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CN110813520A - Multistage independent water circulation flotation method for waste lead-acid storage batteries - Google Patents

Multistage independent water circulation flotation method for waste lead-acid storage batteries Download PDF

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Publication number
CN110813520A
CN110813520A CN201910809142.5A CN201910809142A CN110813520A CN 110813520 A CN110813520 A CN 110813520A CN 201910809142 A CN201910809142 A CN 201910809142A CN 110813520 A CN110813520 A CN 110813520A
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China
Prior art keywords
lead
sorting
materials
primary
waste
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Pending
Application number
CN201910809142.5A
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Chinese (zh)
Inventor
费跃波
陈炳敏
袁成
陈利华
施欢欢
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Zhejiang Zhekuang Heavy Industry Co Ltd
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Zhejiang Zhekuang Heavy Industry Co Ltd
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Priority to CN201910809142.5A priority Critical patent/CN110813520A/en
Publication of CN110813520A publication Critical patent/CN110813520A/en
Priority to PCT/CN2020/110418 priority patent/WO2021036919A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B9/00General arrangement of separating plant, e.g. flow sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B5/00Washing granular, powdered or lumpy materials; Wet separating
    • B03B5/28Washing granular, powdered or lumpy materials; Wet separating by sink-float separation
    • B03B5/30Washing granular, powdered or lumpy materials; Wet separating by sink-float separation using heavy liquids or suspensions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/54Reclaiming serviceable parts of waste accumulators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)
  • Separation Of Solids By Using Liquids Or Pneumatic Power (AREA)

Abstract

The invention discloses a multistage independent water circulation flotation method for waste lead-acid storage batteries, which comprises the steps of S1, extracting crushed materials; step S2, primary hydraulic separation; step S3 hydrodynamic sorting; step S4 secondary hydraulic separation; the method can improve the total recovery rate of lead and the recovery rate of plastics in the waste lead-acid batteries by carrying out water circulation sorting on the waste lead-acid batteries for multiple times, reduces the mutual doping rate of material sorting, reduces loss and reduces pollution to the environment.

Description

Multistage independent water circulation flotation method for waste lead-acid storage batteries
[ technical field ] A method for producing a semiconductor device
The invention relates to the technical field of waste battery treatment, in particular to the technical field of multistage independent flotation of waste lead-acid storage batteries.
[ background of the invention ]
At present, waste lead-acid batteries are a large pollution source in natural environment, if the waste lead-acid batteries are not properly treated, serious influence is caused on the environment, electrodes of the lead-acid batteries are mainly made of lead and oxides thereof, and electrolyte is a storage battery of sulfuric acid solution. In a discharge state, the main component of the positive electrode is lead dioxide, and the main component of the negative electrode is lead; in a charged state, the main components of the positive electrode and the negative electrode are lead sulfate. At present, the method for sorting waste lead-acid battery materials adopts multi-stage integrated hydraulic sorting for domestic and foreign similar equipment, the materials are subjected to one-stage hydraulic sorting and two-stage hydrodynamic sorting, but the water of the whole system comes from a ship-shaped scraper, and the water is weakly acidic and has strong corrosivity, so that the service life of the equipment is greatly shortened. Meanwhile, as the lead plaster in the ship-shaped scraper blade machine cannot be completely precipitated, a large amount of acid water containing the lead plaster enters the hydraulic separation system, the lead content of the separated lead grid, plastic and partition paper is very high, the separation precision is influenced, the total lead recovery rate is reduced, the subsequent material separation precision is poor, the impurity content is high, the lead plaster extraction rate is not high, certain waste is caused, and the environmental damage is great.
[ summary of the invention ]
The invention aims to solve the problems in the prior art, and provides a multistage independent water circulation flotation method for waste lead-acid storage batteries, which can improve the total recovery rate of lead in the waste lead-acid storage batteries, reduce the mutual doping rate of material separation, reduce waste, reduce the pollution to the environment and prolong the service life of equipment.
In order to realize the aim, the invention provides a multistage independent water circulation flotation method for waste lead-acid storage batteries, which comprises the following steps:
step S1 crushed material extraction: crushing and sorting the waste batteries at the front ends, and then, carrying out primary sorting on oversize products of the waste batteries;
step S2 primary hydraulic sorting: the oversize products after crushing and sorting are led into a first-level water conservancy sorting device and then automatically sortedThe chemical adding device automatically adds sodium carbonate to ensure that the density of liquid in the device reaches 1.1-1.2kg/m3So that the density of ABS, PP and the like in the material is less than 1.1kg/m3The light materials float on the water surface, heavy materials such as partition paper, lead grids and the like in the materials sink at the bottom of the primary hydraulic sorting device, a top auger conveyor is arranged at the top in the primary hydraulic sorting device, a bottom auger conveyor is arranged at the bottom of the top auger conveyor, the light materials floating on the water surface are moved out of the system through the top auger conveyor arranged in the primary hydraulic sorting device, and the heavy materials sinking at the bottom are conveyed into the hydrodynamic sorting device in the next step through the bottom auger conveyor;
step S3 hydrodynamic sorting: the hydrodynamic sorting device comprises a hydrodynamic separator, a vertical circulating pump, an impurity sorting screen, a hydrodynamic circulating water tank, a lead grid screw conveyor and a screw conveyor, wherein heavy materials enter the hydrodynamic separator, the vertical circulating pump provides high-pressure water from bottom to top to flush the materials, and the rising buoyancy is generated while the materials are flushed so that the lead grid in the materials is separated from other light materials, wherein the lead grid is deposited at the bottom and is moved out of the system through the lead grid screw conveyor;
step S4 secondary hydraulic sorting: quantitative sodium carbonate is added into the secondary hydraulic separation equipment through an automatic adding device, and the density of the liquid in the secondary hydraulic separation equipment is adjusted to 1.1-1.2kg/m3So that the plastic floats on the surface of the liquid and is removed from the system by the top auger and the separator paper sinks to the bottom and is removed from the system by the bottom auger.
Preferably, the crushed material extracted in step S1 is used to crush the waste lead-acid storage battery twice, the waste lead-acid storage battery raw material is firstly conveyed to a primary hammer crusher to perform primary coarse crushing on the waste battery, the primary coarse crushed raw material directly falls into a primary lead paste sorting sieve to be sorted after the primary crushing, a large amount of lead paste contained in the primary coarse crushed raw material falls through a screen, oversize materials enter a secondary hammer crusher through feeding equipment to perform secondary fine crushing, the secondary fine crushed raw material directly falls into a secondary lead paste sorting sieve to perform secondary sorting, and the lead paste contained in the secondary fine crushed raw material falls through the screen.
Preferably, the crushed material extracted in step S1 is separated from the lead plaster by wet separation, and the lead plaster at the upper end of the separation screen is dropped through the separation screen by high-pressure water washing.
Preferably, the liquids in the step S2 primary hydraulic separation, the step S3 hydraulic separation and the step S4 secondary hydraulic separation are independently circulated and do not interfere with each other.
The multistage independent water circulation flotation method for the waste lead-acid storage batteries has the beneficial effects that: the method can improve the total recovery rate of lead and the recovery rate of plastics in the waste lead-acid batteries by carrying out water circulation sorting on the waste lead-acid batteries for multiple times, reduces the mutual doping rate of material sorting, reduces loss and reduces pollution to the environment.
The features and advantages of the present invention will be described in detail by embodiments in conjunction with the accompanying drawings.
[ description of the drawings ]
Fig. 1 is a schematic view of the working flow of the multistage independent water circulation flotation method for the waste lead-acid storage battery.
[ detailed description ] embodiments
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail below with reference to the accompanying drawings and examples. It should be understood, however, that the description herein of specific embodiments is only intended to illustrate the invention and not to limit the scope of the invention. Moreover, in the following description, descriptions of well-known structures and techniques are omitted so as to not unnecessarily obscure the concepts of the present invention
The invention relates to a multistage independent water circulation flotation method for waste lead-acid storage batteries, which comprises the following steps:
step S1 crushed material extraction: crushing and sorting the waste batteries at the front ends, and then, carrying out primary sorting on oversize products of the waste batteries;
step S2 primary hydraulic sorting: guiding the crushed and sorted oversize materials into a first-stage water conservancy sorting device, and then automatically adding sodium carbonate by an automatic medicine adding device to ensure that the density of liquid in the device reaches 1.1-1.2kg/m3So that the density of ABS, PP and the like in the material is less than 1.1kg/m3The light materials float on the water surface, heavy materials such as partition paper, lead grids and the like in the materials sink at the bottom of the primary hydraulic sorting device, a top auger conveyor is arranged at the top in the primary hydraulic sorting device, a bottom auger conveyor is arranged at the bottom of the top auger conveyor, the light materials floating on the water surface are moved out of the system through the top auger conveyor arranged in the primary hydraulic sorting device, and the heavy materials sinking at the bottom are conveyed into the hydrodynamic sorting device in the next step through the bottom auger conveyor;
step S3 hydrodynamic sorting: the hydrodynamic sorting device comprises a hydrodynamic separator, a vertical circulating pump, an impurity sorting screen, a hydrodynamic circulating water tank, a lead grid screw conveyor and a screw conveyor, wherein heavy materials enter the hydrodynamic separator, the vertical circulating pump provides high-pressure water from bottom to top to flush the materials, and the rising buoyancy is generated while the materials are flushed so that the lead grid in the materials is separated from other light materials, wherein the lead grid is deposited at the bottom and is moved out of the system through the lead grid screw conveyor;
step S4 secondary hydraulic sorting: second-level hydraulic separation device by automatic adding deviceAdding quantitative sodium carbonate in the secondary hydraulic separation equipment, and adjusting the liquid density in the secondary hydraulic separation equipment to 1.1-1.2kg/m3So that the plastic floats on the surface of the liquid and is removed from the system by the top auger and the separator paper sinks to the bottom and is removed from the system by the bottom auger.
Wherein, the step S1 of extracting the crushed materials is to crush the waste lead-acid storage batteries twice, the raw materials of the waste lead-acid storage batteries are firstly conveyed to a primary hammer crusher to carry out primary coarse crushing on the waste batteries, the primary coarse crushed raw materials directly fall into a primary lead paste sorting sieve to be sorted after the primary crushing, a large amount of lead paste contained in the primary coarse crushed raw materials falls down through a screen, oversize products enter a secondary hammer crusher through feeding equipment to carry out secondary fine crushing, the secondary fine crushed raw materials directly fall into a secondary lead paste sorting sieve to carry out secondary sorting, the lead paste contained in the secondary fine crushed raw materials falls down through the screen, the step S1 of extracting the crushed materials from the crushed materials and the lead paste separation adopt a wet sorting method, the lead paste on the upper end of the sorting sieve falls down through the sorting screen by high-pressure washing assistance, and the steps S2 of primary hydraulic sorting, S3 of hydrodynamic sorting and S4 of secondary hydraulic sorting are all independent and cyclic liquids, do not interfere with each other.
The working process of the invention is as follows:
in the working process of the multistage independent water circulation flotation method for the waste lead-acid storage batteries, the waste lead-acid storage batteries are subjected to water circulation sorting for multiple times, so that the total recovery rate of lead in the waste lead-acid storage batteries can be improved, the mutual doping rate of material sorting is reduced, the waste is reduced, and the pollution to the environment is reduced.
The above embodiments are illustrative of the present invention, and are not intended to limit the present invention, and any simple modifications of the present invention are within the scope of the present invention.

Claims (4)

1. A multistage independent water circulation flotation method for waste lead-acid storage batteries is characterized by comprising the following steps: the method comprises the following steps:
step S1 crushed material extraction: crushing and sorting the waste batteries at the front ends, and then, carrying out primary sorting on oversize products of the waste batteries;
step S2 primary hydraulic sorting: guiding the crushed and sorted oversize materials into a first-stage water conservancy sorting device, and then automatically adding sodium carbonate by an automatic medicine adding device to ensure that the density of liquid in the device reaches 1.1-1.2kg/m3So that the density of ABS, PP and the like in the material is less than 1.1kg/m3The light materials float on the water surface, heavy materials such as partition paper, lead grids and the like in the materials sink at the bottom of the primary hydraulic sorting device, a top auger conveyor is arranged at the top in the primary hydraulic sorting device, a bottom auger conveyor is arranged at the bottom of the top auger conveyor, the light materials floating on the water surface are moved out of the system through the top auger conveyor arranged in the primary hydraulic sorting device, and the heavy materials sinking at the bottom are conveyed into the hydrodynamic sorting device in the next step through the bottom auger conveyor;
step S3 hydrodynamic sorting: the hydrodynamic sorting device comprises a hydrodynamic separator, a vertical circulating pump, an impurity sorting screen, a hydrodynamic circulating water tank, a lead grid screw conveyor and a screw conveyor, wherein heavy materials enter the hydrodynamic separator, the vertical circulating pump provides high-pressure water from bottom to top to flush the materials, and the rising buoyancy is generated while the materials are flushed so that the lead grid in the materials is separated from other light materials, wherein the lead grid is deposited at the bottom and is moved out of the system through the lead grid screw conveyor;
step S4 secondary hydraulic sorting: quantitative sodium carbonate is added into the secondary hydraulic separation equipment through an automatic adding device, and the density of the liquid in the secondary hydraulic separation equipment is adjusted to 1.1-1.2kg/m3So that the plastic floats on the liquid level,and removed from the system by the top auger, the separator paper sinks to the bottom, and is removed from the system by the bottom auger.
2. The multistage independent water circulation flotation method for the waste lead-acid storage batteries according to claim 1, characterized by comprising the following steps: the step S1 is characterized in that the crushed material is extracted to crush the waste lead-acid storage battery twice, the waste lead-acid storage battery raw material is conveyed to a primary hammer crusher to carry out primary coarse crushing on the waste battery, the primary coarse crushed raw material directly falls into a primary lead plaster separation sieve to be separated after the primary crushing, a large amount of lead plaster contained in the primary coarse crushed raw material falls down through a screen, oversize materials enter a secondary hammer crusher through feeding equipment to be subjected to secondary fine crushing, the secondary fine crushed raw material directly falls into the secondary lead plaster separation sieve to be subjected to secondary separation, and the lead plaster contained in the secondary fine crushed raw material falls down through the screen.
3. The multistage independent water circulation flotation method for the waste lead-acid storage batteries according to claim 1, characterized by comprising the following steps: and S1, extracting the crushed materials, separating the crushed materials from the lead plaster by adopting a wet separation method, and washing the lead plaster at the upper end of the separation screen by high pressure water to assist the lead plaster to fall through the separation screen.
4. The multistage independent water circulation flotation method for the waste lead-acid storage batteries according to claim 1, characterized by comprising the following steps: the liquid in the step S2 primary hydraulic separation, the step S3 hydraulic separation and the step S4 secondary hydraulic separation are independently circulated and do not interfere with each other.
CN201910809142.5A 2019-08-29 2019-08-29 Multistage independent water circulation flotation method for waste lead-acid storage batteries Pending CN110813520A (en)

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CN201910809142.5A CN110813520A (en) 2019-08-29 2019-08-29 Multistage independent water circulation flotation method for waste lead-acid storage batteries
PCT/CN2020/110418 WO2021036919A1 (en) 2019-08-29 2020-08-21 Multistage independent water circulation flotation method for used lead-acid batteries

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN112186172A (en) * 2020-09-09 2021-01-05 湖南恒晟环保科技有限公司 Combined processing technology of lead plaster treatment modification and flotation
WO2021036919A1 (en) * 2019-08-29 2021-03-04 浙江浙矿重工股份有限公司 Multistage independent water circulation flotation method for used lead-acid batteries
CN113499853A (en) * 2021-07-08 2021-10-15 湖南江冶新能源科技股份有限公司 Hydrodynamic sorting and wet stripping process for waste lithium ion battery crushed materials
CN115230020A (en) * 2022-07-19 2022-10-25 浙江天能电源材料有限公司 Intelligent sorting system and method for heavy plastics of waste storage batteries

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CA1333960C (en) * 1986-01-09 1995-01-17 Marco Olper Hydrometallurgical process for an overall recovery of the components of exhausted lead-acid batteries
CN104752786A (en) * 2015-04-03 2015-07-01 阳煤集团山西吉天利科技有限公司 Waste lead-acid battery high-efficiency sorting recycling process
CN105846005A (en) * 2016-03-22 2016-08-10 安徽华铂再生资源科技有限公司 Waste lead-acid storage battery crushing-and-separation one-step energy-saving recycling process
CN107623151A (en) * 2017-08-31 2018-01-23 浙江浙矿重工股份有限公司 A kind of lead-acid accumulator reclaiming technique

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CN103490115B (en) * 2013-09-02 2015-08-12 浙江天能电源材料有限公司 A kind of Battery recycling piece-rate system
US20160308261A1 (en) * 2013-12-03 2016-10-20 Verdeen Chemicals, Inc. Zero lead pollution process for recycling used lead acid batteries
CN110813520A (en) * 2019-08-29 2020-02-21 浙江浙矿重工股份有限公司 Multistage independent water circulation flotation method for waste lead-acid storage batteries

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Publication number Priority date Publication date Assignee Title
CA1333960C (en) * 1986-01-09 1995-01-17 Marco Olper Hydrometallurgical process for an overall recovery of the components of exhausted lead-acid batteries
CN104752786A (en) * 2015-04-03 2015-07-01 阳煤集团山西吉天利科技有限公司 Waste lead-acid battery high-efficiency sorting recycling process
CN105846005A (en) * 2016-03-22 2016-08-10 安徽华铂再生资源科技有限公司 Waste lead-acid storage battery crushing-and-separation one-step energy-saving recycling process
CN107623151A (en) * 2017-08-31 2018-01-23 浙江浙矿重工股份有限公司 A kind of lead-acid accumulator reclaiming technique

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021036919A1 (en) * 2019-08-29 2021-03-04 浙江浙矿重工股份有限公司 Multistage independent water circulation flotation method for used lead-acid batteries
CN112186172A (en) * 2020-09-09 2021-01-05 湖南恒晟环保科技有限公司 Combined processing technology of lead plaster treatment modification and flotation
CN112186172B (en) * 2020-09-09 2023-01-10 湖南恒晟环保科技有限公司 Combined processing technology of lead plaster treatment modification and flotation
CN113499853A (en) * 2021-07-08 2021-10-15 湖南江冶新能源科技股份有限公司 Hydrodynamic sorting and wet stripping process for waste lithium ion battery crushed materials
CN115230020A (en) * 2022-07-19 2022-10-25 浙江天能电源材料有限公司 Intelligent sorting system and method for heavy plastics of waste storage batteries
CN115230020B (en) * 2022-07-19 2023-10-03 浙江天能电源材料有限公司 Intelligent sorting system and method for heavy plastic of waste storage battery

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Address after: 313100 Industrial Park, Heping Town, Changxing County, Huzhou, Zhejiang

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Application publication date: 20200221