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EP1268741A1 - Serviettes humides (iii) - Google Patents

Serviettes humides (iii)

Info

Publication number
EP1268741A1
EP1268741A1 EP01931553A EP01931553A EP1268741A1 EP 1268741 A1 EP1268741 A1 EP 1268741A1 EP 01931553 A EP01931553 A EP 01931553A EP 01931553 A EP01931553 A EP 01931553A EP 1268741 A1 EP1268741 A1 EP 1268741A1
Authority
EP
European Patent Office
Prior art keywords
wet wipes
alkyl
alcohol
carbon atoms
contain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01931553A
Other languages
German (de)
English (en)
Other versions
EP1268741B1 (fr
Inventor
Michael Elsner
Anja Hanke
Manfred Weuthen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1268741A1 publication Critical patent/EP1268741A1/fr
Application granted granted Critical
Publication of EP1268741B1 publication Critical patent/EP1268741B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049—Cleaning or scouring pads; Wipes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/3188—Next to cellulosic
    • Y10T428/31895—Paper or wood
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31971—Of carbohydrate
    • Y10T428/31993—Of paper

Definitions

  • the invention is in the field of hard surface cleaners and relates to wet wipes impregnated with a particular species of nonionic surfactant.
  • wet wipes are textile fabrics or also tissue papers that are soaked with a cleaning liquid.
  • wet wipes are textile fabrics or also tissue papers that are soaked with a cleaning liquid.
  • a disadvantage of using these wet wipes is that the surfactants used leave a residue in the form of streaks, which makes the treated surface appear less shiny or even dirty.
  • a first object of the present invention was therefore to provide wet wipes using special surfactants which are free from the problems described at the outset. For logistical reasons, the use of concentrates for the preparation of the impregnation solutions for the wet wipes is advantageous. It is disadvantageous that the concentrates often show a tendency to foam when diluted.
  • the object of the invention was therefore to provide surfactants which can be used to produce concentrates which, due to their viscosity, storage stability, low foaming when diluted and rapid dilutability, permit technically simple and therefore inexpensive production of the wet wipes.
  • the invention relates to wet wipes, which are characterized in that they are impregnated with mixed ethers.
  • nonionic surfactants of the mixed ether type preferably in combination with alkyl oligoglucosides
  • Impregnation agents based on mixed ethers prove to be low-viscosity and practically foam-free in use. When used, the wet wipes soaked do not leave streaks and do not impair the gloss. Concentrates based on mixed ethers are low-viscosity and particularly low-foaming when diluted to the application concentration.
  • Mixed ethers are known nonionic surfactants which are usually obtained by adding ethylene oxide and / or propylene oxide, in blocks or in random distribution, to suitable primary alcohols and then etherifying the alkoxylates with alkyl halides; etherification is also referred to as "end group closure”.
  • the mixed ethers usually follow the formula (I),
  • R 1 is an alkyl and / or alkenyl radical having 1 to 22, preferably 6 to 18 and in particular 12 to 16 carbon atoms
  • R 2 is an alkyl radical having 1 to 12, preferably 4 to 8 carbon atoms or a benzyl radical
  • x and z independently of one another are 0 or numbers from 1 to 40 and y is 0 or numbers from 1 to 10, with the proviso that the sum of the carbon atoms in the radicals R 1 and R 2 is at least 4, preferably at least 8 and in particular at least 12 is and the sum of the indices x, y and z of 0 is different.
  • Typical examples are the etherification products of the addition products of on average 1 to 40, preferably 5 to 30 and in particular 8 to 15 moles of ethylene oxide and / or 1 to 10, preferably 2 to 5 moles of propylene oxide to capron alcohol, caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl ristylalkohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol and the technical mixtures thereof with methyl chloride, butyl chloride, benzyl chloride or octyl chloride.
  • the mixed ethers are used together with further anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants.
  • anionic surfactants are soaps, alkyl benzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfate, sulfate etherate sulfate, hydroxymate amide sulfates, hydroxymate ether sulfates, hydroxymate ether sulfate, hydroxymate ether sulfates, Mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salt
  • nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, hydroxymixed ethers, optionally partially oxidized alk (en) yl oligoglycosides or glucoronic acid protein derivatives, especially fatty acid glucoronic acid products, fatty acid glucoronic acid derivatives, vegetable glucoronic acid protein derivatives, based on wheat), polyol fatty acid esters, sugar esters, sorbita nests, polysorbates and amine oxides. If the non-ionic surfactants polyglycol contain colether chains, these can have a conventional, but preferably a narrow, homolog distribution.
  • cationic surfactants are quaternary ammonium compounds, such as, for example, dimethyldistearylammonium chloride, and esterquats, in particular quaternized fatty acid trialkanolamine ester salts.
  • amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, relevant reviews include, for example, J.Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J.Falbe (ed.), " Catalysts, surfactants and mineral oil additives ", Thieme Verlag, Stuttgart, 1978, pp. 123-217.
  • Typical examples of particularly suitable surfactants are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, fatty acid isethionates, Fettklaresa rcosinate, fatty acid taurides, fatty acid glutamates, ⁇ -olefin sulfonates, ethercarboxylic acids, fatty acid glucamides, alkylamidobetaines, amphoacetals and / or protein fatty acid condensates, the latter preferably based on wheat proteins.
  • R 3 is an alkyl and / or alkenyl radical having 4 to 22 carbon atoms
  • G is a sugar radical having 5 or 6 carbon atoms
  • p is a number from 1 to 10.
  • the alkyl and / or alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or Alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the index number p in the general formula (II) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides, and stands for a number between 1 and 10.
  • the value p for a certain alkyl oligoglycoside is an analytically determined arithmetic parameter, which usually represents a fractional number.
  • Alkyl and / or alkenyl oligoglycosides with an average degree of oligomerization p of 1.1 to 3.0 are preferably used. From an application point of view, preference is given to those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4.
  • the alkyl or alkenyl radical R 3 can be derived from primary alcohols having 4 to 11, preferably 8 to 10, carbon atoms. Typical examples are butanol, capronic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and their technical mixtures, such as are obtained, for example, from hydrogenation of technical fatty acid methyl esters or in the course of the hydrogenation of aldehydes from Roelen's oxosynthesis.
  • the alkyl or alkenyl radical R 3 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14, carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol and the technical mixtures described above, which can be obtained as well as the technical mixtures described above.
  • Alkyl oligoglucosides based on hardened C 2 -C 4 coco alcohol with a DP of 1 to 3 are preferred.
  • the alkyl and / or alkenyl oligoglycosides can - based on the wet wipes - in amounts of 0.05 to 2 and preferably 0.5 to 1 wt .-% and - based on the concentrates in amounts of 10 to 50, preferably 25 to 25 wt .-%, the weight ratio of mixed ether to glycoside in the range of 10:90 to 90:10, preferably 25:75 to 75:25 and in particular 40:60 to 60:40.
  • Tissue papers to which the present invention relates can be constructed in one or more layers.
  • the papers have a weight per square meter of 10 to 65, preferably 15 to 30 g and a density of 0.6 g / cm 3 and less.
  • tissue papers to which the invention can extend are, of course, also toilet paper, paper tissues, facial cleaning tissues, make-up removing tissues, refreshing tissues and the like.
  • appropriate tissue fabrics made from fiber or fleece are also suitable.
  • a final object of the invention finally relates to the use of mixed ethers as impregnating agents for the production of wet wipes, in which they can be used in amounts of 0.01 to 2, preferably 0.5 to 1% by weight, based on the wipes.
  • the wet wipes can contain further conventional auxiliaries and additives, in particular complexing agents such as citric acid, HEDP or EDTA, which serve both to stabilize the ingredients and to improve the cleaning performance in the case of stains containing salt (for example water hardness), antibacterial urgent active ingredients, such as hydrogen peroxide or cationic surfactants, preferably ester quats, and skin care products contain.
  • complexing agents such as citric acid, HEDP or EDTA
  • antibacterial urgent active ingredients such as hydrogen peroxide or cationic surfactants, preferably ester quats
  • skin care products preferably moisturizers, oil components and emulsifiers, as are typically used in cosmetic products, are suitable as skin care products.
  • esters of linear C 6 -C 22 fatty acids with linear or branched C 6 -C 22 fatty alcohols or esters of branched C 6 come as oil bodies, for example -C ⁇ 3 - carboxylic acids with linear or branched C 6 -C 22 fatty alcohols, such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristy lerucat, cetyl myristate, Cetylpa Copy, cetyl stearate, Cetylisostearat, cetyl oleate, cetyl behenate, Cetylerucat, Stearylmyristat, Stearylpa Copy, stearyl stearate, Stearylisostearat, stearyl
  • dioctyl malates esters of linear and / or branched fatty acids with polyhydric alcohols (such as propylene glycol, dimer diol or trimer triol) and / or Guerbet alcohols, triglycerides based on C 6 -C0 0 fatty acids, liquid mono- / di- / triglyceride mixtures based on C 6 -C 8 fatty acids, esters of C 6 -C 22 fatty alcohols and / or Guerbet alcohols with aromatic carboxylic acids, especially benzoic acid, esters of C 2 -C 2 dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols with 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, linear and branched C 6 -C 22 fatty alcohol carbonates, wi e eg dicapry
  • Suitable emulsifiers are nonionic surfactants from at least one of the following groups:
  • Partial esters of polyglycerol (average degree of self-condensation 2 to 8), polyethylene glycol (molecular weight 400 to 5000), trimethylolpropane, pentaerythritol, sugar alcohols (e.g. sorbitol), alkyl glucosides (e.g. methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (e.g.
  • polyglucosides ) with saturated and / or unsaturated, linear or branched fatty acids with 12 to 22 carbon atoms and / or hydroxycarboxylic acids with 3 to 18 carbon atoms and their adducts with 1 to 30 moles of ethylene oxide; > Mixed esters of pentaerythritol, fatty acids, citric acid and fatty alcohol according to DE 1165574 PS and / or mixed esters of fatty acids with 6 to 22 carbon atoms, methyl glucose and polyols, preferably glycerol or polyglycerol.
  • Block copolymers e.g. Polyethylene glycol 30 dipolyhydroxystearate;
  • Polymer emulsifiers e.g. Pemulen types (TR-1, TR-2) from Goodrich;
  • the adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols or with castor oil are known, commercially available products. These are mixtures of homologs whose average degree of alkoxylation is based on the ratio of the amounts of ethylene oxide and / or propylene oxide and Substrate with which the addition reaction is carried out corresponds.
  • C 2 8 fatty acid monoesters and diesters of adducts of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
  • Suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid moglyceride, ricinoleic acid diglyceride Remonoglyceride, linoleic acid diglyceride, linolenic acid monoglyceride, linolenic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid diglyceride, malic acid diglyceride, malic acid diglyceride, malic acid diglyceride, malic acid diglyceride, malic acid diglyceride, malic acid dig
  • polyglycerol esters are polyglyceryl-2 dipolyhydroxystearate (Dehymuls® PGPH), polyglycerol-3-diisostearate (Lameform® TGI), polyglyceryl-4 isostateate (Isolan® GI 34), polyglyceryl-3 oleate, diisostearoyl polyglyearylate-3 (Isolan® PDI), Polyglyceryl-3 Methylglucose Distearate (Tego Care® 450), Polyglyceryl-3 Beeswax (Cera Bellina®), Polyglyceryl-4 Caprate (Polyglycerol Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether ( Chimexane® NL), Polyglyceryl-3 Distearate (Cremophor® GS 32) and Polyglyceryl Polyricinoleate (Admul® WOL 1403) Polyglyceryl Dimerate Isostearate
  • polystyrene resin examples include the mono-, di- and triesters of trimethylolpropane or pentaerythritol with lauric acid, coconut fatty acid, tallow fatty acid, palmitic acid, stearic acid, oleic acid, behenic acid and the like which are optionally reacted with 1 to 30 mol of ethylene oxide.
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylmethyl-3-hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate,
  • fatty acid amide derivative known under the CTFA name of Cocamidopropyl Betaine is particularly preferred.
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic Tensi- the those surface-active compounds which, apart from a C8 / ⁇ 8 alkyl or acyl group in the molecule at least one free amino group and at least one - COOH or -S0 3 H group and contain internal to form salts are qualified.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids, each with about 8 to 18 carbon atoms in the alkyl group.
  • ampholytic surfactants are the N-coconut alkyl aminopropionate, the coconut acylaminoethyl amino propionate and the C 2 -C 8 -acyl sarcosine.
  • cationic surfactants are also suitable as emulsifiers, those of the ester quat type, preferably methyl-quaternized di-fatty acid triethanolamine ester salts, being particularly preferred.
  • These preparations are preferably emulsions, preferably micro or PTT emulsions.
  • Examples 5 and 6 Comparative Example V2.
  • Various impregnation concentrates were produced and their viscosity (Höppler, 20 ° C) as well as their tendency to foam and their external appearance were examined. The results are summarized in Table 2. Examples 5 and 6 are according to the invention, example V2 is used for comparison.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
EP01931553A 2000-04-07 2001-03-30 Serviettes humides (iii) Expired - Lifetime EP1268741B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10017190A DE10017190C2 (de) 2000-04-07 2000-04-07 Feuchttücher (III)
DE10017190 2000-04-07
PCT/EP2001/003632 WO2001077281A1 (fr) 2000-04-07 2001-03-30 Serviettes humides (iii)

Publications (2)

Publication Number Publication Date
EP1268741A1 true EP1268741A1 (fr) 2003-01-02
EP1268741B1 EP1268741B1 (fr) 2004-09-29

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ID=7637828

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01931553A Expired - Lifetime EP1268741B1 (fr) 2000-04-07 2001-03-30 Serviettes humides (iii)

Country Status (6)

Country Link
US (1) US6797399B2 (fr)
EP (1) EP1268741B1 (fr)
AT (1) ATE278006T1 (fr)
DE (2) DE10017190C2 (fr)
ES (1) ES2228859T3 (fr)
WO (1) WO2001077281A1 (fr)

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Also Published As

Publication number Publication date
ATE278006T1 (de) 2004-10-15
DE10017190C2 (de) 2002-09-19
EP1268741B1 (fr) 2004-09-29
DE10017190A1 (de) 2001-10-18
ES2228859T3 (es) 2005-04-16
DE50103880D1 (de) 2004-11-04
WO2001077281A1 (fr) 2001-10-18
US20030138652A1 (en) 2003-07-24
US6797399B2 (en) 2004-09-28

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