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ES2632414T3 - Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello - Google Patents

Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello Download PDF

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Publication number
ES2632414T3
ES2632414T3 ES12184233.0T ES12184233T ES2632414T3 ES 2632414 T3 ES2632414 T3 ES 2632414T3 ES 12184233 T ES12184233 T ES 12184233T ES 2632414 T3 ES2632414 T3 ES 2632414T3
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Prior art keywords
styling
polymer
formulation
propellant
mixture
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Active
Application number
ES12184233.0T
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English (en)
Inventor
Susanne Birkel
Wassiliki Christopoulou
Paolo Dal Bò
Klaus Gänger
Bettina Giesen
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Procter and Gamble Co
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Procter and Gamble Co
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Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Application granted granted Critical
Publication of ES2632414T3 publication Critical patent/ES2632414T3/es
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/87—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/34—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
    • B05B1/3405—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
    • B05B1/341—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
    • B05B1/3415—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with swirl imparting inserts upstream of the swirl chamber
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B1/00—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means
    • B05B1/34—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl
    • B05B1/3405—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl
    • B05B1/341—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet
    • B05B1/3421—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber
    • B05B1/3431—Nozzles, spray heads or other outlets, with or without auxiliary devices such as valves, heating means designed to influence the nature of flow of the liquid or other fluent material, e.g. to produce swirl to produce swirl before discharging the liquid or other fluent material, e.g. in a swirl chamber upstream the spray outlet with channels emerging substantially tangentially in the swirl chamber the channels being formed at the interface of cooperating elements, e.g. by means of grooves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • B65D83/75—Aerosol containers not provided for in groups B65D83/16 - B65D83/74
    • B65D83/753—Aerosol containers not provided for in groups B65D83/16 - B65D83/74 characterised by details or accessories associated with outlets
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06F—ELECTRIC DIGITAL DATA PROCESSING
    • G06F30/00—Computer-aided design [CAD]
    • G06F30/20—Design optimisation, verification or simulation
    • G06F30/23—Design optimisation, verification or simulation using finite element methods [FEM] or finite difference methods [FDM]
    • G—PHYSICS
    • G06—COMPUTING OR CALCULATING; COUNTING
    • G06V—IMAGE OR VIDEO RECOGNITION OR UNDERSTANDING
    • G06V20/00—Scenes; Scene-specific elements
    • G06V20/20—Scenes; Scene-specific elements in augmented reality scenes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
    • A61K2800/30—Characterized by the absence of a particular group of ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Theoretical Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Evolutionary Computation (AREA)
  • Geometry (AREA)
  • General Engineering & Computer Science (AREA)
  • Multimedia (AREA)
  • Cosmetics (AREA)
  • Nozzles (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)

Abstract

Un producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello, en donde el producto comprende: i. un recipiente que comprende una pared del recipiente que encierra un depósito para almacenar una formulación para estilismo y un propelente; ii. la formulación para estilismo que comprende: (a) al menos 50 % de agua por peso total de la formulación para estilismo y propelente; y (b) de 0,01 % a 20 % de un polímero de estilismo por peso total de la formulación para estilismo y propelente, en donde el polímero de estilismo es una mezcla de polímeros de estilismo, comprendiendo la mezcla un polímero de estilismo duro y un polímero de estilismo blando, en donde el polímero de estilismo duro se selecciona del grupo que consiste en: copolímeros de acrilato de dos o más monómeros de ácido (met)acrílico o uno de sus ésteres simples; copolímero de acrilatos/hidroxiésteres acrilatos de acrilato de butilo, metacrilato de metilo, ácido metacrílico, acrilato de etilo y metacrilato de hidroxietilo; y mezclas de los mismos; el polímero de estilismo blando se selecciona del grupo que consiste en: una mezcla de polímero de poliuretano-14/AMP-acrilatos; polímeros de estilismo de látex; poliésteres; y mezclas de los mismos, y comprende preferiblemente una mezcla de polímero de poliuretano-14/AMP-acrilatos; y en donde el polímero de estilismo duro tiene una temperatura de transición vítrea mayor de o igual a 10 °C y un PM de 90 mil g/mol a 200 mil g/mol, y el polímero de estilismo blando tiene una temperatura de transición vítrea menor de 10 °C y un PM de aproximadamente 10 mil g/mol a aproximadamente 90 mil g/mol; y en donde la relación de peso del polímero de estilismo duro al polímero de estilismo blando en la mezcla es de 10:1 a 1:10; iii. un propelente, que se selecciona del grupo que consiste en propelentes de gas comprimido, propelentes de gas licuado, y mezclas de los mismos; y iv. un dispositivo pulverizador unido al recipiente para dispensar la formulación para estilismo desde el depósito del recipiente; y en donde el producto comprende 2 % o menos de alcohol por peso total de la formulación para estilismo y propelente, o menos de 1 %;

Description

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La relación de peso del polímero de estilismo duro al polímero de estilismo blando (duro:blando) en la mezcla es de aproximadamente 10:1 a aproximadamente 1:10, o de aproximadamente 10:1 a aproximadamente 1:2. En una realización en donde la mezcla comprende al menos 2 polímeros de estilismo diferentes, o solo 2 polímeros de estilismo diferentes, la relación de peso del duro:blando puede ser de aproximadamente 10:0,5 a aproximadamente 9:3, o de aproximadamente 10:1 a aproximadamente 9:2. En una realización en donde la mezcla comprende al menos 3 polímeros de estilismo diferentes, o solo 3 polímeros de estilismo diferentes, la relación de peso del duro:blando puede ser de aproximadamente 10:1 a aproximadamente 6:4, o de aproximadamente 10:2 a aproximadamente 8:3.
En una realización, la formulación para estilismo comprende además un ingrediente adicional seleccionado del grupo que consiste en: copolímeros de octilacrilamida/acrilato/metacrilato de butilaminoetilo, compuestos de pantenol, compuestos de silicona, compuestos de látex, y mezclas de los mismos. En una realización, la formulación para estilismo comprende además un compuesto de pantenol. En una realización, el compuesto de pantenol se selecciona del grupo que consiste en: pantenol, un derivado de ácido pantoténico, y mezclas de los mismos. En una realización, el compuesto de pantenol se selecciona del grupo que consiste en: D-pantenol ([R]-2,4-dihidroxi-N-[3hidroxipropil)]-3,3-dimetilbutamida), D/L-pantenol, ácido pantoténico y sus sales, triacetato de pantenilo, jalea real, pantetina, pantoteína, pantenil etil éter, ácido pangámico, pantoil lactosa, complejo de vitamina B, y mezclas de los mismos. En una realización, la formulación para estilismo comprende una mezcla que comprende un polímero de estilismo duro, pantenol, y un polímero de estilismo blando. En una realización, la formulación para estilismo comprende pantenol. El compuesto de pantenol puede tener un efecto ‘suavizante’ sobre el polímero de estilismo duro. La formulación para estilismo puede comprender de aproximadamente 0,1 % a aproximadamente 0,6 %, o de aproximadamente 0,1 % a aproximadamente 0,3 %, de un compuesto de pantenol por peso total de la formulación para estilismo y el propelente. La relación de peso del polímero de estilismo duro al compuesto de pantenol puede ser de aproximadamente 100:6 a aproximadamente 100:1, o de aproximadamente 100:4 a aproximadamente
100:20. En una realización, el compuesto de pantenol es bien D-pantenol o bien D/L-pantenol. En una realización, la formulación para estilismo comprende además un compuesto de silicona. La silicona es útil porque proporciona una sensación de suavidad y también brillo al cabello. En una realización, el compuesto de silicona es un compuesto de dimeticona. En una realización, el compuesto de silicona es una PEG dimeticona, por ejemplo, PEG-12 dimeticona. En una realización, la formulación para estilismo comprende además un copolímero de octilacrilamida/acrilato/metacrilato de butilaminoetilo. Amphomer® es un copolímero de octilacrilamida/acrilato/metacrilato de butilaminoetilo.
En una realización, el polímero de estilismo es un polímero de estilismo compatible con agua, de forma alternativa, un polímero de estilismo soluble en agua. En una realización, la formulación para estilismo está prácticamente exenta de un polímero de estilismo incompatible con agua. Balance® CR, Acudyne™ 1000, DynamX® H2O de Akzo Nobel son compatibles con el agua.
En una realización, la formulación para estilismo comprende además un polímero de estilismo de látex. En una realización, el polímero de estilismo de látex es un polímero de poliuretano y/o una dispersión acuosa de poliuretano. En una realización, el polímero de poliuretano es poliuretano-48. Baycusan® C 1008 es un Polyuretano-48, que es una dispersión acuosa de poliuretano.
En una realización, el producto comprende menos de aproximadamente 0,5 % de un tensioactivo catiónico por peso total de la formulación para estilismo y propelente. En una realización, la formulación para estilismo comprende un polímero de poliuretano y la formulación para estilismo está prácticamente exenta de un tensioactivo catiónico. En una realización, el único polímero de estilismo no es ni un polímero de estilismo de látex ni un polímero de poliuretano. En una realización, la formulación para estilismo está prácticamente exenta de un polímero de poliuretano. Esto se debe, en determinadas circunstancias, a que los polímeros de poliuretano pueden producir residuos sobre el cabello una vez que la formulación eyectada se ha secado sobre el cabello. Dichos residuos son antiestéticos y no preferidos por los consumidores, ya que pueden confundirse con caspa.
La adherencia sobre las manos y/o el cabello de la presente invención es menor de la conseguida mediante lacas para el cabello en aerosol de base etanólica convencionales. En una realización, el producto comprende de aproximadamente 20 % a aproximadamente 50 % de COV, por peso total de la formulación para estilismo y el propelente licuados es DME. La ventaja de baja adherencia sobre las manos y/o el cabello también se consigue mediante la presente realización.
Los polímeros tanto anfóteros como aniónicos, tal como Balance® CR están normalmente presentes en sus formas tanto neutralizada como parcialmente neutralizada. En una realización, el polímero de estilismo está neutralizado en al menos 60 %, o al menos 80 %.
Los neutralizantes adecuados incluyen hidróxido potásico, hidróxido sódico, triisopropanolamina (TIPA), 2-aminobutanol, 2-aminometil propanol (AMP), aminoetilpropandiol, dimetil estearamina (Armeen 18 D), silicato de sodio, tetrahidroxipropil etilenediamina (Neutrol® TE), amoniaco (NH3), trietanolamina, trimetilamina (Tris Amino Ultra), aminometilpropandiol (AMPD). En una realización, el agente neutralizante es 2-aminobutanol, amoniaco, o 2-aminometil propanol.
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Claims (1)

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ES12184233.0T 2011-09-15 2012-09-13 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello Active ES2632414T3 (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP11007522 2011-09-15
EP11007522A EP2570190A1 (en) 2011-09-15 2011-09-15 Spray nozzle for dispensing a fluid and sprayer comprising such a spray nozzle
EP11192063 2011-12-06
EP11192063.3A EP2570113B1 (en) 2011-09-15 2011-12-06 Aerosol hairspray product for styling and/or shaping hair

Publications (1)

Publication Number Publication Date
ES2632414T3 true ES2632414T3 (es) 2017-09-13

Family

ID=45044462

Family Applications (3)

Application Number Title Priority Date Filing Date
ES17186155T Active ES2795686T3 (es) 2011-09-15 2011-12-06 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello
ES11192063.3T Active ES2648056T3 (es) 2011-09-15 2011-12-06 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello
ES12184233.0T Active ES2632414T3 (es) 2011-09-15 2012-09-13 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello

Family Applications Before (2)

Application Number Title Priority Date Filing Date
ES17186155T Active ES2795686T3 (es) 2011-09-15 2011-12-06 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello
ES11192063.3T Active ES2648056T3 (es) 2011-09-15 2011-12-06 Producto de laca para el cabello en aerosol para dar estilo y/o forma al cabello

Country Status (9)

Country Link
US (3) US10426979B2 (es)
EP (6) EP2570190A1 (es)
JP (3) JP5844469B2 (es)
CN (3) CN103796761A (es)
BR (1) BR112014005646B1 (es)
CA (1) CA2848870C (es)
ES (3) ES2795686T3 (es)
MX (3) MX348219B (es)
WO (3) WO2013040157A1 (es)

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EP2570190A1 (en) * 2011-09-15 2013-03-20 Braun GmbH Spray nozzle for dispensing a fluid and sprayer comprising such a spray nozzle
US9159277B2 (en) * 2011-09-20 2015-10-13 Pixtronix, Inc. Circuits for controlling an array of light modulators of a display apparatus to generate display images
US9801804B2 (en) 2013-06-28 2017-10-31 L'oreal Compositions and methods for treating hair
US9789051B2 (en) 2013-06-28 2017-10-17 L'oreal Compositions and methods for treating hair
US9795555B2 (en) 2013-06-28 2017-10-24 L'oreal Compositions and methods for treating hair
MX2015005779A (es) * 2013-06-28 2015-09-23 Procter & Gamble Producto de laca en aerosol para el cabello que comprende un dispositivo de rociado.
US9788627B2 (en) 2013-06-28 2017-10-17 L'oreal Compositions and methods for treating hair
US9839600B2 (en) 2013-06-28 2017-12-12 L'oreal Compositions and methods for treating hair
US9795556B2 (en) 2013-06-28 2017-10-24 L'oreal Compositions and methods for treating hair
US9884004B2 (en) 2013-06-28 2018-02-06 L'oreal Compositions and methods for treating hair
CN105491995A (zh) * 2013-06-28 2016-04-13 欧莱雅 用于处理毛发的组合物和方法
US9884002B2 (en) 2013-06-28 2018-02-06 L'oreal Compositions and methods for treating hair
US9884003B2 (en) 2013-06-28 2018-02-06 L'oreal Compositions and methods for treating hair
JP6095143B2 (ja) * 2013-06-28 2017-03-15 ザ プロクター アンド ギャンブル カンパニー 特定のエアロゾルヘアスプレー製品を提供すること及び特定の噴射量で製品を噴射させることを含むヘアスタイリング方法
US9789050B2 (en) 2013-06-28 2017-10-17 L'oreal Compositions and methods for treating hair
US20150174793A1 (en) 2013-12-19 2015-06-25 The Procter & Gamble Company Methods for Shaping Fibrous Material and Treatment Compositions Therefor
US20150173478A1 (en) 2013-12-19 2015-06-25 The Procter & Gamble Company Methods for Shaping Fibrous Material and Treatment Compositions Therefor
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CA2848870A1 (en) 2013-03-21
US11311749B2 (en) 2022-04-26
CN103781458A (zh) 2014-05-07
EP2570192A1 (en) 2013-03-20
EP2570190A1 (en) 2013-03-20
MX2014003231A (es) 2014-06-05
EP3260110A1 (en) 2017-12-27
EP3260110B1 (en) 2020-04-22
BR112014005646A2 (pt) 2017-03-28
US10426979B2 (en) 2019-10-01
MX2014003235A (es) 2014-06-05
EP2570193B1 (en) 2014-08-27
ES2795686T3 (es) 2020-11-24
CN103796761A (zh) 2014-05-14
EP2570192B1 (en) 2015-06-10
WO2013038364A1 (en) 2013-03-21
EP2570113A3 (en) 2014-01-01
US20220107993A9 (en) 2022-04-07
BR112014005646B1 (pt) 2019-03-26
JP5844469B2 (ja) 2016-01-20
MX348219B (es) 2017-06-05
MX339328B (es) 2016-05-20
US20130068243A1 (en) 2013-03-21
WO2013040157A1 (en) 2013-03-21
WO2013040171A3 (en) 2014-02-27
EP2570193A1 (en) 2013-03-20
US20130068849A1 (en) 2013-03-21
CA2848870C (en) 2018-11-13
EP2570113B1 (en) 2017-09-13
US20190384880A1 (en) 2019-12-19
CN103987464A (zh) 2014-08-13
JP5873176B2 (ja) 2016-03-01
EP2570113A2 (en) 2013-03-20
JP2014526376A (ja) 2014-10-06
WO2013040171A2 (en) 2013-03-21
ES2648056T3 (es) 2017-12-28
CN103781458B (zh) 2016-11-09
JP2014531437A (ja) 2014-11-27
JP2014531971A (ja) 2014-12-04

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