MX2019000365A - Composiciones adhesivas a base de solvente, con alto contenido de sólidos y métodos para fabricar las mismas. - Google Patents
Composiciones adhesivas a base de solvente, con alto contenido de sólidos y métodos para fabricar las mismas.Info
- Publication number
- MX2019000365A MX2019000365A MX2019000365A MX2019000365A MX2019000365A MX 2019000365 A MX2019000365 A MX 2019000365A MX 2019000365 A MX2019000365 A MX 2019000365A MX 2019000365 A MX2019000365 A MX 2019000365A MX 2019000365 A MX2019000365 A MX 2019000365A
- Authority
- MX
- Mexico
- Prior art keywords
- component
- isocyanate
- adhesive composition
- disclosed
- methods
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000000853 adhesive Substances 0.000 title abstract 5
- 230000001070 adhesive effect Effects 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 239000007787 solid Substances 0.000 title 1
- 239000002904 solvent Substances 0.000 title 1
- 239000012948 isocyanate Substances 0.000 abstract 5
- 150000002513 isocyanates Chemical class 0.000 abstract 5
- 239000007795 chemical reaction product Substances 0.000 abstract 2
- 229920005906 polyester polyol Polymers 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000002318 adhesion promoter Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 150000007519 polyprotic acids Polymers 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
- C08G18/4213—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from terephthalic acid and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J5/00—Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2475/00—Presence of polyurethane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Se describe una composición adhesiva de dos componentes. La composición adhesiva comprende un componente de isocianato que comprende un prepolímero terminado en isocianato que es el producto-de reacción de un poliisocianato y un componente reactivo con isocianato que tienen un peso molecular medio mayor que 1,000 que comprende un poliol de poliéster que es el producto de reacción de un alcohol polihídrico y un ácido polibásico. El contenido de NCO del componente de isocianato es, opcionalmente, entre 3 y 9%. El componente reactivo con isocianato comprende un poliol de poliéster que presenta 50% en peso o más del componente reactivo con isocianato. La composición comprenda además un componente de poliol que comprende polioles de poliéter que tienen un peso molecular menor que 1500. La composición aun comprende además un promotor de adhesión. La funcionalidad media de la composición adhesiva es dfe 2 a 2.4. La composición adhesiva proporciona un rendimiento y una procesabilidad mejorados. También se describe un método para la formación de un laminado. También se describe un laminado formado por medio de este método.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662360675P | 2016-07-11 | 2016-07-11 | |
| PCT/US2017/033723 WO2018013221A1 (en) | 2016-07-11 | 2017-05-22 | High-solids content solvent-based adhesive compositions and methods of making same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019000365A true MX2019000365A (es) | 2019-06-24 |
Family
ID=58779364
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019000365A MX2019000365A (es) | 2016-07-11 | 2017-05-22 | Composiciones adhesivas a base de solvente, con alto contenido de sólidos y métodos para fabricar las mismas. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US11447671B2 (es) |
| EP (1) | EP3481884B1 (es) |
| JP (1) | JP6980752B2 (es) |
| CN (1) | CN109642011B (es) |
| AR (1) | AR108882A1 (es) |
| BR (1) | BR112019000382B1 (es) |
| MX (1) | MX2019000365A (es) |
| RU (1) | RU2743533C2 (es) |
| TW (1) | TWI744338B (es) |
| WO (1) | WO2018013221A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111032718B (zh) * | 2017-08-30 | 2022-12-02 | 陶氏环球技术有限责任公司 | 溶剂型粘合剂组合物 |
| CN112041364B (zh) | 2018-03-28 | 2022-11-11 | 陶氏环球技术有限责任公司 | 基于磷酸酯改性异氰酸酯的双组分粘合剂组合物和其制造方法 |
| BR112021025679A2 (pt) * | 2019-06-18 | 2022-02-08 | Dow Global Technologies Llc | Composição adesiva de retorta à base de solvente, adesivo, processos para a produção de uma composição adesiva e para a produção de um produto laminado, produto laminado de múltiplas camadas, e, recipiente para embalagem de retorta |
| US12344774B2 (en) | 2019-06-18 | 2025-07-01 | Arkema France | Retort adhesive composition |
| TWI887244B (zh) * | 2019-07-12 | 2025-06-21 | 美商陶氏全球科技有限責任公司 | 基於溶劑之組合物 |
| JP7148705B1 (ja) | 2021-12-21 | 2022-10-05 | 東洋インキScホールディングス株式会社 | 無溶剤型接着剤組成物、積層体、包装体及び積層体の製造方法 |
| CN115215983B (zh) * | 2022-08-12 | 2023-05-02 | 山东高速集团有限公司创新研究院 | 一种高固含量阳离子水性聚氨酯乳液及其制备方法 |
| JP2025537683A (ja) * | 2022-11-10 | 2025-11-20 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタン接着剤 |
| WO2024168616A1 (en) * | 2023-02-15 | 2024-08-22 | Dow Global Technologies Llc | Two component solvent based laminating adhesive for medical cold forming packages |
| CN119039929B (zh) * | 2024-10-28 | 2025-03-07 | 山东凯恩新材料科技有限公司 | 一种耐水的芯片灌封胶及其制备方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3205733A1 (de) * | 1982-02-18 | 1983-08-25 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung von verklebungen sowie von verbundfolien |
| US4775310A (en) | 1984-04-16 | 1988-10-04 | Velcro Industries B.V. | Apparatus for making a separable fastener |
| DE4232015A1 (de) * | 1992-09-24 | 1994-03-31 | Bayer Ag | Lösungsmittelfreie Zweikomponentenpolyurethanklebstoffsysteme |
| WO2001040342A1 (de) * | 1999-11-29 | 2001-06-07 | Henkel Kommanditgesellschaft Auf Aktien | Haftungsverstärker für monomerfreie reaktive polyurethane |
| DE10229519A1 (de) * | 2001-07-10 | 2003-01-30 | Henkel Kgaa | Reaktive Polyurethane mit einem geringen Gehalt an monomeren Diisocyanaten |
| JP2003129024A (ja) | 2001-10-25 | 2003-05-08 | Dainippon Ink & Chem Inc | ラミネート用接着剤組成物およびそのラミネート方法 |
| JP4747585B2 (ja) * | 2005-01-24 | 2011-08-17 | 横浜ゴム株式会社 | 二成分系常温硬化型液状ウレタン組成物およびそれを含む接着材料 |
| JP4455472B2 (ja) * | 2005-09-28 | 2010-04-21 | ローム アンド ハース カンパニー | 二成分アクリル‐ウレタン接着剤 |
| DE102006045041A1 (de) * | 2006-09-25 | 2008-03-27 | Evonik Degussa Gmbh | Strahlenhärtbare Formulierung, die zu flexiblen Beschichtungen mit erhöhtem Korrosionsschutz auf Metalluntergründen führt |
| CN102149739B (zh) * | 2008-09-10 | 2013-06-19 | 陶氏环球技术公司 | 用于将反应性粘合剂粘接到基底的改进方法 |
| CN102020969A (zh) * | 2009-09-18 | 2011-04-20 | 上海合达聚合物科技有限公司 | 一种双组分快固型聚氨酯胶粘剂及其应用 |
| EP2649108B1 (en) * | 2010-12-08 | 2015-09-30 | Dow Global Technologies LLC | Two-part polyurethane adhesive for bonding fiber-reinforced plastics |
| CN102174308B (zh) * | 2011-01-01 | 2013-04-24 | 北京科聚化工新材料有限公司 | 基于聚醚酯的无溶剂双组分聚氨酯复合膜用粘合剂及其制备方法 |
| DE102011007897A1 (de) * | 2011-04-12 | 2012-10-18 | Henkel Ag & Co. Kgaa | Schlagzähmodifizierte Klebstoffe |
| CN102504173B (zh) * | 2011-10-21 | 2013-12-18 | 上海摩尔舒企业发展有限公司 | 一种形状记忆喷涂聚氨酯脲弹性体树脂卫浴产品及其制备方法 |
| JP6002984B2 (ja) | 2011-12-22 | 2016-10-05 | Dic株式会社 | ハイソリッド型接着剤用樹脂組成物、及び接着剤 |
| KR20150038330A (ko) * | 2012-07-25 | 2015-04-08 | 로오드 코포레이션 | 가황후 접합 방법 |
| JP2015067663A (ja) * | 2013-09-27 | 2015-04-13 | 日立化成株式会社 | 2液型接着剤 |
| CN111454440B (zh) * | 2013-12-12 | 2024-03-15 | 陶氏环球技术有限责任公司 | 用于氨基甲酸酯体系的氨基硅烷粘合促进剂 |
| JP6291889B2 (ja) * | 2014-02-17 | 2018-03-14 | 東洋インキScホールディングス株式会社 | 接着剤組成物およびそれを用いた積層体 |
| DE102014212999A1 (de) * | 2014-07-04 | 2016-01-07 | Henkel Ag & Co. Kgaa | Polyurethan-Kaschierklebstoff enthaltend Füllstoffe |
| TWI713479B (zh) * | 2014-12-15 | 2020-12-21 | 美商陶氏全球科技責任有限公司 | 黏著劑組合物 |
-
2017
- 2017-05-22 CN CN201780051390.7A patent/CN109642011B/zh active Active
- 2017-05-22 WO PCT/US2017/033723 patent/WO2018013221A1/en not_active Ceased
- 2017-05-22 MX MX2019000365A patent/MX2019000365A/es unknown
- 2017-05-22 US US16/316,955 patent/US11447671B2/en active Active
- 2017-05-22 RU RU2019102750A patent/RU2743533C2/ru active
- 2017-05-22 JP JP2019500620A patent/JP6980752B2/ja active Active
- 2017-05-22 EP EP17726176.5A patent/EP3481884B1/en active Active
- 2017-05-22 BR BR112019000382-7A patent/BR112019000382B1/pt active IP Right Grant
- 2017-06-14 TW TW106119878A patent/TWI744338B/zh active
- 2017-06-26 AR ARP170101758A patent/AR108882A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| TWI744338B (zh) | 2021-11-01 |
| JP6980752B2 (ja) | 2021-12-15 |
| WO2018013221A1 (en) | 2018-01-18 |
| BR112019000382A2 (pt) | 2019-04-24 |
| CN109642011B (zh) | 2022-01-14 |
| RU2019102750A (ru) | 2020-07-31 |
| US11447671B2 (en) | 2022-09-20 |
| JP2019522092A (ja) | 2019-08-08 |
| EP3481884A1 (en) | 2019-05-15 |
| RU2743533C2 (ru) | 2021-02-19 |
| CN109642011A (zh) | 2019-04-16 |
| AR108882A1 (es) | 2018-10-03 |
| RU2019102750A3 (es) | 2020-09-18 |
| TW201809199A (zh) | 2018-03-16 |
| BR112019000382B1 (pt) | 2022-10-11 |
| US20200181467A1 (en) | 2020-06-11 |
| EP3481884B1 (en) | 2021-03-03 |
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