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WO2018134754A1 - Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult - Google Patents

Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult Download PDF

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Publication number
WO2018134754A1
WO2018134754A1 PCT/IB2018/050300 IB2018050300W WO2018134754A1 WO 2018134754 A1 WO2018134754 A1 WO 2018134754A1 IB 2018050300 W IB2018050300 W IB 2018050300W WO 2018134754 A1 WO2018134754 A1 WO 2018134754A1
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WO
WIPO (PCT)
Prior art keywords
cathode
bar
slot
side wall
cathode assembly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2018/050300
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English (en)
Inventor
Bernard JONQUA
Mustafa MUSTAFA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dubai Aluminium PJSC
Original Assignee
Dubai Aluminium PJSC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dubai Aluminium PJSC filed Critical Dubai Aluminium PJSC
Priority to CA3049822A priority Critical patent/CA3049822C/fr
Priority to PL18741304T priority patent/PL3571333T3/pl
Priority to EP18741304.2A priority patent/EP3571333B1/fr
Publication of WO2018134754A1 publication Critical patent/WO2018134754A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/16—Electric current supply devices, e.g. bus bars

Definitions

  • the invention relates to the field of fused salt electrolysis using the Hall-Heroult process for making aluminium. More specifically it relates to the improvement of the cathode blocks of such an electrolysis cell, the improvement being related to the cathode drop and the current distribution along the cathode blocks. In particular, the invention relates to an improvement for cathode block provided with a cathode collector bar.
  • the Hall-Heroult process is the only continuous industrial process for producing metallic aluminium from aluminium oxide.
  • Aluminium oxide Al 2 0 3
  • molten cryolite Na 3 AIF 6
  • the resulting mixture typically at a temperature comprised between 940 °C and 970 °C acts as a liquid electrolyte in an electrolytic cell.
  • An electrolytic cell used for the Hall-Heroult process typically comprises a steel shell (so-called pot shell), a lining (comprising refractory bricks protecting said steel shell against heat, and cathode blocks usually made from graphite, anthracite or a mixture of both), and a plurality of anodes (usually made from carbon) that plunge into the liquid electrolyte contained in the volume defined by the cathode bottom and a side lining made from carbonaceous material.
  • Anodes and cathodes are connected to external busbars.
  • An electrical current is passed through the cell (typically at a voltage between 3.5 V and 5 V) which electrochemically reduces the aluminium oxide, split in the electrolyte into aluminium and oxygen ions, then into aluminium at the cathode and oxygen at the anode; said oxygen reacting with the carbon of the anode to form carbon dioxide.
  • the resulting metallic aluminium is not miscible with the liquid electrolyte, has a higher density than the liquid electrolyte and will thus accumulate as a liquid metal pad on the cathode surface below the electrolyte from where it needs to be removed from time to time, usually by suction into a crucible.
  • Industrial electrolytic cells used for the Hall-Heroult process are generally rectangular in shape and connected electrically in series, the ends of the series being connected to the positive and negative poles of an electrical rectification and control substation.
  • the general outline of these cells is known to a person skilled in the art and will not be repeated here in detail. They have a length usually comprised between 8 and 25 meters and a width usually comprised between 3 and 5 meters.
  • the cells also called “pots” are always operated in series of several tens (up to several hundreds) of pots (such a series being also called a "potline”); within each series DC currents flow from one cell to the neighbouring cell.
  • the electrical currents in most modern electrolytic cells using the Hall- Heroult process exceed 200 kA and can reach 400 kA, 450 kA or even more; in these potlines the pots are arranged side by side. Most newly installed pots operate at a current comprised between about 350 kA and 600 kA, and more often in the order of 400 kA to 500 kA. The passage of these enormous current intensities through the electrolytic cell leads to ohmic losses at various locations of the pot and its environment.
  • Cathode assemblies for use in electrolytic cells suitable for the Hall-Heroult process are industrially manufactured for more than a century, and the state of the art is summarized in the reference book "Cathodes in Aluminium Electrolysis” by M. S0rlie and H. 0ye, 3 rd edition (Dusseldorf 2010). They comprise a cathode body made from a carbon material and one or more metallic cathode bars that are fitted into slots or grooves machined into the lower surface of said carbon body. Said metallic cathode bar protrudes out of each end of the cathode block, thereby allowing to connect the cathode assembly to the cathode busbar system.
  • the metallic cathode bar is usually mode from steel; copper inserts within the steel bar can be used in order to increase the electrical conductivity of the cathode bar.
  • Said steel bars are inserted into grooves that are wider than the steel bars, and then fixed with electrically conductive glue (carbonaceous glue or cement, or ramming paste) or with cast iron that is poured into the interstitial space between the steel bar and the carbon body, as described in GB 663 763 (assigned to Compagnie de Produits Chimiques et Electrometallurgiques Alais, Froges & Camargue).
  • a cathode with a full copper cathode bar inlaid into a groove machined in the lower surface of the carbon body is known from WO 2016/079605 (Kan Nak s.a.), in particular figures 7 and 9 of said document.
  • the contact between the carbon body and the copper bar is critical for the electrical performance of the electrolysis cell. Copper has a much higher thermal expansion coefficient than the carbon material of the cathode block body, and the copper bar in direct contact with the carbon body will operate at a temperature that is probably less than 100°C lower than its melting point, leading to significant thermal expansion.
  • the problem addressed by the present invention is therefore to improve the quality and reliability of the electrical contact of metallic bars, in particular copper bars, inserted into grooves machined into the carbon body of a cathode block.
  • a first object of the invention is a cathode assembly suitable for a Hall-Heroult electrolysis cell, comprising
  • a cathode body made of a carbonaceous material, said cathode body being provided with at least one slot, said slot being provided with side walls parallel to a longitudinal direction of said slot;
  • cathode collector bar made of a metallic material, said cathode bar being provided with side walls, which are in contact with said side walls of said slot;
  • said cathode bar comprises two bar elements, each bar element being provided with a main side wall which is in contact with a respective side wall of said slot, as well as a tapered wall, the two tapered walls of said bar elements forming a contact line between these two bar elements.
  • said cathode assembly is provided with fixation means, in particular permanent fixation means, between said tapered walls of said bar elements.
  • Said fixation means are advantageously welding means.
  • said welding means comprise at least one welding line, in particular several welding lines, extending over at least part of said contact line.
  • said cathode body is provided with at least one first and one second slots, each slot being provided with a blind wall defining a longitudinal end of said slot, each slot receiving a respective cathode bar.
  • said cathode bar is jammed against said longitudinal end of a respective slot.
  • one first bar element has a triangular shape and comprises a front wall, said main side wall and said tapered wall.
  • one second bar element comprises a further side wall, opposite to main side wall, said further side wall protruding with respect to main side wall of first bar element, along a transversal direction of said slot.
  • said front wall of first bar element is positioned against longitudinal end of said slot, and said second bar element comprises a front wall, the length of which is far inferior to that of front wall of first bar element, front wall of second bar element being remote from end of said slot.
  • said cathode bar has two portions, i.e. a first portion the width of which is equal to that of slot, as well as a second portion the width of which is superior to that of slot.
  • said cathode bar has a protrusion which extends outside said slot.
  • Said protrusion is in particular formed by said second portion and by a fraction of said first portion.
  • main side wall of each bar element protrudes outside said slot.
  • main side wall of each bar element directly contacts a respective side wall of said slot.
  • main side wall of each bar element indirectly contacts a respective side wall of said slot, an intercalary material, in particular at least one graphite foil, being interposed between said main side wall and said respective side wall of said slot.
  • a further intercalary material, in particular at least one further graphite foil may be interposed between upper wall of said slot and facing walls of bar elements.
  • said side walls of said slot and said side walls of said bar elements show a slope, the value of which is in particular of about 10 degrees, so as to retain said bar elements in the inner volume of said slot.
  • Said cathode bar is advantageously made of copper.
  • said cathode bar is made of steel.
  • Another object of the present invention is a process for making a cathode assembly as described above, comprising the steps of
  • each bar element being provided with a main side wall and a tapered wall
  • urging forward said second bar element also provokes the jamming of said first bar element against one longitudinal end of said slot.
  • said process further comprises providing said side walls of said slot and said side walls of said bar elements with a slope, the value of which is in particular of about 10 degrees, so as to retain said bar elements in the inner volume of said slot.
  • second bar element is provided with a handling portion and said second bar is urged forward manually, by handling said handling portion.
  • bar elements are provided by cutting a rough bar along a cutting line, said cutting line being tapered with respect to main axis of said rough bar.
  • said process further comprises providing fixation means, in particular permanent fixation means, between said tapered walls of said bar elements, once said tapered walls of said bar elements are in mutual contact.
  • Another object of the present invention is an electrolytic cell suitable for the Hall-Heroult electrolysis process, comprising a cathode forming the bottom of said electrolytic cell and comprising a plurality of parallel cathode assembly, each cathode assembly comprising at least one metallic cathode collector bar protruding out of each of the two ends of the cathode,
  • each anode assembly comprising at least one anode and at least one metallic anode rod connected to an anode beam
  • At least one of said cathode assembly and preferably more than 60% of said cathode assemblies and, more preferably, each of said cathode assemblies, is a cathode assembly as described above.
  • Another object of the present invention is an electrolytic cell for the production of aluminium by the Hall-Heroult process, comprising at least one cathode assembly as described above.
  • Another object of the present invention is a process for making aluminium by the Hall- Heroult process, using an electrolytic cell provided with cathode assemblies as described above.
  • FIGS 1 to 1 1 represent one embodiment of the present invention.
  • Figure 1 is a perspective view, showing one embodiment of a cathode assembly according to the invention.
  • Figure 2 is a perspective view, showing upside down a cathode body which belongs to said cathode assembly according to the invention, said figure 2 showing in particular slots provided in said cathode body.
  • Figure 3 is a longitudinal section showing the cathode body of figure 2.
  • Figure 4 is a top view, showing at a greater scale a rough bar from which a cathode bar is formed, said cathode assembly of figure 1 being equipped with said cathode bar.
  • Figure 5 is a top view, analogous to figure 4, showing a cutting operation of said rough bar of figure 4, in order to form two bar elements.
  • Figures 6 and 7 are top views, analogous to figure 5, showing two steps of the insertion of said bar elements into a slot of said cathode body.
  • Figure 8 is a top view, analogous to figures 6 and 7, showing the final cathode bar of the cathode assembly according to the invention, said cathode bar being formed from said bar elements once inserted in said slot and mutually attached.
  • Figures 9 and 10 are top views, showing at still a greater scale the details IX and X of figure 8.
  • Figure 1 1 is a cross section showing the cathode bar of figure 8, along line XI-XI of figure 8.
  • a cathode assembly comprises a cathode body 1 and at least one cathode bar 3.
  • the present invention is first applicable to cathode assemblies C comprising a cathode body 1 and at least one cathode bar 3 and 3'.
  • the invention is applicable to cathode assemblies comprising two cathode bars 3,3', one 3 of which is protruding out of the front wall 11 , the other 3' protruding out of the rear wall 12 of the cathode body 1.
  • These cathode bars which are half bars, form two portions of a so-called "split bar” in the sense that they are not through bars, i.e. each cathode bar is not extending through the whole length of the cathode block.
  • the present invention is also applicable to cathode assemblies having one (or more) through bar(s) instead of above defined split bars.
  • the invention applies in particular to such through bars, which have a short length.
  • the use of split bars is preferred, since it allows a better jamming of these bars, as will appear at reading the following description.
  • the present invention applies to cathodes used in the Hall-Heroult process that form the bottom of an electrolysis cell, said cathodes being assembled from individual cathode assemblies C, each of which bears at least one cathode bar 3, 3'.
  • the Hall-Heroult process and the outline of an electrolysis cell (also called “pot") are known to a person skilled in the art and will not be described here in great detail.
  • the invention will be explained in relation with embodiments comprising one split cathode bar per cathode assembly C, said split cathode bar comprising two portions 3, 3' but it is understood that the present invention can be applied to cathode assemblies C comprising any number of split cathode bars with portions 3, 3', such as two sets of split bars arranged parallel to each other. In the following the portion of a split cathode bar will be referred to as the "cathode bar”.
  • the cathode assembly of the invention is designated as a whole by alphanumeric reference C. It is suitable for a Hall-Heroult electrolysis cell, but could be used in other electrolytic processes.
  • the cathode assembly C first comprises a cathode body 1 , of known type, which is made of a carbonaceous material, typically graphitized carbon or graphite.
  • This cathode body 1 which has an elongated shape, has opposite end walls, i.e. front 11 and rear 12 walls, as well as peripheral walls. The latter are formed by parallel upper and lower walls 13 and 14, as well as parallel side walls 15 and 16.
  • its length L1 (see figure 3), i.e. the distance between walls 11 and 12, is between about 3100 millimetres (mm) and about 4000 mm.
  • its width W1 (see figure 2), i.e. the distance between walls 15 and 16, is between about 400 mm and about 700 mm.
  • the lower wall 14 of cathode body 1 is provided with two housings, each being formed by a respective longitudinal slot 17 and 17', the longitudinal main axis of which is referenced A17, A17'.
  • Figure 2 shows cathode body "upside down", with reference to its above defined industrial use position.
  • Each slot 17, 17' is provided with opposite side walls 171, 171' and 172, 172' (see figure 2), parallel to said main axis A17, A17', whereas its top wall is referenced 173, 173' (see figure 3).
  • each slot 17, 17' is provided with a respective rear wall, or blind wall 174, 174' (see figure 2), each defining a respective longitudinal end of said slot.
  • the distance D174 (see figure 3) between these two walls is typically between 200 millimetres (mm) and 600 mm. Viewed from bottom, blind wall 174, 174' is rounded, which makes it possible to ease the slot machining.
  • First slot 17 does lead to front wall 11 of this cathode body, whereas second slot 17' does lead to rear wall 12 of this cathode body.
  • width W17 or W17' (see figure 2) of each slot 17, 17', i.e. the distance between side walls, is between about 50 mm and about 250 mm.
  • each side wall 171 and 172 shows a slope, the value as of which is typically of about 10 degrees. Therefore the above defined width W17 or W17' decreases from top wall 173, 173' of this slot to lower wall 14 of cathode body. As will be described hereafter, these slopes make it possible to maintain the bar elements in the inner volume of the slot, when turning over the cathode assemblies. For sake of clarity, the value of as is exaggerated on this figure 11.
  • depth D17 or D17' of each slot 17, 17' is between about 50 mm and about 150 mm.
  • its length L17 or L17' is between about 1200 mm and about 1850 mm. This length is taken from the junction of rounded portion of said blind wall with rectilinear part of side walls 171, 171' and 172, 172'.
  • the cathode assembly C also comprises two cathode bars 3 and 3' (schematically shown on figure 1), each of which is accommodated in a respective slot 17 and 17'.
  • Each cathode bar 3 or 3' is made of a conductive material, typically able to conduct the current from the cathode to the exterior Bus Bar.
  • the material of these cathode bars is copper.
  • the invention encompasses cathode bars made of other materials, such as for example steel, or other materials usually installed inside the cathode assemblies.
  • the first step of said insertion process is the provision of a so called rough bar, which is shown on figure 5 and is referenced 5 as a whole.
  • the dimensions of said rough bar 5 are globally analogous to those of final cathode bar 3, but slightly different.
  • This bar 5, which has an elongated shape, is not shown with its real scale on figure 4, in order to clearly illustrate the insertion process.
  • the same remark applies to mechanical elements of figures 5 to 10: slot 17, cathode bar 3 and bar elements 7 and 9, formed from rough bar 5.
  • the width of these mechanical elements is far exaggerated with respect to their length.
  • top views of figures 6 to 10 have been hatched to clearly distinguish the different mechanical elements.
  • Rough bar 5 has front 51 and rear 52 walls, parallel upper and lower walls 53 and 54, as well as parallel side walls 55 and 56. Respective length L5, width W5 and height H5 of rough bar 5 are defined the same way as above length L1, width W1 and height H1 of cathode body 1.
  • Length L5 of rough bar is far superior to that L17 of slot 17, so that final cathode bar 3 will protrude outside slot 17, above front wall 11.
  • the value of the difference (L5 - L17) implies the length of the protrusion of final cathode bar 3.
  • this difference (L5 - L17) is between 400 and 700 mm.
  • Side walls 55 and 56 show slopes, the angle of which is similar to that aS of the side walls of the slot.
  • the lengths of slotted parts of these side walls are referred L6 and L6' on figure 4. Both L6 and L6' are superior to the length L17 of the cathode slot.
  • the difference (L6 - L17) or (L6' - L17) is between 150 and 200 mm.
  • width W5 of rough bar 5 is slightly superior to that W17 of slot 17, which enables a steady jamming of final cathode bar 3 in the slot 17.
  • the difference (W5 - W17) is between 5 to 10 mm.
  • height H5 of rough bar 5 is equal or slightly inferior to depth D17 of cathode slot, so as to prevent final cathode bar from protruding outside the slot 17, above lower wall 14.
  • the difference (D17 - H5) is between 0 and 4 mm.
  • the insertion process then implies cutting rough bar 5, so as to form two cathode bar elements, or so called bar elements 7 and 9. Rough bar 5 is cut along a cutting line referenced CL, shown on figure 4.
  • This line CL forms an angle, noted ac, with the main longitudinal axis A5 of rough bar 5.
  • this angle ac is between 1 ° and 4°, typically of about 2°.
  • the cutting operation can be carried out by water jet cutting following a machining of the two surfaces, since the cut cannot be straight and the roughness will not be good enough to get a good contact between the two parts.
  • Another way is cutting the two parts directly by machining using a circular cutting blade, typically of 3 to 6 mm of thickness. The latest way is preferred, since the cutting surface will present a good roughness and machining the cut surfaces will therefore not be necessary.
  • first bar element 7 has a triangular shape. It has a front wall 71 , a main side wall 73, as well as a tapered wall 77. It has neither a rear wall, nor a second side wall, since wall 77 directly connects both walls 71 and 73. Side wall 73 shows a slope, which corresponds to that of side wall 55 of rough bar 5.
  • Width W7 is inferior to that W5 of rough bar 5, and is also slightly inferior to that W17 of the slot, so as to enable an insertion without jamming of said bar element 7 into slot 17.
  • the difference (W17 - W7) is between 10 and 40 mm.
  • Length L7 is far inferior to that L5 of rough bar 5, but is slightly superior to that L17 of slot, so as to enable a protrusion of said bar element 7 outside slot 17.
  • the difference (L7 - L17) is between 20 and 100 mm.
  • height H7 of bar element 7 is equal to that H5 of rough bar 5.
  • second bar element 9 has a shape which is different from a triangle. It has a short front wall 91 , a long rear wall 92, a main side wall 93, a short side wall 94, as well as a tapered wall 97. Side wall 93 shows a slope, which corresponds to that of side wall 56 of rough bar 5.
  • This second bar element can therefore be divided into two parts, namely a handling part 9A with constant width, as well as an insertion part or tip 9B, with a tapered shape.
  • Tip 9B is ended by a shoulder 9C, formed adjacent front wall 91 , which eases the jamming of bars 7 and 9 into the slot.
  • the respective dimensions of above defined walls and parts of bar element 9 are as follows:
  • first bar element 7 is inserted into slot 17. It is to be noted that this step is carried out with a cathode block upside down. In other words, during said insertion, access to slot 17 is permitted from the end of the cathode block groove, whereas so called lower wall of cathode body is in an upper position.
  • bar element 7 rests by gravity against wall 173 of this slot. Since W7 is inferior to W17 of slot, this insertion can be carried out easily, without jamming of said bar element 7 into slot 17.
  • Bar element 7 is positioned in the slot, so that its front wall 71 is close to the end of the slot, and its main side wall 73 is adjacent side wall 172 of the slot. End of the slot is defined by the transition between rectilinear side walls 171 , 172 and rounded wall 174.
  • main side wall 73 of first bar element 7 is urged against facing side wall 172 of slot 17, along arrow F73, whereas main side wall 93 of second bar element 9 is urged against facing opposite side wall 171 of slot 17, along arrow F93.
  • insertion operation has been described manually. However, an automatic operation may be considered, with any appropriate tool.
  • At least one and, preferably several welding lines are provided along the above defined contact line 37.
  • four welding lines 21 to 24 are provided.
  • L21 to L24 the length of each of these lines, as well as Lw the so called welding length, which corresponds to the sum (L21 + L22 +L23 + L24) of the lengths of these lines.
  • L21 to L24 is typically between 50 and 100 mm, whereas the welding ratio, i.e (Lw I L37) is between 10 and 40 %.
  • Said global cathode bar has front 31 and rear 32 walls, as well as side walls 33 and 34.
  • Said figure 8 also illustrates above described tapered line 37, separating walls 77 and 97 of bar elements 7 and 9.
  • front wall 31 is formed by front wall 71 and front wall 91 , as well as by a linking portion 77' of tapered wall 77.
  • Front wall 91 is remote from end of slot, whereas front wall 71 is positioned against said end, as explained above.
  • side wall 33 is formed by side wall 73 and side wall 93, as well as by a linking portion 97' of tapered wall 97.
  • Side wall 93 protrudes laterally, with respect to side wall 73.
  • Cathode can be decomposed into two portions, i.e. a first portion 3A the width of which W3A is equal to that W17 of slot 17, as well as a second portion 3B the width of which W3B is equal to that W5 of rough bar 5.
  • This cathode defines a protrusion 3C, which extends outside slot 17.
  • This protrusion which is formed by portion 3B as well as by a fraction of portion 3A, has a typical length L3C between 400 and 700 mm.
  • cathode bars 3 and 3' are positioned and jammed in their respective slot 17 and 17', the whole cathode assembly is turned upside down, so as to be in its final position of figure 1. Due to the slopes of side walls of both the slots and the bar elements, as above described in reference to figure 11 , cathode bars cannot escape from their slots due to gravity, so that they are firmly retained therein.
  • each side wall of cathode bar 3 directly contacts facing side walls of the slot 17, i.e. without any intercalary material.
  • the invention also encompasses alternative embodiments, wherein side walls of cathode bar indirectly contacts facing side walls of the slot.
  • a thin sheet of an intercalary material is interposed between said facing walls of slot and cathode bar.
  • said intercalary material is a graphite foil, inserted between said facing side walls. This graphite foil is typically placed against the side walls of the slot, before insertion of bar elements.
  • a further intercalary material, in particular at least one further graphite foil may also be interposed between upper wall 173 of said slot and facing walls of the bar elements 7 and 9.
  • one single intercalary graphite foil may recover both side walls and upper wall of the slot.
  • the adjustment will be set, so that no substantial gap or space is left between bar elements, graphite foil and cathode body.
  • Said graphite foil can be a flexible graphite foil of compressed expanded graphite.
  • Said foil is available from various suppliers under different trademarks, such as PAPYEX® by MERSEN.
  • the density of the foil is typically 0.7 and it may have 0.5 mm of thickness.
  • graphite material is compressible to cope with the thermal expansion of bar elements.
  • the D18 technology has been described in several papers such as: “Update on the development of D18 cell technology at DUBAL” (D. Whitfiled et al., Light Metals 2012, p. 727-731); “D18+: potline modernization at DUBAL” (S. Akhmetov et al., Light Metals 2013, p. 561-656); “From D18 to D18+: Progression of DUBAL's original potlines” (D. Whitfield et al. , Light Metals 2015, p. 499-504).
  • the selected electrolysis cell was provided with new cathode blocks; seventeen cathode assemblies were used, and the assembly n° 2,7, 1 1 , and 16 had copper cathode bars according to the invention, whereas the other ones were provided with conventional steel cathode bars.
  • Cathode assemblies n° 2 and 7 had a sheet of graphite foil between the cathode bar and the cathode block, whereas assemblies n° 11 and 16 had a direct contact between the copper cathode bar and the cathode material. All cathode bars were half bars. Contact tabs were made from copper.
  • the cell was started up according to conventional practice and run for about 3.5 months under production conditions (211 kA).
  • cathode assemblies with copper bars according to the invention were pulling about 40 % more current than cathode assemblies with steel bars in the same cell. This demonstrates that a significant gain can be obtained by constructing a pot equipped with all cathodes having full copper bars. At the beginning of the operations, a small difference was observed between copper cathode bars in direct contact with the cathode block and copper cathodes bars with an intercalary graphite foil, giving the benefit to the latest.
  • the cell was then autopsied; the copper bars could be easily cut out, and it was found that for each half bar the two bar elements were firmly welded together at their tapered interface and did not separate upon removal. This shows that the electrical contact at the tapered interface between the two bar elements was excellent. No melting of the copper bar was observed, no significant visual change was observed. Slight remains of graphite foil were visible on the collector bar side for the two bars that had been in contact with graphite foil. The copper could be fully recovered for recycling.

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  • Electrolytic Production Of Metals (AREA)

Abstract

Cet ensemble cathode (C) comprend : - un corps de cathode (1) en matériau carboné, ledit corps de cathode étant pourvu d'au moins une fente (17, 17'), ladite fente étant pourvue de parois latérales (171, 172, 171', 172') parallèles à une direction longitudinale (A17, A17') de ladite fente ; - au moins une barre collectrice de cathode (3, 3') en un matériau métallique, ladite barre de cathode étant pourvue de parois latérales (33, 34), qui sont en contact avec lesdites parois latérales de ladite fente. Selon l'invention, ladite barre de cathode comprend deux éléments de barre (7, 9), chaque élément de barre étant pourvu d'une paroi latérale principale (73, 93) qui est en contact avec une paroi latérale respective (171, 172) de ladite fente, ainsi qu'une paroi conique (77, 97), les deux parois coniques desdits éléments de barre formant une ligne de contact (37) entre ces deux éléments de barre.
PCT/IB2018/050300 2017-01-23 2018-01-18 Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult Ceased WO2018134754A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CA3049822A CA3049822C (fr) 2017-01-23 2018-01-18 Ensemble cathode avec barre collectrice metallique pour cellule d'electrolyse se pretant au procede hall-heroult
PL18741304T PL3571333T3 (pl) 2017-01-23 2018-01-18 Zespół katodowy z metalowym prętem kolektorowym do ogniwa elektrolitycznego odpowiedni do procesu halla-héroulta
EP18741304.2A EP3571333B1 (fr) 2017-01-23 2018-01-18 Ensemble cathode avec barre collectrice métallique pour cellule d'électrolyse se prêtant au procédé hall-héroult

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GB1701067.9A GB2558936A (en) 2017-01-23 2017-01-23 Cathode assembly with metallic collector bar for electrolytic cell suitable for the Hall-Héroult process
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GB2595460A (en) * 2020-05-26 2021-12-01 Dubai Aluminium Pjsc Cathode assembly with metallic collector bar systems for electrolytic cell suitable for the Hall-Héroult process
WO2023119802A1 (fr) 2021-12-23 2023-06-29 Ｓｅｃカーボン株式会社 Ensemble cathode
WO2024034560A1 (fr) * 2022-08-09 2024-02-15 Ｓｅｃカーボン株式会社 Ensemble cathode

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US4795540A (en) * 1987-05-19 1989-01-03 Comalco Aluminum, Ltd. Slotted cathode collector bar for electrolyte reduction cell
US6294067B1 (en) * 2000-03-30 2001-09-25 Alcoa Inc. 3 component cathode collector bar
US20040011661A1 (en) * 2002-07-16 2004-01-22 Bradford Donald R. Electrolytic cell for production of aluminum from alumina
EP1845174A1 (fr) * 2006-04-13 2007-10-17 Sgl Carbon Ag Cathode pour l'électrolyse de l'aluminium avec une rainure de conception non plane
CN105671592A (zh) * 2016-03-14 2016-06-15 中冶天工集团有限公司 一种铝电解槽阴极钢棒等距分段的方法

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GB2595460A (en) * 2020-05-26 2021-12-01 Dubai Aluminium Pjsc Cathode assembly with metallic collector bar systems for electrolytic cell suitable for the Hall-Héroult process
WO2021240353A1 (fr) 2020-05-26 2021-12-02 Dubai Aluminium Pjsc Ensemble cathode avec systèmes de barres collectrices métalliques pour cellule d'électrolyse se prêtant au procédé hall-héroult
WO2023119802A1 (fr) 2021-12-23 2023-06-29 Ｓｅｃカーボン株式会社 Ensemble cathode
WO2024034560A1 (fr) * 2022-08-09 2024-02-15 Ｓｅｃカーボン株式会社 Ensemble cathode

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PL3571333T3 (pl) 2021-12-27
EP3571333A4 (fr) 2020-09-09
CA3049822C (fr) 2024-03-26
EP3571333B1 (fr) 2021-08-18
EP3571333A1 (fr) 2019-11-27
GB2558936A (en) 2018-07-25
GB201701067D0 (en) 2017-03-08

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