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WO2024227724A3 - Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur - Google Patents

Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur Download PDF

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Publication number
WO2024227724A3
WO2024227724A3 PCT/EP2024/061722 EP2024061722W WO2024227724A3 WO 2024227724 A3 WO2024227724 A3 WO 2024227724A3 EP 2024061722 W EP2024061722 W EP 2024061722W WO 2024227724 A3 WO2024227724 A3 WO 2024227724A3
Authority
WO
WIPO (PCT)
Prior art keywords
stream
olefins
oligomerization
catalyst
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/EP2024/061722
Other languages
English (en)
Other versions
WO2024227724A2 (fr
Inventor
Niels Christian Schjødt
Esben Taarning
Rasmus Yding BROGAARD
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Priority to CN202480029614.4A priority Critical patent/CN121039255A/zh
Publication of WO2024227724A2 publication Critical patent/WO2024227724A2/fr
Publication of WO2024227724A3 publication Critical patent/WO2024227724A3/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
    • C10G65/16—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only including only refining steps
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C10G69/126—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step polymerisation, e.g. oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4056—Retrofitting operations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé et une installation de production de produits hydrocarbonés à partir d'éthylène, le procédé consistant à : a) convertir un flux d'éthylène dans un premier réacteur d'oligomérisation par mise en contact dudit flux d'éthylène avec un catalyseur d'oligomérisation, ledit catalyseur d'oligomérisation étant un catalyseur homogène comprenant : un composé ou un complexe de métal de transition comprenant au moins l'un parmi Ti, Zr, Cr, Ni, avec un composé d'aluminium alkyle dissous dans un solvant hydrocarboné ou un solvant éthéré ; ou un composé d'aluminium alkyle dissous dans un solvant hydrocarboné ou un solvant éthéré, éventuellement en tant que co-catalyseur ; afin de produire un premier flux alpha-oléfines linéaires (LAO) dans la plage C2-C20 dont au moins 80 % en poids ont une distribution de Schultz-Flory avec une probabilité de propagation de chaîne (alpha) comprise entre 0,35 et 0,60, ou une distribution de Poisson avec une probabilité de propagation de chaîne (lambda) comprise entre 1,0 et 4,7 ; b -1) séparer ledit premier flux d'alpha-oléfines linéaires dans la plage C2-C20 en un deuxième flux d'oléfines C2, c'est-à-dire un flux d'éthylène (C2=) séparé, un troisième flux d'oléfines C4-C6, et un quatrième flux d'oléfines C8+, telles que des oléfines C8-C20 ; et b -2) recycler au moins une partie du deuxième flux d'oléfines C2 de l'étape b-1) dans le premier réacteur d'oligomérisation ; c-1) convertir le troisième flux d'oléfines C4-C6 de l'étape b-1) dans un deuxième réacteur d'oligomérisation dans des conditions de trimérisation, c'est-à-dire un réacteur de trimérisation, en mettant en contact le troisième flux d'oléfines C4-C6 de l'étape b-1) avec un catalyseur d'oligomérisation, éventuellement un catalyseur d'oligomérisation tel que défini à l'étape a), pour produire un cinquième flux d'oléfines C12-C18 ramifiées ayant un indice de ramification (BI) supérieur à 0,30. Le procédé peut en outre consister à convertir des cinquième et quatrième flux de produits en kérosène paraffinique synthétique (SPK). L'invention concerne également un procédé d'adaptation d'installations d'hydrotraitement existantes.
PCT/EP2024/061722 2023-05-02 2024-04-29 Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur Pending WO2024227724A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202480029614.4A CN121039255A (zh) 2023-05-02 2024-04-29 生产合成链烷烃煤油作为喷气燃料的工艺和设备

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP23171096 2023-05-02
EP23171096.3 2023-05-02

Publications (2)

Publication Number Publication Date
WO2024227724A2 WO2024227724A2 (fr) 2024-11-07
WO2024227724A3 true WO2024227724A3 (fr) 2025-03-27

Family

ID=86328396

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2024/061722 Pending WO2024227724A2 (fr) 2023-05-02 2024-04-29 Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur

Country Status (2)

Country Link
CN (1) CN121039255A (fr)
WO (1) WO2024227724A2 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4439309A (en) * 1982-09-27 1984-03-27 Chem Systems Inc. Two-stage hydrogen donor solvent cracking process
US5744677A (en) * 1991-10-16 1998-04-28 Amoco Corporation Ethylene oligomerization
US20070112150A1 (en) * 2005-07-21 2007-05-17 Small Brooke L Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
WO2016067032A1 (fr) * 2014-10-30 2016-05-06 Battelle Memorial Institute Systèmes et procédés de conversion de matières premières à base d'éthylène en carburants hydrocarbonés
US20200063045A1 (en) * 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing a base stock
US20220396534A1 (en) * 2022-04-06 2022-12-15 ExxonMobil Technology and Engineering Company Methods for Converting C2+ Olefins to Higher Carbon Number Olefins

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK162891A (da) 1991-09-23 1993-03-24 Haldor Topsoe As Fremgangsmaade og reaktor til gennemfoerelse af ikke-adiabatiske reaktioner.
EA015044B1 (ru) 2006-02-08 2011-04-29 Сауди Бейсик Индастриз Корпорейшн Способ олигомеризации этилена
EP2738151B8 (fr) 2012-11-28 2014-12-17 Saudi Basic Industries Corporation Procédé d'oligomérisation de l'éthylène
SG11201903179WA (en) 2016-10-14 2019-05-30 Gevo Inc Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols
EP3574991A1 (fr) 2018-05-31 2019-12-04 Haldor Topsøe A/S Reformage à la vapeur chauffée par un chauffage à résistance
US11377607B2 (en) 2020-03-23 2022-07-05 Exxonmobil Chemical Patents Inc. Branched paraffinic compositions derived from isomerized and hydrogenated linear alpha olefins

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4439309A (en) * 1982-09-27 1984-03-27 Chem Systems Inc. Two-stage hydrogen donor solvent cracking process
US5744677A (en) * 1991-10-16 1998-04-28 Amoco Corporation Ethylene oligomerization
US20070112150A1 (en) * 2005-07-21 2007-05-17 Small Brooke L Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
WO2016067032A1 (fr) * 2014-10-30 2016-05-06 Battelle Memorial Institute Systèmes et procédés de conversion de matières premières à base d'éthylène en carburants hydrocarbonés
US20200063045A1 (en) * 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing a base stock
US20220396534A1 (en) * 2022-04-06 2022-12-15 ExxonMobil Technology and Engineering Company Methods for Converting C2+ Olefins to Higher Carbon Number Olefins

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EAGAN NATHANIEL M ET AL: "Chemistries and processes for the conversion of ethanol into middle-distillate fuels", NATURE REVIEWS CHEMISTRY, NATURE PUBLISHING GROUP UK, LONDON, vol. 3, no. 4, 20 March 2019 (2019-03-20), pages 223 - 249, XP036750009, DOI: 10.1038/S41570-019-0084-4 *

Also Published As

Publication number Publication date
CN121039255A (zh) 2025-11-28
WO2024227724A2 (fr) 2024-11-07

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