FI90985B - För polymerisationskatalysatorer avsedd prokatalysatorkomposition innehållande en effektiv elektrondonator - Google Patents
För polymerisationskatalysatorer avsedd prokatalysatorkomposition innehållande en effektiv elektrondonator Download PDFInfo
- Publication number
- FI90985B FI90985B FI914627A FI914627A FI90985B FI 90985 B FI90985 B FI 90985B FI 914627 A FI914627 A FI 914627A FI 914627 A FI914627 A FI 914627A FI 90985 B FI90985 B FI 90985B
- Authority
- FI
- Finland
- Prior art keywords
- composition according
- electron donor
- procatalyst composition
- procatalyst
- donor
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 23
- 239000000203 mixture Substances 0.000 title claims description 20
- 239000002685 polymerization catalyst Substances 0.000 title claims description 6
- -1 organometallic aluminum compound Chemical class 0.000 claims description 19
- 239000011777 magnesium Substances 0.000 claims description 17
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 150000002148 esters Chemical group 0.000 claims description 13
- 239000010936 titanium Substances 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 11
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical group [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 229910052749 magnesium Inorganic materials 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 235000011147 magnesium chloride Nutrition 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
- VZCYOOQTPOCHFL-OWOJBTEDSA-N fumaric acid group Chemical group C(\C=C\C(=O)O)(=O)O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical group OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- 150000005690 diesters Chemical class 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical group Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001530 fumaric acid Chemical group 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- 238000005507 spraying Methods 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 14
- 239000004743 Polypropylene Substances 0.000 description 11
- CUEJHYHGUMAGBP-UHFFFAOYSA-N 2-[2-(1h-indol-5-yl)phenyl]acetic acid Chemical compound OC(=O)CC1=CC=CC=C1C1=CC=C(NC=C2)C2=C1 CUEJHYHGUMAGBP-UHFFFAOYSA-N 0.000 description 9
- 229920001155 polypropylene Polymers 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 7
- 150000003609 titanium compounds Chemical class 0.000 description 6
- YVNRSOMGUGTRMU-UHFFFAOYSA-N 6-ethyl-5-methylphenanthridin-5-ium-3,8-diamine;bromide Chemical compound [Br-].C1=C(N)C=C2C(CC)=[N+](C)C3=CC(N)=CC=C3C2=C1 YVNRSOMGUGTRMU-UHFFFAOYSA-N 0.000 description 5
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229910003074 TiCl4 Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- VGUWZCUCNQXGBU-UHFFFAOYSA-N 3-[(4-methylpiperazin-1-yl)methyl]-5-nitro-1h-indole Chemical compound C1CN(C)CCN1CC1=CNC2=CC=C([N+]([O-])=O)C=C12 VGUWZCUCNQXGBU-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- ROPXFXOUUANXRR-BUHFOSPRSA-N bis(2-ethylhexyl) (e)-but-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C\C(=O)OCC(CC)CCCC ROPXFXOUUANXRR-BUHFOSPRSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 150000004651 carbonic acid esters Chemical class 0.000 description 1
- 150000004653 carbonic acids Chemical class 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000010960 commercial process Methods 0.000 description 1
- OGVXYCDTRMDYOG-UHFFFAOYSA-N dibutyl 2-methylidenebutanedioate Chemical compound CCCCOC(=O)CC(=C)C(=O)OCCCC OGVXYCDTRMDYOG-UHFFFAOYSA-N 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- BVVRPLNLVUMGSL-VXPUYCOJSA-N didecyl (z)-but-2-enedioate Chemical compound CCCCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCCCC BVVRPLNLVUMGSL-VXPUYCOJSA-N 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000001965 increasing effect Effects 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 1
- 150000002895 organic esters Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 125000005546 pivalic acid group Chemical group 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (12)
1. Prokatalysatorkomposition i en katalysator for polymerisation av α-olefiner, innefattande en magnesiumdihaloge-nidbärare och däruppä en förening av fyrvärt titan samt en 5 elektrondonor, varvid elektrondonom är en mono- eller polyester av en omättad polykarboxylsyra med ätminstone tvä karboxylgrupper bundna till invidliggande dubbelbundna kol-atomer, kännetecknad av att ätminstone den ena av elektrondonorns nämnda dubbelbundna kolatomer eller en 10 därvid dubbelbunden kolatom är substituerad med en lägre kolvätegrupp.
2. Prokatalysatorkomposition enligt patentkrav 1, kännetecknad av att den lägre kolvätegruppen är metyl. 15
3. Prokatalysatorkomposition enligt patentkrav l eller 2, kännetecknad av att magnesiumdihalogenbäraren är magnesiumdiklorid.
4. Prokatalysatorkomposition enligt patentkrav 1, 2 eller 3, kännetecknad av att magnesiumdikloridbäraren framställts genom sammansmältning av torr magnesiumdiklorid och etanol, bildande av smä droppar av smältan och konsoli-dering av de smälta droppama genom avkylning, företrädesvis 25 medels sprutkristallisering, tili finfördelade bärarpartik-lar.
5. Prokatalysatorkonposition enligt patentkrav 1, 2 eller 3, kännetecknad av att föreningen av det fyr- 30 värda titanet är titantetraklorid.
6. Prokatalysatorkomposition enligt nägot av de föregäende patentkraven, kännetecknad av att elektrondonom är en ester av malein- eller fumarsyra, som substitue- 35 rats med nämnda lägre kolvätegrupp. 1 il Prokatalysatorkomposition enligt patentkrav 6, kännetecknad av att elektrondonom är en maleinsyra- 90985 diester, som monosubstituerats med nämnda lägre kolväte-grupp.
8. Prokatalysatorkomposition enligt patentkrav 7, k ä n -5 netecknad av att elektrondonorn är ett dialkyl-cis- 2-metylbutendikarboxylat med 1-10 kolatomer i alkylgruppen.
9. Prokatalysatorkomposition enligt nägot av de föregäende patentkraven, kännetecknad av att dess molför- 10 hell lande elektrondonor/magnesium är mellan cirka 0,01 och 0,50.
10. Prokatalysatorkomposition enligt nägot av de £öregäende patentkraven, kännetecknad av att polymerisa- 15 tionskatalysatom, vars komponent den utgör, ocksä innefattar en organometallisk aluminiumförening som kokatalysator och eventuellt en yttre donor.
11. Prokatalysatorkomposition enligt patentkrav 10, 20 kännetecknad av att den organometalliska alu-miniumföreningen är ett trialkylaluminium, företrädesvis trietylaluminium, och den yttre donorn är dimetyldialkoxi-silan, företrädesvis cyklohexylmetyldimetoxisilan.
12. Prokatalysatorkomposition enligt patentkrav 10 eller 11, kännetecknad av att molförhällandet AI/Ti är mellan cirka 1 och 1 000, företrädesvis mellan cirka 500 och 1 000.
13. Prokatalysatorkompositiön enligt nägot av patentkraven 10, 11 eller 12, kännetecknad av att molförhällandet AI/elektrondonor är mellan cirka 0,1 och 200, företrädesvis mellan cirka 10 och 30.
Priority Applications (9)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI914627A FI90985C (sv) | 1991-10-02 | 1991-10-02 | För polymerisationskatalysatorer avsedd prokatalysatorkomposition innehållande en effektiv elektrondonator |
| PCT/FI1992/000264 WO1993007182A1 (en) | 1991-10-02 | 1992-10-01 | A procatalyst composition containing substituted maleic of fumaric acid esters as electron donor for olefin polymerization |
| JP5506641A JPH06503380A (ja) | 1991-10-02 | 1992-10-01 | 有効な電子供与体を含有する重合触媒用のプロキャタリスト組成物 |
| CA002097516A CA2097516C (en) | 1991-10-02 | 1992-10-01 | A procatalyst composition containing substituted maleic of fumaric acid esters as electron donor for olefin polymerization |
| US08/066,098 US5436213A (en) | 1991-10-02 | 1992-10-01 | Procatalyst composition containing substituted maleic or fumaric acid esters as an electron donor for olefin polymerization |
| EP92921018A EP0559874B1 (en) | 1991-10-02 | 1992-10-01 | A procatalyst composition containing substituted maleic of fumaric acid esters as electron donor for olefin polymerization |
| DE69219755T DE69219755T2 (de) | 1991-10-02 | 1992-10-01 | Procatalytische zusammensetzung zur olefinpolymerisation, die malein- oder fumarsäureester als elektrondonor enthält |
| ES92921018T ES2104944T3 (es) | 1991-10-02 | 1992-10-01 | Composicion de procatalizador que contiene esteres de acido maleico o fumarico substituidos como donador de electrones en la polimerizacion de olefinas. |
| NO93932008A NO932008L (no) | 1991-10-02 | 1993-06-02 | Prokatalysatorsammensetning inneholdende substituerte malein- eller fumarsyreestere som elektrondonor for olefinpolymerisasjon |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI914627 | 1991-10-02 | ||
| FI914627A FI90985C (sv) | 1991-10-02 | 1991-10-02 | För polymerisationskatalysatorer avsedd prokatalysatorkomposition innehållande en effektiv elektrondonator |
Publications (4)
| Publication Number | Publication Date |
|---|---|
| FI914627A0 FI914627A0 (sv) | 1991-10-02 |
| FI914627L FI914627L (sv) | 1993-04-03 |
| FI90985B true FI90985B (sv) | 1994-01-14 |
| FI90985C FI90985C (sv) | 1994-04-25 |
Family
ID=8533221
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI914627A FI90985C (sv) | 1991-10-02 | 1991-10-02 | För polymerisationskatalysatorer avsedd prokatalysatorkomposition innehållande en effektiv elektrondonator |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5436213A (sv) |
| EP (1) | EP0559874B1 (sv) |
| JP (1) | JPH06503380A (sv) |
| CA (1) | CA2097516C (sv) |
| DE (1) | DE69219755T2 (sv) |
| ES (1) | ES2104944T3 (sv) |
| FI (1) | FI90985C (sv) |
| WO (1) | WO1993007182A1 (sv) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100334167B1 (ko) * | 1997-05-08 | 2002-11-22 | 삼성종합화학주식회사 | 알파-올레핀중합방법 |
| KR20040028674A (ko) * | 2001-09-13 | 2004-04-03 | 바셀 폴리올레핀 이탈리아 에스.피.에이. | 올레핀 중합용 성분 및 촉매 |
| MXPA05012830A (es) * | 2003-05-29 | 2006-02-13 | Basell Poliolefine Srl | Procedimiento para la preparacion de un componente catalizador y componentes obtenidos a partir de este. |
| WO2005077990A1 (en) * | 2004-02-16 | 2005-08-25 | Reliance Industries Limited | Catalytic system for polymerisation of lower alpha alkene. |
| ATE401123T1 (de) | 2004-12-17 | 2008-08-15 | Borealis Tech Oy | Verfahren zur polymerisation von olefinen in gegenwart eines olefin polymerisationskatalysators |
| CN101824106B (zh) * | 2009-03-04 | 2012-05-30 | 中国石油天然气股份有限公司 | 烯烃聚合用催化组分及其催化剂 |
| KR101114073B1 (ko) * | 2009-12-08 | 2012-02-22 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매의 제조 방법 |
| KR101235445B1 (ko) | 2010-01-13 | 2013-02-20 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매의 제조 방법 |
| CN102268109B (zh) * | 2010-06-04 | 2012-11-14 | 中国石油天然气股份有限公司 | 一种用于烯烃聚合的固体钛催化剂 |
| EP2644628A4 (en) * | 2010-11-24 | 2014-07-23 | Samsung Total Petrochemicals | SOLID CATALYST FOR POLYMERIZING PROPYLENE AND METHOD FOR THE PRODUCTION THEREOF |
| KR101255913B1 (ko) * | 2011-01-05 | 2013-04-17 | 삼성토탈 주식회사 | 프로필렌 중합용 고체촉매 및 이를 이용한 폴리프로필렌 제조 방법 |
| RU2637930C2 (ru) * | 2013-06-26 | 2017-12-08 | Бореалис Аг | Сополимер пропилена для бутылок, изготавливаемых пневмоформованием с экструзией |
| EP3071607B1 (en) | 2013-11-22 | 2018-05-09 | Borealis AG | Low emission propylene homopolymer |
| WO2022111966A1 (en) | 2020-11-27 | 2022-06-02 | Borealis Ag | Catalyst feed system |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1209255B (it) * | 1980-08-13 | 1989-07-16 | Montedison Spa | Catalizzatori per la polimerizzazione di olefine. |
-
1991
- 1991-10-02 FI FI914627A patent/FI90985C/sv not_active IP Right Cessation
-
1992
- 1992-10-01 ES ES92921018T patent/ES2104944T3/es not_active Expired - Lifetime
- 1992-10-01 WO PCT/FI1992/000264 patent/WO1993007182A1/en not_active Ceased
- 1992-10-01 US US08/066,098 patent/US5436213A/en not_active Expired - Lifetime
- 1992-10-01 EP EP92921018A patent/EP0559874B1/en not_active Expired - Lifetime
- 1992-10-01 CA CA002097516A patent/CA2097516C/en not_active Expired - Fee Related
- 1992-10-01 JP JP5506641A patent/JPH06503380A/ja active Pending
- 1992-10-01 DE DE69219755T patent/DE69219755T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ES2104944T3 (es) | 1997-10-16 |
| US5436213A (en) | 1995-07-25 |
| FI914627A0 (sv) | 1991-10-02 |
| EP0559874A1 (en) | 1993-09-15 |
| EP0559874B1 (en) | 1997-05-14 |
| JPH06503380A (ja) | 1994-04-14 |
| DE69219755T2 (de) | 1997-10-09 |
| FI90985C (sv) | 1994-04-25 |
| CA2097516C (en) | 2004-01-27 |
| WO1993007182A1 (en) | 1993-04-15 |
| FI914627L (sv) | 1993-04-03 |
| CA2097516A1 (en) | 1993-04-03 |
| DE69219755D1 (de) | 1997-06-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Patent granted |
Owner name: BOREALIS A/S |
|
| BB | Publication of examined application | ||
| PC | Transfer of assignment of patent |
Owner name: BOREALIS A/S |
|
| TC | Name/ company changed in patent |
Owner name: BOREALIS A/S |
|
| MM | Patent lapsed |