ZA963652B - Manganese dioxide for lithium batteries - Google Patents
Manganese dioxide for lithium batteriesInfo
- Publication number
- ZA963652B ZA963652B ZA963652A ZA963652A ZA963652B ZA 963652 B ZA963652 B ZA 963652B ZA 963652 A ZA963652 A ZA 963652A ZA 963652 A ZA963652 A ZA 963652A ZA 963652 B ZA963652 B ZA 963652B
- Authority
- ZA
- South Africa
- Prior art keywords
- manganese dioxide
- ion
- lithium
- exchangeable cations
- gamma
- Prior art date
Links
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 title abstract 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title abstract 4
- 229910052744 lithium Inorganic materials 0.000 title abstract 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 abstract 3
- 150000001768 cations Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000011260 aqueous acid Substances 0.000 abstract 1
- 239000003637 basic solution Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 238000005342 ion exchange Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006386 neutralization reaction Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/502—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese for non-aqueous cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/474,871 US5698176A (en) | 1995-06-07 | 1995-06-07 | Manganese dioxide for lithium batteries |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA963652B true ZA963652B (en) | 1996-11-20 |
Family
ID=23885281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA963652A ZA963652B (en) | 1995-06-07 | 1996-05-08 | Manganese dioxide for lithium batteries |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US5698176A (xx) |
| EP (1) | EP0842118B1 (xx) |
| JP (1) | JP4043513B2 (xx) |
| CN (1) | CN1113039C (xx) |
| AT (1) | ATE267772T1 (xx) |
| AU (1) | AU5982596A (xx) |
| BR (1) | BR9608570A (xx) |
| CA (1) | CA2222516C (xx) |
| CZ (1) | CZ385897A3 (xx) |
| DE (1) | DE69632586T2 (xx) |
| NZ (1) | NZ309614A (xx) |
| PL (1) | PL323713A1 (xx) |
| TW (1) | TW422818B (xx) |
| WO (1) | WO1996040588A1 (xx) |
| ZA (1) | ZA963652B (xx) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3590178B2 (ja) * | 1996-01-08 | 2004-11-17 | 三井金属鉱業株式会社 | 電解二酸化マンガンおよびその製造方法、並びにマンガン乾電池 |
| US6190800B1 (en) | 1998-05-11 | 2001-02-20 | The Gillette Company | Lithiated manganese dioxide |
| CA2334377A1 (en) | 1999-04-08 | 2000-10-19 | Mitsui Mining & Smelting Co., Ltd. | Method for preparing lithium manganate having spinel structure |
| JP4274630B2 (ja) * | 1999-05-21 | 2009-06-10 | 三井金属鉱業株式会社 | スピネル型マンガン酸リチウムの製造方法 |
| US6589693B1 (en) * | 1999-08-05 | 2003-07-08 | Eveready Battery Company, Inc. | High discharge electrolytic manganese dioxide and an electrode and alkaline cell incorporating the same |
| JP2001236957A (ja) | 2000-02-25 | 2001-08-31 | Mitsui Mining & Smelting Co Ltd | リチウム一次電池用二酸化マンガン及びその製造方法 |
| US20030162099A1 (en) * | 2002-02-28 | 2003-08-28 | Bowden William L. | Non-aqueous electrochemical cell |
| US6878489B2 (en) * | 2002-05-06 | 2005-04-12 | The Gillette Company | Lithium cell with improved cathode |
| US7045252B2 (en) * | 2002-08-08 | 2006-05-16 | The Gillette Company | Alkaline battery including lambda-manganese dioxide |
| US7045249B2 (en) * | 2003-07-02 | 2006-05-16 | The Gillette Company | Lithium cell with improved cathode |
| US20050048366A1 (en) * | 2003-08-27 | 2005-03-03 | Bowden William L. | Cathode material and method of manufacturing |
| US8137842B2 (en) * | 2004-01-22 | 2012-03-20 | The Gillette Company | Battery cathodes |
| US8003254B2 (en) * | 2004-01-22 | 2011-08-23 | The Gillette Company | Battery cathodes |
| US20050164085A1 (en) * | 2004-01-22 | 2005-07-28 | Bofinger Todd E. | Cathode material for lithium battery |
| US20060222945A1 (en) * | 2005-04-01 | 2006-10-05 | Bowden William L | Battery cathodes |
| US7771873B2 (en) * | 2005-07-12 | 2010-08-10 | Panasonic Corporation | Alkaline battery |
| US7595133B2 (en) * | 2006-07-01 | 2009-09-29 | The Gillette Company | Lithium cell |
| US20080057403A1 (en) * | 2006-09-06 | 2008-03-06 | Issaev Nikolai N | Lithium cell |
| US7981550B2 (en) | 2007-03-19 | 2011-07-19 | The Gillette Company | Lithium cell |
| US20080318123A1 (en) * | 2007-06-22 | 2008-12-25 | Zhiping Jiang | Lithium cell |
| JP2009032677A (ja) * | 2007-07-04 | 2009-02-12 | Hitachi Maxell Ltd | セパレータ用多孔質膜およびその製造方法、電池用セパレータおよびその製造方法、電池用電極およびその製造方法、ならびにリチウム二次電池 |
| US20090023054A1 (en) * | 2007-07-16 | 2009-01-22 | Zhiping Jiang | Lithium cell |
| US20090074953A1 (en) * | 2007-09-14 | 2009-03-19 | Sean Chang | Lithium cell cathode |
| US8460403B2 (en) * | 2007-09-14 | 2013-06-11 | The Gillette Company | Method of storing iron disulfide (FeS2) particles |
| US8617743B2 (en) * | 2007-12-05 | 2013-12-31 | The Gillette Company | Anode balanced lithium-iron disulfide primary cell |
| US8465860B2 (en) * | 2008-01-23 | 2013-06-18 | The Gillette Company | Lithium cell |
| US8273483B2 (en) * | 2008-02-14 | 2012-09-25 | The Gillette Company | Lithium cell |
| US20090214950A1 (en) * | 2008-02-22 | 2009-08-27 | Bowden William L | Lithium cell |
| US8076028B2 (en) * | 2008-04-16 | 2011-12-13 | The Gillette Company | Lithium cell with cathode including iron disulfide and iron sulfide |
| US8859145B2 (en) * | 2008-05-23 | 2014-10-14 | The Gillette Company | Method of preparing cathode containing iron disulfide for a lithium cell |
| JP5530353B2 (ja) * | 2008-06-09 | 2014-06-25 | 日立マクセル株式会社 | セパレータ用多孔質膜、電池用セパレータ、電池用電極およびそれらの製造方法、ならびにリチウム二次電池 |
| US20090317725A1 (en) * | 2008-06-23 | 2009-12-24 | Zhiping Jiang | Lithium cell with cathode containing iron disulfide |
| JP5278332B2 (ja) * | 2008-07-09 | 2013-09-04 | パナソニック株式会社 | リチウム一次電池用電解二酸化マンガンとその製造方法およびそれを用いたリチウム一次電池 |
| US8153296B2 (en) * | 2008-08-27 | 2012-04-10 | The Gillette Company | Lithium cell with cathode containing metal doped iron sulfide |
| US8076029B2 (en) * | 2009-01-20 | 2011-12-13 | The Gillette Company | Lithium cell with iron disulfide cathode and improved electrolyte |
| US20100203370A1 (en) * | 2009-02-12 | 2010-08-12 | Michael Pozin | Lithium cell with iron disulfide cathode |
| US8048562B2 (en) * | 2009-03-27 | 2011-11-01 | The Gillette Company | Lithium cell with improved iron disulfide cathode |
| US8790613B2 (en) * | 2010-02-24 | 2014-07-29 | Erachem Comilog, Inc. | Treated electrolytic manganese dioxide and method for its production |
| US8303840B2 (en) * | 2010-03-12 | 2012-11-06 | The Gillette Company | Acid-treated manganese dioxide and methods of making thereof |
| CN101830513A (zh) * | 2010-05-26 | 2010-09-15 | 中信大锰矿业有限责任公司 | 低钠电解二氧化锰的生产方法 |
| US9048494B2 (en) * | 2010-08-03 | 2015-06-02 | Erachem Comilog, Inc. | Electrolytic manganese dioxide improved for tool wear reduction |
| WO2012046735A1 (ja) * | 2010-10-06 | 2012-04-12 | 東ソー株式会社 | マンガン酸化物及びその製造方法、並びにそれを用いたリチウムマンガン系複合酸化物の製造方法 |
| JP5516463B2 (ja) * | 2011-03-15 | 2014-06-11 | 株式会社豊田自動織機 | リチウムイオン二次電池用正極活物質の製造方法 |
| EP3163655B1 (en) | 2015-10-28 | 2019-02-27 | Renata AG | Electro-active material of a cathode of primary battery |
| KR20190106638A (ko) | 2018-03-09 | 2019-09-18 | 주식회사 엘지화학 | 리튬 이차전지 |
| CN108493444A (zh) * | 2018-03-13 | 2018-09-04 | 福建南平南孚电池有限公司 | 一种锂锰扣式电池的正极及其制备方法 |
| JP6986472B2 (ja) * | 2018-03-22 | 2021-12-22 | Fdk株式会社 | 電池用電極材料の製造方法 |
| JP7488008B2 (ja) * | 2020-03-23 | 2024-05-21 | Fdk株式会社 | アルカリ蓄電池 |
| CN112968175B (zh) * | 2021-02-26 | 2022-05-27 | 广州鹏辉能源科技股份有限公司 | 锂电池正极活性材料的改性方法、改性的锂电池正极活性材料、正极和锂电池 |
| US20230339776A1 (en) * | 2022-04-25 | 2023-10-26 | GM Global Technology Operations LLC | Method to create a lithium manganese nickel oxide cathode using ultra-pure electrolytic manganese dioxide for improved electrochemical cell performance |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2956860A (en) * | 1957-04-11 | 1960-10-18 | Manganese Chemicals Corp | Process for producing manganese dioxide |
| US3065155A (en) * | 1960-09-02 | 1962-11-20 | Manganese Chemicals Corp | Electrolytic manganese dioxide process |
| JPS5216880B2 (xx) * | 1973-09-20 | 1977-05-12 | ||
| JPS5931182B2 (ja) * | 1975-12-17 | 1984-07-31 | 日立マクセル株式会社 | 非水電解液電池の製造方法 |
| US4312930A (en) * | 1978-09-29 | 1982-01-26 | Union Carbide Corporation | MnO2 Derived from LiMn2 O4 |
| US4277360A (en) * | 1979-03-28 | 1981-07-07 | Union Carbide Corporation | Manganese dioxide |
| JPS56126263A (en) * | 1980-03-07 | 1981-10-03 | Fuji Elelctrochem Co Ltd | Production of positive electrode active material for nonaqueous electrolyte battery |
| JPS59139566A (ja) * | 1982-11-29 | 1984-08-10 | Toshiba Battery Co Ltd | 有機溶媒電池 |
| JPH0690925B2 (ja) * | 1984-07-02 | 1994-11-14 | 三洋電機株式会社 | 非水電解液電池 |
| JPS61283342A (ja) * | 1985-06-05 | 1986-12-13 | Agency Of Ind Science & Technol | リチウム吸着剤とその製造方法 |
| JPS62126556A (ja) * | 1985-11-28 | 1987-06-08 | Toshiba Battery Co Ltd | 非水溶媒電池の製造方法 |
| US4921689A (en) * | 1988-06-24 | 1990-05-01 | Duracell Inc. | Process for producing beta manganese dioxide |
| US4959282A (en) * | 1988-07-11 | 1990-09-25 | Moli Energy Limited | Cathode active materials, methods of making same and electrochemical cells incorporating the same |
| GB2244701B (en) * | 1990-05-17 | 1994-01-12 | Technology Finance Corp | Manganese oxide compound |
| US5156934A (en) * | 1991-02-11 | 1992-10-20 | Rbc Universal Ltd. | Method of making a rechargable modified manganese dioxide material and related compound and electrode material |
| US5277890A (en) * | 1992-09-28 | 1994-01-11 | Duracell Inc. | Process for producing manganese dioxide |
-
1995
- 1995-06-07 US US08/474,871 patent/US5698176A/en not_active Expired - Lifetime
-
1996
- 1996-05-08 ZA ZA963652A patent/ZA963652B/xx unknown
- 1996-05-31 TW TW085106468A patent/TW422818B/zh not_active IP Right Cessation
- 1996-06-05 AT AT96917156T patent/ATE267772T1/de not_active IP Right Cessation
- 1996-06-05 CN CN96195236A patent/CN1113039C/zh not_active Expired - Fee Related
- 1996-06-05 PL PL96323713A patent/PL323713A1/xx unknown
- 1996-06-05 NZ NZ309614A patent/NZ309614A/xx unknown
- 1996-06-05 JP JP50131897A patent/JP4043513B2/ja not_active Expired - Fee Related
- 1996-06-05 CZ CZ973858A patent/CZ385897A3/cs unknown
- 1996-06-05 AU AU59825/96A patent/AU5982596A/en not_active Abandoned
- 1996-06-05 CA CA002222516A patent/CA2222516C/en not_active Expired - Fee Related
- 1996-06-05 BR BR9608570A patent/BR9608570A/pt not_active Application Discontinuation
- 1996-06-05 DE DE69632586T patent/DE69632586T2/de not_active Expired - Fee Related
- 1996-06-05 EP EP96917156A patent/EP0842118B1/en not_active Expired - Lifetime
- 1996-06-05 WO PCT/US1996/008833 patent/WO1996040588A1/en not_active Ceased
-
1997
- 1997-06-24 US US08/881,453 patent/US5863675A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| WO1996040588A1 (en) | 1996-12-19 |
| CN1189809A (zh) | 1998-08-05 |
| CA2222516A1 (en) | 1996-12-19 |
| US5698176A (en) | 1997-12-16 |
| TW422818B (en) | 2001-02-21 |
| AU5982596A (en) | 1996-12-30 |
| CZ385897A3 (cs) | 1998-07-15 |
| CA2222516C (en) | 2001-10-30 |
| EP0842118B1 (en) | 2004-05-26 |
| JPH11506721A (ja) | 1999-06-15 |
| NZ309614A (en) | 1999-08-30 |
| CN1113039C (zh) | 2003-07-02 |
| EP0842118A1 (en) | 1998-05-20 |
| ATE267772T1 (de) | 2004-06-15 |
| JP4043513B2 (ja) | 2008-02-06 |
| DE69632586D1 (de) | 2004-07-01 |
| US5863675A (en) | 1999-01-26 |
| PL323713A1 (en) | 1998-04-14 |
| BR9608570A (pt) | 1998-12-29 |
| EP0842118A4 (en) | 1998-08-26 |
| DE69632586T2 (de) | 2005-08-04 |
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