WO2008053571A1 - Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system - Google Patents
Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system Download PDFInfo
- Publication number
- WO2008053571A1 WO2008053571A1 PCT/JP2006/322220 JP2006322220W WO2008053571A1 WO 2008053571 A1 WO2008053571 A1 WO 2008053571A1 JP 2006322220 W JP2006322220 W JP 2006322220W WO 2008053571 A1 WO2008053571 A1 WO 2008053571A1
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- Prior art keywords
- gas
- sealed chamber
- pyrolysis
- inert gas
- chamber
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B19/00—Heating of coke ovens by electrical means
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B7/00—Coke ovens with mechanical conveying means for the raw material inside the oven
- C10B7/10—Coke ovens with mechanical conveying means for the raw material inside the oven with conveyor-screws
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/30—Pyrolysing
- F23G2201/301—Treating pyrogases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/40—Gasification
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2202/00—Combustion
- F23G2202/30—Combustion in a pressurised chamber
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/80—Furnaces with other means for moving the waste through the combustion zone
- F23G2203/801—Furnaces with other means for moving the waste through the combustion zone using conveyors
- F23G2203/8013—Screw conveyors
Definitions
- the present invention relates to a continuous pyrolysis method and apparatus for waste containing organic matter and an i-cracking gasification system. More specifically, the present invention relates to a sealed chamber in which a pyrolysis heating section is formed so as not to always exceed atmospheric pressure. The present invention relates to a method and apparatus, and a pyrolysis gasification system, which cuts outside air by sending an active gas and thermally decomposes organic: waste containing organic matter in an oxygen state below a so-called critical oxygen concentration.
- the critical oxygen concentration is the minimum oxygen concentration required to continuously burn or explode combustible materials. If the oxygen level is less than this value, the combustion or combustion explosion of combustible materials does not occur as in the case of the oxygen-free state. Therefore, in the present invention, the state below this limit oxygen concentration is called the oxygen-free state.
- thermal solution means that when a combustible is normally heated at about 5 0 0 to 6 0 0 ° p with outside air blocked, the thermal decomposition reaction is promoted, It can be made into pyrolysis gas and residue without burning or burning. It is a so-called steamed and burned state of combustible material. Pyrolysis reaction, the heat furnace is heated using a method such as heating the outer jacket of a kiln or other furnace with a gas burner or the like, or delivering high-temperature air to the outer circumference. Heat itself and heat the furnace in the out-of-air condition. It can be realized by heating to about C.
- induction heating ripening using electromagnetic induction is called induction heating or electromagnetic induction heating.
- the principle is> When an alternating current is passed through a conductor, magnetic lines of force are generated around it. An eddy current flows through a conductive material such as a metal that is coiled along a center line, and Joule heat is generated by the electrical resistance of the conductive material, which heats the metal itself.
- a method of adopting this principle to form a heat-heating part made of a conductive material, in which a combustible material is thermally decomposed in an oxygen-free state.
- Japanese Patent Publication No. 7-3 2 3 2 70 discloses that the opening is material-sealed by pyrolyzate, and the heating envelope that follows the hermetic pyrolyzed soot.
- the gas burner is equipped with a device that heats the pyrolysis soot to 2500-500 ° C and pyrolyzes the waste inside.
- the device described in Japanese Patent No. 3 3 7 7 3 9 supplies hot air generated by an air heater in a combustion melting furnace provided on the downstream side of a laterally-oriented ripening drum to the outer periphery of the heating drum.
- Japanese Patent Laid-Open No. 10-4 3 7 1 4 discloses that each container is filled with waste. It is inserted into an electromagnetic induction heating source to completely block out the outside air and make the waste steamed, so that the chlorine component in the waste can be extracted effectively. Yes.
- Japanese Laid-Open Patent Publication No. 20.3-1 4 2 16 relates to an electromagnetic induction heating drum for a heat reaction caused by electromagnetic induction heating.
- the air is evacuated by the suction of the evacuation pump, is brought into a nearly vacuum state (oxygen-free atmosphere), and the waste is pyrolyzed with a drum ⁇ heated with juicy heat. Specifically, heating '.
- the drum is provided with a sealable shutter at each of the waste intake and exhaust, the outlet, and the pyrolysis gas exhaust hole to prevent inflow of air from outside the drum.
- the inside of the drum is kept in a gas state, and the waste product that has been input is transported by a screw conveyor and can undergo a thermal decomposition reaction in an oxygen-free state.
- a double shutter device that can be opened and closed alternately, and an air vent for lowering the internal pressure are provided separately.
- Patent documents of the same series include Japanese Patent Application Laid-Open No.
- the electromagnetic induction heating device disclosed in these licensed documents has a structure in which a crushing / drying unit, a heating unit, and a cooling unit are arranged in front and behind a single drum-shaped combustion chamber, or each unit
- One of the structures is a structure in which a plurality of horizontally-facing drum combustion chambers having intakes and discharge ports are provided in the front, and the discharge ports of the front combustion chamber and the intake ports of the rear combustion chamber are detachable.
- the electromagnetic induction heating unit has an outer wall covered with a heat insulating material and Z or a water jacket, and the surrounding wall is coiled with a conducting wire through which an alternating current flows. It is a horizontal drum-shaped combustion chamber structure made of a conductive material provided at least at the end, and can be freely rotated around an axis as necessary.
- a screw conveyor can be used to enhance the stirring function of the combusted material in the combustion chamber, and a stirring battle can be arranged on the rotating shaft, or a cork screw blade can be arranged on the inner wall of the drum.
- the top cover and bottom cover are alternately used in place of the openable / closable sealing lid so that the batch processing by electromagnetic induction heating of the combusted material can be performed efficiently while blocking the atmosphere.
- An open hopper for combustibles with a double shutter that can be opened and closed freely, and for burning combustibles So as not to burn or combustion explosion Nau combustible gas, a method of replacing the 'inside of the input hopper and dense closed from the inert gas atmosphere is disclosed.
- the disclosed equipment has an injection hopper, a sealed chamber, and heating cylinders arranged in the sealed chamber arranged in a vertical shape. Valves are connected to each other by pipes from an inert gas storage tank provided outside them.
- the inert gas is communicated from the inert gas storage tank through the valve to the charging hopper and the sealed chamber.
- the gas generated from the combustible gas in the charging hopper and closed chamber communicates with the exhaust gas treatment facility via each valve and is discharged.
- flammable gas is generated, so an oxygen concentration sensor is placed in advance in the charging hopper and the sealed chamber, and the replacement state of oxygen (atmosphere) and inert gas such as nitrogen (N 2 ) is always maintained. It can be monitored.
- the amount of generated gas increases as the combustion temperature of the combusted material increases, but it is not possible to keep the sealed chamber at a pressure slightly higher than the atmospheric pressure in order to suppress the inflow of air into the sealed chamber. It is also disclosed that the flow rate of the active gas is increased at the initial stage so that the flow rate can be met with a small flow rate as the amount of generated gas increases. However, such treatment in the sealed room must be released and set repeatedly each time.
- various methods and apparatuses have been proposed in addition to this for the formation of a combustion environment of waste by an inert gas. For example, as described in JP-A-6-2 8 1 3 6 2, heat treatment such as reflow in semiconductor manufacturing is .
- a gas film containing an inert gas is formed at the inlet and outlet of the workpiece to completely block the atmosphere inside and outside the furnace.
- Japanese Patent No. 2 6 3 5 4 5 9 that include a double gate that forms an inert gas film at a certain distance at each of the entrances and exits. .
- Japanese Patent No. 3 3 7 7 3 59 and Japanese Patent Laid-Open No. 20-320 No. 5-2 0 7 6 8 4 can be mentioned.
- the latter includes treatment of medical waste that is very difficult to handle, for example, so that the waste is not exposed to the atmosphere or the worker is not likely to come into contact with it.
- Japanese Patent Publication No. 20.2-5. 1 6. 7 20 It is a medical waste treatment in a fully equipped laboratory where the entrance / exit is completely shut off from the atmosphere by using multiple airlocks, even with prior powder and Z or heat treatment. Also.
- the document also discloses a large fan device equipped with an air filter that keeps the processing chamber in a negative pressure state so that the polluted air generated by the heat treatment does not leak and Z ′ or backflow.
- Patent Document 1 Japanese Patent Application Laid-Open No. 7-3 2 3 2 70
- Patent Document 2 7 7 3 5 9 ⁇
- Patent Document 3 ⁇ 'JP 10-4 3 7 1 4
- Patent Document 4 Japanese Patent Laid-Open No. 2 0 0 3 1 4 2 1 6
- Patent Document 5 Japanese Patent Laid-Open No. 2 0 0 5 1 12 7 6 80
- Patent Document 6 Japanese Patent Laid-Open No. 2 0 0 5 — 1 2 7 6 8 2
- Patent Document 7 Japanese Patent Laid-Open No. 2 0 0 4-2 0 9 3 3 9
- Patent ⁇ : 8 Japanese Patent Laid-Open No. 2 0 0 5 1 8 3 7 1 8
- Patent Document 9 Japanese Patent Laid-Open No. 6-2 8 1 3 6 2
- Patent Document 10 Patent 2 6 3 5 4 5 9
- Patent Document 1 Japanese Unexamined Patent Publication No. 2 0 0 5 1 2 0 7 6 8 4
- Patent Document 1 2 Special Table 2 0 0 2 1 5 1 6 7 2 0 Publication
- an incinerator To remove pollutants and control toxic gas emissions
- One of the solutions is the development of a method and apparatus that enables thermal decomposition in the absence of oxygen. As a result, generation of toxic gases including carbon monoxide and dioxin can be suppressed, and at the same time, contaminants such as viruses and pathogenic bacteria can be removed.
- the formation of anoxic conditions is not easy.
- the inside of the heating device must be completely isolated from the atmosphere by means such as mechanical shutter, air lock or air shutter, material sealing, and replacement with inert gas such as nitrogen (N 2 ). Is extremely difficult and more complete. If you want something, you have to be expensive. Therefore, as a next best measure, in mechanical and pneumatic means ... Double inert, simply inert that does not include the fact that the inside of the inner gas has a gradient of inert gas higher than atmospheric pressure. Examples thereof include a gas atmosphere forming method. .
- a further technical challenge is to prevent leakage and / or backflow of pyrolysis gas generated by pyrolysis.
- Leakage of pyrolysis gas generated from the pyrolysis reaction of waste containing organic substances and prevention of Z or backflow are considered from the viewpoint of contamination from organic substance-containing waste management methods or leakage of poisonous gas from the treatment room.
- the formation of such a chamber in a negative pressure state has the problem that it becomes difficult to completely block the inflow of air by placing the pyrolysis chamber of organic-containing waste in a negative pressure state as described above. Will also face. It is necessary to solve these two issues in a trade-off relationship at the same time.
- the next technical problem is to prevent the deterioration of the equipment function due to melting and Z or viscous adhesion temporarily generated during the heat treatment process of organic material-containing waste containing polymer materials.
- thermal decomposition or combustion treatment that includes a pre-process of crushing plastic containers filled with organic matter-containing waste such as medical waste treatment
- combustibles containing large amounts of polymer materials are exposed to high temperatures. Because it is transported through the horizontal drum-shaped heating chamber to the discharge port in a state of containing the molten high-viscosity polymer material, the viscous polymer material melted on the screw conveyor that is normally adopted as the transport means It is inevitable that adhesion accumulates. This avoids degradation of device functions -If you try to do so, you have to stop the entire system quite often and disassemble and clean the combustion chamber and the screw conveyor itself.
- the solution to the above-mentioned problem is thermal decomposition in which organic-containing waste introduced from the upper side is thermally decomposed, pyrolysis gas generated from the downstream side is exhausted, and residual carbides are discharged.
- the organic waste containing the waste is continuously pyrolyzed so as to be exhausted from the sealed chamber. It can be achieved by the present invention.
- the invention described in claim 1 is a method of thermally decomposing organic matter-containing waste continuously into pyrolysis gas and residual carbides, wherein the organic matter-containing waste introduced from the flow side is heated.
- An inert gas is injected into a sealed chamber that forms a pyrolysis heating section between the upstream side and the downstream side where the pyrolysis gas generated from the downstream side is exhausted and residual carbides are discharged.
- Inert gas is fed in by means of such that the pressure of the inert gas in the closed chamber always exceeds atmospheric pressure, the outside air is shut off to make the sealed chamber oxygen-free, and the pyrolysis gas generated A pressure gradient of the inert gas is formed from the upstream side to the downstream side of the sealed chamber so that the pressure is exceeded, and the pyrolysis gas is exhausted from the sealed chamber without backflowing from the downstream side to the upstream side.
- the invention described in claim 2 is a method for continuous pyrolysis of waste containing organic matter, comprising: a) an inlet for receiving waste containing organic matter from the upstream side, and thermal decomposition of waste containing organic matter from the downstream side. Therefore, it is inactive in a sealed chamber that has an exhaust hole for exhausting the pyrolysis gas generated and an exhaust port for discharging residual carbides, and forms a pyrolysis heating section between the upstream side and the downstream side.
- An inert gas reservoir is formed when the gas injection means feeds the inert gas, and b) the inert gas reservoir is introduced from the inlet of the sealed chamber. ..
- Inert gas reservoir I While maintaining, sequentially send waste containing organic matter to the pyrolysis heating section of the sealed chamber, and d) Waste containing organic matter in the pyrolysis heating section by the inert gas sent to the sealed chamber The waste is continuously pyrolyzed into pyrolysis gas and residual carbides in the absence of oxygen, and e) the gas pressure of the inert gas sent into the sealed chamber is always higher than the gas pressure of the pyrolysis gas.
- a positive pressure state with an inert gas is formed in the sealed chamber, which prevents the atmosphere from entering the sealed chamber in an oxygen-free state, and makes the sealed chamber inactive.
- the gas pressure of the gas always exceeds the gas pressure of the pyrolysis gas generated by pyrolysis,
- the gas pressure P H forms a pressure gradient of the inert gas that exceeds the atmospheric pressure P 0, thereby preventing backflow of pyrolysis gas from the downstream side 'to the upstream side in the sealed chamber. It is characterized by
- the invention described in claim 3 is in addition to the features of the invention described in Requirement Scope 2, and includes an inlet for receiving organic waste from the upstream side and an organic waste containing organic matter from the downstream side.
- An exhaust hole for exhausting pyrolysis gas generated by decomposition and an outlet for discharging residual carbides and a closed chamber that forms a pyrolysis heating section between the upstream side and the downstream side are installed horizontally. It is a sealed chamber.
- the invention described in claim 4 is characterized in that, in addition to the features of the invention described in claim 3, the heat decomposition heating part of the sealed chamber is made of a conductive material, and the outer wall of the pyrolysis heating part is an electromagnetic induction heating coil. It is characterized in that the internal temperature of the pyrolysis heating part is adjusted by controlling the voltage to the electromagnetic induction heating coil.
- the invention described in claim 5 includes a step of sequentially introducing waste containing organic matter from an inlet of the sealed chamber into an inert gas reservoir.
- the method further includes the step of sequentially transferring waste to the input port via a sealed transfer path that continues to the input port of the sealed chamber. It is characterized by that. ⁇
- the step of sequentially transporting the organic substance-containing waste to the inlet is crushed and dried the organic substance-containing waste.
- the method further includes a step of solidifying and shaping later.
- the invention described in claim 7 is a two-stage shutter that opens and closes alternately at the inlet of the sealed chamber. It is characterized by the fact that the waste containing organic matter is made to stay in the transfer chamber at a time by the input means having a self-contained transfer chamber that is formed, and then sequentially put into the sealed chamber. .
- an inert gas injection is provided on the most upstream side of the sealed feed chamber and Z or the sealed chamber at the inlet of the sealed chamber.
- An inert gas injection means having an inlet feeds an inert gas into the transfer chamber and / or sealed chamber, and at least controls the gas pressure of the inert gas in the closed chamber to exceed the arrow pressure.
- the invention described in claim 9 includes at least an introductory space on the most upstream side of the hermetic chamber, at least an inlet of the hermetically sealed chamber Gas pressure in the vicinity of the inlet, upstream of the pyrolysis heating ⁇ in the sealed chamber, and downstream of the pyrolysis heating section of the sealed nitrogen
- An appropriate sensor is installed, so that the inert gas pressure in the inert gas reservoir into which the waste containing organic matter on the upstream side where thermal decomposition starts is injected and the forward stroke of the pusher plate of the reciprocating means Control the amount of inert gas fed while monitoring the mixed gas pressure of the generated pyrolysis gas and inert gas, and the gas pressure of the pyrolysis gas mainly on the downstream side where pyrolysis is completed. Then, it is characterized by the fact that an inert gas pressure from the upstream side to the downstream side and a gradient are formed in the closed chamber.
- the communication means is one or more perforated on the pusher plate of the reciprocating means.
- the inert gas in the inert gas pool filled with waste containing organic matter gradually flows to the rear of the pusher plate through multiple holes in the pusher plate as the pusher plate moves forward in the reciprocating means.
- the pressure gradient in which the inert gas is formed is maintained by gradually flowing in the front of the pusher plate through the plurality of holes of the pusher plate as the pusher plate of the reciprocating means moves backward. It is characterized by that.
- the invention described in claim 11 1 always has a gas pressure of the inert gas sent into the sealed chamber of the pyrolysis gas.
- the step of recovering the pyrolysis gas from the exhaust hole of the exhaust gas further includes a step of passing the recovered pyrolysis gas through a gas cleaning and cooling means and recovering it as an oil component by the oil-water separation means. And .
- the invention described in claim 12 2 allows the recovered pyrolysis gas to pass through a gas cleaning and cleaning or cooling means, and is separated by an oil-water separation means
- the step of recovering as an oil component further includes a step of exhausting residual pyrolysis gas by an exhaust fan via a mist separation means.
- the pusher of the reciprocating means is used for the organic matter-containing waste that is sequentially fed into the sealed chamber.
- the feature is that the carbide of 3 ⁇ 4 is discharged from the discharge port of the sealed chamber by the pushing operation by the forward stroke of one plate.
- the invention described in claim 14 is any one of claims 2 to 1 3 in addition to the features of the invention described in B.
- the process of recovering the residue is: The process of recovering the residual carbide in the recovery container through the carbide cooling chamber having the upstream input port connected to the discharge port and the downstream discharge port connected to the recovery container Is further included.
- Claim 15 The invention described in claim 5 is an apparatus for continuous thermal decomposition of organic matter-containing waste.
- a pyrolysis heating section is formed between the upstream side and the downstream side, which has an exhaust port for exhausting pyrolysis gas generated by the thermal decomposition of waste containing organic matter and an exhaust port for discharging residual carbides.
- an inert gas injection device that communicates with the sealed chamber forming an inert gas reservoir by capping the inert gas into the sealed chamber; and c) the inert gas from the sealed inlet A wastewater containing organic matter is sequentially added to the reservoir, and a reciprocating device having a pusher that substantially matches the cross-sectional shape of the sealed chamber that is sequentially fed to the pyrolysis heating section of the sealed chamber; and d) The inert gas is moved by the inert gas moving before and after the moving pusher plate.
- An inert gas communication device that sequentially feeds the waste containing organic matter to the pyrolysis heating section of the sealed chamber while maintaining the reservoir, and e) heats the waste containing organic matter in the pyrolysis heating section of the sealed chamber.
- a pyrolysis heating device placed in the pyrolysis heating section that continuously pyrolyzes the cracked gas and residual carbides, and f) the gas pressure of the inert gas sent into the sealed chamber is always the gas pressure of the pyrolysis gas.
- a pyrolysis gas recovery device that forms a pressure gradient of the inert gas from the upstream side to the downstream side in the closed chamber, and g) a discharge device that recovers residual carbide from the discharge port of the closed chamber.
- the gas pressure of the inert gas sent using the inert gas injection device should be at least above atmospheric pressure.
- ⁇ pyrolysis gas generated by pyrolysis of the thermal device and gradually increasing the gas pressure of the pyrolysis gas and the upstream side of the sealed chamber
- An inert gas pressure gradient is formed from the upstream side to the downstream side of the sealed chamber so that the gas pressure of the inert gas is balanced at least on the upstream side of the sealed chamber. It is characterized in that the amount of inert gas fed into the sealed chamber is controlled so that the air is exhausted from the sealed chamber without being reversed.
- the invention described in claim 16 includes a loading port that accepts organic-containing waste from the upstream side, and organic-containing waste from the downstream side.
- the pyrolysis heating device disposed in the pyrolysis heating section is an electromagnetic induction heating device, Heat component made of fertile material • Heat the pyrolysis heating part by passing an alternating current through the electromagnetic induction coil wound around the deheating part, and make the outer wall of the pyrolysis heating soot a heat insulating structure, and / or Or, the refrigerant circulates. It is characterized by being covered with a jacket.
- the invention described in claims 1 and 8 can be used to control the internal temperature of the pyrolysis heating unit by controlling the voltage to the electromagnetic induction heating coil.
- the feature is that it has been adjusted. '.
- the invention described in claim 19 is! It further includes a sealed conveyance path connected to the inlet of the sealed chamber into which waste containing organic substances is sequentially added. .
- the invention described in claim 20 further includes a device in which the sealed conveyance path crushes organic matter-containing waste and solidifies after drying. It is characterized by.
- the invention described in claim 21 includes a sealed chamber while temporarily holding organic substance-containing waste at the inlet of the sealed chamber. It further includes a throwing ⁇ device having a sealable transfer chamber formed by at least two upper and lower shutters that are alternately opened and closed.
- an inert gas injection device for sending an inert gas into the sealed chamber includes: The inlet of the door can be sealed freely It is characterized in that an inert gas inlet is provided on the uppermost stream side of the transfer chamber and z or sealed chamber.
- the invention described in claim 23 is characterized in that, in addition to the features of the invention described in any one of claims 15 to 2, the at least the transfer chamber that can be sealed at the inlet of the sealed chamber, the sealed chamber An appropriate gas pressure sensor is installed at the position upstream of the inert gas inlet, upstream of the pyrolysis heating section of the sealed chamber, and downstream of the pyrolysis heating section of the sealed chamber.
- the invention described in claim 24 is characterized in that the communication device is provided in the pusher plate of the reciprocating device in addition to the features of the invention according to any one of claims 15 to 23: One or more holes, and the inert gas in the inert gas reservoir charged with organic substance-containing waste is gradually pushed through the plurality of holes in the pusher plate as the pusher plate of the reciprocating device moves forward. • An inert gas that flows into the back of the plate and gradually flows into the front of the pusher plate through multiple holes in the pusher plate as the reciprocating device pusher plate moves backward The shape of the pressure gradient ⁇
- the invention described in claim 25 is always capable of adjusting the gas pressure of the inert gas sent into the sealed chamber.
- the pyrolysis gas recovery device that creates a pressure gradient of the inert gas from the upstream side to the downstream side in the sealed chamber by exceeding the gas pressure of the pyrolysis gas is a gas scrubbing of the recovered pyrolysis gas And / or further comprising an oil / water separator for recovering as an oil component through a cooling device. .
- the invention described in claim 26 includes an oil-water separator that recovers the recovered pyrolysis gas as an oil component through a gas cleaning and / or cooling device.
- the apparatus further includes a mist separation device for exhausting residual pyrolysis gas by an exhaust fan.
- the invention described in claim 27 includes an organic substance-containing waste that is sequentially fed into a sealed chamber.
- the residual carbides are discharged from the discharge port of the sealed chamber by pushing in with the forward stroke of It is characterized by that. ,
- the discharge device for recovering carbonized carbon from the discharge port of the sealed chamber is a discharge port.
- the carbide is recovered in the recovery container via a carbide cooling chamber having an upstream inlet connected to the outlet and a downstream outlet connected to the recovery container.
- the invention described in claim 29 is a continuous pyrolysis gasification system for organic matter-containing waste, which is an organic matter that has been introduced from the upstream side.
- An inert gas injection system is used to feed an inert gas into a sealed chamber that forms a pyrolysis heating section where the gas is recovered between the upstream side and the upstream side.
- the atmospheric pressure always exceeds the atmospheric pressure, the outside air is shut off and the sealed chamber becomes oxygen-free, and the gas pressure of the generated pyrolysis gas is also exceeded from the upstream side to the downstream side of the sealed chamber.
- a pressure gradient is formed, and the heat component gas is recovered from the sealed chamber without flowing backward from the downstream side to the upstream side.
- the invention described in claim 30 includes a conductive material in which a pyrolysis heating portion is wound by an electromagnetic induction coil, and an outer wall ⁇ It is characterized by having a heat insulation structure and covering with a water jacket through which the refrigerant circulates.
- the invention described in 3.1 adjusts the internal temperature of the pyrolysis heating part by controlling the electromagnetic induction heating coil voltage. 'It is characterized by having done it. .. EFFECT OF THE INVENTION;: According to the present invention having the characteristics as described above, the following excellent effects are exhibited.
- FIG. 1 is an overall configuration diagram showing an organic matter-containing waste pyrolysis method and apparatus and pyrolysis gasification system according to the present invention. '...'.
- FIG. 2 is a flowchart representing the operation procedure of the pyrolysis method and apparatus and the pyrolysis gasification system for organic substance-containing waste according to the present invention.
- FIG. 3 is a longitudinal sectional view (a) and a left side view (b) of the pyrolysis heating section of the sealed chamber.
- Fig. 4 is a schematic diagram showing the inert gas flow in the sealed chamber due to the reciprocating motion of the reciprocating device pusher plate. ⁇ '' +
- Embodiments of the pyrolysis method and apparatus for organic matter-containing waste and pyrolysis gasification system according to the present invention will be described with reference to the drawings.
- the overall configuration of the example is shown in FIG. 1, and the operation procedure is shown by the pro chart in (2).
- the embodiment of the present invention shows a heat decomposing means or apparatus by electromagnetic induction.
- the thermal decomposition in the present invention is not limited to the electromagnetic induction means or apparatus.
- the heating air or gas, or means for directly heating the thermal decomposition apparatus itself with a gas burner or the like. Can also be included.
- FIG. 1 is a conceptual diagram as well as an overall configuration diagram.
- Waste containing organic matter 1 such as medical waste is sent to the crushing device from the outside by a conveyor, etc., cut, and then molded in a solidification molding device via a drum-type drying device, for example.
- the demolition equipment, drying equipment, and solidification molding equipment shown here contain organic matter-containing waste 1 or it may contain hazardous substances such as explosive or flammable.
- the sealed transfer path 2 leads to an input port 4 1 of an input device 4 of the closed chamber 3 described later.
- the end of the closed transport path 2 continues to the upstream side of the input device 4.
- the downstream side of the charging device 4 includes an inlet 4.1 to the sealed chamber 3.
- the input device 4 can be provided with a transfer chamber 4 2 for temporarily retaining the transferred organic substance-containing waste 1 into the sealed chamber 3 in order 5.
- the transfer chamber 4 2 can include a shutter device 43 having two upper and lower stages.
- the upper shutter device 4 3 1 and the lower shutter device 4 3 2 have shutters that are alternately closed by a shutter or the like.
- the organic 3 ⁇ 4-containing waste 1 that has passed through the hermetic transfer path 2 temporarily stays in the transfer chamber 42 composed of an open upper shutter and a closed lower shutter. Next, close the upper shutter 4.3 10 '1 to the lower shutter?
- the organic matter-containing waste 1 can be put into the sealed chamber 3 through the inlet 4 1 by opening the filter 4 3 2 ′.
- the sealed chamber 3 is connected to the sealed conveyance path 2. It is possible to maintain a tightly sealed space.
- FIG. 3 is a cross-sectional view and a side view of the electromagnetic induction heat dissociating and heating unit 31 constituting a part of the sealed chamber.
- the upstream side of the sealed chamber 3 is reciprocated between the inlet 41 of the organic matter-containing waste 1 and the inner portion of the sealed chamber 3 by means of an actuator, etc.
- the pusher plate 5 of the return device 5 is provided with an inert gas injection port 6 1, which will be described later, on the uppermost stream side of the back surface of the reverse device 5. It is done.
- the push-in position of the pusher plate 5 i.e.
- the pusher plate 5 1 of the reciprocating device 5 has an outer circumference that substantially matches the cross-sectional shape 'of the sealed chamber 3, and passes through the front and back surfaces that allow the inert gas sent to the sealed chamber 3 to flow in and out.
- an inert gas communication device 5 2 including a plurality of communication holes 5 1 1 can be provided. Specifically, as shown in the schematic diagram of FIG. 4, the inert gas sent into the sealed chamber 3 by the inert gas injection device 25 is moved forward by the pusher plate 51 of the reciprocating device 5.
- the pusher plate communication hole 5 1 1 gradually flows into the rear of the pusher plate through the communication device 5 2, and the pusher plate 5 1 of the reciprocating device 5 moves in the reverse stroke of the pusher plate 5 1. It is possible to gradually flow into the front of the pusher plate 51 through the communication device 5 2 including the communication hole 5 1 1.
- the communication device 5 2 shown in the schematic diagram of FIG. 4 is composed of one or a plurality of communication holes 5 1 1 penetrating the front and back of the pusher plate 5 1, but is not limited to this configuration. Closed chamber so that it flows into the rear of the pusher plate 51 with the forward stroke of the pusher plate 51 and flows into the front of the pusher plate 51 with the backward stroke of the pusher plate 51.
- the pressure gradient formed by the inert gas sent to 3 can be maintained, for example, the pusher plate 51 of the reciprocating device 5 and the forward position of the backward stroke.
- a communication passage having a communication hole on the inner wall at the retracted position can be provided on the outer wall of the sealed chamber, and the communication device 52 that allows inflow and outflow of inert gas through the gas communication passage can be provided.
- the above-described inert gas injection device 6 is a tank that stores a gas such as nitrogen (N 2 ) or argon (A r). 'With the pipe having the valve, the inert gas is fed through the inert gas inlet 61 on the uppermost stream side of the sealed chamber 3 and the pipe having the pulp also in the transfer chamber 42 described above. It is also possible to send an inert gas through the inert gas inlet 6 2.
- a gas such as nitrogen (N 2 ) or argon (A r).
- the reciprocating motion of the pusher plate 51 also causes a communication device 5.2 comprising the communication hole 5 1.1 provided in the pusher plate 51 to
- a communication device 5.2 comprising the communication hole 5 1.1 provided in the pusher plate 51 to
- an inert gas can flow in and out, and an inert gas pool or an inert gas atmosphere 63 can be formed and maintained in the sealed chamber 3.
- the inert gas atmosphere 6 3 such as New '2 or A r which is formed inside the sealed chamber 3 in order to ⁇ , at least closed chamber 3 of inlet .4 1 of the closed freely conveying chamber 4 2, Close to the inert gas inlet 61 on the upstream side of the closed chamber 3, one of the upstream side of the pyrolysis heating unit 3 1 of the sealed chamber 3 and the downstream side of the pyrolysis heating unit 3 1 of the sealed chamber 3 Gas pressure sensors .6 4 1, 6 4 2, 6 4 3, 6 4 4 (collectively 6 4) need to be provided at appropriate positions.
- the inert gas reservoir or inert gas atmosphere 6 3 into which the organic substance-containing waste 1 on the upstream side where thermal decomposition is started as described later is introduced.
- Pressure, pressure plate of reciprocating device 5 and pressure of mixed gas of pyrolysis gas and inert gas generated with advance stroke of 1, and gas pressure of mainly pyrolysis gas at the downstream side where pyrolysis is completed can be monitored.
- the inert gas injection device 6 can control the amount of inert gas fed into the transfer chamber 4 2 and the sealed chamber 3 in conjunction with these gas pressure sensors 6 4 1 to 6 4 4. it can. .
- the pyrolysis gas generated by the pyrolysis reaction of organic matter-containing waste 1 is exhausted.
- An exhaust hole 71 connected to the gas recovery device 7 and an exhaust port 81 connected to the discharge device 8 for recovering the carbide that is the residue of the pyrolysis reaction of the organic matter-containing waste 1 are provided.
- Pyrolysis gas recovery device 7 and residue carbide discharge device 8 Details of this will be described later.
- a shutter device for preventing the inflow of outside air is appropriately provided in the vicinity of the exhaust hole 71 and the exhaust outlet 8.1.
- one of the features of the present invention is as follows. Such a device is not necessarily required.
- the pyrolysis heating unit 31 by electromagnetic induction is formed between the upstream side and the downstream side of the sealed chamber 3.
- the pyrolysis heating unit 3 1 consists of a cylindrical container 3 1 1 made of a conductive material that generates heat by electromagnetic induction heating, and its outer periphery is covered with a heat insulating material 3 1 '2.
- the coil support members 3 1 4 provided on both ends of the outer periphery of the cylindrical container 3 1 1 can support the electromagnetic induction heating coil 3 1 3 wound around the outer periphery of the heat insulating material 3 1 2 .
- a cooling pipe in which coolant such as cooling water circulates on the electromagnetic induction heating unit 3 1 3 (referred to as “water jacket”) 3 '1 5 is wound, and the cooled cooling pipe 3 .1
- a support member 3 1 6 is provided to support 5 in the longitudinal direction of the cylindrical container 3 1 1.
- ⁇ retirement cooling Bruno drive 3 1 5 'to the supply pump device and providing the high frequency power source for supplying a current to the electromagnetic induction coil 3 1 3 course water.
- the high frequency power supply connection terminal position 3 17 shown in FIG. 3 is the terminal position with the electromagnetic induction coil 3 13.
- the cylindrical container 3 1 1 is connected to the electromagnetic induction coil 3 for cleaning the inside of the sealed chamber 3 by releasing the coil support members 3 1 and '3.16. It is also possible to design it so that it can be divided into 1 and 3 in two.
- Mounting bolt position 3 1 8 is the joint between the cylindrical vessel 3 1 1 and the upstream side of the sealed chamber 3
- mounting bolt position 3 1 9 is the joint between the cylindrical vessel 3 1 1 and the downstream side of the sealed nitrogen 3.
- thermocouple temperature sensor 3 2 0 penetrating the material 3 1 2 can be appropriately provided in the cylindrical container 3 1 1.
- the pyrolysis heating unit 3 1 is composed of a cylindrical container 3 1 1, a heat insulating material 3 1 2 and a water jacket 3 1 5, so that the cylindrical container 3 1 1 is electromagnetically induced from 5 0 0 to 1 0 0 0 Even when heated to ° C, the outer peripheral temperature of the pyrolysis heating unit 31 can be kept at about 40 ° C, so combustion or even combustion explosion due to inflow of outside air into the cylindrical container If it can be controlled, there will be no operational safety or fire hazard.
- the gas pressure of the inert gas sent using the inert gas injection device 6 is set to exceed at least atmospheric pressure, the outside air is shut off, and the sealed chamber 3 is Anoxia can be achieved. Furthermore, it is generated by thermal decomposition in the sealed chamber 3 and gradually increases.
- the gas pressure of the pyrolysis gas and the gas pressure of the inert gas sent from the upstream side of the sealed chamber 3 are balanced from the upstream side of the sealed chamber 3 so that they are balanced at least downstream of the sealed chamber 3.
- a pressure gradient of the inert gas to the side is formed, and the pyrolysis gas is exhausted from the sealed chamber 3 without backflowing from the lower side to the upper side. The amount of feed can be controlled.
- the continuous pyrolysis of the organic matter-containing waste 1 put into the sealed chamber 3 and sequentially sent to the pyrolysis heating unit 3 1 is performed by the inert gas injection device 6 inside the sealed chamber 3.
- the gas pressure PN of the inert gas upstream of the sealed chamber 3 PN and the mixed gas pressure of the inert gas and pyrolysis gas of the pyrolysis heating unit 3 PG and mainly the pyrolysis gas downstream Gas pressure P.H, but atmospheric pressure P.H. This creates a pressure gradient of inert gas that exceeds the flow rate, which prevents the backflow of pyrolysis gas from the downstream side to the upstream side in the sealed chamber.
- the exhaust can be recovered. ⁇ .
- the generated pyrolysis gas is recovered by the exhaust recovery device 7 through the exhaust hole 71. More specifically, the air is turned ⁇ .
- the decomposed gas passes through the exhaust hole 71 and the gas induction pipe 72 and is cooled by cooling water at the outer periphery. It is sent to the oil and water device 7 4 via the cooling device 7 3. 'Here it is separated into oil and water, then by the exhaust fan 7 6', the residual pyrolysis gas is sucked from the oil / water separator 7 4 to the mist separator 7 '5 and then washed here Exhausted outside.
- the liquefied product separated by the oil / water separator 74 and recovered by the recovery device has a calorific value similar to that of heavy oil, and can be reused as fuel for the drying device described above, for example.
- the residual carbides from the pyrolysis reaction are recovered by the discharge device 8 via the discharge port 8 1.
- the discharge device 8 includes a horizontal cylindrical cooling device 8 2 and a container type recovery device 8 3. Cylindrical cooling device 8 2 has an upstream side that is connected to discharge port 8 1 of sealed chamber 3. It is designed to be discharged from the discharge port 8 2 2 provided on the side to the container type recovery device 8 3. Residual carbides are scattered .
- the recovered carbide has a calorific value similar to that of coal, and can be recycled as solid fuel.
- the inert gas force S is sent to the sealed chamber 3 via the inert gas injection 61, and the sent inert gas is sealed by the communication device 5 2 consisting of the communication holes 5 1 1 to 15. It flows into the downstream side of the chamber 3 and expels the air in the sealed chamber, and an inert gas atmosphere is formed inside the sealed chamber.
- the upper stage of the transfer chamber 4 2 is closed and the lower stage shutter is opened.
- T Inert gas sent from the inert gas inlet 6 2 flows into the sealed chamber 3 of the inert gas atmosphere. Inert gas'. A puddle is formed.
- the accumulated organic matter-containing waste 1 is put into the inert gas reservoir formed in this way.
- the introduced organic matter-containing waste 1 is sent to at least the pyrolysis heating section 31 by the forward stroke of the pusher plate 51 of the reciprocating device 5. .
- the plastic contained in the organic matter-containing waste 1 becomes pyrolysis gas, and paper and fibers become carbide.
- the upper shutter of the transfer chamber 4 2 was closed and the lower shutter was opened in an inert gas pool or inert gas atmosphere in the sealed 25 chamber 3 until the thermal decomposition reaction occurred.
- the gas pressure of the inert gas in the transfer chamber 42 is sent via the inert gas inlet 61 by the inert gas sent via the inert gas inlet 62.
- the gas pressure in the sealed chamber 3 is monitored using the, and in conjunction with each other, the inertness is controlled.
- the amount of inert gas delivered from the gas injection device 6 to the sealed chamber 3 is controlled. . This makes it possible to ensure that the gas pressure inside the sealed chamber 3 always exceeds the atmospheric pressure, and at the same time forms a pressure gradient of the inert gas from the upstream side to the downstream side of the sealed chamber. It's also possible.
- Organic matter-containing waste 1 sent via the closed transfer path 2 is partitioned by the two-stage shutter device 4 3.
- the transfer chamber 4 2 is put into the closed chamber 3 sequentially while staying temporarily,
- the organic material-containing wastes 1 that are sequentially fed are sequentially fed to the decomposition heating unit 31 of the sealed chamber 3 by the reciprocating motion of the pusher plate 51 of the reciprocating device 5.
- the generated pyrolysis gas is surely sent into the exhaust hole 71 due to the pressure gradient of the inert gas formed inside the sealed chamber 3.
- Residual carbides can also be discharged by extending the forward stroke of the pusher plate 52 to the vicinity of the discharge port 81, for example. In addition to this, it is also possible to provide a separate discharge device.
- waste containing organic matter can be continuously thermally decomposed with almost no air pollutants, and the heating temperature can be adjusted according to the nature and type of treatment ⁇ ;. is there. : ⁇
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Abstract
Description
明細書' 有機物含有廃棄物の熱分解方法および装置並びに熱分解ガス化システム 5 技術分野 ' Description 'Pyrolysis method and apparatus for organic-containing waste and pyrolysis gasification system 5 Technical field'
本発明は、 有機物含有廃棄物の連続的熱分解方 ¾および装置並びに i分解ガス化システム に関し、 より具体的には、 熱分解加熱部を形成した密閉室に、 常に大気圧を上回るように不 活性ガスを送込むことにより外気を ¾断し、 いわゆる限界酸素濃度以下の^酸素状態で有機 : 物含有廃棄物を熱分解する,方法および装置並びに熱分解ガス化システムに関する。 The present invention relates to a continuous pyrolysis method and apparatus for waste containing organic matter and an i-cracking gasification system. More specifically, the present invention relates to a sealed chamber in which a pyrolysis heating section is formed so as not to always exceed atmospheric pressure. The present invention relates to a method and apparatus, and a pyrolysis gasification system, which cuts outside air by sending an active gas and thermally decomposes organic: waste containing organic matter in an oxygen state below a so-called critical oxygen concentration.
10 . Ten .
背:!:技術 ' · Back :! : Technology
:限界酸素濃度とは、 継続的に可燃物を燃焼または燃焼爆発させるための必要最小限の酸素 濃度をいう。 この値以下の酸素 度であれば、 無酸素状態と同様に可燃物の燃焼または燃焼 爆発が起こらないので、 本発明において 、 この限界酸素濃度以下の状 を無酸素状態とい : The critical oxygen concentration is the minimum oxygen concentration required to continuously burn or explode combustible materials. If the oxygen level is less than this value, the combustion or combustion explosion of combustible materials does not occur as in the case of the oxygen-free state. Therefore, in the present invention, the state below this limit oxygen concentration is called the oxygen-free state.
; 15 う ノ + · ; 15
熱^解'とは、 以下の公知例から明ちかなように、'可燃物を通常は外気を遮断した状態で約' 5 0 0〜6 0 0 °pで加熱すると熱分解反応 促進され、 燃焼または燃焼爆発させることなく ' 熱分解ガ と残渣とにすることができる。 いわゆる可燃物の蒸し焼き状態である。 熱分解反, '応は、 キルンなどの加熱炉の外被をガスバーナーなどで加熱するかまたは 1 0 0 0 °C以 ±の : . 20 高温空気を外周に配送させる方法を用いて加熱炉自体を加熱し、 空気を絶った状態で加熱炉 ' 内部を' 5 0ひ。 C程度に加熱することによって実現することができる。 また、 電磁誘導を利用 して加熟することを誘導加熱または電磁誘導加熱という。.原理は > 導線に交流電流を流すと 周りに磁力線が発生する。 導線をコイル状に卷き中心線に沿って置かれた金属などの導電性 材料に渦電流が流れ、 導電性材料の電気抵抗によってジュール熱が発生し、 その金属自体を 25 加熱する。 この原理を採用して導電性材料からなる熱分 加熱部を形成し、 その内部におい て可燃物を無酸素状態で熱分解反応させる方法もある。 As it is clear from the following known examples, “thermal solution” means that when a combustible is normally heated at about 5 0 0 to 6 0 0 ° p with outside air blocked, the thermal decomposition reaction is promoted, It can be made into pyrolysis gas and residue without burning or burning. It is a so-called steamed and burned state of combustible material. Pyrolysis reaction, the heat furnace is heated using a method such as heating the outer jacket of a kiln or other furnace with a gas burner or the like, or delivering high-temperature air to the outer circumference. Heat itself and heat the furnace in the out-of-air condition. It can be realized by heating to about C. In addition, ripening using electromagnetic induction is called induction heating or electromagnetic induction heating. The principle is> When an alternating current is passed through a conductor, magnetic lines of force are generated around it. An eddy current flows through a conductive material such as a metal that is coiled along a center line, and Joule heat is generated by the electrical resistance of the conductive material, which heats the metal itself. There is also a method of adopting this principle to form a heat-heating part made of a conductive material, in which a combustible material is thermally decomposed in an oxygen-free state.
都市ごみ、 産業廃棄物、 特に医療廃棄物などは有機材料を含有しており、 焼却炉などによ る燃焼によって塩素ガスや許容以上のダイォキシンを発生させることにもなる。 1 9 9 4牟 の焼却 H¾灰の特別管理廃棄物指定や 1 9 9 7年の第 2次のダイォキシン類の抑制ガイドライ 30 ンなどの環境' .公害に関する規制の強化にともなって、 例えば、 医療機関においては自前の 焼却炉を閉鎖ないし廃棄し、 医療廃棄物処理業者に医療廃棄物が入ったプラスチック容器毎 引き取 せて処理をし'ているのが現状である。 そのため、 プラスチック容器を細かく荦断し 高周波加熱などによる滅菌処理を施'し、 圧縮梱包後の埋め立てや加熱分解処理する技術およ .びノまたはシステムなどが実用化され、 公知技術化している。 Municipal waste, industrial waste, especially medical waste, etc. contain organic materials. Combustion in an incinerator or the like can generate chlorine gas and unacceptable dioxin. Incineration of 1 9 9 4 牟 H¾ Ash special management waste designation and environment such as 1 9 9 7 secondary dioxin control guidelines 30. With increasing regulations on pollution, for example, In a medical institution The current situation is that the incinerator is closed or discarded, and the plastic container containing the medical waste is collected and processed by the medical waste disposal contractor. For this reason, a technique and a system or the like for pulverizing a plastic container and performing sterilization treatment by high-frequency heating or the like to perform landfill or compression decomposition after compression packaging have been put into practical use.
従来技術についてみると、 特^平 7— 3 2 3 2 7 0号公報には、 開口部が熱分解物によつ てマテリアルシーリングされ、 それに続く気密状の熱分解菅に沿う加熱外被にガスバーナー. によって 2 5 0〜5 0 0 °Cに熱分解菅を加熱し、 その内部で廃棄物を熱分解する装置が f己載 されている。 同じく特許 3 3 7 7 3 9号公報に記載 装置は、 横向き加熟ドラムの下流側 ' に設けた燃焼溶融炉内の空気加熱器で生成された熱風を加熱ドラムめ外周に供給し、 加熱ド . ' ラム内で被燃焼物を熱分解させる.ものであって、 空気に代わる不活性ガスの 入により加熱 ドラム内を低酸素状態のまま大気圧近くに,推持するようにした特徴を有する。 次に、 電磁誘 導加熱による廃棄物め熱分解方去および装置についてみると、 特開平 1 0— 4 3 7 1 4号公 ' 報には、 閉容器に廃棄物を充填し、 その容器毎に電磁誘導加熱源に挿入して、 外気を完全 に遮断して廃棄物を蒸し宪き状態にする.ことで I棄物中の塩素成分を効果的に抽出できるよ うにしたものが記載されている。 特開 2 0 0 .3— 1 4 2 1 6号公報には、 電磁誘導加熱によ , る熱分^反応.のための電磁誘導加熱ドラムに関する.ドラム内雰囲気が発生した熱分解ガス.を . 抜気ポンプの吸引によって抜気し、 ほぼ真空状態 (無酸素状態の雰囲気) にし、 ジュー 熱 で加熱したドラム Λで廃棄 を熱分解反応させるもの 記載されてい 。 .具体的 は、 加熱 '. ドラムは、 廃棄物の取入口および排,出口、 熱分解ガスの排気孔の各々に密閉自在シャッ ー, を設け、 ドラム外からの大気の流入を阻止する。 ドラム内は気 ¾状態に維持され、 投入され た廃 ¾物がスクリユーコンベアで移送されながら無酸素状態で熱分解反応する.ことができる ' ように、取入口および排出口のいずれか一方を交互に開閉自在'とする 2重シャッター装置と、 内部の気圧を低くするための抜気口とが別途設けられている。 同系列の特許文献としては、 特開 2 0 0 5—1 2 7 6 8 0号公報、 特開 2 0 0 5— 1 2 7 6 8 2号公報、 特開 2 0 0 4— 2ひ 9 3 3 9号公報を挙げることができる。 これらの 許文献に開示された電磁誘導加熱装 置は、 粉砕 ·乾燥部、 加熱部および冷却部を 1つの横向き ドラム状燃焼室の前後に乾燥部お よび冷却部を配する構造か、 または各部に取入口および排出口を有する複数段の横向き ドラ ム状燃焼室を設け、 前段燃焼室の排出口と後段燃焼室の取入口とを着脱可能とした構造かの いずれかである。 後者の場合、 被燃焼物の誘導加熱部への搬入および排出を前処理乾燥工程 および後処理冷却工程とする構造であれば、 いずれの構造のものも可能である。 少なく とも 電磁誘導加熱部は、 外壁を断熱材および Zまたはウ^ータ ·ジャケッ卜で覆い、 その周壁を 交流電流が流れる導線をコイル状に卷き、 2重シャッターを有する取入口および排出 pを両 端部に少なくとも設けた導電性材料からなる横向きドラム状燃焼室構造であり、 必要に応じ て軸線の周りに回転自在とすることもできる。 さちに燃焼室内の被燃焼物の攪拌機能を高め るべくスクリューコンベアを採用し回転軸上に攪拌バトルを配するかドラム内壁にコルクス クリュー状羽などを配することもできる。 Regarding the prior art, Japanese Patent Publication No. 7-3 2 3 2 70 discloses that the opening is material-sealed by pyrolyzate, and the heating envelope that follows the hermetic pyrolyzed soot. The gas burner is equipped with a device that heats the pyrolysis soot to 2500-500 ° C and pyrolyzes the waste inside. Similarly, the device described in Japanese Patent No. 3 3 7 7 3 9 supplies hot air generated by an air heater in a combustion melting furnace provided on the downstream side of a laterally-oriented ripening drum to the outer periphery of the heating drum. '' Pyrolyzes the combustibles in the ram, and has the feature that the heated drum is held near the atmospheric pressure in a low oxygen state by the introduction of an inert gas instead of air. . Next, regarding the pyrolysis method and equipment for waste by electromagnetic induction heating, the publication of Japanese Patent Laid-Open No. 10-4 3 7 1 4 discloses that each container is filled with waste. It is inserted into an electromagnetic induction heating source to completely block out the outside air and make the waste steamed, so that the chlorine component in the waste can be extracted effectively. Yes. Japanese Laid-Open Patent Publication No. 20.3-1 4 2 16 relates to an electromagnetic induction heating drum for a heat reaction caused by electromagnetic induction heating. It is described that the air is evacuated by the suction of the evacuation pump, is brought into a nearly vacuum state (oxygen-free atmosphere), and the waste is pyrolyzed with a drum Λ heated with juicy heat. Specifically, heating '. The drum is provided with a sealable shutter at each of the waste intake and exhaust, the outlet, and the pyrolysis gas exhaust hole to prevent inflow of air from outside the drum. The inside of the drum is kept in a gas state, and the waste product that has been input is transported by a screw conveyor and can undergo a thermal decomposition reaction in an oxygen-free state. A double shutter device that can be opened and closed alternately, and an air vent for lowering the internal pressure are provided separately. Patent documents of the same series include Japanese Patent Application Laid-Open No. 2 0 0 5-1 2 7 6 8 0, Japanese Patent Application Laid-Open No. 2 0 0 5-1 2 7 6 8 2, and Japanese Patent Application Laid-Open No. 2 0 0 4-2 9. 3 3 9 publication. The electromagnetic induction heating device disclosed in these licensed documents has a structure in which a crushing / drying unit, a heating unit, and a cooling unit are arranged in front and behind a single drum-shaped combustion chamber, or each unit One of the structures is a structure in which a plurality of horizontally-facing drum combustion chambers having intakes and discharge ports are provided in the front, and the discharge ports of the front combustion chamber and the intake ports of the rear combustion chamber are detachable. In the latter case, any structure can be used as long as the preheating process and the postprocessing cooling process are used to carry in and discharge the combustibles into the induction heating unit. at least The electromagnetic induction heating unit has an outer wall covered with a heat insulating material and Z or a water jacket, and the surrounding wall is coiled with a conducting wire through which an alternating current flows. It is a horizontal drum-shaped combustion chamber structure made of a conductive material provided at least at the end, and can be freely rotated around an axis as necessary. In addition, a screw conveyor can be used to enhance the stirring function of the combusted material in the combustion chamber, and a stirring battle can be arranged on the rotating shaft, or a cork screw blade can be arranged on the inner wall of the drum.
次に、'特開 2 0 0 5— 8 3 7 1 .8'号公報に記載された加熱 ラム内における不活性ガス (又 は流体). .の置換および気密性の維持方法および装置に いてみると、 上記 た特開平 1 0— 4 3 7 1 3号公報に記載さ.れた、 完全に大気を遮断した開閉自在の密閉蓋を有する密閉室に '配した加熱筒に被燃焼物を投入し、 加熱筒の.電磁誘導加熱により被燃焼物を蒸し焼き状態に して被燃焼物に含まれる塩素成分をガス化させることなく塩素または塩素化合物 して処理 きるようにした被燃焼物の処 ¾方法と同様に、 大気を遮断しつつ被燃焼物の電磁誘導加熱 ' .によるバツチ処理.をよ'り効率的な処理できるように、 開閉自在な密閉蓋に代えて上蓋と底蓋 を交互に開閉自在にした 2重シャッター 有する被燃焼物の投入ホッパーを設け、 かつ被燃 焼物の燃埤にともなう可燃性ガスの燃焼または燃焼爆発させないように、 投入ホッパーと密 閉室 の'内部を不活性ガス雰囲気に置換する方法が開示されている。 開示された装脣は、 投 入ホッパーと密閉室と密閉室に配した加熱筒が縦型に配されており、 それらの外部に設けた 不活性ガス貯蔵タンクから 管によってそれぞれに連 ffiさせバルブを介し^活性 'ス流量を '調整できるようにしたものである。 ^体的には、 不活性ガス貯蔵タンクからバルブを介し不 活性ガスを投入ホッパーおよび密閉室に連通させる。 投入ホッパーおよぴ密 .室において被 燃 ¾杨から発生したガスをそれぞれのバルブを介し排ガス処理施設に連通させ排出する。 そ の際に、 可燃性ガスが発生するので、 事前に投入ホッパーおよび.密閉室に酸素濃度センサー を配し、 酸素(大気)と窒素 (N 2 ) などの不活性ガスとの置換状態を常に監視できるように している。 さらにまた、 同文献においては被燃焼物の燃焼温度の上昇にともない発生ガス量 が増加するが、 密閉室内への大気の流入を抑えるべく密閉室内を大気圧より若干高い圧力に 保たせるように不活性ガスの流量を初期段階で多くし、 発生ガス量の増加にともない僅かな 流量で間に合うようにするこども開示されている。 但し、 こうした密閉室内の処理は一回毎 に解除と設定とを繰返さなければならない。 ところで、 不活性ガスによる廃棄物の燃焼環境 の形成は、 これ以外にも様々な方法および装置が提案されている。 例えば特開平 6— 2 8 1 3 6 2号公報に記載されているように、 半導体製造におけるリフローのような熱処理は、 本 . Next, there is a method and apparatus for replacing inert gas (or fluid) in a heating ram and maintaining airtightness described in 'JP 2 085-8 3 7 1.8'. As can be seen, the burned material is placed in a heating cylinder arranged in a sealed chamber having an openable / closable sealing lid that completely shuts off the atmosphere as described in JP-A-10-4 3 7 1 3 above. Dispose of the combusted material that has been treated as chlorine or a chlorine compound without gasifying the chlorine component contained in the combusted material by steaming the combusted material by electromagnetic induction heating in the heating cylinder. ¾ Similar to the method, the top cover and bottom cover are alternately used in place of the openable / closable sealing lid so that the batch processing by electromagnetic induction heating of the combusted material can be performed efficiently while blocking the atmosphere. An open hopper for combustibles with a double shutter that can be opened and closed freely, and for burning combustibles So as not to burn or combustion explosion Nau combustible gas, a method of replacing the 'inside of the input hopper and dense closed from the inert gas atmosphere is disclosed. The disclosed equipment has an injection hopper, a sealed chamber, and heating cylinders arranged in the sealed chamber arranged in a vertical shape. Valves are connected to each other by pipes from an inert gas storage tank provided outside them. It is possible to adjust the 'active flow rate' through the. Physically, the inert gas is communicated from the inert gas storage tank through the valve to the charging hopper and the sealed chamber. The gas generated from the combustible gas in the charging hopper and closed chamber communicates with the exhaust gas treatment facility via each valve and is discharged. At that time, flammable gas is generated, so an oxygen concentration sensor is placed in advance in the charging hopper and the sealed chamber, and the replacement state of oxygen (atmosphere) and inert gas such as nitrogen (N 2 ) is always maintained. It can be monitored. Furthermore, in this document, the amount of generated gas increases as the combustion temperature of the combusted material increases, but it is not possible to keep the sealed chamber at a pressure slightly higher than the atmospheric pressure in order to suppress the inflow of air into the sealed chamber. It is also disclosed that the flow rate of the active gas is increased at the initial stage so that the flow rate can be met with a small flow rate as the amount of generated gas increases. However, such treatment in the sealed room must be released and set repeatedly each time. By the way, various methods and apparatuses have been proposed in addition to this for the formation of a combustion environment of waste by an inert gas. For example, as described in JP-A-6-2 8 1 3 6 2, heat treatment such as reflow in semiconductor manufacturing is .
来不活性ガス雰囲気炉内での処理であり、 被 理物め出入口に不活性ガスを含むガス膜を开 成し炉内雰囲気と炉外雰囲気とを完全遮 する方法が採用されている。 その中には、 出入口 のそれぞれに'一定の距離をおいて不活性ガス膜を形成する 2重ゲートなども含まれるものと して特許 2 6 3 5 4 5 9号公報 記載のものが挙げられる。 この他にも、 爆発性または引火 性処理対象物の焼却処理装置において不活性ガスで常時封入させる装置に関する提案として、 上記した特許 3 3 7 7 3 5 9号公報およぴ特開 2 0 0 5 - 2 0 7 6 8 4号公報を挙げること ができる。 特に後者は、 例えば廃棄物を大気に曝さないような、 または、 作業者が接触する 恐れがないような取扱の大変難しい 療系廃棄物の処¾を含むものでもある。 This is a treatment in an inert gas atmosphere furnace, and a method is adopted in which a gas film containing an inert gas is formed at the inlet and outlet of the workpiece to completely block the atmosphere inside and outside the furnace. Among them are those described in Japanese Patent No. 2 6 3 5 4 5 9 that include a double gate that forms an inert gas film at a certain distance at each of the entrances and exits. . In addition to the above, as a proposal regarding an apparatus that always encloses with an inert gas in an incineration processing apparatus for an explosive or flammable processing object, the above-mentioned Japanese Patent No. 3 3 7 7 3 59 and Japanese Patent Laid-Open No. 20-320 No. 5-2 0 7 6 8 4 can be mentioned. In particular, the latter includes treatment of medical waste that is very difficult to handle, for example, so that the waste is not exposed to the atmosphere or the worker is not likely to come into contact with it.
ざらに、 医療廃棄物処理方法おょぴ装置として開示された被燃 の前処理方法および装 置に関する提案として特表 2 0 0 .2— 5. 1 6. 7 2 0号公報には、 減菌処理な 事前の粉碎ぉ · よび Zまたは加熱処理であっても出入口を複数のエアロックを用いて完全に大気と遮断しだ 乎備的 理室で行う医療廃棄物^理である。 また。 同文献では、 加熱処理により発生する汚 染空気を 洩および Z'または逆流させないように処理室内を負圧状態に保つエアフィルタを 装備した大型ファン装置も開示されている。 In addition, as a proposal for a pretreatment method and apparatus for burned flames disclosed as a medical waste treatment method and an optoelectronic device, Japanese Patent Publication No. 20.2-5. 1 6. 7 20 It is a medical waste treatment in a fully equipped laboratory where the entrance / exit is completely shut off from the atmosphere by using multiple airlocks, even with prior powder and Z or heat treatment. Also. The document also discloses a large fan device equipped with an air filter that keeps the processing chamber in a negative pressure state so that the polluted air generated by the heat treatment does not leak and Z ′ or backflow.
(特許文献: 1 ): 特開平 7 ― 3 2 3 2 7 0号公報 ·: (Patent Document: 1): Japanese Patent Application Laid-Open No. 7-3 2 3 2 70
(特許文献 2 ): 7 7 3 5 9号^報 (Patent Document 2): 7 7 3 5 9 ^
(特許文献 3 ) · '特開平 1 0 ― 4 3 7 1 4号公報 (Patent Document 3) · 'JP 10-4 3 7 1 4
(特許文献 4 ). 特開 2 0 0 3一 1 4 2 1 6号公報 (Patent Document 4). Japanese Patent Laid-Open No. 2 0 0 3 1 4 2 1 6
(特許文献 5 ) 特開 2 0 0 5一 1 2 .7 6 8 0号公報 (Patent Document 5) Japanese Patent Laid-Open No. 2 0 0 5 1 12 7 6 80
(特許文献 6 ) 特開 2 0 0 5 — 1 2 7 6 8 2号公報 (Patent Document 6) Japanese Patent Laid-Open No. 2 0 0 5 — 1 2 7 6 8 2
(特許文献 7 ) 特開 2 0 0 4 - 2 0 9 3 3 9号公報 (Patent Document 7) Japanese Patent Laid-Open No. 2 0 0 4-2 0 9 3 3 9
(特許^:献 8 ) 特開 2 0 0 5一 8 3 7 1 8号公報 (Patent ^: 8) Japanese Patent Laid-Open No. 2 0 0 5 1 8 3 7 1 8
(特許文献 9 ) 特開平 6 ― 2 8 1 3 6 2号公報 (Patent Document 9) Japanese Patent Laid-Open No. 6-2 8 1 3 6 2
(特許文献 1 0 ) 特許 2 6 3 5 4 5 9号公報 (Patent Document 10) Patent 2 6 3 5 4 5 9
(特許文献 1 1 ) 特開 2 0 0 5一 2 0 7 6 8 4号公報 (Patent Document 1 1) Japanese Unexamined Patent Publication No. 2 0 0 5 1 2 0 7 6 8 4
(特許文献 1 2 ) 特表 2 0 0 2一 5 1 6 7 2 0号公報 有機物含有廃棄物を焼却炉などで燃焼加熱をすると、 発生する汚染物質やダイォキシンな どの有毒ガスの発生は避けられない。 汚染物質の除去および有毒ガス排出を抑制するための . 解決手段の一つが無酸素状態での加熱分解を可能に る方法おょぴ装置の'開発である。 その ことにより、 一酸化炭素、 ダイォキシンなどを含む有毒ガスの発生を抑制するとともに、 併 せてウイルスおよぴ病原菌などの汚 ¾物質を除去することもできる。 ところが無酸素状態の .形成は容易ではない。 有機物含有廃棄物の熱分 '室を抜気による真空またはほぼ真空状態に 形成するか、 形成された真空またはほぼ真空状態に不活性ガスなどを導入させることなどが 提案されている。 有機含有廃棄物の熱分解室を真空またはほぼ真空状態に形成する技術的課 題は、 処理室内を負圧状態にする ^外気流入環境となるため、 廃寧物の投入口、 排出口およ ぴ排気孔などの大気との接点に完全な遮蔽手段を採用しなければならない。. (Patent Document 1 2) Special Table 2 0 0 2 1 5 1 6 7 2 0 Publication When organic waste is burned and heated in an incinerator, the generation of toxic gases such as pollutants and dioxin is avoided. Absent. To remove pollutants and control toxic gas emissions One of the solutions is the development of a method and apparatus that enables thermal decomposition in the absence of oxygen. As a result, generation of toxic gases including carbon monoxide and dioxin can be suppressed, and at the same time, contaminants such as viruses and pathogenic bacteria can be removed. However, the formation of anoxic conditions is not easy. It has been proposed to form a heat chamber for waste containing organic matter in a vacuum or almost vacuum state by venting, or to introduce an inert gas or the like into the formed vacuum or almost vacuum state. The technical challenge of creating a pyrolysis chamber for organic-containing wastes in a vacuum or almost vacuum is to put the processing chamber in a negative pressure environment. A complete shielding means must be adopted at the point of contact with the atmosphere such as the exhaust vent. .
これまでに提示されている機械的シャッター、 エアロックまたはエアシャッター、 マテリ アルシーリング、 窒素 (N 2 ) などの不活性ガスによる置換方法などの手段によって加熱装 置の内部を大気と完全遮断することは極めて難しく、 より完全な.ものを求める場合には手段 も高価なものにならざるを得ない。 そこで次善の策として、 機械的およびエア手段における. . 2重 ャツ,ター構瑋ゃ内部を大気圧より高い不活性ガスの庄カ勾配を形成するようにした点 を含まない単なる不活性ガス雰囲気形成方法などを挙げることができる。 . The inside of the heating device must be completely isolated from the atmosphere by means such as mechanical shutter, air lock or air shutter, material sealing, and replacement with inert gas such as nitrogen (N 2 ). Is extremely difficult and more complete. If you want something, you have to be expensive. Therefore, as a next best measure, in mechanical and pneumatic means ... Double inert, simply inert that does not include the fact that the inside of the inner gas has a gradient of inert gas higher than atmospheric pressure. Examples thereof include a gas atmosphere forming method. .
さらなる技術的課題は、 熱分解により発生した熱分解ガスの漏洩および または逆流を防 • 止することである。 有機物含有廃 物の熱分解反応により発生する熱分解ガスの処理室がら .の漏洩および Zまたは逆流防止は、 有機物含有廃棄物の 理方法における汚染または有毒ガ スの処理室からの漏洩という観点から重要な技術的課題の一つである。 そのため、 従来技術 の多くは、 通常は出入口およ 排気孔の密閉性を保ちつつ室内の負圧状態を形成する とに! よって、 この技術的課題を克服してきた。 ところが、 こうした室内を負圧状態に形成するこ とは、 上記したように有機物含有廃棄物の熱分解室内を負圧状態にすることによって大気の 流入を完全に遮断することが困難になるという問題に直面す.ることにもなる。 トレードオフ 関係にあるこの 2つの課題を同時に解決することが求められる。 A further technical challenge is to prevent leakage and / or backflow of pyrolysis gas generated by pyrolysis. Leakage of pyrolysis gas generated from the pyrolysis reaction of waste containing organic substances and prevention of Z or backflow are considered from the viewpoint of contamination from organic substance-containing waste management methods or leakage of poisonous gas from the treatment room. It is one of the important technical issues. For this reason, most of the conventional technologies usually create a negative pressure in the room while maintaining the sealing of the entrance and exhaust holes! Thus, this technical challenge has been overcome. However, the formation of such a chamber in a negative pressure state has the problem that it becomes difficult to completely block the inflow of air by placing the pyrolysis chamber of organic-containing waste in a negative pressure state as described above. Will also face. It is necessary to solve these two issues in a trade-off relationship at the same time.
次なる技術課題は、 高分子材料を含む有機物含有廃棄物の加熱処理工程中に一時的に発生 する溶融および Zまたは粘性付着にともなう装置機能の低下を防止することである。例えば、 医療廃棄物処理など、 有機物含有廃棄物が充填されたプラスチック容器毎破砕する前工程を 含む熱分解または燃焼処理の場合に、 高分子材料が大量に含まれる被燃焼物は、 高温に曝さ れ溶融された粘性の高い高分子材料を含んだ状態で横向きのドラム状加熱室内を排出口へと 搬送されるため、 搬送手段として通常採用されているスクリューコンベアに溶融した粘性の ある高分子材料が付着蓄積することは避けられない。 このことによる装置機能の低下を回避 - しょうとすると、 かなりの頻度で装置全体を止め、 燃焼室内およびスクリューコンベア自体 を分解してクリーニングするしかない。 The next technical problem is to prevent the deterioration of the equipment function due to melting and Z or viscous adhesion temporarily generated during the heat treatment process of organic material-containing waste containing polymer materials. For example, in the case of thermal decomposition or combustion treatment that includes a pre-process of crushing plastic containers filled with organic matter-containing waste such as medical waste treatment, combustibles containing large amounts of polymer materials are exposed to high temperatures. Because it is transported through the horizontal drum-shaped heating chamber to the discharge port in a state of containing the molten high-viscosity polymer material, the viscous polymer material melted on the screw conveyor that is normally adopted as the transport means It is inevitable that adhesion accumulates. This avoids degradation of device functions -If you try to do so, you have to stop the entire system quite often and disassemble and clean the combustion chamber and the screw conveyor itself.
問題は、 有機物含有廃棄物の熱分^反応の連続性をどう維持するかである。 特に不活性ガ ,ス雰囲気を形成し大量の有機物含有廃棄物の処 をする場合、 始動時を除き通常運転時は連 続処理を前提としなければならない。 ところが、 上記したような技術的課題を^?決しつつ通 常運転時の連続処理を実現する手段はこれまでに提案されておらず、 そうした提案が待たれ ると.ころでもあった。 +' ■ ' ., ·. . . 発明の開示 . '. · · The question is how to maintain the continuity of the thermal reaction of organic waste. In particular, when an inert gas atmosphere is formed and a large amount of waste containing organic substances is to be processed, continuous processing must be assumed during normal operation except during startup. However, no means has been proposed to realize continuous processing during normal operation while solving the technical problems as described above, and such proposals could be awaited. + '■' .. Disclosure of the Invention '.
上述したような課題の解^;は、 上^側から投入された有機物含有廃棄物が熱分解され、 下 流側から発生した熱分解ガスが排気され、 且つ残渣の炭化物が排出される熱分解加熱部を上 流側と下流側との間に形成する密閉室に、不活性ガス注入手段を用 、て不活性ガスを送込み、 ' -密閉室^;不活性ガス圧力が大気圧を常に上回るようにし、 外気を遮断して前記密閉室を無酸 素状態にするとともに、 ¾生する熱分解ガスのガス圧力をも上回るように密閉室の上流側か. ら下流側に不活性ガスの圧力勾配を形成し、 熱分解ガスを下流側から上流側に逆流させるこ : となぐ密閉室から排気するようにレた有機物含有廃棄物を連続的に熱分解するという以卞の : .特徴を有する本発明に''よって達成すること.ができる。 . · '· ' · The solution to the above-mentioned problem is thermal decomposition in which organic-containing waste introduced from the upper side is thermally decomposed, pyrolysis gas generated from the downstream side is exhausted, and residual carbides are discharged. Use an inert gas injection means to feed the inert gas into the sealed chamber where the heating section is formed between the upstream side and the downstream side. And the outside air is shut off to make the sealed chamber oxygen-free, and the inert gas flows from the upstream side to the downstream side of the sealed chamber so as to exceed the gas pressure of the generated pyrolysis gas. Forming a pressure gradient and causing the pyrolysis gas to flow backward from the downstream side to the upstream side: The organic waste containing the waste is continuously pyrolyzed so as to be exhausted from the sealed chamber. It can be achieved by the present invention. .
' 請求の範囲 1に記載の発明は、 有機物含有廃棄物を熱分解ガスと残渣の炭化物とに連続的 '.に熱分解する方法であって、 流側から投入された有機物含有廃棄物が熱分解され、 下流側' .から発生した熱分解ガスが排気され、 且つ残渣の炭化物が排出される熱分解加熱部を上流側 と下流側:との間に形成する密閉室に、 不活性ガス注入手段を用いて不活性ガスを送込み、 密 閉室の不活性ガス圧力が大気圧を常に上回るようにし、 外気を遮断して前記密閉室を無酸素 状態にするとともに、 発生する熱分解ガスのガス圧力をも上回るように密閉室の上流側から 下流側に不活性ガスの圧力勾配を形成し、 熱分解ガスを下流側から上流側に逆流させること なく密閉室から排気するようにしたことを特徴とする。 The invention described in claim 1 is a method of thermally decomposing organic matter-containing waste continuously into pyrolysis gas and residual carbides, wherein the organic matter-containing waste introduced from the flow side is heated. An inert gas is injected into a sealed chamber that forms a pyrolysis heating section between the upstream side and the downstream side where the pyrolysis gas generated from the downstream side is exhausted and residual carbides are discharged. Inert gas is fed in by means of such that the pressure of the inert gas in the closed chamber always exceeds atmospheric pressure, the outside air is shut off to make the sealed chamber oxygen-free, and the pyrolysis gas generated A pressure gradient of the inert gas is formed from the upstream side to the downstream side of the sealed chamber so that the pressure is exceeded, and the pyrolysis gas is exhausted from the sealed chamber without backflowing from the downstream side to the upstream side. And
請求の範囲 2に記載の発明は、 有機物含有廃棄物の連続的熱分解方法であって、 a ) 上流 側から有機物含有廃棄物を受入れる投入口と、 下流側から有機物含有廃棄物の熱分解によつ て発生する熱分解ガスを排気する排気孔および残渣の炭化物を排出する排出口とを有し、 上 流側と下流側との間に熱分解加熱部を形成する密閉室に、 不活性ガス注入手段が不活性ガス を送込むことによって不活性ガス溜まりを形成し、 b ) 密閉室の投入口から不活性ガス溜ま . . The invention described in claim 2 is a method for continuous pyrolysis of waste containing organic matter, comprising: a) an inlet for receiving waste containing organic matter from the upstream side, and thermal decomposition of waste containing organic matter from the downstream side. Therefore, it is inactive in a sealed chamber that has an exhaust hole for exhausting the pyrolysis gas generated and an exhaust port for discharging residual carbides, and forms a pyrolysis heating section between the upstream side and the downstream side. An inert gas reservoir is formed when the gas injection means feeds the inert gas, and b) the inert gas reservoir is introduced from the inlet of the sealed chamber. ..
りに有機物含有廃棄物を順次投入し、 c ) 密閉室の断面形状にほぼ一致するプッシヤー板を 有する往復動手段によって、 不活性ガス^往復動する前記プッシヤー板の前後を移動できる 連通手段を介して不活性ガス溜まり I:維持しながら有機物含有廃棄物を密閉室の熱分解加熱 部に順次送込み、 d ) 密閉室に送込まれた不活 'Ιΐガスによって熱分解加熱部の有機物含有廃 棄物を無酸素状態で熱分解ガスと残渣の炭化物とに連続的に熱分解し、 e ) 密閉室に送込ま れた不活性ガスのガス圧力が常に熱分解ガスのガス圧力を上回るように密閉室に上流側から 下流側べの不活性ガスの氐カ勾配 形成することによって、 密閉寧の排気孔から熱分解ガス を回収し、 f ) 排出手段によって密閉室の排出口から残渣の炭化物を回収する工程を含み、 g ) 前記 a ) から f ) の一連の工程による有機物含有廃棄物の連続的熱分解は、.不活性ガス 注入手段によつて密閉室内に送込まれた不活性ガスのガス圧力 Pが常に大気圧 P。を上回る、 P〉P 0 . . ·' . ( 1 ) C) The waste containing organic matter is sequentially added to the container, and c) by means of reciprocating means having a pusher plate that substantially matches the cross-sectional shape of the sealed chamber, the inert gas can be moved back and forth through the pusher plate that reciprocates. Inert gas reservoir I: While maintaining, sequentially send waste containing organic matter to the pyrolysis heating section of the sealed chamber, and d) Waste containing organic matter in the pyrolysis heating section by the inert gas sent to the sealed chamber The waste is continuously pyrolyzed into pyrolysis gas and residual carbides in the absence of oxygen, and e) the gas pressure of the inert gas sent into the sealed chamber is always higher than the gas pressure of the pyrolysis gas. By forming a gas gradient from the upstream side to the downstream side of the inert gas in the sealed chamber, the pyrolysis gas is recovered from the sealed exhaust holes, and f) residual carbide is discharged from the outlet of the sealed chamber by the discharge means. Including recovery step, g) before Continuous thermal decomposition of an organic substance-containing waste through a series of steps from a) f) are. Always atmospheric P. gas pressure P of the inert gas incorporated sent to by connexion enclosed chamber in an inert gas injection means P〉 P 0 ... '' (1)
すなわち、 密閉室に不活性ガスによる正圧状態が形成されており、 そのことによ 'り、 密閉室 への大気の^入を遮断して無酸素状態でなされるとともに、 密閉室の不活性ガスのガス圧力 が熱分解によって発生する熱分解ガスのガス圧力を常に上回る、, In other words, a positive pressure state with an inert gas is formed in the sealed chamber, which prevents the atmosphere from entering the sealed chamber in an oxygen-free state, and makes the sealed chamber inactive. The gas pressure of the gas always exceeds the gas pressure of the pyrolysis gas generated by pyrolysis,
P N > P G≥P H > P 0 · · · · ( 2 ) . . P N > P G ≥ P H > P 0 ... (2).
すなわち、 密,閉室の上流側の不活性ガスのガス圧力 P:Nと熱分解加熱部の不活性ガスと熱分 解ガスどの混合 ^ス圧力 P Gと下流側の主に熱分解ガスの.ガス圧力 P Hとが、.大気圧 P 0を上 回る不活性ガスの圧力勾配を^成し、 そのことにより、 密閉室において熱分解ガスの下流側 '.から上流側への逆流を阻止す ようになざれることを特徴とする。 That is, the gas pressure P of the inert gas upstream of the closed, closed chamber P: N and the mixture of inert gas and pyrolysis gas in the pyrolysis heating part ^ S pressure P G and mainly the pyrolysis gas downstream. The gas pressure P H forms a pressure gradient of the inert gas that exceeds the atmospheric pressure P 0, thereby preventing backflow of pyrolysis gas from the downstream side 'to the upstream side in the sealed chamber. It is characterized by
. 請求の範囲 3に記載の発明は、 If求め範囲 2に記載の発明の特徴に加.'えて、 上流側から有 機物 有廃棄物を受入れる投入口と、 下流側から有機物含有廃棄物の^分解によって発生す る熱分解ガスを排気する排気孔および残渣の炭化物を排出する 出口と有 'ύ 上流側と下流 側との間に熱分解加熱部を形成する密閉室が、 横設された密閉室であることを特徴とする。 請求の範囲 4に記載の発明は、 請求の範囲 3に記載の発明の特徴に加えて、 密閉室の熱分 解加熱部が導電性材料からなり、 熱分解加熱部の外壁が電磁誘導加熱コイルで卷回されてお り、 電磁誘導加熱コイルへの電圧制御によって熱分解加熱部の内部温度を調整するようにし たことを特徴とする。 The invention described in claim 3 is in addition to the features of the invention described in Requirement Scope 2, and includes an inlet for receiving organic waste from the upstream side and an organic waste containing organic matter from the downstream side. ^ An exhaust hole for exhausting pyrolysis gas generated by decomposition and an outlet for discharging residual carbides and a closed chamber that forms a pyrolysis heating section between the upstream side and the downstream side are installed horizontally. It is a sealed chamber. The invention described in claim 4 is characterized in that, in addition to the features of the invention described in claim 3, the heat decomposition heating part of the sealed chamber is made of a conductive material, and the outer wall of the pyrolysis heating part is an electromagnetic induction heating coil. It is characterized in that the internal temperature of the pyrolysis heating part is adjusted by controlling the voltage to the electromagnetic induction heating coil.
請求の範囲 5に記載の発明は、 請求の範囲 2から 4に記載の発明の特徴に加えて、 密閉室 の投入口から不活性ガス溜まりに有機物含有廃棄物を順次投入する工程が、 有機物含有廃棄 物を密閉室の投入口に連続する密閉搬送路を経由して投入口に順次搬送する工程をさらに含 むことを特徴とする。 · In addition to the features of the invention described in claims 2 to 4, the invention described in claim 5 includes a step of sequentially introducing waste containing organic matter from an inlet of the sealed chamber into an inert gas reservoir. The method further includes the step of sequentially transferring waste to the input port via a sealed transfer path that continues to the input port of the sealed chamber. It is characterized by that. ·
請求の範囲 6に記載の発明は、 請求の範囲 5に記載の発明の特徴に加えて、 有機物含有廃 棄物を投入口へ順次搬送する工程が、' 有機物含有廃棄物を破砕し、 乾燥した後に固化整形す る工程をさらに含むことを特徴とする。 In addition to the features of the invention described in claim 5, in the invention described in claim 6, the step of sequentially transporting the organic substance-containing waste to the inlet is crushed and dried the organic substance-containing waste. The method further includes a step of solidifying and shaping later.
請求の範囲 7に記載の発明は、 .請求の範囲 2カゝら 6のいずれかに記載の発明の特徴に加え て、 密閉室の投入口に少なく とも交互に開閉する上下 2段のシャッターで形成される密閉自 •在な搬送室を有する投入手段によって、 有機物含有廃棄物を一時 に搬送室に滞留させなが ら、 密閉室に順次投入するようにした'ことを特徴とする。 . In addition to the features of the invention described in any one of claims 2 to 6, the invention described in claim 7 is a two-stage shutter that opens and closes alternately at the inlet of the sealed chamber. It is characterized by the fact that the waste containing organic matter is made to stay in the transfer chamber at a time by the input means having a self-contained transfer chamber that is formed, and then sequentially put into the sealed chamber. .
請求の範囲 8に記載の発明は、 請求の範囲 7に記載の発明の特徴に加えて、 密閉室の投入 口の密閉自在な雖送室および Zまたは密閉室の最上流側に不活性ガス注入口を有する不活性 ガス注入手段によって、 搬送室および または密閉室に不活性ガスを送込み、 少なくとも密 閉室の不活性ガスのガス圧力が矢気圧を上回るように制御すること 特徴とする In addition to the features of the invention described in claim 7, the invention described in claim 8 is characterized in that an inert gas injection is provided on the most upstream side of the sealed feed chamber and Z or the sealed chamber at the inlet of the sealed chamber. An inert gas injection means having an inlet feeds an inert gas into the transfer chamber and / or sealed chamber, and at least controls the gas pressure of the inert gas in the closed chamber to exceed the arrow pressure.
: 請求の範囲 9に記載の発明は、 請求の範囲 8に記載の発 の特徴に加えて、 少なくとも密 閉室の投入口め密閉自在な瘢送室、 密閉室の最上流側の不活性 ス注入口の近傍、 密閉室の 熱分解加熱^の上流側、 および密閉窒の熱分解加熱部の下流側 いずれかの位置にガス圧力 In addition to the features of the invention described in claim 8, the invention described in claim 9 includes at least an introductory space on the most upstream side of the hermetic chamber, at least an inlet of the hermetically sealed chamber Gas pressure in the vicinity of the inlet, upstream of the pyrolysis heating ^ in the sealed chamber, and downstream of the pyrolysis heating section of the sealed nitrogen
: センサーを適宜設け、 そのことに り 熱分解が開始される上流側の有機物含有廃棄物を投 . 入した不活性ガス溜まりの不活性ガス圧力と、 往復動手段のプッシヤー板の前進ストローク にともない発生する熱分解ガスおよび不活性ガスの混合ガス圧力と-、.熱分解が完了する下流 '.側の主に熱分解ガスのガス圧力とを監視しながら、 不活性ガスの送込量を制御して密 室に ' 上流側から下流側への不活性ガス 圧力.勾配を形成するようにしたごと'を特徴とする。 : An appropriate sensor is installed, so that the inert gas pressure in the inert gas reservoir into which the waste containing organic matter on the upstream side where thermal decomposition starts is injected and the forward stroke of the pusher plate of the reciprocating means Control the amount of inert gas fed while monitoring the mixed gas pressure of the generated pyrolysis gas and inert gas, and the gas pressure of the pyrolysis gas mainly on the downstream side where pyrolysis is completed. Then, it is characterized by the fact that an inert gas pressure from the upstream side to the downstream side and a gradient are formed in the closed chamber.
請^の範囲 1 0に記載の発明は、 請求め範囲 2から 9のいずれかに記載の発明の特徴に加 えて、 連通手段は、 往復動手段のプッシヤー板に穿設きれた 1つまたは複数の孔であり、 有 機物含有廃棄物を投入した不活性ガス溜まりの不活性ガスが、 往復動手段のプッシヤー板の 前進ス トロークにともないプッシヤー板の複数孔を通じて徐々にプッシヤー板の後方に流入 し、 且つ往復動手段のプッシヤー板の後退ス トロークにともないプッシヤー板の複数孔を通 じて徐々に前記プッシヤー板の前方に流入するようにして不活性ガスの形成された圧力勾配 を維持するようにしたことを特徴とする。 In addition to the features of the invention described in any one of claims 2 to 9, the communication means is one or more perforated on the pusher plate of the reciprocating means. The inert gas in the inert gas pool filled with waste containing organic matter gradually flows to the rear of the pusher plate through multiple holes in the pusher plate as the pusher plate moves forward in the reciprocating means. In addition, the pressure gradient in which the inert gas is formed is maintained by gradually flowing in the front of the pusher plate through the plurality of holes of the pusher plate as the pusher plate of the reciprocating means moves backward. It is characterized by that.
請求の範囲 1 1に記載の発明は、 請求の範囲 2から 1 0のいずれかに記載の発明の特徴に 加えて、 密閉室に送込まれた不活性ガスのガス圧力が常に熱分解ガスのガス圧力を上回るよ うに密閉室に上流側から下流側への不活性ガスの圧力勾配を形成することによって、 密閉室 の排気孔から熱分解ガスを回収する工程は、 回収される熱分解ガ をガス洗浄および また は冷却手段を経由させ'、 油水分離手段によって油成分として回収するェ择をさらに含むこと 'を特徴とする。 . · In addition to the features of the invention described in any one of claims 2 to 10, the invention described in claim 11 1 always has a gas pressure of the inert gas sent into the sealed chamber of the pyrolysis gas. By forming a pressure gradient of the inert gas from the upstream side to the downstream side in the sealed chamber so as to exceed the gas pressure, The step of recovering the pyrolysis gas from the exhaust hole of the exhaust gas further includes a step of passing the recovered pyrolysis gas through a gas cleaning and cooling means and recovering it as an oil component by the oil-water separation means. And .
.. 請求の範囲 1 2に記載の発明は、 請求の範囲 1 1に記載の発明の特徴に加えて、 回収され る熱分解ガスをガス洗浄およびズまたは冷却手段を経由させ、 油水分離手段によって油成分 として回収する工程は、 ミス ト分離手段を経由させ、 排気ファンによって残渣の熱分解ガス を排気する工程をさらに含むこと'を特徴とする。 - 請求の範囲 1 .3に記載の発明は、 請求の範囲 2から 1 2の'いずれかに記載の発明の特徴に 加えて、 密閉室に順次送込まれる有機物 有廃棄物を往復 手段のプッシャ一板の前進ス ト ロークによる押込動作によって、 密閉室の排出口から ¾の炭化物を排出するようにしたこ とを特微とする。 .. In addition to the features of the invention described in claim 11 1, the invention described in claim 12 2 allows the recovered pyrolysis gas to pass through a gas cleaning and cleaning or cooling means, and is separated by an oil-water separation means The step of recovering as an oil component further includes a step of exhausting residual pyrolysis gas by an exhaust fan via a mist separation means. -In addition to the features of the invention described in any one of claims 2 to 12 in the invention described in claim 1.3, the pusher of the reciprocating means is used for the organic matter-containing waste that is sequentially fed into the sealed chamber. The feature is that the carbide of ¾ is discharged from the discharge port of the sealed chamber by the pushing operation by the forward stroke of one plate.
• 請求の範囲 1 4に記載の発明は、 請求の範囲 2から 1 3にいずれかに |B載の発明の特徴に ' 加えて、 排出手段によ'つて密閉室の排出口から残渣の炭化物を回収する工程は、:排出口に接 続された上流側の投入口および回収容器に接続された下流側の排出口を有する炭化物冷却室 を経由させ、 回収容器に残渣の炭化物を回収する工程をさらに含むことを特徴とする。 • The invention described in claim 14 is any one of claims 2 to 1 3 in addition to the features of the invention described in B. The process of recovering the residue is: The process of recovering the residual carbide in the recovery container through the carbide cooling chamber having the upstream input port connected to the discharge port and the downstream discharge port connected to the recovery container Is further included.
請求の範囲.1 5に記載の発明は、.有機物含有廃棄物の連続的熱分解装置であって、. a ) 上 . 流側から有機物 有廃棄物を受入れる投入,口、 および、 下流側から有機物含有廃棄物の熱分 解によって発生する熱分解ガスを排気する排気孔と残渣の炭化物を排出する排出口を有する、 上流側と下流側との間に熱分解加熱部を''形成する.密閉室と、 b ) 密閉室に不活性ガスを送込: .むことによって不活性ガ 溜まりを形成する密閉室に連通する不活性ガス注入装置と、 c ) , 密閉 の投入口から不活性ガス溜まりに有機物含有廃棄物を順次投入レ、 密閉室の熱分解加 熱部に順次送込む密閉室の断面形状にほぼ一致するプッシヤー を有する往復動装置と、 d ) 往復動装置と連動し、 往復動するプッシヤー板の前後を移動する不活性ガスによって不活性 ガス溜まりを維持しながら、 有機物含有廃棄物を密閉室の熱分解加熱部に順次送込むように する不活性ガスの連通装置と、 e ) 密閉室の熱分解加熱部の有機物含有廃棄物を熱分解ガス と残渣の炭化物とに連続的に熱分解する熱分解加熱部に配した熱分解加熱装置と、 f ) 密閉 室に送込まれた不活性ガスのガス圧力を常に熱分解ガスのガス圧力より上回らせて密閉室に 上流側から下流側への不活性ガスの圧力勾配を形成する熱分解ガスの回収装置と、 g ) 密閉 室の排出口から残渣の炭化物を回収する排出装置とを含み、 h ) 通常の運転中には、 不活性 ガス注入装置を用いて送込まれた不活性ガスのガス圧力が少なく とも大気圧を上回るように し、 外気を遮断して密閉室を無酸素状態にするどともに、 熱分解;^熱装置め熱分解によって 発生し徐々に増大する熱分解ガスのガス圧力と密閉室の上流側から送込まれる不活性ガスの ガス圧力とが、 少なくとも密閉室の卞流側で均衡するような密閉室の上流側から下流側に不 .活性ガスの圧力勾配を形成し、 熱分解ガスを下流'側から上流側に逆^させることなく密閉室 から排気するように密閉室内への不活性ガスめ送込量を制御するようにしたことを特徴する。 請求の範囲 1 6に記載め発明は、 請求の範囲 1 5に記載の発明の特徴に加えて、 上流側か ら有機物含有廃棄物を受入れる投乂口、.および、 下流側から有機^含有廃棄物の熱分解によ つて発生する熱分解ガス'を排気する排^孔と残渣の炭化物を排出する排出口を有する、 上流 側と下流側との.間に熱分解加熱部を形成する密閉室が、 横設.された密閉室であることを特徴 とする。 . , ' . :. ' 、 ' Claim 15. The invention described in claim 5 is an apparatus for continuous thermal decomposition of organic matter-containing waste. A) Upper. From the input side, the inlet, and the downstream side for receiving organic waste with waste A pyrolysis heating section is formed between the upstream side and the downstream side, which has an exhaust port for exhausting pyrolysis gas generated by the thermal decomposition of waste containing organic matter and an exhaust port for discharging residual carbides. B) an inert gas injection device that communicates with the sealed chamber forming an inert gas reservoir by capping the inert gas into the sealed chamber; and c) the inert gas from the sealed inlet A wastewater containing organic matter is sequentially added to the reservoir, and a reciprocating device having a pusher that substantially matches the cross-sectional shape of the sealed chamber that is sequentially fed to the pyrolysis heating section of the sealed chamber; and d) The inert gas is moved by the inert gas moving before and after the moving pusher plate. An inert gas communication device that sequentially feeds the waste containing organic matter to the pyrolysis heating section of the sealed chamber while maintaining the reservoir, and e) heats the waste containing organic matter in the pyrolysis heating section of the sealed chamber. A pyrolysis heating device placed in the pyrolysis heating section that continuously pyrolyzes the cracked gas and residual carbides, and f) the gas pressure of the inert gas sent into the sealed chamber is always the gas pressure of the pyrolysis gas. A pyrolysis gas recovery device that forms a pressure gradient of the inert gas from the upstream side to the downstream side in the closed chamber, and g) a discharge device that recovers residual carbide from the discharge port of the closed chamber. H) During normal operation, the gas pressure of the inert gas sent using the inert gas injection device should be at least above atmospheric pressure. In addition to shutting off the outside air and making the sealed chamber oxygen-free, pyrolysis; ^ pyrolysis gas generated by pyrolysis of the thermal device and gradually increasing the gas pressure of the pyrolysis gas and the upstream side of the sealed chamber An inert gas pressure gradient is formed from the upstream side to the downstream side of the sealed chamber so that the gas pressure of the inert gas is balanced at least on the upstream side of the sealed chamber. It is characterized in that the amount of inert gas fed into the sealed chamber is controlled so that the air is exhausted from the sealed chamber without being reversed. In addition to the features of the invention described in claim 15, the invention described in claim 16 includes a loading port that accepts organic-containing waste from the upstream side, and organic-containing waste from the downstream side. A sealed chamber that forms a pyrolysis heating section between the upstream side and the downstream side, which has exhaust holes for exhausting the pyrolysis gas generated by the thermal decomposition of materials and exhaust ports for discharging residual carbides It is characterized by a closed chamber installed horizontally. , '.:.', '
請求の範囲 1 7に記載の発明は、請求の範囲 1 5または 1 6に記載の発明の特徴に加えて、 ' 熱分解加熱部に配した熱分解加熱装置が電磁誘導加熱装置であり、 導霉性材料からなる熱分 • 解加熱部に拳回された電磁誘導コイルに交流電流を流すことによって熱分解加熱部を加熱す るとともに、 熱分解加熱邰の外壁を断熱構造にする、 および/または、 冷媒が循環するゥォ . 一タ'ジャケッ卜で覆うようにしたこと.'を特徴とする。 In addition to the features of the invention described in claims 15 or 16, the invention described in claim 17, in addition to the features of the invention described in claim 15, 'the pyrolysis heating device disposed in the pyrolysis heating section is an electromagnetic induction heating device, Heat component made of fertile material • Heat the pyrolysis heating part by passing an alternating current through the electromagnetic induction coil wound around the deheating part, and make the outer wall of the pyrolysis heating soot a heat insulating structure, and / or Or, the refrigerant circulates. It is characterized by being covered with a jacket.
請求の範囲 ,1. 8に記載の発明は、,請求の範囲 1: 7に記載の発明の特徴に加えて、 電磁誘導 加熱コィルへの電圧制御によつて熱分解加熱部の内部温度.を調整するよう'にしたことを特徴 ' とする。 ; . ■ . ' . ' . In addition to the features of the invention described in claims 1: 7, the invention described in claims 1 and 8 can be used to control the internal temperature of the pyrolysis heating unit by controlling the voltage to the electromagnetic induction heating coil. The feature is that it has been adjusted. '.
'. 請求の範囲 1 9に記載の発明は、請求め範囲 1 5または' 1 8に記載の発明の特罈に加えて、 ! .有機物含有廃棄物を順次投入する密閉室の投入口に接続する密閉搬送路をさら:に含むことを . 特徴とする。 . '. In addition to the features of the invention described in claim 1 5 or' 1 8, the invention described in claim 19 is! It further includes a sealed conveyance path connected to the inlet of the sealed chamber into which waste containing organic substances is sequentially added. .
請求の範囲 2 0に記載の発明は、 請求の範囲 1 9に記載の^^の特徴に加えて、 密閉搬送 路が有機物含有廃棄物を破砕し、 乾燥した後に固化整形する装置をさらに含むことを特徴と する。 In addition to the features of ^^ described in claim 19, the invention described in claim 20 further includes a device in which the sealed conveyance path crushes organic matter-containing waste and solidifies after drying. It is characterized by.
請求の範囲 2 1に記載の発明は請求の範囲 1 5から 2 0のいずれかに記載の発明の特徴に 加えて、 密閉室の投入口に有機物含有廃棄物を一時的に滞留させながら密閉室に順次投入す る、 少なくとも交互に開閉する上下 2段のシャッターで形成される密閉自在な搬送室を有す る投 λ装置をさらに含むことを特徴とする。 In addition to the features of the invention described in any one of claims 15 to 20, the invention described in claim 21 includes a sealed chamber while temporarily holding organic substance-containing waste at the inlet of the sealed chamber. It further includes a throwing λ device having a sealable transfer chamber formed by at least two upper and lower shutters that are alternately opened and closed.
請求の範囲 2 2に記載の発明は、 請求の範囲 1 5から 2 1のいずれかに記載の発明の特徴 に加えて、 密閉室に不活性ガスを送込む不活性ガス注入装置が、 密閉室の投入口の密閉自在 な搬送室および zまたは密閉室の最上流側に不活性ガス注入口を けるようにしたことを特 徴とする。 The invention described in claim 22 is characterized in that, in addition to the features of the invention described in any one of claims 15 to 21, an inert gas injection device for sending an inert gas into the sealed chamber includes: The inlet of the door can be sealed freely It is characterized in that an inert gas inlet is provided on the uppermost stream side of the transfer chamber and z or sealed chamber.
請求の範囲 2 3に記載の発明は、 if求の範囲 1 5から 2 2のいずれかに記載の発明の特徴 .に加えて、 少なく とも密閉室の投入口の密閉自在な搬送室、 密閉室の最上流側に不活性ガス 注入口の近傍、.密閉室の熱分解加熱部の上流側、 および密閉室の熱分解加熱部の下流側のい ずれかの位置にガス圧力センサー適宜設け、 そのことにより、 熱分解が開始ざれる上流側の 有機物含有廃棄物を投入した不活' ガス溜まりの不活性ガス圧力 、 往復動装置のプッシャ —板の前進ストロークにともない発生する熱分解ガスおよび不活性ガスの混合力:ス圧力と、 熱分解が完了する下流側の主に熱分解ガスのガス圧力とを しながら、 ガス圧力センサー と連動させた不活性ガス注入装置が、:不活性ガスの送込量を制御し、 密閉室に上流側^ら下 · 流側への不活性ガスの圧力勾配を形成するようにしたことを特徴とする。 The invention described in claim 23 is characterized in that, in addition to the features of the invention described in any one of claims 15 to 2, the at least the transfer chamber that can be sealed at the inlet of the sealed chamber, the sealed chamber An appropriate gas pressure sensor is installed at the position upstream of the inert gas inlet, upstream of the pyrolysis heating section of the sealed chamber, and downstream of the pyrolysis heating section of the sealed chamber. The inert gas pressure of the organic reservoir containing the upstream organic waste that does not start pyrolysis, the pressure of the inert gas in the gas reservoir, the pusher of the reciprocating device — the pyrolysis gas generated by the forward stroke of the plate Gas mixing force: An inert gas injection device linked to the gas pressure sensor, which adjusts the gas pressure and the gas pressure of the pyrolysis gas mainly on the downstream side where pyrolysis is completed: Control the amount of gas flow into the sealed chamber from the upstream side to the downstream side It is characterized in that a pressure gradient of the inert gas is formed.
請求の範囲 2 4に記載の発明は、 請求の範囲 1 5から 2 3のいずれかの IE載の発明の特徴: : に加えて、連通装置は、往復動装置のプッシヤー板に穿設された 1つまたは複数の孔であり、 有機物含有廃棄物を投入した不活性ガス溜まりの不活性ガスが、,往復動装置のプッシヤー板 . の前進ストロークにともないプッシャ丄板の複数孔を通じて徐タにプッシヤー板の後方に流 • 入し、 且つ往復動装置めプッシャ 板の後退ス ト όークにともないプッシヤー板の複数孔を .通じて徐々にプッシヤー板の前方に.流入するようにして不活性ガスの形^^された圧力勾配を The invention described in claim 24 is characterized in that the communication device is provided in the pusher plate of the reciprocating device in addition to the features of the invention according to any one of claims 15 to 23: One or more holes, and the inert gas in the inert gas reservoir charged with organic substance-containing waste is gradually pushed through the plurality of holes in the pusher plate as the pusher plate of the reciprocating device moves forward. • An inert gas that flows into the back of the plate and gradually flows into the front of the pusher plate through multiple holes in the pusher plate as the reciprocating device pusher plate moves backward The shape of the pressure gradient ^^
' 維持するように υたことを特徴とする。 'Characterized by υ to maintain.
請求の範囲 2 5 .に記載の発明は、 請求の範囲 1 5から 2 4めいずれかに記載の発明の特徴 ' .に加えて、 密閉室に送込まれた不活性ガスのガス圧力を常に熱分解ガスのガス圧力より上回. らせて密閉室に上流側から下流側への不活性ガスの圧力勾配を形成する熱分解ガスの回収装 置は、 回収される熱分解ガスをガス洗浄および または冷却装犟を介して油成分として回収 する油水分離装置をさらに含むことを特徴とする。. In addition to the features of the invention according to any one of claims 15 to 24, the invention described in claim 25 is always capable of adjusting the gas pressure of the inert gas sent into the sealed chamber. The pyrolysis gas recovery device that creates a pressure gradient of the inert gas from the upstream side to the downstream side in the sealed chamber by exceeding the gas pressure of the pyrolysis gas is a gas scrubbing of the recovered pyrolysis gas And / or further comprising an oil / water separator for recovering as an oil component through a cooling device. .
請求の範囲 2 6に記載の発明は、 請求の範囲 2 5に記載の発明の特徴に加えて、 回収され る熱分解ガスをガス洗浄および または冷却装置を介して油成分として回収する油水分離装 置は、 排気ファンによって残渣の熱分解ガスを排気するミス ト分離装置をさらに含むことを 特徴とする。 In addition to the features of the invention described in claim 25, the invention described in claim 26 includes an oil-water separator that recovers the recovered pyrolysis gas as an oil component through a gas cleaning and / or cooling device. The apparatus further includes a mist separation device for exhausting residual pyrolysis gas by an exhaust fan.
請求の範囲 2 7に記載の発明は、 請求の範囲 1 5から 2 6のいずれかに記載の発明の特徴 に加えて、 密閉室に順次送込まれる有機物含有廃棄物を往復動装置のプッシャ 板の前進ス トロークによる押込動作によって、 密閉室の排出口から残渣の炭化物を排出するようにした ことを特徴とする。 , In addition to the features of the invention described in any one of claims 15 to 26, the invention described in claim 27 includes an organic substance-containing waste that is sequentially fed into a sealed chamber. The residual carbides are discharged from the discharge port of the sealed chamber by pushing in with the forward stroke of It is characterized by that. ,
請求の範囲 2 8に記載の発明は、 請求の範囲 1 5から 2 7にいずれかに記載の発明の特徴 に加えて、 密閉室の排出口から炭化^)を回収する排出装置は、 排出口に接続された上流側の .投入口と回収容器に接続された下流側の排出口を'有する炭化物冷却室を経由させて回収容器 に前記炭化物を回収するようにしだことを特徴とする。 The invention described in claim 28 is characterized in that, in addition to the features of the invention described in any of claims 15 to 27, the discharge device for recovering carbonized carbon from the discharge port of the sealed chamber is a discharge port. The carbide is recovered in the recovery container via a carbide cooling chamber having an upstream inlet connected to the outlet and a downstream outlet connected to the recovery container.
請求の範囲 2 9に記載の発明は、 有機物含有廃棄物の連続的熱分解ガス化システムであつ 'て、 上流側から投入された有機物^有廃棄物が熟分解され、 下流 から発生した熱分解ガス が回収される熱分解加熱部を上流側と卞流側との間に形成する密閉室に、 不活性ガス注入シ ステムを用いて不活性ガスを送込み、 密閉室の不活性ガス庄力が大気圧を常に上回るよ に し、 外気を遮断レて密閉室 無酸素状態にするとともに、 発生する熱分解ガ のガス圧力を も上回るように密閉室の上流側から下流側へ不活性ガスの圧力勾配を形成し、.熱分 ガスを 下流側から上流側に逆流させることなく密閉室から回収するようにしたことを特徴とする。 . 請求の,範囲 3 0に記載の発明は、 請求の範囲 2 9に記載の発明の特徴に加えて、 熱分解加 熱部が電磁誘導コイルで卷回された導電性材料からなり、 外壁 ^断熱構造にする、 およびノ または、 冷媒が循環するウォータ 'ジャケットで覆うようにしたことを特徴とする。 The invention described in claim 29 is a continuous pyrolysis gasification system for organic matter-containing waste, which is an organic matter that has been introduced from the upstream side. An inert gas injection system is used to feed an inert gas into a sealed chamber that forms a pyrolysis heating section where the gas is recovered between the upstream side and the upstream side. As the atmospheric pressure always exceeds the atmospheric pressure, the outside air is shut off and the sealed chamber becomes oxygen-free, and the gas pressure of the generated pyrolysis gas is also exceeded from the upstream side to the downstream side of the sealed chamber. A pressure gradient is formed, and the heat component gas is recovered from the sealed chamber without flowing backward from the downstream side to the upstream side. In addition to the features of the invention described in claim 29, the invention described in claim 30 includes a conductive material in which a pyrolysis heating portion is wound by an electromagnetic induction coil, and an outer wall ^ It is characterized by having a heat insulation structure and covering with a water jacket through which the refrigerant circulates.
請求の範囲: 3. 1に記載の発明は、.請求の範囲 3, 0に記載の発明の特徴に加えて、 電磁誘導 加熱コイルへめ電圧制御によって熱分解加熱部の内部温度を調整するよ'うにしたことを特徴 とする。 . · ' . 発明の効舉 、 ; : · 上記したような特徴を有する本発明によれば、. 以下の如き優れた効果を発揮する。 . ' ( 1 ) 例えば医療廃棄物などの有機物含有廃棄物の連続的熱分解を可能にする方法および 装置並びに熱分解ガス化システムにおいて、 熱分解加熱部を有する密閉室を抜気するのでは なく大気圧より常に高い圧力で不活性ガスを送込み、 且つ密閉室の上流から下流に向かって 不活性ガスの圧力勾配を形成することによって、 密閉室内の無酸素状態を容易に形成できる ようにしたことである。 Claims: 3.1 In addition to the features of the inventions described in claims 3, 0, the invention described in 3.1 adjusts the internal temperature of the pyrolysis heating part by controlling the electromagnetic induction heating coil voltage. 'It is characterized by having done it. .. EFFECT OF THE INVENTION;: According to the present invention having the characteristics as described above, the following excellent effects are exhibited. (1) In the method and apparatus and the pyrolysis gasification system that enable continuous pyrolysis of organic-containing waste such as medical waste, the sealed chamber having the pyrolysis heating section is not evacuated. An inert gas is sent at a pressure always higher than the atmospheric pressure, and an inert gas pressure gradient is formed from upstream to downstream of the sealed chamber, so that an oxygen-free state in the sealed chamber can be easily formed. That is.
( 2 ) このことにより、 熱分解加熱部を有する密閉室に外気が流入し燃焼または燃焼爆発 を誘発することがないようにするとともに、 不活性ガスの圧力勾配を利用して熱分解によつ て発生した熱分解ガスを逆流させことなく下流側の排気孔から確実に排気できるようにした . ことである。 . ( 3 ) さらに密閉室の断面形状にほぼ一致する形状のプッシヤー板によって有機物含有廃 棄物を密閉室の熱分解 ^熱部に送込むよう,にしたことにより、 高分子材科を含む有機物含有 廃棄物の加^処理工程中に一時的に ½生する溶融および Zまたは粘性付着にともなう装置機 .能の低下を防止できるようにしたことである。 (2) This prevents the outside air from flowing into the sealed chamber having the pyrolysis heating section and induces combustion or combustion explosion, and uses the pressure gradient of the inert gas to perform pyrolysis. This ensures that the pyrolysis gas generated in this way can be reliably exhausted from the downstream exhaust hole without backflow. . (3) In addition, by using a pusher plate with a shape that roughly matches the cross-sectional shape of the sealed chamber, the organic material-containing waste is pyrolyzed in the sealed chamber ^ This is to prevent the deterioration of the apparatus performance due to melting and Z or viscous adhesion temporarily generated during the waste treatment process.
- ( 4 ) さらに密閉室内の不活性ガス圧力を監視しながら不活性ガスの送込量を制御するよ うにしたことにより、 大量の有機物含有廃棄物の連続的熱分解処理を可能にした。 -(4) Furthermore, by controlling the amount of inert gas fed in while monitoring the inert gas pressure in the sealed chamber, it has become possible to perform continuous pyrolysis treatment of a large amount of organic waste.
( 5 ) さらにまた、 有機物含有 棄物の連続的熱分解によって ¾生する熱分解ガスおよび 残渣の炭化物を回収し、 公害化させる'ことなく再資源化でき'るようにした.ことなどである。 '図面の簡単な |¾明 ' ;. ■ 、 ' . (5) Furthermore, the pyrolysis gas and residual carbides produced by the continuous pyrolysis of waste containing organic matter can be recovered and recycled without 'polluting'. . 'Simple drawing | ¾description';. ■, '.
図 1は、 本発明に係る有機物含有廃棄物の熱分解方法および装置並びに熱分解ガス化シス テムを表す全体構成図である。 ' . . . '. FIG. 1 is an overall configuration diagram showing an organic matter-containing waste pyrolysis method and apparatus and pyrolysis gasification system according to the present invention. '...'.
' 図 2は、 ,本発明に係る有機物含有廃棄物の熱分解方法および装置並びに熱分解ガス化シス テムの動作手順^表すフロチャートである。 ′ FIG. 2 is a flowchart representing the operation procedure of the pyrolysis method and apparatus and the pyrolysis gasification system for organic substance-containing waste according to the present invention.
図 3は、 密閉室の熱分解加熱部の縦断面図 (a ) および左側面図 (b ) である。 FIG. 3 is a longitudinal sectional view (a) and a left side view (b) of the pyrolysis heating section of the sealed chamber.
図 4は、 往復動装置めプッシヤー板の往復動動作による密閉室内の不活性ガス流れを す •模式図である。 / ·. ■ .. . . . . ■' ' + Fig. 4 is a schematic diagram showing the inert gas flow in the sealed chamber due to the reciprocating motion of the reciprocating device pusher plate. ■ '' +
'発明を実施するための最良の形態 . 'Best Mode for Carrying Out the Invention.
. 本発明に係る有機物含有廃棄物の熱分解方法および装置並びに熱分解ガス化システムの実 施例を図面に基づいて説明する。 実施例の全体構成を図 1に示レ、 囪 2のプロチャートによ り動作手順を示した。 本発明の実施例は、 電磁誘導による熱^解手段または装置を示す。 し かしながら、 本発明における熱分解は電磁誘導手段または装置に限定されるものではなく、 図示されてはいないが加熱空気またはガス、 或いは熱分解装置自体をガスバーナーなどで直 接加熱する手段をも含むことができる。 Embodiments of the pyrolysis method and apparatus for organic matter-containing waste and pyrolysis gasification system according to the present invention will be described with reference to the drawings. The overall configuration of the example is shown in FIG. 1, and the operation procedure is shown by the pro chart in (2). The embodiment of the present invention shows a heat decomposing means or apparatus by electromagnetic induction. However, the thermal decomposition in the present invention is not limited to the electromagnetic induction means or apparatus. Although not shown, the heating air or gas, or means for directly heating the thermal decomposition apparatus itself with a gas burner or the like. Can also be included.
図 1は全体構成図であるとともに概念図である。医療廃棄物などの有機物含有廃棄物 1は、 外部から搬送コンベアなどにより破砕装置に送込まれ裁断されて、 例えばドラム式の乾燥装 置を経由させて固化成型装置において成型され、 密閉搬送路 2に順次送込まれる。 ここに示 される破碎装置、 乾燥装置おょぴ固化成型装置は、 有機物含有廃棄物 1が汚染物質を含むか または爆発性や引火性などの危険物質を含むこともあり、 有機物含有廃棄物 1の熱分解の前 . . 処理工程として全体装置の一部とする :ともできる ά 図 1から明らかなように、 密閉搬送路 2は、 後述する密閉室 3の投入装置 4の投入口 4 1に通じている。 Figure 1 is a conceptual diagram as well as an overall configuration diagram. Waste containing organic matter 1 such as medical waste is sent to the crushing device from the outside by a conveyor, etc., cut, and then molded in a solidification molding device via a drum-type drying device, for example. Are sent sequentially. The demolition equipment, drying equipment, and solidification molding equipment shown here contain organic matter-containing waste 1 or it may contain hazardous substances such as explosive or flammable. Before pyrolysis of As part of the entire apparatus as a processing step: As can be seen from FIG. 1, the sealed transfer path 2 leads to an input port 4 1 of an input device 4 of the closed chamber 3 described later.
密閉搬 路 2の終端は投入装置 4 上流側に続く。 投入装置 4の下流側は密閉室 3への投 入口 4 .1を含む。 投入装置 4には、 搬送されてきた有機物含有廃棄物 1を密閉室 3に順次投 5 入する際に、 一時的に滞留させるための搬送室 4 2を設けることができる。 搬送室 4 2は、 上下 2段のシャッター装置 4 3を含むことができる。 上段のシャッター装置 4 3 1および下 段の:ンャッタ一装置 4 3 2は、 ァ'クチユエータ.などにより交互に W閉するシャッターを有す る。 密閉搬送路 2を経由してきた有機 ¾含有廃棄物 1は、 開状態の上段シャッターと閉状態 の下段シャッターとで構成される搬送室 4 2に一時的に滞昝する。 次に上段シャッター 4 .3 10 ' 1を閉状態とし、,下段シャ?ター 4 3 2'を開状態とすることにより、 有機物含有廃棄物 1を 投入口 4 1から密閉室 3に投入することができる。 The end of the closed transport path 2 continues to the upstream side of the input device 4. The downstream side of the charging device 4 includes an inlet 4.1 to the sealed chamber 3. The input device 4 can be provided with a transfer chamber 4 2 for temporarily retaining the transferred organic substance-containing waste 1 into the sealed chamber 3 in order 5. The transfer chamber 4 2 can include a shutter device 43 having two upper and lower stages. The upper shutter device 4 3 1 and the lower shutter device 4 3 2 have shutters that are alternately closed by a shutter or the like. The organic ¾-containing waste 1 that has passed through the hermetic transfer path 2 temporarily stays in the transfer chamber 42 composed of an open upper shutter and a closed lower shutter. Next, close the upper shutter 4.3 10 '1 to the lower shutter? The organic matter-containing waste 1 can be put into the sealed chamber 3 through the inlet 4 1 by opening the filter 4 3 2 ′.
密閉搬送路 2と密閉室 3とを接続する投入装置 4に交互に開閉自在な上下 2段シャッター装 置 4 3 1および 4 3 2'を設けることにより、 密閉室 3を密閉搬送路 2との間を密閉自在に維 持することができる。 . . , By installing the upper and lower two-stage shutter devices 4 3 1 and 4 3 2 'that can be opened and closed alternately in the charging device 4 that connects the sealed conveyance path 2 and the sealed chamber 3, the sealed chamber 3 is connected to the sealed conveyance path 2. It is possible to maintain a tightly sealed space. ,
: 15 密閉室 3の全体構成は図 1に示される。 図 3は、 密閉室の一部を構成する電磁誘導の熱分 . 解加熱部 3 1の断面図および側面図である。 図 1から明らかなように、: 密閉室 3の上流側に . は、 上記した有機物含有廃棄物 1の.投入口.4 1と、 ァクチユエータなどにより密閉室 3の内 ノ 部を往復動する ¾復動装置 5のプッシヤー板 5 1の裏面の最上流側に後述する不活性ガス注 '.入装置 6からバルブを有する配管により密閉室 3に連通する不活性ガス注入口 6 1 とが設け 20 られる。 プッシヤー板 5 1の引込位置す.なわち最後退位置は、 投入口 4 1 とプッシヤー板 5 ' 1 との間になるょラに構成される。 往復動装置 5のプッシヤー板 5 1は密閉室 3の断面形状 'にほぼ一致する外周を有し、 密閉室 3に送込まれた不活性ガスの流出入を可能にする表裏を 貫通する 1つまたは複数の連通孔 5 1 1からなる不活性ガスの連通装置 5 2を設けることが できる。 具体的には、 図 4の模式図に示すように、 密閉室 3に不活性ガス注入装置 6によつ 25 て送込まれた不活性ガスが、 往復動装置 5のプッシヤー板 5 1の前進ストロークにともない プッシヤー板の連通孔 5 1 1からなる連通装置 5 2を通じて徐々にプッシヤー板の後方に流 入し、 且つ往復動装置 5のプッシヤー板 5 1の後退ストロークにともないプッシャ一板 5 1 の連通孔 5 1 1からなる連通装置 5 2を通じて徐々にプッシヤー板 5 1の前方に流入するよ うにすることができる。 図 4の模式図に示した連通装置 5 2は、 プッシヤー板.5 1の表裏を 30 貫通する 1つまたは複数の連通孔 5 1 1からなるが、 こうした構成に限定されることなく、 プッシヤー板 5 1の前進ス トロークにともないプッシヤー板 5 1の後方に流入し、 且つプッ シャ一板 5 1の後退ストロ^"クにともない,プッシヤー板 5 1の前方に流入するようにして密 閉室 3に送込まれた不活性ガスによつて形成された圧力勾配を維持するこ 'とができる構成に あればよく、 例えば往復動装置 5のプッシヤー板 5 1の前進および後退ズトロークの前進位 置および後退位置の内壁に連通孔を有するガ 連通路を密閉室の外壁に併設し、 そのガス連 通路を介して不活性ガスの流出入を可能にする連通装置 5 2とすることもできる。 : 15 The overall configuration of the sealed chamber 3 is shown in Fig. 1. FIG. 3 is a cross-sectional view and a side view of the electromagnetic induction heat dissociating and heating unit 31 constituting a part of the sealed chamber. As is clear from FIG. 1, the upstream side of the sealed chamber 3 is reciprocated between the inlet 41 of the organic matter-containing waste 1 and the inner portion of the sealed chamber 3 by means of an actuator, etc. The pusher plate 5 of the return device 5 is provided with an inert gas injection port 6 1, which will be described later, on the uppermost stream side of the back surface of the reverse device 5. It is done. The push-in position of the pusher plate 5 1, i.e. the last retracted position, is configured between the inlet 4 1 and the pusher plate 5 ′ 1. The pusher plate 5 1 of the reciprocating device 5 has an outer circumference that substantially matches the cross-sectional shape 'of the sealed chamber 3, and passes through the front and back surfaces that allow the inert gas sent to the sealed chamber 3 to flow in and out. Alternatively, an inert gas communication device 5 2 including a plurality of communication holes 5 1 1 can be provided. Specifically, as shown in the schematic diagram of FIG. 4, the inert gas sent into the sealed chamber 3 by the inert gas injection device 25 is moved forward by the pusher plate 51 of the reciprocating device 5. In accordance with the stroke, the pusher plate communication hole 5 1 1 gradually flows into the rear of the pusher plate through the communication device 5 2, and the pusher plate 5 1 of the reciprocating device 5 moves in the reverse stroke of the pusher plate 5 1. It is possible to gradually flow into the front of the pusher plate 51 through the communication device 5 2 including the communication hole 5 1 1. The communication device 5 2 shown in the schematic diagram of FIG. 4 is composed of one or a plurality of communication holes 5 1 1 penetrating the front and back of the pusher plate 5 1, but is not limited to this configuration. Closed chamber so that it flows into the rear of the pusher plate 51 with the forward stroke of the pusher plate 51 and flows into the front of the pusher plate 51 with the backward stroke of the pusher plate 51. It is sufficient that the pressure gradient formed by the inert gas sent to 3 can be maintained, for example, the pusher plate 51 of the reciprocating device 5 and the forward position of the backward stroke. In addition, a communication passage having a communication hole on the inner wall at the retracted position can be provided on the outer wall of the sealed chamber, and the communication device 52 that allows inflow and outflow of inert gas through the gas communication passage can be provided.
■ また、 高分子材料を含む有機物 有廃棄物 1の加熱処理工程中【こ一時的に発生する溶融お よび Zまたは粘性付着にともなう装置機能の低下を防止することは、 有機物含有廃棄物 1の 熱分解反応 連続性をどう,維持するか、 すなわち、 始動時 除き通常運転時は連続処理^前 提としなければならないという点で重要な技術的課題である。 そのため必要に応じ密閉室 3 の内壁への付着物を搔き落す着脱自在な搔き落し爪 5 1 2を装着することもできる。 ■ In addition, during the heat treatment process for organic waste containing polymer material 1 [Preventing degradation of equipment function due to temporary melting and Z or viscous adhesion is the Pyrolysis reaction This is an important technical issue in terms of how to maintain continuity, that is, continuous processing must be a precondition during normal operation except during startup. Therefore, if necessary, it is possible to attach a detachable scraping claw 5 1 2 that scrapes off deposits on the inner wall of the sealed chamber 3.
上記した不活性ガス注入装置 6は、 窒素 (N 2 ) またはアルゴン (A r ) などのガスを貯: '蔵するタンクである。 'バルブを有する配管によつて密閉室 3の最上流側の不活性ガス注入口 6 1を介して不活性ガスを送込むとともに、 上記した搬送室 4 2,にもパルプを有する配管に よ όて同じく不活性ガス注入口 6 2 介して不活性ガスを送込むようにすることもでぎる。 : 不活性ガスが密閉室 3に送込まれることによって、'プッシャ一板 5 1の往復動によってもプ' ツシヤー板 5 1に設けた連通孔 5 1 .1からなる連通装置 5. 2を介して不活性ガスが流出入で ' き、 密閉室 3に不活性ガス溜まりまたは不活性ガス雰 ffi気 6 3を形成し、 維持させることが できる。 密閉室 3の内部に形成される Ν'2または A rなどの不活性ガス雰囲気 6 3を萆視す るために、 少なくとも密閉室 3の投入口.4 1の密閉自在な搬送室 4 2、 閉室 3の梟上流側 の不活性ガス注入口 6 1の近傍、 密閉室 3の.熱分解加熱部 3 1の上流側、 および密閉室 3の 熱分解加熱部 3 1の下流側のいずれかの位置にガス圧力センサー.6 4 1、 6 4 2、 6 4 3、 6 4 4 (まとめて 6 4 ) を適宜設ける必要がある。 これらのガス圧力センサー 6 4 1から 6 4 4によって、 後述するように熱分解が開始される上流側の有機物含有廃棄物 1を投入した 不活性ガス溜まりまたは不活性ガス雰囲気 6 3の不活性ガス圧力と、 往復動装置 5のプッシ ヤー板 5 1の前進ストロークにともない発生する熱分解ガスおよび不活性ガスの混合ガス圧 力と、 熱分解が完了する下流側の主に熱分解ガスのガス圧力とを監視することができる。 さ らに、 不活性ガス注入装置 6は、 これらのガス圧力センサー 6 4 1から 6 4 4と連動させて 搬送室 4 2および密閉室 3への不活性ガスの送込量を制御することができる。 . The above-described inert gas injection device 6 is a tank that stores a gas such as nitrogen (N 2 ) or argon (A r). 'With the pipe having the valve, the inert gas is fed through the inert gas inlet 61 on the uppermost stream side of the sealed chamber 3 and the pipe having the pulp also in the transfer chamber 42 described above. It is also possible to send an inert gas through the inert gas inlet 6 2. : When the inert gas is fed into the sealed chamber 3, the reciprocating motion of the pusher plate 51 also causes a communication device 5.2 comprising the communication hole 5 1.1 provided in the pusher plate 51 to Thus, an inert gas can flow in and out, and an inert gas pool or an inert gas atmosphere 63 can be formed and maintained in the sealed chamber 3. The inert gas atmosphere 6 3 such as New '2 or A r which is formed inside the sealed chamber 3 in order to萆視, at least closed chamber 3 of inlet .4 1 of the closed freely conveying chamber 4 2, Close to the inert gas inlet 61 on the upstream side of the closed chamber 3, one of the upstream side of the pyrolysis heating unit 3 1 of the sealed chamber 3 and the downstream side of the pyrolysis heating unit 3 1 of the sealed chamber 3 Gas pressure sensors .6 4 1, 6 4 2, 6 4 3, 6 4 4 (collectively 6 4) need to be provided at appropriate positions. By these gas pressure sensors 6 4 1 to 6 4 4, the inert gas reservoir or inert gas atmosphere 6 3 into which the organic substance-containing waste 1 on the upstream side where thermal decomposition is started as described later is introduced. Pressure, pressure plate of reciprocating device 5 and pressure of mixed gas of pyrolysis gas and inert gas generated with advance stroke of 1, and gas pressure of mainly pyrolysis gas at the downstream side where pyrolysis is completed And can be monitored. Further, the inert gas injection device 6 can control the amount of inert gas fed into the transfer chamber 4 2 and the sealed chamber 3 in conjunction with these gas pressure sensors 6 4 1 to 6 4 4. it can. .
密閉室 3の下流側には、 有機物含有廃棄物 1の熱分解反応により発生する熱分解ガスを排 気回収する装置 7に接続される排気孔 7 1と、 有機物含有廃棄物 1の熱分解反応の残渣であ る炭化物を回収する排出装置 8に接続される排出口 8 1とが設けられる。 熱分解ガス回収装 置 7およ.ぴ残渣の炭化物排出装置 8 Ϊこ関する 細は後述する。 通常は、 排気孔 7 1およぴ排 .出口 8 .1の近傍には外気の流入を阻止するためのシャッター装置が適宜設けられるが、 後述 するように本 ¾明の特徴の 1つは、 こうした装置を必ずしも必要としないことにある。 On the downstream side of sealed chamber 3, the pyrolysis gas generated by the pyrolysis reaction of organic matter-containing waste 1 is exhausted. An exhaust hole 71 connected to the gas recovery device 7 and an exhaust port 81 connected to the discharge device 8 for recovering the carbide that is the residue of the pyrolysis reaction of the organic matter-containing waste 1 are provided. Pyrolysis gas recovery device 7 and residue carbide discharge device 8 Details of this will be described later. Normally, a shutter device for preventing the inflow of outside air is appropriately provided in the vicinity of the exhaust hole 71 and the exhaust outlet 8.1. As will be described later, one of the features of the present invention is as follows. Such a device is not necessarily required.
電磁誘導による熱分解加熱部 3 1は、 密閉室 3の上流側と下流'側との間に形成される。 図 3にみるように熱分解加熱部 3 1 電磁誘導加熱により発熱する導電性材料の円筒形容器3 1 1からなり、 その外周を断熱材 3 1 '2が覆う。 円筒形容器' 3 1 1の外周両端に設けたコィ ル支持部材 3 1 4により、.断熱材 3 1 2の外周に卷回された電磁誘導加熱コイル 3 1 3を支 '持することができる。 さらに.電磁誘導加熱ユイル 3 1 3上を冷却水などの冷媒が循環する冷 却パイプ (「ウォータ. 'ジャケット」 という。) 3' 1 5を卷回し、 .卷回された冷却パイプ 3 .1 5を円筒形容器 3 1 1·の長手方向に支持する支持部材 3 1 6を設ける。 図示しないが、 ^却 :水を冷却ノ イブ 3 1 5'に供給するポンプ装置および電磁誘導コイル 3 1 3に電流を供給する 高周波電源を設けることはいうまでもない。.図 3に示す高周波電源接続端子位置 3 1 7は、 . 電磁誘導コイル 3 1 3との端子位置である。 また、 図 3から明らかなようにコイル支持部材 3 1 および '3. 1 6を解除するこどによ όて、 密閉室 3内のクリーニングのために円筒形容 器 3 1 1を電磁誘導コイル 3 1 3と一体的に 2分割できるように設計ずるこ.とも可能である。 取付けボルト位置 3 1 8は円筒容器 3 1 1と密閉室 3の上流側との接合部であり、,取付けボ ノレト位置 3 1 9は円筒容器 3 1 1と密閉窒 3の下流側との接合部であるが、 これらは密閉室 . 3どして一体的に形成するようにレてもよい。 電磁誘導加熱による円筒形容 3 1 1の温度. を計測し、 電磁誘導コイル 3 1 3の高周波電源への電圧を制御することによって円筒形容器 3 1 .1の内部温度を調整するために、 断熱材 3 1 2を貫通する熱電対の温度センサー 3 2 0 を円筒形容器 3 1 1に適宜設けることができる。 熱分解加熱部 3 1を円筒形容器 3 1 1と断 熱材 3 1 2とウォータ ·ジャケット 3 1 5から構成したことにより、 円筒容器 3 1 1が電磁 誘導による 5 0 0から 1 0 0 0 °Cに熱した場合であっても熱分解加熱部 3 1の外周温度は約 4 0 °C程度に保たせることができるので、 円筒形容器内部への外気流入にともなう燃焼また は燃焼爆発さえ制御できれば、 作業上の安全性や火災の危険は一切生じない。 The pyrolysis heating unit 31 by electromagnetic induction is formed between the upstream side and the downstream side of the sealed chamber 3. As shown in Fig. 3, the pyrolysis heating unit 3 1 consists of a cylindrical container 3 1 1 made of a conductive material that generates heat by electromagnetic induction heating, and its outer periphery is covered with a heat insulating material 3 1 '2. The coil support members 3 1 4 provided on both ends of the outer periphery of the cylindrical container 3 1 1 can support the electromagnetic induction heating coil 3 1 3 wound around the outer periphery of the heat insulating material 3 1 2 . In addition, a cooling pipe in which coolant such as cooling water circulates on the electromagnetic induction heating unit 3 1 3 (referred to as “water jacket”) 3 '1 5 is wound, and the cooled cooling pipe 3 .1 A support member 3 1 6 is provided to support 5 in the longitudinal direction of the cylindrical container 3 1 1. Although not shown, ^ retirement: cooling Bruno drive 3 1 5 'to the supply pump device and providing the high frequency power source for supplying a current to the electromagnetic induction coil 3 1 3 course water. 3. The high frequency power supply connection terminal position 3 17 shown in FIG. 3 is the terminal position with the electromagnetic induction coil 3 13. In addition, as is apparent from FIG. 3, the cylindrical container 3 1 1 is connected to the electromagnetic induction coil 3 for cleaning the inside of the sealed chamber 3 by releasing the coil support members 3 1 and '3.16. It is also possible to design it so that it can be divided into 1 and 3 in two. Mounting bolt position 3 1 8 is the joint between the cylindrical vessel 3 1 1 and the upstream side of the sealed chamber 3, and mounting bolt position 3 1 9 is the joint between the cylindrical vessel 3 1 1 and the downstream side of the sealed nitrogen 3. Although these are the parts, these may be integrally formed in a sealed chamber. In order to adjust the internal temperature of the cylindrical container 3 1 .1 by measuring the temperature of the cylindrical volume 3 1 1 by electromagnetic induction heating and controlling the voltage to the high frequency power supply of the electromagnetic induction coil 3 1 3 A thermocouple temperature sensor 3 2 0 penetrating the material 3 1 2 can be appropriately provided in the cylindrical container 3 1 1. The pyrolysis heating unit 3 1 is composed of a cylindrical container 3 1 1, a heat insulating material 3 1 2 and a water jacket 3 1 5, so that the cylindrical container 3 1 1 is electromagnetically induced from 5 0 0 to 1 0 0 0 Even when heated to ° C, the outer peripheral temperature of the pyrolysis heating unit 31 can be kept at about 40 ° C, so combustion or even combustion explosion due to inflow of outside air into the cylindrical container If it can be controlled, there will be no operational safety or fire hazard.
密閉室 3を上記のように構成することにより、 不活 ガス注入装置 6を用いて送込まれた 不活性ガスのガス圧力が少なくとも大気圧を上回るようにし、 外気を遮断して密閉室 3を無 酸素状態にすることができる。 さらに密閉室 3における熱分解によって発生し徐々に増大す る熱分解ガスのガス圧力と密閉室 3の上流側から'送込まれる不活性ガスのガス圧力とが少な くとも密閉室 3の下流側で均衡するような、 密閉室 3の上流側から下流側への不活性ガスの 圧力勾配を形成し、'熱分解ガスを下 側から上^ E側に逆流させることなく密閉室 3から排気 . するよ.うに密閉室 3内への不活性ガスの送込量 制御するようにすることもできる。 より具 体的には、 密閉室 3に投入され熱分解加熱部 3 1に順次送込まれた有機物含有廃棄物 1の連 続的熱分解は、 不活性ガス注入装置 6によって密閉室 3の内部に送込まれた不活性ガスのガ ス圧力: Pが常に大気圧 P 0を上回 、 ' .. '. ― .By configuring the sealed chamber 3 as described above, the gas pressure of the inert gas sent using the inert gas injection device 6 is set to exceed at least atmospheric pressure, the outside air is shut off, and the sealed chamber 3 is Anoxia can be achieved. Furthermore, it is generated by thermal decomposition in the sealed chamber 3 and gradually increases. The gas pressure of the pyrolysis gas and the gas pressure of the inert gas sent from the upstream side of the sealed chamber 3 are balanced from the upstream side of the sealed chamber 3 so that they are balanced at least downstream of the sealed chamber 3. A pressure gradient of the inert gas to the side is formed, and the pyrolysis gas is exhausted from the sealed chamber 3 without backflowing from the lower side to the upper side. The amount of feed can be controlled. More specifically, the continuous pyrolysis of the organic matter-containing waste 1 put into the sealed chamber 3 and sequentially sent to the pyrolysis heating unit 3 1 is performed by the inert gas injection device 6 inside the sealed chamber 3. Gas pressure of inert gas sent to the tank: P always exceeds the atmospheric pressure P 0 , '..'.
P〉P ( 1 ) . ' - - すなおち、 密閉室 3に不活性ガスによる正圧状態が形成され、.そのことにより、 密閉室への '大気の流入を.遮断し T無酸 状態にすることができるとともに、 密閉室の不活性ガスのガス 圧力が熱分解によって発生する熱分解ガスのガス圧力を常に上回る、 P〉 P (1). '--In other words, a positive pressure state due to the inert gas is formed in the sealed chamber 3, thereby blocking the inflow of air to the sealed chamber and making it non-acidic. The gas pressure of the inert gas in the sealed chamber always exceeds the gas pressure of the pyrolysis gas generated by pyrolysis,
P N > P G≥P H > P o ' ' · · ( 2 ) , P N > P G ≥P H > P o '' (2),
' すなわち、,.密閉室 3の上流側の不活性ガスのガズ圧力 P Nと熱分解加熱部 3 1の不活性ガス と熱分解ガスとの混合ガス圧力 P Gと下流側の主に熱分解ガスの,ガス圧力 P. Hとが、大気圧 P . 。を上回る不活性ガスの圧力勾配を^成し、 そのことにより、 密閉室において熱分解ガスの • 下流側から上流側への逆流を阻止レ、 · 熱分解ガスを排気孔 7 1を経由させて排気回収するこ とができる。 ^ . 'In other words, the gas pressure PN of the inert gas upstream of the sealed chamber 3 PN and the mixed gas pressure of the inert gas and pyrolysis gas of the pyrolysis heating unit 3 PG and mainly the pyrolysis gas downstream , Gas pressure P.H, but atmospheric pressure P.H. This creates a pressure gradient of inert gas that exceeds the flow rate, which prevents the backflow of pyrolysis gas from the downstream side to the upstream side in the sealed chamber. The exhaust can be recovered. ^.
次に、 発生した熱分解ガスは、 排気孔 7 1を経由させて排気回収装置 7·によ όて回収され '.る。 より具体的には、 大気を ι回る.密閉室 3の不活性ガスのガス圧力によって、 発生した熱1 .分解ガスは排気孔 7 1およびガス誘導管 7 2を通り外周を冷却水で冷やされる冷却 ¾置 7 3 を経由して油水分 装置 7 4に送られる。 'ここで油化物と水に分離され、 次に排気ファン 7 6によって.'、 残渣の熱分解ガスは油水分離装置 7 4からミスト分離装置 7 '5に吸引され、 こ こで洗浄された後に外部に排気される。 油水分離装置 7 4によって分離され、 回収装置によ つて回収された油化物は、 重油並みの発熱量を有しており、 例えば上記した乾燥装置の燃料 として再利用することができる。 Next, the generated pyrolysis gas is recovered by the exhaust recovery device 7 through the exhaust hole 71. More specifically, the air is turned ι. The heat generated by the gas pressure of the inert gas in the sealed chamber 3 1. The decomposed gas passes through the exhaust hole 71 and the gas induction pipe 72 and is cooled by cooling water at the outer periphery. It is sent to the oil and water device 7 4 via the cooling device 7 3. 'Here it is separated into oil and water, then by the exhaust fan 7 6', the residual pyrolysis gas is sucked from the oil / water separator 7 4 to the mist separator 7 '5 and then washed here Exhausted outside. The liquefied product separated by the oil / water separator 74 and recovered by the recovery device has a calorific value similar to that of heavy oil, and can be reused as fuel for the drying device described above, for example.
熱分解反応による残渣の炭化物は、 排出口 8 1を経由させて排出装置 8によって回収され る。 排出装置 8は横設された円筒形冷却装置 8 2と容器型回収装置 8 3とからなる。 円筒形 冷却装置 8 2は、 上流側に密閉室 3の排出口 8 1に接続する投入口 8 2 1から投入された残 渣の炭化物が搬送スクリューによって送られ、 ここで冷却された後に、 下流側に設けた排出 口 8 2 2から容器型回収装置 8 3に排出されるようにしたものである。 残渣の炭化物は飛散 . The residual carbides from the pyrolysis reaction are recovered by the discharge device 8 via the discharge port 8 1. The discharge device 8 includes a horizontal cylindrical cooling device 8 2 and a container type recovery device 8 3. Cylindrical cooling device 8 2 has an upstream side that is connected to discharge port 8 1 of sealed chamber 3. It is designed to be discharged from the discharge port 8 2 2 provided on the side to the container type recovery device 8 3. Residual carbides are scattered .
し粉塵状態になりやすいので、 そうした飛散を防ぐために排出口 8 2 2または容器型回収装 置 8 3の入口に機密性シャッターを設ける,ようにすることが好ましい。 ところで、 回収され た炭化物は固^^燃料とすることによって石炭並みの発熱量を有し、 固形燃料として再資源化 .できることも指摘しておく。 Since it tends to become dusty, it is preferable to provide a confidential shutter at the outlet 8 22 or the inlet of the container-type collection device 8 3 in order to prevent such scattering. By the way, it should be pointed out that the recovered carbide has a calorific value similar to that of coal, and can be recycled as solid fuel.
5 図 2からは、,本発明に係る有機物含有廃棄物 1の熱分解方法および装置並びに熱分解ガス 化システムの始動時から通常運転に至る動作手順が明らかになる。 破砕、 乾燥おょぴ固化成 型された有機物含有廃棄物 1の処 a物量が準備され、 不活性ガス ¾入装置 6の作動確認、-密 閉室 3の熱分解加熱部 3 1の冷却水循¾の確認、その他の各^の設定と動作を確認した後に、 主電源をオン状態にする。熱分解加熱部 3 1の温度は 8 5 0 °Cに設定し、図 2にみるように、 10 密閉搬送路 2の搬送装置を躯動する。 搬送されてきた有 物含有廃棄物 1は、. 上段シャツタ ' 一が開状態で卞段シャッターが閉状態の搬送室 4' 2に至り一時的.に滞留される。 その搬送室 4 2に連通された不活性ガス注入口 6 2を介して不活性ガスが送込まれる。..送込まれた不活. 性ガスは,開状態の上段シャッターを通り密閉搬送路 2に流れ込む。 5 From FIG. 2, the thermal decomposition method and apparatus for organic matter-containing waste 1 according to the present invention and the operation procedure from the start of the pyrolysis gasification system to normal operation become clear. Crushing, drying and solidification of organic waste containing organic waste 1 The amount of waste is prepared, the inert gas ¾Introduction device 6 is checked, -The closed chamber 3 pyrolysis heating section 3 1 cooling water circulation After confirming ¾ and other settings and operations, turn on the main power. The temperature of the pyrolysis heating unit 3 1 is set to 85 ° C., and as shown in FIG. The waste-containing waste 1 that has been transported is temporarily retained by reaching the transport chamber 4 '2 in which the upper shirt is open and the shutter is closed. An inert gas is sent through an inert gas inlet 62 connected to the transfer chamber 42. The inactive gas sent in passes through the upper shutter in the open state and flows into the sealed conveyance path 2.
同様に不活性ガス注入 6 1を介して密閉室 3に不活性ガス力 S送込まれ、.連 ffi孔 5 1 1か 15 らなる連通装置 5 2により、 送込まれた不活性ガスは密閉室 3の下流側に流れ込み密閉室の . 空気を追い出すとともに、 密閉室 の内部には不活性ガス雰囲気が形成される。 次に、 搬送 .室 4 2の上段ジャッターが閉じられ下段シャッターが開かれることよつ T 不活性ガス注入 口 6 2から送込まれた不活性ガスは、 不活性ガス雰囲気の密閉室 3に流れ込み、 不活性ガス '.溜まりが形成される。 滞留された有機物含有廃棄物 1は、 こうして形成された不活性ガス溜 20 まりに投入される。 その投入された有機物含有廃棄物 1は、 往復動装置 5のプッシヤー板 5 1の前進ストロークによって、 少なく とも熱分解加熱部 3 1ま 送込まれる。 . Similarly, the inert gas force S is sent to the sealed chamber 3 via the inert gas injection 61, and the sent inert gas is sealed by the communication device 5 2 consisting of the communication holes 5 1 1 to 15. It flows into the downstream side of the chamber 3 and expels the air in the sealed chamber, and an inert gas atmosphere is formed inside the sealed chamber. Next, the upper stage of the transfer chamber 4 2 is closed and the lower stage shutter is opened. T Inert gas sent from the inert gas inlet 6 2 flows into the sealed chamber 3 of the inert gas atmosphere. Inert gas'. A puddle is formed. The accumulated organic matter-containing waste 1 is put into the inert gas reservoir formed in this way. The introduced organic matter-containing waste 1 is sent to at least the pyrolysis heating section 31 by the forward stroke of the pusher plate 51 of the reciprocating device 5. .
密閉室 3の熱分解加熱部 3 1に送込まれた有機物含有廃棄物:^は、 8 5 0 °Cの熱分解加熱 部において熱分解反応が生じる。 ここで有機物含有廃棄物 1に含まれるプラスチックなどが 熱分解ガスになり、 紙や繊維などが炭化物になる。 こうした熱分解反応が生じるまでの密閉 25 室 3の不活性ガス溜まりまたは不活性ガス雰囲気において、 図 2からも明らかなように、 搬 送室 4 2の上段シャッターが閉じられ下段シャッターが開かれた際には、 搬送室 4 2の不活 性ガスのガス圧力は、 不活性ガス注入口 6 2を介して送込まれる不活性ガスによって、 不活 性ガス注入口 6 1を介して送込まれる不活性ガスによって形成される不活性ガス雰囲気の密 閉室 3のガス圧力を上回る。 熱分解加熱部 3 1において熱分解反応が始まり、 それにともな 30 い発生する熱分解ガスのガス圧力を常に上回るように、 ガス圧力センサー 6 4 1から 6 4 4 ■ Organic waste containing ^: sent to the pyrolysis heating section 31 of the sealed chamber 3 undergoes a pyrolysis reaction in the pyrolysis heating section at 85 ° C. Here, the plastic contained in the organic matter-containing waste 1 becomes pyrolysis gas, and paper and fibers become carbide. As shown in Fig. 2, the upper shutter of the transfer chamber 4 2 was closed and the lower shutter was opened in an inert gas pool or inert gas atmosphere in the sealed 25 chamber 3 until the thermal decomposition reaction occurred. At that time, the gas pressure of the inert gas in the transfer chamber 42 is sent via the inert gas inlet 61 by the inert gas sent via the inert gas inlet 62. The gas pressure in the closed chamber 3 of the inert gas atmosphere formed by the inert gas is exceeded. Gas pressure sensors 6 4 1 to 6 4 4 so that the pyrolysis reaction starts in the pyrolysis heating section 3 1 and always exceeds the gas pressure of the pyrolysis gas that is generated. ■
を用いて密閉室 3のガス圧力を監視しながち、.ぞれ.らと連動させて、 不^性.ガス注入装置 6 から密閉室 3への不活性ガスの送达量を^御する。 このことにより、 密閉室 3の内部のガス 圧力が常に大気圧を上回るようにす'ることが可能となり、 同時に密閉室の上流側から下流側 に向力つて不活性ガスの圧力勾配を形成すること'も可能となる。 The gas pressure in the sealed chamber 3 is monitored using the, and in conjunction with each other, the inertness is controlled. The amount of inert gas delivered from the gas injection device 6 to the sealed chamber 3 is controlled. . This makes it possible to ensure that the gas pressure inside the sealed chamber 3 always exceeds the atmospheric pressure, and at the same time forms a pressure gradient of the inert gas from the upstream side to the downstream side of the sealed chamber. It's also possible.
密閉搬送路 2を経由して送られてくる有機物含有廃棄物 1は、 2段シャッター装置 4 3で 区画される.搬送室 4 2おいて一時的に滞留しながら順次密閉室 3に投入され、 順次投入され た有機物含有廃棄物 1は、 往復動'装置 5のプッシヤー板 5 1の往復動により密閉室 3の勢分 解加熱部 3 1に.順次送込まれる。 発 ½した熱分解ガスは、 密閉室 3の内部に ¾成された不活 性ガスの圧力勾配によって、 排気孔 7 1に確実に送込まれることになる。 また残渣の炭化物 は、 例えばプッシヤー板 5 2の前進ス トロークを排出口 8 1近傍にまで伸ばすことによって 排出することもできる。 これ以外に排出装 を別途設けることも可能である。 Organic matter-containing waste 1 sent via the closed transfer path 2 is partitioned by the two-stage shutter device 4 3. The transfer chamber 4 2 is put into the closed chamber 3 sequentially while staying temporarily, The organic material-containing wastes 1 that are sequentially fed are sequentially fed to the decomposition heating unit 31 of the sealed chamber 3 by the reciprocating motion of the pusher plate 51 of the reciprocating device 5. The generated pyrolysis gas is surely sent into the exhaust hole 71 due to the pressure gradient of the inert gas formed inside the sealed chamber 3. Residual carbides can also be discharged by extending the forward stroke of the pusher plate 52 to the vicinity of the discharge port 81, for example. In addition to this, it is also possible to provide a separate discharge device.
本発明ば、 実施例およびフロチャートで示した動作手順からも明らかなように、、 上記しだ ような効^:を奏するおのである。 さらに、 大気汚染物質をほとんど発生させることなく有機 物含有廃棄物を連続的に熱分解可能にし.、 加熱温度設定を処理^;の性状、 .種類に応じて調整 することも 能にするものである。 : ■ According to the present invention, as apparent from the operation procedures shown in the embodiments and flowcharts, the above-described effects are exhibited. In addition, waste containing organic matter can be continuously thermally decomposed with almost no air pollutants, and the heating temperature can be adjusted according to the nature and type of treatment ^ ;. is there. : ■
Claims
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
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| JP2007513534A JP4015181B1 (en) | 2006-10-31 | 2006-10-31 | Method and apparatus for thermal decomposition of waste containing organic matter |
| PCT/JP2006/322220 WO2008053571A1 (en) | 2006-10-31 | 2006-10-31 | Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system |
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| PCT/JP2006/322220 WO2008053571A1 (en) | 2006-10-31 | 2006-10-31 | Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106574188A (en) * | 2014-07-15 | 2017-04-19 | 阿尔帕亚尔集团有限责任公司 | Method of continuous production of liquid and gaseous fuels from part of organic substances in waste |
| JP2019052234A (en) * | 2017-09-14 | 2019-04-04 | 小林 大志 | Gasification furnace and organic gasification method |
| JP2023057600A (en) * | 2021-10-12 | 2023-04-24 | 株式会社Lixil | Combustible gas recovery equipment |
| US12151404B2 (en) | 2019-09-06 | 2024-11-26 | TyReCycle a.s. | Method for the continuous thermal processing of used, damaged or otherwise degraded tires, and a device for carrying out this method |
| WO2025166392A1 (en) * | 2024-02-05 | 2025-08-14 | Jenascent Gmbh | Reactor for producing coal and synthesis gas from biomass |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102452134B1 (en) * | 2021-02-24 | 2022-10-07 | 에코링크 주식회사 | Pyrolysis furnace system for waste plastic treatment and pyrolysis method of waste plastic |
| KR102851798B1 (en) * | 2023-09-14 | 2025-08-29 | 이건국 | Vehicle-type garbage collection system with high-temperature induction heating means |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH026105A (en) * | 1988-06-24 | 1990-01-10 | Sumitomo Metal Ind Ltd | Plastic waste processing equipment |
| JPH05237467A (en) * | 1992-02-27 | 1993-09-17 | Sanwa Kako Kk | Apparatus for thermally decomposing waste plastic |
| JP2001121536A (en) * | 1999-10-26 | 2001-05-08 | Sanetsu:Kk | Waste plastic volume reduction method and equipment |
-
2006
- 2006-10-31 JP JP2007513534A patent/JP4015181B1/en not_active Expired - Fee Related
- 2006-10-31 WO PCT/JP2006/322220 patent/WO2008053571A1/en not_active Ceased
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH026105A (en) * | 1988-06-24 | 1990-01-10 | Sumitomo Metal Ind Ltd | Plastic waste processing equipment |
| JPH05237467A (en) * | 1992-02-27 | 1993-09-17 | Sanwa Kako Kk | Apparatus for thermally decomposing waste plastic |
| JP2001121536A (en) * | 1999-10-26 | 2001-05-08 | Sanetsu:Kk | Waste plastic volume reduction method and equipment |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106574188A (en) * | 2014-07-15 | 2017-04-19 | 阿尔帕亚尔集团有限责任公司 | Method of continuous production of liquid and gaseous fuels from part of organic substances in waste |
| US20170174997A1 (en) * | 2014-07-15 | 2017-06-22 | ALPAJAR GROUP s.r.o | Method of continuous production of liquid and gaseous fuels from the part of organic substances in the waste |
| JP2019052234A (en) * | 2017-09-14 | 2019-04-04 | 小林 大志 | Gasification furnace and organic gasification method |
| US12151404B2 (en) | 2019-09-06 | 2024-11-26 | TyReCycle a.s. | Method for the continuous thermal processing of used, damaged or otherwise degraded tires, and a device for carrying out this method |
| JP2023057600A (en) * | 2021-10-12 | 2023-04-24 | 株式会社Lixil | Combustible gas recovery equipment |
| WO2025166392A1 (en) * | 2024-02-05 | 2025-08-14 | Jenascent Gmbh | Reactor for producing coal and synthesis gas from biomass |
Also Published As
| Publication number | Publication date |
|---|---|
| JPWO2008053571A1 (en) | 2010-02-25 |
| JP4015181B1 (en) | 2007-11-28 |
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