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RU2008103875A - Бумага с улучшенной жесткостью и пухлостью и способ для ее изготовления - Google Patents

Бумага с улучшенной жесткостью и пухлостью и способ для ее изготовления Download PDF

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RU2008103875A
RU2008103875A RU2008103875/12A RU2008103875A RU2008103875A RU 2008103875 A RU2008103875 A RU 2008103875A RU 2008103875/12 A RU2008103875/12 A RU 2008103875/12A RU 2008103875 A RU2008103875 A RU 2008103875A RU 2008103875 A RU2008103875 A RU 2008103875A
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paper
starch
layer
paperboard
coating
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RU2008103875/12A
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RU2387752C2 (ru
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Агне СВЕРИН (US)
Агне СВЕРИН
Джей К. СОНГ (US)
Джей К. СОНГ
Майкл ГЕРМАН (US)
Майкл ГЕРМАН
Питер Ф. ЛИ (NZ)
Питер Ф. ЛИ
Ладислав БЕДНАРИК (US)
Ладислав БЕДНАРИК
Сен ЯНГ (US)
Сен ЯНГ
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Интернэшнл Пейпер Компани (US)
Интернэшнл Пейпер Компани
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/80—Paper comprising more than one coating
    • D21H19/84—Paper comprising more than one coating on both sides of the substrate
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03—Non-macromolecular organic compounds
    • D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/07—Nitrogen-containing compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/34—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising cellulose or derivatives thereof
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/16—Sizing or water-repelling agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/52—Addition to the formed paper by contacting paper with a device carrying the material
    • D21H23/56—Rolls
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/54—Starch
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/22—Agents rendering paper porous, absorbent or bulky
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/254—Polymeric or resinous material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2984—Microcapsule with fluid core [includes liposome]
    • Y10T428/2985—Solid-walled microcapsule from synthetic polymer
    • Y10T428/2987—Addition polymer from unsaturated monomers only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31975—Of cellulosic next to another carbohydrate
    • Y10T428/31978—Cellulosic next to another cellulosic
    • Y10T428/31982—Wood or paper

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Abstract

1. Бумага или картон, имеющая улучшенную пухлость и жесткость, содержащая: ! трехслойную, образующую единое полотно двутавровую структуру, имеющую верхний слой, центральный слой и нижний слой, в которой центральный слой представляет собой целлюлозный сердцевинный слой, а верхний и нижний слои представляют собой слои покрытия на основе крахмала, которые покрывают верхнюю и нижнюю поверхности центрального слоя c минимальным проникновением в центральный слой, и ! наполнитель, проникающий в центральный слой. ! 2. Бумага или картон по п.1, в которой отношение толщины центрального слоя, по сравнению с толщиной бумаги или картона, находится в пределах между 1:50 и 1:1,1. ! 3. Бумага или картон по п.1, в которой масса на единицу площади бумаги находится в пределах от 59 до 410 г/м2, а масса на единицу площади каждого из верхнего и нижнего слоев покрытия находится в пределах от 2 до 10 г/м2. ! 4. Бумага или картон по п.1, в которой наполнитель выполнен из полимерного материала в форме микросфер. ! 5. Бумага или картон по п.1, в которой верхний и нижний слои формируются из раствора для проклеивания на основе крахмала, имеющего содержание твердых продуктов крахмала в пределах от 6 до 20 мас.%. ! 6. Бумага или картон по п.1, в которой наполнитель представляет собой продукт на основе диамидной соли. ! 7. Бумага или картон по п.1, в которой наполнитель изготавливают из полимерного материала в форме микросфер, выбранного из группы, состоящей из метилметакрилата, орто-хлоростирола, полиорто-хлоростирола, поливинилбензилхлорида, акрилонитрила, винилиденхлорида, пара-трет-бутилстирола, винилацетата, бутилакрилата, стирола, метакриловой кислоты, винилбензилхлори

Claims (32)

1. Бумага или картон, имеющая улучшенную пухлость и жесткость, содержащая:
трехслойную, образующую единое полотно двутавровую структуру, имеющую верхний слой, центральный слой и нижний слой, в которой центральный слой представляет собой целлюлозный сердцевинный слой, а верхний и нижний слои представляют собой слои покрытия на основе крахмала, которые покрывают верхнюю и нижнюю поверхности центрального слоя c минимальным проникновением в центральный слой, и
наполнитель, проникающий в центральный слой.
2. Бумага или картон по п.1, в которой отношение толщины центрального слоя, по сравнению с толщиной бумаги или картона, находится в пределах между 1:50 и 1:1,1.
3. Бумага или картон по п.1, в которой масса на единицу площади бумаги находится в пределах от 59 до 410 г/м2, а масса на единицу площади каждого из верхнего и нижнего слоев покрытия находится в пределах от 2 до 10 г/м2.
4. Бумага или картон по п.1, в которой наполнитель выполнен из полимерного материала в форме микросфер.
5. Бумага или картон по п.1, в которой верхний и нижний слои формируются из раствора для проклеивания на основе крахмала, имеющего содержание твердых продуктов крахмала в пределах от 6 до 20 мас.%.
6. Бумага или картон по п.1, в которой наполнитель представляет собой продукт на основе диамидной соли.
7. Бумага или картон по п.1, в которой наполнитель изготавливают из полимерного материала в форме микросфер, выбранного из группы, состоящей из метилметакрилата, орто-хлоростирола, полиорто-хлоростирола, поливинилбензилхлорида, акрилонитрила, винилиденхлорида, пара-трет-бутилстирола, винилацетата, бутилакрилата, стирола, метакриловой кислоты, винилбензилхлорида и сочетания из двух или более из указанных выше.
8. Бумага или картон по п.7, в которой центральный слой дополнительно содержит удерживающий агент.
9. Бумага или картон по п.1, в которой центральный слой дополнительно содержит добавку, выбранную из группы, состоящей из наполнителей, поверхностно-активных веществ, склеивающих агентов или их сочетаний.
10. Бумага или картон по п.1, в которой крахмал выбирается из группы, состоящей из гидроксиэтилированного крахмала, окисленного крахмала, катионно модифицированного или ферментативно преобразованного крахмала из любого обычно используемого источника крахмала, например из картофеля, кукурузы, пшеницы, риса или тапиоки.
11. Бумага или картон по п.1, в которой верхний и нижний слои дополнительно содержат агент для поперечной сшивки.
12. Бумага или картон по п.1, в которой верхний и нижний слои дополнительно содержат модификатор вязкости.
13. Бумага или картон по п.1, в которой верхний и нижний слои дополнительно содержат пигмент.
14. Бумага или картон по п.1, дополнительно содержащая добавки, выбранные из группы, состоящей из поливиниловых спиртов, аммоний цирконий карбоната, боратных химикатов, глиоксаля, меламинформальдегида, измельченных и преципитированных карбонатов кальция, глин, талька, TiO2 и окиси кремния или их сочетаний.
15. Бумага или картон по п.1, в которой верхний и нижний слои образованы покрытием раствора крахмала с содержанием твердых продуктов от 12 до 20 мас.%.
16. Бумага или картон по п.1, в которой верхний и нижний слои образованы покрытием раствора крахмала с содержанием твердых продуктов от 12 до 18 мас.%.
17. Бумага или картон, имеющая улучшенную пухлость и жесткость, содержащая:
трехслойную, образующую единое полотно двутавровую структуру, имеющую верхний слой, центральный слой и нижний слой, в котором центральный слой представляет собой целлюлозный сердцевинный слой, и верхний и нижний слои представляют собой слои покрытия на основе крахмала, которые покрывают верхнюю и нижнюю поверхность центрального слоя, масса покрытия на основе крахмала каждого из верхнего и нижнего слоев покрытия находится в пределах от 2 до 10 г/м2, и
наполнитель, проникающий в целлюлозный сердцевинный слой.
18. Способ для изготовления бумаги или картона, включающий в себя стадии:
a) создания композиции, содержащей целлюлозные волокна и наполнитель,
b) формирования волокнистого полотна из композиции для изготовления бумаги,
c) обработки полотна c помощью раствора на основе крахмала с формированием верхнего и нижнего слоев покрытия с высокой прочностью на верхней и нижней сторонах волокнистого полотна, и
d) сушки обработанного волокнистого полотна с формированием трехслойного, образующего единое полотно материала, имеющего двутавровую структуру.
19. Способ по п.18, в котором отношение толщины волокнистого полотна, по сравнению с толщиной бумаги или картона, находится в пределах между 1:50 и 1:1,1.
20. Способ по п.18, в котором масса на единицу площади бумаги находится в пределах между 59 и 410 г/м2, а масса на единицу площади каждого из верхнего и нижнего слоев покрытия находится в пределах между 2 и 10 г/м2.
21. Способ по п.18, в котором уровень крахмала из верхнего и нижнего слоев покрытия в волокнистом полотне является незначительным.
22. Способ по п.18, в котором верхний и нижний слои покрытия имеют содержание твердых продуктов в крахмале, меньшее, чем 20 мас.%.
23. Способ по п.18, в котором для обработки используют устройство для дозированного проклеивания.
24. Способ по п.18, в котором наполнитель представляет собой продукт на основе диамидной соли.
25. Способ по п.18, в котором композиция дополнительно содержит добавку, выбранную из группы, состоящей из: наполнителей, поверхностно-активных веществ или их сочетаний.
26. Способ по п.18, в котором крахмал выбирается из группы, состоящей из: гидроксиэтилированного крахмала, окисленного крахмала, катионно модифицированного или ферментативно преобразованного крахмала из любого обычно используемого источника крахмала, например из картофеля, кукурузы, пшеницы, риса или тапиоки.
27. Способ по п.18, в котором раствор для проклеивания дополнительно содержит добавку, выбранную из группы, состоящей из: поливиниловых спиртов, аммоний цирконий карбоната, боратных химикатов, глиоксаля, меламинформальдегида, измельченных и преципитированных карбонатов кальция, глин, талька, TiO2 и окиси кремния или их сочетаний.
28. Способ по п.18, в котором раствор крахмала, для раствора на основе крахмала высокой прочности, предварительно варят вместе c боратным химикатом перед обработкой посредством проклеивания.
29. Способ по п.18, в котором используют наполнитель из полимерного материала в форме микросфер.
30. Способ по п.18, в котором используют наполнитель из полимерного материала в форме микросфер, выбранного из группы, состоящей из метилметакрилата, орто-хлоростирола, полиорто-хлоростирола, поливинилбензилхлорида, акрилонитрила, винилиденхлорида, пара-трет-бутилстирола, винилацетата, бутилакрилата, стирола, метакриловой кислоты, винилбензилхлорида и сочетания из двух или более из указанных выше.
31. Способ по п.18, в котором используют раствор на основе крахмала с содержанием твердых продуктов от 12 до 20 мас.%.
32. Способ по п.18, в котором используют раствор на основе крахмала с содержанием твердых продуктов от 12 до 18 мас.%.
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