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WO2018001717A2 - Produits d'entretien transparents pour textiles - Google Patents

Produits d'entretien transparents pour textiles Download PDF

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Publication number
WO2018001717A2
WO2018001717A2 PCT/EP2017/064364 EP2017064364W WO2018001717A2 WO 2018001717 A2 WO2018001717 A2 WO 2018001717A2 EP 2017064364 W EP2017064364 W EP 2017064364W WO 2018001717 A2 WO2018001717 A2 WO 2018001717A2
Authority
WO
WIPO (PCT)
Prior art keywords
acid
weight
fatty acid
liquid transparent
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2017/064364
Other languages
German (de)
English (en)
Other versions
WO2018001717A3 (fr
Inventor
Tatiana Schymitzek
Ulrich PLATZBECKER
Marine Cabirol
Hans Bouten
Roland Ettl
Ditmar Kischkel
Thomas Holderbaum
Jean-Marc Ricca
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
BASF SE
Original Assignee
Henkel AG and Co KGaA
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA, BASF SE filed Critical Henkel AG and Co KGaA
Publication of WO2018001717A2 publication Critical patent/WO2018001717A2/fr
Publication of WO2018001717A3 publication Critical patent/WO2018001717A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3715—Polyesters or polycarbonates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • the liquid transparent composition is particularly stable. Over long storage periods, the composition remains more transparent than
  • esterquats are widely suitable for the Faseravivage, have in recent years due to their better ecotoxicological compatibility conventional quaternary ammonium compounds such as the well-known Distearyldimethylammonium chloride displaced from the market to a good extent and are well known to those skilled in the field of fabric softeners from the prior art.
  • X is a saturated or unsaturated hydrocarbon radical having 1 to 8
  • R ', R "and R'" independently of one another represent a (C 2 to C 6) -hydroxyalkyl group, in particular 2-hydroxyethyl,
  • Reaction product contained amino group.
  • Alkanolamines of the formula (III) which are suitable as central nitrogen compounds for the purposes of the invention contain a hydroxyalkane radical (alkanol radical) having 2 to 6 carbon atoms, preferably 2 to 4 carbon atoms.
  • alkanol radical alkanol radical
  • triethanolamine is used.
  • the monocarboxylic acids of the formula II and the dicarboxylic acids of the formula I can be used in a molar ratio of 1:10 to 10: 1. However, it has proved to be advantageous to set a molar ratio of 1: 1 to 4: 1 and in particular 1.5: 1 to 3: 1.
  • Suitable nonionic emulsifiers for the liquid transparent compositions are the following nonionic emulsifiers:
  • the at least one and all other nonionic emulsifiers are selected from the group of nonionic emulsifiers having at least one, preferably at least two ethylene oxide groups.
  • the at least one first nonionic emulsifier must have an HLB value of at least 12.0, in particular of at least 13.0, preferably of at least 14.0, most preferably of at least 15.0. If the composition is two or more nonionic
  • the liquid transparent compositions further comprise a thickener (d) selected from a reaction product of at least one fatty acid having 8 to 32 carbon atoms and a polyethylene glycol having a weight average molecular weight of 600 to 10,000, wherein the ratio of the at least one fatty acid to the polyethylene glycol in the reaction product is 0.1 : 1 to 2: 1.
  • the thickener (d) in the liquid transparent composition is selected from a reaction product of at least one fatty acid having 12 to 24 carbon atoms and a polyethylene glycol having one
  • Composition in particular fabric conditioning formulation, and other emulsifiers, for example cationic and / or anionic emulsifiers.
  • the liquid transparent composition does not have a cationic emulsifier.
  • Condensation products of the abovementioned fatty acids with AEEA preferably imidazolines based on lauric acid or, in turn, C 12/14 coconut fatty acid, which are subsequently mixed with
  • the liquid transparent composition may contain the betaines in amounts of from 0.1 to 50% by weight, preferably from 1 to 30% by weight and in particular from 2 to 10% by weight, based on the liquid transparent composition.
  • Solvents that can be used in the liquid transparent composition are derived, for example, from the group of monohydric or polyhydric alcohols. Alkanolamines or glycol ethers are also possible, provided that they are miscible with water in the concentration range indicated.
  • the liquid transparent composition after storage for 16 weeks at 40 ° C still has an NTU value of 30 or less.
  • perfume oils may also contain natural fragrance mixtures such as are available from vegetable sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are muscatel, sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil,
  • the agents according to the invention can be dyed with suitable dyes.
  • Preferred dyes the choice of which presents no difficulty to the skilled person, have a high storage stability and insensitivity to the other ingredients of the agents and to light and no pronounced
  • Technical oligoglycene mixtures having an inherent degree of condensation of 1.5 to 10 such as technical diglycene mixtures having a diglycol content of 40 to 50% by weight,
  • Enzyme mixtures for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic acting Enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular interest.
  • lipolytic enzymes are the known cutinases.
  • Peroxidases or oxidases have also proved suitable in some cases.
  • Suitable amylases include, in particular, alpha-amylases, iso-amylases, pullulanases and pectinases.
  • cellulases are preferably cellobiohydrolases,
  • Optical brighteners can be added to the compositions according to the invention in order to eliminate graying and yellowing of the treated textiles. These fabrics impinge on the fiber and cause whitening and bleaching by transforming invisible ultraviolet radiation into visible longer wavelength light, emitting the ultraviolet light absorbed from the sunlight as faint bluish fluorescence, and pure with the yellowness of the grayed or yellowed wash White results.
  • Compounds originate, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, benzoxazole, Benzisoxazole and benzimidazole systems and substituted by heterocycles pyrene derivatives.
  • the optical brighteners are usually used in amounts between 0.1 and 0.3 wt .-%, based on the finished composition. Grayness inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus preventing the dirt from being rebuilt.
  • Water-soluble colloids of mostly organic nature are suitable for this purpose, for example the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether sulfonic acids or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • water-soluble polyamides containing acidic groups are suitable for this purpose.
  • soluble starch preparations and starch products other than those mentioned above, for example degraded starch, aldehyde starches etc.
  • Polyvinylpyrrolidone is also useful.
  • bacteriostats and bacteriocides, fungistats and fungicides, etc.
  • Important substances from these groups are, for example, benzalkonium chlorides.
  • Preferred compounds in the context of the present invention are, for example, alkylaryl sulfonates, halophenols and phenol mercuriacetate, it also being possible entirely to dispense with these compounds in the compositions according to the invention.
  • preservatives In order to achieve optimal performance characteristics and to protect the products against germs, it may be advantageous to add preservatives to the products. Infestation of the fabric softeners according to the invention by microorganisms can be prevented by the use of commercially available preservatives.
  • Another object of the invention is a process for the preparation of
  • the inventive method ensures that the liquid compositions of the invention can be prepared in a transparent form.
  • the liquid compositions of the present invention can be prepared repeatedly and without the purification of the devices used in the process in a transparent form.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne des produits d'entretien pour textiles et des formulations d'adoucissant optiquement clairs et transparents et de consistance visqueuse, contenant une combinaison de composés adoucissants cationiques avec des émulsifiants non ioniques et des épaississants spéciaux. L'invention concerne également l'utilisation de ces produits d'entretien pour textiles et de ces formulations d'adoucissant, ainsi qu'un procédé de lavage de textiles au moyen de ces produits d'entretien pour textiles et de ces formulations d'adoucissant. La présente invention concerne en outre des procédés de production de ces produits d'entretien pour textiles transparents liquides.
PCT/EP2017/064364 2016-06-30 2017-06-13 Produits d'entretien transparents pour textiles Ceased WO2018001717A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP16177323.9A EP3263680B1 (fr) 2016-06-30 2016-06-30 Produit clair d'entretien de textile
EP16177323.9 2016-06-30

Publications (2)

Publication Number Publication Date
WO2018001717A2 true WO2018001717A2 (fr) 2018-01-04
WO2018001717A3 WO2018001717A3 (fr) 2018-06-07

Family

ID=56296700

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2017/064364 Ceased WO2018001717A2 (fr) 2016-06-30 2017-06-13 Produits d'entretien transparents pour textiles

Country Status (2)

Country Link
EP (1) EP3263680B1 (fr)
WO (1) WO2018001717A2 (fr)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1156513A (fr) 1956-07-24 1958-05-19 Préparation permettant d'éliminer l'électricité statique des fibres textiles de synthèse
GB839407A (en) 1957-10-31 1960-06-29 British Nylon Spinners Ltd Detergent compositions
GB873214A (en) 1958-08-20 1961-07-19 British Nylon Spinners Ltd Non-ionic detergent compositions
DE2024051B2 (de) 1970-05-16 1979-10-04 Henkel Kgaa, 4000 Duesseldorf Verwendung der Veresterungsprodukte von Glycerin-Athylenoxid-Addukten mit Fettsauren als Rückfettungsmittel in kosmetischen Zubereitungen

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1165574B (de) 1960-08-08 1964-03-19 Dehydag Gmbh Verfahren zur Herstellung von als Emulgiermittel fuer Salbengrundlagen dienenden Mischestern
GB8905552D0 (en) * 1989-03-10 1989-04-19 Unilever Plc Fabric conditioning
ES2021900A6 (es) 1989-07-17 1991-11-16 Pulcra Sa Procedimiento de obtencion de tensioactivos cationicos derivados de amonio cuaternario con funcion amino-ester.
DE4026184A1 (de) 1990-08-18 1992-02-20 Henkel Kgaa Verfahren zur verminderung des restgehaltes an freiem alkylierungsmittel in waessrigen loesungen kationischer tenside
DE4137317A1 (de) * 1991-11-13 1993-05-19 Henkel Kgaa Ester von fettsaeuren mit ethoxylierten polyolen
DE4308792C1 (de) 1993-03-18 1994-04-21 Henkel Kgaa Verfahren zur Herstellung farb- und geruchstabiler quaternierten Fettsäuretriethanolaminester-Salze
DE4409322C1 (de) 1994-03-18 1995-04-06 Henkel Kgaa Verfahren zur Herstellung von Esterquats
ZA991635B (en) * 1998-03-02 1999-09-02 Procter & Gamble Concentrated, stable, translucent or clear, fabric softening compositions.
DE102015204206A1 (de) * 2014-12-17 2016-06-23 Henkel Ag & Co. Kgaa Transparente Textilpflegemittel
US7138366B2 (en) * 2002-11-01 2006-11-21 Colgate-Palmolive Company Aqueous composition comprising oligomeric esterquats
DE102014010875A1 (de) 2014-07-25 2016-01-28 Basf Se Transparente Textilpflegemittel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1156513A (fr) 1956-07-24 1958-05-19 Préparation permettant d'éliminer l'électricité statique des fibres textiles de synthèse
GB839407A (en) 1957-10-31 1960-06-29 British Nylon Spinners Ltd Detergent compositions
GB873214A (en) 1958-08-20 1961-07-19 British Nylon Spinners Ltd Non-ionic detergent compositions
DE2024051B2 (de) 1970-05-16 1979-10-04 Henkel Kgaa, 4000 Duesseldorf Verwendung der Veresterungsprodukte von Glycerin-Athylenoxid-Addukten mit Fettsauren als Rückfettungsmittel in kosmetischen Zubereitungen

Also Published As

Publication number Publication date
EP3263680A1 (fr) 2018-01-03
EP3263680B1 (fr) 2018-08-15
WO2018001717A3 (fr) 2018-06-07

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