WO2025166392A1 - Reactor for producing coal and synthesis gas from biomass - Google Patents
Reactor for producing coal and synthesis gas from biomassInfo
- Publication number
- WO2025166392A1 WO2025166392A1 PCT/AT2024/060228 AT2024060228W WO2025166392A1 WO 2025166392 A1 WO2025166392 A1 WO 2025166392A1 AT 2024060228 W AT2024060228 W AT 2024060228W WO 2025166392 A1 WO2025166392 A1 WO 2025166392A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- reactor
- working chamber
- biomass
- electrically conductive
- working space
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B19/00—Heating of coke ovens by electrical means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
- C10B57/06—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition containing additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/18—Modifying the properties of the distillation gases in the oven
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B7/00—Coke ovens with mechanical conveying means for the raw material inside the oven
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/002—Horizontal gasifiers, e.g. belt-type gasifiers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/005—Rotary drum or kiln gasifiers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/18—Continuous processes using electricity
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
- C10J3/60—Processes
- C10J3/62—Processes with separate withdrawal of the distillation products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/005—Reducing the tar content by partial oxidation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/12—Heating the gasifier
- C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1662—Conversion of synthesis gas to chemicals to methane
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
Definitions
- the invention relates to a reactor for producing coal and synthesis gas from biomass, comprising a working chamber laterally delimited by a working chamber wall, an inlet through which the biomass can be introduced into the working chamber, and an outlet through which coal and synthesis gas can be discharged from the working chamber, wherein biomass can be moved along a transport path from the inlet to the outlet through the working chamber.
- the invention further relates to a process for producing coal and synthesis gas from biomass.
- the object of the invention is to provide a reactor and a process of the type mentioned above, with which the conversion of biomass into coal and synthesis gas is possible with a particularly high yield.
- the first object is achieved according to the invention with a reactor of the type mentioned at the outset, in which an electrically conductive element is provided in the working chamber and/or in the working chamber wall, wherein the electrically conductive element can be heated electrically, preferably inductively, in particular by an induction coil, in order to To convert biomass in the working space into synthesis gas and coal.
- electrical energy can also be used particularly efficiently to convert biomass into coal and synthesis gas if the biomass is heated electrically, in particular inductively, in the working chamber.
- electrical energy can also be used particularly efficiently to convert biomass into coal and synthesis gas if the biomass is heated electrically, in particular inductively, in the working chamber.
- the process implementable with the reactor according to the invention makes it possible to use electrical energy, which is particularly inexpensive when solar radiation or wind speeds are high, to convert biomass, which is difficult to transport due to its large volume, into more easily transportable energy sources such as coal and synthesis gas.
- the process is suitable for converting electrical energy and energy stored in biomass into coal and synthesis gas.
- the electrically conductive element can be arranged both in the working chamber and in the working chamber wall in order to heat biomass located in the working chamber.
- coal produced with a reactor according to the invention and a process according to the invention naturally contains ash in addition to combustible material.
- the ash content of the coal can increase to, for example, 90% or more, so that the carbon content is very low.
- coal is understood not only to mean combustible material, but also the ash content contained in the solid.
- the electrically conductive element can, for example, be designed as a thin heating wire, which can act both as a heating resistor of a resistance heater and as an element that is inductively heated by an additional induction coil.
- the element can also be designed, for example, as a plate- or cylinder-shaped element made of graphite or the like.
- coal and synthesis gas are usually moved together at the outlet from the working chamber, which is why the reactor acts as an inductively operated allothermal cocurrent gasifier.
- the reactor also includes an induction coil, which can heat the electrically conductive element.
- the induction coil can be arranged on the outside of the working chamber wall or within the working chamber, in particular on a mandrel arranged within the working chamber.
- the working chamber wall has proven effective for the working chamber wall to have openings through which a gasification medium, in particular steam, can be introduced into the working chamber.
- the openings are arranged in the working chamber in such a way that the outflow direction of the gasification medium is approximately parallel to the transport direction. This enables a particularly uniform distribution of the gasification medium in the working chamber and in the biomass.
- a mandrel having openings is arranged in the working chamber, preferably approximately centrally, through which mandrel a gasification medium, in particular water vapor or carbon dioxide, can be introduced into the working chamber.
- a gasification medium in particular water vapor or carbon dioxide
- the operation of the reactor can be controlled via the temperature in the working chamber and/or the mass flow of the gasification medium via the mandrel in such a way that 100% synthesis gas, 100% coal, or a combination product of synthesis gas and coal with any proportions of synthesis gas and coal is obtained.
- the mandrel is oriented parallel to the transport path, in particular along a direct connection from inlet to outlet.
- the working space is usually arranged approximately rotationally symmetrically to a central axis, in particular approximately cylindrical or conical, along which central axis the mandrel is preferably arranged in order to ensure the most uniform possible penetration of To allow the gasification medium to enter the working chamber.
- the mandrel is typically elongated, preferably designed as a tube with a closed end and a diameter of, for example, less than 10 cm, and has several openings to minimize the movement of the biomass in the working chamber and simultaneously enable the most even distribution of the gasification medium in the working chamber and in the biomass.
- multiple mandrels with openings can also be provided, for example, four mandrels, which are supplied with the same or different gasification media.
- the volume flows across the individual mandrels can be the same or different. If multiple mandrels are provided, they can be distributed longitudinally within the working chamber, circumferentially, and/or radially throughout the working chamber to control chemical processes in the working chamber with particular precision and, for example, to supply different gasification media and/or gasification media with different volume flows to different positions within the working chamber.
- the working chamber is designed with a cross-section that increases at least in some areas from the inlet to the outlet, in particular, for example, conical. This ensures that only minimal energy is required to move the biomass in the working chamber from the inlet to the outlet, and blockage of the working chamber is avoided.
- the working chamber can be designed, for example, by cylindrical sections with increasing cross-sections, resulting in one or more diameter jumps, or with a continuously increasing cross-section, for example, in the shape of a truncated cone.
- the mandrel is approximately cylindrical. This allows for a uniform introduction of gasification medium into the working chamber, particularly via openings distributed radially and axially along the mandrel.
- a longitudinal axis of the mandrel or a cylinder axis is preferably coaxial with an axis of the working chamber, which can be cylindrical or conical.
- the mandrel is made of an electrically conductive material or has an electrically conductive material.
- the induction coil which usually enclosing the working space and arranged with a central axis which corresponds to a central axis of the working space, thus also causes the mandrel to be heated, whereby the mandrel can be used on the one hand to release a gasification medium and on the other hand to heat the biomass.
- the working chamber has a substantially rotationally symmetrical cross-section.
- the working chamber wall is typically designed as a cylindrical or conical surface.
- a rotational axis of the working chamber is typically coaxial with a longitudinal axis of the mandrel to ensure a very uniform distribution of the gasification medium in the working chamber.
- the rotational axis is also coaxial with a coil axis of the induction coil.
- the working chamber wall it has proven useful for the working chamber wall to be made of an electrically non-conductive material, particularly glass or ceramic.
- the material of the working chamber wall then allows an electromagnetic field generated by the induction coil, which is usually arranged on the outside around the working chamber wall, to act through the working chamber wall into the working chamber, in which one or more electrically conductive elements are arranged. These elements are heated by the induction coil in order to bring the biomass to a temperature at which the chemical reaction for conversion into coal and synthesis gas is initiated.
- glass and ceramic are also suitable for permanently withstanding correspondingly high temperatures, making these materials particularly well suited for forming the working chamber wall.
- the reactor is usually operated at a temperature of around 1100 degrees Celsius in the working chamber.
- the work chamber wall may also be partially or completely made of an electrically conductive material such as a metal, in particular steel.
- the work chamber wall is made of a high-temperature-resistant material, in particular glass, ceramic, or steel. If the work chamber wall is made of an electrically conductive material, the work chamber wall itself can serve as a heating element. It may thus be provided that the work chamber wall consists at least partially of an electrically conductive material and thus acts as a heating element.
- the electrically conductive elements can be made of graphite, which can withstand high temperatures well.
- the work chamber wall may be provided with electrically conductive heating elements on the outside, preferably made of graphite. This allows high temperatures in the work chamber to be achieved in a particularly favorable manner.
- insulation is provided that surrounds the work chamber wall at least in part. This insulation ensures that heating caused by the induction coil in the electrically conductive elements essentially leads to heating of the biomass in the work chamber, and that the thermal energy is not released into the environment, or at least only to a small extent. It is advantageous if the insulation is arranged directly on heating elements arranged on the outside of the work chamber wall.
- the insulation is at least partially made of an electrically non-conductive material. This ensures that the insulation itself is not heated by an electromagnetic field generated by the induction coil.
- the insulation is formed at least partially by a gas.
- the insulation can also be formed by a vacuum, so that the heating elements arranged on the outside of the work chamber wall are separated from the surroundings by a gas or a vacuum, thereby significantly inhibiting heat transfer from the heating elements to the surroundings.
- the conveying mechanism can be designed in a variety of ways, for example, as a conveyor screw.
- it has proven effective for the conveying mechanism to have a movable piston, by means of which the biomass located in the working chamber can be moved along the transport path, with the piston being movable, in particular, parallel to the transport direction.
- biomass feed through which biomass can be fed into a region upstream of the inlet, in particular along a feed direction that is transverse to the transport direction, in particular perpendicular to the transport direction.
- the upstream region can, in particular, be a region through which the piston moves during one stroke, so that biomass introduced into this upstream region transverse to the transport direction is pressed into the working chamber by the piston during one stroke.
- a discharge device in particular a screw conveyor or a piston, is preferably provided at the outlet, by means of which coal can be conveyed from the working chamber into a coal container connected to the outlet.
- the screw conveyor can have a plate with openings at its end, whereby the biomass can penetrate through the openings into the screw conveyor.
- the plate provides sufficient resistance so that a desired pressure can be maintained in the biomass in the working chamber. can determine which pressure is advantageous for achieving the chemical processes for the formation of coal and synthesis gas.
- a conveying mechanism which in particular has a piston
- a discharge device which in particular has a conveyor screw with an end plate
- the conveying mechanism and the discharge device thus perform parallel, i.e. simultaneous and usually co-directional lifting movements in or against the transport direction, thereby enabling a continuous feeding of biomass into the working chamber and discharge of coal from the working chamber with the most uniform pressure possible in the working chamber.
- the discharge device comprises a bearing for a mandrel arranged in the working chamber, wherein the mandrel is preferably not mounted in the working chamber between the inlet and outlet.
- This bearing can be formed, for example, by a roller or plain bearing arranged centrally in the end plate of the conveyor screw, in which the mandrel, formed by, for example, a tube, is mounted. It has been shown that additional bearing of the mandrel in the working chamber entails a risk of biomass becoming caught on supports of such a bearing point and blocking transport within the working chamber. This risk is avoided by exclusively bearing the mandrel at the end.
- a gas outlet is provided connected to the working chamber, through which synthesis gas generated in the working chamber can be extracted.
- the synthesis gas can, for example, be fed into a pipeline or filled into containers for subsequent use.
- the induction coil can be provided with different pitches along an axial extension of the working chamber. These different pitches can result in different power densities at the same current intensity, which are introduced into the working chamber by the induction coil, allowing different areas within the working chamber to be heated to different degrees.
- induction coils can also be provided, which have different gradients in order to be able to control the energy input into individual areas of the work space with particular precision.
- one or more temperature sensors are provided in the work chamber, with a control system provided to achieve a predefined temperature in the work chamber using the induction coil.
- the various temperature sensors can be arranged along an axial extent of the work chamber and/or distributed over a circumference of the work chamber in order to be able to control the chemical processes in the work chamber particularly well.
- the induction coil is controlled to a desired target temperature in the work chamber, for example, 1,100 °C, or that the current of the induction coil is increased or decreased until the desired temperature is reached.
- the working space wall is surface-treated and/or coated on the inside, in particular in order to achieve improved wear resistance and/or low roughness, preferably a roughness with a mean roughness value Ra of less than 0.5 pm.
- the lock system can, for example, comprise a first gas-tight lock, through which Which biomass, coal, and synthesis gas can enter one lock chamber, and from which lock chamber the biomass, coal, and synthesis gas can then be moved through a second gas-tight lock into the work chamber or surrounding area.
- a first gas-tight lock through which Which biomass, coal, and synthesis gas can enter one lock chamber, and from which lock chamber the biomass, coal, and synthesis gas can then be moved through a second gas-tight lock into the work chamber or surrounding area.
- both locks are opened sequentially, rather than simultaneously, so that there is never a direct connection between the work chamber and the surrounding area.
- the working chamber is gas-tight from the surrounding environment. This can be achieved, for example, by means of a lock system at the inlet and outlet, so that only system media such as biomass, gasification agents, and synthesis gases or product gas can enter the working chamber.
- the further object is achieved by a method for producing coal and synthesis gas from biomass of the type mentioned above, wherein the biomass is heated electrically, in particular by an induction coil, in a reactor in a working chamber, in particular in a reactor according to the invention.
- This enables particularly precise control of the temperature in the working chamber and the use of excess electrical energy to produce coal or synthesis gas from biomass, particularly on windy days or days with high solar radiation.
- electrically conductive additives which in particular have a spherical shape, are added to the biomass before it is introduced into the working chamber, wherein the additives are inductively heated in the working chamber in order to heat the biomass by means of the inductively heated additives.
- Fig. 1 shows a reactor according to the invention in a schematic representation
- Fig. 3 shows a section through the reactor of Fig. 2.
- Fig. 1 shows a schematic representation of a reactor 1 according to the invention for carrying out a method according to the invention. It shows a working chamber 2, which is defined by a working chamber wall 3 and on which three induction coils 8 are arranged on the outside to inductively heat heating elements 11 located in or on the working chamber 2, so that biomass located in the working chamber 2 reaches a temperature of, for example, 1,100 °C, which temperature is required to initiate chemical reactions through which this biomass is converted into coal and synthesis gas.
- Biomass is fed to the reactor 1 via a feed hopper 6, through which the biomass reaches an area upstream of the working chamber 2, from which the biomass is moved by means of a piston 14 along a transport direction 7 through an inlet 4 into the working chamber 2.
- the biomass is converted into coal and synthesis gas by the inductive heat supply.
- Produced coal or biochar is discharged from the working chamber 2 via an outlet 5, specifically into a coal container 16 adjacent to the working chamber 2.
- the transport direction 7 is defined here by a direct connection from inlet 4 to outlet 5.
- the working chamber 2 can also have a longitudinal axis that corresponds to a non-straight line, so that the transport direction 7, along which the biomass or coal is moved in the working chamber 2, can in principle also be formed by a curved line.
- the synthesis gas leaves the reactor 1 via a gas outlet 19, which is also directly or indirectly connected to the outlet.
- a mandrel 9 is arranged in the working chamber 2, which is connected to a supply line for a gasification medium, so that a gasification medium, for example, water vapor or carbon dioxide, can be introduced into the working chamber 2 through the mandrel 9.
- a gasification medium for example, water vapor or carbon dioxide
- the mandrel 9 is also made of an electrically conductive material, so that the mandrel 9 can also be inductively heated by the induction coils 8.
- the biomass is fed through the feed hopper 6 transversely to the transport direction 7 into an area in front of the working chamber 2, from which the biomass is moved into the working chamber by means of the piston.
- a screw conveyor 15 with an end plate 18 is arranged in the working chamber 2.
- the end plate 18 has openings (not shown) through which coal is introduced into the screw conveyor 15 along the transport direction 7, after which the coal is discharged into a coal container 16 by means of the screw conveyor 15.
- the conveyor screw 15, together with the end plate 18, is movable parallel to the transport direction 7 and in the same direction as the piston 14, which is indicated by an additional dash-dotted representation of piston 14 and conveyor screw 15 at a position with a modified stroke in Fig. 1.
- the piston 14 and conveyor screw are thus usually moved simultaneously and in the same direction in a translational manner along the transport direction 7, whereby biomass located in the working chamber 2 is also pressed against the end plate 18.
- the conveyor screw 15 with the end plate 18 acts as a compression piston and a predefined pressure can be maintained in the working chamber 2 during the process.
- heating elements 11 are arranged on the work chamber wall 3, which are also heated by the induction coils 8.
- insulation 12 usually high-temperature insulation 12 is arranged on the outside of these heating elements 11.
- these heating elements 11 are surrounded by a closed gas space 13, which also has an insulating effect.
- a vacuum could also be provided at this position.
- a coating with a low emission coefficient or emissivity can be provided on the outside of the heating elements 11 in order to ensure that the heat radiated by the heating elements 11 essentially acts on the work chamber 2.
- the working chamber 2 is depicted as cylindrical here. However, in order to consume as little energy as possible for moving the biomass along the transport direction 7 through the working chamber 2, it can also be provided that the cross-section of the working chamber 2 increases between the inlet 4 and the outlet 5, so that the working chamber 2 can be designed, for example, conically or with cylindrical tubes with a cross-section that increases along the transport direction 7.
- Heating elements 11, which are not shown in Fig. 1, can also be arranged on the inside of the work chamber wall 3 in order to bring the work chamber 2 or the biomass located therein to the appropriate temperature.
- the heating elements 11 are preferably made of graphite, although another material that can be heated inductively can also be used.
- the heating elements 11 are made of an electrically conductive material that can withstand temperatures of more than 1,000 °C.
- a corresponding coating can also be provided on the outside of these internal heating elements 11 in order to prevent or minimize the radiation of thermal energy to the outside.
- a chemically resistant coating in particular an ash- and/or slag-repellent protective layer, can be provided on the inside of the work chamber wall 3. It is understood that this coating is usually not electrically conductive itself in order to avoid heating by the electromagnetic field generated by the induction coils 8.
- three coils are provided in the illustrated embodiment, so that the working chamber 2 can be heated to different intensities along an axial extent by means of the three coils. In this way, a desired temperature can be easily set in each area.
- temperature sensors (not shown here) are usually positioned in the working chamber 2, and a control system is provided which is connected to the temperature sensors and the induction coils 8.
- a cooling device can be provided, in particular a cooling medium flowing around the induction coils 8.
- the temperature sensors can be arranged along the transport direction and at different distances from a central axis of the working chamber in order to be able to record a temperature profile in the working chamber as accurately as possible, which can subsequently be used to control the induction coils, the piston and/or the volume flow of the gasification medium.
- Fig. 1 shows that additives 17 are introduced into the working chamber 2 together with the biomass.
- additives 17 can be, for example, graphite spheres, which are also heated by the induction tracks in order to ensure the most uniform heating possible of the biomass in the working chamber 2.
- Additives 17 can also be used to influence the pyrolysis process by influencing the ash softening temperature or by effecting in-situ desulfurization.
- the additives 17 are conveyed with the coal via outlet 5 into the coal container 16 and can thus subsequently be separated from the coal and reused.
- the working chamber wall 3 is usually made of ceramic or glass, so that it easily allows the electromagnetic field generated by the induction coils 8 to pass into the working chamber 2 and at the same time can withstand the high temperatures.
- the mandrel 9, which is usually approximately cylindrical, has openings 10 in particular on its circumference and can also be made of a metal, so that the mandrel 9 is also heated by the induction coils 8 in order to achieve appropriate temperature control of the biomass.
- the biomass is thus moved from the inlet 4 to the outlet 5 through the working chamber 2, where it is heated by the heating elements 11 and the mandrel 9.
- the biomass pyrolyzes and is converted into pyrolysis gas and biochar, or synthesis gas and coal.
- the coal is conveyed further and experiences a defined accumulation at the end plate 18, which acts as a compression piston, creating a dense and defined coal bed through which the generated synthesis gas and a gasification medium supplied via the mandrel 9 flow.
- the synthesis gas has CO, H2, CH4, and CO2 as its main components, although its composition is variable and can depend in particular on process parameters such as temperature, volume flow of the gasification medium, and/or pressure in the working chamber.
- the synthesis gas produced by the reactor can then be further processed into various other products, such as feed-in synthetic natural gas/methane (CH4), methanol or purified into (green) hydrogen.
- CH4 feed-in synthetic natural gas/methane
- methanol methanol
- purified into (green) hydrogen tars are reformed into short-chain hydrocarbons by the pyrolysis gas, and on the other hand, biochar itself is decomposed and partially gasified by the gasification medium.
- the coal accumulated at the end plate 18 of the screw conveyor 15 is subsequently moved into the screw conveyor 15 via openings arranged in the end plate 18 and discharged with it into the coal container 16.
- the mandrel 9 is mounted only in the piston 14. Especially in longer reactors 1, a second mounting of the mandrel 9 can also be provided, preferably in the area of the conveyor screw 15 or the end plate 18.
- FIG. 2 and 3 show a further embodiment of a reactor 1, which is designed essentially analogously to the reactor 1 shown in Fig. 1.
- Fig. 3 shows a section through the reactor 1 along the line III - III in Fig. 2.
- a gasification medium is supplied not only via the openings 10 in the mandrel 9, but also via wall openings 20 in the working chamber wall 3.
- these wall openings 20 are arranged so as to be regularly distributed over a circumference of the working chamber 2 and are aligned such that the gasification medium flows out approximately parallel to the transport direction 7.
- the wall openings 20 can also be designed for the gasification medium to flow out at a different angle.
- biomass can be converted into coal and synthesis gas in a particularly simple and robust manner by supplying electrical energy, whereby, for example, sawmills can inexpensively convert waste wood chips into coal and synthesis gas and utilize them for energy purposes.
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Abstract
Description
Reaktor zur Erzeugung von Kohle und Synthesegas aus Biomasse Reactor for producing coal and synthesis gas from biomass
Die Erfindung betrifft einen Reaktor zur Erzeugung von Kohle und Synthesegas aus Biomasse, aufweisend einen durch eine Arbeitsraumwandung seitlich begrenzten Arbeitsraum, einen Einlass, durch welchen die Biomasse in den Arbeitsraum einbringbar ist, sowie einen Auslass, durch welchen Kohle und Synthesegas aus dem Arbeitsraum ausgetragen werden können, wobei Biomasse entlang eines Transportweges vom Einlass zum Auslass durch den Arbeitsraum bewegbar ist. The invention relates to a reactor for producing coal and synthesis gas from biomass, comprising a working chamber laterally delimited by a working chamber wall, an inlet through which the biomass can be introduced into the working chamber, and an outlet through which coal and synthesis gas can be discharged from the working chamber, wherein biomass can be moved along a transport path from the inlet to the outlet through the working chamber.
Weiter betrifft die Erfindung ein Verfahren zur Erzeugung von Kohle und Synthesegas aus Biomasse. The invention further relates to a process for producing coal and synthesis gas from biomass.
Reaktoren der eingangs genannten Art sind zur Erzeugung von Kohle und Synthesegas aus Biomasse aus dem Stand der Technik bereits bekannt. Bei Vorrichtungen und Verfahren des Standes der Technik wird in aller Regel Biomasse unterstöchiometrisch verbrannt, um Holzkohle und Synthesegas zu bilden. Reactors of the type mentioned above are already known from the state of the art for producing coal and syngas from biomass. In state-of-the-art devices and processes, biomass is generally burned substoichiometrically to produce charcoal and syngas.
Darüber hinaus sind Vorrichtungen bekannt geworden, wobei Biomasse mittels Sonnenenergie erhitzt wird, um eine für eine chemische Reaktion erforderliche Temperatur zu erreichen. In addition, devices have become known in which biomass is heated using solar energy to reach a temperature required for a chemical reaction.
Nachteilig bei derartigen Verfahren ist, dass nur eine geringe Ausbeute erreicht wird, zumal ein Teil der Biomasse für die Erreichung der entsprechenden Temperatur verbrannt werden muss oder eine Heizleistung abhängig von einer Sonneneinstrahlung und damit nicht stabil verfügbar ist. The disadvantage of such processes is that only a low yield is achieved, especially since part of the biomass has to be burned to reach the corresponding temperature or heating power is dependent on solar radiation and is therefore not available in a stable manner.
Hier setzt die Erfindung an. Aufgabe der Erfindung ist es, einen Reaktor und ein Verfahren der eingangs genannten Art anzugeben, mit welchen eine Umwandlung von Biomasse in Kohle und Synthesegas mit besonders hoher Ausbeute möglich ist. This is where the invention comes in. The object of the invention is to provide a reactor and a process of the type mentioned above, with which the conversion of biomass into coal and synthesis gas is possible with a particularly high yield.
Die erste Aufgabe wird erfindungsgemäß mit einem Reaktor der eingangs genannten Art gelöst, bei welchem ein elektrisch leitfähiges Element im Arbeitsraum und/oder in der Arbeitsraumwandung vorgesehen ist, wobei das elektrisch leitfähige Element elektrisch, vorzugsweise induktiv, insbesondere durch eine Induktionsspule, erhitzbar ist, um eine Umwandlung von im Arbeitsraum befindlicher Biomasse in Synthesegas und Kohle zu bewirken. The first object is achieved according to the invention with a reactor of the type mentioned at the outset, in which an electrically conductive element is provided in the working chamber and/or in the working chamber wall, wherein the electrically conductive element can be heated electrically, preferably inductively, in particular by an induction coil, in order to To convert biomass in the working space into synthesis gas and coal.
Im Rahmen der Erfindung wurde erkannt, dass zur Umwandlung von Biomasse in Kohle und Synthesegas auch elektrische Energie auf besonders effiziente Weise genutzt werden kann, wenn eine Erhitzung der Biomasse im Arbeitsraum auf elektrische, insbesondere auf induktive, Weise erfolgt. So kann mittels einer Regelung einer Leistung einer Stromquelle oder einer Induktionsspule, mit welcher das elektrisch leitfähige Element beispielsweise erhitzbar ist, besonders rasch auf geänderte Bedingungen im Arbeitsraum reagiert werden, welche sich beispielsweise durch eine andere Zusammensetzung der Biomasse ergeben. Darüber hinaus ermöglicht es das mit dem erfindungsgemäßen Reaktor umsetzbare Verfahren, elektrische Energie, welche insbesondere dann sehr günstig verfügbar ist, wenn Sonneneinstrahlung oder Windaufkommen hoch sind, zu nutzen, um Biomasse, welche aufgrund eines großen Volumens nur schwer transportierbar ist, in leichter transportierbare Energieträger wie Kohle und Synthesegas umzuwandeln, sodass das Verfahren zur Umwandlung von elektrischer und in Biomasse gespeicherter Energie in Kohle und Synthesegas geeignet ist. Das elektrisch leitfähige Element kann sowohl im Arbeitsraum als auch in der Arbeitsraumwandung angeordnet sein, um im Arbeitsraum befindliche Biomasse zu erhitzen. Within the scope of the invention, it was recognized that electrical energy can also be used particularly efficiently to convert biomass into coal and synthesis gas if the biomass is heated electrically, in particular inductively, in the working chamber. Thus, by regulating the power of a power source or an induction coil, with which the electrically conductive element can be heated, for example, it is possible to react particularly quickly to changing conditions in the working chamber, which may arise, for example, from a different composition of the biomass. Furthermore, the process implementable with the reactor according to the invention makes it possible to use electrical energy, which is particularly inexpensive when solar radiation or wind speeds are high, to convert biomass, which is difficult to transport due to its large volume, into more easily transportable energy sources such as coal and synthesis gas. Thus, the process is suitable for converting electrical energy and energy stored in biomass into coal and synthesis gas. The electrically conductive element can be arranged both in the working chamber and in the working chamber wall in order to heat biomass located in the working chamber.
Die mit einem erfindungsgemäßen Reaktor und einem erfindungsgemäßen Verfahren hergestellte Kohle weist neben brennbarem Material natürlich auch Asche auf. Je nach Vergasungsgrad kann der Ascheanteil der Kohle auch auf beispielsweise bis zu 90 % oder mehr ansteigen, sodass der Kohlenstoffanteil nur mehr sehr gering ist. Als Kohle wird somit im Rahmen dieser Anmeldung nicht nur brennbares Material verstanden, sondern auch ein im Feststoff enthaltener Ascheanteil. The coal produced with a reactor according to the invention and a process according to the invention naturally contains ash in addition to combustible material. Depending on the degree of gasification, the ash content of the coal can increase to, for example, 90% or more, so that the carbon content is very low. Thus, in the context of this application, coal is understood not only to mean combustible material, but also the ash content contained in the solid.
Das elektrisch leitfähige Element kann beispielsweise als dünner Heizdraht ausgebildet sein, welcher sowohl als Heizwiderstand einer Widerstandsheizung als auch als Element, welches durch eine zusätzliche Induktionsspule induktiv erwärmt wird, wirken kann. Das Element kann jedoch beispielsweise auch als platten- oder zylinderförmiges Element aus Graphit oder dergleichen ausgebildet sein. Bei dem mit dem erfindungsgemäßen Reaktor umsetzbaren Verfahren wird somit üblicherweise Kohle und Synthesegas gemeinsam am Auslass aus dem Arbeitsraum bewegt, weswegen der Reaktor als induktiv betriebener allothermen Gleichstromvergaser wirkt. The electrically conductive element can, for example, be designed as a thin heating wire, which can act both as a heating resistor of a resistance heater and as an element that is inductively heated by an additional induction coil. However, the element can also be designed, for example, as a plate- or cylinder-shaped element made of graphite or the like. In the process that can be implemented with the reactor according to the invention, coal and synthesis gas are usually moved together at the outlet from the working chamber, which is why the reactor acts as an inductively operated allothermal cocurrent gasifier.
Bevorzugt ist vorgesehen, dass bei dem Reaktor auch eine Induktionsspule vorgesehen ist, durch welche das elektrisch leitfähige Element erhitzbar ist. Die Induktionsspule kann außenseitig an der Arbeitsraumwandung oder auch im Arbeitsraum, insbesondere an einem im Arbeitsraum angeordneten Dorn angeordnet sein. Preferably, the reactor also includes an induction coil, which can heat the electrically conductive element. The induction coil can be arranged on the outside of the working chamber wall or within the working chamber, in particular on a mandrel arranged within the working chamber.
Es hat sich bewährt, dass die Arbeitsraumwandung Wandöffnungen aufweist, durch welche ein Vergasungsmedium, insbesondere Wasserdampf, in den Arbeitsraum einbringbar ist, wobei die Öffnungen insbesondere derart im Arbeitsraum angeordnet sind, dass eine Ausströmrichtung des Vergasungsmediums etwa parallel zur Transportrichtung ist. Dies ermöglicht eine besonders gleichmäßige Verteilung des Vergasungsmedium im Arbeitsraum bzw. in der Biomasse. It has proven effective for the working chamber wall to have openings through which a gasification medium, in particular steam, can be introduced into the working chamber. The openings are arranged in the working chamber in such a way that the outflow direction of the gasification medium is approximately parallel to the transport direction. This enables a particularly uniform distribution of the gasification medium in the working chamber and in the biomass.
Günstig ist es, wenn ein Öffnungen aufweisender Dorn im Arbeitsraum angeordnet ist, vorzugsweise etwa mittig, durch welchen Dorn ein Vergasungsmedium, insbesondere Wasserdampf oder Kohlendioxid in den Arbeitsraum einbringbar ist. Somit kann auf besonders einfache Weise durch Änderung eines Volumenstromes des Vergasungsmediums und Anpassung einer Temperatur im Arbeitsraum variabel ein Anteil der Biomasse eingestellt werden, welcher den Reaktor in Form von Kohle oder in Form von Synthesegas verlässt. Beispielsweise kann somit abhängig von Marktpreisen und/oder Transportkapazitäten eine Funktionsweise des Reaktors derart über Temperatur im Arbeitsraum und/oder Massenstrom des Vergasungsmediums über den Dorn gesteuert werden, dass 100 % Synthesegas, 100 % Kohle oder ein Kombinationsprodukt aus Synthesegas und Kohle mit beliebigen Anteilen an Synthesegas und Kohle erhalten wird. It is advantageous if a mandrel having openings is arranged in the working chamber, preferably approximately centrally, through which mandrel a gasification medium, in particular water vapor or carbon dioxide, can be introduced into the working chamber. In this way, a proportion of the biomass leaving the reactor in the form of coal or in the form of synthesis gas can be variably adjusted in a particularly simple manner by changing a volume flow of the gasification medium and adjusting a temperature in the working chamber. For example, depending on market prices and/or transport capacities, the operation of the reactor can be controlled via the temperature in the working chamber and/or the mass flow of the gasification medium via the mandrel in such a way that 100% synthesis gas, 100% coal, or a combination product of synthesis gas and coal with any proportions of synthesis gas and coal is obtained.
Bevorzugt ist vorgesehen, dass der Dorn parallel zum Transportweg orientiert ist, insbesondere entlang einer direkten Verbindung von Einlass zu Auslass. Der Arbeitsraum ist üblicherweise etwa rotationssymmetrisch zu einer Mittelachse angeordnet, insbesondere etwa zylindrisch oder kegelförmig ausgebildet, entlang welcher Mittelachse der Dorn bevorzugt angeordnet ist, um eine möglichst gleichmäßige Eindringung von Vergasungsmedium in den Arbeitsraum zu ermöglichen. Der Dorn ist üblicherweise länglich, vorzugsweise als endseitig abgeschlossenes Rohr mit einem Durchmesser von beispielsweise weniger als 10 cm ausgebildet und weist mehrere Öffnungen auf, um einerseits eine Bewegung der Biomasse im Arbeitsraum möglichst nicht zu behindern und gleichzeitig eine möglichst gleichmäßige Verteilung des Vergasungsmediums im Arbeitsraum und in der Biomasse zu ermöglichen. Preferably, the mandrel is oriented parallel to the transport path, in particular along a direct connection from inlet to outlet. The working space is usually arranged approximately rotationally symmetrically to a central axis, in particular approximately cylindrical or conical, along which central axis the mandrel is preferably arranged in order to ensure the most uniform possible penetration of To allow the gasification medium to enter the working chamber. The mandrel is typically elongated, preferably designed as a tube with a closed end and a diameter of, for example, less than 10 cm, and has several openings to minimize the movement of the biomass in the working chamber and simultaneously enable the most even distribution of the gasification medium in the working chamber and in the biomass.
Es können natürlich auch mehrere Dorne mit Öffnungen vorgesehen sein, beispielsweise vier Dorne, welche mit gleichen oder unterschiedlichen Vergasungsmedien beaufschlagt werden. Weiter können Volumenströme über die einzelnen Dorne gleich oder unterschiedlich sein. Wenn mehrere Dorne vorgesehen sind, können diese in Längsrichtung des Arbeitsraumes, in Umfangsrichtung und/oder Radialrichtung über den Arbeitsraum verteilt angeordnet sein, um chemische Prozesse im Arbeitsraum besonders genau steuern und beispielsweise unterschiedlichen Positionen im Arbeitsraum unterschiedliche Vergasungsmedien und/oder Vergasungsmedien mit unterschiedlichen Volumenströmen zuführen zu können. Of course, multiple mandrels with openings can also be provided, for example, four mandrels, which are supplied with the same or different gasification media. Furthermore, the volume flows across the individual mandrels can be the same or different. If multiple mandrels are provided, they can be distributed longitudinally within the working chamber, circumferentially, and/or radially throughout the working chamber to control chemical processes in the working chamber with particular precision and, for example, to supply different gasification media and/or gasification media with different volume flows to different positions within the working chamber.
Es kann vorgesehen sein, dass der Arbeitsraum mit einem vom Einlass zum Auslass zumindest bereichsweise zunehmenden Querschnitt ausgebildet sein, insbesondere etwa konisch. Dies gewährleistet, dass für eine Bewegung der Biomasse im Arbeitsraum vom Einlass zum Auslass nur eine geringe Energie erforderlich ist und ein Verstopfen des Arbeitsraumes vermieden wird. Der Arbeitsraum kann hierzu beispielsweise durch zylindrische Abschnitte mit zunehmenden Querschnitten, sodass sich ein oder mehrere Durchmessersprünge ergeben, oder einem kontinuierlich zunehmenden Querschnitt, beispielsweise in Form eines Kegelstumpfes, ausgebildet sein. It can be provided that the working chamber is designed with a cross-section that increases at least in some areas from the inlet to the outlet, in particular, for example, conical. This ensures that only minimal energy is required to move the biomass in the working chamber from the inlet to the outlet, and blockage of the working chamber is avoided. For this purpose, the working chamber can be designed, for example, by cylindrical sections with increasing cross-sections, resulting in one or more diameter jumps, or with a continuously increasing cross-section, for example, in the shape of a truncated cone.
Günstig ist es, wenn der Dorn etwa zylinderförmig ausgebildet ist. Dies ermöglichst eine gleichmäßige Einbringung von Vergasungsmedium in den Arbeitsraum, insbesondere über radial und axial entlang des Dornes verteilte Öffnungen. Eine Längsachse des Dornes bzw. eine Zylinderachse ist vorzugsweise koaxial mit einer Achse des Arbeitsraumes, welcher eine Zylinder- oder Kegelform aufweisen kann. It is advantageous if the mandrel is approximately cylindrical. This allows for a uniform introduction of gasification medium into the working chamber, particularly via openings distributed radially and axially along the mandrel. A longitudinal axis of the mandrel or a cylinder axis is preferably coaxial with an axis of the working chamber, which can be cylindrical or conical.
Es hat sich bewährt, dass der Dorn aus einem elektrisch leitfähigen Material ausgebildet ist oder ein elektrisch leitfähiges Material aufweist. Die Induktionsspule, welche üblicherweise den Arbeitsraum umschließend und mit einer Mittelachse, welche einer Mittelachse des Arbeitsraumes entspricht, angeordnet ist, bewirkt somit insbesondere auch eine Erhitzung des Dornes, wodurch der Dorn einerseits zur Abgabe eines Vergasungsmediums und andererseits zum Erhitzen der Biomasse eingesetzt werden kann. It has proven useful that the mandrel is made of an electrically conductive material or has an electrically conductive material. The induction coil, which usually enclosing the working space and arranged with a central axis which corresponds to a central axis of the working space, thus also causes the mandrel to be heated, whereby the mandrel can be used on the one hand to release a gasification medium and on the other hand to heat the biomass.
Bevorzugt ist vorgesehen, dass der Arbeitsraum einen im wesentlichen rotationssymmetrischen Querschnitt aufweist. Die Arbeitsraumwandung ist üblicherweise als Zylindermantelfläche oder Kegelmantelfläche ausgebildet. Eine Rotationsachse des Arbeitsraumes ist üblicherweise koaxial mit einer Längsachse des Dornes, um eine sehr gleichmäßige Verteilung des Vergasungsmediums im Arbeitsraum zu gewährleisten. Besonders bevorzugt ist vorgesehen, dass die Rotationsachse auch mit einer Spulenachse der Induktionsspule koaxial ist. Preferably, the working chamber has a substantially rotationally symmetrical cross-section. The working chamber wall is typically designed as a cylindrical or conical surface. A rotational axis of the working chamber is typically coaxial with a longitudinal axis of the mandrel to ensure a very uniform distribution of the gasification medium in the working chamber. Particularly preferably, the rotational axis is also coaxial with a coil axis of the induction coil.
Es hat sich bewährt, dass die Arbeitsraumwandung aus einem elektrisch nicht leitfähigen Material, insbesondere Glas oder Keramik, besteht. Das Material der Arbeitsraumwandung erlaubt es dann, dass ein von der Induktionsspule, welche üblicherweise außenseitig um die Arbeitsraumwandung angeordnet ist, erzeugtes elektromagnetisches Feld durch die Arbeitsraumwandung hindurch in den Arbeitsraum wirkt, in welchem eine oder mehrere elektrisch leitfähige Elemente angeordnet sind, welche durch die Induktionsspule erhitzt werden, um die Biomasse auf eine Temperatur zu bringen, bei welcher die chemische Reaktion zur Umwandlung in Kohle und Synthesegas eingeleitet wird. Gleichzeitig sind Glas und Keramik auch dazu geeignet, entsprechend hohen Temperaturen dauerhaft zu widerstehen, sodass diese Materialien besonders gut geeignet zur Bildung der Arbeitsraumwand sind. Üblicherweise wird der Reaktor bei einer Temperatur von etwa 1100 Grad Celsius im Arbeitsraum betrieben. It has proven useful for the working chamber wall to be made of an electrically non-conductive material, particularly glass or ceramic. The material of the working chamber wall then allows an electromagnetic field generated by the induction coil, which is usually arranged on the outside around the working chamber wall, to act through the working chamber wall into the working chamber, in which one or more electrically conductive elements are arranged. These elements are heated by the induction coil in order to bring the biomass to a temperature at which the chemical reaction for conversion into coal and synthesis gas is initiated. At the same time, glass and ceramic are also suitable for permanently withstanding correspondingly high temperatures, making these materials particularly well suited for forming the working chamber wall. The reactor is usually operated at a temperature of around 1100 degrees Celsius in the working chamber.
Die Arbeitsraumwandung kann jedoch teilweise oder vollständig auch aus einem elektrisch leitfähigen Material wie einem Metall, insbesondere Stahl, bestehen. Üblicherweise wird die Arbeitsraumwandung aus einem hochtemperaturbeständigen Material gebildet, insbesondere Glas, Keramik oder Stahl. Wenn die Arbeitsraumwandung aus einem elektrisch leitfähigen Material besteht, kann die Arbeitsraumwandung selbst als Heizelement dienen. Es kann somit vorgesehen sein, dass die Arbeitsraumwandung zumindest teilweise aus einem elektrisch leitfähigen Material besteht und somit als Heizelement wirkt. However, the work chamber wall may also be partially or completely made of an electrically conductive material such as a metal, in particular steel. Typically, the work chamber wall is made of a high-temperature-resistant material, in particular glass, ceramic, or steel. If the work chamber wall is made of an electrically conductive material, the work chamber wall itself can serve as a heating element. It may thus be provided that the work chamber wall consists at least partially of an electrically conductive material and thus acts as a heating element.
Es hat sich bewährt, dass an der Arbeitsraumwandung innenseitig gelegte elektrisch leitfähige Elemente und/oder eine elektrisch leitfähige Beschichtung angeordnet sind. Dies ermöglicht eine besonders gleichmäßige Erwärmung des Arbeitsraumes. Die elektrisch leitfähigen Elemente können insbesondere aus Graphit bestehen, welcher hohen Temperaturen gut widerstehen kann. It has proven effective to install electrically conductive elements and/or an electrically conductive coating on the inside of the work chamber wall. This allows for particularly uniform heating of the work chamber. The electrically conductive elements can be made of graphite, which can withstand high temperatures well.
Es kann vorgesehen sein, dass die Arbeitsraumwandung außenseitig elektrisch leitfähige Heizelemente aufweist, welche vorzugsweise aus Graphit bestehen. Dadurch werden auf besonders günstige Weise hohe Temperaturen im Arbeitsraum erreicht. The work chamber wall may be provided with electrically conductive heating elements on the outside, preferably made of graphite. This allows high temperatures in the work chamber to be achieved in a particularly favorable manner.
Bevorzugt ist vorgesehen, dass eine die Arbeitsraumwandung zumindest bereichsweise umschließende Isolierung vorgesehen ist. Durch die Isolierung kann gewährleistet werden, dass eine mittels der Induktionsspule in den elektrisch leitfähigen Elementen bewirkte Erwärmung im Wesentlichen zu einer Erhitzung der Biomasse im Arbeitsraum führt und die Wärmeenergie nicht oder zumindest nur im geringen Ausmaß an eine Umgebung abgegeben wird. Günstig ist es, wenn die Isolierung unmittelbar an außenseitig an der Arbeitsraumwandung angeordneten Heizelementen angeordnet ist. Preferably, insulation is provided that surrounds the work chamber wall at least in part. This insulation ensures that heating caused by the induction coil in the electrically conductive elements essentially leads to heating of the biomass in the work chamber, and that the thermal energy is not released into the environment, or at least only to a small extent. It is advantageous if the insulation is arranged directly on heating elements arranged on the outside of the work chamber wall.
Bevorzugt ist vorgesehen, dass die Isolierung zumindest teilweise aus einem elektrisch nicht leitfähigen Material besteht. Dies gewährleistet, dass die Isolierung selbst nicht durch ein mittels der Induktionsspule erzeugtes Elektromagnetisches Feld erhitzt wird. Preferably, the insulation is at least partially made of an electrically non-conductive material. This ensures that the insulation itself is not heated by an electromagnetic field generated by the induction coil.
Mit Vorteil ist vorgesehen, dass die Isolierung zumindest teilweise durch ein Gas gebildet ist. Alternativ kann die Isolierung auch durch ein Vakuum gebildet sein, sodass die außenseitig an der Arbeitsraumwandung angeordneten Heizelemente durch ein Gas oder ein Vakuum von einer Umgebung getrennt sind, wodurch eine Wärmeübertragung von den Heizelementen an eine Umgebung stark gehemmt ist. Advantageously, the insulation is formed at least partially by a gas. Alternatively, the insulation can also be formed by a vacuum, so that the heating elements arranged on the outside of the work chamber wall are separated from the surroundings by a gas or a vacuum, thereby significantly inhibiting heat transfer from the heating elements to the surroundings.
Es hat sich bewährt, dass die Isolierung eine wärmereflektierende Schicht aufweist, die selbst nicht durch Induktion erhitzt wird. Dadurch wird eine Abstrahlung von Wärmeenergie nach außen vermieden bzw. minimiert. Günstig ist es, wenn innenseitig an der Arbeitsraumwandung eine chemisch beständige Beschichtung, insbesondere eine asche- und schlackeabweisende Schutzschicht angeordnet ist. Auf diese Weise werden insbesondere Anbackungen innenseitig an der Arbeitsraumwandung vermieden, welche zu einem erhöhten Widerstand gegen eine Bewegung der Biomasse vom Einlass zum Auslass führen. Es kann auch vorgesehen sein, dass ein Grundmaterial der Arbeitsraumwandung chemisch besonders beständig ausgebildet ist. It has proven effective to incorporate a heat-reflecting layer into the insulation, which is not itself heated by induction. This prevents or minimizes the radiation of heat energy to the outside. It is advantageous to apply a chemically resistant coating, particularly an ash and slag-repellent protective layer, to the inside of the working chamber wall. This prevents, in particular, caking on the inside of the working chamber wall, which leads to increased resistance to the movement of biomass from the inlet to the outlet. It can also be provided that a base material for the working chamber wall is particularly chemically resistant.
Günstig ist es, wenn ein Fördermechanismus vorgesehen ist, durch welchen Biomasse vom Einlass durch den Arbeitsraum zum Auslass förderbar ist. It is advantageous if a conveying mechanism is provided by which biomass can be conveyed from the inlet through the working chamber to the outlet.
Der Fördermechanismus kann auf verschiedenste Weisen ausgebildet sein, beispielsweise als Transportschnecke. Es hat sich in dem Zusammenhang bewährt, dass der Fördermechanismus einen verfahrbaren Kolben aufweist, durch welchen im Arbeitsraum befindliche Biomasse entlang des Transportweges bewegbar ist, wobei der Kolben insbesondere parallel zur Transportrichtung bewegbar ist. The conveying mechanism can be designed in a variety of ways, for example, as a conveyor screw. In this context, it has proven effective for the conveying mechanism to have a movable piston, by means of which the biomass located in the working chamber can be moved along the transport path, with the piston being movable, in particular, parallel to the transport direction.
Um eine Zuführung der Biomasse auf robuste und gleichzeitig konstruktiv einfache Weise umzusetzen, hat es sich bewährt, dass eine Biomasse-Zuführung vorgesehen ist, durch welche Biomasse in einem dem Einlass vorgelagerten Bereich zuführbar ist, insbesondere entlang einer Zuführrichtung, welche quer zur Transportrichtung, insbesondere normal zur Transportrichtung, ist. Der vorgelagerte Bereich kann insbesondere ein Bereich sein, welchen der Kolben bei einem Hub durchfährt, sodass quer zur Transportrichtung in diesen vorgelagerten Bereich eingebrachte Biomasse durch den Kolben bei einem Hub in den Arbeitsraum eingepresst wird. In order to implement biomass feeding in a robust yet structurally simple manner, it has proven effective to provide a biomass feed through which biomass can be fed into a region upstream of the inlet, in particular along a feed direction that is transverse to the transport direction, in particular perpendicular to the transport direction. The upstream region can, in particular, be a region through which the piston moves during one stroke, so that biomass introduced into this upstream region transverse to the transport direction is pressed into the working chamber by the piston during one stroke.
Um Biomasse kontrolliert aus dem Arbeitsraum auszufördern, ist bevorzugt am Auslass eine Ausfördereinrichtung, insbesondere eine Förderschnecke oder ein Kolben, vorgesehen, mittels welcher Kohle aus dem Arbeitsraum in einen mit dem Auslass verbundenen Kohlebehälter förderbar ist. Die Förderschnecke kann endseitig eine Platte mit Öffnungen aufweisen, wobei die Biomasse durch die Öffnungen in die Förderschnecke eindringen kann. Gleichzeitig bildet die Platte ausreichend Widerstand, sodass ein gewünschter Druck in der Biomasse im Arbeitsraum aufrechterhalten werden kann, welcher Druck für eine Erreichung der chemischen Prozesse zur Bildung von Kohle und Synthesegas vorteilhaft ist. In order to discharge biomass from the working chamber in a controlled manner, a discharge device, in particular a screw conveyor or a piston, is preferably provided at the outlet, by means of which coal can be conveyed from the working chamber into a coal container connected to the outlet. The screw conveyor can have a plate with openings at its end, whereby the biomass can penetrate through the openings into the screw conveyor. At the same time, the plate provides sufficient resistance so that a desired pressure can be maintained in the biomass in the working chamber. can determine which pressure is advantageous for achieving the chemical processes for the formation of coal and synthesis gas.
Günstig ist es, wenn ein Fördermechanismus, welcher insbesondere einen Kolben aufweist, und eine Ausfördereinrichtung, welche insbesondere eine Förderschnecke mit einer Endplatte aufweist, vorgesehen sind, welche parallel zur Transportrichtung bewegbar sind, wobei eine Steuerung vorgesehen ist, mittels welcher der Fördermechanismus und die Ausfördereinrichtung parallel verfahrbar sind. Der Fördermechanismus und die Ausfördereinrichtung führen somit parallele, also gleichzeitige und üblicherweise gleichsinnige Hubbewegungen in bzw. entgegen der Transportrichtung aus, wodurch ein stetes Nachfördern von Biomasse in den Arbeitsraum und Ausfördern von Kohle aus dem Arbeitsraum bei möglichst gleichmäßigem Druck im Arbeitsraum ermöglichst ist. It is advantageous if a conveying mechanism, which in particular has a piston, and a discharge device, which in particular has a conveyor screw with an end plate, are provided, which are movable parallel to the transport direction, wherein a control is provided by means of which the conveying mechanism and the discharge device can be moved in parallel. The conveying mechanism and the discharge device thus perform parallel, i.e. simultaneous and usually co-directional lifting movements in or against the transport direction, thereby enabling a continuous feeding of biomass into the working chamber and discharge of coal from the working chamber with the most uniform pressure possible in the working chamber.
Bevorzugt ist vorgesehen, dass die Ausfördereinrichtung eine Lagerung für einen im Arbeitsraum angeordneten Dorn aufweist, wobei der Dorn bevorzugt zwischen Einlass und Auslass nicht im Arbeitsraum gelagert ist. Diese Lagerung kann beispielsweise durch ein mittig in der endseitigen Platte der Förderschnecke angeordnetes Wälz- oder Gleitlager gebildet sein, in welchem der durch beispielsweise ein Rohr gebildete Dorn gelagert ist. Es hat sich gezeigt, dass eine zusätzliche Lagerung des Dornes im Arbeitsraum ein Risiko birgt, dass Biomasse an Stützen einer solchen Lagerstelle hängen bleibt und einen Transport im Arbeitsraum blockiert, welches Risiko bei einer ausschließlich endseitigen Lagerung des Dornes vermieden wird. Preferably, the discharge device comprises a bearing for a mandrel arranged in the working chamber, wherein the mandrel is preferably not mounted in the working chamber between the inlet and outlet. This bearing can be formed, for example, by a roller or plain bearing arranged centrally in the end plate of the conveyor screw, in which the mandrel, formed by, for example, a tube, is mounted. It has been shown that additional bearing of the mandrel in the working chamber entails a risk of biomass becoming caught on supports of such a bearing point and blocking transport within the working chamber. This risk is avoided by exclusively bearing the mandrel at the end.
Bevorzugt ist vorgesehen, dass ein mit dem Arbeitsraum verbundener Gasauslass vorgesehen ist, durch welchen im Arbeitsraum erzeugtes Synthesegas entnehmbar ist. Das Synthesegas kann beispielsweise in eine Pipeline eingespeist oder in Behältern abgefüllt werden, um das Synthesegas in weiterer Folge einer weiteren Verwendung zuzuführen. Preferably, a gas outlet is provided connected to the working chamber, through which synthesis gas generated in the working chamber can be extracted. The synthesis gas can, for example, be fed into a pipeline or filled into containers for subsequent use.
Es hat sich bewährt, dass elektrisch leitfähige Zusatzstoffe vorgesehen sind, welche mit der Biomasse durch den Arbeitsraum förderbar und durch die Induktionsvorrichtung erhitzbar sind. Dies können beispielsweise Kugeln aus Graphit oder dergleichen sein, welche somit im Arbeitsraum erhitzt werden, um die Biomasse möglichst gleichmäßig zu erhitzen. Diese Zusatzstoffe verlassen den Arbeitsraum gemeinsam mit der Kohle und können leicht von der Kohle getrennt und wieder verwendet werden. It has proven useful to provide electrically conductive additives that can be conveyed through the working chamber with the biomass and heated by the induction device. These can be, for example, graphite balls or similar, which are heated in the working chamber to distribute the biomass as evenly as possible. These additives leave the work area together with the coal and can be easily separated from the coal and reused.
Günstig ist es, wenn zumindest zwei Induktionsspulen vorgesehen sind, um unterschiedliche Bereiche des Arbeitsraumes unterschiedlich stark erhitzen zu können. It is advantageous if at least two induction coils are provided in order to be able to heat different areas of the work space to different degrees.
Es kann vorgesehen sein, dass die Induktionsspule entlang einer axialen Erstreckung des Arbeitsraumes unterschiedliche Steigungen aufweist. Durch die unterschiedlichen Steigungen kann bei gleicher Stromstärke eine unterschiedliche Leistungsdichte bewirkt werden, welche durch die Induktionsspule in den Arbeitsraum eingebracht wird, um unterschiedliche Bereiche im Arbeitsraum unterschiedlich stark erhitzen zu können.The induction coil can be provided with different pitches along an axial extension of the working chamber. These different pitches can result in different power densities at the same current intensity, which are introduced into the working chamber by the induction coil, allowing different areas within the working chamber to be heated to different degrees.
Natürlich können auch mehrere Induktionsspulen vorgesehen sein, welche unterschiedliche Steigungen aufweisen, um einen Energieeintrag in einzelne Bereiche des Arbeitsraumes besonders genau steuern zu können. Of course, several induction coils can also be provided, which have different gradients in order to be able to control the energy input into individual areas of the work space with particular precision.
Günstig ist es, wenn ein oder mehrere Temperatursensoren im Arbeitsraum vorgesehen sind, wobei eine Regelung vorgesehen ist, um mittels der Induktionsspule eine vordefinierte Temperatur im Arbeitsraum zu erreichen. Die unterschiedlichen Temperatursensoren können entlang einer axialen Erstreckung des Arbeitsraumes und/oder über einen Umfang des Arbeitsraumes verteilt im Arbeitsraum angeordnet sein, um die chemischen Prozesse im Arbeitsraum besonders gut steuern zu können. So kann beispielsweise vorgesehen sein, dass die Induktionsspule auf eine gewünschte Solltemperatur im Arbeitsraum, beispielsweise 1.100 °C hin geregelt bzw. ein Strom der Induktionsspule erhöht bzw. reduziert wird, bis die gewünschte Temperatur erreicht ist. It is advantageous if one or more temperature sensors are provided in the work chamber, with a control system provided to achieve a predefined temperature in the work chamber using the induction coil. The various temperature sensors can be arranged along an axial extent of the work chamber and/or distributed over a circumference of the work chamber in order to be able to control the chemical processes in the work chamber particularly well. For example, it can be provided that the induction coil is controlled to a desired target temperature in the work chamber, for example, 1,100 °C, or that the current of the induction coil is increased or decreased until the desired temperature is reached.
Bevorzugt ist vorgesehen, dass die Arbeitsraumwandung innenseitig oberflächlich behandelt und/oder beschichtet ist, insbesondere um eine verbesserte Verschleißresistenz und/oder eine niedrige Rauheit, vorzugsweise eine Rauheit mit einem Mittenrauwert Ra von weniger als 0,5 pm, zu erreichen. It is preferably provided that the working space wall is surface-treated and/or coated on the inside, in particular in order to achieve improved wear resistance and/or low roughness, preferably a roughness with a mean roughness value Ra of less than 0.5 pm.
Es hat sich bewährt, dass am Einlass und/oder am Auslass ein Schleusensystem vorgesehen ist, durch welches Schleusensystem ein Eindringen von Umgebungsluft in den Arbeitsraum und ein Austreten von Produktgas in eine Umgebung reduziert sind. Das Schleusensystem kann beispielsweise eine erste gasdichte Schleuse aufweisen, durch welche Biomasse bzw. Kohle und Synthesegas in einen Schleusenraum gelangen kann, von welchem Schleusenraum Biomasse bzw. Kohle und Synthesegas anschließend über eine zweite gasdichte Schleuse in den Arbeitsraum bzw. eine Umgebung bewegt werden kann. Bevorzugt werden beide Schleusen nicht gleichzeitig, sondern nur sequenziell geöffnet, sodass nie eine direkte Verbindung zwischen Arbeitsraum und Umgebung besteht. It has proven useful to provide a lock system at the inlet and/or outlet, which lock system reduces the penetration of ambient air into the working space and the escape of product gas into the environment. The lock system can, for example, comprise a first gas-tight lock, through which Which biomass, coal, and synthesis gas can enter one lock chamber, and from which lock chamber the biomass, coal, and synthesis gas can then be moved through a second gas-tight lock into the work chamber or surrounding area. Preferably, both locks are opened sequentially, rather than simultaneously, so that there is never a direct connection between the work chamber and the surrounding area.
Günstig ist es zur Erreichung eines besonders reinen Gases, wenn der Arbeitsraum gasdicht gegenüber einer Umgebung abgedichtet ist. Dies kann beispielsweise über ein Schleusensystem am Einlass und am Auslass erfolgen, sodass nur Systemmedien wie Biomasse, Vergasungsmittel und Synthesegase bzw. Produktgas in den Arbeitsraum eindringen können. To achieve particularly pure gas, it is advantageous if the working chamber is gas-tight from the surrounding environment. This can be achieved, for example, by means of a lock system at the inlet and outlet, so that only system media such as biomass, gasification agents, and synthesis gases or product gas can enter the working chamber.
Die weitere Aufgabe wird durch ein Verfahren zur Erzeugung von Kohle und Synthesegas aus Biomasse der eingangs genannten Art gelöst, wobei die Biomasse in einem Reaktor in einem Arbeitsraum, insbesondere in einem erfindungsgemäßen Reaktor, elektrisch, insbesondere durch eine Induktionsspule, erhitzt wird. Dies ermöglicht ein besonders genaues Kontrollieren einer Temperatur im Arbeitsraum sowie die Nutzung elektrischer Überschussenergie zur Erzeugung von Kohle bzw. Synthesegas aus Biomasse, insbesondere an windstarken Tagen oder an Tagen mit hoher Sonneneinstrahlung. The further object is achieved by a method for producing coal and synthesis gas from biomass of the type mentioned above, wherein the biomass is heated electrically, in particular by an induction coil, in a reactor in a working chamber, in particular in a reactor according to the invention. This enables particularly precise control of the temperature in the working chamber and the use of excess electrical energy to produce coal or synthesis gas from biomass, particularly on windy days or days with high solar radiation.
Günstig ist es, wenn der Biomasse vor einer Einbringung in den Arbeitsraum elektrisch leitfähige Zusatzstoffe zugesetzt werden, welche insbesondere eine Kugelform aufweisen, wobei die Zusatzstoffe im Arbeitsraum induktiv erhitzt werden, um die Biomasse mittels der induktiv erhitzten Zusatzstoffe zu erhitzen. It is advantageous if electrically conductive additives, which in particular have a spherical shape, are added to the biomass before it is introduced into the working chamber, wherein the additives are inductively heated in the working chamber in order to heat the biomass by means of the inductively heated additives.
Weitere Vorteile, Merkmale, Vorteile und Wirkungen der Erfindung ergeben sich anhand des nachfolgend dargestellten Ausführungsbeispiels. In den Zeichnungen, auf welche dabei Bezug genommen wird, zeigen: Further advantages, features, benefits, and effects of the invention will become apparent from the following exemplary embodiment. Reference is made to the drawings, which show:
Fig. 1 einen erfindungsgemäßen Reaktor in schematischer Darstellung; Fig. 1 shows a reactor according to the invention in a schematic representation;
Fig. 2 zeigt eine schematische Darstellung eines weiteren Reaktors; Fig. 2 shows a schematic representation of another reactor;
Fig. 3 zeigt einen Schnitt durch den Reaktor der Fig. 2. Fig. 1 zeigt einen erfindungsgemäßen Reaktor 1 zur Durchführung eines erfindungsgemäßen Verfahrens in schematischer Darstellung. Ersichtlich ist ein Arbeitsraum 2, welcher durch eine Arbeitsraumwandung 3 begrenzt ist und an welchem außenseitig drei Induktionsspulen 8 angeordnet sind, um im bzw. am Arbeitsraum 2 befindliche Heizelemente 11 induktiv zu erwärmen, sodass im Arbeitsraum 2 befindliche Biomasse eine Temperatur von beispielsweise 1.100 °C erreicht, welche Temperatur erforderlich ist, um chemische Reaktionen zu bewirken, durch welche diese Biomasse in Kohle und Synthesegas umgewandelt wird. Fig. 3 shows a section through the reactor of Fig. 2. Fig. 1 shows a schematic representation of a reactor 1 according to the invention for carrying out a method according to the invention. It shows a working chamber 2, which is defined by a working chamber wall 3 and on which three induction coils 8 are arranged on the outside to inductively heat heating elements 11 located in or on the working chamber 2, so that biomass located in the working chamber 2 reaches a temperature of, for example, 1,100 °C, which temperature is required to initiate chemical reactions through which this biomass is converted into coal and synthesis gas.
Biomasse wird dem Reaktor 1 über einen Zuführtrichter 6 zugeführt, durch welchen die Biomasse in einem dem Arbeitsraum 2 vorgelagerten Bereich gelangt, von welchem aus die Biomasse mittels eines Kolbens 14 entlang einer Transportrichtung 7 durch einen Einlass 4 in den Arbeitsraum 2 bewegt wird. Im Arbeitsraum 2 erfolgt durch die induktive Wärmezufuhr eine Umwandlung der Biomasse in Kohle und Synthesegas. Erzeugte Kohle bzw. Biokohle wird aus dem Arbeitsraum 2 über einen Auslass 5 ausgetragen, und zwar in einen an den Arbeitsraum 2 angrenzenden Kohlebehälter 16. Die Transportrichtung 7 ist hier durch eine direkte Verbindung von Einlass 4 zu Auslass 5 definiert. Grundsätzlich kann der Arbeitsraum 2 jedoch auch eine einer nicht geraden Linie entsprechende Längsachse aufweisen, sodass die Transportrichtung 7, entlang welcher die Biomasse bzw. Kohle im Arbeitsraum 2 bewegt werden, grundsätzlich auch durch eine gekrümmte Linie gebildet sein kann. Biomass is fed to the reactor 1 via a feed hopper 6, through which the biomass reaches an area upstream of the working chamber 2, from which the biomass is moved by means of a piston 14 along a transport direction 7 through an inlet 4 into the working chamber 2. In the working chamber 2, the biomass is converted into coal and synthesis gas by the inductive heat supply. Produced coal or biochar is discharged from the working chamber 2 via an outlet 5, specifically into a coal container 16 adjacent to the working chamber 2. The transport direction 7 is defined here by a direct connection from inlet 4 to outlet 5. In principle, however, the working chamber 2 can also have a longitudinal axis that corresponds to a non-straight line, so that the transport direction 7, along which the biomass or coal is moved in the working chamber 2, can in principle also be formed by a curved line.
Das Synthesegas verlässt den Reaktor 1 über einen Gasauslass 19, welcher ebenfalls mittelbar oder unmittelbar mit dem Auslass verbunden ist. The synthesis gas leaves the reactor 1 via a gas outlet 19, which is also directly or indirectly connected to the outlet.
Weiter ist ersichtlich, dass im Arbeitsraum 2 ein Dorn 9 angeordnet ist, welcher mit einer Zuleitung für ein Vergasungsmedium verbunden ist, sodass durch den Dorn 9 in den Arbeitsraum 2 ein Vergasungsmedium, beispielsweise Wasserdampf oder Kohlendioxid, einbringbar ist. Auch der Dorn 9 ist aus einem elektrisch leitfähigen Material ausgebildet, sodass auch der Dorn 9 durch die Induktionsspulen 8 induktiv erwärmt werden kann. It can also be seen that a mandrel 9 is arranged in the working chamber 2, which is connected to a supply line for a gasification medium, so that a gasification medium, for example, water vapor or carbon dioxide, can be introduced into the working chamber 2 through the mandrel 9. The mandrel 9 is also made of an electrically conductive material, so that the mandrel 9 can also be inductively heated by the induction coils 8.
Wie ersichtlich erfolgt die Zuführung der Biomasse durch den Zuführtrichter 6 quer zur Transportrichtung 7 in einen dem Arbeitsraum 2 vorgelagerten Bereich, von welchem aus die Biomasse mittels des Kolbens in den Arbeitsraum bewegt wird. Am Auslass 5 des Arbeitsraumes 2 ist eine Förderschnecke 15 mit einer Endplatte 18 angeordnet. Die Endplatte 18 weist dabei nicht dargestellte Durchbrüche auf, durch welche Kohle entlang der Transportrichtung 7 in die Förderschnecke 15 eingebracht wird, wonach die Kohle mittels der Förderschnecke 15 in einen Kohlebehälter 16 ausgetragen wird. As can be seen, the biomass is fed through the feed hopper 6 transversely to the transport direction 7 into an area in front of the working chamber 2, from which the biomass is moved into the working chamber by means of the piston. At the outlet 5 of the A screw conveyor 15 with an end plate 18 is arranged in the working chamber 2. The end plate 18 has openings (not shown) through which coal is introduced into the screw conveyor 15 along the transport direction 7, after which the coal is discharged into a coal container 16 by means of the screw conveyor 15.
Die Förderschnecke 15 ist samt der Endplatte 18 parallel zur Transportrichtung 7 und gleichsinnig mit dem Kolben 14 bewegbar, was durch eine zusätzliche strichpunktierte Darstellung von Kolben 14 und Förderschnecke 15 an einer Position mit geändertem Hub in Fig. 1 angedeutet ist. Um Biomasse kontinuierlich von Einlass 4 durch den Arbeitsraum 2 bis zum Auslass 5 zu bewegen, werden Kolben 14 und Transportschnecke somit üblicherweise gleichzeitig und gleichsinnig translatorisch entlang der Transportrichtung 7 bewegt, wobei im Arbeitsraum 2 befindliche Biomasse auch gegen die Endplatte 18 gepresst wird. Auf diese Weise wirkt die Förderschnecke 15 mit der Endplatte 18 als Komprimierkolben und kann einen vordefinierten Druck im Arbeitsraum 2 während des Verfahrens aufrechterhalten werden. The conveyor screw 15, together with the end plate 18, is movable parallel to the transport direction 7 and in the same direction as the piston 14, which is indicated by an additional dash-dotted representation of piston 14 and conveyor screw 15 at a position with a modified stroke in Fig. 1. In order to move biomass continuously from the inlet 4 through the working chamber 2 to the outlet 5, the piston 14 and conveyor screw are thus usually moved simultaneously and in the same direction in a translational manner along the transport direction 7, whereby biomass located in the working chamber 2 is also pressed against the end plate 18. In this way, the conveyor screw 15 with the end plate 18 acts as a compression piston and a predefined pressure can be maintained in the working chamber 2 during the process.
Außenseitig am Arbeitsraum 2 sind an der Arbeitsraumwandung 3 Heizelemente 11 angeordnet, welche durch die Induktionsspulen 8 ebenfalls erhitzt werden. Um zu verhindern, dass Wärmeenergie von den außenseitig am Arbeitsraum 2 angeordneten Heizelementen 11 an eine Umgebung verloren wird, ist außenseitig an diesen Heizelementen 11 eine Isolierung 12 angeordnet, üblicherweise eine Hochtemperatur- Isolierung 12. Darüber hinaus sind diese Heizelemente 11 von einem abgeschlossenen Gasraum 13 umgeben, welcher ebenfalls isolierend wirkt. Alternativ könnte an dieser Position auch ein Vakuum vorgesehen sein. Weiter kann außenseitig an den Heizelementen 11 eine Beschichtung mit einem geringen Emissionskoeffizienten bzw. Emissionsgrad vorgesehen sein, um zu erreichen, dass von den Heizelementen 11 abgestrahlte Wärme im Wesentlichen in den Arbeitsraum 2 wirkt. On the outside of the work chamber 2, heating elements 11 are arranged on the work chamber wall 3, which are also heated by the induction coils 8. In order to prevent heat energy from the heating elements 11 arranged on the outside of the work chamber 2 from being lost to the environment, insulation 12, usually high-temperature insulation 12, is arranged on the outside of these heating elements 11. Furthermore, these heating elements 11 are surrounded by a closed gas space 13, which also has an insulating effect. Alternatively, a vacuum could also be provided at this position. Furthermore, a coating with a low emission coefficient or emissivity can be provided on the outside of the heating elements 11 in order to ensure that the heat radiated by the heating elements 11 essentially acts on the work chamber 2.
Der Arbeitsraum 2 ist hier zylindrisch dargestellt. Um möglichst wenig Energie für das Bewegen der Biomasse entlang der Transportrichtung 7 durch den Arbeitsraum 2 zu verbrauchen, kann jedoch auch vorgesehen sein, dass ein Querschnitt des Arbeitsraumes 2 zwischen Einlass 4 und Auslass 5 zunimmt, sodass der Arbeitsraum 2 beispielsweise konusförmig oder mit zylindrischen Rohren mit entlang der Transportrichtung 7 zunehmendem Querschnitt ausgebildet sein kann. Es können auch innen an der Arbeitsraumwandung 3 Heizelemente 11 angeordnet sein, welche in Fig. 1 nicht dargestellt sind, um den Arbeitsraum 2 bzw. darin befindliche Biomasse auf entsprechende Temperatur bringen zu können. Die Heizelemente 11 sind bevorzugt aus Graphit gebildet, wenngleich auch ein anderes Material eingesetzt werden kann, welches induktiv erwärmbar ist. Günstig ist es, wenn die Heizelemente 11 aus einem elektrisch leitfähigen Material bestehen, welches Temperaturen von mehr als 1.000 °C standhalten kann. Auch an diesen innenseitigen Heizelementen 11 kann außenseitig eine entsprechende Beschichtung vorgesehen sein, um eine Abstrahlung von Wärmeenergie nach außen zu vermeiden bzw. zu minimieren. Weiter kann innenseitig an der Arbeitsraumwandung 3 eine chemisch beständige Beschichtung, insbesondere eine asche- und/oder schlackeabweisende Schutzschicht vorgesehen sein. Es versteht sich, dass diese Beschichtung üblicherweise selbst nicht elektrisch leitfähig ausgebildet ist, um eine Erwärmung durch das elektromagnetische Feld, welches mittels der Induktionsspulen 8 erzeugt wird, zu vermeiden. The working chamber 2 is depicted as cylindrical here. However, in order to consume as little energy as possible for moving the biomass along the transport direction 7 through the working chamber 2, it can also be provided that the cross-section of the working chamber 2 increases between the inlet 4 and the outlet 5, so that the working chamber 2 can be designed, for example, conically or with cylindrical tubes with a cross-section that increases along the transport direction 7. Heating elements 11, which are not shown in Fig. 1, can also be arranged on the inside of the work chamber wall 3 in order to bring the work chamber 2 or the biomass located therein to the appropriate temperature. The heating elements 11 are preferably made of graphite, although another material that can be heated inductively can also be used. It is advantageous if the heating elements 11 are made of an electrically conductive material that can withstand temperatures of more than 1,000 °C. A corresponding coating can also be provided on the outside of these internal heating elements 11 in order to prevent or minimize the radiation of thermal energy to the outside. Furthermore, a chemically resistant coating, in particular an ash- and/or slag-repellent protective layer, can be provided on the inside of the work chamber wall 3. It is understood that this coating is usually not electrically conductive itself in order to avoid heating by the electromagnetic field generated by the induction coils 8.
Wie ersichtlich sind im dargestellten Ausführungsbeispiel drei Spulen vorgesehen, sodass der Arbeitsraum 2 entlang einer axialen Erstreckung mittels der drei Spulen unterschiedlich stark beheizt werden kann. Auf diese Weise kann in jedem Bereich eine gewünschte Temperatur auf einfache Weise eingestellt werden. Zur Überwachung der Temperatur sind üblicherweise hier nicht dargestellte Temperatursensoren im Arbeitsraum 2 positioniert und ist eine Regelung vorgesehen, welche mit den Temperatursensoren und den Induktionsspulen 8 verbunden ist. Zur Kühlung der Induktionsspulen 8 kann eine Kühleinrichtung vorgesehen sein, insbesondere ein die Induktionsspulen 8 umströmendes Kühlmedium. Die Temperatursensoren können entlang der Transportrichtung sowie mit unterschiedlichem Abstand zu einer Mittelachse des Arbeitsraumes angeordnet sein, um ein Temperaturprofil im Arbeitsraum möglichst genau erfassen zu können, welches in weiterer Folge für eine Regelung der Induktionsspulen, des Kolbens und/oder des Volumenstromes des Vergasungsmediums eingesetzt werden kann. As can be seen, three coils are provided in the illustrated embodiment, so that the working chamber 2 can be heated to different intensities along an axial extent by means of the three coils. In this way, a desired temperature can be easily set in each area. To monitor the temperature, temperature sensors (not shown here) are usually positioned in the working chamber 2, and a control system is provided which is connected to the temperature sensors and the induction coils 8. To cool the induction coils 8, a cooling device can be provided, in particular a cooling medium flowing around the induction coils 8. The temperature sensors can be arranged along the transport direction and at different distances from a central axis of the working chamber in order to be able to record a temperature profile in the working chamber as accurately as possible, which can subsequently be used to control the induction coils, the piston and/or the volume flow of the gasification medium.
Weiter ist in Fig. 1 ersichtlich, dass Zusatzstoffe 17 gemeinsam mit der Biomasse in den Arbeitsraum 2 eingebracht werden. Dabei kann es sich beispielsweise um Graphitkugeln handeln, welche durch die Induktionsspuren ebenfalls erhitzt werden, um eine möglichst gleichmäßige Erhitzung der Biomasse im Arbeitsraum 2 zu gewährleisten. Die Zusatzstoffe 17 können auch dazu eingesetzt werden, auf den Pyrolyseprozess zu wirken, indem diese eine Ascheerweichungstemperatur zu beeinflussen oder eine In-Situ- Entschwefelung bewirken. Die Zusatzstoffe 17 werden über den Auslass 5 mit der Kohle in den Kohlebehälter 16 gefördert und können somit in weiterer Folge von der Kohle getrennt und wieder verwendet werden. Furthermore, Fig. 1 shows that additives 17 are introduced into the working chamber 2 together with the biomass. These can be, for example, graphite spheres, which are also heated by the induction tracks in order to ensure the most uniform heating possible of the biomass in the working chamber 2. Additives 17 can also be used to influence the pyrolysis process by influencing the ash softening temperature or by effecting in-situ desulfurization. The additives 17 are conveyed with the coal via outlet 5 into the coal container 16 and can thus subsequently be separated from the coal and reused.
Die Arbeitsraumwandung 3 ist üblicherweise aus Keramik oder Glas gebildet, sodass diese einen Durchtritt des elektromagnetischen Feldes, welches von den Induktionsspulen 8 erzeugt wird, in den Arbeitsraum 2 leicht ermöglicht und gleichzeitig den hohen Temperaturen gut standhalten kann. Der Dorn 9, welcher üblicherweise etwa zylindrisch ausgebildet ist, weist insbesondere umfangsseitig Öffnungen 10 auf und kann ebenfalls aus einem Metall ausgebildet sein, sodass auch der Dorn 9 durch die Induktionsspulen 8 erhitzt wird, um eine entsprechende Temperierung der Biomasse zu erreichen. Um eine Abschirmung des Arbeitsraumes 2 von den Induktionsspulen 8 zu vermeiden, kann vorgesehen sein, dass zwischen den an der Arbeitsraumwandung 3 außenseitig und/oder innenseitig angebrachten Heizelementen 11 jeweils Freiräume vorgesehen sind, sodass das durch die Induktionsspulen 8 erzeugte elektromagnetische Feld gut durch die Arbeitsraumwandung 3 in den Arbeitsraum 2 eindringen kann. The working chamber wall 3 is usually made of ceramic or glass, so that it easily allows the electromagnetic field generated by the induction coils 8 to pass into the working chamber 2 and at the same time can withstand the high temperatures. The mandrel 9, which is usually approximately cylindrical, has openings 10 in particular on its circumference and can also be made of a metal, so that the mandrel 9 is also heated by the induction coils 8 in order to achieve appropriate temperature control of the biomass. To avoid shielding the working chamber 2 from the induction coils 8, it can be provided that free spaces are provided between the heating elements 11 attached to the outside and/or inside of the working chamber wall 3, so that the electromagnetic field generated by the induction coils 8 can easily penetrate through the working chamber wall 3 into the working chamber 2.
Die Biomasse wird somit während des Verfahrens vom Einlass 4 zum Auslass 5 durch den Arbeitsraum 2 bewegt und dabei durch die Heizelemente 11 und den Dorn 9 erhitzt. Dabei pyrolysiert die Biomasse und wird in Pyrolysegas und Biokohle bzw. Synthesegas und Kohle umgewandelt. Die Kohle wird weitergefördert und erfährt an der Endplatte 18, welche als Komprimierkolben wirkt, eine definierte Anstauung, wodurch ein dichtes und definiertes Kohlebett erzeugt wird, welches vom erzeugten Synthesegas und einem über den Dorn 9 zugeführten Vergasungsmedium durchströmt wird. Das Synthesegas weist als Hauptbestandteile CO, H2, CH4 und CO2 auf, wobei eine Zusammensetzung variabel ist und insbesondere von Prozessparametern wie Temperatur, Volumenstrom des Vergasungsmediums und/oder Druck im Arbeitsraum abhängig sein kann. During the process, the biomass is thus moved from the inlet 4 to the outlet 5 through the working chamber 2, where it is heated by the heating elements 11 and the mandrel 9. The biomass pyrolyzes and is converted into pyrolysis gas and biochar, or synthesis gas and coal. The coal is conveyed further and experiences a defined accumulation at the end plate 18, which acts as a compression piston, creating a dense and defined coal bed through which the generated synthesis gas and a gasification medium supplied via the mandrel 9 flow. The synthesis gas has CO, H2, CH4, and CO2 as its main components, although its composition is variable and can depend in particular on process parameters such as temperature, volume flow of the gasification medium, and/or pressure in the working chamber.
Das mit dem Reaktor produzierte Synthesegas kann anschließend zu verschiedenen weiteren Produkten weiterverarbeitet werden, wie zum Beispiel einspeisefähiges synthetisches Erdgas/Methan (CH4), Methanol oder zu (grünem) Wasserstoff aufgereinigt werden. Bei diesem Durchströmen werden einerseits Teere vom Pyrolysegas zu kurzkettigen Kohlenwasserstoffen reformiert und andererseits wird Biokohle selbst durch das Vergasungsmedium zersetzt und teilweise vergast. Die an der Endplatte 18 der Förderschnecke 15 angestaute Kohle wird in weiterer Folge über in der Endplatte 18 angeordnete Durchbrüche in die Förderschnecke 15 bewegt und mit dieser in den Kohlebehälter 16 ausgefördert. The synthesis gas produced by the reactor can then be further processed into various other products, such as feed-in synthetic natural gas/methane (CH4), methanol or purified into (green) hydrogen. During this flow, on the one hand, tars are reformed into short-chain hydrocarbons by the pyrolysis gas, and on the other hand, biochar itself is decomposed and partially gasified by the gasification medium. The coal accumulated at the end plate 18 of the screw conveyor 15 is subsequently moved into the screw conveyor 15 via openings arranged in the end plate 18 and discharged with it into the coal container 16.
Der Dorn 9 ist im dargestellten Ausführungsbeispiel nur im Kolben 14 gelagert. Gerade bei längeren Reaktoren 1 kann auch eine zweite Lagerung des Dornes 9 vorgesehen sein, vorzugsweise im Bereich der Förderschnecke 15 bzw. der Endplatte 18. In the illustrated embodiment, the mandrel 9 is mounted only in the piston 14. Especially in longer reactors 1, a second mounting of the mandrel 9 can also be provided, preferably in the area of the conveyor screw 15 or the end plate 18.
Fig. 2 und 3 zeigen ein weiteres Ausführungsbeispiel eines Reaktors 1 , welcher im Wesentlichen analog zu dem in Fig. 1 dargestellten Reaktor 1 ausgebildet ist. Fig. 3 zeigt dabei einen Schnitt durch den Reaktor 1 entlang der Linie III - III in Fig. 2. Im Unterschied zu dem in Fig. 1 dargestellten Ausführungsbeispiel wird hier ein Vergasungsmedium nicht nur über die Öffnungen 10 im Dorn 9 zugeführt, sondern auch über Wandöffnungen 20 in der Arbeitsraumwandung 3. Wie ersichtlich sind diese Wandöffnungen 20 über einen Umfang des Arbeitsraumes 2 regelmäßig verteilt angeordnet und derart ausgerichtet, dass das Vergasungsmedium etwa parallel zur Transportrichtung 7 ausströmt. Natürlich können die Wandöffnungen 20 auch zur Ausströmung des Vergasungsmediums unter einem anderen Winkel ausgebildet sein. Durch die Einbringung des Vergasungsmediums über die Wandöffnungen 20 wird eine besonders gute Verteilung des Vergasungsmediums im Arbeitsraum 2 erreicht. 2 and 3 show a further embodiment of a reactor 1, which is designed essentially analogously to the reactor 1 shown in Fig. 1. Fig. 3 shows a section through the reactor 1 along the line III - III in Fig. 2. In contrast to the embodiment shown in Fig. 1, here a gasification medium is supplied not only via the openings 10 in the mandrel 9, but also via wall openings 20 in the working chamber wall 3. As can be seen, these wall openings 20 are arranged so as to be regularly distributed over a circumference of the working chamber 2 and are aligned such that the gasification medium flows out approximately parallel to the transport direction 7. Of course, the wall openings 20 can also be designed for the gasification medium to flow out at a different angle. By introducing the gasification medium via the wall openings 20, a particularly good distribution of the gasification medium in the working chamber 2 is achieved.
Mit einem erfindungsgemäßen Reaktor 1 kann Biomasse unter Zuführung von elektrischer Energie auf besonders einfache und robuste Weise in Kohle und Synthesegas umgewandelt werden, wodurch beispielsweise Sägewerke abfallende Holzspäne auf günstige Weise in Kohle und Synthesegas wandeln und energetisch nutzbar machen können. With a reactor 1 according to the invention, biomass can be converted into coal and synthesis gas in a particularly simple and robust manner by supplying electrical energy, whereby, for example, sawmills can inexpensively convert waste wood chips into coal and synthesis gas and utilize them for energy purposes.
Claims
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| ATA50094/2024 | 2024-02-05 | ||
| ATA50094/2024A AT527982A1 (en) | 2024-02-05 | 2024-02-05 | Reactor for producing coal and synthesis gas from biomass |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1106672A1 (en) * | 1999-12-07 | 2001-06-13 | Donizetti Srl | Process and equipment for the transformation of refuse using induced currents |
| WO2008053571A1 (en) * | 2006-10-31 | 2008-05-08 | Medical Safety System, Inc. | Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system |
| US20080171899A1 (en) * | 2007-01-16 | 2008-07-17 | Peter Pulkrabek | Production of Synthesis Gas from Biomass and Any Organic Matter by Reactive Contact with Superheated Steam |
| US20120217442A1 (en) * | 2009-10-15 | 2012-08-30 | Pyromex Holding Ag | High-temperature furnace and method for converting organic materials to synthesis gas |
| EP2016159B1 (en) * | 2006-04-24 | 2016-05-11 | REW Regenerative Energie Wirtschaftssysteme GmbH | Biomass gasifier and method for the allothermic gasification of biomass |
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| DE3234017C2 (en) * | 1982-09-14 | 1985-08-29 | Nukem Gmbh, 6450 Hanau | Continuous furnace for incineration of solid organic substances |
| DE102012001102B4 (en) * | 2012-01-23 | 2019-03-14 | Fritz Peter | Process for the gasification of substances |
| HUE042135T2 (en) * | 2012-11-29 | 2019-06-28 | Care Beteiligungsverwaltung Gmbh | Use of an apparatus for transporting fuels in a gasification reactor |
| AT516178B1 (en) * | 2014-09-16 | 2016-03-15 | Ame Handelsgesellschaft M B H | Process and apparatus for producing synthesis gas from carbonaceous waste |
| IT202000032600A1 (en) * | 2020-12-29 | 2021-03-29 | Benzi & Partners S R L | Method and plant for the disposal of waste consisting of plastic materials or biomass, and of all organic materials that contain carbon in their molecules |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1106672A1 (en) * | 1999-12-07 | 2001-06-13 | Donizetti Srl | Process and equipment for the transformation of refuse using induced currents |
| EP2016159B1 (en) * | 2006-04-24 | 2016-05-11 | REW Regenerative Energie Wirtschaftssysteme GmbH | Biomass gasifier and method for the allothermic gasification of biomass |
| WO2008053571A1 (en) * | 2006-10-31 | 2008-05-08 | Medical Safety System, Inc. | Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system |
| US20080171899A1 (en) * | 2007-01-16 | 2008-07-17 | Peter Pulkrabek | Production of Synthesis Gas from Biomass and Any Organic Matter by Reactive Contact with Superheated Steam |
| US20120217442A1 (en) * | 2009-10-15 | 2012-08-30 | Pyromex Holding Ag | High-temperature furnace and method for converting organic materials to synthesis gas |
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