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WO2022018767A1 - Composition agrochimique comprenant des fongicides sdhi - Google Patents

Composition agrochimique comprenant des fongicides sdhi Download PDF

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Publication number
WO2022018767A1
WO2022018767A1 PCT/IN2021/050721 IN2021050721W WO2022018767A1 WO 2022018767 A1 WO2022018767 A1 WO 2022018767A1 IN 2021050721 W IN2021050721 W IN 2021050721W WO 2022018767 A1 WO2022018767 A1 WO 2022018767A1
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Prior art keywords
formulation
acid
oil
weight
group
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Inventor
Dipakkumar Patel
Kenal V. Shah
Bhavesh V. Shah
Kawarlal DABHODIA
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Rajdhani Petrochemicals Pvt Ltd
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Rajdhani Petrochemicals Pvt Ltd
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Priority to BR112023001314A priority Critical patent/BR112023001314A2/pt
Publication of WO2022018767A1 publication Critical patent/WO2022018767A1/fr
Anticipated expiration legal-status Critical
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
    • A01P3/00—Fungicides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof

Definitions

  • the present invention relates to synergistic fungicidal compositions comprising bioactive amounts of (A) a fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometylor mixture thereof; (C) at least one more compound selected from plant health additive or mixture thereof.
  • the present invention further relates to process of preparing said composition along with at least one inactive excipients and formulation thereof.
  • Combination of fungicides are used to broaden the spectrum of control of fungus and fungal disease, to improve the pest control with synergistc effect, reduce dosage, thereby reducing environmental impact, to broaden the spectrum of control, i.e. decrease chances of development and management of resistance and to enhance residual control so lesser the number of sprays for crop protections and minimizing the pesticidal load in ecosystem.
  • the combination of fungicide at times demonstrate an additive or synergistic effect that results in an improved control on the pests.
  • Fungicide or pesticides are used widely and very frequently in commercial agriculture and have enabled an enormous increase in crop yields and product quality which ultimately increased the ease to farmers in term of economic advantage as well as ease offarming activities.
  • Plant health additives are typically any substance or mixture of substances intended to accelerate or slow down the rate of growth or ripening, or otherwise change the development of plants, or to produce plants.
  • Some plant growth regulators protect plants from abiotic stress. They give tolerance to extreme temperatures, both high and low, to drought, to high salt content, which are some examples of abiotic stresses that plants can undergo.
  • PGA allows plants to withstand abiotic stresses by controlling the natural expression of hormones in the plant.
  • fungicdesalong with plant heakthadditieves are known in the art for the control of soil borne pests.
  • US 10219514 patent relates fungicidal compositions for the treatment of phytopathogenic diseases of useful plants, especially phytopatho genic fungi, and to a method of controlling phytopathogenic diseases on useful plants.
  • the patent more specifically relates to a composition comprising thifuzamide and related fungiceds along with paclobutrazol and other plant health additives.
  • WO2018202428 patent relates to a fungicidal mixture for controlling phytopathogenic harmful fungi using mixtures of fungicides.
  • the fungicidal mixture comprises fungicides like fluxapyroxad, pyraclostrobin, mancoze, azoxystrobin along with paclobutrazol and other plant health additives.
  • US 10076119 patent relates pesticidal mixtures comprising one biological compound and at least one fungicidal or plant growth regulating compound as defined herein and respective agricultural uses thereof. Further it relates to fluxapyroxad, pyraclostrobin along with gibberlic acid, brassinolide along with various plant growth regulators.
  • composition comprises at least one fungicide from SDHI (Succinate Dehydrogenase Inhibitors); one more fungiced from various mode of action; and at least one plant health additiveswhich overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
  • SDHI Surface Dehydrogenase Inhibitors
  • plant health additives which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
  • the pesticide actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target organism, such as plants, fungi and insects.
  • the target organism such as plants, fungi and insects.
  • most active pesticide compounds that are used as pesticides are only sparingly or even insoluble in water.
  • the low solubility of such compounds present the challenges and difficulties to formulator in formulating pesticide compounds in stable formulations that can be easily stored for a long time and which still have a high stability and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.
  • Yet another object of the present invention is to provide improved combinations of fungicide that promote plant health.
  • Yet another object of the present invention is to provide improved combinations of fungicide that promote plant health, plant yield enhancement, induce tolerance to fungal and bacterial diseases.
  • Embodiment of the present invention can ameliorate one or more of the above mentioned problems.
  • Inventors of the present invention have surprisingly found that the novel synergistic composition of at least one fungicide from SDHI ( Succinate Dehydrogenase Inhibitors); one more fungiced from various mode of action; and at least one plant health additivesas described herein which can providesolution to the above mentioned problems.
  • SDHI Succinate Dehydrogenase Inhibitors
  • plant health additivesas described herein which can providesolution to the above mentioned problems.
  • an aspect of the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometylor mixture thereof; (C) At least one more compound selected from plant health additive or mixture thereof.
  • a fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof
  • B at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport
  • a fungicide from class of SDHI selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl- benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof
  • B at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof
  • C At least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane
  • the present invention provides a method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs that grow at a later point in time against pathogenic damage or pest damage by applying to the plant propagation material a composition comprising afungicidal composition defined in the first aspect.
  • formulation for the fungicidal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (
  • the remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts.
  • the formulation is preferably, completely free from organic solvents.
  • the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4- carboxamides, pyridine carboxamides or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof;
  • SDHI Stuccinate de
  • Bioactive amounts as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
  • an aspect of the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one more compound selected from plant health additive or mixture thereof.
  • a fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof
  • B at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or
  • a further aspect of the present invention provides a synergistic fugicidal compositions comprising bioactive amounts of (A) A fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4- carboxamides, pyridine carboxamides or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C
  • a fungicide from class of SDHI selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4- carboxamides, pyridine carboxamides or mixture thereof
  • SDHI Stinate dehydrogenase inhibitors
  • class of fungicides from group of phenyl benzamides may be selected from benodanil, flutolanil, mepronil.
  • SDHI Stinate dehydrogenase inhibitors
  • SDHI succinate dehydrogenase inhibitors
  • isofetamid isofetamid
  • SDHI Stinate dehydrogenase inhibitors
  • group of pyridinyl-ethyl-benzamides is fluopyram.
  • SDHI succinate dehydrogenase inhibitors
  • SDHI succinate dehydrogenase inhibitors
  • fungicides from group of furan carboxamides is fenfuran.
  • SDHI (Succinate dehydrogenase inhibitors) class of fungicides from group of oxathincarboxamides may be selected from carboxin, oxycarboxin, thiazole carboxamides-thifluzamide.
  • SDHI succinate dehydrogenase inhibitors
  • Qol Quinone outside Inhibitors
  • Qol (Quinone outside Inhibitors) class of fungicides from group of dihydrodioxazines is fluoxastrobin.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of imidazolinones is fenamidone.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of methoxy acrylates may be selected from azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of methoxy carbamates may be selected from pyraclostrobin, pyrametostrobin, triclop yricarb.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of methoxyacetamide is mandestrobin.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of oximinoacetamides may be selected from dimoxystrobin, fenamistrobin, metominostrobin, orysastrobin.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of oximino acetates may be selected from kresoxim methyl, trifloxystrobin.
  • Qol (Quinone outside Inhibitors) class of fungicides from group of oxazolidinediones is famoxadone.
  • Qil (Quinone inside Inhibitors) class of fungicides from group of cyano imidazole is cyazofamid; from group of sulfamoyltriazol is amisulbrom; from group of picolinamides is fenpicoxamid, florylpicoxamid; from group of tetrazolinones is metyltetraprole.
  • Lipid or transport and membrane synthesis inhibitor class of fungicides from group of dithiolanes is isoprothiolane; from group of phosphorthiolates may be selected from edifenphos, iprobenfos (IBP), pyrazophos; from group of aromatic hydrocarbons (F3) may be selected from biphenyl, chloroneb, dicloran, quintozene, tecnazene, tolcofos methyl, etridiazole; from group of carbamates may be selected from iodocarb, propamocarb, prothiocarb; from group of terpene hydrocarbons is extract from Melaleuca arternifolia (tea tree), plant oils (mixtures); eugenol, geraniol, thymol; from group of amphoteric macrolide antifungal is natamycin (pimaricin); from group of piperidinylthiazoleisox
  • sterol biosynthesis Inhibitors class of fungicides from group of morpholines may be selected from aldimoprh, dedomorph, tridemorph, fenpropimorph; from group of piperidines may be selected from fenpropidin, piperalin.
  • sterol biosynthesis Inhibitors class of fungicides from group of spiroketal amines is spiroxamine; from amino pyrazolinone is fenpyrazamine; from group of hydroxyanilide is fenhexamid; from group of allaylamines may be selected from naftifine, terbinafine, pyributicarb.
  • fungicides from the class Melanin synthesis in cell wall Inhibitors may be selected from fthalide, pyroquilon, tricyclazole, diclycymet, carpropamid, fenoxanil, trifluoroethyl, tolprocarb.
  • fungicides with unknow mode of action may be selected from cymoxanil, teclofthalam, -triazoxide, fluslfamide, diclomezine, cyflufenamid, guanindines- dodine, flutianil, ferimzone, tebufloquin, picarbutrazox, validamycin.
  • multisite contact fungicides may be selected from inorganic-copper (copper hydroxide, copper oxychloride, copper (II) sulphate, Bordeaux mixture, copper salicylate, cuprous oxide), sulphur, dithiocarbamates and relatives-ferbam, mancozeb, maneb, metiram, propineb, thiram, zinc thiazole, zineb, ziram, phthalimides-captan, captafol, folpet, chloronitriles (phthalonitriles)-chlorothalonil, sulfamides-dichlofluanid, tolylfluanid, bisguanidines-guazatine, iminoctadine, triazines-anilazine, quinones (anthraquinones)-dithianon, quinoxalines-chinomethionat / quinomethionate, maleimide-fluoroimide, thiocarbamate- met
  • fungicides may also be selected from Ipflufenoquin, Pyridachlometyl.
  • plant health additives from the group of Auxins may be selected Indole acetic acid, Indole butyric acid, alpha-naphthyl acetic acid.
  • plant health additives from the group of Cytokinins may be selected from kinetin, zeatin, 6-benzylaminopurine, dipheylurea, thidiazuron
  • plant health additives from the group of Ethylene modulators may be selected from aviglycine, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, aminoethoxyvinylglycine (AVG).
  • plant health additives from the group of Gibberellins may be selected from gibberelline, gibberellic acid, GA3.
  • plant health additives from the group of Growth inhibitors may be selected from abscisic acid, chlorpropham, flumetralin, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquatpentaborate.
  • plant health additives from the group of Growth retardants may be selected from chlormequat, chlormequat chloride, paclobutrazol, uniconazole-
  • plant health additives from the group of Growth stimulators may be selected from brassinolide, forchlorfenuron, triacontanol, silicic acid, silicyclic acid, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5- nitroguaiacolate), nitrobenzene.
  • plant health additives from the group of Micronutrients may be selected from Zinc (zinc sulphate heptahydrate ZnS047H20, zinc sulphate mono hydrate ZnS04.H20, chelated zinc as Zn-EDTA, zinc oxide, Zinc Lactate Gluconate, Zinc Polyflavonoid), Boron (borax-sodium tetraborate, boric acid (H3B03), di-sodium octa borate tetra hydrate (Na2B8013.4H20), di-sodium tetra borate penta hydrate, anhydrous borax, ), Manganese (manganese sulphate), Copper (copper sulphate), Iron (ferrous sulphate, chelated iron as Fe- EDTA), Molybdanum (ammonium molybdate), Magnesium (Magnesium sulphate) or Sulphur (elemental sulphur,
  • plant health additives from the group of Biostimulants may be selected from humic acid, potassium humate, fulvic acid, potassium fulvic acid, amino acid, protein hydrolysates, peptides, organic acid, acetylthioproline, thiazolidine carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, seaweed extract (Ascophyllumnodosum), polyamines, brassinolide, silicon compound-silicic acid, monosilicic acid, orthosilicic acid, disilicic acid, and pyrosilicic acid, silica nanoparticles (10-100 nm), calcium silicate, potassium silicate, sodium silicate), silicyclic acid, lactic acid, phenyllactic acid, fumaric acid, acibenzolar- s-methyl.
  • SDHIs Succinate dehydrogenase inhibitors
  • SDH succinate dehydrogenase
  • Fluxapyroxad is an aromatic amide class of fungicide. It has a role as a succinate dehydrogenase (quinone) inhibitor and an antifungal agrochemical. It is used to control a number of cereal fungal pathogens including those belonging to the Ascomycetes, Basidiomycetes and Zygomycetes families. It targets the succinate dehydrogenase, one of the enzymes in the respiratory chain within the mitochondria of the fungus.
  • succinate dehydrogenase one of the enzymes in the respiratory chain within the mitochondria of the fungus.
  • Thifluzamide is an aromatic amide. It has a role as a succinate dehydrogenase (quinone) inhibitor and an antifungal agrochemical. It has an IUPAC name as N-[2,6-dibromo-4- (trifluoromethoxy)phenyl]-2-methyl-4-(trifluoromethyl)-l,3-thiazole-5-carboxamide. It is an aromatic amide, an aromatic ether, an organofluorine compound, a member of 1,3-thiazoles, a dibromobenzene and an anilide fungicide.
  • Qo inhibitors are a group of fungicides used in agriculture. They represent the most important development made in fungicides by the chemicals industry, [citation needed] Qol are chemical compounds which act at the quinol outer binding site of the cytochrome bcl complex.
  • Qol's are the resulting fusion of three fungicides families, the well-known family of strobilurins and two new families, represented by fenamidone and famoxadone.
  • Some strobilurins are azoxystrobin, kresoxim-methyl, picoxystrobin, pyraclostrobin, and trifloxystrobin.
  • Strobilurins are a group of natural products and their synthetic analogs. A number of strobilurins are used in agriculture as fungicides. They are part of the larger group of Qol (Quinone outside Inhibitors) inhibitors, which act to inhibit the respiratory chain at the level of Complex III. Strobilurins are mostly contact fungicides with a long half time as they are absorbed into the cuticle and not transported any further. They have a suppressive effect on other fungi, reducing competition for nutrients; they inhibit electron transfer in mitochondria, disrupting metabolism and preventing growth of the target fungi.
  • Qol Quinone outside Inhibitors
  • Pyraclostrobin is strobilurin class of fungicide. It has a role as a mitochondrial cytochrome-bcl complex inhibitor, a xenobiotic, an environmental contaminant and an antifungal agrochemical. It is a member of pyrazoles, a carbamate ester, an aromatic ether, a member of monochlorobenzenes, a methoxycarbanilatestrobilurin antifungal agent and a carbanilate fungicide.
  • Pyraclostrobin is a member of the strobilurin group of fungicides.
  • the strobilurin fungicides act through inhibition of mitochondrial respiration by blocking electron transfer within the respiratory chain, which in turn causes important cellular biochemical processes to be severely disrupted, and results in cessation of fungal growth.
  • Azoxystrobin is an aryloxypyrimidine having a 4,6-diphenoxypyrimidine skeleton. It has IUPAC name as methyl (E)-2-[2-[6-(2-cyanophenoxy)pyrimidin-4-yl]oxyphenyl]-3-methoxyprop-2- enoate.
  • An inhibitor of mitochondrial respiration by blocking electron transfer between cytochromes b and c 1 it is used widely as a fungicide in agriculture. It has a role as a mitochondrial cytochrome-bcl complex inhibitor, a xenobiotic, an environmental contaminant, an antifungal agrochemical and a quinone outside inhibitor. It is a nitrile, an aryloxypyrimidine, an enoate ester, an enol ether, a methyl ester and a methoxyacrylatestrobilurin antifungal agent.
  • Azoxystrobin is a fungicide with protectant, eradicant, translaminar & systemic properties. It powerfully inhibits spore germination &, in addition to its ability to inhibit mycelial growth, also shows antisporulant activity. Acts by inhibiting mitochondrial respiration by blocking electron transfer between cytochrome b & cytochrome cl. Controls pathogenic strains resistant to the 14 demethylase inhibitors, phenylamides, dicarboxamides or benzimidazoles.
  • Trifloxystrobin is used as an agricultural fungicide and belongs to the class of strobilurin. It has IUPAC name as methyl 2-methoxyimino-2-[2-[[l-[3 (trifluoromethyl) phenyl] ethylidene amino] oxymethyl] phenyl] acetate. As s Strobilurin fungicidal activity, it inhibits mitochondrial respiration by disrupting the cytochrome complex, thus blocking electron transfer. Multisite fungicide:
  • Mancozeb is a dithiocarbamate non-systemic agricultural fungicide with multi-site, protective action on contact. It controls many fungal diseases in a wide range of field crops, fruits, nuts, vegetables, and ornamentals. Mancozeb reacts with, and inactivates, the sulfhydryl groups of amino acids and enzymes within fungal cells, resulting in disruption of lipid metabolism, respiration, and production of adenosine triphosphate.
  • Chlorothalonil a dinitrile that is benzene-1, 3-dicarbonitrile substituted by four chloro groups.
  • a non-systemic fungicide used to control a range of diseases in a wide variety of crops. It has a role as an antifungal agrochemical. Chlorothalonil reduces deactivates glutathione.
  • Copper fungicides represent one of the oldest active ingredients developed to fight plant diseases. Copper based plant protection products have, unlike conventional fungicides, low risk of developing resistant fungal strains due to their multilateral mode of action. Copper is used in various forms as an algaecide, bactericide, fungicide and water treatment. Copper fungicides are classified as multisite and act by disrupting cellular proteins. Because of this characteristic they have grate value in antiresistant strategy in suppression of important fungal diseases. There is less chance of occurrence of phytotoxicity due to good buffer capacity; resistance does not occur; copper residues in crops are below the limit value. Most copper fungicides are applied as foliar sprays although drench applications have been shown to be safe and effective in some situations.
  • Difenoconazole is a member of the class of dioxolanes.
  • a broad spectrum fungicide with novel broad-range activity used as a spray or seed treatment. It has IUPAC name as l-[[2-[2-chloro-4- (4-chlorophenoxy)phenyl] -4-methyl- 1, 3 -dioxolan-2-yl] methyl]- 1, 2, 4-triazole. It has a role as a sterol 14alpha-demethylase inhibitor and an antifungal agrochemical. It is an aromatic ether, a dioxolane, a member of triazoles, a cyclic ketal, a conazole fungicide and a triazole fungicide.
  • Difenoconazole is applied by foliar spray or seed treatment and acts by interference with the synthesis of ergosterol in the target fungi by inhibition of the 14alpha-demethylation of sterols, which leads to morphological and functional changes in the fungal cell membrane.
  • Prothiconazole is a member of the class of triazoles that is l,2,4-triazole-3-thione substituted compounds. It has IUPAC name as 2-[2-(l-chlorocyclopropyl)-3-(2-chlorophenyl)-2- hydroxypropyl]-lH-l,2,4-triazole-3-thione. Prothioconazole is a systemic demethylation inhibitor fungicide which belongs to the triazolinthione class of fungicides.
  • Plant Growth Additives are defined as small, simple chemicals produced naturally by plants to regulate their growth and development.
  • Plant Growth Regulators can be of a diverse chemical composition such as gases (ethylene), terpenes (gibberellic acid) or carotenoid derivatives (abscisic acid). They are also referred to as plant growth substances, phytohormones or plant hormones.
  • Plant growth hormones are organic compounds which are either produced naturally within the plants or are synthesized in laboratories. They profoundly control and modify the physiological processes like the growth, development, and movement of plants.
  • Gibberellic acid is a simple gibberellin, a pentacyclicditerpene acid promoting growth and elongation of cells. It affects decomposition of plants and helps plants grow if used in small amounts, but eventually plants develop tolerance to it. Gibberellic acid is a very potent hormone whose natural occurrence in plants controls their development. Since GA regulates growth, applications of very low concentrations can have a profound effect while too much will have the opposite effect. Gibberellins have a number of effects on plant development. They can stimulate rapid stem and root growth, induce mitotic division in the leaves of some plants, and increase seed germination rates.
  • GA3 Gibberellic acid
  • Paclobutrazol ( PBZ ) is a plant growth retardant and triazole fungicide. It is a known antagonist of the plant hormone gibberellin. It acts by inhibiting gibberellin biosynthesis, reducing internodal growth to give stouter stems, increasing root growth, causing early fmitset and increasing seedset in plants such as tomato and pepper. PBZ has also been shown to reduce frost sensitivity in plants. Moreover, paclobutrazol can be used as a chemical approach for reducing the risk of lodging in cereal crops. PBZ is used by arborists to reduce shoot growth and has been shown to have additional positive effects on trees and shrubs. Among those are improved resistance to drought stress, darker green leaves, higher resistance against fungi and bacteria, and enhanced development of roots. Cambial growth, as well as shoot growth, has been shown to be reduced in some tree species.
  • Triacontanol is a fatty alcohol of the general formula C30H62O, also known as melissyl alcohol or myricyl alcohol. It is found in plant cuticle waxes and in beeswax. Triacontanol has been reported to increase the growth of plants by enhancing the rates of photosynthesis, protein biosynthesis, the transport of nutrients in a plant and enzyme activity, reducing complex carbohydrates among many other purposes. The fatty alcohol appears to increase the physiological efficiency of plant cells and boost the potential of the cells responsible for the growth and maturity of a plant.
  • Brassinolide is a plant hormone. The first isolated brassinosteroid, it was discovered when it was shown that pollen from rapeseed (Brassica napus) could promote stem elongation and cell division. The biologically active component was isolated and named brassinolide.
  • Silicic acid is important, very important. It acts as a bio-stimulant for the growth of the plant and helps the plant to overcome infections and stress factors like heat, drought and salinity.So, when bio-active silicic acid is added, plants show an improved growth, higher yield, reduced mineral toxicities and better disease and insect resistance. Moreover, silicon stimulates the beneficial micro-organisms in the (top) soil resulting in synergistic effects for the uptake of nutrients by the plant. Moreover, application of silicic acid along with half dose of recommended pesticide as foliar spray increased the grain and straw yield.
  • Salicylic acid is a monohydroxy benzoic acid that is benzoic acid with a hydroxy group at the ortho position. It has IUPAC name as 2-hydroxybenzoic acid.
  • Salicylic acid is a phenolic phytohormone and is found in plants with roles in plant growth and development, photosynthesis, transpiration, ion uptake and transport. Salicylic acid is involved in endogenous signalling, mediating in plant defence against pathogens. It plays a role in the resistance to pathogens by inducing the production of pathogenesis-related proteins. It is involved in the systemic acquired resistance in which a pathogenic attack on one part of the plant induces resistance in other parts. The signal can also move to nearby plants by salicylic acid being converted to the volatile ester methyl salicylate. Methyl salicylate is taken up by the stomata of the nearby plant, and once deep in the leaf, is converted back to salicylic acid to induce the immune response.
  • Mepiquat chloride is a quaternary ammonium salt consisting of equimolar amounts of mepiquat cations and chloride anions. It is having IUPAC name as l,l-dimethylpiperidin-l-ium;chloride.
  • a plant growth regulator it is used in agriculture to reduce vegetative growth including sprout suppression in garlic, leeks and onions. It has a role as a plant growth retardant and an agrochemical. It is a quaternary ammonium salt and a chloride salt. It contains a mepiquat.
  • Zinc is an essential micronutrient which means it is essential for plant growth and development, but is required in very small quantities. Although zinc requirements vary among crops, zinc leaf concentrations (on a dry matter basis) in the range 20 to 100 mg/kg are adequate for most crops. Zinc occurs in plants as a free ion, as a complex with a variety of low molecular weight compounds, or as a component of proteins and other macromolecules. In many enzymes, zinc acts as a functional, structural, or regulatory cofactor; a large number of zinc -deficiency disorders are associated with the disruption of normal enzyme activity (including that of key photosynthetic enzymes). Zinc deficiency also increases membrane leakiness as zinc-containing enzymes are involved in the detoxification of membrane-damaging oxygen radicals. Zinc may be involved in the control of gene expression; it appears important in stabilizing RNA and DNA structure, in maintaining the activity of DNA-synthesizing enzymes and in controlling the activity of RNA- degrading enzymes.
  • Zinc can also be supplied as a seed treatment, or by root-dipping of transplant.
  • the combinations of the present invention allow for a broad spectrum of pest control and has surprisingly improved plant vigour and yield.
  • the broad spectrum of the present combination also provides a solution for preventing the development of resistance.
  • the synergistic composition has very advantageous curative, preventive and systemic fungicidal properties for protecting cultivated plants.
  • said active ingredient composition can be used to inhibit or destroy the pathogens that occur on plants or parts of plants (fruit, blossoms, leaves, stems, tubers, roots) of different crops or useful plants, while at the same time those parts of plants which grow later are also protected from attack by such pathogens.
  • Active ingredient composition has the special advantage of being highly active against diseases in the soil that mostly occur in the early stages of plant development.
  • the synergistic composition of pesticide are used to protect the crops and plants from fungus and pests.
  • the lists of the major crops includes but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticumaestavum), Barley (Hordeumvulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetumglaucum), Sugarcane (Saccharumofficinamm) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachishypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linumusitatissimum), Sesame (Sesamum
  • berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.
  • the term "health of a plant” or “plant health” is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the method according to the invention, is increased independently of the pesticidal properties of the active ingredients used because the increase in health is not based upon the reduced disease pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of diseases pressure.
  • the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors.
  • the above identified indicators for the health condition of a plant may be interdependent or they may result from each other.
  • An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress.
  • One indicator for the condition of the plant is the yield.
  • Yield is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals).
  • the plant products may in addition be further utilized and/or processed after harvesting.
  • the yield of the treated plant is increased.
  • the yield of the plants treated according to the method of the invention is increased synergistically.
  • "increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the mixture according to the invention.
  • Increased yield can be characterized, among others, by the following improved proper-ties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
  • FW overall fresh weight
  • branches side shoots
  • the yield is increased by at least 5 %, preferable by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 % compared to the untreated control plants or plants treated with pesticides in a way different from the method according to the present invention.
  • the yield increase may even be higher.
  • a further indicator for the condition of the plant is the plant vigor.
  • the plant vigor becomes manifest in several aspects such as the general visual appearance.
  • the plant vigor of the treated plant is increased.
  • the plant vigor of the plants treated according to the method of the invention is increased synergistically.
  • Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobium nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g.
  • the improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
  • Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
  • the quality of the treated plant is increased.
  • the quality of the plants treated according to the method of the invention is increased synergistically.
  • enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention.
  • Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.
  • Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors.
  • Biotic and abiotic stress can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes.
  • "enhanced tolerance or resistance to biotic and/or abiotic stress factors” means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with a mixture according to the invention and (2.) that the negative effects are not diminished by a direct action of the mixture according to the invention on the stress factors, e.g. by its fungicidal action which directly destroys the microorganisms or diseases, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
  • One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation.
  • the purpose determines whether the “free” active ingredient and the “release rate” are relevant properties of a specific product.
  • composition fugicidal compositions comprising bioactive amounts of (A) a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) selected from group of phenyl benzamides, phenyl-oxo-ethyl thiophene amid, pyridinyl-ethyl-benzamides, furan carboxamides, oxathincarboxamides, pyrazole-4-carboxamides, pyridine carboxamides or mixture thereof; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil- fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one plant health additive selected from the group consisting
  • the present invention relates to the synergistic fungicidal composition
  • the synergistic fungicidal composition comprising bioactive amounts of (A) is 0.1 to 35% w/w of the composition; (B) is 0.1 to 45% w/w of the composition; and (C) is 0.001 to 20% w/w of the composition.
  • composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, thickener, wall forming materials, slow releasing agents and buffering agent.
  • inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, thickener, wall forming materials, slow releasing agents and buffering agent.
  • a wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading.
  • Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
  • wetting agent used herein for SC (Suspension concentrate) formulation examples include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenylsulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate.
  • wetting agent used herein for Oil dispersion (OD) formulation includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate.
  • wetting agent used herein for ZC includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
  • wetting agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation includes but not limited to sodium N-methyl-N-oleoyl taurate, alkylated naphtalene sulfonate, sodium salt, mixture of isomers of dibutylnaphthalene sulphonic acid sodium salt, sodium diisopropylnaphthalenesulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and nonionics such as tridexyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl
  • Examples of Wetting and spreading agent used herein for SC (Suspension concentrate) formulation, CS (Capsule Suspension), Oil dispersion (OD), SE (Suspo Emulsion) and WG (Wettable Granule), WDG (Water Dispersible Granule) formulation include but not limited to organic silicone type surfactant which includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, or mixture thereof etc;
  • organic silicone type surfactant works as super wetting agent, speading agent, penetrating agent which improves the bioefficacy.
  • a dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating.
  • Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules.
  • Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types.
  • dispersants For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
  • dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol- polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles
  • dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide -propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO
  • Examples of dispersants or dispersing agent used herein for ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Ethoxylated lignosulfonic acid salts, lignosulfonic acid salts, oxidized lignins, lignin salts, salts of styrenemaleic anhydride copolymers, polyvinyl alcohol, salts of partial esters of styrene-maleic anhydride copolymers, partial salts of polyacrylic acid and partial salts of polyacrylic acid terpolymers.
  • the surfactant is ligno sulfonate of calcium or sodium or mixtures thereof or a modified kraft lignin with a high sulfonic acid group , dibutylnaphthalenesulfonic acid , fatty acids, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols and of fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl-, octyl- or nonyl
  • Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide, polyethylene oxide and polypropylene oxide, polyacids or polybases.
  • Examples of dispersants or dispersing agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation include but not limited to naphthalene sulfonic acid, sodium salt condensated with formaldehyde, polyalcoxylated alkylphenol, naphthalenesulfonic acid formaldehyde condensate, methylnaphtaline-formaldehyde-condensate sodium salt, napthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate, lignin sulfonate sodium salt;
  • Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation.
  • antifoam agents there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air- water interface.
  • Antifoaming agent used herein for SC Sepension concentrate
  • Oil dispersion (OD) formulation and ZC mixed of SC Suspension concentrate formulation
  • silicone oil silicone compound, C10 ⁇ C20 saturated fat acid compounds or C8 ⁇ C10 aliphatic alcohols compound
  • silicone antifoam emulsion dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
  • Examples of Antifoaming agent used herein for WG (Wettable Granule) formulation includes but not limited to polydimethylsiolxane.
  • Anti-freezing agent for the present formulation is selected from various compounds and selectively used according to the formulation.
  • Anti-freezing agent used herein for SC (Suspension concentrate) and Oil dispersion (OD) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
  • Disintegrating agent used herein for the WG (Wettable Granule) formulation is selected from citric acid, succinic acid or the sodium bicarbonate.
  • Preservative used herein for the SC (Suspension concentrate) formulation, Oil dispersion (OD) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to l,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-l,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2- methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
  • Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspoemulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets.
  • Thickening, gelling, and antisettling agents generally fall into two categories, namely water- insoluble particulates and water- soluble polymers.
  • thickeners used herein for SC include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols, gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, sodium polyacrylate, modified starch;
  • thickeners used herein for ZC include but not limited to Xanthan gum ,Carboxy methyl cellulose, Attapulgite clay, Bentonite clay;
  • Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil.
  • This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated.
  • the carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
  • suspending agent used herein for SC Suspension concentrate
  • ZC mixture of SC Suspension concentrate and CS Capsule suspension
  • examples of suspending agent used herein for SC (Suspension concentrate) formulation and ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation include but not limited to Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
  • Carrier for the present formulation is selected from selected from various compounds and selectively used according to the formulation.
  • Carrier used herein for Oil dispersion (OD) formulation examples include but not limited to olive oil, kapok oil, castor oil, papaya oil, camellia oil, palm oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, palm (Elaeis guineensis) oil, neem (azadirecha indica) oil, eucalyptus oil, karanja (Milletia pinnata/Pongamia pinnata) oil, coconut oil, tall oil, alkyl ester of vegetable oils, (e.g.
  • rapeseed oil methyl ester or rapeseed oil ethyl ester rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.
  • diesel mineral oil
  • fatty acid amides e.g. Cl -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids
  • fatty acids tall oil fatty acids
  • alkyl esters of fatty acids e.g.
  • Ci Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols.
  • the above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
  • Certain vegetables/plant/seed oils as a carrier increases the bioefficacy and residual control of products through increase in penetration of active ingredients into leaf surface, improves the retention of active ingredietns on leaf surface especially on waxy leaf surface, improves the spreading properties and thereby improves the spray coverage.
  • Carrier used herein for WG (Wettable Granule) formulation includes but not limited to china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, com starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulfate, sodium chloride, gypsum, calcium sulfate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals,
  • Solvents used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (e.g. toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as Cl-ClO-alkylester of a C10-C22-fatty acid; or, methyl- or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-Heptanon , 3- heptanone, 2-hexanone, 5-methyl-2-hexanone , 5-methyl-3-heptan
  • Colorant used herein for the Granule (GR), Soil Applied Granule (SAG), Controlled Release granule (CR) formulation includes but not limited to crystal violet, thalocyano dye chlorinated, aerosol green FFB dye, rodamine, azo compound.
  • Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide -propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
  • Stabilizers or stabilizing agent used herein for the Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
  • Buffering agent used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Sodium hydroxide, potassium hydroxide, acetic acid, sulphuric acid, hydrochloric acid, ortho phosphoric acid, ammonium hydroxide.
  • Wall forming material used herein for the ZC (mixture of SC Suspension concentrate and CS Capsule suspension) formulation includes but not limited to Tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, toluene diisocyanate, diphenylmethene-4, 4’ -diisocyanate, polymethylene polyphenylene isocyanate, 2,4,4’ -diphenyl ether tri-isocyanate, 3,3 ’-dimethyl-4,4’ -diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate and 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate; Ammonia, hexamine, ethylenediamine, propylene- 1,3
  • the present invention highlights the synergistic effect of the combination of the at least one fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group or mixture thereof; at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil- fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; at least one more compound selected from plant health additive or mixture thereof.
  • SDHI Surface dehydrogenase inhibitors
  • EXAMPLE 5 WG (Water dispersible granule/Wettable Granule) formulation of Fluxapyroxad 5% + Copper 50% + Zinc 5%
  • synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
  • E Expected % control by mixture/combination of Compound A, Compound B and Compound C in a defined dose
  • X Observed % control by Compound A
  • Y Observed % control by Compound B
  • Z Observed % control by Compound C
  • FIELD BIO-EFFICACY STUDIES Field experiments of innovative combinations / ready-mix formulations comprising of (A) SDHI (Succinate dehydrogenase inhibitors); (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl; (C) At least one more compound from plant health additive, were carried out in different crops to study the synergism and their benefits.
  • % Sheath blight control Observations was recorded on disease severity in each treatment before and at 14 days after spray. The observations of severity of sheath blight disease were recorded using 0-9 grade (SES.IRRI 1996). Twenty randomly selected hills were scored as per scale. The percent disease index (PDI) of plants was calculated by the following formula.
  • Sheath blight disease Grading (0-9 scale) % Grain discoloration: Count the number of healthy and diseased grains per panicle. Record the observations from 10 panicles randomly selected per plot. Calculate % grain discoloration and % disease control.
  • the % disease control data used in Colby s formula to calculate the synergism.
  • Crops & Varieties Chilly, Nisha
  • Time of Application 75 days after transplanting. Applied 2 sprays at 15 days interval.
  • Method of Application Foliar spray with knapsack sprayer fitted with hollow cone nozzle. Water volume : 500 liter per hectare.
  • % Die-back (Colletotrichum capsici) disease control Observe randomly selected 10 plants per plot and rate disease severity (0-9 grade) of 5 twigs per plant. Calculate disease severity (PDI) and % disease control.
  • % Fruit rot Coldhouse rot (Colletotrichum capsici) disease control-Count the number of healthy and diseased fruits per plant. Observe such 10 plants per plot and calculate % disease control (i.e. reduction in fruit rot disease).
  • Healthy Fruit Count-Count the number of healthy fruits per plant. Record such observations from 10 plants per plot.
  • Time of Application 80 days after transplanting. Applied 2 sprays at 15 days interval.
  • Method of Application Foliar spray with knapsack sprayer fitted with hollow cone nozzle. Water volume : 550 liter per hectare.
  • Healthy Fruit Count-Count the number of healthy fruits per plant. Record such observations from 10 plants per plot. Table 5.
  • Time of Application 45 days after transplanting. Applied 2 sprays at 15 days interval.
  • Method of Application Foliar spray with knapsack sprayer fitted with hollow cone nozzle. Water volume : 500 liter per hectare.
  • Crops & Varieties Potato, Locker
  • Time of Application 50 days after transplanting. Applied 2 sprays at 10 days interval.
  • Method of Application Foliar spray with knapsack sprayer fitted with hollow cone nozzle. Water volume : 500 liter per hectare.
  • Agronomic Practices All other agronomic practices for weed control, insect control was followed ss per the requirement.
  • the ready-mix treatments (Tl, T2, T3 and T4) provides synergistic control of early blight disease of potato in comparison to all prior art treatments (T5 to T13).
  • Crops & Varieties Groundnut, GG-2 Location : Idar, India
  • Time of Application 75 days after sowing. Applied 2 sprays at 15 days interval.
  • % Leaf spot/Tikka disease (Cercospora arachidicola): Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control. % Rust disease control (Puccinia arachidis): Observe randomly selected 100 leaflet per plot and rate disease severity (0-9 grade). Calculate disease severity (PDI) and % disease control. Calculate synergism by using % disease control data.
  • Pod count at harvest-Count the number of pods per plant at the time of harvest. Record such observations from 10 plants per plot and workout the average.
  • GR/Gr- Granule/soil applied granule GR-SLGranule Slow release, SC Suspension concentrate, SE Suspo emulsion, OD Oil dispersion, SL Soluble liquid, WG/WDG-Water dispersible granule, WP Wettable powder, SG Soluble granule, L Liquid, SL Soluble liquid, EC Emulsifiable concentrate.
  • the field trials results shows many benefits/advantages of ready mix formulations comprising of (A) A fungicide selected from SDHI (Succinate dehydrogenase inhibitors) group; (B) at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall Inhibitors, compound with unknow mode of action, multisite contact fungicides, Ipflufenoquin, Pyridachlometyl or mixture thereof; (C) At least one more compound selected from plant health additive.
  • SDHI Stuccinate dehydrogenase inhibitors
  • B at least one more fungicide selected from the class of Qol (Quinone outside Inhibitors), Qil-fungicides (Quinone inside Inhibitors), Lipid or transport and membrane synthesis inhibitors, Sterol biosynthesis Inhibitors, Melanin synthesis in cell wall
  • All synergistic ready mixtures of the present invention shows excellent field trial results, shows synergistic control of plant diseases, provides higher level of disease control (increase % control), provides effective control of different diseases at a time, provides longer duration of control (residual control), increases plant growth, vigor, height, produces a greater number of tillers, shoots, branches, flowers, fruits, pods, square, bolls, seeds, grains etc. and overall biomass of the crop, which directly increases the yield of the crop.

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Abstract

L'invention concerne une composition agrochimique comprenant des fongicides SDHI. La présente invention concerne en outre des compositions fongicides synergiques comprenant des quantités bioactives d'un fongicide choisi dans le groupe des SDHI (inhibiteurs de succinate déshydrogénase) ou un mélange de ceux-ci; au moins un autre fongicide choisi parmi la classe des QoI (inhibiteurs externes de la quinone), des fongicides QiI (inhibiteurs internes de la quinone), des inhibiteurs de synthèse lipidique ou de transport et de membrane, des inhibiteurs de biosynthèse de Stérol, des inhibiteurs de synthèse de la mélanine dans la paroi cellulaire, un composé ayant un mode d'action non connu, des fongicides de contact multisite, l'ipflufénoquine, le pyridachlométyle ou un mélange de ceux-ci; au moins un autre composé choisi parmi des additifs pour la santé des plantes ou un mélange de ceux-ci. La présente invention concerne en outre un procédé de préparation desdites compositions en un rapport spécifique. La présente invention concerne en outre le procédé de préparation de ladite composition conjointement avec au moins un excipient inactif; et des formulations de celle-ci. La présente invention concerne en outre les compositions fongiques agrochimiques synergiques, le principe actif présent dans un rapport fixe présentant une synergie dans l'activité fongique.
PCT/IN2021/050721 2020-07-24 2021-07-23 Composition agrochimique comprenant des fongicides sdhi Ceased WO2022018767A1 (fr)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114451416A (zh) * 2022-03-12 2022-05-10 青岛海利尔生物科技有限公司 一种含苯并烯氟菌唑的农药组合物及其应用
CN114467956A (zh) * 2022-02-23 2022-05-13 青岛奥迪斯生物科技有限公司 一种含氟茚唑菌胺的农药组合物及其应用
CN114586791A (zh) * 2022-03-10 2022-06-07 青岛恒宁生物科技有限公司 一种含氟唑菌酰胺的杀菌组合物及其应用
CN114617129A (zh) * 2022-04-13 2022-06-14 青岛海利尔生物科技有限公司 一种杀菌组合物及其用途
WO2024009138A1 (fr) * 2022-07-04 2024-01-11 Upl Limited Composition fongicide
CN117687268A (zh) * 2024-02-01 2024-03-12 湖南初源新材料股份有限公司 感光性树脂组合物、感光干膜和覆铜板
EP4349171A1 (fr) * 2022-10-08 2024-04-10 Insignes Labs Sp. z o.o. Forme solide pour la préparation d'une dispersion aqueuse, dispersion aqueuse, concentré de suspension stable, dispersion aqueuse combinée et leurs utilisations
WO2024107910A1 (fr) * 2022-11-18 2024-05-23 Fmc Corporation Mélanges d'inhibiteurs de succinate déshydrogénase et de picolinamides
WO2024165719A1 (fr) * 2023-02-10 2024-08-15 Upl Mauritius Limited Combinaison fongicide
WO2024201289A1 (fr) * 2023-03-30 2024-10-03 Upl Limited Composition agrochimique stable
WO2024254580A3 (fr) * 2023-06-08 2025-02-13 Speedagro Inc. Mélange de composés actifs sur le plan agricole et d'adjuvants de pulvérisation

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015181009A1 (fr) * 2014-05-27 2015-12-03 Basf Se Mélanges ternaires comprenant des biopesticides et des fongicides qoi et des fongicides sdhi
WO2016170784A1 (fr) * 2015-04-20 2016-10-27 Mitsui Chemicals Agro, Inc. Formulation comprenant un engrais et une substance agrochimique

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015181009A1 (fr) * 2014-05-27 2015-12-03 Basf Se Mélanges ternaires comprenant des biopesticides et des fongicides qoi et des fongicides sdhi
WO2016170784A1 (fr) * 2015-04-20 2016-10-27 Mitsui Chemicals Agro, Inc. Formulation comprenant un engrais et une substance agrochimique

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114467956A (zh) * 2022-02-23 2022-05-13 青岛奥迪斯生物科技有限公司 一种含氟茚唑菌胺的农药组合物及其应用
CN114586791A (zh) * 2022-03-10 2022-06-07 青岛恒宁生物科技有限公司 一种含氟唑菌酰胺的杀菌组合物及其应用
CN114586791B (zh) * 2022-03-10 2024-03-08 青岛恒宁生物科技有限公司 一种含氟唑菌酰胺的杀菌组合物及其应用
CN114451416B (zh) * 2022-03-12 2023-09-15 青岛海利尔生物科技有限公司 一种含苯并烯氟菌唑的农药组合物及其应用
CN114451416A (zh) * 2022-03-12 2022-05-10 青岛海利尔生物科技有限公司 一种含苯并烯氟菌唑的农药组合物及其应用
CN114617129A (zh) * 2022-04-13 2022-06-14 青岛海利尔生物科技有限公司 一种杀菌组合物及其用途
CN114617129B (zh) * 2022-04-13 2023-09-15 青岛海利尔生物科技有限公司 一种杀菌组合物及其用途
WO2024009138A1 (fr) * 2022-07-04 2024-01-11 Upl Limited Composition fongicide
WO2024076250A1 (fr) * 2022-10-08 2024-04-11 Insignes Labs Sp. Z O.O. Forme solide pour la préparation d'une dispersion aqueuse, dispersion aqueuse, concentré stable, dispersion aqueuse combinée et leurs utilisations
EP4349171A1 (fr) * 2022-10-08 2024-04-10 Insignes Labs Sp. z o.o. Forme solide pour la préparation d'une dispersion aqueuse, dispersion aqueuse, concentré de suspension stable, dispersion aqueuse combinée et leurs utilisations
WO2024107910A1 (fr) * 2022-11-18 2024-05-23 Fmc Corporation Mélanges d'inhibiteurs de succinate déshydrogénase et de picolinamides
WO2024165719A1 (fr) * 2023-02-10 2024-08-15 Upl Mauritius Limited Combinaison fongicide
WO2024201289A1 (fr) * 2023-03-30 2024-10-03 Upl Limited Composition agrochimique stable
WO2024254580A3 (fr) * 2023-06-08 2025-02-13 Speedagro Inc. Mélange de composés actifs sur le plan agricole et d'adjuvants de pulvérisation
CN117687268B (zh) * 2024-02-01 2024-04-19 湖南初源新材料股份有限公司 感光性树脂组合物、感光干膜和覆铜板
CN117687268A (zh) * 2024-02-01 2024-03-12 湖南初源新材料股份有限公司 感光性树脂组合物、感光干膜和覆铜板

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