CN107384636B - A kind of relatively mild Transparent soap base cleaning formulation - Google Patents
A kind of relatively mild Transparent soap base cleaning formulation Download PDFInfo
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- CN107384636B CN107384636B CN201710649513.9A CN201710649513A CN107384636B CN 107384636 B CN107384636 B CN 107384636B CN 201710649513 A CN201710649513 A CN 201710649513A CN 107384636 B CN107384636 B CN 107384636B
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- fatty acid
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/361—Carboxylic acids having more than seven carbon atoms in an unbroken chain; Salts or anhydrides thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/005—Synthetic soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/007—Soaps or soap mixtures with well defined chain length
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/265—Organic compounds, e.g. vitamins containing oxygen containing glycerol
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/38—Products in which the composition is not well defined
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
- A61K2800/262—Transparent; Translucent
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The invention discloses a kind of relatively mild Transparent soap base skin cleansing formulations, it is characterized in that, including organic amine and fatty acid with dissolving and heat absorbing, wherein the fatty acid and organic amine weight ratio 1:(1-2.5), Transparent soap base cleaning formulation is made into the method for fatty acid using in organic amine, with foaming abundancy, it easily rinses, and high temperature is non-discolouring, 5 DEG C of low temperature the features such as not being precipitated, and it is more nearly the pH range of human skin, more mildly.
Description
Technical field
The present invention relates to daily chemicals fields, especially design a kind of mild Transparent soap base cleaning compositions.
Background technique
It is also higher and higher to cosmetics requirement recently as the improvement of people's living standards, for washing class product, soap
The foaming power of base face cleaning is good, foaming abundancy, with rear Yi Chongxi, carrys out clean salubrious sense to skin tape, exactly because these characteristics, soap
Base class product is be deeply loved by everyone, but has the product of many soaps, such as solid soap on the market, face cleaning cream, liquid facial soap, is all white
The appearance of color, and the PH of soap base face cleaning class product is usually in 9.5-10.5 or so, and few soap base face cleaning gels.Face cleaning gel
Also more AES, glycine betaine etc. are principal surfactant to shape product, do not have the easy flushing of soap base to feel in cleaning process.Such as specially
Sharp CN103126911A discloses a kind of mild Soap-base facial cleanser composition comprising the Soap-base facial cleanser composition gross weight
The soap base of amount 2.0% to 50.0%, the anion surface active of the Soap-base facial cleanser composition total weight 2.0%-30.0%
Agent, the rheology control agent and excess water of Zhan Suoshu Soap-base facial cleanser composition total weight 0.1% to 10.0%.The soap base is clean
Face composite cream pH value is 8.0-11.0, wherein the soap base is made of 2.0-40.0% fatty acid and 0-10% alkali, wherein
Alkali is sodium hydroxide, potassium hydroxide, triethanolamine, solve moistened after mildly washing it is not tight, but with three ethyl alcohol in the patent
Amine neutralizes, and the soap surfactant produced has the shortcomings that easy high-temperature discoloration, and the soap made, which is put, also can become yellow by transparent long afterwards
It is transparent.If patent CN201611247052A discloses a kind of in the transparent soap sill of low-temperature stabilization and composition, technical problem is solved
Discoloration problem is precipitated in low temperature, provides a kind of fatty acid comprising higher concentration and a plurality of types of surfactants, and alkali selects hydrogen
Potassium oxide, the composition keep transparent appearance after restoring room temperature at transparent state and (- 5 ± 2) DEG C at 5 DEG C, avoid making
It is used with triethanolamine with potassium hydroxide and prepares Transparent soap base with comprising higher concentration fatty acid.CN201611242812 is disclosed
A kind of high-temperature stable, cost performance is high, foaming abundancy, not tight Soap-base facial cleanser is moistened after washing comprising stearic acid, laurel
Acid, myristic acid, rilanit special, stearine, PGE-100 stearate, potassium hydroxide, glycerol, propylene glycol, EDTA
Disodium, preservative, essence, hydroxypropyl methyl cellulose, preservative etc., be also in the patent in potassium hydroxide with fatty acid come
Prepare the soap base of high-temperature stable.But the highly basic such as sodium hydroxide, potassium in plant produced, dissolve there is a great harm for human skin
Potassium hydroxide, sodium hydroxide can be highly exothermic, have certain risk in operation.CN201310522853A discloses one kind
Transparent soap base, including liquid alkaline, palm oil, coconut oil, castor oil, alcohol, glycerol, granulated sugar and water, by adjusting said components
Ratio controls the transparency of soap base, inoxidizability and moisturizing function.
Therefore, a kind of Transparent soap base and product have foaming abundancy, Yi Chongxi, and high temperature is non-discolouring, and 5 ° of low temperature are not analysed
It out, is mildly the product of market in urgent need to the inirritative soap based cleansing product of skin.
Summary of the invention
In order to solve the above technical problem, the present invention provides a kind of relatively mild Transparent soap base skin cleansing formulations, should
Preparation has that transparent, high temperature is non-discolouring, and low temperature is not precipitated, mild inirritative effect, and in technological operation, the neutralization used
Agent organic amine is endothermic process, safe operation in course of dissolution.
A kind of preparation method of relatively mild Transparent soap base skin cleansing formulations of another object of the present invention.
To achieve the above object, the present invention is achieved through the following technical solutions:
A kind of relatively mild Transparent soap base skin cleansing formulations, which is characterized in that including with the organic of dissolving and heat absorbing
Amine and fatty acid, wherein the fatty acid and organic amine weight ratio 1:(1-2.5).Said preparation is genuine soap base.
Preferably, in above-mentioned technical proposal, fatty acid and organic amine weight ratio 1:(2-2.5).
A kind of relatively mild Transparent soap base skin cleansing formulations, including following materials by weight percentage
Fatty acid 6-20%
Organic amine 13-35%
Thickener 0-2%
Helper component 0-30%
Water surplus.
Preferably, a kind of relatively mild Transparent soap base skin cleansing formulations, including following materials by weight percentage
Fatty acid 6-20%
Organic amine 13-20%
Thickener 1-2%
Helper component 3-30%
Water surplus.
It is further preferred that a kind of relatively mild Transparent soap base skin cleansing formulations, including following weight percentage
Raw material
Fatty acid 6-10%
Organic amine 13-20%
Thickener 1-2%
Helper component 3-30%
Water surplus.
Preferably, in above-mentioned technical proposal, a kind of relatively mild Transparent soap base skin cleansing formulations pH value of the present invention≤
9, preferable ph 8.0-9.0, pH value range of the pH value closer to human skin, comfort level milder be not tight.
Preferably, in above-mentioned technical proposal, the fatty acid includes but is not limited to octanoic acid, lauric acid, myristic acid, palm
Acid, stearic acid, one in mountain Yu acid, 12 carbon fatty acids, tetradecacarbon fatty acid, 16 carbon fatty acids, 22 carbon fatty acids
Kind or its more than.It is preferred that lauric acid, myristic acid, palmitinic acid, stearic acid is one or more of in mountain Yu acid.Selected by the present invention
Higher fatty acids prepare that Transparent soap base molten point is controllable, and the water-soluble of soap is more preferable, and foam mildly enriches.
Preferably, in above-mentioned technical proposal, the organic amine is tromethamine, one or two kinds of groups in aminomethyl propanol
It closes.The tromethamine, aminomethyl propanol reacts as neutralizer and fatty acid to be prepared soap base and plays cleaning action,
It prevents high temperature soap base ontology from changing colour, and is endothermic process in course of dissolution, safe operation is suitble to industry in technique preparation
Metaplasia produces.Using tromethamine, aminomethyl propanol makes soap base pH value≤9 being prepared, and does not need to reuse acid-base modifier.
Present invention preferably employs the soap base high temperature low temperature of tromethamine preparation without changing colour and being precipitated problem, and foaming abundancy.And ammonia
Methylpropanol high temperature is non-discolouring, and low temperature is not precipitated, but foam is not very abundant relatively.
Preferably, in above-mentioned technical proposal, the thickener includes but is not limited to cellulose, carbomer series etc., institute
Stating cellulose includes but is not limited to hydroxyethyl cellulose, methylcellulose, hydroxypropyl methyl cellulose, carboxymethyl cellulose etc..
The carbomer series includes Acritamer 940, Carbopol 941, carbomer 934, carbomer934, Carbopol etc..The present invention
Preferred thickener is cellulose, can increase the vicidity of soap base, reaches suitable use feeling, to guarantee that soap base is low in high temperature
Stablize under the conditions of temperature not stratified.
Preferably, in above-mentioned technical proposal, after helper component is added, it is high that the soap base of preparation more moistens skin sensitivity.
The helper component includes but is not limited to polyalcohol, surfactant, skin conditioning agent, antioxidant, preservative, essence, chela
Mixture, several combinations one or more of pigment etc..
The polyalcohol includes but is not limited to 1,2- propylene glycol, 1,3- propylene glycol, 1,3 butylene glycol, glycerol, polyethylene glycol-
8, the combination of one or more of polyethylene glycol -32, pungent glycol.Dosage 5-30%.Solubility can be increased after increasing polyalcohol,
Enhance stability.
The surfactant includes but is not limited to anionic surfactant, cationic surfactant and nonionic table
Face activity, the one or more combination of amphoteric surfactant, for adjusting the abundant degree and different skin sense experience of foam.
Dosage 0-10%.
The skin conditioning agent refers to common functional additive such as salicylic acid, tea tree ethereal oil etc..Dosage 0-3%.
The antioxidant is dibutyl hydroxy toluene.
The chelating agent is EDTA-2Na.
The present invention also provides a kind of relatively mild Transparent soap base skin cleansing formulations can be used for including but not limited to thoroughly
Clear and bright face gel, transparent bath foam use in the transparent formula for washing hair care.
The present invention also provides a kind of preparation methods of relatively mild Transparent soap base skin cleansing formulations comprising as follows
Step:
1. water is added in main still, thickener room temperature is added to the water to stir evenly it is heated to 80-85 DEG C, swelling sufficiently, adds
Enter organic amine, dissolve, polyalcohol is added before being saponified；
2. fatty acid, antioxidant are heated to 80-85 DEG C of dissolution, it is added in water phase, heat preservation saponification is added chelating agent, stirs
Mix dissolution；
3. being cooled to 60-65 DEG C of addition surfactant；
4. being cooled to 40-45 DEG C, preservative is added, is cooled to 38 DEG C, detection discharging.
In order to preferably embody beneficial effects of the present invention, illustrated by following test examples
One stability of test example and comparative test
1. method: of the present invention group, contrast groups and ratio are shown in Table 1, stability table 2 Fig. 1, Fig. 2 after comparing 2 months.
2. result: by table 2 as it can be seen that the embodiment of the present invention 1 and comparative example 1 compare, the present invention is prepared using tromethamine
Soap base high temperature low temperature without change colour and be precipitated problem, pellucidity is very stable always.And comparative example 1 is matched using triethanolamine
The soap base of system occurs discoloration at 40,48 degrees Celsius of high temperature, and color is gradually deepened as the temperature rises, is occurred in low temperature
Precipitation problem.Comparative example 2 using potassium hydroxide configuration soap base, high temperature is non-discolouring, can low temperature can be precipitated.The embodiment of the present invention
2.3 and embodiment 1 compare, embodiment 2.3 is to increase polyalcohol on the basis of embodiment 1, the assisted groups such as surfactant
Point, but helper component does not influence the stability of Transparent soap base, the problem of high-temperature discoloration low temperature precipitation does not occur.
The grouping of table 1 and prescription
Table 2, PH are two months stability datas of 8.5-9.0:
Test example difatty acid, organic amine selection or proportion screening test
Mild Transparent soap base preparation of the invention not being not that can obtain any selection of fatty acid, organic amine or cooperation,
But it can just overcome in background technique that there are some unsatisfactory parameters or phenomenon for soap base by the screening of characteristic ratio.Specifically
It is shown in Table 3.Visible by table 3: content of fatty acid is higher, and viscosity is bigger, and foam is also abundanter.It can be adjusted, send out according to demand
Bright people's discovery, when content of fatty acid is excessively high, it may appear that low temperature precipitation phenomenon.In order to avoid foaming abundancy simultaneously saltout by fatty acid
Out, then it needs to increase simultaneously the organic amine i.e. dosage of tromethamine, that is, can avoid the precipitation of high fatty acid, it is therefore necessary to meet rouge
Fat acid and organic amine ratio maintain 1:(1-2.5), preferably 1:(2-2.5) when avoid precipitation phenomenon.But in comparative example 2, right
Even if inventor has found fatty acid and organic amine amount ratio in 1:(1-2.5 in 3 groups of ratio) in, when fatty acid is total with organic acid
When dosage reaches 40%, 5 DEG C of low temperature are slightly precipitated, when fatty acid and the total dosage of organic acid are higher than 60%, it may appear that low temperature is a large amount of
It is precipitated.Therefore, inventor obtains only when meeting fatty acid and the total dosage of organic acid and being no more than 40%, no matter soap base system
Whether the auxiliary auxiliary material such as polyalcohol is dosed in agent, it is necessary to meet fatty acid and organic amine ratio maintains 1:(1-2.5), preferably 1:
Under (2-2.5) state, soap base high temperature obtained is non-discolouring, and low temperature is not precipitated.
Table 3 is grouped
Three skin sense of test example test
Method: human body face cleaning test assessment measurement
10 volunteers are chosen, formulation product face cleaning in table 4 is taken, is evaluated by scoring mechanism, it is more by washing Experimental comparison by rubbing with the hands
The compounding of first alcohol is can be improved to the tight feeling after soap base system is washed.
Table 4
Compared with prior art, the present invention has the advantages that
The present invention is made into Transparent soap base cleaning formulation with the method for fatty acid using in organic amine, has foaming abundancy, easily
It rinses, and high temperature is non-discolouring, 5 DEG C of low temperature the features such as not being precipitated, and is more nearly the pH range of human skin, more mildly.
It can be configured by the auxiliary elements such as compounding polyalcohol and table work with the Transparent soap base cleaning formulation for moistening skin sense.This hair
Bright selection organic amine type dissolving and heat absorbing in production, avoids operational hazards, is easy to industrialization.And pH value≤9 pH value is more
Close to the pH value range of human skin, comfort level milder is not tight.
Detailed description of the invention
Fig. 1 is embodiment according to the present invention 1 and comparison 1 at 48 DEG C, 2 months stability experiment figures.
Wherein 1 colourless transparent solution of embodiment, comparative example 1 are yellow solution
Fig. 2 is embodiment according to the present invention 1 and comparison 1 at 5 DEG C, 2 months stability experiment figures
Wherein 1 colourless transparent solution of embodiment, 1 white crystals of comparative example
Specific embodiment
With reference to the accompanying drawing, specific embodiments of the present invention will be described in detail, it is to be understood that guarantor of the invention
Shield range is not limited by the specific implementation.
Unless otherwise explicitly stated, otherwise in entire disclosure and claims, term " includes " or its change
Changing such as "comprising" or " including " etc. will be understood to comprise stated element or component, and not exclude other members
Part or other component parts.
Embodiment 1-8
A kind of mild Transparent soap base preparation of the invention
Preparation method: water is added in main still, hydroxyethyl cellulose room temperature is added to the water to stir evenly is heated to 80-85
DEG C, sufficiently, tromethamine is added in swelling, and PEG-8, glycerol is added before being saponified in dissolution；By lauric acid, myristic acid, dibutyl hydroxyl
Base toluene is heated to 80-85 DEG C of dissolution, is added in water phase, and EDTA2NA, stirring and dissolving is added in heat preservation saponification 20min；It is cooled to
60-65 DEG C of addition Cocoamidopropyl betaine, Sodium Lauroamphoacetate；It is cooled to 40-45 DEG C, preservative, drop is added
Temperature is to 38 DEG C, detection discharging.
Embodiment 9-16
Change tromethamine in embodiment 1-8 into aminomethyl propanol, other compositions are constant.
Embodiment 17-24
The aforementioned description to specific exemplary embodiment of the invention is in order to illustrate and illustration purpose.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to the above instruction, can much be changed
And variation.The purpose of selecting and describing the exemplary embodiment is that explaining specific principle of the invention and its actually answering
With so that those skilled in the art can be realized and utilize a variety of different exemplary implementation schemes of the invention and
Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (9)
1. a kind of relatively mild Transparent soap base skin cleansing formulations, which is characterized in that including the organic amine with dissolving and heat absorbing
And fatty acid, wherein the fatty acid and organic amine weight ratio 1:(1-2.5), the fatty acid is less than with the total dosage of organic amine
40%, the organic amine is tromethamine.
2. a kind of relatively mild Transparent soap base skin cleansing formulations as described in claim 1, including following weight percentage
Raw material
Fatty acid 6-20%
Organic amine 13-35%
Thickener 0-2%
Helper component 0-30%
Water surplus.
3. a kind of relatively mild Transparent soap base skin cleansing formulations as claimed in claim 2, including following weight percentage
Raw material
Fatty acid 6-20%
Organic amine 13-20%
Thickener 1-2%
Helper component 3-30%
Water surplus.
4. the relatively mild Transparent soap base skin cleansing formulations of one kind a method according to any one of claims 1-3, which is characterized in that institute
State fatty acid be one of octanoic acid, lauric acid, myristic acid, palmitinic acid, stearic acid, mountain Yu's acid or more than one.
5. a kind of relatively mild Transparent soap base skin cleansing formulations as described in Claims 2 or 3 is any, which is characterized in that
The thickener is cellulose or carbomer.
6. a kind of relatively mild Transparent soap base skin cleansing formulations as claimed in claim 2 or claim 3, which is characterized in that described
Helper component include polyalcohol, antioxidant, chelating agent, surfactant, skin conditioning agent, preservative, essence, pigment it is a kind of or
Above several combinations.
7. a kind of relatively mild Transparent soap base skin cleansing formulations as claimed in claim 6, which is characterized in that described polynary
Alcohol is 1,2- propylene glycol, 1,3- propylene glycol, 1,3 butylene glycol, glycerol, polyethylene glycol-8, polyethylene glycol -32, one in pungent glycol
Kind or several combinations, dosage 5-30%.
8. a kind of relatively mild Transparent soap base skin cleansing formulations as claimed in claim 6, which is characterized in that the surface
Activating agent is one kind of anionic surfactant, cationic surfactant, non-ionic surface active, amphoteric surfactant
Or several combinations, dosage 0-10%.
9. the relatively mild Transparent soap base skin cleansing formulations of one kind a method according to any one of claims 1-3, it is characterised in that: use
It is used in transparent face cleaning gel, transparent bath foam, the transparent formula for washing hair care.
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| EP3610848B1 (en) * | 2017-04-10 | 2025-08-27 | Kao Corporation | Skin cleansing composition |
| CN109897745A (en) * | 2017-12-07 | 2019-06-18 | 株式会社Lg生活健康 | Composition of skin cleanser and preparation method thereof |
| CN108066164B (en) * | 2017-12-28 | 2020-06-19 | 上海家化联合股份有限公司 | Transparent composite cleaning composition and preparation method thereof |
| CN109010122A (en) * | 2018-09-26 | 2018-12-18 | 湖南御家化妆品制造有限公司 | A kind of Soap-base facial cleanser and preparation method thereof |
| CN109825386B (en) * | 2019-01-29 | 2021-09-10 | 丰益油脂科技（东莞）有限公司 | Soap grain containing organic sodium gluconate and environment-friendly soap |
| CN110074992A (en) * | 2019-04-24 | 2019-08-02 | 上海中翊日化有限公司 | Transparent soap base shower cream and preparation method |
| CN110876692B (en) * | 2019-12-16 | 2023-03-28 | 上海家化联合股份有限公司 | Cleaning composition |
| JP2022151660A (en) * | 2021-03-23 | 2022-10-07 | 株式会社マンダム | Sebum odor inhibitor composition |
| CN114921296A (en) * | 2022-06-17 | 2022-08-19 | 上海家化联合股份有限公司 | Soap-based self-thickening cleansing compositions |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160113A (en) * | 2005-03-17 | 2008-04-09 | 伽佰农万事达橄榄油市场有限公司 | Soaps from organic residues and method of producing the same |
| CN102140392A (en) * | 2011-02-16 | 2011-08-03 | 南相镇 | Ginseng extract perfumed soap and preparation method thereof |
| CN102438703A (en) * | 2009-01-13 | 2012-05-02 | 宝洁公司 | Rinse-off personal care compositions |
| CN103421626A (en) * | 2012-05-18 | 2013-12-04 | 李平 | Phyllanthus emblica cleaning soap |
| CN103849473A (en) * | 2012-12-04 | 2014-06-11 | 丁兴清 | Triethanolamine soap |
| CN106398905A (en) * | 2016-09-06 | 2017-02-15 | 佛山市芊茹化妆品有限公司 | Application of hydroxyl substituent of 2-amino-2-methyl propane in amino acid transparent soap |
-
2017
- 2017-08-02 CN CN201710649513.9A patent/CN107384636B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160113A (en) * | 2005-03-17 | 2008-04-09 | 伽佰农万事达橄榄油市场有限公司 | Soaps from organic residues and method of producing the same |
| CN102438703A (en) * | 2009-01-13 | 2012-05-02 | 宝洁公司 | Rinse-off personal care compositions |
| CN102140392A (en) * | 2011-02-16 | 2011-08-03 | 南相镇 | Ginseng extract perfumed soap and preparation method thereof |
| CN103421626A (en) * | 2012-05-18 | 2013-12-04 | 李平 | Phyllanthus emblica cleaning soap |
| CN103849473A (en) * | 2012-12-04 | 2014-06-11 | 丁兴清 | Triethanolamine soap |
| CN106398905A (en) * | 2016-09-06 | 2017-02-15 | 佛山市芊茹化妆品有限公司 | Application of hydroxyl substituent of 2-amino-2-methyl propane in amino acid transparent soap |
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