CN109825386B - Soap grain containing organic sodium gluconate and environment-friendly soap - Google Patents
Soap grain containing organic sodium gluconate and environment-friendly soap Download PDFInfo
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- CN109825386B CN109825386B CN201910087476.6A CN201910087476A CN109825386B CN 109825386 B CN109825386 B CN 109825386B CN 201910087476 A CN201910087476 A CN 201910087476A CN 109825386 B CN109825386 B CN 109825386B
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- soap
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- friendly
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- 239000000344 soap Substances 0.000 title claims abstract description 275
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 title claims abstract description 59
- 239000000176 sodium gluconate Substances 0.000 title claims abstract description 59
- 235000012207 sodium gluconate Nutrition 0.000 title claims abstract description 59
- 229940005574 sodium gluconate Drugs 0.000 title claims abstract description 59
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 62
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- 239000002738 chelating agent Substances 0.000 claims abstract description 49
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 24
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 24
- 235000011187 glycerol Nutrition 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 19
- 239000000194 fatty acid Substances 0.000 claims abstract description 19
- 229930195729 fatty acid Natural products 0.000 claims abstract description 19
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 18
- PQHYOGIRXOKOEJ-UHFFFAOYSA-N 2-(1,2-dicarboxyethylamino)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NC(C(O)=O)CC(O)=O PQHYOGIRXOKOEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
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- 150000001875 compounds Chemical class 0.000 claims description 21
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- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 18
- JOOXCMJARBKPKM-UHFFFAOYSA-N 4-oxopentanoic acid Chemical compound CC(=O)CCC(O)=O JOOXCMJARBKPKM-UHFFFAOYSA-N 0.000 claims description 16
- 239000000284 extract Substances 0.000 claims description 16
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 16
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 11
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 10
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 10
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- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 10
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 10
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- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 9
- 229940080279 sodium cocoate Drugs 0.000 claims description 9
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 claims description 8
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- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 claims description 8
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- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 claims description 8
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- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 claims description 7
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- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 claims description 7
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Abstract
本发明涉及日化香皂技术领域，具体涉及一种含有有机葡萄糖酸钠的皂粒及环保皂。该皂粒包括如下重量百分比的原料：混合脂肪酸60‑80份、液碱27‑38份、精制甘油2‑10份、金属螯合剂0.2‑1.5份、精制盐0.5‑1.0份和去离子水4.5‑6.5份；所述金属螯合剂为有机葡糖酸钠，或者为有机葡萄糖酸钠、亚氨基二琥珀酸和二聚天冬氨酸钠的混合物。本发明的皂粒以有机葡萄酸钠作为主要螯合剂，能在较高pH值条件下仍能将水中和污垢中的重金属离子螯合，并避免金属离子引起皂粒的氧化、变质和异味，且有机葡萄酸钠具有易生物降解的环保特点，提高了皂粒的环境友好性，且皂粒具有去污效果佳、不刺激人体皮肤、安全性高的特点。The invention relates to the technical field of daily chemical soap, in particular to a soap particle and environmental protection soap containing organic sodium gluconate. The soap particles include the following raw materials by weight percentage: 60-80 parts of mixed fatty acids, 27-38 parts of liquid caustic soda, 2-10 parts of refined glycerin, 0.2-1.5 parts of metal chelating agent, 0.5-1.0 parts of refined salt and 4.5 parts of deionized water 6.5 parts; the metal chelating agent is organic sodium gluconate, or a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dimerized aspartate. The soap particles of the invention use organic sodium gluconate as the main chelating agent, which can still chelate heavy metal ions in water and dirt under the condition of higher pH value, and avoid the oxidation, deterioration and peculiar smell of soap particles caused by metal ions. Moreover, the organic sodium gluconate has the environmental protection characteristics of being easily biodegradable, which improves the environmental friendliness of the soap particles, and the soap particles have the characteristics of good decontamination effect, no irritation to human skin, and high safety.
Description
Technical Field
The invention relates to the technical field of daily chemical toilet soap, in particular to a soap grain containing organic sodium gluconate and an environment-friendly soap.
Background
At present, in the production of soap particles and daily chemical product laundry soap and soap in the base oil chemical industry, peculiar smell or color change of the soap particles or the soap is usually caused by oxidation of unsaturated fatty acid caused by trace metal ions, and a metal chelating agent is usually added in the production process for chelating trace heavy metal ions possibly existing in the soap particles or the soap, so that the peculiar smell and the color change caused by oxidation of unsaturated acid of the soap caused by the metal ions are avoided, the shelf life of the soap particles and the soap can be prolonged, and the effect of softening water quality can be achieved.
Currently, an amino-carboxyl chelating agent is mostly adopted in the soap particle production process, and the amino-carboxyl chelating agent is an organic complexing agent with both amino and carboxyl. At present, dozens of ammonia-carboxyl coordination agents are researched, wherein the most widely applied agents are ethylenediaminetetraacetic acid tetrasodium salt and disodium salt thereof, namely EDTA-4Na and EDTA-2Na, under the condition of soap particle alkalinity (PH10-11), for heavy metal iron ions (trivalent), ferric hydroxide is easy to generate and precipitates without being chelated, and the chelatability of the ferric hydroxide is influenced, so that under the alkaline condition, for the chelation of the heavy metal iron ions, the chelating agent of ammonia acids can not meet the chelating requirement. Other commonly used chelating agents for amino acids, mainly diethylenetriaminepentaacetic acid (DTPA), hydroxyethylenediaminetriacetic acid (HEDTA), etc., are also used in conventional soap granules and soaps.
However, after the chelating agent is chelated with heavy metal ions, the produced chelate can not be degraded through biochemical treatment and always exists in soil, and along with the wide use and the accumulation of time of soap products, the chelate can certainly cause great pollution to the soil and damage to the whole ecological environment.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide a soap grain containing organic sodium gluconate, the soap granule uses organic sodium gluconate as a main metal ion chelating agent to replace the currently adopted aminocarboxylic chelating agent, has strong metal chelating property, particularly under alkaline conditions, has higher chelating performance to metal ions (particularly iron ions), and the metal ions are included in the chelating agent to become a stable compound with higher molecular weight, thereby preventing the metal ions from acting, avoiding the oxidation of soap particles caused by the heavy metal ions, thereby causing deterioration and peculiar smell, the organic sodium gluconate and the chelate thereof have the characteristics of environmental protection and easy biodegradation, the environmental friendliness of the soap particles is improved, the product is natural chelating agent, and has the advantages of no irritation to human skin and high safety.
The invention also aims to provide the environment-friendly soap prepared from the soap granules containing the organic sodium gluconate, the environment-friendly soap is mild and safe in raw materials, the antibacterial, anti-inflammatory, moisturizing and nourishing performances of the environment-friendly soap can be improved by adopting a plant extract and a moisturizing factor, the skin is effectively protected, the permeability of the skin is improved, the elasticity of the skin is increased, the skin color is improved, the dirt removing capability and the moisturizing capability of the environment-friendly soap are improved by using a compound enzyme, the skin is not damaged, the softness of the environment-friendly soap is improved by using a softening agent, the skin does not generate tight feeling after cleaning and use, the bubble force and the foam stability of the environment-friendly soap are improved, the dirt particles are prevented from being reprecipitated, the stimulation of the soap to the skin is inhibited, and the cleaning and decontaminating capability of the environment-friendly soap is improved.
The purpose of the invention is realized by the following technical scheme: the soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is organic sodium gluconate or a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate.
The organic sodium gluconate is used as a main metal ion chelating agent, so that metal ions (such as calcium ions, magnesium ions, iron ions and the like) in water and dirt can be chelated to form a stable chelate, the dirt is prevented from being precipitated, and the phenomenon that soap grains are oxidized by the metal ions to cause deterioration is avoided.
Preferably, the mixing ratio of the organic sodium gluconate to the iminodisuccinic acid to the sodium dipolyaspartate is 2-4:1: 1.5-2.5.
In addition, the organic sodium gluconate, the iminodisuccinic acid and the sodium aspartate are mixed to be used as a metal chelating agent, and the mixing proportion is strictly controlled, so that the metal chelating effect of the soap particles can be obviously improved, the biodegradation is easy, and the dirt-removing power and the environmental protection performance of the soap particles are effectively improved; the adopted iminodisuccinic acid is phosphorus-free, nontoxic and pollution-free and is easy to biodegrade, anions of the iminodisuccinic acid can form a coordination geometric structure with metal cations, the iminodisuccinic acid has strong chelating force on calcium, magnesium, zinc and other transition metal ions, the chelating ability on heavy metal ions such as copper, iron, manganese, nickel and the like is equivalent to that of other common chelating agents such as EDTA and the like, and the iminodisuccinic acid can be matched with organic sodium gluconate and sodium aspartate to obviously improve the chelating force; the adopted sodium dipolyaspartate is a water-soluble polymer, has the characteristics of no phosphorus, no toxicity, no pollution and complete biodegradation, has strong chelating capacity to ions, has double effects of corrosion inhibition and scale inhibition, has good scale inhibition effect on scale forming salts such as calcium carbonate, calcium sulfate, barium sulfate, calcium phosphate and the like, and can effectively improve the metal ion chelating and dirt removing capacity of soap particles.
Preferably, each part of the mixed fatty acid comprises 4-5 parts of lauric acid, 2-4 parts of palmitic acid, 2-4 parts of oleic acid and 0.2-0.5 part of linoleic acid; the mass fraction of the liquid caustic soda is 32-40%.
According to the invention, by adopting the mixed fatty acid, the foamability and the decontamination and cleaning capability of the soap particles can be effectively improved, so that the foam is very fine and smooth, mild and skin-friendly, no stimulation is generated to the skin, the mild protection of the soap particles to the skin is improved, and the safety is high; the lauric acid is a medium-carbon chain fatty acid, so that the foamability of the soap particles can be improved, the soap particles can foam instantly, meanwhile, the foam is very fine and smooth, the skin feel is soft, the lauric acid and the palmitic acid are both saturated fatty acids and have very good oxidation stability, the environment-friendly soap prepared by processing is not easy to oxidize and easy to store, and the service life of the environment-friendly soap is prolonged; the adopted oleic acid is very mild to the skin and has better cleaning power, but the excessive oleic acid is easy to reduce the oxidation stability of soap particles, so the dosage of the oleic acid is controlled to be 2-4 parts; the adopted linseed oil acid has two double bonds, is extremely mild and fresh to the skin, improves the use refreshing feeling of the environment-friendly soap, does not damage the skin, but easily reduces the oxidation stability of soap particles due to excessive linseed oil acid, easily causes the prepared environment-friendly soap to be soft and collapsed, and therefore the dosage of the environment-friendly soap is strictly controlled to be 0.2-0.5 part.
Preferably, the soap granule containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 25-35% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 55-65% saponification reaction at the temperature of 80-90 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 105-125 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 10-13%, and then refining, extruding, stripping, granulating and forming the soap base to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 105-125 ℃, the vacuum degree is-880 mbar, and the refined particle temperature of soap particles is 40-50 ℃.
The soap particles are prepared by the steps, so that the operation is simple, the control is convenient, the production efficiency is high, the production cost is low, the soap particles can be used for large-scale production, the prepared soap particles have high chelating activity and good formability by strictly controlling the process steps and the process parameters, the soap particles do not collapse after being mutually dissolved with water, the soap particles are not easy to oxidize, turn yellow and deteriorate, and the stability of the soap particles is improved; by respectively dissolving refined glycerol and a metal chelating agent in deionized water and adding the refined glycerol and the metal chelating agent into the premix, the mixing uniformity of the refined glycerol, the metal chelating agent, the mixed fatty acid and the liquid alkali is improved, the dispersibility of the metal chelating agent in soap particles is improved, and the chelating and cleaning performance of the metal chelating agent in the cleaning process is fully exerted; and refined salt is added, so that glycerin, excessive alkali liquor and water can be separated from the soap base, and the purity and the formability of the soap base are improved.
The other purpose of the invention is realized by the following technical scheme: the environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
the environment-friendly soap disclosed by the invention adopts the raw materials which are mild and safe, has better dirt-removing and cleaning capabilities, is mild and skin-friendly, has no stimulation to skin, and can be used for improving the moisture retention and permeability of the skin when being used as a facial soap or a washing soap; the plant extract and the moisturizing factor are adopted, so that the antibacterial, anti-inflammatory, moisturizing and nourishing performances of the environment-friendly soap can be improved, the skin is effectively protected, the permeability of the skin is improved, the elasticity of the skin is increased, the skin color is lightened, the dirt-removing capacity and the moisturizing capacity of the environment-friendly soap are improved through the compound enzyme, the skin is not damaged, the softness of the environment-friendly soap is improved through the emollient, the skin does not feel tight after being cleaned and used, the air bubble force and the foam stability of the environment-friendly soap are improved, the dirt particles are prevented from being reprecipitated, the stimulation to the skin is inhibited, and the cleaning and dirt-removing capacity of the environment-friendly soap is improved; the adopted surfactant can improve the emulsifying property and the cleaning and decontaminating capacity of the environment-friendly soap. After the metal chelating agent of the soap particles is chelated with metal ions in water and dirt, and the metal ions are removed from the soap particles and the grease dirt on the surface is removed by the compound enzyme, the skin permeation and absorption performance of subsequent plant extracts and moisturizing factors is facilitated, and the antibacterial, anti-inflammatory, moisturizing and nourishing effects of the plant extracts and the moisturizing factors on the skin are improved; the adopted natural essence can improve the faint scent of the environment-friendly soap, relieve the spirit and improve the skin care effects of diminishing inflammation, replenishing water, removing acnes, moistening and the like of the environment-friendly soap.
According to the environment-friendly soap disclosed by the invention, after the metal chelating agent in the soap granules carries out metal chelation on water and dirt and removes metal ions, the mild decontamination effect of the environment-friendly soap is improved by combining with the compound enzyme, and meanwhile, the clean environment can promote the plant extract, the moisturizing factor and the emollient to play a role in nourishing the skin, so that the dual effects of cleaning and moisturizing the environment-friendly soap are realized.
Preferably, each part of the compound enzyme is prepared from protease, superoxide dismutase, lipolytic enzyme and sphingomyelin enzyme in a weight ratio of 2-3:1: 1-2: 0.5-1.0; each part of the plant extract comprises 0.3-0.8 part of chlorella extract, 0.4-0.8 part of wild chrysanthemum extract and 0.2-0.6 part of sea grape extract.
By adopting the composite enzyme, the skin-friendly soap is mild, has good cleaning and dirt-removing capabilities, and can not damage the skin when being used as a facial soap or a washing soap; the adopted protein enzyme can hydrolyze keratin, mildly and targetedly remove skin keratin and soften skin; the superoxide dismutase adopted can improve the anti-oxidation effect of the skin and eliminate oxygen free radicals; the adopted lipolysis ferment can effectively remove the solidified sebum on the surface of the skin and remove garbage dirt such as acne, blackhead and the like; the adopted sphingomyelin ferment can improve the balance moisturizing performance of the environment-friendly soap, permeate into the deep layer of skin, supplement water and moisten deeply, and combine with moisturizing factors to improve the moisturizing effect of the environment-friendly soap, thereby avoiding the phenomenon of water shortage and dry wrinkle after cleaning; the compound enzyme is combined with a plurality of components, so that the prepared environment-friendly soap can break down pore grease and discharge, hydrolyze keratin, remove cutin, clear oxygen free radicals, decompose skin deep melanin, permeate skin deep in time to supplement water, and improve the cleanness, moisture retention and oxidation resistance of the environment-friendly soap.
By adopting the plant extracts, after soap grains are chelated to remove metal ions and the compound enzyme is used for removing surface grease dirt, the soap grains can effectively permeate into the skin to play a role in resisting bacteria, diminishing inflammation, preserving moisture and nourishing the skin; the adopted chlorella extract is rich in nutrients such as protein, lipid, carbohydrate, mineral substances, vitamins, water and the like, contains CGF active factors, and can improve the functions of moisturizing, nourishing, repairing and regenerating skin, whitening, removing freckles and resisting skin aging of the environment-friendly soap; the adopted wild chrysanthemum extract can effectively improve the antibacterial and anti-inflammatory effects of the environment-friendly soap; the adopted sea grape extract can enable the prepared environment-friendly soap to stimulate synthetic aquaporins of human skin, promote the circulation of water molecules and improve the moisturizing effect of the environment-friendly soap.
Preferably, each part of the moisturizing factor is at least one of acetylated sodium hyaluronate, provitamin B5, maltitol, hydrolyzed glycosaminoglycans and sodium PCA; each part of the softening agent is formed by mixing 0.2-0.5 part of glyceryl oleate, 3-5 parts of calcium gluconate, 1-1.5 parts of levulinic acid and 2-4 parts of octyl dodecanol lauroyl glutamate.
By adopting the moisturizing factors, the invention can comprehensively clean the skin and timely supplement moisture, thereby avoiding the phenomenon of water shortage and dry and wrinkle after comprehensive cleaning and improving the cleaning and moisturizing effects of the environment-friendly soap; the adopted sodium hyaluronate is hyaluronic acid-derivative, is easy to use due to the amphiphilic property, can soften horny layer, has high water retention capacity (more than 2 times higher than the conventional hyaluronic acid), is mild and non-irritant to skin, and is firmly kept on the surface of the skin to prevent water from evaporating from the skin, so that the environment-friendly soap has the water retention and locking effects when being used as a facial soap, and the phenomenon of tightness after cleaning is avoided; the adopted provitamin B5 has good permeability, is mild and non-irritant, can penetrate through the surface layer of the skin to achieve the effect of deep moisturizing, can stimulate the division and proliferation of cells, promote the proliferation of elastic fibers, assist in repairing skin tissues, diminish inflammation, heal damaged skin cells and improve the moisturizing, repairing and skin care effects of the environment-friendly soap; the maltitol has mild performance and high hygroscopicity, can absorb moisture in the air, enables the moisture to be combined with cells, and improves the moisture-preserving and water-locking effects of the environment-friendly soap on the skin; the adopted hydrolyzed glycosaminoglycans are mild and safe, have high skin-friendly property and excellent water locking effect and osmosis effect, can increase the hydration degree of the environment-friendly soap and the skin, improve the elasticity and compactness of the skin, and improve the moisture retention, water locking, skin elasticity improvement, oxidation resistance, wrinkle removal and aging resistance of the environment-friendly soap; the adopted sodium PCA belongs to natural moisturizing factors, is mild and safe, can absorb moisture in the air, enables the moisture to be combined with cells, can effectively improve the moisture of the stratum corneum of the skin and promotes the metabolism of the cells, and if the dosage of the sodium PCA is too small, the sodium PCA can easily absorb the moisture in the skin reversely to cause the skin to be lack of water, so that the dosage of the moisturizing factors is strictly controlled to be 3-7 parts.
More preferably, each part of the moisturizing factor is prepared from acetylated sodium hyaluronate, provitamin B5 and hydrolyzed glycosaminoglycans in a weight ratio of 2-3: 1.5-2.5: 1.
By adopting the softening agent, the softening texture of the environment-friendly soap can be improved, the effect of softening the skin can be achieved, and the phenomenon that the skin is tight after being cleaned is avoided; the glyceryl oleate belongs to unsaturated refined glyceride, can effectively improve the emulsifying property and certain viscosity of the environment-friendly soap, and can promote the mutual solubility of the raw materials; the calcium gluconate has better moisturizing effect, can permeate into skin cells to condition the water-oil balance of the cells and increase the water-moistening degree and the soft-moistening degree of the skin; the levulinic acid is mild and safe, and can regulate the pH value and the lubrication degree of the skin to a certain extent, so that the skin is in a healthy state of water-oil balance and acid-base balance.
Preferably, the surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate isethionate in a weight ratio of 2-3: 1; the natural essence is at least one of tea tree essential oil, thyme essential oil, lavender essential oil, sandalwood essential oil, sage essential oil, eucalyptus essential oil and clove essential oil.
By adopting the surfactant, the invention can improve the hydrophily and lipophilicity of the environment-friendly soap, promote the removal of dirt and improve the dirt-removing capacity and the dispersibility of the environment-friendly soap; the adopted sodium cocoate isethionate has excellent skin-friendly mildness, good high foamability, easy air bubble, rich and fine foam, and can promote the foamability and the detergency of the environment-friendly soap, and the sodium cocoate isethionate is compounded with sodium dodecyl sulfate to improve the cleaning and detergency effects of the environment-friendly soap, is mild and lubricating, and enables the cleaned skin to be smooth and moist.
By adopting the natural essence, the environment-friendly soap can be endowed with fresh fragrance, and the skin care effects of diminishing inflammation, replenishing water, removing acnes, moistening and the like of the environment-friendly soap can be improved; the fruit essence can be apple essence, strawberry essence, cherry essence, lemon essence, etc.
Preferably, the environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 34-36 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 3-5min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 30-36 ℃, adding the compound enzyme, stirring for 1-3min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
The environment-friendly soap is prepared by the steps, so that the operation is simple, the control is convenient, the production efficiency is high, the production cost is low, the environment-friendly soap can be used for large-scale production, the raw materials of the prepared environment-friendly soap are uniformly dispersed by strictly controlling the process steps and the process parameters, the formability is better, the soft collapse phenomenon is avoided after the environment-friendly soap is mutually dissolved with water, the environment-friendly soap is not easy to oxidize, turn yellow and deteriorate, and the stability is high; the soap particles and the refined glycerin are heated and stirred, so that the solubility of the soap particles in the refined glycerin can be promoted, then the surfactant is added and mixed to improve the dispersibility of each raw material of the raw material system, and the plant extract, the softening agent and the natural essence are added and uniformly dispersed with the soap particles, the refined glycerin and other materials under the action of the surfactant and the homogeneous stirring to improve the dispersibility of the materials; finally, the compound enzyme is added at the temperature of 30-36 ℃, so that the activity of the enzyme is ensured, the enzyme is prevented from being inactivated at high temperature, the enzyme cleaning activity of the environment-friendly soap is fully activated, and the mild decontamination effect of the environment-friendly soap is improved; the soap is not added in the step of homogenizing and stirring, and the stirring time is strictly controlled, so that the foam generated in the process of homogenizing and stirring or excessively stirring can be avoided, the subsequent processing and forming procedures such as refining and the like are not facilitated, and the stability of the environment-friendly soap is improved.
The invention has the beneficial effects that: the soap grain of the invention takes the organic sodium gluconate as a main chelating agent, can include metal ions in water and dirt into the chelating agent to form a stable chelate, prevents dirt from precipitating, and avoids oxidative deterioration of soap caused by the metal ions, and the organic sodium gluconate has the environmental protection characteristic of easy biodegradation.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate has mild and safe raw materials, can improve the performances of antibiosis, antiphlogosis, moisturizing and nourishing of the environment-friendly soap by adopting the plant extract and the moisturizing factor, effectively protects the skin, improves the permeability of the skin, increases the elasticity of the skin, brightens the skin color, improves the dirt-removing capacity and the moisturizing capacity of the environment-friendly soap through the compound enzyme, does not damage the skin, improves the softness of the environment-friendly soap through the softening agent, does not generate tight feeling on the skin after cleaning and using, improves the bubble force and the foam stability of the environment-friendly soap, prevents dirt particles from being reprecipitated, inhibits the irritation of the environment-friendly soap to the skin, and improves the cleaning and decontaminating capacity of the environment-friendly soap.
Detailed Description
The present invention will be further described with reference to the following examples for facilitating understanding of those skilled in the art, and the description of the embodiments is not intended to limit the present invention.
Example 1
The soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is organic sodium gluconate.
Each part of the mixed fatty acid comprises 4 parts of lauric acid, 2 parts of palmitic acid, 2 parts of oleic acid and 0.2 part of linoleic acid; the mass fraction of the liquid caustic soda is 32%.
The soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 25% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 55% saponification reaction at the temperature of 80 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 105 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 10%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 105 ℃, the vacuum degree is-900 mbar, and the refined particle temperature of soap particles is 40 ℃.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
each part of the composite enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of 2:1: 0.5 of the composition; each part of the plant extract comprises 0.3 part of chlorella extract, 0.4 part of wild chrysanthemum extract and 0.2 part of sea grape extract.
Each part of the moisturizing factor is acetylated sodium hyaluronate and/or provitamin B5; each part of the softening agent is formed by mixing 0.2 part of glyceryl oleate, 3 parts of calcium gluconate, 1 part of levulinic acid and 2 parts of octyl dodecanol lauroyl glutamate.
The surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 2: 1; the natural essence is fruity essence.
The environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 34 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 3min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 30 ℃, adding the compound enzyme, stirring for 3min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
Example 2
The soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate in a weight ratio of 2:1: 1.5.
Each part of the mixed fatty acid comprises 4.2 parts of lauric acid, 2.5 parts of palmitic acid, 2.5 parts of oleic acid and 0.3 part of linoleic acid; the mass fraction of the liquid caustic soda is 34%.
The soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 28% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 58% saponification reaction at the temperature of 82 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 110 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 11%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 110 ℃, the vacuum degree is-890 mbar, and the refined particle temperature of soap particles is 42 ℃.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
each part of the compound enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of 2.2:1: 1.2: 0.6; each part of the plant extract comprises 0.4 part of chlorella extract, 0.5 part of wild chrysanthemum extract and 0.3 part of sea grape extract.
Each part of the moisturizing factor is maltitol and/or hydrolyzed glycosaminoglycans; each part of the softening agent is formed by mixing 0.3 part of glyceryl oleate, 3.5 parts of calcium gluconate, 1.1 parts of levulinic acid and 2.5 parts of octyl dodecanol lauroyl glutamate.
The surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 2.2: 1; the natural essence is fruity essence.
The environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 34.5 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 3.5min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 32 ℃, adding the compound enzyme, stirring for 2.5min, refining, grinding, vacuum stripping, cooling and printing to obtain the environment-friendly soap.
Example 3
The soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate in a weight ratio of 3:1: 2.
Each part of the mixed fatty acid comprises 4.5 parts of lauric acid, 3 parts of palmitic acid, 3 parts of oleic acid and 0.3 part of linoleic acid; the mass fraction of the liquid caustic soda is 36%.
The soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 30% of the total weight of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 560% saponification reaction at the temperature of 85 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 115 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 12%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 115 ℃, the vacuum degree is-880 mbar, and the refined particle temperature of soap particles is 45 ℃.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
each part of the compound enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of 2.5:1: 1.5: 0.8; each part of the plant extract comprises 0.5 part of chlorella extract, 0.6 part of wild chrysanthemum extract and 0.4 part of sea grape extract.
Each part of the moisturizing factor is hydrolyzed glucosaminoglycan and/or sodium PCA; each part of the softening agent is formed by mixing 0.3 part of glyceryl oleate, 4 parts of calcium gluconate, 1.2 parts of levulinic acid and 3 parts of octyl dodecanol lauroyl glutamate.
The surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 2.5: 1; the natural essence is fruity essence.
The environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 35 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 4min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 33 ℃, adding the compound enzyme, stirring for 2min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
Example 4
The soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate in a weight ratio of 3.5:1: 2.2.
Each part of the mixed fatty acid comprises 4.8 parts of lauric acid, 3.5 parts of palmitic acid, 3.5 parts of oleic acid and 0.4 part of linoleic acid; the mass fraction of the liquid caustic soda is 38%.
The soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 32% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 63% saponification reaction at the temperature of 88 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 120 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 12%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 120 ℃, the vacuum degree is-860 mbar, and the refined particle temperature of soap particles is 48 ℃.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
each part of the compound enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of 2.8:1: 1.8: 0.9; each part of the plant extract comprises 0.6 part of chlorella extract, 0.7 part of wild chrysanthemum extract and 0.5 part of sea grape extract.
Each part of the moisturizing factor is prepared from acetylated sodium hyaluronate, provitamin B5 and hydrolyzed glycosaminoglycans in a weight ratio of 2: 1.5: 1; each part of the softening agent is formed by mixing 0.4 part of glyceryl oleate, 4.5 parts of calcium gluconate, 1.3 parts of levulinic acid and 3.5 parts of octyl dodecanol lauroyl glutamate.
The surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 2.8: 1; the natural essence is fruity essence.
The environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 35.5 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 4.5min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 34 ℃, adding the compound enzyme, stirring for 1.5min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
Example 5
The soap grain containing organic sodium gluconate comprises the following raw materials in parts by weight:
the metal chelating agent is a mixture of organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate in a weight ratio of 4:1: 2.5.
Each part of the mixed fatty acid comprises 5 parts of lauric acid, 4 parts of palmitic acid, 4 parts of oleic acid and 0.5 part of linoleic acid; the mass fraction of the liquid caustic soda is 40%.
The soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 35% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 65% saponification reaction at the temperature of 90 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 125 ℃ to prepare a soap base;
and (5): and (4) carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 13%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain the soap granules containing the organic sodium gluconate.
In the step (5), the inlet temperature of vacuum spray drying is 125 ℃, the vacuum degree is-850 mbar, and the refined particle temperature of soap particles is 50 ℃.
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
each part of the composite enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of (3: 1: 2): 1.0; each part of the plant extract comprises 0.8 part of chlorella extract, 0.8 part of wild chrysanthemum extract and 0.6 part of sea grape extract.
Each part of the moisturizing factor is prepared from acetylated sodium hyaluronate, provitamin B5 and hydrolyzed glycosaminoglycans in a weight ratio of 3: 2.5: 1; each part of the softening agent is formed by mixing 0.5 part of glyceryl oleate, 5 parts of calcium gluconate, 1.5 parts of levulinic acid and 4 parts of octyl dodecanol lauroyl glutamate.
The surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 3: 1; the natural essence is fruity essence.
The environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 36 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 5min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 36 ℃, adding the compound enzyme, stirring for 1min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
Comparative example 1
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
the surfactant is sodium dodecyl sulfate.
Comparative example 2
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
comparative example 3
The environment-friendly soap prepared from the soap granules containing the organic sodium gluconate comprises the following raw materials in parts by weight:
the soap pellets prepared in examples 1-5 were subjected to the oxidation stability test, and the test methods and test results are shown below:
the test method comprises the following steps: the cured soap pellets obtained in examples 1 to 5 were divided into three equal portions, which were placed in paper boxes, the first portion was placed in an oven environment at a constant temperature of 45 ℃, the second portion was placed in an ambient temperature environment, and the third portion was placed in a refrigerator at 4 ℃ (the third portion was used as a standard sample for subsequent observation of color changes).
The color change of the sample is observed once a week in the early month, compared with the standard sample, and the smell is smelled. After one month, the observation was carried out for two weeks, and the color change and the odor change were observed in comparison with the standard sample until the end of the 100 th day.
And (3) testing results:
the soap grain of the invention takes the organic sodium gluconate as the main chelating agent, can include the metal ions in water and dirt into the chelating agent to form a stable chelate, prevents the dirt from precipitating, avoids the oxidative deterioration of the soap grain caused by the metal ions, improves the oxidative stability of the soap grain, and is not easy to be oxidized, yellowed and generate peculiar smell.
The eco-friendly soaps prepared in examples 1 to 5 and comparative examples 1 to 3 were subjected to measurements of foamability, wet crack property, wet soap touch and water wettability of skin surface, and the test methods and test results are as follows:
the test method comprises the following steps:
(1) foaming test: the measurement was carried out according to the method for measuring the foaming power of GB7462, and the results are expressed in terms of the number of milliliters of foam formed when the flow of liquid was stopped for 5 min. (2) And (3) wet cracking property test: completely soaking the environment-friendly soap in water with the constant temperature of 30 ℃ for 2h, then draining, drying at the temperature of 30 ℃ for 16-24h, observing the crack condition of the environment-friendly soap, and grading, wherein 0 represents that the soap body has no crack, 5 represents that the crack of the soap body is serious, and the grade of 0-5 reflects the crack occurrence condition of the environment-friendly soap;
(3) wet soap gritty feel test: placing the environment-friendly soap in tap water at 26.7 +/-1 ℃, slightly rubbing the environment-friendly soap with a palm for about 1min, judging the smoothness and the roughness (whether obvious sandy sense exists) of the surface of the environment-friendly soap by touch, grading, wherein 0 represents that the soap body is smooth and has no sandy sense, 1-3 represents that the soap body has slight sandy sense, more than 4 represents that the soap body has more sandy sense and the hand feeling is rough, and the grade of 0-5 reflects the wet soap touch grade of the environment-friendly soap;
(4) water wettability test of skin surface: detecting the water and oil values of the skin before the environment-friendly soap is used by a German DJM skin tester to obtain an initial value of water content 52.16 and an oil content value 56.89;
then, the cleansing was performed using the eco-friendly soaps of examples 1 to 5 and comparative examples 1 to 3, respectively, and the water and oil values of the skin 10min after cleansing were tested.
And (3) testing results:
according to the comparative analysis of the data, the surfactant in the environment-friendly soap in the comparative example 1 is only sodium dodecyl sulfate, so that the environment-friendly soap is low in foam height and poor in foamability, and the environment-friendly soap disclosed by the invention is prepared by compounding the sodium dodecyl sulfate and the coconut oil acid hydroxyethyl sodium sulfonate, so that the foaming power and the foam stability of the environment-friendly soap can be effectively improved, the foam is rich and fine, and the dirt-removing capacity of the environment-friendly soap can be promoted.
Comparative example 2 no softening agent was used in the environment-friendly soap, and the prepared environment-friendly soap had a slight foreign particle feeling and a rough hand feeling in the touch under the condition of running water, which shows that the softening agent of the present invention can effectively improve the softening texture of the environment-friendly soap, and can provide a softening effect to the skin, thereby preventing the skin from being tense after cleaning.
Comparative example 3 no moisturizing factor was used in the environment-friendly soap, the moisture value of the skin surface cleaned with the environment-friendly soap did not increase much, and the oil value was higher than that of other examples, which shows that by using the moisturizing factor of the present invention, moisture can be supplemented in time while the skin is fully cleaned with the environment-friendly soap, the phenomenon of water-deficient dry wrinkles after full cleaning (the phenomenon of slightly higher oil value due to the fact that skin is in water-deficient dry wrinkles and can automatically secrete oil to protect epidermal cells) is avoided, and the cleaning and moisturizing effects of the environment-friendly soap are improved.
The above-described embodiments are preferred implementations of the present invention, and the present invention may be implemented in other ways without departing from the spirit of the present invention.
Claims (2)
1. An environment-friendly soap containing organic sodium gluconate is characterized in that: the environment-friendly soap comprises the following raw materials in parts by weight:
80-100 parts of soap grain
3-7 parts of compound enzyme
2-4 parts of plant extract
0.5-1 part of moisturizing factor
0.5 to 1.5 portions of softening agent
3-5 parts of surfactant
Refined glycerin 2-5 parts
0.3-1.5 parts of natural essence;
each part of the composite enzyme is prepared from a protein enzyme, a superoxide dismutase, a lipolytic enzyme and a sphingomyelin enzyme in a weight ratio of (2-3: 1: 1-2): 0.5-1.0;
each part of the moisturizing factor is prepared from acetylated sodium hyaluronate, provitamin B5 and hydrolyzed glycosaminoglycans in a weight ratio of 2-3: 1.5-2.5: 1; each part of the softening agent is formed by mixing 0.2-0.5 part of glyceryl oleate, 3-5 parts of calcium gluconate, 1-1.5 parts of levulinic acid and 2-4 parts of octyl dodecanol lauroyl glutamate;
the surfactant is a mixture of sodium dodecyl sulfate and sodium cocoate hydroxyethyl sulfonate in a weight ratio of 2-3: 1;
each part of the plant extract comprises 0.3-0.8 part of chlorella extract, 0.4-0.8 part of wild chrysanthemum extract and 0.2-0.6 part of sea grape extract;
the soap particles are composed of the following raw materials in parts by weight:
60-80 parts of mixed fatty acid
27-38 parts of liquid caustic soda
2-10 parts of refined glycerol
0.2 to 1.5 portions of metal chelating agent
Refined salt 0.5-1.0 part
4.5-6.5 parts of deionized water;
the metal chelating agent is prepared by mixing organic sodium gluconate, iminodisuccinic acid and sodium dipolyaspartate according to the weight ratio of 2-4:1: 1.5-2.5;
each part of the mixed fatty acid comprises 4-5 parts of lauric acid, 2-4 parts of palmitic acid, 2-4 parts of oleic acid and 0.2-0.5 part of linoleic acid; the mass fraction of the liquid caustic soda is 32-40%;
the soap grain containing the organic sodium gluconate is prepared by the following steps:
step (1): adding refined glycerol and refined salt into deionized water accounting for 25-35% of the total amount of the deionized water according to the weight parts, and stirring and mixing to obtain a phase A;
step (2): adding the metal chelating agent into the rest deionized water according to the parts by weight, stirring and mixing until the metal chelating agent is completely dissolved to obtain a phase B;
and (3): respectively pumping mixed fatty acid, liquid alkali, the phase A prepared in the step (1) and the phase B prepared in the step (2) into a continuous saponification system by using a metering pump according to the parts by weight, and premixing in a mixer to complete 55-65% saponification reaction at the temperature of 80-90 ℃;
and (4): conveying the partially saponified soap liquid discharged from the premixer in the step (3) to a continuous saponification tank for continuous saponification reaction, wherein the saponification temperature is controlled at 105-125 ℃ to prepare a soap base;
and (5): carrying out vacuum spray drying on the soap base prepared in the step (4) to obtain the soap base with the water content of 10-13%, and then refining, extruding and stripping the soap base, and carrying out grain-sized forming to obtain soap granules containing organic sodium gluconate;
in the step (5), the inlet temperature of vacuum spray drying is 105-125 ℃, the vacuum degree is-850 to-900 mbar, and the refined particle making temperature of the soap particles is 40-50 ℃;
the environment-friendly soap is prepared by the following steps:
step A: adding refined glycerol and heat preservation factors into the soap particles according to the weight parts, fully and uniformly stirring, and controlling the temperature of the mixture to be 34-36 ℃ to prepare a component A;
and B: adding surfactant into the component A prepared in the step A according to the weight part, stirring and mixing uniformly, then respectively adding the plant extract, the emollient and the natural essence, stirring for 3-5min, and mixing uniformly to obtain a component B;
and C: and C, cooling the component B prepared in the step B to 30-36 ℃, adding the compound enzyme, stirring for 1-3min, refining, grinding, discharging in vacuum, cooling and printing to obtain the environment-friendly soap.
2. The environmental soap containing organic sodium gluconate according to claim 1, wherein: the natural essence is fruity essence.
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