[go: up one dir, main page]

WO2024227723A3 - Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur - Google Patents

Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur Download PDF

Info

Publication number
WO2024227723A3
WO2024227723A3 PCT/EP2024/061720 EP2024061720W WO2024227723A3 WO 2024227723 A3 WO2024227723 A3 WO 2024227723A3 EP 2024061720 W EP2024061720 W EP 2024061720W WO 2024227723 A3 WO2024227723 A3 WO 2024227723A3
Authority
WO
WIPO (PCT)
Prior art keywords
stream
olefins
catalyst
plant
ethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/EP2024/061720
Other languages
English (en)
Other versions
WO2024227723A2 (fr
Inventor
Esben Taarning
Rasmus Yding BROGAARD
Niels Christian Schjødt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Priority to CN202480029628.6A priority Critical patent/CN121039256A/zh
Publication of WO2024227723A2 publication Critical patent/WO2024227723A2/fr
Publication of WO2024227723A3 publication Critical patent/WO2024227723A3/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C10G69/126—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step polymerisation, e.g. oligomerisation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4056—Retrofitting operations
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé et une installation de production de produits hydrocarbonés à partir d'éthylène, le procédé comprenant : a) la conversion d'un flux d'éthylène dans un réacteur d'oligomérisation par mise en contact dudit flux d'éthylène avec un catalyseur d'oligomérisation, ledit catalyseur d'oligomérisation étant un catalyseur homogène comprenant : un composé ou un complexe de métal de transition comprenant au moins l'un parmi Ti, Zr, Cr, Ni, conjointement avec un composé d'aluminium alkyle dissous dans un solvant hydrocarboné ou un solvant éthéré ; ou un composé d'aluminium alkyle dissous dans un solvant hydrocarboné ou un solvant éthéré, éventuellement en tant que co-catalyseur ; de production d'un premier flux d'alpha-oléfines linéaires (AOL) dans la plage C2-C30, dont au moins 80 % en poids ont une distribution de Schultz-Flory avec une probabilité de propagation de chaîne (alpha) de 0,49-0,73, ou une distribution de Poisson avec une probabilité de propagation de chaîne (lambda) de 3,5 à 8,5 ; b-1) séparer ledit premier flux d'alpha-oléfines linéaires dans la plage C2-C30 en un deuxième flux d'oléfines C2-C6, un troisième flux d'oléfines et de paraffines en C8-C18, et un quatrième flux d'oléfines et de paraffines en C18-C30 + ; et b-2) recycler au moins une partie du deuxième flux d'oléfines en C2-C6 de l'étape b-1) au réacteur d'oligomérisation. Le procédé peut en outre consister à convertir le troisième et le quatrième flux en kérosène paraffinique synthétique (KPS). L'invention concerne également un procédé d'adaptation d'installations d'hydrotraitement existantes.
PCT/EP2024/061720 2023-05-02 2024-04-29 Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur Pending WO2024227723A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202480029628.6A CN121039256A (zh) 2023-05-02 2024-04-29 生产作为喷气燃料的合成链烷烃煤油的方法和设备

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP23171099.7 2023-05-02
EP23171099 2023-05-02

Publications (2)

Publication Number Publication Date
WO2024227723A2 WO2024227723A2 (fr) 2024-11-07
WO2024227723A3 true WO2024227723A3 (fr) 2025-03-27

Family

ID=86328496

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2024/061720 Pending WO2024227723A2 (fr) 2023-05-02 2024-04-29 Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur

Country Status (2)

Country Link
CN (1) CN121039256A (fr)
WO (1) WO2024227723A2 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US12415962B2 (en) * 2023-11-10 2025-09-16 Marathon Petroleum Company Lp Systems and methods for producing aviation fuel

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002000339A2 (fr) * 2000-06-30 2002-01-03 Shell Internationale Research Maatschappij B.V. Ligands et systemes de catalyseur contenant ceux-ci pour l'oligomerisation d'ethylene en alpha olefines lineaires
EP2199373A1 (fr) * 2007-09-28 2010-06-23 Japan Oil Gas and Metals National Corporation Procédé de fabrication de carburant diesel
WO2014154798A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbures de distillat moyen
US8957270B2 (en) * 2010-05-06 2015-02-17 IFP Energies Nouvelles Process for the production of a fuel base from an ethylene feedstock implementing at least one oligomerization stage in the presence of a homogeneous catalytic system
US20150247100A1 (en) * 2013-07-03 2015-09-03 David Bradin Process for producing renewable jet fuel compositions
WO2016067032A1 (fr) * 2014-10-30 2016-05-06 Battelle Memorial Institute Systèmes et procédés de conversion de matières premières à base d'éthylène en carburants hydrocarbonés
WO2019084518A1 (fr) * 2017-10-27 2019-05-02 Xyleco, Inc. Traitement de la biomasse
US20200063049A1 (en) * 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US20220396534A1 (en) * 2022-04-06 2022-12-15 ExxonMobil Technology and Engineering Company Methods for Converting C2+ Olefins to Higher Carbon Number Olefins

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK162891A (da) 1991-09-23 1993-03-24 Haldor Topsoe As Fremgangsmaade og reaktor til gennemfoerelse af ikke-adiabatiske reaktioner.
EA015044B1 (ru) 2006-02-08 2011-04-29 Сауди Бейсик Индастриз Корпорейшн Способ олигомеризации этилена
EP2738151B8 (fr) 2012-11-28 2014-12-17 Saudi Basic Industries Corporation Procédé d'oligomérisation de l'éthylène
SG11201903179WA (en) 2016-10-14 2019-05-30 Gevo Inc Conversion of mixtures of c2-c8 olefins to jet fuel and/or diesel fuel in high yield from bio-based alcohols
EP3574991A1 (fr) 2018-05-31 2019-12-04 Haldor Topsøe A/S Reformage à la vapeur chauffée par un chauffage à résistance
US11377607B2 (en) 2020-03-23 2022-07-05 Exxonmobil Chemical Patents Inc. Branched paraffinic compositions derived from isomerized and hydrogenated linear alpha olefins

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002000339A2 (fr) * 2000-06-30 2002-01-03 Shell Internationale Research Maatschappij B.V. Ligands et systemes de catalyseur contenant ceux-ci pour l'oligomerisation d'ethylene en alpha olefines lineaires
EP2199373A1 (fr) * 2007-09-28 2010-06-23 Japan Oil Gas and Metals National Corporation Procédé de fabrication de carburant diesel
US8957270B2 (en) * 2010-05-06 2015-02-17 IFP Energies Nouvelles Process for the production of a fuel base from an ethylene feedstock implementing at least one oligomerization stage in the presence of a homogeneous catalytic system
WO2014154798A1 (fr) * 2013-03-28 2014-10-02 Bp P.L.C. Production d'une composition d'hydrocarbures de distillat moyen
US20150247100A1 (en) * 2013-07-03 2015-09-03 David Bradin Process for producing renewable jet fuel compositions
WO2016067032A1 (fr) * 2014-10-30 2016-05-06 Battelle Memorial Institute Systèmes et procédés de conversion de matières premières à base d'éthylène en carburants hydrocarbonés
WO2019084518A1 (fr) * 2017-10-27 2019-05-02 Xyleco, Inc. Traitement de la biomasse
US20200063049A1 (en) * 2018-08-22 2020-02-27 Exxonmobil Research And Engineering Company Manufacturing hydrocarbons
US20220396534A1 (en) * 2022-04-06 2022-12-15 ExxonMobil Technology and Engineering Company Methods for Converting C2+ Olefins to Higher Carbon Number Olefins

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
EAGAN NATHANIEL M ET AL: "Chemistries and processes for the conversion of ethanol into middle-distillate fuels", NATURE REVIEWS CHEMISTRY, NATURE PUBLISHING GROUP UK, LONDON, vol. 3, no. 4, 20 March 2019 (2019-03-20), pages 223 - 249, XP036750009, DOI: 10.1038/S41570-019-0084-4 *

Also Published As

Publication number Publication date
WO2024227723A2 (fr) 2024-11-07
CN121039256A (zh) 2025-11-28

Similar Documents

Publication Publication Date Title
KR102184256B1 (ko) 최소 1-부텐 함량을 갖는 c4 흐름의 올리고머화
Forestière et al. Oligomerization of monoolefins by homogeneous catalysts
Belov et al. Processes for the production of higher linear α-olefins.
CN101848880B (zh) 整合烯烃裂化与复分解以增加轻质烯烃产量
RU2012101476A (ru) Олигомеризация альфа-олефинов с применением каталитических систем металлоцен-тск и применение полученных полиальфаолефинов для получения смазывающих смесей
EP2711349A1 (fr) Procédé de production de butadiène-1,3 mettant en oeuvre la dimérisation de l'éthylène et la déshydrogénation des butènes obtenus
WO2024227723A3 (fr) Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur
FR2984311A1 (fr) Procede de production d'octenes mettant en oeuvre la dimerisation de l'ethylene en butenes et la dimerisation des butenes en octenes
US8344196B2 (en) Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels
CN107282129B (zh) 一种乙烯三聚、四聚催化剂组合物及其应用
US8350107B2 (en) Selective isomerization and oligomerization of olefin feedstocks for the production of turbine and diesel fuels
US8957270B2 (en) Process for the production of a fuel base from an ethylene feedstock implementing at least one oligomerization stage in the presence of a homogeneous catalytic system
Small et al. Comparative Dimerization of 1‐Butene with a Variety of Metal Catalysts, and the Investigation of a New Catalyst for C H Bond Activation
CA2707120C (fr) Composition de catalyseur et procede d'obtention d'alpha-olefines lineaires
CN102746095B (zh) 苯和甲醇或二甲醚制石油级甲苯的方法
Belov Catalytic synthesis of higher olefins from ethylene
CA2990185A1 (fr) Procede de fabrication d'ether de methyle et de tert-butyle (mtbe) et d'hydrocarbures
Li et al. Characterization of the NiSO4 site on a NiSO4-ReOx/γ-Al2O3 catalyst for tandem conversion of ethylene to propylene
WO2024227724A3 (fr) Procédé et installation de production de kérosène paraffinique synthétique en tant que carburéacteur
US8618342B2 (en) Process for the production of alkylbenzenes from an olefinic feedstock produced by oligomerization that is catalyzed homogeneously
US3829520A (en) Inhibition of olefin isomerization and reverse displacement in catalytic displacement reactions
CN107282133B (zh) 乙烯四聚催化剂组合物及应用
AU2023249904A1 (en) Renewable kerosene fuel having excellent properties at low temperatures
US4737479A (en) Process for the oligomerization of olefins and a catalyst thereof
CN102285854B (zh) 增产丙烯、乙烯和丁二烯的方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 24722608

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: 2024722608

Country of ref document: EP