ZA200803687B - Reactive polyurethane-hot melt adhesive having a low isocyanate-monomer content - Google Patents
Reactive polyurethane-hot melt adhesive having a low isocyanate-monomer contentInfo
- Publication number
- ZA200803687B ZA200803687B ZA200803687A ZA200803687A ZA200803687B ZA 200803687 B ZA200803687 B ZA 200803687B ZA 200803687 A ZA200803687 A ZA 200803687A ZA 200803687 A ZA200803687 A ZA 200803687A ZA 200803687 B ZA200803687 B ZA 200803687B
- Authority
- ZA
- South Africa
- Prior art keywords
- group
- optionally
- hydrocarbyl
- heteroatom
- integer
- Prior art date
Links
- 239000004831 Hot glue Substances 0.000 title 1
- 239000000178 monomer Substances 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 6
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- 125000005842 heteroatom Chemical group 0.000 abstract 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 3
- 239000001301 oxygen Substances 0.000 abstract 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 150000004705 aldimines Chemical group 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 150000001412 amines Chemical class 0.000 abstract 1
- 125000002837 carbocyclic group Chemical group 0.000 abstract 1
- 150000001733 carboxylic acid esters Chemical class 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- ALJYEHUPOPFBCG-UHFFFAOYSA-N nitrophosphonic acid Chemical compound OP(O)(=O)[N+]([O-])=O ALJYEHUPOPFBCG-UHFFFAOYSA-N 0.000 abstract 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 abstract 1
- 125000002130 sulfonic acid ester group Chemical group 0.000 abstract 1
- 229910052717 sulfur Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1021—Polyurethanes or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/088—Removal of water or carbon dioxide from the reaction mixture or reaction components
- C08G18/0885—Removal of water or carbon dioxide from the reaction mixture or reaction components using additives, e.g. absorbing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/089—Reaction retarding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/12—Polyurethanes from compounds containing nitrogen and active hydrogen, the nitrogen atom not being part of an isocyanate group
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Polyurethanes Or Polyureas (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP05109112A EP1770107A1 (fr) | 2005-09-30 | 2005-09-30 | Composition de polyuréthanne durcissant par l'humidité |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ZA200803687B true ZA200803687B (en) | 2009-04-29 |
Family
ID=35788013
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200803687A ZA200803687B (en) | 2005-09-30 | 2006-09-29 | Reactive polyurethane-hot melt adhesive having a low isocyanate-monomer content |
| ZA200803689A ZA200803689B (en) | 2005-09-30 | 2008-04-25 | Moisture-hardened polyurethane compositions containing compounds comprising aldimine |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ZA200803689A ZA200803689B (en) | 2005-09-30 | 2008-04-25 | Moisture-hardened polyurethane compositions containing compounds comprising aldimine |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US8088244B2 (fr) |
| EP (3) | EP1770107A1 (fr) |
| JP (2) | JP5197370B2 (fr) |
| KR (2) | KR20080055978A (fr) |
| CN (2) | CN101309947B (fr) |
| AT (1) | ATE486900T1 (fr) |
| BR (2) | BRPI0616775B8 (fr) |
| CA (2) | CA2628329A1 (fr) |
| DE (1) | DE502006008247D1 (fr) |
| DK (1) | DK1937741T3 (fr) |
| ES (1) | ES2355273T3 (fr) |
| RU (2) | RU2410399C2 (fr) |
| WO (2) | WO2007036575A1 (fr) |
| ZA (2) | ZA200803687B (fr) |
Families Citing this family (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005023529A2 (fr) * | 2003-09-09 | 2005-03-17 | Vision-Ease Lens, Inc. | Stratifie de polyurethanne photochromique |
| EP1772447A1 (fr) * | 2005-09-30 | 2007-04-11 | Sika Technology AG | Aldimines avec groupements réactifs comprenant de l'hydrogène actif et leur utilisation |
| EP1770107A1 (fr) * | 2005-09-30 | 2007-04-04 | Sika Technology AG | Composition de polyuréthanne durcissant par l'humidité |
| JP2008004691A (ja) * | 2006-06-21 | 2008-01-10 | Toppan Printing Co Ltd | 太陽電池裏面封止用シート |
| EP1918314A1 (fr) | 2006-10-31 | 2008-05-07 | Sika Technology AG | Composition de polyuréthane ayant une résistance initiale élevée |
| EP1923445B1 (fr) * | 2006-11-17 | 2009-06-24 | Sika Technology AG | Composition adhésive thermofusible réticulable à l'humidité contenant un polyaldimine |
| EP1975189A1 (fr) | 2007-03-27 | 2008-10-01 | Sika Technology AG | Composition de polyuréthane comprenant de la dialdimine asymétrique |
| EP1975186A1 (fr) * | 2007-03-27 | 2008-10-01 | Sika Technology AG | Composition munie de groupes d'isocyanat et d'aldimine contenant une teneur en isocyanat monomère moindre |
| EP1975187A1 (fr) * | 2007-03-28 | 2008-10-01 | Sika Technology AG | Procédé de fabrication de composition de polyuréthane ayant une teneur en isocyanat monomère moindre |
| EP1975190A1 (fr) * | 2007-03-28 | 2008-10-01 | Sika Technology AG | Aldimine comportant des groupes réactifs à hydrogène actif |
| EP1990387B1 (fr) * | 2007-05-11 | 2010-07-21 | Sika Technology AG | Corps de couche composite lié par de la matière collante transdermique tout comme procédé de collage de plastifiants comprenant du plastique |
| EP2031001A1 (fr) * | 2007-08-31 | 2009-03-04 | Sika Technology AG | Utilisation d'une composition de colle fondue à chaud en tant que première couche |
| US20090068479A1 (en) * | 2007-09-11 | 2009-03-12 | Sika Technology Ag | Moisture-reactive adhesive compositions with very low temperature dependency of the shear modulus |
| EP2036931A1 (fr) * | 2007-09-11 | 2009-03-18 | Sika Technology AG | Compositions de colle réactive à l'humidité à module de poussée peu dépendant de la température |
| WO2009062985A1 (fr) | 2007-11-13 | 2009-05-22 | Sika Technology Ag | Aldimines aromatiques et compositions de polyuréthane contenant de l'aldimine |
| EP2072551A1 (fr) * | 2007-12-21 | 2009-06-24 | Sika Technology AG | Compositions de couche primaire comprenant de l'aldimine |
| DE502008002085D1 (de) * | 2008-07-14 | 2011-02-03 | Sika Technology Ag | Amorphes Polyurethanpolymer und dessen Verwendung in Heissschmelzklebstoffen |
| ATE546480T1 (de) | 2008-07-17 | 2012-03-15 | Sika Technology Ag | Verfahren zur herstellung geblockter alkohole |
| ES2364725T3 (es) * | 2008-10-31 | 2011-09-13 | Sika Technology Ag | Composición de poliuretano que contiene organometoxisilano con propiedades de material anisotrópico. |
| DE502008002637D1 (de) * | 2008-10-31 | 2011-03-31 | Sika Technology Ag | Alpha-Silan enthaltende Polyurethanzusammensetzung mit anisotropen Materialeigenschaften |
| DK2194081T3 (da) * | 2008-12-02 | 2011-12-19 | Sika Technology Ag | Polyurethansammensætning, som indeholder hydroxyaldimin |
| EP2194082B1 (fr) * | 2008-12-02 | 2011-09-07 | Sika Technology AG | Aldimine et composition contenant aldimine |
| US8277601B2 (en) * | 2008-12-12 | 2012-10-02 | Henkel Corporation | Reactive hot melt adhesive |
| EP2330140A1 (fr) * | 2009-12-02 | 2011-06-08 | Sika Technology AG | Composition de nettoyage à base d'aldimines pour compositions réactives de polyuréthane. |
| US9116253B2 (en) * | 2011-01-11 | 2015-08-25 | Pgs Geophysical As | System and method for using biocide coating to prevent marine growth on geophysical equipment |
| CN104903378B (zh) * | 2013-01-22 | 2019-05-17 | Sika技术股份公司 | 包含三醛亚胺的屋顶用液体施加的防水膜 |
| CN106232663B (zh) * | 2014-03-11 | 2019-06-28 | Sika技术股份公司 | 无溶剂的聚氨酯液体薄膜 |
| EP3116930B1 (fr) | 2014-03-11 | 2018-05-16 | Sika Technology AG | Adhésif thermofusible en polyuréthane avec une faible teneur en diisocyanates monomères et une bonne vitesse de réticulation |
| CN106103525B (zh) * | 2014-03-11 | 2019-06-25 | Sika技术股份公司 | 具有长开放时间的双组份聚氨酯粘合剂 |
| BR112016027351B1 (pt) * | 2014-05-30 | 2022-03-15 | Dow Global Technologies Llc | Sistema selante curável com umidade, sistema selante curável reativo e método para formar um selante |
| CN104263218B (zh) * | 2014-09-04 | 2017-02-01 | 三棵树涂料股份有限公司 | 一种弹性环氧聚氨酯木地板漆及其制备方法 |
| CN104194602B (zh) * | 2014-09-04 | 2016-10-19 | 三棵树涂料股份有限公司 | 一种弹性环氧聚氨酯哑光木地板漆及其制备方法 |
| MX2017004870A (es) * | 2014-10-13 | 2017-07-04 | Dow Global Technologies Llc | Adhesivo de laminacion de monomero bajo. |
| US10072178B2 (en) * | 2015-04-21 | 2018-09-11 | Ndsu Research Foundation | Biobased cyclic carbonate functional resins and polyurethane thermosets therefrom |
| EP3088435A1 (fr) | 2015-04-28 | 2016-11-02 | Sika Technology AG | Procédé en deux étapes destiné à la fabrication d'une colle polyuréthane à fondre à chaud à faible teneur en diisocyanates monomères et à durcissement rapide |
| DE102015106982A1 (de) * | 2015-05-05 | 2016-11-10 | Lisa Dräxlmaier GmbH | Zeolithhaltige Heißschmelzklebe-, Heißschmelzdicht- und Heißklebebeschichtungsmassen |
| WO2017009310A1 (fr) * | 2015-07-15 | 2017-01-19 | Sika Technology Ag | Colle thermofusible polyuréthane, contenant des dialdimines, offrant une meilleure adhérence sur l'acier inoxydable |
| WO2017102888A1 (fr) * | 2015-12-15 | 2017-06-22 | Lisa Dräxlmaier GmbH | Procédé pour revêtir une pièce en matière plastique avec un adhésif fusible |
| WO2017108834A1 (fr) | 2015-12-21 | 2017-06-29 | Sika Technology Ag | Compositions de polyuréthane présentant une migration des plastifiants réduite |
| CN108431067B (zh) * | 2015-12-21 | 2021-11-23 | Sika技术股份公司 | 羟基醛亚胺和具有低单体异氰酸酯含量的可固化聚氨酯组合物 |
| EP3426710B1 (fr) * | 2016-03-10 | 2022-09-28 | Momentive Performance Materials Inc. | Résine silylée durcissable à l'humidité dérivée de polycarbonate diol et revêtement, matériau d'étanchéité et compositions adhésives la contenant |
| EP3279231A1 (fr) | 2016-08-03 | 2018-02-07 | Sika Technology AG | Adhesif polyurethane bicomposants tres resistant et ayant des proprietes mecaniques essentiellement asservies a la temperature |
| US20190367661A1 (en) * | 2016-10-18 | 2019-12-05 | Dow Global Technologies Llc | Aldimine containing glass bonding primer |
| CN107142068B (zh) * | 2017-04-10 | 2021-02-26 | 广东普赛达密封粘胶有限公司 | 一种热固化单组分聚氨酯组合物及其制备方法 |
| EP3679107B1 (fr) * | 2017-09-08 | 2021-07-14 | Sika Technology AG | Adhésif thermofusible de polyuréthane durcissant à l'humidité présentant une bonne adhérence à des substrats polaires |
| CN111542434B (zh) * | 2017-10-27 | 2022-05-24 | 安特科技有限公司 | 将聚合物膜施加到基底的方法和所得物品 |
| CN111040707A (zh) * | 2018-10-12 | 2020-04-21 | 苏州美山子制衣有限公司 | 布料点胶机用胶水及其制备方法 |
| CN109593456A (zh) * | 2018-12-06 | 2019-04-09 | 长沙盾甲新材料科技有限公司 | 耐磨型单组分聚氨酯涂料及其制备方法 |
| CN109609013A (zh) * | 2018-12-06 | 2019-04-12 | 长沙盾甲新材料科技有限公司 | 耐高温单组分聚氨酯涂料及其制备方法 |
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| EP4013803B1 (fr) * | 2019-08-15 | 2024-07-31 | Sika Technology AG | Composition de polyuréthane durcissable à l'humidité présentant une adhésivité de surface réduite |
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| EP1524282A1 (fr) * | 2003-10-15 | 2005-04-20 | Sika Technology AG | Compsition de polyurethanne à deux composants, présentant une grande resistance initiale |
| KR20080071132A (ko) * | 2005-09-30 | 2008-08-01 | 시카 테크놀러지 아게 | 알디민 함유 화합물 |
| EP1770107A1 (fr) * | 2005-09-30 | 2007-04-04 | Sika Technology AG | Composition de polyuréthanne durcissant par l'humidité |
-
2005
- 2005-09-30 EP EP05109112A patent/EP1770107A1/fr not_active Withdrawn
-
2006
- 2006-09-29 EP EP06806899A patent/EP1937740A1/fr not_active Withdrawn
- 2006-09-29 RU RU2008117165/04A patent/RU2410399C2/ru not_active IP Right Cessation
- 2006-09-29 ZA ZA200803687A patent/ZA200803687B/xx unknown
- 2006-09-29 AT AT06819065T patent/ATE486900T1/de active
- 2006-09-29 RU RU2008117166/04A patent/RU2408611C2/ru not_active IP Right Cessation
- 2006-09-29 ES ES06819065T patent/ES2355273T3/es active Active
- 2006-09-29 DK DK06819065.1T patent/DK1937741T3/da active
- 2006-09-29 KR KR1020087010607A patent/KR20080055978A/ko not_active Withdrawn
- 2006-09-29 US US11/992,130 patent/US8088244B2/en not_active Expired - Fee Related
- 2006-09-29 KR KR1020087010606A patent/KR20080063814A/ko not_active Withdrawn
- 2006-09-29 BR BRPI0616775A patent/BRPI0616775B8/pt not_active IP Right Cessation
- 2006-09-29 WO PCT/EP2006/066929 patent/WO2007036575A1/fr not_active Ceased
- 2006-09-29 JP JP2008532801A patent/JP5197370B2/ja not_active Expired - Fee Related
- 2006-09-29 CN CN2006800429379A patent/CN101309947B/zh not_active Expired - Fee Related
- 2006-09-29 CA CA002628329A patent/CA2628329A1/fr not_active Abandoned
- 2006-09-29 EP EP06819065A patent/EP1937741B1/fr not_active Not-in-force
- 2006-09-29 BR BRPI0616635-0A patent/BRPI0616635A2/pt not_active IP Right Cessation
- 2006-09-29 DE DE502006008247T patent/DE502006008247D1/de active Active
- 2006-09-29 JP JP2008532800A patent/JP5193047B2/ja not_active Expired - Fee Related
- 2006-09-29 WO PCT/EP2006/066927 patent/WO2007036574A1/fr not_active Ceased
- 2006-09-29 US US11/992,120 patent/US7741425B2/en not_active Expired - Fee Related
- 2006-09-29 CN CN2006800428978A patent/CN101309946B/zh not_active Expired - Fee Related
- 2006-09-29 CA CA002628327A patent/CA2628327A1/fr not_active Abandoned
-
2008
- 2008-04-25 ZA ZA200803689A patent/ZA200803689B/xx unknown
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