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WO2024034560A1 - Ensemble cathode - Google Patents

Ensemble cathode Download PDF

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Publication number
WO2024034560A1
WO2024034560A1 PCT/JP2023/028739 JP2023028739W WO2024034560A1 WO 2024034560 A1 WO2024034560 A1 WO 2024034560A1 JP 2023028739 W JP2023028739 W JP 2023028739W WO 2024034560 A1 WO2024034560 A1 WO 2024034560A1
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WO
WIPO (PCT)
Prior art keywords
bar
sub
groove
cathode assembly
collector
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2023/028739
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English (en)
Japanese (ja)
Inventor
涼 秋田
泰弘 小山
拓也 津田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SEC Carbon Ltd
Original Assignee
SEC Carbon Ltd
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Filing date
Publication date
Application filed by SEC Carbon Ltd filed Critical SEC Carbon Ltd
Publication of WO2024034560A1 publication Critical patent/WO2024034560A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/16—Electric current supply devices, e.g. bus bars
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02—Electrodes; Connections thereof

Definitions

  • the present invention relates to a cathode assembly.
  • a carbon cathode block is used as the cathode of an electrolytic furnace for aluminum smelting.
  • the cathode block is installed in an iron box called a shell and forms the bottom of the electrolytic furnace.
  • the cathode block is also responsible for supplying electrons to the electrolytic bath.
  • Electrons are supplied to the cathode block via a metal collector bar.
  • a collector bar is connected to a cathode block.
  • WO 2018/134754 discloses a cathode assembly comprising a cathode body made of a carbonaceous material and at least one cathode collector bar made of a metal material.
  • This cathode collector bar includes two bar elements. Each of the two bar elements has a main side that contacts the side of the slot in the cathode body, and a tapered surface. The two tapered surfaces form a contact line between the two bar elements.
  • Japanese Patent Publication No. 2017-534770 discloses a cathode current collector assembly assembled within a carbon cathode.
  • the cathode current collector assembly includes a highly conductive metal current collection bar positioned below a carbon cathode.
  • the current collector bar has an electrically conductive flexible foil or sheet at the interface with the carbon cathode.
  • WO 2021/240353 discloses a cathode assembly comprising a cathode body made of carbonaceous material with at least one slot and a collector bar system partially accommodated in the slot.
  • the collector bar system comprises two individual bars and retaining means attached to the individual bars to ensure that the outer surface of the collector bar system is in firm contact with the inner wall of the slot.
  • the collector bar is typically placed in a groove (also called a "cathode slot") formed in the cathode block.
  • the operating temperature of an electrolytic furnace for aluminum smelting is approximately 960° C.
  • the collector bar in the groove thermally expands and comes into strong contact with the side surface of the groove. Since strong contact pressure is applied to the side surfaces of the groove, the contact resistance at that portion is low.
  • the objective of the present invention is to minimize the current path within the cathode block and suppress power consumption by applying stronger contact pressure to the bottom of the groove of the cathode block than to the sides when the collector bar thermally expands.
  • the purpose of the present invention is to provide a cathode assembly that can be used.
  • a cathode assembly is a cathode assembly used in an electrolytic furnace for aluminum smelting, and includes a carbon cathode block having a groove at the bottom, and a metal cathode block disposed in the groove. and a support bar disposed in the groove, the collector bar having a first surface in contact with a bottom surface of the groove, and a surface opposite to the first surface.
  • the support bar has a support surface that is in contact with the second surface and has a shape along the second surface, and the support bar is installed in the electrolytic furnace.
  • the direction in which the collector bar extends is the length direction
  • the direction perpendicular to both the length direction and the height direction is the width direction
  • each of the second surface and the support surface is such that the collector bar is The collector bar is inclined so as to move upward in the height direction when expanded in the width direction.
  • FIG. 1 is a cross-sectional view schematically showing the overall configuration of an example of an electrolytic furnace for aluminum smelting.
  • FIG. 2 is a perspective view schematically showing the configuration of the cathode assembly according to the first embodiment of the present invention.
  • 3 is a perspective view of the cathode assembly of FIG. 2 viewed from a different direction (from the bottom side) than in FIG. 2.
  • FIG. 4 is a diagram showing a cathode block extracted from FIG. 3.
  • FIG. 5 is a sectional view (yz sectional view) of the cathode assembly of FIG. 4 taken along the line VV in FIG. 4.
  • FIG. FIG. 6A is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 6A is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 6B is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 6C is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 6D is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 7 is a cross-sectional view schematically showing how the collector bar expands in the width direction.
  • FIG. 8 is a sectional view schematically showing the configuration of a cathode assembly according to a hypothetical comparative example.
  • FIG. 9 is a sectional view schematically showing a configuration of a modification of the cathode assembly according to the first embodiment of the present invention.
  • FIG. 10 is a sectional view schematically showing another configuration of a modification of the cathode assembly according to the first embodiment of the present invention.
  • FIG. 11 is a perspective view schematically showing the configuration of a cathode assembly according to a second embodiment of the present invention.
  • FIG. 12 is a sectional view (yz sectional view) of the cathode assembly of FIG. 11 taken along the line XII-XII of FIG.
  • FIG. 13 is a sectional view (yz sectional view) of the cathode assembly of FIG. 11 taken along the line XIII-XIII of FIG. 11.
  • FIG. 14A is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 14B is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 14C is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 14A is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 14B is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 14C is a diagram for explaining the assembly procedure of the catho
  • FIG. 14D is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 15 is a cross-sectional view schematically showing how the collector bar expands in the width direction.
  • FIG. 16 is a sectional view schematically showing the configuration of a modified example of the cathode assembly according to the second embodiment of the present invention.
  • FIG. 17 is a perspective view schematically showing the configuration of a cathode assembly according to a third embodiment of the present invention.
  • FIG. 18 is a perspective view schematically showing the structure of the cathode assembly shown in FIG. 17 with the main body portion of the support bar removed.
  • FIG. 19 is a sectional view (yz sectional view) of the cathode assembly of FIG. 17 taken along the line XIX-XIX of FIG. 17.
  • FIG. 20A is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 20B is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 20C is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 20D is a diagram for explaining the assembly procedure of the cathode assembly.
  • FIG. 21 is a cross-sectional view schematically showing how the collector bar expands in the width direction.
  • FIG. 1 is a cross-sectional view schematically showing the overall configuration of an electrolytic furnace 1, which is an example of an electrolytic furnace for aluminum smelting.
  • the electrolytic furnace 1 includes a cathode assembly 100 according to the first embodiment of the present invention.
  • a plurality of cathode assemblies 100 are arranged side by side in the depth direction (y direction) in FIG.
  • Each cathode assembly 100 includes a cathode block 10, a collector bar 20, and a support bar 30.
  • the cathode block 10 constitutes the bottom of the electrolytic furnace 1.
  • the collector bar 20 and the cathode block 10 are electrically connected, and the end of the collector bar 20 is drawn out to the outside of the electrolytic furnace 1.
  • the support bar 30 supports the collector bar 20 from below. The detailed configuration of the cathode assembly 100 will be described later.
  • the electrolytic furnace 1 includes an anode 91, a shell 92, a lining 93, and the like. Inside the electrolytic furnace 1, a melt 94 containing aluminum oxide is accommodated.
  • the collector bar 20 and the anode 91 are electrically connected to a power supply device (not shown).
  • a voltage is applied between the cathode block 10 and the anode 91 by the power supply device. As a result, aluminum oxide in the melt 94 is reduced, and aluminum 95 is produced.
  • FIG. 2 is a perspective view schematically showing the configuration of the cathode assembly 100.
  • FIG. 3 is a perspective view of the cathode assembly 100 viewed from a direction different from that in FIG. 2 (from the bottom side).
  • FIG. 4 is a diagram showing the cathode block 10 extracted from FIG. 3.
  • FIG. 5 is a cross-sectional view (yz cross-sectional view) of the cathode assembly 100 taken along the line VV in FIG.
  • the cathode assembly 100 includes the cathode block 10, the collector bar 20, and the support bar 30.
  • the cathode assembly 100 further includes a fixing member 41 (FIGS. 3 and 5), a spacer 42 (FIG. 5), and the like.
  • the cathode assembly 100 is installed, for example, on a floor F (FIG. 5) covered with powder such as alumina.
  • the cathode block 10 is made of carbon.
  • the "cathode block made of carbon” also includes a cathode block made of a composite material of TiB2 , TiC, etc., and carbon.
  • Cathode block 10 is preferably made of graphite.
  • the cathode block 10 has a rectangular parallelepiped shape, and as shown in FIG. 4, a groove 11 is provided at the bottom.
  • the groove 11 is open not only at the bottom of the cathode block 10 but also at the side surface of the cathode block 10 (the surface perpendicular to the x direction in FIG. 2). That is, the groove 11 penetrates the cathode block 10 in the x direction.
  • the groove 11 has a bottom surface 10a and two side surfaces 10b.
  • the bottom surface 10a of the groove 11 is a plane substantially parallel to the horizontal plane.
  • the two side surfaces 10b are inclined from the vertical direction (see FIG. 5). More specifically, the two side surfaces 10b are inclined so that the distance between them becomes smaller as they approach the bottom surface (lower side in the z direction) of the cathode block 10.
  • the inclination angle is, for example, 1 to 20°.
  • the groove 11 has a trapezoidal shape in a yz cross section (a cross section perpendicular to the direction in which the collector bar 20 extends).
  • This cross-sectional shape is a preferable shape because it can prevent the collector bar 20 and the support bar 30 from falling off from the groove 11.
  • the cross-sectional shape of the groove 11 is arbitrary.
  • the cross-sectional shape of the groove 11 may be, for example, rectangular. That is, the two side surfaces 10b of the groove 11 may be surfaces perpendicular to the horizontal surface.
  • a collector bar 20 and a support bar 30 are arranged within the groove 11.
  • the collector bar 20 is arranged within the groove 11 so that both ends in the x direction protrude outside the groove 11.
  • a certain member is said to be "arranged within the groove 11" it means that at least a part of the member is arranged within the groove 11, and another part of the member is "arranged within the groove 11". This includes cases where it protrudes outside the area.
  • the collector bar 20 is made of metal.
  • the collector bar 20 is made of a metal with high electrical conductivity.
  • the collector bar 20 is made of, for example, iron or copper, or an alloy thereof, preferably copper or a copper alloy.
  • the collector bar 20 has a shape extending in one direction.
  • the direction in which the collector bar 20 extends (x direction) will be referred to as the length direction.
  • a direction (y direction) perpendicular to both the length direction and the height direction (the vertical direction (z direction) in a state where the cathode assembly 100 is placed in the electrolytic furnace 1) is referred to as the width direction.
  • the collector bar 20 is arranged so that the direction in which the groove 11 extends is parallel to the length direction.
  • the collector bar 20 has an upper surface (first surface) 20a that contacts the bottom surface 10a of the groove 11 of the cathode block 10, and a lower surface (second surface) 20b that is the surface opposite to the upper surface 20a. , and two outer side surfaces 20c, which are surfaces facing the side surface 10b of the groove 11.
  • the upper surface 20a has a shape that follows the bottom surface 10a of the groove 11.
  • the upper surface 20a is, for example, a plane parallel to the horizontal plane.
  • the lower surface 20b is in contact with support surfaces (31a, 32a) of a support bar 30, which will be described later.
  • the lower surface 20b has a shape that follows the support surfaces (31a, 32a). More specifically, when the cathode assembly 100 is assembled and installed in the electrolytic furnace 1 (FIG. 1), the lower surface 20b is inclined such that the height increases from the inside to the outside in the width direction. . Details of the lower surface 20b will be described later.
  • a gap c1 is provided between each of the two outer surfaces 20c and the corresponding side surface 10b of the groove 11. That is, the collector bar 20 is not in contact with the side surface 10b of the groove 11.
  • the two outer surfaces 20c may have any shape.
  • the two outer surfaces 20c are, for example, planes perpendicular to the horizontal plane.
  • the support bar 30 is arranged below the collector bar 20 within the groove 11.
  • the support bar 30 has a shape extending in one direction, and is arranged so that the direction in which the groove 11 extends and the direction in which the support bar 30 extends are parallel to each other.
  • the entire support bar 30 is illustrated as being disposed within the groove 11, but this configuration is merely an example, and like the collector bar 20, a portion of the support bar 30 also extends from the groove 11. It may stick out.
  • the length of the support bar 30 (dimension in the x direction) is preferably approximately the same as the length of the cathode block 10, but may be shorter than the length of the cathode block 10.
  • the length of the support bar 30 is preferably 30% or more, more preferably 50% or more, and even more preferably 80% or more of the length of the cathode block 10.
  • the support bar 30 may or may not have conductivity. Although the material of the support bar 30 is arbitrary, it is preferable that the material has a predetermined strength and heat resistance.
  • the support bar 30 is made of, for example, metal or ceramics, preferably iron or an iron alloy.
  • the support bar 30 consists of a first sub-bar (first sub-support bar) 31 and a second sub-bar (second sub-support bar) 32, which are arranged side by side in the width direction.
  • the first sub-bar 31 faces the upper surface 31a disposed so as to be in contact with the lower surface 20b of the collector bar 20, the lower surface 31b which is the surface opposite to the upper surface 31a, and the side surface 10b of the groove 11. It has an outer surface 31c that is a surface, and an inner surface 31d that is a surface that faces the second sub-bar 32.
  • the second sub-bar 32 has an upper surface 32a that is arranged to be in contact with the lower surface 20b of the collector bar 20, a lower surface 32b that is a surface opposite to the upper surface 32a, and an outer surface that is a surface that faces the side surface 10b of the groove 11. It has a side surface 32c and an inner surface 32d which is a surface facing the first sub-bar 31.
  • the collector bar 20 is supported by the upper surface 31a of the first sub-bar 31 and the upper surface 32a of the second sub-bar 32.
  • the surface constituted by the upper surface 31a and the upper surface 32a will be referred to as the "support surface (31a, 32a) of the support bar 30" or simply the “support surface (31a, 32a).”
  • the support surfaces (31a, 32a) have a shape that follows the lower surface 20b of the collector bar 20. Further, the lower surface 20b and the support surfaces (31a, 32a) are each inclined such that when the collector bar 20 expands in the width direction, the collector bar 20 moves upward in the height direction.
  • each of the lower surface 20b and the support surfaces (31a, 32a) is raised from the inside to the outside in the width direction when the cathode assembly 100 is assembled and installed in the electrolytic furnace 1 (FIG. 1). It is sloped so that the height is higher. More specifically, each of the lower surface 20b and the support surfaces (31a, 32a) is inclined by an inclination angle ⁇ from the horizontal plane so that the height increases from the inside to the outside in the width direction.
  • the angle of inclination ⁇ is not particularly limited, but is, for example, 1 to 60°.
  • the lower limit of the inclination angle ⁇ is preferably 3°, more preferably 5°, and even more preferably 10°.
  • the upper limit of the inclination angle ⁇ is preferably 50°, more preferably 45°, and even more preferably 30°.
  • the lower surface 31b of the first sub-bar 31 and the lower surface 32b of the second sub-bar 32 may have any shape.
  • the lower surface 31b and the lower surface 32b are, for example, planes parallel to the horizontal plane.
  • the outer surface 31c of the first sub-bar 31 and the outer surface 32c of the second sub-bar 32 are in contact with the side surface 10b of the corresponding groove 11. More precisely, a spacer 42, which will be described later, is arranged between the outer surface 31c and the side surface 10b and between the outer surface 32c and the side surface 10b, and the outer surfaces 31c and 32c are arranged with the spacer 42 between them.
  • the groove 11 is in contact with the side surface 10b of the corresponding groove 11 with the groove 11 interposed therebetween. It is preferable that the outer surfaces 31c and 32c have a shape that follows the corresponding side surface 10b of the groove 11.
  • a gap c2 is provided between the inner surface 31d of the first sub-bar 31 and the inner surface 32d of the second sub-bar 32. That is, the first sub-bar 31 and the second sub-bar 32 are not in contact with each other.
  • the inner surface 31d and the inner surface 32d may have any shape.
  • the inner surface 31d and the inner surface 32d are, for example, planes perpendicular to the horizontal plane.
  • the size of the gap c2 between the first sub-bar 31 and the second sub-bar 32 is fixed by the fixing member 41.
  • a plurality of fixing members 41 are arranged at predetermined intervals along the length direction of the support bar 30.
  • Each of the fixing members 41 has a plate-like shape extending in the width direction, and is in contact with the lower surface 31b of the first sub-bar 31 and the lower surface 32b of the second sub-bar 32.
  • Each of the fixing members 41 is fixed to the support bar 30 by drill screws 411 at two locations near both ends in the width direction.
  • the fixing member 41 may or may not have conductivity.
  • the material of the fixing member 41 is arbitrary.
  • the fixing member 41 is made of metal or ceramics, for example.
  • the fixing member 41 preferably has a smaller coefficient of thermal expansion than the collector bar 20, and more preferably has a smaller coefficient of thermal expansion than both the collector bar 20 and the support bar 30.
  • the position where the fixing member 41 and the support bar 30 are fixed is as far outside the support bar 30 in the width direction as possible. That is, it is preferable to make the length between the two positions where the fixing member 41 and the support bar 30 are fixed as long as possible.
  • the length between the two positions where fixing member 41 and support bar 30 are fixed is preferably 50% or more, more preferably 75% or more of the width of support bar 30.
  • the outer surface 31c of the first sub-bar 31 and the outer surface 32c of the second sub-bar 32 are in contact with the side surface 10b of the corresponding groove 11 with the spacer 42 interposed therebetween. Furthermore, the size of the gap c2 between the first sub-bar 31 and the second sub-bar 32 is fixed by a fixing member 41. According to this configuration, the widthwise position of the support bar 30 is fixed by sandwiching the support bar 30 between the side surfaces 10b of the groove 11 with the spacer 42 interposed therebetween. Further, since the collector bar 20 is sandwiched between the upper surface 31a of the first sub-bar 31 and the upper surface 32a of the second sub-bar 32, the position of the collector bar 20 in the width direction is fixed. This fixes the collector bar 20 and the support bar 30 within the groove 11.
  • the spacer 42 relieves the stress that the cathode block 10 receives when the support bar 30 thermally expands.
  • the spacer 42 is, for example, a sheet-like member made of thermoplastic resin or metal with a melting point of 650° C. or lower. Spacer 42 is preferably a sheet of thermoplastic resin.
  • a procedure for assembling cathode assembly 100 will be described with reference to FIGS. 6A to 6D. As shown in FIGS. 6A to 6D, the cathode assembly 100 is assembled by placing the cathode block 10 with its bottom facing upward.
  • the collector bar 20 is placed near the center of the bottom surface 10a of the groove 11 in the width direction. At this time, the collector bar 20 is arranged so that the upper surface 20a is in contact with the bottom surface 10a of the groove 11.
  • the spacer 42 is placed on the side surface 10b of the groove 11, and the support bar 30 is placed on the collector bar 20.
  • the support bar 30 is arranged so that the support surfaces (31a, 32a) are in contact with the lower surface 20b of the collector bar 20.
  • the first sub-bar 31 and the second sub-bar 32 are brought to the outside in the width direction so that the outer surface 31c and the outer surface 32c come into contact with the side surface 10b of the corresponding groove 11 with the spacer 42 interposed therebetween.
  • a plurality of fixing members 41 are placed on the support bar 30, and a drill screw 411 is driven in to fix the support bar 30 and the plurality of fixing members 41.
  • the cathode assembly 100 is installed in the electrolytic furnace 1 (FIG. 1) in an upside-down state from FIG. 6D.
  • FIG. 7 is a cross-sectional view schematically showing how the collector bar 20 expands in the width direction.
  • a gap c1 exists between the two outer surfaces 20c of the collector bar 20 and the side surface 10b of the groove 11. Therefore, when the collector bar 20 is heated, the collector bar 20 thermally expands outward from the center in the width direction, as schematically shown by the white arrow in FIG.
  • the lower surface 20b of the collector bar 20 and the support surfaces (31a, 32a) of the support bar 30 are each inclined so that the height increases from the inside to the outside in the width direction. Therefore, when the collector bar 20 expands outward in the width direction, it slides up on the support surfaces (31a, 32a), and the collector bar 20 moves upward in the height direction (z direction). As a result, a strong contact pressure is applied between the bottom surface 10a of the groove 11 and the top surface 20a of the collector bar 20.
  • FIG. 8 is a cross-sectional view schematically showing the configuration of a cathode assembly 900 according to a hypothetical comparative example.
  • Cathode assembly 900 includes a cathode block 910 and a collector bar 920.
  • a groove 911 is formed in the cathode block 910, and the collector bar 920 is disposed within the groove 911.
  • collector bar 20 and the support bar 30 thermally expand not only in the width direction but also in the height direction. Thermal expansion in the height direction also contributes to improving the contact pressure between the bottom surface 10a and the top surface 20a.
  • the configuration of the cathode assembly 100 according to the first embodiment of the present invention has been described above. According to the configuration of the cathode assembly 100, when the collector bar 20 thermally expands, a stronger contact pressure is applied to the bottom surface 10a than the side surface 10b of the groove 11 of the cathode block 10, so that the current path inside the cathode block 10 is It is possible to minimize the time and reduce power consumption.
  • the support bar 30 consists of the first sub-bar 31 and the second sub-bar 32 has been described above.
  • the support bar 30 is composed of one part, it is preferable to match the width of the support bar 30 and the width of the groove 11 with high accuracy, but such processing is difficult, especially in production on an industrial scale. It can be difficult.
  • the width of the support bar 30 can be easily adjusted.
  • the first sub-bar 31 and the second sub-bar 32 are also arranged so as not to contact each other. Furthermore, the support bar 30 and the fixing member 41 are fixed by a drill screw 411 on the outside of the support bar 30 in the width direction. According to this configuration, the first sub-bar 31 and the second sub-bar 32 expand from the outside in the width direction to the inside, starting from the position of the drill screw 411, as schematically shown by the white arrow in FIG. do. Thereby, the influence of thermal expansion of the fixing member 41 can be canceled. Alternatively, the collector bar 20 can be moved higher in the height direction by expanding the first sub-bar 31 and the second sub-bar 32 to a greater extent than the amount of thermal expansion of the fixing member 41.
  • the effect of bringing the collector bar 20 into stronger contact with the bottom surface 10a of the groove 11 than with the side surface 10b can be obtained even when the support bar 30 is composed of one component. Therefore, it is not essential that the support bar 30 consist of the first sub-bar 31 and the second sub-bar 32, and the support bar 30 may be composed of one component. In this case, the cathode assembly 100 does not need to include the fixing member 41.
  • the spacer 42 is also not essential from the viewpoint of bringing the collector bar 20 into stronger contact with the bottom surface 10a of the groove 11 than with the side surface 10b. Therefore, the cathode assembly 100 does not need to include the spacer 42.
  • both ends of the collector bar 20 in the x direction protrude outside the groove 11.
  • two collector bars 20 may be arranged in one groove 11, with one end of each protruding outside the groove 11.
  • one groove 11 is formed in the cathode block 10
  • a plurality of grooves may be provided in the cathode block 10
  • a plurality of collector bars 20 and support bars 30 may be arranged in one cathode block.
  • FIG. 9 is a cross-sectional view schematically showing the configuration of a cathode assembly 100A, which is one of the modified examples of the cathode assembly 100.
  • the cathode assembly 100A includes a collector bar 20A in place of the collector bar 20 of the cathode assembly 100 (FIG. 5).
  • the collector bar 20A consists of a first sub-bar (first sub-collector bar) 21 and a second sub-bar (second sub-collector bar) 22, which are arranged side by side in the width direction. That is, collector bar 20 of cathode assembly 100 (FIG. 5) is comprised of one part, whereas collector bar 20A of cathode assembly 100A (FIG. 9) is comprised of two parts. The first sub-bar 21 and the second sub-bar 22 are arranged in contact with each other. Effects similar to those of the cathode assembly 100 can also be obtained by the configuration of the cathode assembly 100A.
  • the collector bar 20A may be composed of three or more parts.
  • FIG. 10 is a cross-sectional view schematically showing the configuration of a cathode assembly 100B, which is one of the modified examples of the cathode assembly 100. As shown in FIG. Cathode assembly 100B differs from cathode assembly 100A (FIG. 9) in the magnitude of the tilt angle ⁇ .
  • the inclination angle ⁇ is preferably determined in consideration of the effect of increasing the contact pressure between the bottom surface 10a and the top surface 20a and the effect of decreasing the cross-sectional area of the collector bar 20A.
  • FIG. 11 is a perspective view schematically showing the configuration of the cathode assembly 200.
  • FIG. 11 is a perspective view of the cathode assembly 200 viewed from the bottom side, similar to FIG. 3.
  • 12 is a sectional view (yz sectional view) of the cathode assembly 200 taken along the line XII-XII of FIG. 11
  • FIG. 13 is a sectional view of the cathode assembly 200 taken along the line XIII-XIII of FIG. It is a cut sectional view (yz sectional view).
  • the cathode assembly 200 includes a collector bar 50 and a support bar 60 in place of the collector bar 20 and support bar 30 of the cathode assembly 100 (FIG. 3). That is, the cathode assembly 200 includes a cathode block 10, a collector bar 50, and a support bar 60. The cathode assembly 200 further includes a fixing member 43 and a spacing adjustment member 44.
  • the collector bar 50 consists of a first sub-bar (first sub-collector bar) 51 and a second sub-bar (second sub-collector bar) 52, which are arranged side by side in the width direction.
  • the first sub-bar 51 has an upper surface 51a that is arranged to be in contact with the bottom surface 10a of the groove 11, a lower surface 51b that is the opposite surface of the upper surface 51a, and a side surface 10b of the groove 11. It has an outer surface 51c that is a facing surface, and an inner surface 51d that is a surface that faces the second sub-bar 52.
  • the second sub-bar 52 has an upper surface 52a that is arranged to be in contact with the bottom surface 10a of the groove 11, a lower surface 52b that is a surface opposite to the upper surface 52a, and an outer surface that is a surface that faces the side surface 10b of the groove 11. 52c, and an inner surface 52d that faces the first sub-bar 51.
  • the surface (first surface) constituted by the upper surface 51a and the upper surface 52a will be referred to as the “upper surface (51a, 52a) of the collector bar” or simply the “upper surface (51a, 52a).
  • the surface (second surface) constituted by the lower surface 51b and the lower surface 52b is referred to as the “lower surface (51b, 52b) of the collector bar” or simply the “lower surface (51b, 52b).
  • the upper surfaces (51a, 52a) have a shape that follows the bottom surface 10a of the groove 11.
  • the upper surface (51a, 52a) is, for example, a plane parallel to the horizontal plane.
  • the lower surfaces (51b, 52b) are in contact with support surfaces (61a, 62a) of a support bar 60, which will be described later.
  • the lower surface (51b, 52b) has a shape along the support surface (61a, 62a). More specifically, the lower surfaces (51b, 52b) are inclined so that the height increases from the outside to the inside in the width direction when the cathode assembly 200 is assembled and installed in the electrolytic furnace. Details of the lower surfaces (51b, 52b) will be described later.
  • each of the outer surface 51c of the first sub-bar 51 and the outer surface 52c of the second sub-bar 52 is in contact with the side surface 10b of the corresponding groove 11. That is, the collector bar 50 is in contact with the side surface 10b of the groove 11. It is preferable that each of the outer surface 51c of the first sub-bar 51 and the outer surface 52c of the second sub-bar 52 has a shape along the side surface 10b of the corresponding groove 11.
  • a gap c3 is provided between the inner surface 51d of the first sub-bar 51 and the inner surface 52d of the second sub-bar 52. That is, the first sub-bar 51 and the second sub-bar 52 are not in contact with each other.
  • the inner surface 51d and the inner surface 52d may have any shape.
  • the inner surface 51d and the inner surface 52d are, for example, planes perpendicular to the horizontal plane.
  • the support bar 60 consists of a first sub-bar (first sub-support bar) 61 and a second sub-bar (second sub-support bar) 62, which are arranged side by side in the width direction.
  • the first sub-bar 61 includes an upper surface 61a that is arranged to be in contact with the lower surface (51b, 52b) of the collector bar 50, a lower surface 61b that is the opposite surface of the upper surface 61a, and a groove. It has an outer surface 61c that is a surface that faces the side surface 10b of 11, and an inner surface 61d that is a surface that faces the second sub-bar 62.
  • the second sub-bar 62 faces the upper surface 62a arranged to be in contact with the lower surface (51b, 52b) of the collector bar 50, the lower surface 62b which is the surface opposite to the upper surface 62a, and the side surface 10b of the groove 11. It has an outer surface 62c that is a surface, and an inner surface 62d that is a surface that faces the first sub-bar 61.
  • the collector bar 50 is supported by the upper surface 61a of the first sub-bar 61 and the upper surface 62a of the second sub-bar 62.
  • the surface constituted by the upper surface 61a and the upper surface 62a will be referred to as the "support surface (61a, 62a) of the support bar 60" or simply the “support surface (61a, 62a)."
  • the support surfaces (61a, 62a) have a shape that follows the lower surface (51b, 52b) of the collector bar 50. Further, each of the lower surfaces (51b, 52b) and the support surfaces (61a, 62a) are inclined so that when the collector bar 50 expands in the width direction, the collector bar 50 moves upward in the height direction.
  • each of the lower surfaces (51b, 52b) and the support surfaces (61a, 62a) has a height that increases from the outside in the width direction to the inside when the cathode assembly 200 is assembled and installed in the electrolytic furnace. It is sloped so that it is higher. More specifically, each of the lower surfaces (51b, 52b) and the support surfaces (61a, 62a) is inclined by an inclination angle ⁇ from the horizontal plane so that the height increases from the outside to the inside in the width direction. There is.
  • the angle of inclination ⁇ is not particularly limited, but is, for example, 1 to 60°.
  • the preferred range of tilt angle ⁇ is similar to the preferred range of tilt angle ⁇ of cathode assembly 100 (FIG. 5).
  • the lower surface 61b of the first sub-bar 61 and the lower surface 62b of the second sub-bar 62 may have any shape.
  • the lower surface 61b and the lower surface 62b are, for example, planes parallel to the horizontal plane.
  • a gap c4 is provided between the outer surface 61c of the first sub-bar 61 and the outer surface 62c of the second sub-bar 62 and the corresponding side surface 10b of the groove 11. That is, the support bar 60 is not in contact with the side surface 10b of the groove 11.
  • the outer surface 61c and the outer surface 62c may have any shape.
  • the outer surface 61c and the outer surface 62c are, for example, planes perpendicular to the horizontal plane.
  • a gap c5 is provided between the inner surface 61d of the first sub-bar 61 and the inner surface 62d of the second sub-bar 62. That is, the first sub-bar 61 and the second sub-bar 62 are not in contact with each other.
  • the inner surface 61d and the inner surface 62d may have any shape.
  • the inner surface 61d and the inner surface 62d are, for example, planes perpendicular to the horizontal plane.
  • the gap c5 between the first sub-bar 61 and the second sub-bar 62 is maintained at a predetermined size by the gap adjustment member 44.
  • a plurality of interval adjustment members 44 are arranged at predetermined intervals along the length direction of the support bar 60.
  • the interval adjustment member 44 is, for example, a screw. As shown in FIG. 13, a screw hole 611 is provided in the first sub-bar 61, the gap adjustment member 44 is inserted therein, and the degree of protrusion of the gap adjustment member 44 is adjusted depending on the degree of fastening, thereby controlling the size of the gap c5. Can be adjusted.
  • the spacing adjustment member 44 is not limited to the above configuration.
  • the interval adjustment member 44 may be any member as long as it can adjust the size of the gap c5. However, from the viewpoint of being able to finely control the size of the gap c5, it is preferable to use a screw mechanism.
  • a fixing member 43 is arranged below the support bar 60 in the height direction.
  • the positions of the collector bar 50 and the support bar 60 in the height direction are fixed by being sandwiched between the bottom surface 10a of the groove 11 and the fixing member 43 from above and below in the height direction.
  • a plurality of fixing members 43 are arranged at predetermined intervals along the length direction of the support bar 60.
  • Each of the fixing members 43 has a plate-like shape extending in the width direction, and is in contact with the lower surface 61b of the first sub-bar 61 and the lower surface 62b of the second sub-bar 62.
  • Each of the fixing members 43 is fixed to the bottom surface of the cathode block 10 by screws 431 near both ends in the width direction.
  • the through hole 43a formed in the fixing member 43 for passing the screw 431 preferably has a shape extending in the width direction, as shown in FIG. 12. This makes it possible to reduce the stress applied to the cathode block 10 when the fixing member 43 thermally expands in the width direction. Further, in order to alleviate the influence of thermal expansion in the height direction, it is preferable that the length of the screw 431 is made long. On the other hand, if the screw 431 is too long, the pressure on the bottom surface 10a of the groove 11 may drop too much. It is preferable that the length of the screw 431 is set to an appropriate length in consideration of these factors. Further, in order to prevent the screw hole 12 from being damaged, it is preferable to use a multi-thread screw such as a double-thread screw as the screw 431.
  • the fixing member 43 may or may not have conductivity.
  • the material of the fixing member 43 is arbitrary.
  • the fixing member 43 is made of metal or ceramics, for example.
  • the fixing member 43 preferably has a smaller coefficient of thermal expansion than the collector bar 50, and more preferably has a smaller coefficient of thermal expansion than both the collector bar 50 and the support bar 60.
  • the gap c5 between the first sub-bar 61 and the second sub-bar 62 is maintained at a predetermined size by the gap adjustment member 44.
  • the support surfaces (61a, 62a) of the support bar 60 are inclined so that the height increases from the outside toward the inside in the width direction.
  • the first sub-bar 51 of the collector bar 50 receives resistance from the first sub-bar 61 of the support bar 60 outward in the width direction.
  • the second sub-bar 52 of the collector bar 50 receives resistance from the second sub-bar 62 of the support bar 60 outward in the width direction.
  • the first sub-bar 51 and the second sub-bar 52 are in contact with the side surface 10b of the groove 11, they cannot move outward in the width direction. This configuration fixes the collector bar 50 and the support bar 60 within the groove 11.
  • the assembly procedure of cathode assembly 200 will be described with reference to FIGS. 14A to 14D. As shown in FIGS. 14A to 14D, the cathode assembly 200 is assembled by arranging the cathode block 10 with its bottom facing upward.
  • the first sub-bar 51 and the second sub-bar 52 are placed on the bottom surface 10a of the groove 11.
  • the upper surface 51a and the upper surface 52a are arranged so as to be in contact with the bottom surface 10a of the groove 11.
  • the first sub-bar 51 and the second sub-bar 52 are brought to the outside in the width direction so that the outer surface 51c and the outer surface 52c contact the corresponding side surface 10b of the groove 11.
  • the first sub-bar 61 and the second sub-bar 62 are placed on the first sub-bar 51 and the second sub-bar 52.
  • the support surface (61a, 62a) of the support bar 60 is arranged so as to be in contact with the lower surface (51b, 52b) of the collector bar 50.
  • a plurality of fixing members 43 are placed on the support bar 60 and fixed to the cathode block 10 by tightening the screws 431 into the screw holes 12. Thereafter, the collector bar 50 and the support bar 60 are fixed in the groove 11 by loosening the spacing adjustment member 44.
  • the cathode assembly 200 is installed in the electrolytic furnace in an upside-down state from FIG. 14D.
  • FIG. 15 is a cross-sectional view schematically showing how the collector bar 50 expands in the width direction. While the outer surface 51c of the first sub-bar 51 and the outer surface 52c of the second sub-bar 52 are restrained by the side surface 10b of the groove 11, a gap c3 exists between the first sub-bar 51 and the second sub-bar 52. do. Therefore, when the collector bar 50 is heated, the collector bar 50 thermally expands inward from the outside in the width direction, as schematically shown by the white arrow in FIG.
  • the lower surface (51b, 52b) of the collector bar 50 and the support surface (61a, 62a) of the support bar 60 are each inclined so that the height increases from the outside toward the inside in the width direction. Therefore, when the collector bar 50 expands inward in the width direction, it slides up on the support surfaces (61a, 62a), and the collector bar 50 moves upward in the height direction (z direction). As a result, strong contact pressure is applied between the bottom surface 10a of the groove 11 and the top surface (51a, 52a) of the collector bar 50.
  • the outer surface 61c of the first sub-bar 61 and the outer surface 62c of the second sub-bar 62 are arranged so as not to contact the side surface 10b of the corresponding groove 11. According to this configuration, the first sub-bar 61 and the second sub-bar 62 expand from the inside to the outside in the width direction, as schematically shown by the white arrows in FIG. This allows the collector bar 50 to be moved higher in the height direction.
  • the configuration of the cathode assembly 200 according to the second embodiment of the present invention has been described above. According to the configuration of the cathode assembly 200, when the collector bar 50 thermally expands, a stronger contact pressure is applied to the bottom surface 10a than the side surface 10b of the groove 11 of the cathode block 10, so that the current path inside the cathode block 10 is It is possible to minimize the time and reduce power consumption.
  • the width of the support bar 60 can be easily adjusted by dividing the support bar 60 into the first sub-bar 61 and the second sub-bar 62 and adjusting the size of the gap c5 using the interval adjustment member 44.
  • the cathode assembly 200 does not need to include the interval adjustment member 44.
  • FIG. 16 is a cross-sectional view schematically showing the configuration of a cathode assembly 200A that is a modification of the cathode assembly 200.
  • Cathode assembly 200A includes a pair of fixing members 45 in place of fixing members 43 of cathode assembly 200 (FIG. 12).
  • Each of the pair of fixing members 45 has an L-shaped cross section, and has a portion in contact with the side surface 10b of the groove 11 and a portion in contact with the lower surface 61b of the first sub-bar 61 or the lower surface 62b of the second sub-bar 62. have.
  • Each of the fixing members 45 has a protrusion 451 at a portion that contacts the side surface 10b of the groove 11. By inserting the projection 451 into the slit 13 formed in the side surface 10b of the groove 11, the position of the fixing member 45 in the height direction is fixed.
  • the positions of the collector bar 50 and the support bar 60 in the height direction are fixed by being sandwiched between the bottom surface 10a of the groove 11 and the fixing member 45 from above and below in the height direction. Further, the fixing member 45, the collector bar 50, and the support bar 60 are sandwiched between the grooves 11, so that their positions in the width direction are fixed. With this configuration, the collector bar 50 and the support bar 60 are fixed within the groove 11.
  • FIG. 17 is a perspective view schematically showing the configuration of the cathode assembly 300.
  • FIG. 17 is a perspective view of the cathode assembly 300 viewed from the bottom side, similar to FIGS. 3 and 11.
  • FIG. 18 is a perspective view schematically showing the structure of the cathode assembly 300 with the main body portion 71 of the support bar 70, which will be described later, removed.
  • FIG. 19 is a cross-sectional view (yz cross-sectional view) of the cathode assembly 300 taken along the line XIX-XIX in FIG.
  • the cathode assembly 300 includes a support bar 70 in place of the support bar 60 of the cathode assembly 200 (FIG. 11). That is, the cathode assembly 300 includes a cathode block 10, a collector bar 50, and a support bar 70. Cathode assembly 300 further includes a height retention member 46 .
  • the support bar 70 consists of a main body portion 71 and a seat 72.
  • the main body portion 71 is made of solidified ceramic powder.
  • Body portion 71 is preferably made of cement, such as alumina cement.
  • the support bar 70 is formed by placing a sheet 72 on the lower surface (51a, 52a) of the collector bar 50 and filling the sheet with cement, etc., which is the material of the main body portion 71. be.
  • the sheet 72 is arranged to prevent cement, etc., which is the material of the main body portion 71, from entering the gap between the first sub-bar 51 and the second sub-bar 52.
  • the material of the sheet 72 is not particularly limited.
  • the sheet 72 is made of, for example, thermoplastic resin. When a thermoplastic resin is used as the sheet 72, the sheet 72 softens when the temperature rises, thereby providing the effect of relieving stress applied to the cathode block 10.
  • the support bar 70 includes a support surface 70a that is arranged to be in contact with the lower surface (51b, 52b) of the collector bar 50, a lower surface 70b that is the surface opposite to the support surface 70a, and a groove 11. It has two outer side surfaces 70c that are opposite sides of the side surface 10b.
  • the support surface 70a of the support bar 70 has a shape that follows the lower surface (51b, 52b) of the collector bar 50. Furthermore, each of the lower surfaces (51b, 52b) and the support surface 70a are inclined so that when the collector bar 50 expands in the width direction, the collector bar 50 moves upward in the height direction. Specifically, each of the lower surfaces (51b, 52b) and the support surface 70a is such that the height increases from the outside to the inside in the width direction when the cathode assembly 300 is assembled and installed in the electrolytic furnace. is inclined to.
  • the lower surface 70b of the support bar 70 may have any shape.
  • the lower surface 70b is, for example, a plane parallel to the horizontal plane.
  • the two outer surfaces 70c of the support bar 70 are in contact with the side surfaces 10b of the corresponding grooves 11. That is, the support bar 70 is in contact with the side surface 10b of the groove 11.
  • the height holding member 46 is embedded in the main body portion 71 of the support bar 70.
  • the height holding member 46 supports the collector bar 50 from below in the height direction so that the height of the collector bar 50 does not decrease when the sheet 72 softens at high temperature.
  • a plurality of height holding members 46 are arranged at predetermined intervals along the length direction of the sheet 72.
  • Each of the height holding members 46 has a plate shape extending in the width direction of the sheet 72.
  • a screw 461 is attached to each of the height holding members 46.
  • the screw 461 is arranged so that its tip passes through the sheet 72 and contacts the collector bar 50. Since the height holding member 46 is embedded in the main body portion 71 of the support bar 70, the positions of the height holding member 46 and the screw 461 are fixed. Thereby, it is possible to suppress the height of the collector bar 50 from decreasing when the sheet 72 is softened at high temperature.
  • the material of the height holding member 46 is arbitrary.
  • the height holding member 46 is made of metal or ceramics, for example.
  • the height holding member 46 is not limited to the above configuration.
  • the height holding member 46 may be any member as long as it can support the collector bar 50 from below in the height direction so that the height of the collector bar 50 does not decrease when the sheet 72 is softened at high temperature.
  • the assembly procedure of cathode assembly 300 will be described with reference to FIGS. 20A to 20D. As shown in FIGS. 20A to 20D, the cathode assembly 300 is assembled by arranging the cathode block 10 with its bottom facing upward.
  • the first sub-bar 51 and the second sub-bar 52 are placed on the bottom surface 10a of the groove 11.
  • the upper surface 51a and the upper surface 52a are arranged so as to be in contact with the bottom surface 10a of the groove 11.
  • the first sub-bar 51 and the second sub-bar 52 are brought to the outside in the width direction so that the outer surface 51c and the outer surface 52c contact the corresponding side surface 10b of the groove 11.
  • the sheet 72 is placed on the first sub-bar 51 and the second sub-bar 52.
  • the height holding member 46 is placed on the sheet 72.
  • the tip of the screw 461 penetrates the sheet 72 and contacts the collector bar 50.
  • the support bar 70 is formed by filling the sheet 72 with cement or the like, which is the material for the main body portion 71.
  • the cathode assembly 300 is installed in the electrolytic furnace in an upside-down state from FIG. 20D.
  • FIG. 21 is a cross-sectional view schematically showing how the collector bar 50 expands in the width direction. While the outer surface 51c of the first sub-bar 51 and the outer surface 52c of the second sub-bar 52 are restrained by the side surface 10b of the groove 11, a gap exists between the first sub-bar 51 and the second sub-bar 52. . Therefore, when the collector bar 50 is heated, the collector bar 50 thermally expands inward from the outside in the width direction, as schematically shown by the white arrow in FIG.
  • the lower surface (51b, 52b) of the collector bar 50 and the support surface 70a of the support bar 70 are each inclined so that the height increases from the outside to the inside in the width direction. Therefore, when the collector bar 50 expands inward in the width direction, it slides up on the support surface 70a, and the collector bar 50 moves upward in the height direction (z direction). As a result, strong contact pressure is applied between the bottom surface 10a of the groove 11 and the top surface (51a, 52a) of the collector bar 50.
  • the configuration of the cathode assembly 300 according to the third embodiment of the present invention has been described above. According to the configuration of the cathode assembly 300, when the collector bar 50 thermally expands, a stronger contact pressure is applied to the bottom surface 10a than the side surface 10b of the groove 11 of the cathode block 10, so that the current path inside the cathode block 10 is can be minimized and power consumption can be suppressed.
  • Electrolytic furnace 100 100A, 100B, 200, 200A, 300, 900 Cathode assembly 10, 910 Cathode block 11, 911 Groove 10a Bottom surface 11b Side surfaces 20, 50, 920 Collector bar 20a, (51a, 52a) Top surface (first surface) 20b, (51b, 52b) Bottom surface (second surface) 20c Outer surface 30, 60, 70 Support bar (31a, 32a), (61a, 62a), 70a Support surface 91 Anode 92 Shell 93 Lining 94 Melt 95 Aluminum

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Furnace Details (AREA)

Abstract

Un ensemble cathode (100) comprend : un bloc de cathode (10) constitué de carbone et ayant une rainure (11) formée dans le fond ; une barre collectrice métallique (20) disposée dans la rainure (11) ; et une barre de support (30) disposée dans la rainure (11). La barre collectrice (20) possède une première surface (20a), qui est en contact avec la surface inférieure (10a) de la rainure (11), et une seconde surface (20b), qui est une surface sur le côté opposé à la première surface (20a). La barre de support (30) possède des surfaces de support (31a, 32a) qui sont des surfaces en contact avec la seconde surface (20b) et ont une forme se conformant à la seconde surface (20b). La seconde surface (20b) et les surfaces de support (31a, 32a) sont inclinées de telle sorte que, lorsque la barre collectrice (20) s'étend dans la direction de la largeur, la barre collectrice (20) se déplace vers le haut dans la direction de la hauteur.
PCT/JP2023/028739 2022-08-09 2023-08-07 Ensemble cathode Ceased WO2024034560A1 (fr)

Applications Claiming Priority (2)

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JP2022126882A JP2024024213A (ja) 2022-08-09 2022-08-09 カソードアセンブリ
JP2022-126882 2022-08-09

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WO2024034560A1 true WO2024034560A1 (fr) 2024-02-15

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009533550A (ja) * 2006-04-13 2009-09-17 エスゲーエル カーボン ソシエタス ヨーロピア 非平坦なスロット形態を有する、アルミニウム電解セルのためのカソード
WO2018134754A1 (fr) * 2017-01-23 2018-07-26 Dubai Aluminium Pjsc Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009533550A (ja) * 2006-04-13 2009-09-17 エスゲーエル カーボン ソシエタス ヨーロピア 非平坦なスロット形態を有する、アルミニウム電解セルのためのカソード
WO2018134754A1 (fr) * 2017-01-23 2018-07-26 Dubai Aluminium Pjsc Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult

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