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WO2024180261A3 - Oxyde d'éthylène respectueux de l'environnement, oxyde de propylène et produits en aval - Google Patents

Oxyde d'éthylène respectueux de l'environnement, oxyde de propylène et produits en aval Download PDF

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Publication number
WO2024180261A3
WO2024180261A3 PCT/EP2024/055617 EP2024055617W WO2024180261A3 WO 2024180261 A3 WO2024180261 A3 WO 2024180261A3 EP 2024055617 W EP2024055617 W EP 2024055617W WO 2024180261 A3 WO2024180261 A3 WO 2024180261A3
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WO
WIPO (PCT)
Prior art keywords
alkoxylated
polyamines
oligo
polyethylenimines
ethanolamines
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Pending
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PCT/EP2024/055617
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English (en)
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WO2024180261A2 (fr
Inventor
Stephan Hueffer
Marco Krueger
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BASF SE
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BASF SE
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Priority to CN202480016027.1A priority Critical patent/CN121079338A/zh
Publication of WO2024180261A2 publication Critical patent/WO2024180261A2/fr
Publication of WO2024180261A3 publication Critical patent/WO2024180261A3/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C01C1/0488—Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/04—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton by reaction of ammonia or amines with olefin oxides or halohydrins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2618—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen
    • C08G65/2621—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing nitrogen containing amine groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C25B15/081—Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

La présente invention concerne un procédé de préparation d'oxyde d'éthylène ou d'oxyde de propylène comprenant (b) la réaction d'hydrogène avec des oxydes de carbone pour former du méthanol, (c) la conversion du méthanol de l'étape (b) en éthène et/ou propène, (d) la réaction de l'éthène et/ou du propène de l'étape (c) avec de l'oxygène ou un agent oxydant pour former de l'oxyde d'éthylène et/ou de l'oxyde de propylène, le dioxyde de carbone dans l'étape (b) étant au moins en partie capturé à partir de gaz de combustion industriels ou d'air ou d'eau océanique ou d'autres eaux naturelles ou obtenu à partir de processus biologiques, par exemple à partir de processus de fermentation à partir de déchets ou de biomasse, et/ou l'hydrogène dans l'étape (b) étant obtenu au moins en partie par dissociation de l'eau, la dissociation de l'eau utilisant de préférence l'énergie générée au moins en partie à partir de ressources non fossiles ; un procédé de préparation d'éthanolamines, un procédé de préparation de composés alcoxylés, un procédé de fabrication de diamines, d'oligoamines et de polyamines alcoxylées ou de polyéthylèneimine alcoxylée, un procédé de fabrication de polyéthylèneimine alcoxylée, un procédé de fabrication de tensioactif, chaque procédé étant basé sur ledit procédé de préparation d'oxyde d'éthylène ou d'oxyde de propylène ; les polyéthylèneimines, les éthanolamines, les composés alcoxylés, les tensioactifs, les diamines, oligoamines et polyamines alcoxylées, et les polyéthylèneimines alcoxylées pouvant être obtenues par les procédés susmentionnés ; l'utilisation des polyéthylèneimines, des éthanolamines, des composés alcoxylés, des tensioactifs, des diamines, oligoamines et polyamines alcoxylées, et des polyéthylèneimines alcoxylées ; une composition étant un détergent de nettoyage, une composition de nettoyage ou un tissu et un produit d'entretien ménager, contenant au moins des diamines, oligoamines et polyamines alcoxylées ou de la polyéthylèneimine alcoxylée, ou un tensioactif ; les polyéthylèneimines, les éthanolamines, les tensioactifs alcoxylés, les diamines, oligoamines et polyamines alcoxylées, et les polyéthylèneimines alcoxylées avec une quantité réduite de teneur en hydrogène à base de fossiles ayant ainsi un berceau réduit global pour déclencher une empreinte carbone de produit.
PCT/EP2024/055617 2023-03-02 2024-03-04 Oxyde d'éthylène respectueux de l'environnement, oxyde de propylène et produits en aval Pending WO2024180261A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202480016027.1A CN121079338A (zh) 2023-03-02 2024-03-04 环境友好型环氧乙烷、环氧丙烷和下游产品

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
EP23159730 2023-03-02
EP23159730.3 2023-03-02
EP23175778.2 2023-05-26
EP23175778 2023-05-26
EP23207078 2023-10-31
EP23207077 2023-10-31
EP23207077.1 2023-10-31
EP23207078.9 2023-10-31

Publications (2)

Publication Number Publication Date
WO2024180261A2 WO2024180261A2 (fr) 2024-09-06
WO2024180261A3 true WO2024180261A3 (fr) 2024-10-17

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PCT/EP2024/055617 Pending WO2024180261A2 (fr) 2023-03-02 2024-03-04 Oxyde d'éthylène respectueux de l'environnement, oxyde de propylène et produits en aval

Country Status (2)

Country Link
CN (1) CN121079338A (fr)
WO (1) WO2024180261A2 (fr)

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