AU2014287025B2 - Methods and compositions of granule formulations - Google Patents

Methods and compositions of granule formulations Download PDF

Info

Publication number: AU2014287025B2
Authority: AU; Australia
Prior art keywords: granule formulation; mcp; granule; plant; formulation
Prior art date: 2013-07-11
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU2014287025A

Other languages

English (en)

Other versions

AU2014287025A1 (en

Inventor

Christian Guy BECKER

Bridget Marie Stevens

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

AgroFresh Inc

Original Assignee

AgroFresh Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2013-07-11

Filing date

2014-07-11

Publication date

2017-03-23

2014-07-11 Application filed by AgroFresh Inc filed Critical AgroFresh Inc

2016-01-28 Publication of AU2014287025A1 publication Critical patent/AU2014287025A1/en

2017-03-23 Application granted granted Critical

2017-03-23 Publication of AU2014287025B2 publication Critical patent/AU2014287025B2/en

Status Ceased legal-status Critical Current

2034-07-11 Anticipated expiration legal-status Critical

Links

239000000203 mixture Substances 0.000 title claims abstract description 116
239000008187 granular material Substances 0.000 title claims abstract description 103
238000009472 formulation Methods 0.000 title claims abstract description 65
238000000034 method Methods 0.000 title claims abstract description 54
239000011230 binding agent Substances 0.000 claims abstract description 20
239000003039 volatile agent Substances 0.000 claims abstract description 16
239000002808 molecular sieve Substances 0.000 claims abstract description 10
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 10
-1 cyclopropene compound Chemical class 0.000 claims description 100
239000005969 1-Methyl-cyclopropene Substances 0.000 claims description 58
SHDPRTQPPWIEJG-UHFFFAOYSA-N 1-methylcyclopropene Chemical compound CC1=CC1 SHDPRTQPPWIEJG-UHFFFAOYSA-N 0.000 claims description 58
240000007594 Oryza sativa Species 0.000 claims description 36
239000008393 encapsulating agent Substances 0.000 claims description 26
125000000217 alkyl group Chemical group 0.000 claims description 24
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 24
230000008569 process Effects 0.000 claims description 24
239000000126 substance Substances 0.000 claims description 24
239000004927 clay Substances 0.000 claims description 21
229910000278 bentonite Inorganic materials 0.000 claims description 20
229940092782 bentonite Drugs 0.000 claims description 20
239000000440 bentonite Substances 0.000 claims description 20
244000038559 crop plants Species 0.000 claims description 14
125000001424 substituent group Chemical group 0.000 claims description 14
235000019738 Limestone Nutrition 0.000 claims description 11
239000006028 limestone Substances 0.000 claims description 11
229920000858 Cyclodextrin Polymers 0.000 claims description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 10
229920001450 Alpha-Cyclodextrin Polymers 0.000 claims description 9
125000000304 alkynyl group Chemical group 0.000 claims description 9
HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 claims description 9
229940043377 alpha-cyclodextrin Drugs 0.000 claims description 9
125000003545 alkoxy group Chemical group 0.000 claims description 8
ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 8
229910052736 halogen Inorganic materials 0.000 claims description 8
238000009490 roller compaction Methods 0.000 claims description 8
239000004480 active ingredient Substances 0.000 claims description 7
150000002367 halogens Chemical class 0.000 claims description 7
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229940080314 sodium bentonite Drugs 0.000 claims description 7
125000003342 alkenyl group Chemical group 0.000 claims description 6
125000000753 cycloalkyl group Chemical group 0.000 claims description 6
125000001624 naphthyl group Chemical group 0.000 claims description 6
240000008042 Zea mays Species 0.000 claims description 5
125000001316 cycloalkyl alkyl group Chemical group 0.000 claims description 5
125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 5
239000001116 FEMA 4028 Substances 0.000 claims description 4
WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 claims description 4
235000011175 beta-cyclodextrine Nutrition 0.000 claims description 4
229960004853 betadex Drugs 0.000 claims description 4
GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 claims description 4
229940080345 gamma-cyclodextrin Drugs 0.000 claims description 4
244000068988 Glycine max Species 0.000 claims description 3
244000098338 Triticum aestivum Species 0.000 claims description 3
235000004341 Gossypium herbaceum Nutrition 0.000 claims description 2
240000002024 Gossypium herbaceum Species 0.000 claims description 2
230000001850 reproductive effect Effects 0.000 claims description 2
230000005070 ripening Effects 0.000 claims description 2
230000000087 stabilizing effect Effects 0.000 claims description 2
240000000385 Brassica napus var. napus Species 0.000 claims 1
239000002671 adjuvant Substances 0.000 abstract description 4
235000007164 Oryza sativa Nutrition 0.000 description 28
235000009566 rice Nutrition 0.000 description 26
239000002245 particle Substances 0.000 description 23
238000005056 compaction Methods 0.000 description 21
125000003118 aryl group Chemical group 0.000 description 17
125000004122 cyclic group Chemical group 0.000 description 17
241000196324 Embryophyta Species 0.000 description 16
229910001868 water Inorganic materials 0.000 description 15
125000004435 hydrogen atom Chemical group [H]* 0.000 description 13
239000000463 material Substances 0.000 description 13
239000000843 powder Substances 0.000 description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
125000001072 heteroaryl group Chemical group 0.000 description 12
229910052739 hydrogen Inorganic materials 0.000 description 12
239000001257 hydrogen Substances 0.000 description 11
238000011282 treatment Methods 0.000 description 11
125000001931 aliphatic group Chemical group 0.000 description 10
125000004432 carbon atom Chemical group C* 0.000 description 10
239000000969 carrier Substances 0.000 description 10
150000001875 compounds Chemical class 0.000 description 10
125000003636 chemical group Chemical group 0.000 description 9
238000005469 granulation Methods 0.000 description 8
230000003179 granulation Effects 0.000 description 8
230000012010 growth Effects 0.000 description 8
230000015556 catabolic process Effects 0.000 description 7
238000006731 degradation reaction Methods 0.000 description 7
125000000623 heterocyclic group Chemical group 0.000 description 7
235000002639 sodium chloride Nutrition 0.000 description 7
229920002261 Corn starch Polymers 0.000 description 6
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
125000004429 atom Chemical group 0.000 description 6
239000008120 corn starch Substances 0.000 description 6
229940099112 cornstarch Drugs 0.000 description 6
239000003337 fertilizer Substances 0.000 description 6
239000010440 gypsum Substances 0.000 description 6
229910052602 gypsum Inorganic materials 0.000 description 6
238000003306 harvesting Methods 0.000 description 6
239000007788 liquid Substances 0.000 description 6
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
125000006413 ring segment Chemical group 0.000 description 6
125000004178 (C1-C4) alkyl group Chemical group 0.000 description 5
238000007906 compression Methods 0.000 description 5
230000006835 compression Effects 0.000 description 5
238000009826 distribution Methods 0.000 description 5
OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 5
239000007858 starting material Substances 0.000 description 5
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
108700019146 Transgenes Proteins 0.000 description 4
238000005054 agglomeration Methods 0.000 description 4
230000002776 aggregation Effects 0.000 description 4
238000004458 analytical method Methods 0.000 description 4
230000015572 biosynthetic process Effects 0.000 description 4
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
235000013339 cereals Nutrition 0.000 description 4
239000007789 gas Substances 0.000 description 4
125000005842 heteroatom Chemical group 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
229910052939 potassium sulfate Inorganic materials 0.000 description 4
125000006239 protecting group Chemical group 0.000 description 4
238000005070 sampling Methods 0.000 description 4
239000011780 sodium chloride Substances 0.000 description 4
239000007787 solid Substances 0.000 description 4
108091032973 (ribonucleotides)n+m Proteins 0.000 description 3
235000004977 Brassica sinapistrum Nutrition 0.000 description 3
125000004399 C1-C4 alkenyl group Chemical group 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
241000209510 Liliopsida Species 0.000 description 3
WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 3
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
235000002017 Zea mays subsp mays Nutrition 0.000 description 3
150000008064 anhydrides Chemical class 0.000 description 3
229910052799 carbon Inorganic materials 0.000 description 3
239000000084 colloidal system Substances 0.000 description 3
235000005822 corn Nutrition 0.000 description 3
125000004093 cyano group Chemical group *C#N 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000002474 experimental method Methods 0.000 description 3
230000002209 hydrophobic effect Effects 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
125000003367 polycyclic group Chemical group 0.000 description 3
229920001223 polyethylene glycol Polymers 0.000 description 3
150000003254 radicals Chemical class 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
238000003786 synthesis reaction Methods 0.000 description 3
238000002054 transplantation Methods 0.000 description 3
125000004169 (C1-C6) alkyl group Chemical group 0.000 description 2
235000014698 Brassica juncea var multisecta Nutrition 0.000 description 2
235000006008 Brassica napus var napus Nutrition 0.000 description 2
235000011299 Brassica oleracea var botrytis Nutrition 0.000 description 2
240000003259 Brassica oleracea var. botrytis Species 0.000 description 2
235000006618 Brassica rapa subsp oleifera Nutrition 0.000 description 2
244000188595 Brassica sinapistrum Species 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
244000241235 Citrullus lanatus Species 0.000 description 2
235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 2
241000219112 Cucumis Species 0.000 description 2
235000015510 Cucumis melo subsp melo Nutrition 0.000 description 2
235000009854 Cucurbita moschata Nutrition 0.000 description 2
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DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
240000005561 Musa balbisiana Species 0.000 description 2
235000018290 Musa x paradisiaca Nutrition 0.000 description 2
241000209094 Oryza Species 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 2
239000004111 Potassium silicate Substances 0.000 description 2
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
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244000062793 Sorghum vulgare Species 0.000 description 2
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 2
FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 2
238000013019 agitation Methods 0.000 description 2
125000002723 alicyclic group Chemical group 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
150000001345 alkine derivatives Chemical group 0.000 description 2
125000003277 amino group Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
230000008901 benefit Effects 0.000 description 2
125000002619 bicyclic group Chemical group 0.000 description 2
238000009835 boiling Methods 0.000 description 2
125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
229940097362 cyclodextrins Drugs 0.000 description 2
230000001419 dependent effect Effects 0.000 description 2
ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
238000004090 dissolution Methods 0.000 description 2
239000002706 dry binder Substances 0.000 description 2
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235000013399 edible fruits Nutrition 0.000 description 2
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238000011049 filling Methods 0.000 description 2
125000000524 functional group Chemical group 0.000 description 2
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238000006703 hydration reaction Methods 0.000 description 2
150000002430 hydrocarbons Chemical group 0.000 description 2
125000001261 isocyanato group Chemical group *N=C=O 0.000 description 2
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125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
125000001810 isothiocyanato group Chemical group *N=C=S 0.000 description 2
230000007774 longterm Effects 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000002844 melting Methods 0.000 description 2
230000008018 melting Effects 0.000 description 2
125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
125000001820 oxy group Chemical group [*:1]O[*:2] 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052698 phosphorus Inorganic materials 0.000 description 2
238000005498 polishing Methods 0.000 description 2
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235000015320 potassium carbonate Nutrition 0.000 description 2
239000001103 potassium chloride Substances 0.000 description 2
235000011164 potassium chloride Nutrition 0.000 description 2
NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 2
229910052913 potassium silicate Inorganic materials 0.000 description 2
235000019353 potassium silicate Nutrition 0.000 description 2
235000011151 potassium sulphates Nutrition 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
238000003825 pressing Methods 0.000 description 2
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238000004064 recycling Methods 0.000 description 2
239000004576 sand Substances 0.000 description 2
239000011734 sodium Substances 0.000 description 2
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238000003860 storage Methods 0.000 description 2
239000011593 sulfur Substances 0.000 description 2
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239000002699 waste material Substances 0.000 description 2
239000001993 wax Substances 0.000 description 2
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240000006432 Carica papaya Species 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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Classifications

- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N27/00—Biocides, pest repellants or attractants, or plant growth regulators containing hydrocarbons
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
- C07C13/02—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
- C07C13/04—Monocyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with a three-membered ring

Landscapes

Life Sciences & Earth Sciences (AREA)
Health & Medical Sciences (AREA)
General Health & Medical Sciences (AREA)
Dentistry (AREA)
Wood Science & Technology (AREA)
Plant Pathology (AREA)
Agronomy & Crop Science (AREA)
Engineering & Computer Science (AREA)
Environmental Sciences (AREA)
Zoology (AREA)
Pest Control & Pesticides (AREA)
Chemical & Material Sciences (AREA)
Toxicology (AREA)
Organic Chemistry (AREA)
Agricultural Chemicals And Associated Chemicals (AREA)
Cultivation Of Plants (AREA)
Medicinal Preparation (AREA)
Compositions Of Macromolecular Compounds (AREA)
Inorganic Chemistry (AREA)

AU2014287025A 2013-07-11 2014-07-11 Methods and compositions of granule formulations Ceased AU2014287025B2 (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
US201361845029P	2013-07-11	2013-07-11
US61/845,029		2013-07-11
PCT/US2014/046308 WO2015006667A1 (fr)	2013-07-11	2014-07-11	Procédés et compositions de formulations de type granulés

Publications (2)

Publication Number	Publication Date
AU2014287025A1 AU2014287025A1 (en)	2016-01-28
AU2014287025B2 true AU2014287025B2 (en)	2017-03-23

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AU2014287025A Ceased AU2014287025B2 (en)	2013-07-11	2014-07-11	Methods and compositions of granule formulations

Country Status (18)

Country	Link
EP (1)	EP3019007A4 (fr)
JP (1)	JP6469672B2 (fr)
KR (1)	KR20160030538A (fr)
CN (1)	CN105377032B (fr)
AR (1)	AR096871A1 (fr)
AU (1)	AU2014287025B2 (fr)
BR (1)	BR102014016880A2 (fr)
CA (1)	CA2917341A1 (fr)
CL (1)	CL2015003768A1 (fr)
IL (1)	IL243331B (fr)
MX (1)	MX2016000388A (fr)
PE (1)	PE20160222A1 (fr)
PH (1)	PH12016500053A1 (fr)
RU (1)	RU2016104395A (fr)
SG (1)	SG11201510772UA (fr)
TW (1)	TW201534217A (fr)
UY (1)	UY35657A (fr)
WO (1)	WO2015006667A1 (fr)

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WO2008071714A1 (fr) *	2006-12-15	2008-06-19	Rohm And Haas Company	Mélanges comprenant du 1-méthylcyclopropène
CN102119719A (zh) *	2010-12-10	2011-07-13	山东营养源食品科技有限公司	一种环丙烯类保鲜剂及其制备和包装方法
US20130019348A1 (en) *	2011-07-12	2013-01-17	Dow Agrosciences Llc	Pesticidal compositions and processes related thereto

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US3192290A (en) *	1962-08-06	1965-06-29	Minerals & Chem Philipp Corp	Method for producing rounded clay granules
US3931036A (en) *	1974-05-13	1976-01-06	Philadelphia Quartz Company	Compacted alkali metal silicate
JPS5718602A (en) *	1980-05-28	1982-01-30	Hokko Chem Ind Co Ltd	Herbicide
JPS5821602A (ja) *	1981-07-30	1983-02-08	Hokko Chem Ind Co Ltd	改良された殺虫殺センチユウ製剤
US5645843A (en) *	1986-11-24	1997-07-08	American Cyanamid Company	Safened pesticidal resin compositions for controlling soil borne pests and process for the preparation thereof
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- 2014-07-10 AR ARP140102555A patent/AR096871A1/es unknown
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- 2014-07-11 KR KR1020167003038A patent/KR20160030538A/ko not_active Ceased
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2015
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Publication number	Publication date
AU2014287025A1 (en)	2016-01-28
JP6469672B2 (ja)	2019-02-13
MX2016000388A (es)	2016-04-29
AR096871A1 (es)	2016-02-03
IL243331A0 (en)	2016-02-29
JP2016528208A (ja)	2016-09-15
TW201534217A (zh)	2015-09-16
SG11201510772UA (en)	2016-01-28
CN105377032A (zh)	2016-03-02
EP3019007A1 (fr)	2016-05-18
IL243331B (en)	2019-07-31
CN105377032B (zh)	2018-08-07
BR102014016880A2 (pt)	2015-03-17
RU2016104395A (ru)	2017-08-16
KR20160030538A (ko)	2016-03-18
PH12016500053A1 (en)	2016-03-28
WO2015006667A1 (fr)	2015-01-15
UY35657A (es)	2015-02-27
CA2917341A1 (fr)	2015-01-15
EP3019007A4 (fr)	2016-11-16
PE20160222A1 (es)	2016-04-20
CL2015003768A1 (es)	2016-08-12

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