol 11.5-12.6% stigmasterol 9.2-9.7% milyacinpentacyclic terpenoid 8.5-9, 2% The composition of the vitamins of the extract includes carotene, xanthophyll, tocopherol.

 The processes of inflammation complicated by the bacterial flora proceed more favorably under the action of biologically active substances of millet torch due to increased growth of granulation, improved epithelization.

The biologically active substances of the CO ₂ extract of millet flour are stimulating the permeability of blood vessels and skin cells, contribute to the accelerated entry of pharmacologically active and lipoid constituents of extracts into skin cells, help accelerate the healing process of wounds, and stabilize the skin condition with eczema.

An equivalent substitute for the CO ₂ extract of millet flour is the CO ₂ extract of hemp sowing, containing up to 50% fatty oil, consisting mainly of glycerides of unsaturated acids (linoleic, linolenic and butyric), vitamin K, cholesterol, etc. which gives the extract an anti-inflammatory, analgesic effect.

Hydrophytoconcentrates of these plants, exhibiting vitaminizing, nourishing properties, contain water-soluble vitamins, mucus, tannins and bitter substances, plant hormones, proteins, i.e. these dietary supplements can be a substitute (partial or complete) for CO ₂ extracts.

CO ₂ -extract of fir is an oily liquid with a pronounced aroma inherent in needles. The aroma of the extract is determined by the content of a significant amount of essential oil in it, the main components of which are free borneol and bornyl acetate.

CO ₂ -extract of fir is a biologically active complex, which includes essential oil, sterols, waxes, carotenoids, vitamins E, F, trace elements, resins, terpenes.

Essential oil of fir extract and terpenes contained in it act slightly irritating on the skin, which helps to strengthen local blood circulation and, thus, has a beneficial effect on metabolic processes in the skin. Components of fir essential oil CO ₂ extract such as borneol, camphene, borne acetate act on the body as an analgesic. The amount of extract introduced into the detergent formulation has a general tonic effect on the body.

In addition, the essential oil of CO ₂ -extract of fir has antimicrobial, bactericidal and hemostatic properties. Fir oil in small doses stimulates the body's defenses.

Vitamin F contained in the CO ₂ extract is involved in fat metabolism, has a positive effect on carbohydrate metabolism, enhances the lipolytic activity and regenerative ability of the epidermis, and activates local blood and lymph circulation. Vitamin F promotes fat absorption. Its deficiency leads to dryness and peeling of the skin.

Carotenoids CO ₂ extract of fir involved in metabolic processes in the skin, in redox processes. Carotenoids positively affect the elasticity of the skin, reduce sweating and sebum secretion. They protect the skin from dryness. Carotenoids are easily absorbed by the skin and renew it, promoting metabolism.

Tocopherols (Vitamin F) CO ₂ -extract of fir increase the effect and absorption of carotenoids by the skin.

The presence of micronutrients in the CO ₂ extract of fir together with the vitamin complex creates the conditions for the mutual penetration of phytohormones and for their action on the skin of the hands.

The resinous substances CO ₂ -extracts of fir dissolve well in lipids and are able to penetrate deeply into the skin, irritating its receptors and causing reflex changes in the body. Thus, they are able to have a stimulating, tonic, slightly stimulating effect on the central nervous system. In addition, they exhibit bactericidal and antiseptic properties.

 Detergents are complex mixtures. They consist of a synthetic detergent and additional inorganic and organic components that increase the effectiveness of the main detergent.

 Surfactants of detergents, adsorbing at phase boundaries and forming aggregates (micelles), play an important role in the dispersion and dissolution of contaminants, in foaming, etc. But one detergent cannot provide high quality washing of fabrics.

 As complexones, sodium tripolyphosphate, zeolite Na-A and diphonate are introduced into the composition of the developed formulation, the functions of which are to soften hard water. This occurs due to the binding of alkaline-earth and heavy metal ions to water-soluble complexes. Zeolites are microporous Na-A aluminosilicates of crystalline structure with high ion exchange ability and very small particle sizes.

 In order to reduce the environmental impact, a complex-forming composition diphonate based on partially substituted sodium salts of aminomethylphosphonic, hydroxyethylidene diphosphonic, phosphorous hydrochloric acids has been introduced into detergents.

The combination of complexing substances of CO ₂ extracts or hydrophytoconcentrates with sodium tripolyphosphate and diphonate enhances their overall positive effect. Corrosion inhibitor of aluminum, cast iron, brass and other metals caused by detergents is sodium glass. Due to it, the optimal pH of detergent solutions is maintained, and the acidity of the laundry is neutralized. Liquid glass helps to improve the drying of detergent compositions and to obtain free-flowing powders.

 Sodium sulfate used in the manufacture of synthetic detergents serves as a neutral filler.

 For chemical destruction of contaminants, sodium perborate is used. The whitening effect of hydrogen peroxide is due to the perhydroxyl ion. With increasing pH of the medium, the bleaching rate increases, but at the same time, there is a danger of oxidative destruction of cellulose fibers. When washing with detergents containing such bleaches, some damage to the fabric fibers occurs. To increase the stability of peroxide solutions, the trilon B stabilizer is used. This peroxide salt stabilizer protects tissue fibers from damage, slowing the release of active oxygen.

Contaminants that are well removed by detergents are poorly retained by them in solution. Due to the combination of impurities on the fabric, during numerous washes it acquires a gray tint. To eliminate it, sodium carboxymethyl cellulose is used as an antiresorption agent. Due to the numerous carboxyl groups in the Na molecule, CMC has a large electronegative charge, which leads to strong electrostatic repulsion between the fiber and the contamination. A strong loosening of the contamination occurs, as a result, it is easily removed during washing. The introduction of waxes with CO ₂ extracts and an additional amount of Na CMC with complexing agents of hydrophytoconcentrates enhances the retention of contaminants in the aquatic environment and facilitates their rapid leaching from tissue fibers.

 Optical whitening substances are luminescent dyes, these are slightly colored organic compounds that can absorb ultraviolet rays. The whitening effect of optical brighteners is based on the fact that the blue fluorescence light emitted by them compensates for the lack of blue rays in the light reflected from the yellowish fabric. Fabrics treated with a small amount of optical brightener acquire a high degree of whiteness.

 Due to the ability of chamomile prochamazulenes to absorb ultraviolet rays in aqueous solutions in the region of 300-400 mmk and convert them to blue or violet color with a wavelength of 400-500 mmk, the introduction of chamomile extractives enhances the whitening effect of chemical bleach and reduces its harmful effect on the skin of the hands .

 In order to determine the dosages of the components of the claimed composition, a series of experiments was conducted with the preparation of various mixtures of ingredients. The result of processing the obtained data was the justification of the selected combination of components and their boundary values.

, где Р_э дозировка экстракта,
Р_БАВ дозировка биологически активных компонентов,
С_БАВ концентрация БАВ в экстрактах,
Дозировки комплексных СО₂-экстрактов N 21 или N 27, СО₂-экстракта просяной мучели или СО₂-экстракта конопли, СО₂-экстракта пихты принята от содержания в них биологически активных веществ каротиноидов, токоферолов, витаминов и существующих пределов их внесения в моющие средства. Изменение дозировок остальных компонентов порошка принято в соответствии с принятыми нормами их внесения в различные косметические продукты.The preliminary composition of the formulation was selected based on the properties of the individual components in combination, providing a high washing effect, maintaining turgor and a healthy tone of soft tissues and epidermis of the skin. Dosages of the introduced ingredients are determined by the formula:
P _e =

where P _{e the} dosage of the extract,
R _BAS dosage of biologically active components,
With _{biologically active substances, the} concentration of biologically active substances in extracts,
Dosages of complex CO ₂ extracts N 21 or N 27, CO ₂ extract of millet flour or CO ₂ extract of hemp, CO ₂ extract of fir are taken from the content of biologically active substances carotenoids, tocopherols, vitamins and the existing limits of their application to detergents facilities. Changing the dosages of the remaining components of the powder is taken in accordance with the accepted standards for their introduction into various cosmetic products.

Effect of dose integrated CO ₂ extracts of camomile or gidrofitokontsentrata and carrot seed or extract of an integrated CO ₂ or gidrofitokontsentrata of chamomile, carrot seeds and rice waste CO ₂ extract of millet or gidrofitokontsentrata mucheli or CO ₂ extract of cannabis or gidrofitokontsentrata, CO ₂ -extract or hydrophytoconcentrate of fir and surfactant mixture on the physicochemical parameters of detergent and the content of valuable biologically active substances was studied using mathematical planning according to the scheme ogonalnyh Latin rectangles for the four factors at four levels.

Based on the matrix, taking into account the selected concentration levels of complex CO ₂ -extracts N 21 or N 27 (or their GFK), CO ₂ -extract of millet flour or CO ₂ -extract of hemp (or their GFK), CO ₂ -extract or GFK of fir and a mixture of surfactants was drawn up experiment plan.

The investigated parameters for assessing the quality of detergent were physical and chemical indicators:
hydrogen indicator; washing ability (OST 6-15-1574-87) foaming ability (TU 6-39-23-90)
the content of tocopherols.

The essence of the method for determining the washing ability of SMS is a comparative assessment of the washing ability of the test detergent and the composition of the comparison. Washing ability was defined as the ratio of the degree of removal of contamination on cotton fabric with the solution of the test detergent to the degree of removal of pollution on the same fabric, under the same conditions of washing with the standard solution. The reference was the composition of the comparison, prepared on the basis of linear alkylbenzene sulfonate (surfactant) company "Hulz" (Marlon ARL). The washing was carried out on a Linitest laboratory washing machine under the following conditions: Detergent dose 5 g / l Bath module 1:90 Calcium water hardness 5.35 mEq / l Type of fabric cotton Type of pollution Pigment oil fabrics Duration wash 20 + 2 minutes washing temperature 90 ^{° C} + 5 2 number of washes
The analysis of the data obtained (Tables 1, 2, 3) showed that the optimal values of detergent quality indicators such as: tocopherols, hydrogen, pH, washing ability, foaming ability are achieved with certain ratios of the components of the formulation of the developed product, namely: complex CO ₂ extract N 21 or GFK or complex CO ₂ extract N 27 or GFK 0.001-1.0% CO ₂ extract or GFK millet flour or CO ₂ extract or GFK hemp 0.001-1.0% CO ₂ extract or HFC fir 0.001-0.5% mixture of surfactant 10-20%
All components of the detergent in combination with CO ₂ -extracts at selected dose limits provide the tool with a healthy tone of soft tissues, reducing dry skin. The introduction into the formulation of a complex CO ₂ extract of N 21 or N 27 or their GFK, CO ₂ extract of millet flour or CO ₂ hemp extract or their GFK in an amount of less than 0.001% does not allow to achieve the desired effect, the introduction of the extracts in the formulation an amount of more than 1.0% is not economically feasible, due to the high cost of the extracts.

 All data on the comparative characteristics of the new tool was obtained by comparing the options of the prototype with the boundary and average values of the concentration of the components and the proposed three options with the boundary and average concentrations of all components of the formulation.

As a result of processing the obtained data on the comparative characteristics of the three options for the developed tool and the prototype, taking into account the minimum, average and maximum dosage values of all components, the following was established:
various combinations of the components of the developed detergent make it possible to obtain optimal values of the hydrogen index, increase the washing ability and low foaming, which is ensured by the selection of certain biologically active components, when mixed with the components of the formulation exhibiting an enhanced effect and determining the stability of the detergent:
a complex of extractives from chamomile, carrot seeds and rice waste, from hemp or millet flour in combination with other detergent components at selected boundary values of the components of the formulation reduces the sharp degreasing and peeling of the skin of the hands, increases the skin's vitaminization, showing anti-allergic effect.

The method of preparation of the detergent is as follows: in the mixer, to prepare the composition, equipped with a heating jacket and stirrer, load the calculated amount of sulfonol and soap powder, diphonate, Na-A zeolite and / or sodium tripolyphosphate, liquid sodium glass, Trilon B, Na CMC, optical brightener, sodium sulfate and water. At a temperature of 70-90 ^{° C} the composition was stirred for 10-15 minutes and then through a decanter trap, where the separated foreign impurities is pumped into the feed mixer where mixing of the ultimate composition are within 10 min. A composition containing 35-40% of water is subjected to homogenization (grinding of large particles formed during the preparation of the composition) and fed to a high-pressure pump for spray drying. The resulting powder contains 10-15% of residual water. The non-thermostable components of the sodium perborate formulation, perfume, liquid surfactants mixed with CO ₂ -extracts or their HFC are fed into the obtained semi-finished product.

 The following is an example (N6) of powder preparation (per 100 kg). Other examples are given in table 4.

In the reactor to prepare the composition with the stirrer loaded, kg: sulfonol 12; soap powder 1.5; diphonate 8; zeolite 5; liquid sodium glass 5; sodium tripolyphosphate 10; disodium salt of ethylenediaminetetraacetic acid 0.1; sodium carboxymethyl cellulose 1.0, optical brightener 0.1; sodium sulfate 38.4 and water. At 70-90 ^{° C} the composition was stirred for 15 min. The finished composition through decanter trap is pumped into the feed mixer where it was stirred for 10 min, and passed through the homogenizer serves to drying in a drying tower at a temperature of drying agent ^of 450-550 C. The temperature of the powder at the exit of the drying tower is not more than 70 ^C. .

A mixture is prepared separately in a container with a stirrer, kg: flavoring agent 0.1, complex CO ₂ extract of chamomile seeds of porcini and rice waste 0.1; CO ₂ extract of millet mucheli 0.1; hydrophytoconcentrate of fir 0.1.

During transportation, 1.5 kg of syntanol is sprayed onto the finished powder through spray nozzles, a solution of CO ₂ extracts in a perfume is sprayed, 17 kg of sodium perborate is added.

 Testing the new product for consumer properties showed that it can be used for washing and boiling cotton and linen. The proposed detergent has an excellent washing and whitening effect, reduces dry skin, maintains a healthy tone of its soft tissues, does not cause allergic reactions.

 Its introduction into production allows us to expand the range of detergents. According to the proposed recipe, it can be manufactured and produced on the existing equipment of the Moscow SMS factory.

Claims (1)

DETERGENT FOR WASHING TEXTILE MATERIALS, containing a mixture of anionic and nonionic surfactants, a complexing composition based on partially substituted sodium salts of aminomethylphosphonic, hydroxyethylidene diphosphonic, phosphorous and hydrochloric acid / diphonate, sodium nitrate / glass triethol phosphate sodium, disodium salt of ethylenediaminetetraacetic acid, optical brightener, sodium carboxymethyl cellulose, sodium sulfate and water, characterized in that it additionally contains a complex CO ₂ extract, or a hydrophytoconcentrate from chamomile and carrot seeds, or a complex CO ₂ extract, or a hydrophytoconcentrate from chamomile, carrot seeds and rice waste, a CO ₂ extract or hydrophytoconcentrate of millet flour, or CO ₂ extract , or hemp hydrophytoconcentrate, CO ₂ extract or fir hydrophytoconcentrate in the following ratio of components, wt. A mixture of anionic and nonionic surfactants 10 20
Diphonate 5 10
Zeolite and / or 0.1 10
Sodium tripolyphosphate 10 20
Liquid sodium glass 3 8
Sodium peroxoborate 15 20
Ethylenediaminetetraacetic acid disodium salt 0.05 0.2
Optical bleach 0.05 0.15
Sodium carboxymethyl cellulose 0.5 1.5
Complex CO ₂ extract, or hydrophytoconcentrate from chamomile and carrot seeds, or complex CO ₂ extract, or hydrophytoconcentrate from chamomile, carrot seeds and rice waste 0.001 1.0
CO ₂ extract or hydrophytoconcentrate of millet flour, or CO ₂ extract or hemp hydrophytoconcentrate 0.001 1.0
Fir CO ₂ extract or hydrophytoconcentrate 0.001 0.5
Fragrance 0.05 0.2
Sodium sulfate and water Up to 100

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